Study of Processes Study of Processes of Hydrogen Isotope of Hydrogen Isotope
Interaction with Interaction with Lithium CPSLithium CPS
I. Tazhibayeva1, E. Kenzhin1, T. Kulsartov1, Yu. Gordienko1, Yu. Ponkratov1, E. Tulubaev1,
N.Barsukov1, A. Kulsartova2
1: Institute of Atomic Energy of National Nuclear Center RK, 071100, Kurchatov, Kazakhstan2: Nuclear Technology Safety Center, Almaty, Kazakhstan
International Symposium on Lithium Applications for Fusion Devices,
PPPL, Princeton, New Jersey, USA, 27-29 April, 2011
KTM TokamakKTM Tokamak UniquenessUniquenessKTM tokamak is located in Kurchatov city, Kazakhstan, former STS. Tokamak KTM has an opportunity of operative access to vacuum chamber to replace divertor components without loss of vacuum. Parameters of energy loads, wide range of used methods and diagnostics allow for high level studies and tests in divertor volume, which is highly important for study of plasma facing materials for ITER and DEMO programs and for other experimental and power fusion reactors.These properties allow to successfully solve a problem of lithium divertor development. Trial start-up of Tokamak KTM was done September, 5,2010.
Kazakhstan Material Testing Tokamak - KTM
• Tokamak KTM is facility, where plasma has the configuration, extended on a vertical
• Working body is the mix of hydrogen and deuterium• Cooling coils of electromagnetic system of tokamak KTM by
water (warm windings) is used• Main stream power of the plasma is directed into divertor
area at the receiving tiles • Research and study of the divertor tiles made from various
materials and of various designs is main goal of the facility operation
• Potentials of the capillary-porous liquid metal units as power divertor receivers are proposed to study at the tokamak KTM.
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Scheme of location of lithium divertor Scheme of location of lithium divertor module in KTMmodule in KTM
Development and justification of lithium Development and justification of lithium divertor demonstration models of KTM tokamakdivertor demonstration models of KTM tokamak
Work is carried out jointly by IAE NNC, Krasnaya Zvezda (Red Star) and TRINITI in framework of the ISTC project K-1561; EU financing, collaborator – ENEA, Italy.Goal – testing of the lithium divertor model at KTM and issuing the recommendations on use of lithium technologies in tokamak-reactors.
Principal Scheme of module of lithium CPS Principal Scheme of module of lithium CPS for KTM Tokamakfor KTM Tokamak
1 − vacuum chamber; 2 − lithium divertor module;3 − pipeline for liquid metal supply (Li, Na-K);
4 − receiving divertor plates.
1 − CPS; 2 − cooling lids; 3 − collector; 4 − coolant tank; 5 − collector's lids;
6 − lithium channel; 7 − coolant channels.
Characteristic Value
Power flux to the surface up to 10 MW/m2
Discharge duration up to 5 s
Max. energy on PFS per plasma shot 750 kJ
Initial lithium surface temperature ≥ 200oC
Max. lithium surface local temperature during plasma interaction
≤550oC
Number of shots in experiments > 1000
Strutural material 316 SS type
CPS material 316 SS, W felt
Heat transfer media of heating/cooling system Na-K eutectic alloy
Characteristics of the lithium Characteristics of the lithium divertor module of KTMdivertor module of KTM
Demonstration models of lithium Demonstration models of lithium divertor of KTM tokamakdivertor of KTM tokamak
Size of MLD and distribution of heat load along the surface in
the lithium divertor module
Module will replace one of 24 graphite tiles of the divertor and will be connected with module’s external components through the pipelines.
Main aims of lithium experiment in KTM should be:• investigation of lithium behavior under tokamak conditions,
• investigation of efficiency of lithium non-coronal radiation,
• plasma confinement in tokamak with lithium divertor and wall,
• investigations of plasma wall interaction,Lithium divertor module consist of:
1. In-vessel lithium unit
2. External system for thermal stabilization
Main Goal of lithium Main Goal of lithium experiments in KTMexperiments in KTM
In-vessel unit of the lithium divertor moduleIn-vessel unit of the lithium divertor module
Cooling channel
PF surface – Li CPS
Lithium volume
Na-K flow direction
Internal structure of module
Main Goal of WorkMain Goal of Work
• Goal of present work is to assess parameters of hydrogen isotope interaction with lithium CPS under conditions modeling the operation modes of the tokamak KTM to regulate pre-start modes of working gases’ input.
• The experimental results of hydrogen isotopes interaction with Li CPS and effects of atmosphere gases in-leak are presented.
Samples and Li filling techniqueSamples and Li filling technique• The samples under study were lithium CPS based on net-matrix
of stainless steel 12Cr18Ni10Ti of 100 µm thickness; cell was about 100 µm. Temperature range was similar to the working temperatures of lithium divertor module and was 200 – 350oC.
• Eight identical squares of 10x10 mm were cut from SS. 30-mm wick,10 fragments of SS wire and 0,1 mm thickness was fastened through a hole to a SS base. The mat of 30-40% porosity was made.
Samples and Li filling techniqueSamples and Li filling technique
• A wick intended for filling the CPS matrix with liquid Li due to capillary forces was connected with a Li feeding tract. Vacuum filling of the sample’s matrix with liquid Li was carried out using experimental device VIKA. The experimental device, which was preliminary annealed, was filled with 3 g Li. CPS model
( at T=400 C) was filled with Li through the wick due to capillary forces.
Experimental Device SchemeExperimental Device SchemeExperimental Device Scheme for
filling CPS with lithium:1– fastenings; 2 – CPS; 3 – thermocouples; 4 – wick; 5 – liquid lithium; 6 – chamber frame; 7 – heat insulation; 8 – heaters; 9 – lithium vessel;10 – watch window;11 – sealed output for
thermocouples
VIKA experimental deviceVIKA experimental deviceVIKA facility includes:
Vacuum tracts and fittings providing for two-step vacuum pumping of the experimental device: fore-vacuum on the basis of the pump 2NVR-5DM and high-vacuum oil-free on the basis of the pump NORD-250;
• A device containing lithium CPS sample;
• Hydrogen/deuterium feeding system on the basis of diffusion palladium-silver filter;
• Measurement system consisting of pressure meters and two mass-spectrometers (quadruple mass-spectrometer RGA-100 and omegatron mass-spectrometer on the basis of RMO-13).
Experimental conditionExperimental condition • The gas absorption technique was used to study hydrogen
isotope interaction with the samples of lithium CPS• The experimental procedure was as follows: gas was fed to
lithium CPS chamber at given temperature, then gas pressure kinetics in a chamber was measured. During the experiments residual gas composition was controlled as well.
Experimental conditions were as follows: Experimental conditions were as follows: • Hydrogen isotopes H2, D2;• Temperature range 200 – 350°С;• Input pressure of hydrogen isotopes 100 – 550 Pa;• Calibration leak from atmosphere 1.2·10-10 mole/s.
• First stage of the experiments was aimed to assess effects of atmosphere gases on the parameters of hydrogen interaction with lithium CPS. As a result of the experiments the time dependencies were obtained for hydrogen pressure over the sample under various vacuum conditions (with and without leakage of atmosphere gases through calibration hole) . Lithium CPS temperature was 200°С. Initial pressure in the experimental device was 100 Pa and pressure during experiment was 100 – 550 Pa.
Experimental resultsExperimental results
Determination of sorption properties of lithium Determination of sorption properties of lithium CPS against atmosphere gases CPS against atmosphere gases
Leakage of atmosphere gases into experimental device through calibration hole
Changes in pressure of atmosphere gases in
experimental device under CPS temperature of 200°С
Normalized graph of deuterium pressure changes in experimental device taking into account leak of
atmosphere gases
Experiments with deuterium Experiments with deuterium
• Second stage – Second stage – Experiments with Experiments with deuterium under leak of deuterium under leak of atmosphere gases atmosphere gases
Experimental conditions:sample’s temperature was
250 and 350°С,
initial pressure of deuterium was 450 – 520 Pa.
Determination of parameters of hydrogen isotope interaction with lithium CPSDetermination of parameters of hydrogen isotope interaction with lithium CPS
k – constant of hydrogen isotope interaction with lithium CPS without leakage
dν – moles of gas interacted with lithium CPS during time dt ,
V- volume of experimental device with lithium CPS;
R – universal gas constant;
T – gas temperature;
P – gas pressure in the experimental device;
P′ – rate of changes in gas pressure in experimental device;
Scps – square of lithium CPS surface.
kI- constant of hydrogen isotope interaction with lithium CPS under leakage of atmosphere gases into the experimental device
dvS – changes of gas concentration in a chamber with lithium CPS during time dt , dvнат – quantity of atmosphere gas leaked in the chamber during time dt;P1(t) - pressure of hydrogen isotope in a chamber during saturation.V – volume of experimental device with lithium CPS;R – universal gas constant;T – gas temperature;P – gas pressure in experimental device;P’ – rate of gas pressure changes ;SCPS – area of lithium CPS surface.
Determination of parameters of hydrogenDetermination of parameters of hydrogen isotope interaction with lithium CPS isotope interaction with lithium CPS
Determination of parameters of hydrogenDetermination of parameters of hydrogen isotope interaction with lithium CPS isotope interaction with lithium CPS
Table . Constants of hydrogen isotope interaction with lithium CPS Table . Constants of hydrogen isotope interaction with lithium CPS
CPS Temperature , °С
kн, Р0=100 Pa,mole/(s×Pa×m2)
kн, Р0=100 Pa with leakage
mole/(s×Pa×m2)
kн, Р0=550 Pa.,with leakage
mole/(s×Pa×m2)
kD, Р0=550 PaWith leakage
mole/(s×Pa×m2)
200 1,68Е-7 1,09Е-7 0,96Е-7 —
250 — — — 6,61Е-8
350 — — — 1,34Е-7
Reference data on H-Li interaction constants (Gardner M. P., Altermatt R. E., 1985)
Lithium temperature, °С 520 485 455 200
kн, mole/(s×Pa×m2) (4,9E-6) (4,4E-6) (3,9E-6) (8,8E-7)
Values of hydrogen/deuterium interaction constants calculated for initial sector of sorption curves are given in the Table Using the temperature dependence curve of constant of deuterium interaction with lithium CPS we defined activation energy of interaction process – 19.23 kJ/mole. Kd=55.10-7 exp (-19,23/RT)
Thermodesorption experiments with Thermodesorption experiments with Lithium CPSLithium CPS
Release of hydrogen isotopes from lithium CPS
Release of all residual gases from lithium CPS
TDS spectra were obtained under linear heating up to 350 0С and heating rate of 13 С/min. These peaks of hydrogen/deuterium concentration were obtained for classical diffusion approximation model. Mass-transfer activation energy obtained for hydrogen and deuterium was in the ranger of 100-130 kJ/mole, pre-exponential factor in Arrhenius dependence can be in a range of 1-100 m2/s.
Thermodesorption experiments with Thermodesorption experiments with Lithium CPSLithium CPS
H and D concentration change at a surface of lithium CPS
Rate of atom H and D concentration change at a lithium surface
The pictures show ,that the temperature dependences of rate concentration changes of H and D atoms in the Li surface are equally in view of the fact that the H and D TDS peaks location are equally too.
SummarySummary• Main parameters of hydrogen isotope interaction with lithium
CPS were obtained as a result of the experiments. • Influence of atmosphere gases leak (permissible leak of
~1.77*10-12 Pa/(m3s)) on interaction rate of hydrogen isotopes with lithium CPS was registered: rate of hydrogen isotope sorption decreased and interaction constant was decreased in 1.5 times at least.
This effect can be explained by interaction of atmosphere gases with liquid lithium and formation of poorly soluble films in lithium.
• The obtained parameters of hydrogen isotope interaction with lithium CPS were used for calculation of a rate of deuterium (hydrogen) supply into KTM chamber during pre-start mode.
Future work
• Influence of neutron irradiation on parameters of hydrogen isotopes interaction with Li CPS
• T and He generation and release in/from Li CPS under neutron irradiation
Goal – Li technology application for fusion power reactor
Welcome to the International Workshop“Innovation Project-creation of KTM
tokamak. Research program and international cooperation”,
5-7 September, 2011,Astana, Kazakhstan