Мембранное материаловеден ие проф. д.х.н. Ямпольский Ю.П. д.х.н. Алентьев А.Ю. ИНХС РАН
Мембранное материаловедение проф. д.х.н. Ямпольский Ю.П. д.х.н. Алентьев А.Ю. ИНХС РАН
Jan 27, 2016
Мембранное материаловедение проф. д.х.н. Ямпольский Ю.П. д.х.н. Алентьев А.Ю. ИНХС РАН. 7 Зондовые методы исследования свободного объема в мембранных материалах. Классификация зондовых методов. 1. Переменный размер зонда : Обращенная газовая хроматография Метод спинового зонда - PowerPoint PPT Presentation
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7
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1. : ()
2. (d=1,06 )129Xe- (d=4,4 )
-
** o-Ps p-Ps 1.06 ** p-Ps 0.125 ns*** o-Ps 140 ns
-
Tao-Eldrup
i = 1/2[1 - (Ri/Ro) + (1/2)sin(2Ri/Ro)]-1
Goworek
i = [8.6(R/Ri)3(1-3R/4Ri)]-1
i = 3 4, Ri=R3 R4, Ro=Ri+R, R=1.66
:vf3=4/3(R33); vf4=4/3(R43); FFV3=N3vf3; FFV4=N4vf4
-
trVgSHS Hm, Sm
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129Xe-: = o + s + Xe/Xe p 0s = - os = 499/(2.05 + )
: = (Dsp/2) 2.2: = Dc 4.4
-
()
P(O2), R3,vf3,3R4, vf4,3 Copolyester Vectra0.00052.139--PMMA0.092.674--PC1.62.94106--6FDA-ODA2.43.2136--PVTMS443.211384.35345PPrSiDPA2303.832356.381088AF240011402.68815.95882PTMSP77003.411666.811323
-
7
0
0
0
0
0
0
0
0
0
0.02855
0.1067
0.2199
0.3465
0.4653
0.5586
0.6186
0.6421
0.6327
0.5958
0.5384
0.4668
0.3865
0.3021
0.2185
0.1407
0.0751
0.02809
0.003294
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.02429
0.1099
0.2615
0.4444
0.6163
0.7384
0.7804
0.737
0.6162
0.4487
0.2719
0.1233
0.03308
0
0
0
0.06787
0.2304
0.4849
0.7831
1.063
1.257
1.308
1.199
0.9406
0.6025
0.2754
0.05406
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
a(l)l
PFPDMSS
PFPDX
1/XYs+Y
6.66670
6.32910
6.02410
5.71430
5.43480
5.15460
4.9020
4.67290
4.42480
4.21940.02855
40.1067
3.80230.2199
3.61010.3465
3.43640.4653
3.2680.5586
3.10560.6186
2.94990.6421
2.80110.6327
2.66670.5958
2.53160.5384
2.40380.4668
2.28830.3865
2.17390.3021
2.06610.2185
1.96080.1407
1.86570.0751
1.7730.02809
1.68350.003294
1.60
1.51980
1.44510
1.37360
1.30550
1.24070
1.17790
1.11980
1.06380
1.01110
0.961540
0.917430
0.869570
0.826450
0.781250
0.746270
0.709220
0.671140
0.641030.02429
0.606060.1099
0.578030.2615
0.549450.4444
0.520830.6163
0.495050.7384
0.47170.7804
0.448430.737
0.425530.6162
0.404860.4487
0.384620.2719
0.364960.1233
0.347220.03308
0.330030
0.313480
0.297620
0.282490.06787
0.268820.2304
0.25510.4849
0.242720.7831
0.230411.063
0.21931.257
0.208331.308
0.198021.199
0.187970.9406
0.178890.6025
0.169780.2754
0.161550.05406
0.153370
0.145770
0.13850
0.131750
0.125160
0.118910
0.112990
0.107410
0.102040
0.0970870
0.0917430
0.0877190
0.0833330
0.0793650
0.0751880
0.0714290
PFPDX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PFPDMSS
PVTMSX
1/XYs+Y
6.66670
6.32910
6.02410
5.71430.01915
5.43480.09048
5.15460.2009
4.9020.3274
4.67290.4453
4.42480.5337
4.21940.5843
40.5948
3.80230.5733
3.61010.5307
3.43640.4799
3.2680.4326
3.10560.3954
2.94990.3719
2.80110.3591
2.66670.3514
2.53160.3406
2.40380.3186
2.28830.281
2.17390.2265
2.06610.1612
1.96080.09464
1.86570.03993
1.7730.008693
1.68350
1.60
1.51980
1.44510
1.37360
1.30550
1.24070
1.17790
1.11980
1.06380
1.01110
0.961540
0.917430
0.869570
0.826450
0.781250
0.746270
0.709220
0.671140
0.641030.00841
0.606060.07429
0.578030.2101
0.549450.3838
0.520830.5536
0.495050.6788
0.47170.7271
0.448430.6914
0.425530.5781
0.404860.4179
0.384620.2483
0.364960.1076
0.347220.02607
0.330030
0.313480
0.297620
0.282490
0.268820.018
0.25510.1234
0.242720.3155
0.230410.5662
0.21930.8143
0.208330.9939
0.198021.056
0.187970.9702
0.178890.7603
0.169780.4767
0.161550.2088
0.153370.04476
0.145770
0.13850
0.131750
0.125160
0.118910
0.112990
0.107410
0.102040
0.0970870
0.0917430
0.0877190
0.0833330
0.0793650
0.0751880
0.0714290
PVTMSX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PVTMS
AF24NI
1/XYs+Y
100
9.4340.1315
8.92860.2835
8.47460.4
80.4474
7.57580.4265
7.14290.3502
6.75680.2451
6.41030.1397
6.06060.0568
5.74710.01223
5.43480
5.12820
4.85440
4.58720
4.34780
4.11520
3.89110
3.67650
3.48430
3.28950
3.11530
2.94990
2.78550
2.63850
2.49380.003039
2.35850.01152
2.23210.02302
2.11420.03412
20.04157
1.89040.04297
1.78890.03829
1.6920.0287
1.60.01722
1.51520.0072
1.43270.001107
1.3550
1.28210
1.21210
1.14680
1.08460
1.02670
0.970870
0.917430
0.869570
0.819670
0.775190
0.735290
0.694440.01651
0.657890.05959
0.621120.1343
0.588240.2379
0.558660.3645
0.526320.5045
0.497510.6473
0.47170.7822
0.446430.8987
0.421940.9888
0.41.046
0.377361.068
0.357141.053
0.337841.004
0.319490.9255
0.303030.8229
0.286530.7041
0.2710.5774
0.256410.451
0.242130.3321
0.229360.2274
0.216920.1412
0.205340.07633
0.194170.03277
0.183490.00889
0.173610
0.16420
0.155520.007121
0.147060.02066
0.139080.03848
0.131580.05799
0.124380.07635
0.117790.09083
0.111360.09944
0.105370.1007
0.10.09458
0.094340.08159
0.0892860.06371
0.0840340.04344
0.080.02398
0.0757580.008596
0.0714290
AF24NI
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
AF2400
NSIPAX
1/XYs+Y
200
18.7620
17.6370
16.5290
15.5280
14.5770
13.680
12.8370
12.0480
11.3120.05694
10.6160.2318
100.4657
9.34580.6802
8.77190.8108
8.26450.8149
7.75190.7033
7.24640.5096
6.80270.2944
6.41030.1191
6.02410.01815
5.64970
5.2910
4.97510
4.67290
4.3860
4.11520.02773
3.8610.1009
3.62320.2
3.40140.2964
3.18470.3612
2.9940.3721
2.8090.3277
2.63850.2384
2.47520.1335
2.32560.04632
2.18340
2.04920
1.92310
1.80510
1.6920
1.58980
1.49250
1.40060
1.31410
1.2330
1.15740
1.0870
1.02040
0.961540
0.90090
0.840340
0.793650
0.740740
0.69930
0.653590
0.61350
0.578030.135
0.540540.3441
0.507610.5274
0.476190.602
0.448430.5229
0.420170.3386
0.395260.1332
0.370370.001647
0.347220
0.32680
0.306750
0.287360
0.270270
0.253160
0.23810.05892
0.223210.3161
0.209640.7524
0.196851.172
0.18451.367
0.173311.246
0.16260.8212
0.152670.3209
0.143270.01984
0.134590
0.126260
0.118480
0.111230
0.104380
0.0980390
0.0917430
0.0862070
0.0813010
0.0763360
0.0714290
NSIPAX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PP2SiDPA
PTMSPN
1/XYs+Y
12.50
11.7920.1469
11.1360.4118
10.5040.6907
9.9010.8959
9.34580.9756
8.84960.9029
8.33330.7207
7.8740.5015
7.40740.2931
6.9930.12
6.62250.01835
6.21120
5.88240
5.55560
5.23560
4.95050
4.65120
4.40530
4.14940
3.92160
3.690
3.48430.01223
3.28950.04037
3.10560.07405
2.93260.102
2.76240.1193
2.6110.1154
2.46310.088
2.32560.04824
2.1930.01442
2.07040
1.95310
1.84160
1.73910
1.63930
1.5480
1.45990
1.37740
1.30040
1.2270
1.15740
1.09290
1.03090
0.970870
0.917430
0.869570
0.819670
0.769230
0.729930
0.684930.03948
0.649350.1213
0.609760.2269
0.578030.3211
0.543480.3766
0.512820.3787
0.485440.321
0.456620.225
0.431030.12
0.408160.03713
0.384620
0.362320.01163
0.342470.1045
0.322580.275
0.304880.5006
0.287360.7314
0.2710.9135
0.255750.9989
0.241550.9509
0.227790.7806
0.215050.5194
0.202840.2501
0.191570.06604
0.180830
0.170650
0.161030
0.151980
0.143270
0.135320
0.127550
0.120480
0.113640
0.107180
0.101210
0.0952380
0.090090
0.0847460
0.080
0.0757580
0.0714290
PTMSPN
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PTMSP
OMAX
1/XYs+Y
40
3.81680
3.64960
3.49650
3.33330
3.19490.01665
3.04880.06559
2.91550.145
2.78550.2476
2.65960.3599
2.54450.4679
2.43310.5583
2.32560.6196
2.22220.6455
2.12310.6323
2.02840.5826
1.94170.5018
1.85530.4002
1.7730.2901
1.69490.1849
1.61810.09756
1.5480.0367
1.47930.006795
1.41440
1.35140
1.2920
1.23460
1.17920
1.12740
1.07760
1.02990
0.980390
0.94340
0.90090
0.862070
0.819670
0.78740
0.751880
0.719420
0.684930
0.653590.01484
0.6250.06154
0.59880.1463
0.571430.2601
0.546450.3892
0.523560.516
0.50.6232
0.478470.698
0.456620.7309
0.436680.7206
0.416670.67
0.398410.5898
0.380230.4931
0.363640.3969
0.347220.318
0.332230.2711
0.317460.2679
0.303950.313
0.289860.406
0.277780.5376
0.265250.6937
0.253160.8537
0.242130.9948
0.231481.095
0.221241.133
0.211421.1
0.202020.9901
0.193050.8169
0.18450.6007
0.176370.3763
0.168630.1819
0.161290.04978
0.154080
0.147280
0.140850
0.134590
0.128530
0.122850
0.117510
0.112230
0.10730
0.102560
0.0980390
0.0934580
0.0892860
0.085470
0.0819670
0.0781250
0.0746270
0.0714290
OMAX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
OMAX
8
0
0
0
0.01915
0.09048
0.2009
0.3274
0.4453
0.5337
0.5843
0.5948
0.5733
0.5307
0.4799
0.4326
0.3954
0.3719
0.3591
0.3514
0.3406
0.3186
0.281
0.2265
0.1612
0.09464
0.03993
0.008693
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.00841
0.07429
0.2101
0.3838
0.5536
0.6788
0.7271
0.6914
0.5781
0.4179
0.2483
0.1076
0.02607
0
0
0
0
0.018
0.1234
0.3155
0.5662
0.8143
0.9939
1.056
0.9702
0.7603
0.4767
0.2088
0.04476
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
t, ns
a(l)l
PVTMS
PFPDX
1/XYs+Y
6.66670
6.32910
6.02410
5.71430
5.43480
5.15460
4.9020
4.67290
4.42480
4.21940.02855
40.1067
3.80230.2199
3.61010.3465
3.43640.4653
3.2680.5586
3.10560.6186
2.94990.6421
2.80110.6327
2.66670.5958
2.53160.5384
2.40380.4668
2.28830.3865
2.17390.3021
2.06610.2185
1.96080.1407
1.86570.0751
1.7730.02809
1.68350.003294
1.60
1.51980
1.44510
1.37360
1.30550
1.24070
1.17790
1.11980
1.06380
1.01110
0.961540
0.917430
0.869570
0.826450
0.781250
0.746270
0.709220
0.671140
0.641030.02429
0.606060.1099
0.578030.2615
0.549450.4444
0.520830.6163
0.495050.7384
0.47170.7804
0.448430.737
0.425530.6162
0.404860.4487
0.384620.2719
0.364960.1233
0.347220.03308
0.330030
0.313480
0.297620
0.282490.06787
0.268820.2304
0.25510.4849
0.242720.7831
0.230411.063
0.21931.257
0.208331.308
0.198021.199
0.187970.9406
0.178890.6025
0.169780.2754
0.161550.05406
0.153370
0.145770
0.13850
0.131750
0.125160
0.118910
0.112990
0.107410
0.102040
0.0970870
0.0917430
0.0877190
0.0833330
0.0793650
0.0751880
0.0714290
PFPDX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PFPDMSS
PVTMSX
1/XYs+Y
6.66670
6.32910
6.02410
5.71430.01915
5.43480.09048
5.15460.2009
4.9020.3274
4.67290.4453
4.42480.5337
4.21940.5843
40.5948
3.80230.5733
3.61010.5307
3.43640.4799
3.2680.4326
3.10560.3954
2.94990.3719
2.80110.3591
2.66670.3514
2.53160.3406
2.40380.3186
2.28830.281
2.17390.2265
2.06610.1612
1.96080.09464
1.86570.03993
1.7730.008693
1.68350
1.60
1.51980
1.44510
1.37360
1.30550
1.24070
1.17790
1.11980
1.06380
1.01110
0.961540
0.917430
0.869570
0.826450
0.781250
0.746270
0.709220
0.671140
0.641030.00841
0.606060.07429
0.578030.2101
0.549450.3838
0.520830.5536
0.495050.6788
0.47170.7271
0.448430.6914
0.425530.5781
0.404860.4179
0.384620.2483
0.364960.1076
0.347220.02607
0.330030
0.313480
0.297620
0.282490
0.268820.018
0.25510.1234
0.242720.3155
0.230410.5662
0.21930.8143
0.208330.9939
0.198021.056
0.187970.9702
0.178890.7603
0.169780.4767
0.161550.2088
0.153370.04476
0.145770
0.13850
0.131750
0.125160
0.118910
0.112990
0.107410
0.102040
0.0970870
0.0917430
0.0877190
0.0833330
0.0793650
0.0751880
0.0714290
PVTMSX
0
0
0
0.01915
0.09048
0.2009
0.3274
0.4453
0.5337
0.5843
0.5948
0.5733
0.5307
0.4799
0.4326
0.3954
0.3719
0.3591
0.3514
0.3406
0.3186
0.281
0.2265
0.1612
0.09464
0.03993
0.008693
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.00841
0.07429
0.2101
0.3838
0.5536
0.6788
0.7271
0.6914
0.5781
0.4179
0.2483
0.1076
0.02607
0
0
0
0
0.018
0.1234
0.3155
0.5662
0.8143
0.9939
1.056
0.9702
0.7603
0.4767
0.2088
0.04476
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PVTMS
AF24NI
1/XYs+Y
100
9.4340.1315
8.92860.2835
8.47460.4
80.4474
7.57580.4265
7.14290.3502
6.75680.2451
6.41030.1397
6.06060.0568
5.74710.01223
5.43480
5.12820
4.85440
4.58720
4.34780
4.11520
3.89110
3.67650
3.48430
3.28950
3.11530
2.94990
2.78550
2.63850
2.49380.003039
2.35850.01152
2.23210.02302
2.11420.03412
20.04157
1.89040.04297
1.78890.03829
1.6920.0287
1.60.01722
1.51520.0072
1.43270.001107
1.3550
1.28210
1.21210
1.14680
1.08460
1.02670
0.970870
0.917430
0.869570
0.819670
0.775190
0.735290
0.694440.01651
0.657890.05959
0.621120.1343
0.588240.2379
0.558660.3645
0.526320.5045
0.497510.6473
0.47170.7822
0.446430.8987
0.421940.9888
0.41.046
0.377361.068
0.357141.053
0.337841.004
0.319490.9255
0.303030.8229
0.286530.7041
0.2710.5774
0.256410.451
0.242130.3321
0.229360.2274
0.216920.1412
0.205340.07633
0.194170.03277
0.183490.00889
0.173610
0.16420
0.155520.007121
0.147060.02066
0.139080.03848
0.131580.05799
0.124380.07635
0.117790.09083
0.111360.09944
0.105370.1007
0.10.09458
0.094340.08159
0.0892860.06371
0.0840340.04344
0.080.02398
0.0757580.008596
0.0714290
AF24NI
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
AF2400
NSIPAX
1/XYs+Y
200
18.7620
17.6370
16.5290
15.5280
14.5770
13.680
12.8370
12.0480
11.3120.05694
10.6160.2318
100.4657
9.34580.6802
8.77190.8108
8.26450.8149
7.75190.7033
7.24640.5096
6.80270.2944
6.41030.1191
6.02410.01815
5.64970
5.2910
4.97510
4.67290
4.3860
4.11520.02773
3.8610.1009
3.62320.2
3.40140.2964
3.18470.3612
2.9940.3721
2.8090.3277
2.63850.2384
2.47520.1335
2.32560.04632
2.18340
2.04920
1.92310
1.80510
1.6920
1.58980
1.49250
1.40060
1.31410
1.2330
1.15740
1.0870
1.02040
0.961540
0.90090
0.840340
0.793650
0.740740
0.69930
0.653590
0.61350
0.578030.135
0.540540.3441
0.507610.5274
0.476190.602
0.448430.5229
0.420170.3386
0.395260.1332
0.370370.001647
0.347220
0.32680
0.306750
0.287360
0.270270
0.253160
0.23810.05892
0.223210.3161
0.209640.7524
0.196851.172
0.18451.367
0.173311.246
0.16260.8212
0.152670.3209
0.143270.01984
0.134590
0.126260
0.118480
0.111230
0.104380
0.0980390
0.0917430
0.0862070
0.0813010
0.0763360
0.0714290
NSIPAX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PP2SiDPA
PTMSPN
1/XYs+Y
12.50
11.7920.1469
11.1360.4118
10.5040.6907
9.9010.8959
9.34580.9756
8.84960.9029
8.33330.7207
7.8740.5015
7.40740.2931
6.9930.12
6.62250.01835
6.21120
5.88240
5.55560
5.23560
4.95050
4.65120
4.40530
4.14940
3.92160
3.690
3.48430.01223
3.28950.04037
3.10560.07405
2.93260.102
2.76240.1193
2.6110.1154
2.46310.088
2.32560.04824
2.1930.01442
2.07040
1.95310
1.84160
1.73910
1.63930
1.5480
1.45990
1.37740
1.30040
1.2270
1.15740
1.09290
1.03090
0.970870
0.917430
0.869570
0.819670
0.769230
0.729930
0.684930.03948
0.649350.1213
0.609760.2269
0.578030.3211
0.543480.3766
0.512820.3787
0.485440.321
0.456620.225
0.431030.12
0.408160.03713
0.384620
0.362320.01163
0.342470.1045
0.322580.275
0.304880.5006
0.287360.7314
0.2710.9135
0.255750.9989
0.241550.9509
0.227790.7806
0.215050.5194
0.202840.2501
0.191570.06604
0.180830
0.170650
0.161030
0.151980
0.143270
0.135320
0.127550
0.120480
0.113640
0.107180
0.101210
0.0952380
0.090090
0.0847460
0.080
0.0757580
0.0714290
PTMSPN
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PTMSP
OMAX
1/XYs+Y
40
3.81680
3.64960
3.49650
3.33330
3.19490.01665
3.04880.06559
2.91550.145
2.78550.2476
2.65960.3599
2.54450.4679
2.43310.5583
2.32560.6196
2.22220.6455
2.12310.6323
2.02840.5826
1.94170.5018
1.85530.4002
1.7730.2901
1.69490.1849
1.61810.09756
1.5480.0367
1.47930.006795
1.41440
1.35140
1.2920
1.23460
1.17920
1.12740
1.07760
1.02990
0.980390
0.94340
0.90090
0.862070
0.819670
0.78740
0.751880
0.719420
0.684930
0.653590.01484
0.6250.06154
0.59880.1463
0.571430.2601
0.546450.3892
0.523560.516
0.50.6232
0.478470.698
0.456620.7309
0.436680.7206
0.416670.67
0.398410.5898
0.380230.4931
0.363640.3969
0.347220.318
0.332230.2711
0.317460.2679
0.303950.313
0.289860.406
0.277780.5376
0.265250.6937
0.253160.8537
0.242130.9948
0.231481.095
0.221241.133
0.211421.1
0.202020.9901
0.193050.8169
0.18450.6007
0.176370.3763
0.168630.1819
0.161290.04978
0.154080
0.147280
0.140850
0.134590
0.128530
0.122850
0.117510
0.112230
0.10730
0.102560
0.0980390
0.0934580
0.0892860
0.085470
0.0819670
0.0781250
0.0746270
0.0714290
OMAX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
OMAX
11
0
0.1469
0.4118
0.6907
0.8959
0.9756
0.9029
0.7207
0.5015
0.2931
0.12
0.01835
0
0
0
0
0
0
0
0
0
0
0.01223
0.04037
0.07405
0.102
0.1193
0.1154
0.088
0.04824
0.01442
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.03948
0.1213
0.2269
0.3211
0.3766
0.3787
0.321
0.225
0.12
0.03713
0
0.01163
0.1045
0.275
0.5006
0.7314
0.9135
0.9989
0.9509
0.7806
0.5194
0.2501
0.06604
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
t, ns
a(l)l
PTMSP
PFPDX
1/XYs+Y
6.66670
6.32910
6.02410
5.71430
5.43480
5.15460
4.9020
4.67290
4.42480
4.21940.02855
40.1067
3.80230.2199
3.61010.3465
3.43640.4653
3.2680.5586
3.10560.6186
2.94990.6421
2.80110.6327
2.66670.5958
2.53160.5384
2.40380.4668
2.28830.3865
2.17390.3021
2.06610.2185
1.96080.1407
1.86570.0751
1.7730.02809
1.68350.003294
1.60
1.51980
1.44510
1.37360
1.30550
1.24070
1.17790
1.11980
1.06380
1.01110
0.961540
0.917430
0.869570
0.826450
0.781250
0.746270
0.709220
0.671140
0.641030.02429
0.606060.1099
0.578030.2615
0.549450.4444
0.520830.6163
0.495050.7384
0.47170.7804
0.448430.737
0.425530.6162
0.404860.4487
0.384620.2719
0.364960.1233
0.347220.03308
0.330030
0.313480
0.297620
0.282490.06787
0.268820.2304
0.25510.4849
0.242720.7831
0.230411.063
0.21931.257
0.208331.308
0.198021.199
0.187970.9406
0.178890.6025
0.169780.2754
0.161550.05406
0.153370
0.145770
0.13850
0.131750
0.125160
0.118910
0.112990
0.107410
0.102040
0.0970870
0.0917430
0.0877190
0.0833330
0.0793650
0.0751880
0.0714290
PFPDX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PFPDMSS
PVTMSX
1/XYs+Y
6.66670
6.32910
6.02410
5.71430.01915
5.43480.09048
5.15460.2009
4.9020.3274
4.67290.4453
4.42480.5337
4.21940.5843
40.5948
3.80230.5733
3.61010.5307
3.43640.4799
3.2680.4326
3.10560.3954
2.94990.3719
2.80110.3591
2.66670.3514
2.53160.3406
2.40380.3186
2.28830.281
2.17390.2265
2.06610.1612
1.96080.09464
1.86570.03993
1.7730.008693
1.68350
1.60
1.51980
1.44510
1.37360
1.30550
1.24070
1.17790
1.11980
1.06380
1.01110
0.961540
0.917430
0.869570
0.826450
0.781250
0.746270
0.709220
0.671140
0.641030.00841
0.606060.07429
0.578030.2101
0.549450.3838
0.520830.5536
0.495050.6788
0.47170.7271
0.448430.6914
0.425530.5781
0.404860.4179
0.384620.2483
0.364960.1076
0.347220.02607
0.330030
0.313480
0.297620
0.282490
0.268820.018
0.25510.1234
0.242720.3155
0.230410.5662
0.21930.8143
0.208330.9939
0.198021.056
0.187970.9702
0.178890.7603
0.169780.4767
0.161550.2088
0.153370.04476
0.145770
0.13850
0.131750
0.125160
0.118910
0.112990
0.107410
0.102040
0.0970870
0.0917430
0.0877190
0.0833330
0.0793650
0.0751880
0.0714290
PVTMSX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PVTMS
AF24NI
1/XYs+Y
100
9.4340.1315
8.92860.2835
8.47460.4
80.4474
7.57580.4265
7.14290.3502
6.75680.2451
6.41030.1397
6.06060.0568
5.74710.01223
5.43480
5.12820
4.85440
4.58720
4.34780
4.11520
3.89110
3.67650
3.48430
3.28950
3.11530
2.94990
2.78550
2.63850
2.49380.003039
2.35850.01152
2.23210.02302
2.11420.03412
20.04157
1.89040.04297
1.78890.03829
1.6920.0287
1.60.01722
1.51520.0072
1.43270.001107
1.3550
1.28210
1.21210
1.14680
1.08460
1.02670
0.970870
0.917430
0.869570
0.819670
0.775190
0.735290
0.694440.01651
0.657890.05959
0.621120.1343
0.588240.2379
0.558660.3645
0.526320.5045
0.497510.6473
0.47170.7822
0.446430.8987
0.421940.9888
0.41.046
0.377361.068
0.357141.053
0.337841.004
0.319490.9255
0.303030.8229
0.286530.7041
0.2710.5774
0.256410.451
0.242130.3321
0.229360.2274
0.216920.1412
0.205340.07633
0.194170.03277
0.183490.00889
0.173610
0.16420
0.155520.007121
0.147060.02066
0.139080.03848
0.131580.05799
0.124380.07635
0.117790.09083
0.111360.09944
0.105370.1007
0.10.09458
0.094340.08159
0.0892860.06371
0.0840340.04344
0.080.02398
0.0757580.008596
0.0714290
AF24NI
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
AF2400
NSIPAX
1/XYs+Y
200
18.7620
17.6370
16.5290
15.5280
14.5770
13.680
12.8370
12.0480
11.3120.05694
10.6160.2318
100.4657
9.34580.6802
8.77190.8108
8.26450.8149
7.75190.7033
7.24640.5096
6.80270.2944
6.41030.1191
6.02410.01815
5.64970
5.2910
4.97510
4.67290
4.3860
4.11520.02773
3.8610.1009
3.62320.2
3.40140.2964
3.18470.3612
2.9940.3721
2.8090.3277
2.63850.2384
2.47520.1335
2.32560.04632
2.18340
2.04920
1.92310
1.80510
1.6920
1.58980
1.49250
1.40060
1.31410
1.2330
1.15740
1.0870
1.02040
0.961540
0.90090
0.840340
0.793650
0.740740
0.69930
0.653590
0.61350
0.578030.135
0.540540.3441
0.507610.5274
0.476190.602
0.448430.5229
0.420170.3386
0.395260.1332
0.370370.001647
0.347220
0.32680
0.306750
0.287360
0.270270
0.253160
0.23810.05892
0.223210.3161
0.209640.7524
0.196851.172
0.18451.367
0.173311.246
0.16260.8212
0.152670.3209
0.143270.01984
0.134590
0.126260
0.118480
0.111230
0.104380
0.0980390
0.0917430
0.0862070
0.0813010
0.0763360
0.0714290
NSIPAX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PP2SiDPA
PTMSPN
1/XYs+Y
12.50
11.7920.1469
11.1360.4118
10.5040.6907
9.9010.8959
9.34580.9756
8.84960.9029
8.33330.7207
7.8740.5015
7.40740.2931
6.9930.12
6.62250.01835
6.21120
5.88240
5.55560
5.23560
4.95050
4.65120
4.40530
4.14940
3.92160
3.690
3.48430.01223
3.28950.04037
3.10560.07405
2.93260.102
2.76240.1193
2.6110.1154
2.46310.088
2.32560.04824
2.1930.01442
2.07040
1.95310
1.84160
1.73910
1.63930
1.5480
1.45990
1.37740
1.30040
1.2270
1.15740
1.09290
1.03090
0.970870
0.917430
0.869570
0.819670
0.769230
0.729930
0.684930.03948
0.649350.1213
0.609760.2269
0.578030.3211
0.543480.3766
0.512820.3787
0.485440.321
0.456620.225
0.431030.12
0.408160.03713
0.384620
0.362320.01163
0.342470.1045
0.322580.275
0.304880.5006
0.287360.7314
0.2710.9135
0.255750.9989
0.241550.9509
0.227790.7806
0.215050.5194
0.202840.2501
0.191570.06604
0.180830
0.170650
0.161030
0.151980
0.143270
0.135320
0.127550
0.120480
0.113640
0.107180
0.101210
0.0952380
0.090090
0.0847460
0.080
0.0757580
0.0714290
PTMSPN
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PTMSP
OMAX
1/XYs+Y
40
3.81680
3.64960
3.49650
3.33330
3.19490.01665
3.04880.06559
2.91550.145
2.78550.2476
2.65960.3599
2.54450.4679
2.43310.5583
2.32560.6196
2.22220.6455
2.12310.6323
2.02840.5826
1.94170.5018
1.85530.4002
1.7730.2901
1.69490.1849
1.61810.09756
1.5480.0367
1.47930.006795
1.41440
1.35140
1.2920
1.23460
1.17920
1.12740
1.07760
1.02990
0.980390
0.94340
0.90090
0.862070
0.819670
0.78740
0.751880
0.719420
0.684930
0.653590.01484
0.6250.06154
0.59880.1463
0.571430.2601
0.546450.3892
0.523560.516
0.50.6232
0.478470.698
0.456620.7309
0.436680.7206
0.416670.67
0.398410.5898
0.380230.4931
0.363640.3969
0.347220.318
0.332230.2711
0.317460.2679
0.303950.313
0.289860.406
0.277780.5376
0.265250.6937
0.253160.8537
0.242130.9948
0.231481.095
0.221241.133
0.211421.1
0.202020.9901
0.193050.8169
0.18450.6007
0.176370.3763
0.168630.1819
0.161290.04978
0.154080
0.147280
0.140850
0.134590
0.128530
0.122850
0.117510
0.112230
0.10730
0.102560
0.0980390
0.0934580
0.0892860
0.085470
0.0819670
0.0781250
0.0746270
0.0714290
OMAX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
OMAX
-
2
3.04139268520.556302500812.531478917-0.251811973
2.3424226808-0.3746875490.85733249640.8808135923-0.7447274949
2.1760912591-0.61978875830.845098040.5797835966-0.5086383062
2.39794000870.39794000870.7160033436-1.3187587626
2.2041199827-0.39794000870
02.264817823
0.3979400087-0.8860566477
-1.251811973-0.5686362358
-0.1079053973
PTMSP
AF2400
AF1600
PVTMS
PC
d2, A2
7+LogD
1
De77+LogD
gasd,APTMSPAF2400AF1600PVTMSPCPTMSPAF2400AF1600PVTMSPCd2,A2
He1.78110034064.53.04139268522.5314789171.80955971463.1684
O22.89220107.60.562.342422680810.8808135923-0.2518119738.3521
N23.041507.23.80.182.17609125910.85733249640.5797835966-0.74472749499.2416
CO23.0225075.20.312.39794000870.845098040.7160033436-0.50863830629.1204
CH43.181602.510.0482.20411998270.39794000870-1.318758762610.1124
H22.141842.2648178234.5796
C2H63.693.60.40.130.5563025008-0.3979400087-0.886056647713.6161
C2H43.5710.270-0.568636235812.7449
C2H23.382.50.780.3979400087-0.107905397311.4244
C3H84.090.4220.056-0.374687549-1.25181197316.7281
C4H104.40.24-0.619788758319.36
Ar0
18.3521
0.85733249649.2416
0.845098049.1204
0.397940008710.1124
-0.397940008713.6161
012.7449
0.397940008711.4244
-1.25181197316.7281
2
2
3.04139268520.556302500812.531478917-0.251811973
2.3424226808-0.3746875490.85733249640.8808135923-0.7447274949
2.1760912591-0.61978875830.845098040.5797835966-0.5086383062
2.39794000870.39794000870.7160033436-1.3187587626
2.2041199827-0.39794000870
02.264817823
0.3979400087-0.8860566477
-1.251811973-0.5686362358
-0.1079053973
PTMSP
AF2400
AF1600
PVTMS
PC
d2, A2
7+LogD
3
-
7
0.124
0.168
0.207
0.27
0.31
0.28
0.385
0.435
0.435
0.5
, A3
-aD
PSF
PTMSP
PPrSiDPA
AF-2400
AF-1600
PVTMS
PPhSiDPA
PFPDMSS
PC
PS
1
6.80.816.85.02
60.5662.29
6.40.6550.37
3.80.056.42.17
3.70.023.80.06
3.70.033.70.05
4.30.163.70.09
3.4-0.034.30.14
3.40
PTMSP13230.124
PPrSiDPA10880.168
AF 24008820.207
AF 16004900.27
PVTMS3450.31
PPhSiDPA2260.28
PVPDMS1680.385
PS1100.435
PC1000.435
PSF1000.5
PDMS3500.065
3.89319.8
3.063.714.4
2.3616.224.4
1.084934.7
1.7511.731.6
1.5813.629
1.6424.731.5
0.428.535.2
1
00
00
00
00
00
00
00
00
Homo
Hetero
log P (Barrer)
Vf3/(Vf3+Vf4)
2
00
0
0
0
0
0
0
0
0
0
PDMS
Vf, A3
-a
8
9
7
6
5
4
3
2
1
10
PDMS
3
0
0
0
0
0
0
0
0
R4,
Dt
4
0
0
0
0
0
0
0
0
0
R4,
5
5
319.8
3.714.4
16.224.4
4934.7
11.731.6
13.629
24.731.5
28.535.2
Homo
Hetero
log P (Barrer)
-
Vf ():
-
Vf
2
-102.34.3
-13.801.2
-14.2-1.5-17.5
-18.4-2.3-20.3
-7.9-3.3-14.3
-1.7-0.7-11.3
2.9-5.1-5.8
2.9-5.82.9
-0.71
4.6
PVTMS
AF 2400
AF 1600
Vc [cm3/mol]
Hm [kJ/mol]
5-a
-102.34.3
-13.801.2
-14.2-1.5-17.5
-18.4-2.3-20.3
-7.9-3.3-14.3
-1.7-0.7-11.3
2.9-5.1-5.8
2.9-5.82.9
-0.71
4.6
PVTMS
AF 2400
AF 1600
Vc [cm3/mole]
Hm [kJ/mol]
5-b
0000
-0.014-0.02-0.0065-0.081
-0.043-0.094-0.024-0.224
-0.093-0.234-0.052-0.381
-0.157-0.41-0.089-0.49
-0.229-0.57-0.129-0.5
-0.296-0.68-0.169-0.395
-0.315-0.72-0.203-0.226
-0.35-0.66-0.223-0.069
-0.386-0.52-0.2260
-0.429-0.335-0.213
-0.486-0.16-0.181
-0.586-0.04-0.14
-0.5930-0.095
-0.586-0.052
-0.533-0.019
-0.443-0.003
-0.3290
-0.2
-0.086
-0.021
0
PVTMS
AF 2400
PTMSP
AF 1600
Vf, 3
- f (R)
5-a
AF 1600AF 2400PVTMS
VcHmVcHmVcHm
2554.32552.3200-10
3111.22600255-13.8
368-17.5311-1.5263-14.2
426-20.3368-2.3311-18.4
486-14.3426-3.3368-7.9
543-11.3543-0.7426-1.7
660-5.8602-5.14862.9
7182.9660-5.85432.9
718-0.71
7804.6
5-b
PVTMSPTMSP24001600
RfRfRfRf
12.56370014.9493014.3333014.53820
22.64477-0.01425.1555-0.0224.46371-0.006524.67426-0.081
32.68481-0.04335.3623-0.09434.65421-0.02434.75449-0.224
42.80993-0.09345.5697-0.23444.86481-0.05244.88487-0.381
52.945107-0.15755.6735-0.4155523-0.08955.02530-0.49
63.032117-0.22965.8817-0.5765.23599-0.12965.21592-0.5
73.173134-0.29676904-0.6875.42667-0.16975.34638-0.395
83.213139-0.31586.41098-0.7285.62743-0.20385.5697-0.226
93.352158-0.3596.61204-0.6695.84834-0.22395.62743-0.069
103.743220-0.386106.81316-0.52106.05927-0.226105.778040
113.833236-0.429117.061473-0.335116.281037-0.213
123.939256-0.486127.31629-0.16126.511155-0.181
134.052279-0.586137.51766-0.04136.721271-0.14
144.245320-0.593147.719110146.951405-0.095
154.353345-0.586157.21563-0.052
164.528389-0.533167.421710-0.019
174.704436-0.443177.671889-0.003
184.752449-0.329187.920640
194.844476-0.2
204.978516-0.086
215.022530-0.021
225.2125930
3
3
0000
-0.014-0.02-0.0065-0.081
-0.043-0.094-0.024-0.224
-0.093-0.234-0.052-0.381
-0.157-0.41-0.089-0.49
-0.229-0.57-0.129-0.5
-0.296-0.68-0.169-0.395
-0.315-0.72-0.203-0.226
-0.35-0.66-0.223-0.069
-0.386-0.52-0.2260
-0.429-0.335-0.213
-0.486-0.16-0.181
-0.586-0.04-0.14
-0.5930-0.095
-0.586-0.052
-0.533-0.019
-0.443-0.003
-0.3290
-0.2
-0.086
-0.021
0
PVTMS
AF 2400
PTMSP
AF 1600
Vf, 3
- f (R)
-102.34.3
-13.801.2
-14.2-1.5-17.5
-18.4-2.3-20.3
-7.9-3.3-14.3
-1.7-0.7-11.3
2.9-5.1-5.8
2.9-5.82.9
-0.71
4.6
PVTMS
AF 2400
AF 1600
Vc [cm3/mol]
Hm [kJ/mol]
-
: 2 SiMe3 ()
-
(Vc)min P ()
-
(3)
-
()Vf=NholeVhole
1
3.8864907252
3.0569048513
2.2304489214
2.3560258572
1.079181246
1.748188027
1.5797835966
1.6434526765
0.3979400087
1/Vf4
1/Vf4
LogP
1
PolymerHomogeneous modelHeterogeneous model
Vf3103Vf4103(Vf3+Vf3)103Vf3/(Vf3+Vf4)Vf3103Vf4103(Vf3+Vf3)103Vf3/(Vf3+Vf4)
PTMSP2.580.683.10.0322.591113.50.198
AF24001.334.235.50.0377.343.350.60.144
AF16000.319.319.60.0150.7424.425.10.029
PPrSiDPA10.55464.80.16228.488.1116.20.244
PPhSiDPA7.7815.70.4911.922.434.30.347
PTMSS3.425.6290.11714.932.247.10.316
PFPDMSS2.817.820.60.13610.926.737.60.29
PVTMS8.425.6340.24722.248.370.50.315
PVPDMS4.912.317.20.28511.621.332.90.352
Polymerr, g/cm3FFV, %Tg, oCP(O2), Barrer[O2]10-18, cm-3
PTMSP0.750.34>28077007-Oct
AF24001.740.3224011405
AF16001.80.281601704.1
PPrSiDPA1.040.12>27022714
PhSiDPA1.210.15>430124.2
PTMSS0.9650.191135561.6
PFPDMSS1.1270.18662380.84
PVTMS0.860.195150442.4
PVPDMS1.0430.1341202.50.43
Nafion-1172.02-1201.11
2
HomoP(O2), BarrerVf4, %vf3+vf4, %logP1/Vf41/(Vf3+Vf4)
PTMSP77008.068.313.88649072520.12406947890.1203369434
AF240011403.423.553.05690485130.29239766080.2816901408
AF16001701.931.962.23044892140.5181347150.5102040816
PPrSiDPA2275.46.482.35602585720.18518518520.1543209877
PhSiDPA120.81.571.0791812461.250.6369426752
PTMSS562.562.91.7481880270.3906250.3448275862
PFPDMSS381.782.061.57978359660.56179775280.4854368932
PVTMS442.563.41.64345267650.3906250.2941176471
PVPDMS2.51.231.720.39794000870.81300813010.5813953488
HeteroP(O2), BarrerVf4, %vf3+vf4, %logP1/Vf41/(Vf3+Vf4)
PTMSP77009.111.353.88649072520.10989010990.0881057269
AF240011404.335.063.05690485130.23094688220.1976284585
AF16001702.442.512.23044892140.40983606560.3984063745
PPrSiDPA2278.8111.622.35602585720.1135073780.0860585198
PhSiDPA122.243.431.0791812460.44642857140.2915451895
PTMSS563.224.711.7481880270.31055900620.2123142251
PFPDMSS382.673.761.57978359660.37453183520.2659574468
PVTMS444.837.051.64345267650.20703933750.1418439716
PVPDMS2.52.133.290.39794000870.46948356810.3039513678
3
3
3.8864907252
3.0569048513
2.2304489214
2.3560258572
1.079181246
1.748188027
1.5797835966
1.6434526765
0.3979400087
1/Vf4
1/Vf4
LogP
Homo
3.8864907252
3.0569048513
2.2304489214
2.3560258572
1.079181246
1.748188027
1.5797835966
1.6434526765
0.3979400087
1/Vf4
1/(Vf3+Vf4)
LogP
Homo
3.8864907252
3.0569048513
2.2304489214
2.3560258572
1.079181246
1.748188027
1.5797835966
1.6434526765
0.3979400087
1/Vf4
1/Vf4
LogP
Hetero
3.8864907252
3.0569048513
2.2304489214
2.3560258572
1.079181246
1.748188027
1.5797835966
1.6434526765
0.3979400087
1/Vf4
1/(Vf3+Vf4)
LogP
Hetero
2
3.8864907252
3.0569048513
2.2304489214
2.3560258572
1.079181246
1.748188027
1.5797835966
1.6434526765
0.3979400087
1/Vf4
1/(Vf3+Vf4)
LogP
1
PolymerHomogeneous modelHeterogeneous model
Vf3103Vf4103(Vf3+Vf3)103Vf3/(Vf3+Vf4)Vf3103Vf4103(Vf3+Vf3)103Vf3/(Vf3+Vf4)
PTMSP2.580.683.10.0322.591113.50.198
AF24001.334.235.50.0377.343.350.60.144
AF16000.319.319.60.0150.7424.425.10.029
PPrSiDPA10.55464.80.16228.488.1116.20.244
PPhSiDPA7.7815.70.4911.922.434.30.347
PTMSS3.425.6290.11714.932.247.10.316
PFPDMSS2.817.820.60.13610.926.737.60.29
PVTMS8.425.6340.24722.248.370.50.315
PVPDMS4.912.317.20.28511.621.332.90.352
Polymerr, g/cm3FFV, %Tg, oCP(O2), Barrer[O2]10-18, cm-3
PTMSP0.750.34>28077007-Oct
AF24001.740.3224011405
AF16001.80.281601704.1
PPrSiDPA1.040.12>27022714
PhSiDPA1.210.15>430124.2
PTMSS0.9650.191135561.6
PFPDMSS1.1270.18662380.84
PVTMS0.860.195150442.4
PVPDMS1.0430.1341202.50.43
Nafion-1172.02-1201.11
2
HomoP(O2), BarrerVf4, %vf3+vf4, %logP1/Vf41/(Vf3+Vf4)
PTMSP77008.068.313.88649072520.12406947890.1203369434
AF240011403.423.553.05690485130.29239766080.2816901408
AF16001701.931.962.23044892140.5181347150.5102040816
PPrSiDPA2275.46.482.35602585720.18518518520.1543209877
PhSiDPA120.81.571.0791812461.250.6369426752
PTMSS562.562.91.7481880270.3906250.3448275862
PFPDMSS381.782.061.57978359660.56179775280.4854368932
PVTMS442.563.41.64345267650.3906250.2941176471
PVPDMS2.51.231.720.39794000870.81300813010.5813953488
HeteroP(O2), BarrerVf4, %vf3+vf4, %logP1/Vf41/(Vf3+Vf4)
PTMSP77009.111.353.88649072520.10989010990.0881057269
AF240011404.335.063.05690485130.23094688220.1976284585
AF16001702.442.512.23044892140.40983606560.3984063745
PPrSiDPA2278.8111.622.35602585720.1135073780.0860585198
PhSiDPA122.243.431.0791812460.44642857140.2915451895
PTMSS563.224.711.7481880270.31055900620.2123142251
PFPDMSS382.673.761.57978359660.37453183520.2659574468
PVTMS444.837.051.64345267650.20703933750.1418439716
PVPDMS2.52.133.290.39794000870.46948356810.3039513678
3
3
3.8864907252
3.0569048513
2.2304489214
2.3560258572
1.079181246
1.748188027
1.5797835966
1.6434526765
0.3979400087
1/Vf4
1/Vf4
LogP
Homo
3.8864907252
3.0569048513
2.2304489214
2.3560258572
1.079181246
1.748188027
1.5797835966
1.6434526765
0.3979400087
1/Vf4
1/(Vf3+Vf4)
LogP
Homo
3.8864907252
3.0569048513
2.2304489214
2.3560258572
1.079181246
1.748188027
1.5797835966
1.6434526765
0.3979400087
1/Vf4
1/Vf4
LogP
Hetero
3.8864907252
3.0569048513
2.2304489214
2.3560258572
1.079181246
1.748188027
1.5797835966
1.6434526765
0.3979400087
1/Vf4
1/(Vf3+Vf4)
LogP
Hetero
-
D Vf(Faupel et al., 2002)log D = log Do B/2.3Vh
-
(Faupel et al., 2002) = a + b ecoh
-
N 1020 -3
-
PTMSSPTMSS-33.0 slices along the z-axis 4.50 nm D.Hofmann (GKSS)
-
PTMSPPTMSP-13.11 slices along the z-axis4.99 nm D.Hofmann (GKSS)
-
AF2400AF2400-22.99 slices along the x-axis 4.983 nm D.Hofmann (GKSS)n=0.87
-
P D - PTMSP AF P, D107, 2 -1
-
Economou (2003)
-
D.Hofmann (GKSS)
-
(Rmax)R3 R4
-
(Vconnect)
R3 R4
-
7
0
0
0
0
0
0
0
0
0
0.02855
0.1067
0.2199
0.3465
0.4653
0.5586
0.6186
0.6421
0.6327
0.5958
0.5384
0.4668
0.3865
0.3021
0.2185
0.1407
0.0751
0.02809
0.003294
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.02429
0.1099
0.2615
0.4444
0.6163
0.7384
0.7804
0.737
0.6162
0.4487
0.2719
0.1233
0.03308
0
0
0
0.06787
0.2304
0.4849
0.7831
1.063
1.257
1.308
1.199
0.9406
0.6025
0.2754
0.05406
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
a(l)l
PFPDMSS
PFPDX
1/XYs+Y
6.66670
6.32910
6.02410
5.71430
5.43480
5.15460
4.9020
4.67290
4.42480
4.21940.02855
40.1067
3.80230.2199
3.61010.3465
3.43640.4653
3.2680.5586
3.10560.6186
2.94990.6421
2.80110.6327
2.66670.5958
2.53160.5384
2.40380.4668
2.28830.3865
2.17390.3021
2.06610.2185
1.96080.1407
1.86570.0751
1.7730.02809
1.68350.003294
1.60
1.51980
1.44510
1.37360
1.30550
1.24070
1.17790
1.11980
1.06380
1.01110
0.961540
0.917430
0.869570
0.826450
0.781250
0.746270
0.709220
0.671140
0.641030.02429
0.606060.1099
0.578030.2615
0.549450.4444
0.520830.6163
0.495050.7384
0.47170.7804
0.448430.737
0.425530.6162
0.404860.4487
0.384620.2719
0.364960.1233
0.347220.03308
0.330030
0.313480
0.297620
0.282490.06787
0.268820.2304
0.25510.4849
0.242720.7831
0.230411.063
0.21931.257
0.208331.308
0.198021.199
0.187970.9406
0.178890.6025
0.169780.2754
0.161550.05406
0.153370
0.145770
0.13850
0.131750
0.125160
0.118910
0.112990
0.107410
0.102040
0.0970870
0.0917430
0.0877190
0.0833330
0.0793650
0.0751880
0.0714290
PFPDX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PFPDMSS
PVTMSX
1/XYs+Y
6.66670
6.32910
6.02410
5.71430.01915
5.43480.09048
5.15460.2009
4.9020.3274
4.67290.4453
4.42480.5337
4.21940.5843
40.5948
3.80230.5733
3.61010.5307
3.43640.4799
3.2680.4326
3.10560.3954
2.94990.3719
2.80110.3591
2.66670.3514
2.53160.3406
2.40380.3186
2.28830.281
2.17390.2265
2.06610.1612
1.96080.09464
1.86570.03993
1.7730.008693
1.68350
1.60
1.51980
1.44510
1.37360
1.30550
1.24070
1.17790
1.11980
1.06380
1.01110
0.961540
0.917430
0.869570
0.826450
0.781250
0.746270
0.709220
0.671140
0.641030.00841
0.606060.07429
0.578030.2101
0.549450.3838
0.520830.5536
0.495050.6788
0.47170.7271
0.448430.6914
0.425530.5781
0.404860.4179
0.384620.2483
0.364960.1076
0.347220.02607
0.330030
0.313480
0.297620
0.282490
0.268820.018
0.25510.1234
0.242720.3155
0.230410.5662
0.21930.8143
0.208330.9939
0.198021.056
0.187970.9702
0.178890.7603
0.169780.4767
0.161550.2088
0.153370.04476
0.145770
0.13850
0.131750
0.125160
0.118910
0.112990
0.107410
0.102040
0.0970870
0.0917430
0.0877190
0.0833330
0.0793650
0.0751880
0.0714290
PVTMSX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PVTMS
AF24NI
1/XYs+Y
100
9.4340.1315
8.92860.2835
8.47460.4
80.4474
7.57580.4265
7.14290.3502
6.75680.2451
6.41030.1397
6.06060.0568
5.74710.01223
5.43480
5.12820
4.85440
4.58720
4.34780
4.11520
3.89110
3.67650
3.48430
3.28950
3.11530
2.94990
2.78550
2.63850
2.49380.003039
2.35850.01152
2.23210.02302
2.11420.03412
20.04157
1.89040.04297
1.78890.03829
1.6920.0287
1.60.01722
1.51520.0072
1.43270.001107
1.3550
1.28210
1.21210
1.14680
1.08460
1.02670
0.970870
0.917430
0.869570
0.819670
0.775190
0.735290
0.694440.01651
0.657890.05959
0.621120.1343
0.588240.2379
0.558660.3645
0.526320.5045
0.497510.6473
0.47170.7822
0.446430.8987
0.421940.9888
0.41.046
0.377361.068
0.357141.053
0.337841.004
0.319490.9255
0.303030.8229
0.286530.7041
0.2710.5774
0.256410.451
0.242130.3321
0.229360.2274
0.216920.1412
0.205340.07633
0.194170.03277
0.183490.00889
0.173610
0.16420
0.155520.007121
0.147060.02066
0.139080.03848
0.131580.05799
0.124380.07635
0.117790.09083
0.111360.09944
0.105370.1007
0.10.09458
0.094340.08159
0.0892860.06371
0.0840340.04344
0.080.02398
0.0757580.008596
0.0714290
AF24NI
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
AF2400
NSIPAX
1/XYs+Y
200
18.7620
17.6370
16.5290
15.5280
14.5770
13.680
12.8370
12.0480
11.3120.05694
10.6160.2318
100.4657
9.34580.6802
8.77190.8108
8.26450.8149
7.75190.7033
7.24640.5096
6.80270.2944
6.41030.1191
6.02410.01815
5.64970
5.2910
4.97510
4.67290
4.3860
4.11520.02773
3.8610.1009
3.62320.2
3.40140.2964
3.18470.3612
2.9940.3721
2.8090.3277
2.63850.2384
2.47520.1335
2.32560.04632
2.18340
2.04920
1.92310
1.80510
1.6920
1.58980
1.49250
1.40060
1.31410
1.2330
1.15740
1.0870
1.02040
0.961540
0.90090
0.840340
0.793650
0.740740
0.69930
0.653590
0.61350
0.578030.135
0.540540.3441
0.507610.5274
0.476190.602
0.448430.5229
0.420170.3386
0.395260.1332
0.370370.001647
0.347220
0.32680
0.306750
0.287360
0.270270
0.253160
0.23810.05892
0.223210.3161
0.209640.7524
0.196851.172
0.18451.367
0.173311.246
0.16260.8212
0.152670.3209
0.143270.01984
0.134590
0.126260
0.118480
0.111230
0.104380
0.0980390
0.0917430
0.0862070
0.0813010
0.0763360
0.0714290
NSIPAX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PP2SiDPA
PTMSPN
1/XYs+Y
12.50
11.7920.1469
11.1360.4118
10.5040.6907
9.9010.8959
9.34580.9756
8.84960.9029
8.33330.7207
7.8740.5015
7.40740.2931
6.9930.12
6.62250.01835
6.21120
5.88240
5.55560
5.23560
4.95050
4.65120
4.40530
4.14940
3.92160
3.690
3.48430.01223
3.28950.04037
3.10560.07405
2.93260.102
2.76240.1193
2.6110.1154
2.46310.088
2.32560.04824
2.1930.01442
2.07040
1.95310
1.84160
1.73910
1.63930
1.5480
1.45990
1.37740
1.30040
1.2270
1.15740
1.09290
1.03090
0.970870
0.917430
0.869570
0.819670
0.769230
0.729930
0.684930.03948
0.649350.1213
0.609760.2269
0.578030.3211
0.543480.3766
0.512820.3787
0.485440.321
0.456620.225
0.431030.12
0.408160.03713
0.384620
0.362320.01163
0.342470.1045
0.322580.275
0.304880.5006
0.287360.7314
0.2710.9135
0.255750.9989
0.241550.9509
0.227790.7806
0.215050.5194
0.202840.2501
0.191570.06604
0.180830
0.170650
0.161030
0.151980
0.143270
0.135320
0.127550
0.120480
0.113640
0.107180
0.101210
0.0952380
0.090090
0.0847460
0.080
0.0757580
0.0714290
PTMSPN
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PTMSP
OMAX
1/XYs+Y
40
3.81680
3.64960
3.49650
3.33330
3.19490.01665
3.04880.06559
2.91550.145
2.78550.2476
2.65960.3599
2.54450.4679
2.43310.5583
2.32560.6196
2.22220.6455
2.12310.6323
2.02840.5826
1.94170.5018
1.85530.4002
1.7730.2901
1.69490.1849
1.61810.09756
1.5480.0367
1.47930.006795
1.41440
1.35140
1.2920
1.23460
1.17920
1.12740
1.07760
1.02990
0.980390
0.94340
0.90090
0.862070
0.819670
0.78740
0.751880
0.719420
0.684930
0.653590.01484
0.6250.06154
0.59880.1463
0.571430.2601
0.546450.3892
0.523560.516
0.50.6232
0.478470.698
0.456620.7309
0.436680.7206
0.416670.67
0.398410.5898
0.380230.4931
0.363640.3969
0.347220.318
0.332230.2711
0.317460.2679
0.303950.313
0.289860.406
0.277780.5376
0.265250.6937
0.253160.8537
0.242130.9948
0.231481.095
0.221241.133
0.211421.1
0.202020.9901
0.193050.8169
0.18450.6007
0.176370.3763
0.168630.1819
0.161290.04978
0.154080
0.147280
0.140850
0.134590
0.128530
0.122850
0.117510
0.112230
0.10730
0.102560
0.0980390
0.0934580
0.0892860
0.085470
0.0819670
0.0781250
0.0746270
0.0714290
OMAX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
OMAX
8
0
0
0
0.01915
0.09048
0.2009
0.3274
0.4453
0.5337
0.5843
0.5948
0.5733
0.5307
0.4799
0.4326
0.3954
0.3719
0.3591
0.3514
0.3406
0.3186
0.281
0.2265
0.1612
0.09464
0.03993
0.008693
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.00841
0.07429
0.2101
0.3838
0.5536
0.6788
0.7271
0.6914
0.5781
0.4179
0.2483
0.1076
0.02607
0
0
0
0
0.018
0.1234
0.3155
0.5662
0.8143
0.9939
1.056
0.9702
0.7603
0.4767
0.2088
0.04476
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
t, ns
a(l)l
PVTMS
PFPDX
1/XYs+Y
6.66670
6.32910
6.02410
5.71430
5.43480
5.15460
4.9020
4.67290
4.42480
4.21940.02855
40.1067
3.80230.2199
3.61010.3465
3.43640.4653
3.2680.5586
3.10560.6186
2.94990.6421
2.80110.6327
2.66670.5958
2.53160.5384
2.40380.4668
2.28830.3865
2.17390.3021
2.06610.2185
1.96080.1407
1.86570.0751
1.7730.02809
1.68350.003294
1.60
1.51980
1.44510
1.37360
1.30550
1.24070
1.17790
1.11980
1.06380
1.01110
0.961540
0.917430
0.869570
0.826450
0.781250
0.746270
0.709220
0.671140
0.641030.02429
0.606060.1099
0.578030.2615
0.549450.4444
0.520830.6163
0.495050.7384
0.47170.7804
0.448430.737
0.425530.6162
0.404860.4487
0.384620.2719
0.364960.1233
0.347220.03308
0.330030
0.313480
0.297620
0.282490.06787
0.268820.2304
0.25510.4849
0.242720.7831
0.230411.063
0.21931.257
0.208331.308
0.198021.199
0.187970.9406
0.178890.6025
0.169780.2754
0.161550.05406
0.153370
0.145770
0.13850
0.131750
0.125160
0.118910
0.112990
0.107410
0.102040
0.0970870
0.0917430
0.0877190
0.0833330
0.0793650
0.0751880
0.0714290
PFPDX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PFPDMSS
PVTMSX
1/XYs+Y
6.66670
6.32910
6.02410
5.71430.01915
5.43480.09048
5.15460.2009
4.9020.3274
4.67290.4453
4.42480.5337
4.21940.5843
40.5948
3.80230.5733
3.61010.5307
3.43640.4799
3.2680.4326
3.10560.3954
2.94990.3719
2.80110.3591
2.66670.3514
2.53160.3406
2.40380.3186
2.28830.281
2.17390.2265
2.06610.1612
1.96080.09464
1.86570.03993
1.7730.008693
1.68350
1.60
1.51980
1.44510
1.37360
1.30550
1.24070
1.17790
1.11980
1.06380
1.01110
0.961540
0.917430
0.869570
0.826450
0.781250
0.746270
0.709220
0.671140
0.641030.00841
0.606060.07429
0.578030.2101
0.549450.3838
0.520830.5536
0.495050.6788
0.47170.7271
0.448430.6914
0.425530.5781
0.404860.4179
0.384620.2483
0.364960.1076
0.347220.02607
0.330030
0.313480
0.297620
0.282490
0.268820.018
0.25510.1234
0.242720.3155
0.230410.5662
0.21930.8143
0.208330.9939
0.198021.056
0.187970.9702
0.178890.7603
0.169780.4767
0.161550.2088
0.153370.04476
0.145770
0.13850
0.131750
0.125160
0.118910
0.112990
0.107410
0.102040
0.0970870
0.0917430
0.0877190
0.0833330
0.0793650
0.0751880
0.0714290
PVTMSX
0
0
0
0.01915
0.09048
0.2009
0.3274
0.4453
0.5337
0.5843
0.5948
0.5733
0.5307
0.4799
0.4326
0.3954
0.3719
0.3591
0.3514
0.3406
0.3186
0.281
0.2265
0.1612
0.09464
0.03993
0.008693
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.00841
0.07429
0.2101
0.3838
0.5536
0.6788
0.7271
0.6914
0.5781
0.4179
0.2483
0.1076
0.02607
0
0
0
0
0.018
0.1234
0.3155
0.5662
0.8143
0.9939
1.056
0.9702
0.7603
0.4767
0.2088
0.04476
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PVTMS
AF24NI
1/XYs+Y
100
9.4340.1315
8.92860.2835
8.47460.4
80.4474
7.57580.4265
7.14290.3502
6.75680.2451
6.41030.1397
6.06060.0568
5.74710.01223
5.43480
5.12820
4.85440
4.58720
4.34780
4.11520
3.89110
3.67650
3.48430
3.28950
3.11530
2.94990
2.78550
2.63850
2.49380.003039
2.35850.01152
2.23210.02302
2.11420.03412
20.04157
1.89040.04297
1.78890.03829
1.6920.0287
1.60.01722
1.51520.0072
1.43270.001107
1.3550
1.28210
1.21210
1.14680
1.08460
1.02670
0.970870
0.917430
0.869570
0.819670
0.775190
0.735290
0.694440.01651
0.657890.05959
0.621120.1343
0.588240.2379
0.558660.3645
0.526320.5045
0.497510.6473
0.47170.7822
0.446430.8987
0.421940.9888
0.41.046
0.377361.068
0.357141.053
0.337841.004
0.319490.9255
0.303030.8229
0.286530.7041
0.2710.5774
0.256410.451
0.242130.3321
0.229360.2274
0.216920.1412
0.205340.07633
0.194170.03277
0.183490.00889
0.173610
0.16420
0.155520.007121
0.147060.02066
0.139080.03848
0.131580.05799
0.124380.07635
0.117790.09083
0.111360.09944
0.105370.1007
0.10.09458
0.094340.08159
0.0892860.06371
0.0840340.04344
0.080.02398
0.0757580.008596
0.0714290
AF24NI
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
AF2400
NSIPAX
1/XYs+Y
200
18.7620
17.6370
16.5290
15.5280
14.5770
13.680
12.8370
12.0480
11.3120.05694
10.6160.2318
100.4657
9.34580.6802
8.77190.8108
8.26450.8149
7.75190.7033
7.24640.5096
6.80270.2944
6.41030.1191
6.02410.01815
5.64970
5.2910
4.97510
4.67290
4.3860
4.11520.02773
3.8610.1009
3.62320.2
3.40140.2964
3.18470.3612
2.9940.3721
2.8090.3277
2.63850.2384
2.47520.1335
2.32560.04632
2.18340
2.04920
1.92310
1.80510
1.6920
1.58980
1.49250
1.40060
1.31410
1.2330
1.15740
1.0870
1.02040
0.961540
0.90090
0.840340
0.793650
0.740740
0.69930
0.653590
0.61350
0.578030.135
0.540540.3441
0.507610.5274
0.476190.602
0.448430.5229
0.420170.3386
0.395260.1332
0.370370.001647
0.347220
0.32680
0.306750
0.287360
0.270270
0.253160
0.23810.05892
0.223210.3161
0.209640.7524
0.196851.172
0.18451.367
0.173311.246
0.16260.8212
0.152670.3209
0.143270.01984
0.134590
0.126260
0.118480
0.111230
0.104380
0.0980390
0.0917430
0.0862070
0.0813010
0.0763360
0.0714290
NSIPAX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PP2SiDPA
PTMSPN
1/XYs+Y
12.50
11.7920.1469
11.1360.4118
10.5040.6907
9.9010.8959
9.34580.9756
8.84960.9029
8.33330.7207
7.8740.5015
7.40740.2931
6.9930.12
6.62250.01835
6.21120
5.88240
5.55560
5.23560
4.95050
4.65120
4.40530
4.14940
3.92160
3.690
3.48430.01223
3.28950.04037
3.10560.07405
2.93260.102
2.76240.1193
2.6110.1154
2.46310.088
2.32560.04824
2.1930.01442
2.07040
1.95310
1.84160
1.73910
1.63930
1.5480
1.45990
1.37740
1.30040
1.2270
1.15740
1.09290
1.03090
0.970870
0.917430
0.869570
0.819670
0.769230
0.729930
0.684930.03948
0.649350.1213
0.609760.2269
0.578030.3211
0.543480.3766
0.512820.3787
0.485440.321
0.456620.225
0.431030.12
0.408160.03713
0.384620
0.362320.01163
0.342470.1045
0.322580.275
0.304880.5006
0.287360.7314
0.2710.9135
0.255750.9989
0.241550.9509
0.227790.7806
0.215050.5194
0.202840.2501
0.191570.06604
0.180830
0.170650
0.161030
0.151980
0.143270
0.135320
0.127550
0.120480
0.113640
0.107180
0.101210
0.0952380
0.090090
0.0847460
0.080
0.0757580
0.0714290
PTMSPN
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
PTMSP
OMAX
1/XYs+Y
40
3.81680
3.64960
3.49650
3.33330
3.19490.01665
3.04880.06559
2.91550.145
2.78550.2476
2.65960.3599
2.54450.4679
2.43310.5583
2.32560.6196
2.22220.6455
2.12310.6323
2.02840.5826
1.94170.5018
1.85530.4002
1.7730.2901
1.69490.1849
1.61810.09756
1.5480.0367
1.47930.006795
1.41440
1.35140
1.2920
1.23460
1.17920
1.12740
1.07760
1.02990
0.980390
0.94340
0.90090
0.862070
0.819670
0.78740
0.751880
0.719420
0.684930
0.653590.01484
0.6250.06154
0.59880.1463
0.571430.2601
0.546450.3892
0.523560.516
0.50.6232
0.478470.698
0.456620.7309
0.436680.7206
0.416670.67
0.398410.5898
0.380230.4931
0.363640.3969
0.347220.318
0.332230.2711
0.317460.2679
0.303950.313
0.289860.406
0.277780.5376
0.265250.6937
0.253160.8537
0.242130.9948
0.231481.095
0.221241.133
0.211421.1
0.202020.9901
0.193050.8169
0.18450.6007
0.176370.3763
0.168630.1819
0.161290.04978
0.154080
0.147280
0.140850
0.134590
0.128530
0.122850
0.117510
0.112230
0.10730
0.102560
0.0980390
0.0934580
0.0892860
0.085470
0.0819670
0.0781250
0.0746270
0.0714290
OMAX
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Ys+Y
OMAX
11
0
0.1469
0.4118
0.6907
0.8959
0.9756
0.9029
0.7207
0.5015
0.2931
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