TestAmericaTHE LEADER IN ENVIRONMENTAL TESTING
TestAmerica St. Louis
TestAmerica Laboratories, Inc.
ANALYTICAL REPORT
REVISED
PROJECT NO. 1991-~35-11/o02
Honeywell Ponds
Lot #: F9E010213
Sean Chisek
Andrews Engineering, Inc.3300 Ginger Creek DriveSpr~gfield, IL 62711
TEST1\MKRICA LABORATORIES I INC.
January 7 I 2010
LOT # F9E070213-REVISED13715 Rider Trail North Earth (itv. MO 63045 t@) ~14.JgR.RSnn faY ~14.?QR.R7'i7 www.t~~tamt!rl~ain~_tom
1 of 57
F9E070213 (4): E-74 LOWERF9E070213 (5): E-67 LOWERF9E070213 (6): E-65 LOWER
TestAmerica St. Louis
Case NarrativeLOT NUMBER: F9E070213
Revised
This report contains the analytical results for the six samples received under chain of custody by STLSt. Louis on May 6. 2009. These samples are associated with your Honeywell Ponds project
The analytical results included in this report meet all applicable quality control procedure requirementsexcept as noted on the following page~
The test results in this report meet all NELAP requirements for parameters in which accreditations areheld by STL St. Louis. Any exceptions to NELAP requirements are noted in the case narrative. Thecase narrative is an integral part of this report.
All chemical analysis results are based upon sample as received, wet weight, unless noted otherwise.All radiochemistry results are based upon sample as dried and ground with the exception of tritium,unless requested wet weight by the client.
This report is revised to report Chemistry data on a wet-weight basis~
observationsINonconformances
Reference the chain of custody and condition upon receipt report for any variations on receipt conditionsand temperature of samples on receipt.
Cation Exchange Capacity
Batch 9133197:The samples were analyzed at a dilution due to high concentrations of target analytes~ The reportinglimit has been adjusted for the dilution since no analysis at a lesser dilution was performed.Affected Samples:F9E070213 (1): E-65 UPPER F9E070213 (6): E-65 LOWER
Gamma Spectroscopy
The presence of Thorium 234/Uranium 238 indicate the presence of Proactinium 234m. TheProactinium 234m results were calculated above the MDA in the samples, however, the results maybe biased high due to the low abundance at keyline 1001.3 keV.Affected Samples:F9E070213 (1): E-65 UPPERF9E070213 (2): E-67 UPPERF9E070213 (3): E-74 UPPER
Reactive Cyanide
LCS/MS recoveries for Reactive cyanide are outside the established QC limits. AU results are nondetect for this batch. Since this test is semi-qualitative no further action is required.Affected Samples:F9E070213 (6): E-65 LOWER
OT # F9E070213-REVISED 2 of 57
TestAmerica St. Louis
TCLP Preparation
Due to limited sample volume, a reduced sample amount was used for the TCLP extraction. The 20:1leachate:sample ratio was maintained.Affected Samples:F9E070213 (1): E-65 UPPER F9E070213 (6): E-65 LOWER
Trace ICP Metals
Batch 9131193:The sample was analyzed at a dilution due to high concentrations of target analytes. The reportinglimit has been adjusted for the dilution since no analysis at a lesser dilution was performed.Affected Samples:F9E070213 (5): E-67 LOWER
There were no nonconformances or observations noted with any other analysis on this lot.
LOT # F9E070213-REVISED 3 of 57
TestAmerica St. Louis
METIIODSSUMMAKY
P9B070213
PARAMETER
Bulk DensityCation-Exchange CapacityChlorideGamma Spectroscopy - Radium-226 & HitsIsotopic Thorium by Alpha SpectroscopyIsotopic Uranium by Alpha SpectroscopyMercury in Liquid Waste (Manual Cold-Vapor)Method D2216 Percent H20 Dry 105 Degrees C, weighPaint Filter TestReactive CyanideReactive SulfideSoil and Waste pHSulfideTotal Organic CarbonTrace Inductively Coupled Plasma (Iep) MetalsTrace Inductively Coupled Plasma (Iep) Metals
References:
ASTM D-5057-90SW846 9081MCAWW 300. OA
EML GA-Ol-R MODEML A-OI-R MODEML A-01-R MODSW846 7470AASTM Mois·ture,SW846 9095SW846 7.3.3SW846 7.3~4
SW846 9045CMCAWW 376.1SW846 9060SW846 6010BSW846 6010B
PREPARATIONMETHOD
ASTM D-5057-90SW846 9081MCAWW 300. OA
SW846 1311/7470. ASTM ASTM 2216
SW846 9095SW846 7.3.3SW846 7.3.4SW846 DI-LEACHAMCAWW 376.1SW846 9060
SW846 1311/3010
ASTM
EML
MCAWW
SW846
Annual Book.Of ASTM Standards.
"ENVIRONMENTAL MEASUREMENTS LABORATORY PROCEDURES MANUAL"
HASL-300 28TH EDITION! VOLUME I and II DEPARTMENT OF ENERGY
"Methods for Chemical Analysis of Water and Wastes" I
EPA-600/4-79-020, March 1983 and subsequent revisions.
"Test Methods for Evaluating Solid Waste, Physical/ChemicalMethods", Third Edition, November 1986 and its updates.
LOT # F9E070213-REVISED 4 of 57
TestAmerica St. Louis
SAMPLE SUMMARY
F9E07·0213
wo # SAMPLE# CLIENT SAMPLE ID
LCJNP 001 E-65 UPPER.LCJPG 002 E-67 UPPERLCJPM 003 E-74 UPPERLCJPV 004 E-74 LOWERLCJP3 005 E-67 LOWERLCJP6 006 E-65 LOWER
NOTE(S) :
- The analytical results of the samples listed above are presented on the following pages•
• All calculations arc performed before rounding lQ avoid round-off errors in calculated results.
• Results noted as ttND II were not detected at or above the stated limit.
- This report must not be reproduced t excepl in full, without the written approval of the laboratory.
- Results for the following. parameters are never reported on a dry weight basis: colort corrosivity, density, tlashpoint, ignitability ~ layers~ od~r,
paint filter test, pH t porosity pressure, reactivity I redox potential, specifiC gravity, spot testS7 solids, solubility, temperature, viscosity t and weight_
OT # F9E070213-REVISED
SAMPLED SAMP
DATE TIME
05/04/09 14:0005/05/09 10:1505/06/09 10:3005/06/09 10:3005/05/09 10:15.05/04/09 14: 00
5 of 57
TestAmerica St. Louis
An~ews Engineering J Inc.
Client Sample ID: E-65 UPPER
TOTAL Metals
Lot-sample i ... : F9E070213-001Date Sampled.. _: 05/04/09 14:00 Date Received•• : 05/06/09'Moisture..•.• : 48
Matrix••.•... : SOLID
WORKORDER #RESULTPARAMETER
REPORTING PREPARATION-LIMIT UNITS METHOD ·ANALYSIS DATE------- ------ ----- ---------
Dilution Factor: 1
Prep Batch I ... : 9131193Uranium 121 50.0 mg/kg SW846 6010B
Analysis Time .. : 19:44
05/12-05/15/09 LCJNP1A3
LOT # F9E070213-REVISED 6 of 57
Andrews Engineering, Inc.
Client Sample ID: E-65 UPPER
TCLP Metals
TestAmerica St. Louis
Lot-~le I ... : F9E070213-001Date ~led..• : 05/04/09 14:00Leach Date..... : 05/13/09
Date Received.• : 05/06/09Leach Batch I .. : P913310
Matrix••••••. : SOLID
REPORTING PREPARATION- WORKPARAMETER RESULT LIMIT UNITS METHOD ANALYSIS DATE ORDER #
Prep Batch I ... : 9134386Silver ND 20.0 ug/L SW846 6010B 05/14-05/16/09 LCJNPIAJ
Dilution Factor: 1 Analysis Time .. : 00:19
Arsenic 427 20.0 ug/L SWB46 6010B 05/14-05/16/09 LCJNPLAKDilution Factor: 1 Analysis Time .. : 00:19
Barium 60.0 B,J 100 ug/L SW846 6010B 05/14-05/16/09 LCJNPlALDilution Factor: 1 Analysis Time .. : 00:19
Cadmium ND 10.0 ug/L SW846 60l0B 05/14-05/16/09 LCJNP1AMDilution Factor: 1 Analysis Time .. : 00:19
Chromium NO 20.0 ug/L SW846 GOlOB 05/14-05/l6/09 LCJNPIANDilution Factor: 1 Analysis Time .. : 00:19
Lead ND 40.0 ug/L SW846 GOlOB 05/14-05/16/09 LCJNP1APDilution Factor: 1 Analysis Time .. : 00:19
Selenium ND 30.0 ug/L SW846 6010B 05/14-05/16/09 LCJNP~Q
Dilution Factor: 1 Analysis Time .. : 00:19
Analysis performed in accordance with USEPA Toxicity Characteristic Leaching Procedure Method 1311
B Estimated resull:. Result is less than RL.
J Method blank contamination. The associated method blank contains the target analyte at a reportable level.
Dilution Factor: 1
Prep BatCh I ... : 9139074Mercury ND
NOTE(S) :
1.0 ug/L SW846 7470AAnalysis Time .. : 13:21
05/19/09 LCJNP1AR
LOT # F9E070213-REVISED 7 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client Sample ID: E-65 UPPER·
General Chemistry
Lot-Sample i : F9E070213-001Date S~led : 05/04/09 14:00'MOisture.•.•• : 48
Work Order # •.• : LCJNPDate Received.. : 05/06/09
Matrix••••.•.•• : SOLID
PARAMETERpH (solid)
RESULT12.4
Dilution Factor: 1
PREPBATCH #9132177
cation Exchangecapacity
10.2 2.5 meq/1DOg SW846 9081 05/15-05/20/09 9133197
Dilution Factor: 5 Analysis Time .. : 00:00
Dilution Factor: 1
Chloride 18.3 J 2.0 mg/kg MCAWW 300. OA
Analysis Time .. : 00:00
06/01-06/02/09 9152365
Density
Paint Filter Test
1.5 g/mLDilution Factor: 1
No unitsDilution Factor: 1
ASTM D-S057-90Analysis Time .. : 00:00
SW846 9095Analysis Time .. : 00:00
06/02/09
05/09/09
9153158
9131058
Percent Moisture 48.3 0.10 '"Dilution Factor: 1
ASTM MOisture. % 05/09-05/11/09 9131062Analysis Time .. : 00:00
'rotal OrganicCarbon
0.77 B 2.0 g/kg SW846 9060 OS/21/09 9141537
Dilution Factor: 1 Analysis Time .. : ~3:38
Dilution Factor: 1
Total Sulfide
NOTE (S) :
ND 10.0 mg/kg MCAWW 376.1ADalysis Time .. : 00:00
06/02/09 9152376
RL Reporting Limit
J Method blank contamination. The associated method blank contains the target anaIyte at a reporlable level.
CNF Contains No Free Liquid
B Estimated result. Result is less than RL.
LOT # F9E070213-REVISED 8 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client S~le ID: E-67 UPPER
TOTAL Metals
Lot-sample , ..• : F9E070213~002
Date sampled•.. : 05/05/09 10:15 Date Received.. : 05/06/09'Moisture..... : 47
Matr±X .: SOLID
REPORTING PREPARATION-_PARAMET_E_R R_ES_UL_T LIMIT _UN_I_T_S~ l"1E_TH_O_D AN.ALYSIS DATE
WORKORDER #
Dilution Factor: 1
Prep Batch 1_ .. : 9131193Uranium 98 .4:
LOT # F9E070213-REVISED
50.0 mg/kg 8W846 6010BAnalysis Time .. : 19:51
05/12-05/15/09 LCJPG~V
9 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client Sample In: E-67 UPPER
TCLP Metals
Lot-~le I : F9E07D213-002Date Sampled : 05/05/09 10:15Leach Date••••• : 05/13/09
Date Received.. : 05/06/09Leach Batch # •• : P913310
Matrix•.•.... : SOLID
REPORTING PREPARATION- WORKPARAMETER RESULT LIMIT UNITS METHOD ANALYSIS DATE ORDER #
Prep Batch # ..• : 9134386Silver ND 20.0 ug/L SW846 6010B 05/14-05/16/09 LCJPG~
Dilution Factor: 1 Analysis Time .. : 00:26
Arsenic 300 20 .. 0 ug/L SW846 6010B 05/14-05/16/09 LCJPG1AKDilution Factor: 1 Analysis Time .. : 00:26
Barimn 62.8 B,J 100 ug/L SW846 6010B 05/14-05/16/09 LCJPGlALDilution Factor: 1 Analysis Time .. : 00:26
Cadmium 1.8 B 10.0 ug/L SW846 6010B 05/14-05/16/09 LCJPGLNMDilution Factor: 1 Analysis Time .. : 00:26
Chromium ND 20.0 ug/L SW846 60l0B 05/14-05/16/09 LCJPGlANDilution Factor: 1 Analysis Time .. : 00:26
Lead NO 40.0 ug/L SW846 60l0B 05/14-05/16/09 LCJPG~P
Dilution Factor: 1 Analysis Time .. : 00:26
Selenium ND 30.0 ug/L SW846 6010B 05/14-05/16/09 LCJPG1AQDilution Factor: 1 Analysis Time .. : 00:26
Analysis performed in accordance with USEPA Toxicity Characteristic Leaching Procedure Method 1.311
B Estimated resuU. Result is less than RL.
J Method blank contamination. The associated method blank contains the target analyte at a reportable level.
Dilution Factor: 1
LCJPGl..AR05/19/09SW846 7470AAnalysis Time .. : 13:23
ug/L1 .. 0
NOTE (S) :
Prep BatCh I .. a: 9139074Mercury 0 .44 B
LOT # F9E070213-REVISED 10 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client Sample ID: E-67 UPPER.
General Chemistry
Lot-S~le 1 : F9E070213-002Date S~led : 05/05/09 10:15% MOisture ••••• : 47
Work Order # ... : LCJPGDate Received•. : 05/06/09
Matrix••••..... : SOLID
PREPARATION- PREP
PARAMETER RESULT RL UNITS f'.mTHOD ANALYSIS DATE BATCH #
pH (solid) 12.4 0.10 No Units SW846 9045C 05/12/09 9132177
Dilution Factor: 1 Analysis Time~~: 00:00
Paint Filter Test CNF No Units SW846 9095 05/09/09 9131058Dilution Factor: 1 Analysis Time~.: 00:00
Percent Moisture
NOTR{S) :
RL Reporting Unlit
CNF Contains No Free Liquid
46.6 0 .. 10 !IiDilution Factor: 1
ASTM Moisture,' 05/09-05/11/09 9131062Analysis Time~~: 00:00
LOT # F9E070213-REVISED 11 of 57
Andrews Engineering, Inc: _
Client Sample ID: E-74 UPPER
TOTAL Metals
Lot-~le # ... : F9E070213-003Date S~led••• : 05/06/09 10:30 Date Received.. : 05/06/09t MOisture..... : 48
TestAmerica St. Louis
Matrix•••••.• : SOLID
P.ARAMETER RESULTWORKORDER #
Dilution Factor: 1
Prep Batch # ... : 9131193Uranium 83 • 9
LOT # F9E070213-REVISED
50,,0 mg/kg SW846 6010BAnalysis Time .. : 19:57
05/12-05/15/09~V
12 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client Sample ID: B-74 UPPER
TCLP Metals
Lot-S~le I ... : F9E070213-003Date Sampled••. : 05/06/09 10:30LeaCh Date..... : 05/13/09
Date Received.. : 05/06/09Leach BatCh I .. : P913310
Matrix : SOLID
P.ARA.!liJETER RESULTREPORTING PREPARATION-LIMIT UNITS METHOD ANALYSIS DATE----- ---------
WORKORDER #
Prep Batch :JI: ••• : 9134386Silver ND 20.0 ug/L SW846 60l0B 05/14-05/16/09 LCJPM~
Dilution Factor: 1 .Analysis Time .. : 00:32
Arsenic 555 20.0 ug/L SW846 6010B 05/14-05/16/09 LCJPMlAKDilution Factor: 1 Analysis Time .. : 00:32
Barimn 34.0 B,J 100 ug/L SW846 6010B 05/14-05/16/09 LCJPM1ALDilution Factor: 1 Analysis Time .. : 00:32
CadmiUDl 1.3 B 10.0 ug/L SW846 6010B 05/14-05/16/09 LCJBM1AMDilution Factor: 1 Analysis Time .. : 00:32
Chromium 30.3 20.0 ug/L SW846 6010B 05/14-05/16/09 LCJPM1ANDilution Factor: 1 Analysis Time .. : 00:32
Lead ND 40.0 ug/L SW846 6010B 05/14-05/16/09 LCJPM1APDilution Factor: 1 Analysis Time .. : 00:32
Selenium ND 30.0 ug/L SW846 6010B 05/14-05/16/09 LCJPM1AQDilution Factor: 1 Analysis Time .. : 00:32
Analysis performed in accordance with USEPA Toxicity Characteristic Leaching Procedure Method 1311
B Estimated result. Result is less than RL.
J Method blank contamination. The associated method blank contains the target analyte at a reportable level.
Dilution Factor = 1
Prep Batch i ... : 9139074Mercury 0.58 B
NOTE(S):
1.0 ug!L SW846 7470AAnalysis Time .. : 13:25
05/19/09 LCJPMJ.AR
LOT # F9E070213-REVISED 13 of 57
TestAmerica St. Louis
Andrews Bngineering, Inc.
Client Sample ID: E-74 UPPER
General Chemistry
Lot-S~le I ... : F9E070213-003Date sampled•.. : 05/06/09 10:30% Moisture••.•. : 48
Work Order I ... : LCJPMDate Received•. : 05/06/09
Matrix.......•. : SOLID
PREPARATION- PREPPARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH it
pH (solid) 12.5 0.10 No Units S1f846 9045C 05/12/09 9132177Dilution Factor: 1 Analysis Time .. : 00:00
Paint Filter Test CNF No Units SW846 9095 05/09/09 9131058Dilution Factor: 1 Analysis Time .. ~ 00:00
Percent Moisture
NOTE (S) :
RL Reporting Limit
CNF Contains No Free Liquid
48.4 0.10 ,Dilution Factor: 1
ASTM Moisture, , 05/09-05/11/09 9131062Analysis Time .. : 00:00
LOT # F9E070213-REVISED 14 of 57
TestAmerica St. Louis
Andrews Engineering. Inc.
Client Sample In: E-74 LOtmR
TOTAL Meta1s
Lot-Sample I ... : F9E070213-004Date Sampled••. : 05/06/09 10:30 Date Received.. : 05/06/09'MOisture..... : 48
Matrix••••••. : SOLID
WORKORDER #RESULTPARAMETER
REPORTING PREPARATION-LIMIT UNITS METHOD ANALYSIS DATE------- ------ ----- ------~-----
Dilution Factor: 1
Prep Batch i ... : 9131193uranium. 188 50.0 mg/kg SW846 6010B
Analysis Time .. : 20:04
05/12-05/15/09 LC~V
LOT # F9E070213-REVISED 15 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client Sample In: E-74 LOWER
TCLP Meta1s
Lot-Sample D._.: F9E070213-004Date sampled.•. : 05/06/09 10:30LeaCh Date•.... : 05/13/09
Date Received•. : 05/06/09Leach Batch I ... : P913310
Matrix.•..... : SOLID
PARAMETERREPORTING PREPARATION-LIMIT UNITS METHOD ANALYSIS DATE----- ---------
WORKORDER #
Prep Batch # ••• : 9134386Silver ND 20.0 ug/L SW846 6010B 05/14-05/16/09 LCJPV1AJ
Dilution Factor: 1 Analysis Time .. : 00:38
Ars~c 88.1 20.0 ug/L SW846 6010B 05/14-05/16/09~Dilution Factor: 1 Analysis Time .. : 00:38
BarilDD. 26.3 B,J 100 ug/L SW846 6010B 05/14-05/16/09 LC~Dilution Factor: 1 Analysis Time .. : 00:38
Cadmium ND 10.0 ug/L SW846 6010B 05/14-05/16/09 LCJPV1AMDilution Factor: 1 Analysis Time .. : 00:38
Chromium ND 20.0 ug/L SW846 6010B 05/14-05/16/09 LCJPV1ANDilution Factor: 1 Analysis Time .. : 00:38
Lead ND 40.0 ug/L SW846 6010B 05/14-05/16/09 LCJPV1APDilution Factor: 1 Analysis Time .. : 00:38
Selenium ND 30.0 ug/L SW846 6010B 05/14-05/16/09 LCJPVIAQDilution Factor: 1 Analysis Time .. : 00:38
Dilution Factor: 1
Prep Batch i ... : 9139074Mercury ND
NOTE(S):
1.0 ug/L SW846 7470AAnalysis Time .. : 13:27
05/19/09 LCJPV1AR
Analysis performed in accordance with USEPA Toxicity Cbaracteristic Leaching Procedure Method 1311
B Estimated result. Result is less than RL.
J Method blank contamination. The associated method blank contains the target analyte at a reportable level.
LOT # F9E070213-REVISED 16 of 57
TestAmerica St. Louis
Andrews Engineering. J:nc .
Client sample ID: E-74 LOWER.
General Chemistry
Lot-Sample 1_ •• : F9E070213-004Date Sampled_._: 05/06/09 10:30l Moisture..... : 48
Work Order # ... : LCJl?VDate Received.• : 05/06/09
Matrix_ ... __ ... : SOLID
PREPARATION- PREPPARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH #
pH (solid) 12 .. 6 0.10 No Units SW846 9045C 05/12/09 9132177Dilution Factor~ 1 Analysis Time .. : 00:00
Paint Filter Test CNF No Units SW846 9095 05/09/09 9131058Dilution Factor: 1 Analysis Time .. : 00:00
Percent Moisture
HOTE(S):RL Reporting Limit
CNF Contains No Free Liquid
48.4 0.10 tDilution Factor: 1
ASTM Moisture,' 05/09-05/11/09 9131062Analysis Time .. : 00:00
LOT # F9E070213-REVISED 17 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client Sample ID: £-67 LONER
TOTAL Metals
Lot-sample I ... : F9E070213-00SDate Sampled••• : 05/05/09 10:15 Date Received•• : 05/06/09t MOisture..... : 48
Matrix : SOLID
REPORTING PREPARATION- WORK_PARAl'tmTE_R RE_S_UL_T LIMIT _UN_I_T_S ME_T_H_O_D ANALYSIS DATE ORDER #
Dilution Factor: 2
Prep BatCh I ... : 9131193Uranium 1280
OT # F9E070213-REVISED
100 mg/kg SW846 6010BAnalysis Time .. : 20;10
05/12-05/15/09 LCJP3~V
18 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client sample m: :£-67 LOWER
TCLP Metals
Lot-~le I : F9E070213-005Date sampled : 05/05/09 10:15LeaCh Date : 05/13/09
Date Received.• : 05/06/09Leach Batch # .. : P913310
Matrix..•.•.• : SOLID
METHODPARAMETERREPORTINGLIMIT UNITS-----
PREPARATIONANALYSIS DATE---------
WORKORDER #
Prep Batch # ... : 9134386Silver ND 20.0 ug/L SW846 6010B 05/14-05/16/09 LCJP3lAJ
Dilution Factor: i Analysis Time .. : OO~45
Arsenic 104 20.0 ug/L SW846 6010B 05/14-05/16/09 LCJP31AKDilution Factor: 1 Analysis Time .. : 00:45
Barium 50.4 B,J 100 ug/L SW846 60108 05/14-05/16/09 LCJP31ALDilution Factor: 1 Analysis Time .. : ·00:45
Cadmium ND 10.0 ug/L SW846 6010B 05/14-05/16/09 LCJP31AMDilution Factor: 1 Analysis Time .. : 00:45
Chromium ND 20.0 ug/L SW846 6010B 05/14-05/16/09 LCJP31ANDilution Factor: 1 Analysis Time .. : 00:45
Lead ND 40.0 ug/L SW846 6010B 05/14-Q5/16/09 LCJP31APDilution Factor: 1 Analysis Time .. : 00:45
Selenium ND 30.0 ug/L SW846 6010B 05/14-05/16/09 LCJP31AQDilution Factor: 1 Analysis Time .. : 00:45
Analysis performed in accordance with USEPA Toxicity Char4lcteristic Leaching Procedure Method 1311
B Estimated result. Result is less than RL.
J Method blank comamination. The associated method blank contains the target analyte at a reportable level.
Dilution Factor: 1
LCJP31AR05/19/09SW846 7470AAnalysis Time .. : 13:29
ug/L1.0
NOTE(S) :
Prep BatCh 1 __ .: 9139074
Mercury ND
LOT # F9E070213-REVISED 19 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client Samp1e ID: E-67 LOWER
General Chemistry
Lot-Sample I ... : F9E070213-00SDate S~led•.• : 05/05/09 10:15% Moisture••.•• : 48
Work Order i ... : LCJP3Date Received•• : 05/06/09
Matrix : SOLID
PREPARATION- PREP
PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH #
pH (solid) 12.6 0.10 No Units SW846 9045C 05/12/09 9132177
Dilution Factor: 1 Analysis Time .. : 00:00
Paint Filter Test CNF No Units SW846 9095 05/09/09 9131058
Dilution Factor: 1 Analysis Time .. : 00:00
Percent Moisture
HQTE(S) :
RL Reporting Limit
CNF Contains No Free Liquid
47.9 0.10 "Dilution Factor: 1
ASTM MOisture, t 05/09-05/11/09 9131062Analysis Time .. : 00:00
LOT # F9E070213-REVISED 20 of 57
Andrews Engineering, Inc ..
Client sample ID: :8-65 LOWER
TOTAL Meta1s
Lot-Sample i ... : F9E070213-006Date Sampled••. : 05/04/09 14:00 Date Received•. : 05/06/09, Moisture..... : 50
TestAmerica St. Louis
Matrix : SOLID
PARAMETER RESULTWORKORDER #
Dilution Factor: 1
Pr~ BatCh # ... : 9131193Uranium 391 50.0 .mg/kg SW846 6010B
Analysis Time .. : 20:16
05/12-05/15/09 LCJP61A5
LOT # F9E070213-REVISED 21 of 57
------------------------------~----
TestAmerica St. Louis
.Andrews Engineering, Inc.
Client Sample In: B-65 LOWER
TCLP Metals
Lot-Sample i : F9E070213-006Date Sampled : 05/04/09 14:00LeaCh Date : 05/13/09
Date Received.. : 05/06/09Leach Batch I ... : P913310
Matrix..•.... : SOLID
PARAMETER RESULTREPORTING PREPARATION-LIMIT UNITS METHOD ANALYSIS DATE----- ---------
WORKORDER #
Analysis performed in accordance with USEPA Toxicity Characteristic Leachjng Procedure Method 1311
B Estimated result. Result is less than RL.
J Method blank contamination. The associated method blank contains the target analyte at a reportable level.
2040 ug/L SW846 GOlOB 05/14-05/16/09 LCJP61AMDilution Factor: 1 Analysis Time .. : 00:51
20.0 ug/L SW846 60l0B 05/14-05/16/09 LCJP61ANDilution Factor: 1 Analysis Time .. ; 00:51
100 ug!L SW846 601DB 05/14-05/16/09 LOJP61APDilution Factor: 1 Analysis Time .. : 00:51
10.0 ug/L SW846 GOlOB 05/14-05/16/09 LCJP61AQDilution Factor: 1 Analysis Time .. : 00:51
20.0 ug/L SW84"6 GOlOB 05/14-05/16/09 LCJP61ARDilution Factor: 1 Analysis Time .. : 00:51
40.0 ug/L SW846 GOlOB 05/14-05/16/09 LCJP61ATDilution Factor: 1 Analysis Time .. : 00:51
30.0 ug/L SW846 6010B 05/14-05/16/09 LCJP61AUDilution Factor: 1 Analysis Time .. : 00:51
Dilution Factor: 1
LCJP61AV05/19/09SW846 7470AAnalysis Time .. : 13:31
ug/L1.0
NQTE(S) :
Prep BatCh i ... : 9134386Silver ND
Prep BatCh I ... : 9139074Mercury 0 .24 B
Arsenic 128
Barium 54.3 B,J
Cadmium ND
Chromium ND
Lead ND
Selenium
LOT # F9E070213-REVISED 22 of 57
TestArnerica St. Louis
Andrews Engineering, Inc ..
Client Sample m: E-65 LOWER
General Chemistry
Lot-sample I ... : F9E070213-006Date Sampled..• : 05/04/09 14:00'Moisture..... : 50
Work Order i ... : LCJP6Date Received•• : 05/06/09
Matrix........• : SOLID
PREPARATION- PREP
PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH #
pH (solid) 12.5 0.10 No Units SW846 9045C 05/12/09 9132177
Dilution Factor: 1 Analysis Time ... : 00:00
Cation Exchange 9.1 2.5 meq/lOOg 8W846 9081 0'5/15-05/20/09 9133197Capacity
Dilution Factor: 5 Analysis Time .. : 00:00
Chloride 24.3 J 2.0 mg/kg MCAIiIf 300.0A 06/01-06/02/09 9152365Dilution Factor: 1 Analysis Time .. : 00:00
Density 1.3 g/mL ASTM D-5057-90 06/02/09 9153158
Dilution Factor: 1 Analysis ~ime .. : 00:00
Paint Filter Test CNF No Units SW846 9095 05/09/09 9131058Dilution Factor: 1 Analysis Time .. : 00:00
Percent Moisture 50.1 0.10 %Dilution Factor: 1
ASTM MOisture, , 05/09-05/11/09 9131062Analysis Time .. : 00:00
Dilution Factor: 1
Reactive Cyanide ND 0.25 mg/kg SW846 7 .. 3.3Analysis Time .. : 00:00
OS/25-05/26/09 9145035
RL Reporting Umit
J Method blank contamination. The associated method blank contains the target analyte at a reportable level.
CNF Contains No Free Liquid
Dilution Factor: 1
Dilution Factor: 1
9141537
9145034
9152376
OS/21/09
OS/25/09
06/02/09
SW846 9060
Analysis Time .. : 13:41
MCAWW 376.1Analysis Time .. : 00:00
SW846 7.3.4Analysis Time .. : 00:00
mg/kg
mg/kg
g/kg
10.0
2.0
22.2Dilution Factor: 1
ND
2.7
ND
Total OrganicCarbon
ROTE (S) :
Total Sulfide
Reactive Sulfide
LOT # F9E070213-REVISED 23 of 57
TestAmerica St. Louis
METHOD BLANK REPORT
TOTAL Metals
Client Lot I ... : F9E070213 Matrix•••..•... : SOLID
REPORTING PREPARATION-_PARAMET_E_R R_E_S_U_L_T LIMIT ....;..UN__I_T..;..S ME_TH_O_D_----- ANALYSIS DATE
WORKORDER #
MB Lot-Sample #: F9EII0000-193 Prep Batch # ... : 9131193Uranium ND 50.0 mg/kg SW846 6010B
Dilution Factor: 1
Analysis Time .. ~ 13:17
:HOTE(S) :
Calculations are performed before rounding to avoid round-off errors in calculated results.
OT # F9E070213-REVISED
05/12-05/14/09 LCP951AA
24 of 57
METHOD BI..d\NX REPORT
TCLP Metals
Client Lot I ... : F9E070213
TestAmerica St. Louis
·Matrix.•••••••• : SOLID
PARAMETER RESULTREPORTINGLIMIT UNITS----- l"tETHOD
WORKORDER i
MB Lot-Sample #: F9E130000-303 Prep Batch #~ •• : 9139074Leach Date..... : 05/13/09 Leach BatCh I .. : P913310Mercury NO 1.0 ug/L SW846 7470A
Dilution Factor: 1
Analysis Time .. : 13:02
05/19/09 LCXAF1AJ
MB Lot-Sample I: F9E130000-303 Prep BatCh fi ..• : 9134386Leach Date.•... : 05/13/09 Leach Batch ft .• : P913310Arsenic ND 20.0 ug/L SW846 6010E
Dilution Factor: 1
Analysis Time .. : 23:21
05/14-05/15/09 LCXAF1AC
Barium 3.9 B 100 ug/LDilution Factor: 1
Analysis Time .. : 23:21
SW846 6010B 05/14-05/15/09 LCXAF1AD
Cadmium ND 10.0 ug/L SW846 6010B 05/14-05/15/09 LCXAF1AE
Lead 3.6 B 40.0 ug/L 8W846 6010B 05/14-05/15/09 LCXAF1AGDilution Factor: 1
Analysis Time .. : 23:21
Selenium ND 30 .. 0 ug/L SW846 6010B 05/14-05/15/09 LCXAFIAHDilution Factor: 1
Analysis Time .. : 23:21
Calculations are performed before rounding to avoid round-off errors in calculated results.
B Estimated result. Result is less than RL.
Chromium
Silver
NOTE(S) :
ND
Dilution Factor: 1
Analysis Time .. : 23:21
20.0 ug/LDilution Factor: 1
Analysis Time .. : 23:21
20.0 ug/LDilution Factor: 1
Analysis Time .. : 23:21
SW846 60l0B
SW846 6010B
05/14-05/15/09 LCXAF1AF
05/14-05/15/09 LCXAF1AA
LOT # F9E070213-REVISED 25 of 57
· TestAmerica St. Louis
METHOD BLANK REPORT
General Chemistzy
Client Lot I ... : F9E070213 Matrix............ : SOLID
REPORTING PREPAR.A.TION- PREPP.ARAJvIETER RESULT LIMIT UNITS IvIETHOD ANALYSIS DATE BATCH #Cation Exchange Work Order #: LCWVMlAA MB Lot-Sample #: F9E130000-197
CapacityND 0.50 meq/1OOg SW846 9081 05/15-05/20/09 9133197
Dilution Factor: 1
Analysis Time .. : 00:00
Chloride Work Order #: LD6PP1AA ME Lot-Sample #: F9F01OOOO-3650.24 B 2.0 mg/kg MCAJfW 300.0A 06/01-06/02/09 9152365
Dilution Factor: 1
Analysis Time .. : 00:00
Reactive Cyanide Work Order #: LDN3J1AA MB Lot-Sample #: F9E250000-035NO 0.25 mg/kg SW846 7.3.3 OS/25-05/26/09 9145035
Dilution Factor: 1
Analysis Time .. : 00:00
Reactive Sulfide Work Order #: LDN3H1AA MB Lot-Sample #: F9E2S0000-034ND 22.2 mg/kg SW846 7.3 .. 4 OS/25/09 9145034
Dilution Factor: 1
Analysis Time .. : 00:00
Total Organic Work Order #: LDH7D1AA MB Lot-Sample #: D9E210000-S37Carbon
ND 2.0 g!kg SW846 9060 OS/21/09 9141537Dilution Factor~ 1
Analysis Time .. : 13:21
Total Sulfide
NOTE (S) :
ND
Work Order #: LD5R11AA ME Lot-Sample #: F9F010000-37610.0 mg/kg MCAWW 376.1 06/02/09 9152376
Dilution Factor: 1Analysis Time .. : 00:00
Calculations are performed before rounding to avoid round·off errors in calculated resul[S.
B Estimated result. Result is less than RL.
OT # F9E070213-REVISED 26 of 57
TestAmerica St. Louis
LABORATORY CONTROL SAMPLE EVALUATION REPORT
TOTAL Metals
. Client Lot I. __ : F9E07D213 Matrix.•.•••••• : SOLID
PARAMETERPERCENTRECOVERY
RECOVERY
LIMITSPREPARATION-
M_E_T_H_O_D ANALYSIS DATE WORK ORDER #
LCS Lot-S~le#: F9Ell0000-l93 Pr~ Batch #_._: 9131193Uranium 106 (80 - 120) SW846 60l0B 05/12-05/14/09 LCP951AC
Dilution Factor: 1
NOTE (8) :
Calculations are pcrfonned before rounding to avoid round-off errors in calculated results.
LOT # F9E070213-REVISED
Analysis Time .. : 13:23
27 of 57
TestAmerica St. Louis
LABORATORY CONTROL SAMPLE EYALUATIOB REPORT
TCLP Metals
Client Lot I ... : F9E070213 Matrix..••••••. : SOLID
PARAMETER
PERCENTRECOVERY
RECOVERY
LIMITSPREPARATION
_ME_T-H-O-D------ ANALYSIS DATE WORK ORDER #
LeS Lot-sampleD: F9E140000-386 Prep Batch I ... : 9134386Silver 97 (80 - 120) SW846 60l0B 05/14-05/15/09 LC2PT~
Dilution Factor: 1 Analysis Time .. : 23:28
Arsenic 111 (BO - 120) SW846 601GB 05/14-05/15/09 LC2PTlACDilution Factor: 1 Analysis Time .. : 23:28
Barium 113 (80 - 120) SW846 6010B 05/14-05/15/09 LC2PT1ADDilution Factor: 1 Analysis Time .. : 23:28
Cadmium 110 (80 - 120) SW846 60l0B 05/14-05/15/09 LC2PT1AE
Dilution Factor: 1 Analysis Time .. : 23:28
Chromium 107 (80 - 120) SW846 6010B 05/14-05/15/09 LC2PTIAFDilution Factor: 1 Analysis Time .. : 23:28
Lead 108 (80 ... 120) SW846 6010B 05/14-05/15/09 LC2PT1AGDilution Factor~ 1 Analysis Time .. : 23:28
Selenium 111 (80 - 120) SW846 6010B 05/14-05/15/09 LC2PT1AHDilution Factor: 1 Analysis Time .. : 23:28
LCS Lot-Sample#: F9E190000-0i4 Prep Batch # ... : 9139074Mercury 94 (80 - 120) SW846 7470A
Dilution Factor: 1
NOTE(S) :
Calculations are performed before rounding to avoid round-off errors in calculated results.
LOT # F9E070213-REVISED
05/19/09Analysis Time .. : 13:04
LC9481AA
28 of 57
TestAmerica St. Louis
LABORATORY CONTROL SAMPLE EVALUATION REPORT
General Cheai.stry
Lot-S~le # ... : F9E070213 Matrix••....... : SOLID
PERCENTPARAMETER RECOVERYTotal Organic
Carbon
RECOVERY RPD PREPARATI ON- PREPLIMITS RPD LIMITS _ME_T....;H~O...;,D ANALYSIS DATE BATCH #
WO#:LDH7D~C-LCS/LDH7D~-LCSD LCS Lot-Sample#: D9E210000-537
6958
(46 - 130)
(46 - 130) 17SW846 9060
(0-20) SW846 9060OS/21/09OS/21/09
9141537
9141537
ROTE (8) :
Dilution Factor: 1 Arialysis Time .. : 13:16
Calculations are performed before rounding to avoid round-off errors in calculated results.
LOT # F9E070213-REVISED 29 of 57
TestArnerica St. Louis
LABORATORY CONTROL SAMPLE EVALUATION REPORT
General Chemistry
Client Lot I ... : F9E070213 Matrix•.•••.••• : SOLID
PREPARATION- PREPANALYSIS DATE BATCH #
LCS Lot-Sample#: F9E120000-17705/12/09 9132177
RECOVERY
LIMITS METHOD---------Work Order #: LC9E71AA
(99 - 101) SW846 9045C100
PERCENTRECOVERYPARAMETER
pH (solid)
Dilution Factor: 1 Analysis Time .. : 00:00
Chloride95
Work Order #: LD6PPIAC Les Lot-Sample#: F9FOIOOOO-365(90 - 110) MCAWW 300.0A 06/01-06/02/09 9152365Dilution Factor: 1 Analysis Time .. : 00:00
Reactive cyanide0.0
Work Order #: LDN3J1AC(10 - 75) SW846 7.3.3
Les Lot-Sample#: F9E250000-035OS/25-05/26/09 9145035
Dilution Factor: 1 Analysis Time .. : 00:00
Reactive Sulfide27
Work Order #: LDN3H1AC(10 - 128) SW846 7.3.4
LCS Lot-Sample#: F9E250000-034OS/25/09 9145034
Dilution Factor: 1 A?alysis Time .. : 00:00
Total Sulfide97
Work Order #: LD5RllAC(90 - 110) MCAWW 376.1
Les Lot-Sample#: F9FOIOOOO-37606/02/09 9152376
Dilution Factor: 1 Analysis Time .. : 00:00
NOTE(S) :
Calculaoons are performed before rounding to avoid round·off errors in calculated results.
LOT # F9E070213-REVISED 30 of 57
TestAmerica St. Louis
MATRIX SPIKE SAMPLE EVALUATION REPORT
TOTAL Metals
Client Lot I ... : F9E070213Date Sampled••• : 05/04/09 13:15 Date Received•• : 05/06/09
Matrix.••...... : SOLID
PARAMETERPERCENT RECOVERY
RECOVERY LIMITSRPD PREPARATION-
RPD ~IMITS _ME_TH_O_D ANALYSIS DATE
WORKORDER #
Uranium 115 (75 - 125) SW846 6010B102 (75 - 125) 5.6 (0-30) SW846 6010B
Dilution Factor: 1
Analysis Time .. : 13:55
MS Lot-~le I: F9E070159-001 Prep BatCh #.~.: 9131193'Moisture..... : 4505/12-05/14/09 LCH811AE05/12-05/14/09 LCHBI1AF
NOTE(S) :
Calculations are performed before rounding to avoid round-off errors in calculated results.
LOT # F9E070213-REVISED 31 of 57
TestAmerica St. Louis
MATRIX SPIKE SAMPLE DATA REPORT
TOTAL Metals
Client Lot # ••• : F9E070213Date S~led... : 05/04/09 13:15 Date Received•• : 05/06/09
Matrix•. _._ .. _.: SOLID
SA1'1PLE SPIKE MEASRDPARAMETER AMOUNT Al\1T .AMOUNT---- UNITS
PERCNT PREPARATION-RECVRY RPD METHOD ANALYSIS DATE-------
WORKORDER #
MS Lot-S~le #: F9E070159-001 ~ Batch I ... : 9131193, Moisture_ •••• : 45
Uranium111
111100100
226213
mg/kgmgjkg
11.5102
SW846 6010B5.6 SW846 60l0B
05/12-05/14/09 LCH81lAE05/12-05/14/09 LCH811AF
NOTE (8) :
Dilution Factor: 1
Analysis Time .. : 13:55
Calculations are performed before rounding to avoid round-off errors in calculated resuhs.
LOT # F9E070213-REVISED 32 of 57
TestAmerica St. Louis
MATRIX SPIKE SAMPLE EVALUATION REPORT
TCLP Metals
Client Lot I ... : F9E070213Date 8amp1ed••• : 04/27/09 14:25 Date Received.. : 05/01/09
Matrix..•..•..• : SOLID
PARAMETERPERCENT RECOVERYRECOVERY LIMITS
RPDRPD LIMITS
PREPARATION-_ME_TH_O~D ~~_ ANALYSIS DATE
WORKORDER #
MS Lot-~le I: F9E010256-001 Prep BatCh t ... : 9134386LeaCh Date ..... : 05/13/09 LeaCh BatCh # .. : P913310Arsenic 104 (75 - 125) SWB46 6010B
103 (75 - 125) 0.97 (O-20) SW846 60l0BDilution Factor: 1Analysis Time .. : 23:47
05/14-05/15/09 LA7D6~3
05/14-05/15/09 LA7D6lA4
Barium 113112
(75 - 125)(75 - 125) . 0.93 (0-20)
Dilution Factor: 1
Analysis Time .. : 23:47
SW846 60l0BSW846. 6010B
05/14-05/15/09 LA7D61A505/14-05/15/09 LA7D61A6
Cadmium 97
96(75 - 125)
(75 - 125) 1.0SW846 6010B
(0-20) SW846 60l0B05/14-05/15/09 LA7D61A705/14-05/15/09 LA7D61A8
MS Lot-Sample #: F9E010256-001Leach Date..... : 05/13/09
Prep Batch # ... : 9139074Leach Batch :ft •• : P913310(Continued on next page)
Chromium
Lead
Selenium
Silver
9696
9796
9998
107106
Dilution Factor: 1Analysis Time .. : 23:47
(75 - 125)(75 - 125) 0 .. 82 (0-20)
Dilution Factor: 1
Analysis Time .. : 23:47
(75 - 125)( 75 - 125) 0 .. 66 ( 0 - 20)
Dilution Factor: 1
Analysis Time .. : 23:47
(75 - 125)(75 - 125) 0.58 (0-20)
Dilution Factor: 1
Analysis Time .. : 23:47
(75 - 125)(75 - 125) 0.72 (0-20)
Dilution Factor: 1
Analysis Time .. : 23:47
SW846 6010BSW846 6010B
SW846 6010BSW846 6010B
SW846 6010BSW846 60l0B
SW846 6010BSW846 6010B
05/14-05/15/09 LA7D61A905/14-05/15/09 LA7D61CA
05/14-05/15/09 LA7D61CC05/14-05/15/09 LA7D61CD
05/14-05/15/09 LA7D61CE05/14-05/15/09 LA7D6lCF
05/14-05/15/09 LA7D61Al05/14-05/15/09 LA7D61A2
LOT # F9E070213-REVISED 33 of 57
MATRIX SPIKE SAMPLE EVALUATION REPORT
TCLP Metals
Client Lot •... : F9E070213Date samp1ed .•• : 04/27/09 14:25 Date Received•. : 05/01/09
TestAmerica St. Louis
Matrix••....... : SOLID
PARAMETERMercury
PERCENTRECOVERY7876
RECOVERY
LIMITS RPD(70 - 130)
(70 - 130) 1 .. 6
RPD
LIMITS
(0-20)
METHODSW846 7470ASW846 7470A
WORKORDER #LA7D61CGLA7D61CH
NOTE(S) :
Dilution Factor: 1
Analysis Time .. : 13:08
Calculations are performed before rounding to avoid round-off errors in calculated results.
LOT # F9E070213-REVISED . 34 of 57
TestAmerica St. Louis
MATRIX SPIKE SAMPLE DATA REPORT
TCLP Metals
Client Lot 1: ••• : F9E070213 Matrix......... : SOLIDDate Sampled••• : 04/27/09 14:25 Date Received~.: 05/01/09
SAMPLE SPIKE MEASRD PERCNT PREPARATION- WORKPARAMETER .AMOUNT AMT AMOUNT UNITS RECVRY RPD METHOD ANALYSIS DATE ORDER #
MS Lot-Sample I: F9E010256-001 Prep Batch # ... : 9134386Leach Date•. _.• : 05/13/09 Leach Batch # •• : P913310
Arsenic146 2000 2230 ug/L 104 SWB46 6010B 05/14-05/15/09 LA7D61A31.46 2000 2200 ug/L 103 0.97 SW846 60l0B 05/14-05/15/09 LA7D61A4
Dilution Factor: 1
Analysis Time .. : 23:47
Barium57.7 2000 2320 ug/L 113 SW846 60l0B 05/14-05/15/09 LA7D61A5
57.7 2000 2300 ug/L 112 0.93 SW846 60l0B 05/14-05/15/09 LA7D61A6Dilution Factor: '1
Analysis Time w ~ : 23:47
CadmiumND 2000 1930 ug/L 97 SW846 6010B 05/14-05/15/09 LA7D61A7
ND 2000 1910 ug/L 96 1.0 SW846 6010B 05/14-05/15/09 LA7D61A8Dilution Factor: 1
Analysis Time .. : 23:47
ChromiumNO 2000 1930 ug/L 96 SW846 6010B 05/14-05/15/09 LA7D61A9ND 2000 1910 ug/L 96 0.82 SW846 60l0B 05/14-05/15/09 LA7D61CA
Dilution Factor: 1
Analysis Time .. : 23:47
LeadND 2000 1940 ug/L 97 SW846 GOlOB 05/14-05/15/09 LA7D61CCND 2000 1920 ug/L 96 0.66 SW846 60l0B 05/14-05/15/09 LA7D61CD
Dilution Factor: 1
Analysis Time. 4 : 23:47
SeleniumND 2000 1980 ug/L 99 SW846 6010B 05/14-05/15/09 LA7D61CEND 2000 1970 ug/L 98 0.5B SWB46 6010B 05/14-05/15/09 LA7D61CF
Dilution Factor: 1
Analysis Time .. : 23:47
SilverND 200 213 ug/L 107 SW846 6010B 05/14-05/15/09 LA7D61AlND 200 212 ug/L 106 0.72 SW846 6010B 05/14-05/15/09 LA7D61A2
Dilution Factor: 1
Analysis Time .. : 23:47
MS Lot-Sample #: F9E010256-001 Prep Batch :It ..... : 9139074Leach Date ..... : 05/13/09 Leach Batch :If: .... : P913310
LOT # F9E070213-REVISED (Continued on next page) 35 of 57
TestArnerica St. Louis
MATRIX. SPIKE SAMPLE DATA REPORT
TCLP Meta1s
Client Lot I ... : F9E070213Date S~led. __ : 04/27/09 14:25 Date Received.. : 05/01/09
Matrix..•...... : SOLID
SAMPLE SPIKE MEASRD PERCNT PREPARATION-P.ARAIv1ETER AMOUNT AMT AMOUNT UNITS RECVRY RPD METHOD .ANALYSIS DATE---- ------ -------Mercury
NOTE (S) :
ND
ND
25.025.0
19.4 ug/L 7819.1 ug/L 76
Dilution Factor: 1Analysis Time .. : 13:08
SWB46 7470A1.6 SWB46 7470A
05/19/0905/19/09
WORKORDER #
LA7D61CGLA7D61CH
Calculations are performed before rounding to avoid. round-off errors in calculated results.
LOT # F9E070213-REVISED 36 of 57
· .. __._-._.__ .- ------
TestAmerica St. Louis
MATRIX SPIKE SAMPLE EVALUATION REPORT
General Chemistry
Client Lot I : F9E070213Date Sampled : 05/12/09 10:24 Date Received .• : 05/13/09
Matrix.•..•...• : SOLID
Total OrganicCarbon
WO#: LCQ4T1AD-MS/LCQ4T1AE-MSD
PARAMETERPERCENT RECOVERYRECOVERY LIMITS
RPD PREPARATION- PREP
RPD LIMITS ME__TH_O_D_~~__ ANALYSIS DATE BATCH #'MOisture..... : 3.5
ME Lot-Sample #: D9E1I0164-011
HOTE(S) :
101101
(46 - 130)
(46 - 130) 0.08 (0-20)
Dilution Factor: 1Analysis Time.. : ~3:26
SW846 9060SW846 9060
OS/21/09OS/21/09
91415379141537
Calculations are perfonned before rounding to avoid round-off errors in calculated results.
N Spiked analyte recovery is outside stated control limits.
LOT # F9E070213-REVISED 37 of 57
TestAmerica St. Louis
MATRIX SPIKE SAMPLE DATA REPORT
General Chemistry·
Client Lot I ... : F9E070213Date Sampled.~_: 05/12/09 10:24 Date Received.. : 05/13/09
Matrix : SOLID
SAMPLE SPIKE MEASRD
PARAMETER AMOUNT AMT AMOUNT----- UNITS
Total OrganicCarbon
PREPARATION- PREP_ME_T_H_O_D ANALYSIS DATE BATCH #
% Moisture••••. : 3.5WO#: LCQ4TIAD-MS/LCQ4T1AE-MSD MS Lot-Sample #: D9El10164-011
ND
ND120120
122122
g/kgg/kg
101101
SW846 90600.08 SW846 9060
OS/21/09OS/21/09
91415379141537
ROTE (S):
Dilution Factor: 1
Analysis Time .. : 13:26
Calculations are performed before rounding to avoid round-off errors in calculated results.
N Spiked analytc recovery is outside stated control limits.
LOT # F9E070213-REVISED 38 of 57
TestAmerica St. Louis
MATRIX SPIKE SAMPLE EVALUATION REPORT
General Chemistry
Client Lot I ... : F9EO?0213Date S~led.•• : 05/04/09 14:00 Date Received•. : 05/06/09
Matrix : SOLID
Percnt Moisture: 45PERCENT
PARAMETER RECOVERYChloride
104
RECOVERY PREPARATION- PREPLIMITS _ME_TH_O_D ANALYSIS DATE BATCH #Work Order # ... : LCJNPIA9 MS Lot-Sample #: F9E070213-001{90 - 110} MCAWW 300.0A 06/01-06/02/09 9152365Dilution Factor: 1 Analysis Time .. : 00:00
Reactive Cyanide0.0
Work Order # ... : LCJP6~9 MS Lot-Sample #: F9E070213-006(10 - 45) SW846 7.3.3 OS/25-05/26/09 9145035Dilution Factor: 1 Analysis Time .. : 00:00
Reactive Sulfide22 N
Work Order # ... : LCJP6~7
(10 - 121) SW846 7.3.4MS Lot-Sample #: F9E070213-006
OS/25/09 9145034Dilution Factor~ 1 Analysis Time .. : 00:00
Total Sulfide98 N
Work Order # ... : LC1M61A4(O.o- 0.0) MCAWW 376.1
MS Lot-Sample #: F9E140145-00206/02/09 9152376
NOTE (S) :
Dilution Factor: 1 Analysis Time .. ~ 00:00
Calculations are performed before rounding to avoid round-off errors in calculated results.
N Spiked analyte recovery is outside stated control limits.
LOT # F9E070213-REVISED 39 of 57
TestAmerica St. Louis
MATRIX SPIKE SAMPLE DATA REPORT
General Chemist:ry
Client Lot I : F9E070213Date sampled : 05/04/09 14:00 Date Received•• : 05/06/09·
Matrix__ ......• : SOLID
Percnt Moisture: 45
SAMPLE SPIKEPARAMETER AMOUNT AMT
Chloride18.3 20.0
MEASURED PERCENT PREPARATION- PREPAMOUNT UNITS RECOVERY METHOD ANALYSIS DATE BATCH #
Work Order #••• : LCJNP1A9 MS Lot-Sample #: F9E070213-00139.2 mg/kg 104 MCAWW 300.0A 06/01-06/02/09 9152365
Dilution Factor: 1 Analysis Time .. : 00:00
Reactive CyanideND 6.25
Work Order # ... : LCJP61A9mg/kg 0.0
MS Lot-Sample #: F9E070213-006SW846 7.3.3 OS/25-05/26/09 9145035
Dilution Factor: 1 Analysis Time .. : 00:00
Reactive SulfideND 200
Work Order # .•• : LCJP61A744.5 N mg/kg 22
ME Lot-Sample #: F9E070213-006SW846 7.3.4 OS/25/09 9145034
Dilution Factor: 1 Analysis Time •. : 00:00
Total SulfideND 1000
Work Order # ... : LCIM61A4980 N mg/kg 98
MS Lot-Sample #: F9E140145-002MCAWW 376.1 06/02/09 9152376
NOTE(S) :
Dilution Factor: 1 Analysis Time .. : 00:00
Calculations are performed before rounding to avoid round-off errors in calculated results.
N Spiked analyte recovery is outside stated conlrollimits.
LOT # F9E070213-REVISED 40 of 57
TestAmerica St. Louis
SAMPLE DUPLICATE EVALtIATIQR REPORT
General Chemistry
PREP
BATCH #
9131058
Matrix..••.•• : SOLID
RPD PREPARATION-LIMIT METHOD ANALYSIS DATE
SD Lot~Sample #: F9D230347-001(0-0.0) SW846 9095 05/09/09
Analysis Time~~: 00:00
RPD
Work Order I ... : LAM2F-SMPLAM2F-DUP
Date Received.. : 04/23/09
No Units 0Dilution Factor: 1
UNITS-----
Client Lot I ... : F9E070213
PARAM RESULT
Paint Filter Test
Date Samp1ed.•• : 04/21/09 13:05'Moisture..... : 46
DUPLICATERESULT
LOT # F9E070213-REVISED 41 of 57
TestAmerica St. Louis
SAMPLE DUPLICATE EVALUATION REPORT
General Chemistry
Dilution Factor: 1
Matrix••••••. : SOLID
PREPARATION- PREPMETHOD ANALYSIS DATE BATCH #SD Lot-Sample #: F9E070213-006
(O-O.O) ASTM Moisture, % 05/09-05/~1/09 9131062Analysis Time .. : 00:00
RPD
LIMIT
0.26
RPD
Work Order I ... : LCJP6-SMPLCJP6-DUP
Date Received.. : 05/06/09
%50.2
Client Lot # •.. : F9E070213
PARAM RESULTPercent Moisture
50.1
Date sampled : 05/04/09 14:00% MOisture : 50
DUPLICATERESULT
Dilution Factor: 1
Reactive CyanideND ND mg/kg o
SD Lot-Sample #: F9E070213-006(0-30) SW846 7.3.3 OS/25-05/26/09 9145035
Analysis Time .. : 00:00
Dilution Factor: 1
Reactive SulfideND ND mg/kg o
SD Lot-Sample #: F9E070213-006(0-20) SW846 7.3.4 OS/25/09
Analysis Time .. : 00:00
9145034
LOT # F9E070213-REVISED 42 of 57
TestAmerica St. Louis
SAMPLE DUPLICATE EVALUATION REPORT
General Chemistry
Work Order I ... : LCJNP-SMPLCJNP-DUP
Date Received•. : 05/06/09
Matrix•.•.... : SOLID
PREPARATION- PREP
METHOD ANALYSIS DATE BATCH #SD Lot-Sample #: F9E070213-001MCAWW 300.0A 06/01-06/02/09 9152365
RPDLIMIT
(0-20)0.78
RPD
mg!kg18.5
UNITS-~-~-~
Client Lot I ... : F9E070213
Date Sampled••• : 05/04/09 14:00~ Moisture..... : 48
DUPLICATERESULTPARAM RESULT
Chloride18.3 J
Dilution Factor: 1 Analysis Time .. : 00:00
pH (solid)12.4 12.6 No Units 1.7
Dilution Factor: 1
SD Lot-Sample #: F9E070213-001(0-0.0) SW846 9045C 05/12/09
Analysis Time .. : 00:00
9132177
SD Lot.-Sample #: F9E070213-001
Analysis Time .. : 00:00
Cation ExchangeCapacity
10.2 9.7 meq/100g 5.8Dilution Factor: 5
(0-30) SW846 9081 05/15-05/20/09 9133197
HOTE(S) :
Calculations are performed before rounding to avoid round~off errors in calculated results.
J Method blank contamination. The associated method blank. contains the target anatyre at a reportable level.
LOT # F9E070213-REVISED 43 of 57
TestAmerica St. Louis
SAMPLE DUPLICATE EVALUATION REPORT
General Chemistry
9152376
Matrix : SOLID
a
RPD PREPARATION- PREPRPD LIMIT METHOD ANALYSIS DATE BATCH #
SD Lot-Sample #: F9E140145-002(0-0.0) MCAWW 376.1 06/02/09
Work Order # ••• : LC1M6-SMPLC1M6-DUP
Date Received•• : 05/13/09
mg/kgND
UNITS-----
C1ient Lot I ... : F9E070213
PARAM RESULT
Total SulfideND
Date S~led... : 05/12/09 10:24, MOisture •.••• : 45
DUPLICATERESULT
Dilution Factor: l Analysis Time .. : 00:00
LOT # F9E070213-REVISED 44 of 57
TestAmerica St. Louis
SAMPLE DUPLICATE EVALUATION REPORT
General Chemistry
9153158
Matrix•.••..• : SOLID
RPD PREPARATION- PREPLIMIT METHOD ANALYSIS DATE BATCH #
SD Lot-Sample #: F9E140145-001(0-0.0) ASTM D-5057-90 06/02/09
RPD
6.5
Work Order i ... : LC1MO-SMPLC1MO-DUP
Date Received.. : 05/13/09
g/mL1.4
UNITS-----
Client Lot i ... : F9E070213
Date Sampled.•• : 05/12/09 10:15, MOisture..... : 47
DUPLICATERESULTPARAM RESULT
Density1.5
Dilution Factor: 1 Analysis Time .. : 00:00
LOT # F9E070213-REVISED 45 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client SamDle ID: 1-65 UPPER
Radiochemistry
Lab Sample ID: F9E070213-001Work Order: LCJNPMatrix: SOLID
Date Collected:Date Received:
05/04/0905/06/09
14001855
A.. Ol-R MODOS/21/09 OS/29/09 9141383 77
OS/21/09 OS/29/09 9141383 77OS/21/09 OS/29/09 9141383 77
A-Ol-R HODOS/21/09 05/30/09 9141381 87
OS/21/09 05/30/09 9141381 87
OS/21/09 05/30/09 9141381 87
05/11/09 06/01/09 9131396
Yld ,AnalysisDate BatCh I
GA-Ol .. R MOD05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
PrepDate
'rotaluncert.
Parameter Result Qua.l (2 0+/-) MOe
Gamma Ra~226 &. Hits By DOE GA-Ol0R MOD pCi/gBismuth 214 0.89 0.29 0.33
Lead 212 0.11 U 0.17 0.30
Lead 214 1.12 0.29 0.29
Protactinium 234M 97 21 8
Protactinium 231 -0.02 U 2.4 4.2
Radium (226) 0.89 0.29 0.33
Thorium 232 0.0 U 0.45 0.82
Thorium 234 81.0 9.0 6.0
Uranium 235 4.3 1.0 1.0
--- Other Detected Radionuclides
Potassium 40 5.7 1.9 2.3
Iso URANIUM (SHORT CT) DOE A.. Ql-R MOD pCi/gUranium 234 58.1 5.4 0.2
Uranium 235/236 3.60 0.74 0.21
Uranium 238 60.5 5.7 0.2
Iso THORIUM (SHORT CT) DOE A-Ol-R MOD pCi/gThorium 228 0.01 U 0.12 0.25
Thorium 230 1.04 0.33 0.19
Thorium 232 0.028 U 0.066 0.13
NOTE (S)
Data are incomplete without the case narrative.
MOC is determined by instrument performance only.Bold results are greater tban the MOe
LOT # F9E070213-REVISED 46 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client Sam~le ID: ~-67 UPPER
Radiochemistry
Lab Sample ID: F9E070213-002Work Order: LCJPGMatrix: SOLID
Date Collected:Date Received:
05/05/0905/06/09
10151855
A-Ol-R MODQ5/21/09 OS/29/09 9141383 58
OS/21/09 OS/29/09 9141383 58
OS/21/09 OS/29/09 9141383 58
A-Ol-R MODOS/21/09 05/30/09 9141381 89
OS/21/09 05/30/09 9141381 89
OS/21/09 05/30/09 9141381 89
05/11/09 06/01/09 9131396
GA-Ol-R MOD05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 913139605/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
Ylcl ,AnalysisDate EBtch #
prepDate
TotalUncert.
Parameter Result Qual (2 (1+/-) MDC
Gamma Ra-226 & Hits By DOE GA-Ol0R MOD pCi/gBismuth 214 0.61 0.23 0.24
Lead 212 0.09 U 0.13 0.23
Leaa 214 0.73 0.24 0.23
Protactinium 234M 119 25 9
Protactinium 231 0.4 U 1.6 2.9
Radium (226) 0.61 0.23 0.24
Thorium 232 0.01 U 0.39 0.72
Thorium 234 102 8.7 6.0Uraniwn 235 6.01 0.94 0.87
--- Other Detected Radionuclides
Potassium 40 9.8 2.4 1.6
Iso URANIUM (SHORT CT) DOB A-Ol-R MOD pCi/gUranium 234 88.7 8.2 0.2
Uranium 235/236 4.87 0.9a 0,,11
Uranium 238 95.6 8.8 0.2
Iso THORltlM (SHORT C'r) DOE A-Ol-R HOD pCi/gThorium 228 0.037 U 0.088 0.17
Thorium 230 1.18 0.33 0.12Thorium 232 0.089 U 0.095 0.12
NOTE(S)Data are iDCQ~lete without the case narrative.
MDC is determined by instrument perfo~ce only.Bold results are greater than the Nne
LOT # F9E070213-REVISED 47 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client SamDle ID: E-74 UPPER
Radiochemistry
Lab Sample ID: F9E070213-003Work Order: LCJPMMatrix: SOLID
Date Collected:Date Received:
05/06/0905/06/09
10301855
A-Ol-R MOD .
OS/21/09 05/30/09 9141381 B7
OS/21/09 05/30/09 9141381 87
OS/21/09 05/30/09 9141381 87
A-Ol-R MODOS/21/09 OS/29/09 9141383 74
OS/21/09 OS/29/09 9141383 7.
OS/21/09 OS/29/09 9141383 74
05/11/09 06/01/09 9131396
GA-Ol-R MOD05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
OS/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
Yld \1UI.alyai.Date 3atch ,
Prepnate
TotaltrDcert.
Parameter Result Qual (2 a+/-) MDC
Gamma Ra-226 & Hits By DOE GA-010R MOD pCi/gBismuth 214 0.39 U 0.24 0 .. 39
Lead 212 0.05 U 0.15 0.28
Lead 214 0.62 0.21 0.24
Protaotinium 234M 96 20 7
Protactinium 231 -0.2 U 1.7 3.1
Radium (226) 0.39 U 0.24 0.39
Thorium 232 -0.01 U 0.30 0.56
Thorium 234 77.5 8.6 5.5Uranium 235 4.26 0.82 0.93
-~- Other Detected Radionuclides ---
Potassium 40 8.8 2.2 1.8
Iso URANIUM (SHORT CT) DOE A-Ol-R MOD pCi/guranium 234 57.9 5.4 0.2
Uranium 235/236 3.20 0.69 0.13
Uranium 238 58.2 5.5 0.2
Iso THORIUM (SHORT CT) DOE A-Ol-R MOD pCi/gThorium. 228 0.028 U 0 .. 078 0.16
-rhorium 230 0.93 0.30 0.16Thorium 232 0.028 U 0.071 0.14
NOTE (8)
Data are iucQDPlete without the case narrative.
MOC is determined by instrument perfo~ce only.Bold results are greater than the MDe
LOT # F9E070213-REVISED 48 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client Sample ID: E-74 LOWER
Radiochemistry
Lab Sample 1D: F9E070213-004Work Order: LCJPV
Matrix: SOLID
Date Collected:Date Received:
05/06/0905/06/09
10301855
A-Ol-R MODOS/21/09 OS/29/09 9141383 43
OS/21/09 OS/29/09 9141383 4305/21/09 OS/29/09 9141383 43
A-Ol-R MODOS/21/09 05/30/09 9141381 89
OS/21/09 05/30/09 9141381 89
OS/21/09 05/30/09 9141381 89
05/11/09 06/01/09 9131396
GA-Ol-R MOD05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 913139G
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
Yld %AnalysisD&~. BatCh #
PrepDate
TotaltJDcert.
Parameter Re8ul~ Qual (2 0+/-) MOO
Gamma. Ra-226 & Hits By DOE GA-010R MOD pCi/gBismuth 214 0.93 0.39 0.40
Lead 212 0.10 U 0.20 0.35
Lead 214 0.75 0.30 0.33
Protactinium 234M 255 44 13
Protactinium 231 -0.1 U 2.6 4.7
Radium (226) 0.93 0.39 0.40Thorium 232 0.1 U 0.28 0.53
Thorium 234 239 22 10
Uranium 235 12.4 1.8 1.5
--- Other Detected Radionuclides
Potassium 40 8.1 2.6 2.2
Iso URANIUM (SHORT CT) DOE A-Ol-R KOD pCi/gUranium 234 173 16 0.5
Uranium 235/236 8.9 1.6 0.5
Uranium 238 177 16 0.6
Iso THORIUM (SHORT CT) DOE A-Ol-R MOD pCi/gThorium 228 0.08 U 0.14 0.24
Thorium 230 1.95 0.45 0.19
Thorium 232 0.071 U 0.089 0.13
NOTE(S)
Data are incomplete wiChout the case narrative.
MOe is dete~ined by instrument performance only.Bola results are greater than the MOe
LOT # F9E070213-REVISED 49 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client SamDle ID: E-67 LOWER
Radiochemistry
Lab Sample ID; F9E070213-005Work Order: LCJP3Matrix: SOLID
Date Collected:Date Received:
05/05/0905/06/09
10151855
A-Ol-R MODOS/21/09 OS/29/09 9141383 44
OS/21/09 OS/29/09 9141383 44
OS/21/09 OS/29/09 9141383 44
A-Ol-R MODOS/21/09 05/30/09 9141381 90
OS/21/09 05/30/09 9141381 90
OS/21/09 05/30/09 9141381 90
05/11/09 06/01/09 9131396
Yld ,ADaly.iaDate Batch I
GA-Ol-R HOD05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
prepDate
TotaltJncert.
Parameter Result Qual (20+/-) MOe
Gamma Ra-226 & Hits By DOE GA-Ol0R MOD pCi/sBismuth 214 0.31 U 0.30 0.51
Lead 212 -0.002 U 0.21 0.36
Lead 214 0.73 0.34 0.35
Protactinium 234M 261 41 10
Protactinium 231 1.9 U 2.8 4.7
Radium (226) 0.31 U 0.30 0.51
Thorium 232 -0.10 U 0.40 0.73
Thorium 234 252 22 10
Uranium 235 12.4 1.' 1.5
--- Other Detected Radionuclides
Potassium 40 6.2 .... 2.2 2.3
Iso URANIUM (SHORT CT) DOE A-Ol-R MOD pCi/gUranium 234 188 17 0.4
Uranium 235/236 8.4 1.5 0.3
Uranium 23 B 194 17 0.3
Iso THORIOM (SHORT CT) DOB A-Ol-R MOD pCi/gThorium 228 -0.015 U 0.079 0.20
Thorium 230 2.28 0.48 0.15
Thorium 232 -0.010 U 0.047 0.15
NOTE(S)Data are incomplete witbout the ease narrative.
MOe is dete~ined by instrument p.rfo~ce only.Bold results are greater than the MOe
LOT # F9E070213-REVISED 50 of 57
TestAmerica St. Louis
Andrews Engineering, Inc.
Client SamDle ID: E-65 LOWER
Radiochemistry
Lab Sample ID:Work Order:Matrix:
F9E070213-006LCJP6SOLID
Date Collected:Date Received:
05/04/0905/06/09
14001855
A-OI-R MODOS/21/09 OS/29/09 9141383 38
OS/21/09 OS/29/09 9141383 38
OS/21/09 OS/29/09 9141383 38
A-Ol-R MODOS/21/09 05/30/09 9141381 87
OS/21/09 05/30/09 9141381 87
OS/21/09 05/30/09 9141381 87
05/11/09 06/01/09 9131396
Yld 5kb.alysisDate Batc:h ,.
GA-Ol-R MOD05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
05/11/09 06/01/09 9131396
PrepDate
Total'Dncert.
Pa:ram.etezo Result Qual (2 a+/-) MOC
Gamma Ra-226 & Hits By DOE GA-010R MOD pCi/gBismuth 214 0.92 0.35 0.39
Lead 212 0.27 U 0.21 0.30
Lead 214 1.17 0.34 0.37
Protactinium 234M 343 42 8
Protactinium 231 -0.2 U 3.8 6.5
Radium (226) 0.92 0.35 0.39Thorium 232 0.23 U 0.41 0.70
Thorium 234 332 28 10
Uranium 235 16.6 2.1 1.8
--~ Other Detected Radionuclides
Potassium 40 5.4 1.9 2.4
Iso.URANIUM (SHORT CT) DOE A-Ol-R MOD pCi/;Uranium 234 228 20 0.4
Uranium 235/236 11.4 1.9 0.3
Uranium 238 239 21 0.4
Iso THORIUM (SHORT CT) DOB A-Ol-R MOD pCi/gThorium 228 0.06 U 0.10 0.17
Thorium 230 2.61 0.52 0.12
Thorium 232 0.027 U 0.063 0.12
NOTE(S)
Data are incomplete without the case narrative.
MOe is determined by instrument performance only.Bold results are greater than the MOe
LOT # F9E070213-REVISED 51 of 57
METHOD BLANK REPORT
Radiochemistry
TestAmerica St. Louis
Client Lot ID: F9E070213Matrix: SOLID
:rotal LIID Sample ID
UDcert. Pr:ep ADalysia
Pat:amete:r Result Qual (2 a+/-) !IDe Date Date Batch # Yld \
Gamma Ra-226 & Hits By DOE GA-010R MOD pCi/g GA-Ol-R MOD F9El10000-396B
Bismuth 214 0.030 U 0.045 0.10 05/11/09 06/01/09 9131396
Lead 212 0.074 U 0.059 0.OB5 05/11/09 06/01/09 9131396Lead 214 0.028 U 0.067 0.12 05/11/09 06/01/09 9131396
Protactinium 234M 0.0 U 1.2 4.4 05/11/09 06/01/09 9131396
Protactinium 231 -0.23 U 0.74 1.3 05/11/09 06/01/09 9131396
Radium (226) 0.030 U 0.045 0.10 05/11/09 06/01/09 9131396Thorium 232 0.09 U 0.13 0.21 05/11/09 06/01/09 9131396
Thorium 234 -0.01 U 0.55 1.1 05/11/09 06/01/09 9131396
Uranium 235 -0.02 U 11 0.2 05/11/09 06/01/09 9131396
Iso THORIUM (SHORT C'1') DOE A-Ol-R MOD pCi/g A-Ol-R MOD P9E210000-381BThorium 228 0.005 U 0.023 0.060 OS/21/09 05/31/09 9141381 88
Thorium 230 0.076 0.059 0.047 OS/21/09 05/31/09 9141381 88
Thorium 232 0.0 U 0.0095 0.030 OS/21/09 05/31/09 9141381 88
Iso URANIUM (SHORT CT) DOE A-OI-R MOD pCi/g A... Ol-R MOD F9E210000-383B
Uranium 234 0.0006 U 0.022 0.062 OS/21/09 OS/29/09 9141383 94
Uranium 235/236 0.012 U 0.025 0.034 OS/21/09 OS/29/09 9141383 94
Uranium 238 0.018 U 0.028 0.042 OS/21/09 OS/29/09 9141383 94
NOTE(S)
Data are incomplete without the dass narrative.
MOC is dete~ined using instrument performance onlyBold results are greater than the MDC
LOT # F9E070213-REVISED 52 of 57
Laboratory Control Sample Report
Radiochemistry
TestAmerica St. Louis
Client Lot ID:Matrix:
F9E070213SOLID
-.t'otal Lab Spple ID
Vncert. OC Ccmtrcl
Parameter Spike Amount Result (2 a+/-' MOe % Yld , Ree Limits
Gamma Ra-226 & Hits By DOB GA-010R MOD pCi/g GA-Ol-R MOD F9Bl10000-396C
Radium (226) 12.2 11.1 0.93 0.37 91 (82 - 110)
Thorium 232 9.50 10.1 0.87 0.42 106 (89 - 130)
Bateh #: 9131396 Analysis Date: 06/01/09
Iso THORIUM (SHORT C'X) DOE A-Ol-R MOD pCi/g A-Ol-R MOD F9E210000-381C
Thorium 230 57.4 59.8 6.7 0.4 90 104 (83 - 126)
Batcb i: 9141381 Analysis Date: 05/31/09
Iso URANIUM (SHORT eT) DOE A-Ol-R MOD pCi/g A-Ol-R MOD F9B210000-383C
Uranium 234 19.2 18.0 3.0 0.5 79 94 (69 - 125)
Uranium 238 19.2 17.9 3.0 0.4 79 93 (68 - 121)
Batch #: 9141383 Analysis Date: OS/29/09
NOTE(S)LOT # P~E070213 ~EVIgED
MOC is dete:mined by instrument performance only_.. ~... - ..53 of 57
DUPLICATE EVALUATION REPORT
Radiochemistry
TestAmerica St. Louis
Client Lot ID:Matrix:
F9E070213SOLID
Date Sampled:Date Received:
05/04/09
05/06/09
Total Total QC Sample ID
SAMPLE l1J1cert. DUPLICATE l1Dcert.Parameter Result (2a+/-) , Yld Result (2 u+/-) % Yld Pz:eci.icm
Gamma Ra-226 & Hits By DOE GA-010R MOD pCi/g GA-Ol-R MOD F9E070213-001
Bismuth 214 0.89 0.29 1.01 0.33 13 %RPD
Lead 212 0.11 U 0.17 -0.1 U 67 3700 %RPD
Lead 214 ~.12 0.29 1.03 0.30 B %RPD
Protactinium 231 -0.02 U 2.4 0.7 U 2.2 210 %"RPDProtactinium 234M 97 21 91 25 7 %RPD
Radium (226) 0.89 0.29 1.01 0.33 13 %RPDThorium 232 0.0 U 0.45 -0.02 U 0.39 200 %"RPDThorium 234 81 .. 0 9.0 76.0 7.1 6 %RPD
Uranium 235 4.3 1.0 3.90 0.85 10 %RPD
---Other Dedec~ed Radionuclides---Potassium 40 5.7 1.9 4.7 2.0 19 %RPD
Batch #: 9131396 (Sample) 9131396 (Duplicate)
Iso THORIUM (SHORT CT) DOE A-Ol-R MOD pCi/g A-Ol-R MOD F9E070213-001
Thorium 228 O~Ol U 0.12 87 0.004 U 0.095 84 113 %RPD
Thorium 230 1.04 0.33 87 1.25 0.35 84 18 %RPD
Thorium 232 0.028 U 0.066 87 0.033 U 0.080 84 16 %RPDBatch t. 9141381 (Sample) 9141381 (Duplicate)
Iso URANIUM (SHORT CT) DOE A-Ol-R MOD pCi/g A-Ol-R MOD F9E070213-001
Uranium 234 58.1 5.4 77 63.5 5.9 69 9 %RPDUranium 235/236 3.60 0.74 77 3.50 0 .. 75 69 3 %RPDUranium 238 60.5 5.7 77 67.2 6 .. 3 69 11 %RPD
BateA I: 9141383 (Sample) 9141383 (Dupl icate)
NOTE(S)
Data are incomplete without the case narrative.Calculations are perfor.med before roundiDg to avo14 ~oUD4-cf! er~or 1~ calculated %esults
LOT # F9E070213-REVISED 54 of 57
t-toreSfAmerica St Louisl31t1 Rider Trail North~anlIjCityl MO 63045)ho~314..298-8566 fax 314-298..8566
"e., ~ ~~t fA.--~ J
t\~ Ce-o~4- Z-,
Df} i£..sC!J
-3./a-e-Chain of Custody Record
TestAmericaTHE LEADER-IN ENVlnONMENTAL TE6TIt.IG
TestAmerica Laboratories,
~ Client Contact Project Manager: Sean Chisek Site Contact: W. Brines Date: COC No:~ncliBws Engineering. Inc. TellFax: 217-622-3084 Lab Co.tact: T. Romanko Carrier: _ of__ coes~3~Ginger Creek Drive A~alysis Turnaround Time Job No.
3prjt gfield, IL 62711 Calendar ( C) or Work Days (W) •
!1~ 87-2334 TAT irdifferent &om Below Standard GJ
~17-;" 87-9495 FAX Cl 2 weeks -e ~ ~ ~ ~ SOG No.U) G) (U!E --
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Sample Sample Sample #I of 0 Q 0 0 0 0 .!! mX CLt 0 1U :; I! :c 0 0 .Sample IdentiOcatlon Date Time Type Matrix Con'. t- ~ .... t- I- t- LL D.. a. ~ .!! 0 m C) 0 I- I- sample Specific Notes:
f.'-(, Lf 6/'110"1 13:I~'~- )(,X " ~ '. J • I •
J~ -,S' \Affe7l, S/9/00, 1'1:00 A ~ ~ ~I~ ~~~~~~ ~~ 2~£ -~c S'1G1t1: gJ'lO 1\IJ , ~ ~
£ - ,ry V1t'P~,..", ~/$}fJ'I 'IJ:/S~ :f'l J !X IXl" X ~~-~£ -,B b/G1~ IIXX rf:~I'f~£ ...,q 5'ISM I/:l{f) t:l'£ -.?O iG~/IJ? IJ!Zo .~ .xE -~ry {j/~/di J3'LfO l' ~ -E -.,(, 1$U;/#1llf:/t>XX~- ?$;- S/~/r, IS.'Jt; , IX' 1\E - '? I f>/~/#'i 8: DO ~~ )(
1= -"1 2- ~~/'~ g:30 ,~resel'YQtlon Used: 1== Ice, 2== BCI; 3-= H2S04; 4=-HNOJ; 5-NaOH; 6- Other I
tosl'ble Hn'l.tlrd Identljica110n Sample Disposal ( A fee may bu assessed ifsamples are retained longer than 1 month)
::J Non-HQZQrd CJ Flammable .. Skin Irritant Polson B Cl Unknown Cl CJ Return To Client .. Disposal By Lab CJ Archive For Months .-::pl:ciallnstruc:tlonslQC Requirements & Comments: ~
)Iease email [email protected][email protected] i~ /~ 1
~elin~y • ~~ C07ony:.t ~iJP;,:.:I~~ Rece~~n \. lJ I J Company: ~telfime: n.---....~ ~~~~ "r"~r~$ t:1MD9 ~ ~~G..J.Jt....J~ ~-oq 3:'&0 PJ
~elinqui~edhY: {'---riJ1 .4 ~ Company: DatelTimY1'JT" l~tiV / / Company: DatelTime: t:t:
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resJl\merica St. Louisl37i5 Rider Trail North~rtfflCity, MO 63045]hOM 314..298-8566 fax 314-298-8566
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Chain of Custody RecordTestAmerica
THE LEADER IN e~VlnONMe.NTALTESTING
TestAmerica Laboratories,
o aleRt Contact IProJect Maoaeer: Sean Chisek Site CODtad: W_ Brines Date: COC No:
\ntiws Engineering, Inc. lTeJlFax: 217-622-3084 Lab Contact: T. Romsnko Carrier: of, COCs
l300>Ginger Creek Drive Analysis Turnaround TIme Job No.
)prWJfield. IL 62711 Calendar ( C) or Work Days (W)
~1~ 87-2334 TATirdiffereutrromBe1owStandard CD
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Sample Sample Sample #I of 0 0 0 0 (.) as -Ci ::J: Q) 0 ~ :s l!.c 0 0SImple Identification . nate Time Type Matrix Cant. I- ~ I- I- I- I- u: B. a. a:: .!! 0 m (!) (.) I- I- Sample Specific Notes:.. · E .. 73 S~"t 9:"0····· .. . . .. A"
~~ ... 7Lf Wfe~ SI'/df /0:'0 I~·~ ~~ ii ,'1 ,-~.t2~~ # -€I" pj'tldtl/2!2fJ ~A
.£,,83'" ~'/tf7 Il:lfS rx ~\t .. 7 i.t Lowell ~/D" If): 3D l.. ~'1 X. X '}\ 3X25lJG£~--c,? Lf!)~ ~~_q IO~/S· X. 1"'- '" ~ 't I/<-~ ,E-'.5'" t.o We'L, ~/ij/" I'I:~ }('.~X XxiX ~IX XXX ,X .JIr .~I1,! 'AI... J~.. _V~·J "" I-L ~ ...J
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Ireservatlon Used: 1= Ice. 2a. HCI; 3- H2SO4; 4=HN03; 5=NaOH; 6= Other
·osslbleHtUard IdentJflcatlon Sample Disposal ( A fee maybe assassed Ifsamples are retained longer thlllJ 1 month)
::J Non-JlazDrd 0 FIQlrlmab11i - SkIn [rritanl Polson B 0 Unknown 0 0 Return To Client - Disposal By Lab 0 Archive For Months ~:pecial InstrodionslQC Req_lremenfs & Comments: m
h)Iease email [email protected]@andrews-eng.com ~
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TestAmerica St. Louis
6. ------7. ------8. ------9. ------
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Time: ----""""""'----------
2. ---_-:.-3. --_.....-.--4. -----5. -----
Multiple Packages:
Sample Temperature (s)=**1. (J·7
3,1·o.f'
Other: - _
45'4
Date: tJ5=.tJ~·~9Information
Lot #(8): P7.__'Et._._o ~_
9. _
10, ------------4. --------
5. ------
CONDm?N.UPONRE~E~FORMChent. ~1Ve'/PC iJY~d?i!J9
Quote NO:.PIP9Z>t.P05~COCIRFA No: IZ7J?'/ .
fuili~d~~~~ ~ _
TestAmerica
Shipper: FedEx UPS - DHL Courier
Shipping # (s):*
1. 6: ----_:..---------2. 7. ___.....0-- _
3. 8. ------------
*Numbered shipping Hnes colTe5P:ond to Numbered Sample Temp lines 1(1*Sample must be received at 4DC =2°C.. If not, note contents below. Temperaturevariance' does NOT affect the following: Metals-Liquid or Rad tests- Liquid or SoUds
Condition (Circle "Y" for}'es.!~ for n~.and "N/A!1 for·not ·Jicabl.c)~
1 Y/::) Are there custody seals present on the'
. UI-' cooler? 8. · Y <5) Are there custody seals present on bottles?
Was sample received With proper pHI? (lfnotmake note below
Do custody seals on bottles appear to betam ered with?
Sample received in proper containers?
y9.
11.
10.
· 12, 'Y N tN1h." Headspace in VOA or TOX liquid samples?~ (IfYes, note sample IO's below)
Were contenm ofcooler frisked aftero en,n t but before un ackin ?
Do cllstody seals .on cooler appear to bet ~reCI with?
Sample recejve~ with Chain ofCustod ?
N/A DOeS'the Chain of Custody match r
sam ;le ID's on the containe s?
4.
3.
2.
5.
6. Was sample received broken? 13. Y· N@ Was Internal COCIWorkshare received?
7 Is s$ple volume suffici~nt·for 14 Y N' NI W' H tak b'· aJ i' stA ' 1 b?. anal :~is? " .. as p en y orIgm· e merlea a ·
1.For DOB-AL (pantex. LAN L~ Sandia) sites~ pH ofALL containers received must be verified, EXCEPT VOA. TOX and soils.
Notes:
THIS FORM MUST BE COMPLETED AT THE TIME THE ITEMS ARE BEING CHECKED IN. IF ANY ITEM IS COMPLETED BY SOMEONE OTHER THANTHE iNITIATOR. THEN THAT 'PERSON IS RSQU1REP TO AfPLYTHEIRlNlTlAL AND THE DATE NEXT TO THAT ITEM.
#: ' ADMJN..OOO4, REVISBD 10121108 \\SlsvrOl\QA\FORMS\sT-LOUlS\ADM1N\Admin004 re1/ll.doc
F9E070213-REVISED " . 57 of 57
Corrective Action:o Client Conta~t Name: ~
o Sample(s) processed t~~ is"o Sample(s) on hold uno!l:Project Management Review:
','
Informed by~ _~~ - _
ff~cle~e~~~:~~~~~ ~~__~~~~_pate: _