On the dynamics of periodically perturbed quantum systems
Consider a system of n ODEs
π
ππ‘π π‘ = π΄ π‘ π π‘ , π:β βΆ ππΓ1 β
where π΄:β βΆ ππΓπ β is a continuous, (π Γ π) matrix-valued function of real
parameter t, periodic with period T,
β π‘ β β β π β β€ βΆ π΄ π‘ + ππ = π΄ π‘ .
Let Ξ¦ π‘ to be the fundamental matrix of this system, satisfying the following:
π
ππ‘Ξ¦ π‘ = π΄ π‘ Ξ¦ π‘ , detΞ¦ π‘ β 0, π π‘ = Ξ¦ π‘ π
WroΕskian
Any general solution
(c = ππππ π‘.) of
system of ODEs
On the dynamics of periodically perturbed quantum systems
Proposition 1.
a) There exists some π‘0 β β such that π π‘ = πΈ π‘, π‘0 π π‘0 where
πΈ π‘, π‘0 β Ξ¦ π‘ Ξ¦ π‘0β1 is called the resolvent matrix or state transition matrix.
b) Resolvent matrix is a fundamental matrix itself, i.e. it satisfies the same differential
equation
π
ππ‘πΈ π‘, π‘0 = π΄ π‘ πΈ π‘, π‘0 .
Proposition 2. Resolvent matrix has some basic properties:
a) Divisibility: πΈ π‘, π‘0 = π=1π πΈ π‘π+1, π‘π for any partition π‘π , π‘π+1 of π‘0, π‘ , iff π‘0, π‘ =
π=1π π‘π , π‘π+1 , and π‘π , π‘π+1 β© π‘πβ² , π‘πβ²+1 = β for π β πβ²
b) πΈ π‘, π‘0β1 = πΈ π‘0, π‘
c) πΈ π‘0, π‘0 = ππππ β .
On the dynamics of periodically perturbed quantum systems
Theorem 1 (Floquetβs).
If Ξ¦ π‘ is a fundamental matrix of a system of n ODEs and π΄ π‘ is a T-periodic function of
codomain in the ππ β linear space of n-by-n matrices, then a matrix Ξ¦ π‘ + π is also a
fundamental matrix of this system.
Remark: If Ξ¦ π‘ + π is a fundamental matrix then there exist two constant matrices πΆ and π΅such that
Ξ¦ π‘ + π = Ξ¦ π‘ πΆ, πΆ = ππ΅π .
Assume a spectral decomposition π΅ = π ππ ππ , .β ππ:
ππ΅π =
π
ππ ππ , .β ππ , ππ = ππππ.
ππ: βFloquet
exponentsβ
On the dynamics of periodically perturbed quantum systems
Let π π‘ to be a solution of a system of ODEs, i.e. let it fulfillπ
ππ‘π π‘ = π΄ π‘ π π‘ .
Define ππ π‘ β Ξ¦ π‘ ππ . Then it follows from Floquetβs theorem that
Ξ¦ π‘ + π ππ = Ξ¦ π‘ ππ΅πππ = ππππππ π‘ = ππ π‘ + π
Putting ππ π‘ = ππ π‘ πβπππ‘ one gets a set of βbase solutionsβ of system of ODEs,
ππ π‘ = ππππ‘ππ π‘ , ππ π‘ + π = ππ π‘ .
T-periodic
On the dynamics of periodically perturbed quantum systems
Considering ππ π‘0 + π one obtains an eigenequation of Ξ¦ π‘0 + π Ξ¦β1 π‘0 :
ππ π‘0 + π = Ξ¦ π‘0 + π Ξ¦β1 π‘0 ππ π‘0 = ππππππ π‘0
Floquetβs operator
πΉ π‘0 β πΈ π‘0 + π, π‘0
Floquetβs basis
{ππβ ππ π‘0 }
πΈ π‘0 + π, π‘0
On the dynamics of periodically perturbed quantum systems
β’ π΄ π‘ = π» π‘ β periodic, self-adjoint Hamiltonian of quantum-mechanical system
β’ ODEs describe an evolution of wavefunction (state) π π‘ β SchrΓΆdinger equation:
π
ππ‘π π‘ = β
π
βπ» π‘ π π‘ , π» π‘ + π = π» π‘ .
β’ Resolvent matrix β unitary propagator πΌ π, ππ :
πΈ π‘, π‘0 = π π‘, π‘0 = Texp βπ
β
π‘0
π‘
π» π‘β² ππ‘β² ,ππ π‘, π‘0
ππ‘= β
π
βπ» π‘ π π‘, π‘0 .
β’ Floquetβs operator πΉ π‘0 = π π‘0 + π, π‘0 = πβππ
β π»:
π ππ ππ ππ = πβππ»βππππ ππ ,
ππ β ππ π‘0 β Floquet basis, ππ β set of Bohr-Floquet quasienergies.
On the dynamics of periodically perturbed quantum systems
Floquet Hamiltonian:
π»πΉ π, π‘ = π» π, π‘ β πβπ
ππ‘, π»πΉπ π, π‘ = 0
Main analysis based on SchrΓΆdinger equation for states ππ π, π‘ = ππ π, π‘ + π :
π»πΉππ π, π‘ = ππππ π, π‘
Solutions are not unique:
They generate the same physical state ππ π, π‘
πππ π, π‘ β ππ π, π‘ πππΞ©π‘ π»πΉπππ π, π‘ = ππ + πβΞ© ππ π, π‘
πππHigher Floquet
modes
On the dynamics of periodically perturbed quantum systems
Extended Hilbert space ββΆββ² = ββπ― (example: particle in free space)
π― = β2 ππ1 , ππ‘ = span ππ π‘ β πππΞ©π‘
Space of square-integrable functions
with period T = 2π/Ξ©, defined over a
circle π1.
ππ, ππβ² =1
π π1ππ π‘ ππβ² π‘ ππ‘ = πΏππβ²
π
ππβ β ππ = πππ―
β = β2 β3, ππ = span ππ: β3 β β
Space of square-integrable functions
defined over β3.
ππ , ππβ² =
β3
ππ π ππβ² π ππ π = πΏππβ²
π
ππβ β ππ = ππβ
ββπ― = span πππ β ππ βππ , πππ π, π‘ = ππ π πππΞ©π‘
ππ
πππβ β πππ = ππββπ― , πππ
β ππβ²πβ² = πΏππβ²πΏππβ² , πππβ β β βπ― β
On the dynamics of periodically perturbed quantum systems
Structure of Hamiltonian: π» π, π‘ = π»0 π + π π, π‘ , π π, π‘ + π = π π, π‘ .
Idea: We are applying a transformation of variables:
π = Ξ©π‘, π = Ξ©
π» π, π, π = π»0 π + π π, π + πππ
Canonical
quantization:
π β π,
ππ β βπβπ
ππ,
π, ππ = πβ
π» π, π, π = π»0 π + π π, π β πβΞ©π
ππ, π» π, π, π πππ π, π = ππππππ π, π
On the dynamics of periodically perturbed quantum systems
π» π, π, π πππ π, π = ππππππ π, π , πππ = ππ + πβΞ©
πππ β β βπ―, π― = β2 π2π1 ,
1
Ξ©ππ
Square-integrable functions of period
2π over a unit circle π1 = π = πΊπ‘
How to include multi-mode setting?
Ansatz: add a sufficient number of new ππ variables, such that
π» π, π, π = π»0 π + π π, π1, β¦ , ππ β πβ
π=1
π
Ξ©ππ
πππ, Ξ©π =
2π
ππ
On the dynamics of periodically perturbed quantum systems
New SchrΓΆdinger equation:
π» π, π1, π2, β¦ , ππ πππ1π2β¦ππ π, π1, π2, β¦ , ππ = πππ1π2β¦πππππ1π2β¦ππ π, π1, π2, β¦ , ππ
Periodicity of π functions:
πππ1π2β¦ππ π, π1 + 2π, π2 + 2π,β¦ , ππ + 2π = πππ1π2β¦ππ π, π1, π2, β¦ , ππ
Extension of Hilbert space of π functions:
πππ1π2β¦ππ β β βπ―1βπ―2ββ―βπ―π, π―π = β2π2 π1,
1
πΊππππ
π=1
π
β2π2 π1,
1
πΊππππ β‘ β2 π1 Γ π1 Γβ―Γ π1, ππ = β2 ππ, ππ , ππ =
π=1
ππππ
πΊπ
Product measure
On the dynamics of periodically perturbed quantum systems
Qpen problem:
How to incorporate the multi-mode Floquet theory into Open Quantum Systems
realm?
Possible answer for π = 2 (2-dimensional torus)
(H. R. Jauslin and J. L. Lebowitz, Chaos 1, 114 (1991))
Generalized Floquet operator πΉ π1 : β β π―1 βΆββπ―1,
πΉ π1 = π βπ2 π π2, 0 , π βπ2 π π1 0 = π π1 0 β π2 .
On the dynamics of periodically perturbed quantum systems
Theorem 2.
If π β ββπ―1 is an eigenfunction of Floquet operator, πΉπ = πβπππ2π, then the
function π β ββπ―1βπ―2 defined
π π1, π2 = πππ2ππ 0,βπ2 π π1 β π2
is an eigenfunction of π» π, π1, π2, π1, π2 with eigenvalue (quasienergy) π.
Proof in: H. R. Jauslin and J. L. Lebowitz, Chaos 1, 114 (1991)
Problem:
Spectrum of π» may become very complex (p.p., a.c. or s.c.), even in finite
dimensional case.
On the dynamics of periodically perturbed quantum systems
π, βπ
π 1, βπ 1
π 2, βπ 2
π 3, βπ 3π 4, βπ 4
π π,
βπ π
β = βπ ββπ 1 ββ―ββπ π
π» = π»π +
π=1
π
π»π π +
π=1
π
ππ
π»π β‘ π»π β πΌπ 1 ββ―β πΌπ π
π»π π β‘ πΌπ ββ―βπ»π π ββ―β πΌπ π
ππ = ππ
πΌ
ππ,πΌ βπ π,πΌ
ππ,πΌ:βπ βΆβπ, π π,πΌ:βπ π βΆβπ π
π1
π2
π3
π4
ππ
βπ π‘ =ππ π‘
ππ‘=
π,π
π
πββ€
πΊπππ + πΞ© ππ,π π, π π π‘ ππ,π
β π, π β1
2ππ,πβ π, π ππ,π π, π , π π‘ ,
πΊπππ =
ββ
β
ππππ‘ π π,π π‘ π π,π ππ‘ , πΊ βπ = πββπππ΅ππΊ π
On the dynamics of periodically perturbed quantum systems
KMS condition
(in equilibrium)
Floquet Theorem β±ππ = πβπβπππππ
ππ quasienergies
ππ Floquet basis
Fourier transform of
ππ,π π‘
Bohr frequencies
π =1
βππ β ππ
π + πΞ© , π β β€
Bohr β Floquet
quasifrequencies
ππ π‘ = πβ π‘ πππ π‘ = ππ
π
ππ,π π‘ β π π,π π‘ , π π‘ = Ξ€ exp βπ
β
0
π‘
π»π π‘β² ππ‘β²
On the dynamics of periodically perturbed quantum systems
Ξπ‘,π‘0 = Ξ€exp
π‘0
π‘
β π‘β² ππ‘β² β‘ π° π‘, π‘0 ππ‘βπ‘0 β
Dynamical map reconstructed from its interaction picture:
π° π‘, π‘0 β one-parameter unitary map defined on C*-algebra of operators π,
π°:π Γ 0,β βΆ π defined as π° π‘ π΄ = π π‘ π΄πβ π‘ .
π π‘ = Ξπ‘ π0 = π π‘ ππ‘βπ0 πβ π‘
π π‘ in interaction
picture
π π‘ in SchrΓΆdinger
picture
On the dynamics of periodically perturbed quantum systems
9 Floquet quasifrequencies: 0,Β±Ξ©π , Β±Ξ©,Β± Ξ© β Ξ©π , Β± Ξ© + Ξ©π
Interaction with molecular gas Interaction with
electromagnetic field
π ππ,
βππ
π π, βπ
Two-level system
βπ β‘ β2
Bosonic heat bath
(EM field)
β±+ βπβ =
π=0
β1
π!βπβ
βπ
+
ππ
laser, Ξ©π0
Dephasing bath
(molecular gas),
βπ β‘ β2 β3, ππ π
ππ
ππ = π3βπΉπ
πΉπ:βπ βΆβπ
ππ = π1β πβ π + π π
On the dynamics of periodically perturbed quantum systems
Markovian master equation
in interaction picture:
π
ππ‘π π‘ = βπππ ππππ + βπππβππ πππ π π‘
ππ11 π‘
ππ‘= β πΌ + π
βΞ©βΞ©π ππ πΏβ + πΏ+ π11 π‘ + π
βΞ©π πππΌ + πΏβ + π
βΞ©+Ξ©π ππ πΏ+ π22 π‘
πΎ =1
2πΌ0 + πΌ 1 + π
βΞ©π ππ + πΏ0 1 + π
βΞ©ππ + πΏβ 1 + π
βΞ©βΞ©π ππ + πΏ+ 1 + π
βΞ©+Ξ©π ππ
ππ22 π‘
ππ‘= β
ππ11 π‘
ππ‘,
ππ21 π‘
ππ‘= βπΎπ21 π‘ ,
ππ12 π‘
ππ‘= βπΎπ12 π‘ .
πΏΒ± =Ξ©π Β± Ξ
2Ξ©π
2
πΊπ Ξ© Β± Ξ©π , πΌ0 =2Ξ
Ξ©π
2
πΊπ 0 , πΌ =2π
Ξ©π
2
πΊπ Ξ©π ,
On the dynamics of periodically perturbed quantum systems
1. U. Vogl, M. Weitz: βLaser cooling by collisional redistribution of radiationβ,
Nature 461, 70-73 (3 Sep. 2009).
2. R. Alicki, K. Lendi: βQuantum Dynamical Semigroups and Applicationsβ,
Lecture Notes in Physics; Springer 2006.
3. R. Alicki, D. Gelbwaser-Klimovsky, G. Kurizki: βPeriodically driven quantum
open systems: Tutorialβ, arXiv:1205.4552v1.
4. K. Szczygielski, D. Gelbwaser-Klimovsky, R. Alicki: βMarkovian master
equation and thermodynamics of a two-level system in a strong laser
fieldβ, Phys. Rev. E 87, 012120 (2013)
5. D. Gelbwaser-Klimovsky, K. Szczygielski, R. Alicki: βLaser cooling by
collisional redistribution of radiation: Theoretical modelβ (in preparation)
6. R. Alicki, D. A. Lidar, P. Zanardi: βInternal consistency of fault-tolerant
quantum error correction in light of rigorous derivations of the quantum
Markovian limitβ Phys. Rev. A 73, 052311 (2006)