SYLLABUS AND REGULATIONS
UNDER CHOICE BASED CREDIT SYSTEM (CBCS) (Those who joined in 2018-2019 and after)
PG Degree Course
in M.Sc. (Chemistry)
Regulations 2018
SRI S. RAMASAMY NAIDU MEMORIAL COLLEGE SATTUR- 626 203 (An Autonomous Institution Affiliated to Madurai Kamaraj University, Madurai)
(Re-Accredited with Grade ‘A’ by NAAC)
Placed at the meeting of Academic
Council held on 17.04.2018
SRNMC Regulations-2018 Syllabus
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OBJECTIVES To enable the students
1. To gain knowledge on the basic and advanced level aspects in the different disciplines of
chemistry.
2. To get an exposure to the basics in nano chemistry and biochemistry.
3. To gain knowledge on the basic and advanced level experimental techniques.
4. To get an exposure on some current trends in chemistry.
ELIGIBILITY FOR ADMISSION
B.Sc. degree with chemistry as the core subject and physics as one of the allied subjects; the
other allied subject may be any one of the following: Mathematics, Botany and Zoology.
DURATION OF THE COURSE
The duration of the course shall be two academic years comprising four semesters with two
semesters in each academic year.
COURSES OF STUDY
1. Core subjects
2. Major elective subjects
.
CREDITS
The term ‘credit’ refers to the weight age given to the course, usually in relation to the instructional
hours assigned to it. The total credits required for completing Master of Science in Chemistry is 90.
The particulars of the credits for individual components and courses are placed on Table-1.
EXTRA CREDITS PAPER
1. This paper is optional. Students may or may not select this paper. If he/she selects
this paper and if he/she passes the paper, then 3 extra credits will be added in his/her total
credit to the degree, even otherwise, it won’t affect the completion of degree.
2. Though this paper is common to all PG programmes, the syllabus varies according to
the subject selected by the department.
3. The title of this paper is ―Model Paper for NET/ SET Examinations- Chemical sciences
4. Examination for this paper will be held at the end of the 4th
semester examinations.
5. There is no internal examination and only external examination for this paper.
6 . Maximum marks for this paper is 100.
SRNMC Regulations-2018 Syllabus
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SCHEME OF EXAMINATION
It is presented on Table-2
PATTERN OF THE QUESTION PAPER
THEORY
Part A
Ten questions (Multiple choice) 10 x 1 = 10 marks
Two questions from each Unit
Part B
Five questions (either or type) 5 x 7 = 35 marks
One question from each Unit
Part C
Three questions (out of five) 3 x 10 = 30 marks
One question from each unit
---------------
Total 75 Marks
---------------
EVALUATION
The performance of the student is evaluated in terms of percentage of marks with a
provision for conversion to grade points. Evaluation for each course shall be done by a
continuous internal assessment by the concerned course teacher as well as by an end semester
examination which will be written type examination of 3 hours duration and will be
consolidated at the end of the course. The ratio of marks to be allotted to continuous internal
assessment and to end semester examination is 25:75 (i.e. Internal 25 Marks and external 75
Marks)
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The components of continuous internal assessment are
Two tests and their average 15 Marks
Seminar/Group Discussion 5 Marks
Assignment 5 Marks
Total 25 Marks
PASSING MINIMUM
A) Theory
1. 50% of the aggregate (External+ Internal)
2. No separate pass minimum for Internal
3. 34 Marks out of 75 is the pass minimum for the External.
B) Practical
1. 50% of the aggregate (External+ Internal)
2. No separate pass minimum for Internal
3. 27 Marks out of 60 is the pass minimum for the External.
C) Project
1. 50% of the aggregate (Project Evaluation + Viva Voce+ Internal)
2. No separate pass minimum for internal.
3. 27 marks out of 60 is the pass minimum for the External.
SRNMC Regulations-2018 Syllabus
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M.Sc (CHEMISTRY)
Table -1: Course pattern
(For those who joining in 2018-2019 and after)
Extra Credit paper : 3 credits
Grand Total : 93
S.No
Semester
I
II
III
IV
V
Total
Hours
Total
Credits
1
I
Core
5(5)
Core
5(5)
Core
5(4)
Elective
5(4)
Practical
10(4)
30
22
2
II
Core
5(5)
Core
5(4)
Core
5(5)
Elective
5(4)
Practical
10(4)
30
22
3
III
Core
5(5)
Core
5(5)
Core
5(5)
Elective
5(4)
Practical
10(4)
30
23
4
IV
Core
5(5)
Core
5(5)
Core
5(5)
Elective
5(4)
Project
10(4)
30
23
TOTAL
120
90
SRNMC Regulations-2018 Syllabus
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M.Sc (CHEMISTRY)
Table -2: Course details and scheme of examinations
(For those who joining in 2018-2019 and after)
Semester Title of the Paper Subject Code
Hrs
per
week
Credit
Exam
hrs.
Marks Total
Marks Int Ext
I
Organic chemistry- I
Stereochemistry and reaction
mechanism–I
P18CHC11 5 5 3 25 75 100
Inorganic Chemistry -I
Atomic properties,
coordination and solid state
chemistry- I
P18CHC12 5 5 3 25 75 100
Physical Chemistry -I
Thermodynamics and
electrochemistry
P18CHC13 5 4 3 25 75 100
Major elective: (Any one)
1) Environmental chemistry
2) Biochemistry
P18CHE11
P18CHE12
5
4
3
25
75
100
Practical–I Inorganic
chemistry P18CHPC1P1 10 4 6 40 60 100
II
Organic Chemistry –II
Natural products,
conformational analysis and
reaction mechanism– II
P18CHC21 5 5 3 25 75 100
Inorganic Chemistry -II
Bioinorganic and solid state
chemistry -II
P18CHC22 5 4 3 25 75 100
Physical Chemistry -II
Quantum, catalysis and
molecular spectroscopy-I
P18CHC23 5 5 3 25 75 100
Major Elective: (Any one)
1) Analytical chemistry
2) Industrial chemistry
P18CHE21
P18CHE22
5 4 3 25 75 100
Practical – II
Organic chemistry P18CHC2P1 10 4 6 40 60 100
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III
Organic Chemistry -III
Reactions , reagents and
spectroscopy
P18CHC31 5 5 3 25 75 100
Inorganic Chemistry -III
Inorganic spectroscopy and
Nano Chemistry
P18CHC32 5 5 3 25 75 100
Physical Chemistry-III
Group theory and molecular
spectroscopy-II
P18CHC33 5 5 3 25 75 100
Major elective: (Any one)
1) Computer applications
2) Pharmaceutical chemistry
P18CHE31
P18CHE32
5 4
3
25
75
100
Practical- III
Physical chemistry P18CHC3P1 10 4 6 40 60 100
IV
Organic chemistry -IV
Molecular rearrangements and
synthetic methods
P18CHC41 5 5 3 25 75 100
Inorganic Chemistry -IV
Nuclear and organometallic
Chemistry.
P18CHC42 5 5 3 25 75 100
Physical Chemistry IV -
Chemical Kinetics , surface,
biophysical and photo chemistry
P18CHC43 5 5 3 25 75 100
Major Elective: (Any one)
1) Introduction to Nano science
2) Polymer chemistry
P18CHE41
P18CHE42
5 4 3 25 75 100
Project / Review of recent
aspects of Chemistry
Viva Voce
P18CHPT41 10 4 6 40 40
20 100
Extra credit paper
Model paper for NET/SET
examination- Chemical sciences
P18CHX41 3 2 100
SRNMC Regulations-2018 Syllabus
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SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
Programme : M.Sc. Chemistry Subject Code : P18CHC11
Semester : I No. of Hours allotted : 5 / week
Subject : Core Paper I No of Credits : 5
Title of the Paper : ORGANIC CHEMISTRY - I
STEREOCHEMISTRY AND REACTION MECHANISM- I
Objectives :
To enable the learners
to learn the basic concepts of organic chemistry
to know about the basic concept of stereochemistry in detail
to understand the aromatic character of organic compounds.
to learn the fundamentals of reaction mechanism.
UNIT-I ELECTRON DISPLACEMENT AND STRUCTURE-REACTIVITY
CORRELATION
Inductive and field effects – bond distances - bond energies – delocalised bonds -
cross conjugation– rules of resonance effect -steric inhibition of resonance–hyper conjugation
- hydrogen bonding–addition compound–EDA complexes -inclusion compounds. Quantitative
treatment of the effect of structure on reactivity – The Hammett relationship - significance of
reaction and substituent constants - application of the Hammett equation in reaction
mechanism – limitations and deviation.
UNIT- II STEREOCHEMISTRY –I
Symmetry elements - Concept of chirality , necessary and sufficient conditions for
chirality–Relationship between substrate symmetry and chirality-Projection formulae– Wedge,
Fischer, Sawhorse and Newmann - Optical isomerism due to centre of chirality - Molecules
with one stereogenic centre (chiral centre) and molecules with more than one chiral centr –
properties of enantiomers and diastereoisomers–erythro and threo nomenclature – Cahn-
Ingold - Prelog system of designation of configuration .
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Geometrical isomerism: E-Z nomenclature-determination of configuration of geometrical
isomers using physical and chemical methods–stereoisomerism in monocyclic compounds
(upto six membered ring).
UNIT -III STEREOCHEMISTRY II
Prochirality and prosteroisomerism, enantiotopic and diastereotopic ligands and
faces and their nomenclature - pro-R and pro-S and Re and Si faces - Stereospecfic and
stereoselective reactions - Asymmetric synthesis; Cram and Prelog rule - Optical isomerism
due to axial chirality - biphenyl, Allenes and spiranes - Molecules with planar chirality –
paracyclophanes, trans-cyclooctene and ansa compounds.
UNIT –IV AROMATIC CHARACTER
Aromatic character in benzene, six membered rings, five, seven and eight
membered rings – other systems with aromatic sextets–Huckel’s rule–Craigs rule–concept of
homoaromaticity and antiaromaticity-systems with 2,4,8 and 10 electrons – systems with
more than 10electrons– Alternant and nonalternant hydrocarbons-Chemistry of
cyclopentadienyl anion– Fulvene, Azulene, Tropolones, Sydnones and Annulenes .
Novel ring system: Nomenclature of bicyclic and tricyclic systems- chemistry of adamantane,
diamantane (congressane), cubane and catenanes.
UNIT–V INTRODUCTION TO REACTION MECHANISM
Reaction intermediates–free radicals, carbenes, nitrenes, carbanions, carbocations
formation and stability of reaction intermediates–methods of determination of reaction
mechanism-kinetic and thermodynamic control of chemical reaction - Kinetic and non kinetic
methods for determining organic reaction mechanism–principle of microscopic reversibility –
Hammond postulate-Partial rate factors - ortho/para ratio .
Text books
Text book-1
Title of the book : Reaction mechanism and reagents in organic chemistry
Names of the Author : G.R. Chatwal
Publisher : Himalaya publishing house,
Edition/Year : 5/2012
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Text book-2
Title of the book : Stereochemistry of Organic compounds, Principles and
Application,
Name of the Author : D.Nasipuri
Publisher : Wiley eastern Ltd
Edition/Year : 2 /2006
Text book-3
Title of the book : Stereochemistry conformation and Mechanism
Name of the Author : P.S.Kalsi
Publisher : New age international publishers
Edition/Year : 1/1990
Text book-4
Title of the book : Organic chemistry Vol-II
Name of the Author : I.L.Finar
Publisher : ELBS Longmann
Edition/Year : 5 /1975
Text book-5
Title of the book : Organic reaction mechanism
Name of the Author : V.K Ahluwalia
Publisher : Narosa publishing House New Delhi
Edition/Year : 3 /2007
Unit –I (From text book 1)
Chapter –2 (Page No.2.1- 2.46)
Unit –II (From text book –2) Chapter – 2 (Page No.15-20)
Chapter – 3 (PageNo.27-36)
Chapter – 5 (Page No. 43-67)
(From text book –4) Chapter – 4 (Page No.170-200)
Unit –III (From text book –3)
Chapter – 1 (Page No.84-130)
Unit –IV (From text book –1)
Chapter –13 (Page No.13.1-13.37)
Unit –V (From text book –5) Chapter –2 (Page No.78-118)
Reference books
Reference Book-1
Title of the book : Guide book to Mechanism in Organic chemistry
Name of the Author : Peter Sykes
Publisher : Orient longmann Ltd., New Delhi,1998,
Edition/Year : 6 / 1984
Reference Book-2
Title of the book : Organic chemistry,
Name of the Author : R.T.Morrison and R.N. Boyd,
Publisher : Prentice, Hall,
Edition/Year : 6/ 1995,
SRNMC Regulations-2018 Syllabus
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Reference Book-3
Title of the book : Mechanism and Structure of Organic Chemistry,
Name of the Author : E.S. Gould,
Publisher : Holt, Rinehart and Winston Inc, New York,
Edition/Year : 2 /2006
Reference Book-4
Title of the book : Stereo chemistry of carbon compounds,
Name of the Author : E.l.Eliel
Publisher : Mc Graw Hill
Edition/Year : Reprint 2008 Edition / 1975
Reference Book- 5
Title of the book : Advanced Organic Chemistry,
Name of the Author : Jerry March,
Publisher : John Wiley and Sons,
Edition/Year : 4/ 2004.
Prepared by : 1. Ms. V. SOUNDARANAYAKI
2. Ms. K. RAJASULOCHANA
Signature :
SRNMC Regulations-2018 Syllabus
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SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc Chemistry Subject Code : P18CHC12
Semester : I No. of Hours allotted: 5 / week
Subject : Core - Paper II No. of Credits : 5
Title of the Paper : INORGANIC CHEMISTRY – I
ATOMIC PROPERTIES, COORDINATION AND SOLID
STATE CHEMISTRY -I
Objectives :
To enable the learners
to apply molecular orbital theory to the poly atomic molecules
to study the application of redox potential.
to know about bond properties , Ionic bonding and the concepts of solid chemistry
to interrelate the structure of inorganic cages, chains and poly-acids.
UNIT- I ATOMIC PROPERTIES
Bond length- bond order- bond energy, bond polarity – partial ionic character of
covalent bond- covalent character in ionic compounds (Fajan’s rule) - different types of
electrostatic interactions-hydrogenbonding.-Electron affinity-electronegativity- determination
of electronegativity by pauling’s mulliken’s and Allred Rochow methods-factors
determining electronegativity–Lattice energy - Born-Lande equation -Kapustinski’s equation-
Born-Haber cycle.
UNIT- II CHEMICAL BONDING AND REDOX POTENTIAL
Covalent bond: Hybridisation – Calculation of S and P characters – Bent’s rule –
VSEPR theory - M.O.theory- LCAO approximation – application of MOT to heteronuclear
diatomic molecules like NO, CO and triatomic molecule BeH2.
Oxidation and reduction: Concept of oxidation and reduction potentials-periodic
trends- Application of electrode potentials- electrode potential diagrams- Latimer diagram-
Frost diagram –Pourbaix diagram- Ellingham diagram.
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UNIT -III CO-ORDINATION CHEMISTRY-I
Basics of co-ordination compounds-IUPAC nomenclature of co-ordination
compounds–isomerism in co-ordination compounds–types of ligand monodentate,
ambidentate and macrocyclic ligands–chelate and its applications–detection of complex
formation in solution–stepwise stability constant-overall stability constant-factors affecting
stability constant in solution–determination of stability constant by spectrophotometric,
polorographic and potentiometric and Job’s method.
UNIT –IV SOLID STATE CHEMISTRY – I
Elements of crystallography-space lattice - unit cell-crystal system - X ray
diffraction - Bragg’s equation-Bragg’s method-Rotating crystal method and powder method
of x-ray diffraction - evaluation of unit cell parameters- structure of typical lattice
such as cesium chloride, zinc blende, wurzite, rutile, fluorite, antifluorite, perovskite,
covalent crystal as diamond and graphite.
UNIT -V INORGANIC CHAINS, RINGS AND CAGES
Preparation and structure of polyacids: Classification – isopoly acids like
polymolybdate, polyvanadate and polytungstate ,heteropolyacids 6, 9 and 12 heteropolyacids.
Silicates-classification of silicates - Silicones- Phosphazenes and their polymers – S4N4 –
polymeric sulphur nitride (polythiazyl). Cage compounds:–Nomenclature of boranes and
carboranes –Wade’ rules – Styx number – Multicentered bond in diborane- preparation and
structures of, B4H10, and C2B10H12.- Borazine
Text books
Text Book-1
Title of the book : Inorganic Chemistry- principles of structure and reactivity.
Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,
Publisher : Harper Collins College Publishers
Edition/Year : 4 /1993
Text Book- 2 Title of the book : Fundamental concepts of inorganic chemistry
Name of the Author : Asim k Das & mahuda Das
Publisher : CBS Publishers & Distributors pvt Ltd, New Delhi.
Edition/Year : 1/ 2014
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Text Book- 3 Title of the book : Concise Inorganic Chemistry
Name of the Author : J. D Lee
Publisher : Blackwell Science Ltd
Edition/Year : 5/1996
Text Book- 4 Title of the book : Text book of Inorganic Chemistry
Name of the Author : G. S Sodhi
Publisher : Viva books Pvt Ltd
Edition/Year : Reprint2013
Text Book- 5 Title of the book : Inorganic Chemistry.
Name of the Author : P.W.Atkins, Overton,Rourke, weller , Armstrong
Publisher : oxford - - ELBS
Edition/Year : 4/2006, reprint 2011
Unit-I (From Text Book-1) Chapter – 4 (Page No 99 to105,129)
Chapter – 5 (Page No 182 to183,194)
Chapter – 8 (Page No296 to 303)
(From Text Book-3)
Chapter – 6(Page No 153 to 161)
(From Text Book-4)
Chapter – 3(Page No 61 to 69)
Unit II (From Text Book-1&5)
Chapter –6 (Page No201 to 229)
Chapter –5 (Page No 153 to 157,167to177)
(From Text Book-3)
Chapter – 3,4 (Page No 54- 57, 74-97 107 to 110)
(From Text Book-5) Chapter – 5 (Page141 to 159)
Unit III (From Text Book-2) Chapter – 1(Page No 28 to 39,56 to 61,145 to 156)
Chapter – 4(Page No538 to 548 )
Unit IV (From Text Book-5)
Chapter – 6(Page No 169 to 172)
Chapter – 3(Page No 71 to 97)
Unit V (From Text Book-1)
Chapter – 16 (Page No 752 to 775, 779 to 802)
Reference Books
Reference Book-1
Title of the book : Fundamental concepts of Inorganic Chemistry(volume 2)
Name of the Author : Asim K Das & Mahua Das
Publisher : CBS publishers& Distributors Pvt Ltd, New Delhi.
Edition/Year : 1/2014
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Reference Book-2
Title of the book : Advanced Inorganic Chemistry
Name of the Author : F.A Cotton and G. Wilkinson
Publisher : John Wiley & Sons Singapore
Edition/Year : 5 /1988
Reference Book-3
Title of the book : Inorganic Chemistry.
Name of the Author : Alan G Sharpe
Publisher : Pearson education Ltd ,Singapore.
Edition/Year : 3/ reprint 2005
Reference Book-4
Title of the book : Modern Inorganic Chemistry.
Name of the Author : R.D Madan
Publisher : S. Chand &company Ltd.
Edition/Year : 2/ reprinted 2002.
Prepared by : 1. Ms. K. BUVANESWARI
2. Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
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SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc .Chemistry Subject Code : P18CHC13
Semester : I No. of Hours allotted : 5 / week
Subject : Core - Paper III No. of Credits : 4
Title of the Paper : PHYSICAL CHEMISTRY – I
THERMODYNAMICS AND ELECTROCHEMISTRY
Objectives :
To enable the students
to understand the importance and significance of thermodynamics and the principle
of chemical equilibrium.
to acquire an insight into phase rule.
to understand the principles of quantum chemistry.
to know about the importance and significance of electrochemistry and its
applications.
UNIT-I CHEMICAL THERMODYNAMICS
Second law of thermodynamics, concept of entropy. Gibbs-Helmholtz equation,
Maxwell relations and thermodynamic equation of state. Partial molar quantities - Chemical
potential, its variation with temperature and pressure, Gibbs Duhem equation. Experimental
determinations of fugacity of real gases (Graphical, from state equation, approximate and
generalized methods).Third law of thermodynamics – Nernst theorem, absolute entropies,
determinations of absolute entropies, exception to third law and unattainability of absolute
zero.
UNIT-II CHEMICAL AND PHASE EQUILIBRIA
Spontaneous reactions, free energy of a spontaneous reaction, role of temperature,
standard free energy change of a reaction. Thermodynamic derivation for the law of chemical
equilibrium, Van’t Hoff’s reaction isotherm. Temperature dependence of equilibrium
constant, Integrated form of the Van’t Hoff equation. Relation between Kp and Kc. De
Donder’s concept of degree of advancement of a reaction.
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Gibbs phase rule - its thermodynamic derivation. Application of phase rule to
three component systems - systems composed of two solids and a liquid ( crystallization of
pure components only, hydrate and double salt formation ). Formation of one pair, two pairs
and three pairs of partially miscible liquids.
UNIT–III BASIC PRINCIPLES OF QUANTUM MECHANICS
Planck’s explanation about black- body radiation, de-Broglie’s concept of matter
waves ( Experimental technique and verification), Compton effect, Heisenberg’s uncertainty
principle, Postulates of quantum mechanics, Operators (addition, subtraction, multiplication,
commutator, Hermitian, Hamiltonian and linear operators), Rules for setting up the following
quantum mechanical operators - position, momentum, kinetic energy, potential energy, total
energy, angular momentum, raising and lowering of spin angular momentum. Orthogonality
and normalization of wave functions. Problems on evaluation of commutators and find
expressions of some operators. Simple problems based on to find out the eigen values and
eigen functions.
UNIT-IV ELECTROCHEMISTRY - I
Theory of electrolytic conductance – inter ionic attraction, ionic atmosphere,
thickness of ionic atmosphere. Debye Huckel - Onsager conductance equation – its derivation
and experimental verification, deviations and modifications-Debye Falkenhagen and Wein
effects. Mean ionic activity and activity coefficients of strong electrolytes. Liquid junction
potential and membrane potential. Construction and working of metal-metal ion electrode,
hydrogen electrode, calomel electrode and oxidation-reduction electrode. Types of cells -
Electrochemical cells –primary cells, secondary cells and fuel cells. Experimental
determination of EMF of cells. Nernst equation. Applications of EMF measurements-
determination of equilibrium constant, pH and solubility product.
UNIT-V ELECTROCHEMISTRY - II
The electrical double layer and zeta potential. Perrin, Gouy-Chapmen and Stern
models. Butler-Volmer equation - Tafel equation. Over voltage, Hydrogen over voltage.
current-potential curves , Potentiometric titrations – principles and types (acid- base, redox
and precipitation).Conductometric titrations – principles and types ( acid – base and
precipitation )
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Text books
Text book-1
Title of the book : Principles of Physical chemistry
Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania
Publication : Vishal publishing Co,New Delhi.
Edition/ year : 45 /2012
Text Book- 2
Title of the book : Advanced Physical chemistry
Name of the Author : Gurdeep Raj
Publisher : Goel Publishing Co.Meerut.
Edition/Year : 30 /2004
Text Book- 3
Title of the book : Quantum chemistry
Name of the Author : R.K Prasad
Publisher : New Age International publishers
Edition/Year : 3 /2008
Text Book- 4
Title of the book : An Introduction to Electrochemistry
Name of the Author : S.Glasstone
Publisher : East West Press (P) Ltd.
Edition/Year : 10 /1942
Unit-I (From Text Book-1) Chapter – 14 (Page No.517-541,546-549)
Unit-II (From Text Book-1) Chapter – 16 (Page No.564-573,581-582)
(From Text Book-2)
Chapter – 18 (Page No.1050-1052, 1054-1056, 1079-1083, 1085-1088)
Unit- III (From Text Book-1) Chapter -1(Page No.23-25, 32-39, 43, 44)
(From Text Book-3)
Chapter -2(Page No.32, 33)
Chapter -3(Page No. 34-55)
Unit-IV (From Text Book-1)
Chapter – 22 (Page No.770-829,845-850,867-887)
(From Text Book-4)
Chapter – 3 (Page No.79-105)
Unit-V (From Text Book-1)
Chapter – 24 (Page No.845-851,867-873)
Reference Books
Reference Book-1
Title of the book : Thermodynamics for chemists
Name of the Author : S.Glasstone
Publisher : East West Press (P) Ltd,New Delhi.
Edition/Year : 3 /1947
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Reference Book-2
Title of the book : Thermodynamics
Name of the Author : J.Rajaram and J.C. Kuriakose
Publisher : Shoban Lal Nagin, Chand & Co, New Delhi.
Edition/Year : 3 /1999
Reference Book-3
Title of the book : Advanced Physical chemistry
Name of the Author : D.N. Bajpai
Publisher : S.Chand &Company Ltd, New Delhi.
Edition/Year : 1 /1992
Reference Book-4
Title of the book : Electrochemistry
Name of the Author : B.K. Sharma
Publisher : Goel Publishing House,Meerut.
Edition/Year : 5 /1998
Prepared by : 1. Ms. M. SELVAMARIAMMAL
2. Ms. K. BUVANESWARI
Signature :
SRNMC Regulations-2018 Syllabus
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SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR- 626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc., Chemistry Subject Code : P18CHE11
Semester : I No. of Hours allotted : 5 / week
Subject : Paper IV Major Elective I- (a) No. of Credits : 4
Title of the Paper : ENVIRONMENTAL CHEMISTRY
Objectives:
To enable the students
to learn about pollutions and its types.
to know the sources and control measures of various pollution.
UNIT- I INTRODUCTION AND CLASSIFICATION OF POLLUTION
Introduction, definitions – environment, environmental science, environmental
education. Types of environment and its components. Definitions- ecology, ecosystem. Types
and components of ecosystem. Cycling of minerals, elements and gases –Phosphate cycle-
Carbon cycle- Nitrogen Cycle- Hydrological cycle. Sources, effects and control measures of
various pollution - air pollution-water pollution- soil pollution- radioactive pollution- thermal
pollution- noise pollution- marine pollution.
UNIT-II ANALYSIS OF POLLUTANT
Neutron activation analysis-Anodic stripping voltametry-Atomic absorption
spectrophotometry - X-RayFlorescence - non-dispersive infrared spectrometry -Fourier
transform infrared spectroscopy- chemiluminescence-gas chromatography-High performance
liquid chromatography-Ion selective electrode.
UNIT-III AIR POLLUTION
Introduction – sources of air pollution – air pollutants – classification and effects of air
pollutants – oxides of nitrogen, sulphur and carbon- acid rain-effects and control-hydrogen
sulphide – effects and control- carbon mono oxide – effects and control- photochemical smog
– effects and control – fly ash – effects and control – green house effect – global warming –
effects and control – ozone layer – ozone depletion – choloro fluoro carbons – effects and
control.
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UNIT- IV SOIL POLLUTION
Introduction- types of soil on the basis of its texture- sources of soil pollution-
fertilizers and pesticides- radioactive pollutants- soil sediments as pollutant. Soil erosion –
types- harmful effects-causes and its control measures. Solid waste management-types,
sources and effect of improper solid wastes. Process of solid waste management- disposal
methods- sanitary land filling - incineration and composting methods. Control measures of
soil pollution.
UNIT- V INDUSTRIAL POLLUTION & CHEMICAL TOXICOLOGY
Introduction-causes of industrial pollution–thermal power plants-nuclear power
reactors-fertilizers and chemical industry-pulp and paper industries – agro based industries-
cement industry. Toxic chemicals in the environment –biochemical effects of arsenic,
cadmium, lead, mercury and cyanide- bio-ware agents.
Text books
Text Book- 1
Title of the book : Environmental Chemistry,
Name of the Author : A.K De,
Publisher : New Age International Publishers, Delhi
Edition/Year : 7 /2010 (Reprint)
Text Book- 2
Title of the book : Environmental chemistry
Name of the Author : B.K.Sharma
Publisher : Goel Publishing House
Edition/Year : 11 /2007
Unit I (From Text Book-1)
Chapter 1 (Page No 1 to 12)
Chapter 6 (Page No 85, 86)
Unit II (From Text book -1)
Chapter 14(Page No 295 to 313)
Unit III (From Text book -2)
Chapter 2 (Page No 47 to 68)
Chapter 4 &5 (Page No 157 to163, 181)
Chapter 9 (Page No 374 to 385)
Chapter 10 (Page No 398 to 401)
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Unit IV (From Text Book-2)
Chapter -1(Page No. 33 to 34)
Chapter -2(Page No 47-55, 62-64)
Chapter-3(Page No 75-80)
Unit V (From Text book -1)
Chapter 7 (Page No 230 to 325)
Chapter 9 (Page No 110 to 129)
Reference Books
Reference Book-1
Title of the book : Environmental Chemistry,
Name of the Author : B.K Sharma and H.Kaur,
Publisher : Krishna Prakashan, Meerut
Edition/Year : 11/2010
Prepared by : Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
22
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHE12
Semester : I No. of Hours allotted: 5 / week
Subject : Paper V- Major Elective – I (b) No. of Credits : 4
Title of the Paper: BIO CHEMISTRY
Objectives:
To enable the students
to understand the biological role of enzymes in living organisms
to get a knowledge about the metabolism and genetic information.
UNIT-I ENZYMES
Classifications, nomenclature, properties of enzymes, some features of active sites of
enzymes, enzyme kinetics-Michaelis-Menton model-significance of Km and Vmax Values,
Enzyme inhibition-competitive and non-competitive. Allosteric interaction-Mechanism of
enzyme action .Lysozyme and carboxypeptidase.
UNIT-II GENERATION AND STORAGE OF METABOLIC ENERGY
Metabolism-basic concepts and design: glycolysis-citric acid cycle-oxidative
phosphorylation-pentose pathway and gluoneogenesis. Glycogen and disaccharide
metabolism, fatty acid metabolism –amino acid degradation and urea cycle-photosynthesis.
UNIT-III INFORMATION, STORAGE, TRANSMISSION OF GENETIC
INFORMATION
DNA-Genetic role structure and replication: messenger RNA and transcription
genetic code and gene protein relationship-protein synthesis, control of gene expression -
Eukaryotic chromosomes, Recombinant DNA technology and viruses.
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UNIT-IV BIO-INORGANIC CHEMISTRY
Metalloproteins and enzymes- Blue copper proteins-copper proteins as
oxidases/reductases-Nickel containing enzymes-structure of DNA-types of nucleic acid
interactions-coordination, intercalation and hydrogen bonding-interactions of metal ions with
nucleic acid-redox chemistry. Hydrolytic chemistry- monitoring the DNA binding by UV, IR,
NMR and CV spectral techniques.
UNIT-V BIOPHYSICAL ASPECTS
Electron transport and oxidative phosphorylation - Thermodynamic and kinetic
aspects-Photosynthesis-An overview- Photo system II-The light harvesting chlorophyll -
protein complexes of photo system II-Role of carotenoids in photosynthesis-The primary
electron donor of photo system II, P680 - The stable primary electron acceptor QA and the
secondary electron acceptor QB–The transient intermediate electron acceptor of photo
system II, pheophytin-Oxygen evolution-The role of manganese-The electron donor to P680+
- Charge recombination in photo system II-Photo system I-Light-harvesting chlorophyll -
protein complexes of photo system I - The primary electron donor of photo system I ,P700-
The primary electron acceptor Ao of photo system I- The intermediate electron acceptor A1
of photo system I-Mobile electron carriers plastocynanin and ferredoxin NADP+ - reductase.
Text books
Text Book- 1
Title of the book : Fundamentals of Biochemistry
Name of the Author : J.L Jain
Publisher : S.Chand & company Limited
Edition/Year : 5/2001
Text Book- 2
Title of the book : Bioinorganic Chemistry
Name of the Author : I.Bertini, H.B.Gray S.J.Leppard and J.S Valentine
Publisher : Viva Books Pvt Ltd..
Edition/Year : 1 /2007
Text Book- 3
Title of the book : Biochemistry
Name of the Author : A.L.Lehninger,
Publisher : CBS publishers
Edition/Year : 1/1990
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Text Book -4 Title of the book : An Introduction to Inorganic Chemistry
Name of the Author : K.F. Purcell and J.C. Koltz,
Publisher : W.B. Saunders Company, Philadelpha 1980
Edition/Year : 1/19
Unit-I (From Text Book-1)
Chapter 16 (Page No. 277-286,309-331)
Unit-II (From Text Book-1)
Chapter 21(Page No 367-412,420-422)
Unit-III (From Text Book-3 )
Chapter 4 (Page No 791-913)
Unit IV (From Text Book -2)
Chapter 6 (page No 315-346)
Unit-V (From Text Book -4) Study materials will be provided
Reference Books
Reference Book-1
Title of the book : Biochemistry
Name of the Author : B.D.Hames and N.M.Hooper
Publisher : Viva Books Ltd
Edition/Year : 1/2003
Reference Book-2
Title of the book : Biochemistry,
Name of the Author : J.M. Berg, J.L.Tymoczko and L.Stryer,
Publisher : W.H.Freeman and company, New York
Edition/Year : 5/2002
Reference Book-3
Title of the book : Bio-inorganic Chemistry.
Name of the Author : Asim.K.Das
Publisher : Books&Allied Pvt Ltd, Kolkata
Edition/Year : 1/Reprinted 2013
Prepared by : Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
25
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHC1P1
Semester : I No. of Hours allotted: 10 / week
Subject : Paper V Practical - I No. of Credits : 4
Title of the Paper : INORGANIC CHEMISTRY PRACTICAL
Objectives:
To enable the learners
to understand the principle for the estimation of binary mixture.
to apply the principle in the semi-micro analysis of an inorganic salt mixture.
to prepare the inorganic complexes
1. SEMI-MICRO QUALITATIVE ANALYSIS: Analysis of mixtures containing one
familiar and one less familiar cations from the following W, Pb, Se, Mo, Cu, Cd,
Bi,V,Ce, Th,Zr Mn, Ni, Co, Zn, Ca, Ba, Sr, Li, Mg (insoluble and interfering an ion
may be avoided).
2. INORGANIC PREPARATIONS: preparation of at least 5 inorganic complexes.
3. QUANTITATIVE ANALYSIS: separation and estimation of mixtures by volumetric
and gravimetric methods, some recommended mixtures are
i) Cu and Ni
ii) Fe and Ni
iii) Ca and Ba
iv) Cu and Zn
v) Fe and Cu
4. ESTIMATIONS: Estimation of Cu & Mg by EDTA Method (class work only)
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References
Reference Book-1
Title of the book : Vogel’s Text Book of Quantitative Chemical Analysis
Name of the Author : J. Bassett et al
Publisher : ELBS, Longmann, U.K
Edition/Year : 5/ 1997
Reference Book-2
Title of the book : Inorganic Semi micro Qualitative Analysis
Name of the Author : V.V. Ramanujam
Publisher : The National Publishing Co, Chennai
Edition/Year : 3/2008
Prepared by : Ms. K. BUVANESWARI
Signature :
SRNMC Regulations-2018 Syllabus
27
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
Programme : M.Sc ., Chemistry Subject Code : P18CHC21
Semester : II No. of Hours allotted : 5 / week
Subject : Core Paper VI No of Credits : 5
Title of the Paper : ORGANIC CHEMISTRY – II
NATURAL PRODUCTS, CONFORMATIONAL ANALYSIS
AND REACTION MECHANISM – II
Objectives:
To enable the learners
to know the concept of aliphatic nucleophilic and electrophilic substitution and
elimination.
to learn the concept of addition to multiple bonds.
to understand the principle of UV, IR and Mass spectroscopy and their application in
organic chemistry.
to know about the chemistry of carbohydrates and terpenoids.
to understand the concept of conformational analysis.
UNIT- I ALIPHATIC NUCLEOPHILIC SUBSTITUTION
Nucleophilicity and basicity – SN1and SN2 mechanisms – Effect of substrate structure
- Effect of the attacking nucleophile–Effect of the leaving group –Effect of the reaction
medium – ambident nucleophiles – ambident substrates– neighbouring group participation by
n, π and σ bonds–SNi mechanism- nucleophilic substitution at an allylic and a vinylic carbon.
Aliphatic electrophilic substitution: Electrophilic substitution at saturated carbon – SE1,SE2
and SEi mechanism.
Elimination: Elimination - E1, E2 and E1CB mechanism – stereochemistry of
Elimination – orientation of the double bond– Effect of changes in the substrates base,
leaving group and medium on E1, E2, and E1CB reactions – elimination Vs substitution –
pyrolytic cis eliminations – Bredts rule .
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UNIT- II ADDITION TO MULTIPLE BONDS
Electrophilic, nucleophilic and free radical additions - addition to conjugated systems
– orientation of the addendum - stereochemical factors in reactions like addition of hydrogen,
halogens, hydrogen halides and hypohalous acids, hydroboration and hydroxylation -
epoxidation. Addition to carbonyl groups – mechanism - Aldol condensation – Perkin
reaction - Knoevenagel reaction - Mannich reaction - Cannizaro reaction – Benzoin
condensation - Claisen ester condensation –Darzen’s reaction - Reformatsky reaction - Wittig
reaction – Grignard reactions.
Addition to α,β -Unsaturated carbonyl groups : Addition of Grignard reagents to α,β-
unsaturated carbonyl compounds – Michael addition – Diels-Alder reaction .
UNIT- III SPECTROSCOPY I
UV Spectroscopy: Principle-absorption spectra of conjugated dienes–α,β -
unsaturated carbonyl compounds–Woodward-Fieser rules-Scott’s rules for aromatic
carbonyls.
IR Spectroscopy : Principle- Molecular vibrations – vibrational frequency - factors
influencing group frequencies – quantitative studies.
Mass Spectrometry: Principle – type of ions – base peak – parent ion, meta stable and
isotopic peaks – nitrogen rule – fragmentation - general rules - pattern of fragmentation for
compounds such as hydrocarbons, amines, alcohols, ketones, acids, phenols and nitro
compounds – McLafferty rearrangement – Retro Diels-Alder reaction.
UNIT- IV CARBOHYDRATES , AMINOACIDS, PROTEINS AND TERPENOIDS
Carbohydrates: Methods used for determination of ring size – structure elucidation
of maltose, lactose and cellobiose - a brief study of starch and cellulose (structure only).
Terpenoids: Classification of terpenoids – structural elucidation of Camphor,
α-pinene, zingiberene , lanosterol and squalene.
Aminoacids and Proteins: General structure of amino acids - peptides –representation
of peptide bond-determination of the amino acid sequence of a polypeptide chain-
Classification of proteins – structure of (primary, secondary, tertiary and quaternary) peptides
- structural elucidation of glutathione and oxytocin
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UNIT -V CONFORMATIONAL ANALYSIS
Configuration and Conformation – Conformation of ethane, 1,2-dicholoroethane and
n-butane-conformational analysis–stereoelectronic and steric factors - conformation of simple
acyclic compounds-conformation of monosubtituted and disubstituted cyclohexanes –
conformation of acyclic and cyclic systems with their physical and chemical properties –
conformational free energy – Curtin- Hammett principle - Quantitative treatment of Mobile
system - Eliel-Ro equation – conformations and reactivity of cyclohexanones.
Text books
Text book-1
Title of the book : Reaction mechanism and reagents in organic chemistry
Name of the Author : G.R. Chatwal
Publisher : Himalaya publishing house,
Edition/Year : 5/2012
Text book-2
Title of the book : Organic reaction mechanism
Name of the Author : V.K Ahluwalia
Publisher : Narosa publishing House New Delhi
Edition/Year : 3 /2007
Text Book- 3
Title of the book : Reactions, Rearrangements and Reagents
Name of the Author : Somorendra Nath Sanyal
Publisher : Bharati Bhawan Publishers
Edition/Year : 4 / 2003
Text Book- 4
Title of the book : Elementary organic spectroscopy principles and chemical
applications
Name of the Author : Y.R.Sharma
Publisher : S.Chand and company Ltd, New Delhi
Edition/Year : Reprint /2012
Text book-5
Title of the book : Stereochemistry conformation and Mechanism
Name of the Author : P.S.Kalsi
Publisher : New age international publishers
Edition/Year : 1/1990
Text book-6
Title of the book : Organic chemistry of natural products
Name of the Author : G.R. Chatwal
Publisher : Himalaya publishing house,
Edition/Year 4/2007
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Unit-I (From Text Book-2) Chapter-1(page No 12-33, 50-59)
Unit-II (From Text Book-1)
Chapter -7 (Page No 7.1-7.61)
(From Text Book-3) Chapter-2(PageNo77-83,97-107,117-121,141-146,148-152,154-158,161-164,182-185)
Unit-III (From Text Book-4) Chapter-2 (Page No.9-12, 15-33, 34-42, 44-54)
Chapter-3 (Page No.69-82, 89-140)
Chapter-7 (Page No.280-328)
Unit-IV (From Text Book-6)
Chapter-1 (Page No.1.46-53, 1.115-123, 1.132-144)
Chapter-2 (Page No.2.62-93, 2.98-101)
Unit-V (From Text Book-5)
Chapter-4 (Page No.217-252)
Reference Books
Reference Book-1
Title of the book : Stereochemistry of Organic Compounds, Principles and
Applications Name of the Author : D.Nasipuri,
Publisher : New Age International (P) Ltd.,
Edition/Year : 2 / 1994.
Reference Book-2
Title of the book : Mechanism and Structure in Organic Chemistry,
Name of the Author : E.S. Gould,
Publisher : Henry Holt& Co.,New York ,
Edition/Year : 1 / 1959
Reference Book-3
Title of the book : Organic Spectroscopy,
Name of the Author : William Kemp,
Publisher : ELBS,
Edition/Year : 3 / 1991
Reference Book-4
Title of the book : Spectrometric Identification of Organic Compounds,
Name of the Author : Robert M.Silverstein, Francis X. Webster,
Publisher : John Wiley and Sons Inc.,
Edition/Year : 6 / 2010.
Reference Book-5
Title of the book : Spectroscopy of Organic Compounds,
Name of the Author : P.S.Kalsi,
Publisher : New Age International Publishers,
Edition/Year : 6 / 2009.
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Reference Book-6
Title of the book : Advanced Organic Chemistry,
Name of the Author : Jerry March,
Publisher : John Wiley and Sons,
Edition/Year : 4 / 2004.
Reference Book-7
Title of the book : Stereo chemistry of carbon compounds,
Name of the Author : E.l.Eliel
Publisher : Mc Graw Hill
Edition/Year : Reprint 2008
Prepared by : 1. Ms. V. SOUNDARANAYAKI
2. Ms. K. RAJASULOCHANA
Signature :
SRNMC Regulations-2018 Syllabus
32
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc., Chemistry Subject Code : P18CHC22
Semester : II No. of Hours allotted: 5 / week
Subject : Core Paper VII No. of Credits : 4
Title of the Paper : INORGANIC CHEMISTRY – II
BIOINORGANIC AND SOILD STATE CHEMISTRY- II
Objectives:
To enable the learners
To have an insight into study of coordination compounds and their reactions
To have an understanding of role of inorganic metal complexes in living systems
UNIT -I CO-ORDINATION CHEMISTRY-II
Theories of bonding: VB theory and CFT theory – splitting of d-orbitals in Oh, Td,
square planar and tetragonal distortion –Jahn-Teller distortions – CFSE calculation in terms
of Dq – factors affecting crystal field splitting energy– spectrochemical series – applications
of CFSE – MOT diagram of octahedral, Td and square planar complexes – effect of π-donor
and π-acceptor ligands – magnetic properties of transition metal complexes – calculation of
spin-only magnetic moments –orbital contribution to the magnetic moment – spin orbit
coupling.
UNIT -II BIO – INORGANIC CHEMISTRY–I
Porphyrin ring system – metalloporphyrins – hemogolobin and myoglobin
structures and work functions – synthetic oxygen carriers – cytochromes and its types –
structure and work functions in respiration – chlorophyll – structure – photosynthetic
sequence – iron sulphur proteins [ non – heme iron protein] – copper containing proteins –
classification – blue copper proteins – structure of blue copper electron transferases, copper
proteins as Oxidases .
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UNIT -III BIO – INORGANIC CHEMISTRY – II
Structure and function of enzyme: carboxypeptidase A–carbonic anhydrase –
inhibition and poisoning – corin ring system – vitamin B12 and B12 Coenzymes – in – vivo
and in – vitro nitrogen fixation – essential and trace elements in biological systems- metal ion
toxicity(Cu, Cd Fe, Pb, Hg, Cr) and its detoxification -sodium and potassium ions pumps –
chelate therapy – cis platin
UNIT -IV ACID – BASE SYSTEMS AND NON AQUEOUS SOLVENTS
Acid –base definition: Bronsted–Lowry, Lux–flood, Solvent system , Lewis concept
Usanovich concept , generalized acid – base concept – steric effect on the strength of acids
and bases – HSAB concept – Symbiosis.
Non Aqueous Solvents: Classification of solvents- A general study of typical reactions in
non aqueous media like liquid NH3, H2SO4 , liquid N2O4 , liquid SO2 and molten salts as non
aqueous solvents.
UNIT- V SOLID STATE CHEMISTRY II
Dislocation in solids- point defects-stoichiometric-schottky defect and frenkel defect
and non stoichiometric defects-metal excess defect and metal deficiency defect-color centers
–free electron theory (Drude Lorentz model) merits and demerits – Band theory - types of
solids – super conductivity – high temperature super conductors – types of semiconductors –
Hall effect - photo voltaic effect – Semi conductors in solar energy conversion-solar cell.
Text books
Text Book- 1
Title of the book : Inorganic Chemistry-principles of structure and reactivity
Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,
Publisher : Harper Collins College Publishers
Edition/Year : 4/1993
Text Book-2
Title of the book : Inorganic Chemistry.
Name of the Author : P.W.Atkins, Overton,Rourke, weller , Armstrong
Publisher : oxford university press
Edition/Year : 4/2006, reprinted 2011
Unit-I - V (From Text Book-1) Chapter 11( page No 391to 393, 394-424,459-464)
Chapter 19(Page No 891 to 936,941-947,956-958)
Chapter 9 (Page No 318 to 330,341to 355)
Chapter 10 (Page No 360 to 366,375-376)
Chapter 7 (Page No 263- 275, 285-288)
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Unit-I - V (From Text Book-2)
Chapter 3 (Page No102-106)
Chapter 26 (Page No719-720,727-730,761-762)
Reference Books
Reference Book-1
Title of the book : An Introduction to Inorganic Chemistry
Name of the Author : K.F. Purcell and J.C. Koltz,
Publisher : W.B. Saunders Company, Philadelpha 1980
Edition/Year : 1 /1980
Reference Book-2
Title of the book : Bio-inorganic Chemistry.
Name of the Author : Asim.K.Das
Publisher : Books&Allied Pvt Ltd, Kolkata
Edition/Year : 1/Reprinted 2013
Reference Book-3
Title of the book : Inorganic Chemistry.
Name of the Author : Alan G Sharpe
Publisher : Pearson education Ltd ,Singapore.
Edition/Year : 3/ reprint 2005
Reference Book-3
Title of the book : Introduction to solids
Name of the Author : L.V.Azaroff
Publisher : Tata Mc Graw Hill Publishing House
Edition/Year : 1/2007
Reference Book-4
Title of the book : Coordination Chemistry- An approach
Name of the Author : S.F.A Kettle
Publisher : SpectrumAcademic publishers,
Edition/Year : 1/1996
Prepared by : 1. Ms. V. SOUNDARANAYAKI
2. Ms. K. BUVANESWARI
Signature :
SRNMC Regulations-2018 Syllabus
35
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc. Chemistry Subject Code : P18CHC23
Semester : II No. of Hours allotted : 5 / week
Subject : Core Paper VIII No. of Credits : 5
Title of the Paper : PHYSICAL CHEMISTRY - II
QUANTUM, CATALYSIS AND MOLECULAR SPECTROSCOPY-I
Objectives:
To enable the learners
to apply the principles of quantum chemistry to simple systems, atomic and molecular
systems and to obtain their energies.
to understand the theory and applications of catalysis.
to get an insight into the principles of molecular spectroscopy.
UNIT- I APPLICATION OF QUANTUM MECHANICS TO SIMPLE SYSTEMS
Derivation of Schrodinger wave equation (SWE). Application of SWE to simple
systems - particle moving in one dimensional box, particle moving in a 3-D box- degeneracy
– distortion, particle moving in a ring, rigid rotator, simple harmonic oscillator. Radial
wave function and radial probability distribution function. Shapes of various atomic orbitals.
UNIT- II APPROXIMATION METHODS IN QUANTUM MECHANICS
Need for approximation methods (variation and Perturbation methods). Perturbation
corrections-first order correction. Schrodinger equation for He atom. Variation theorem-
application to hydrogen and He atoms. Hartee - Fock Self Consistent Field (HFSCF) theory-
application to He atom, HFSCF method of many electron system. Electron spin and Pauli
principle, anti symmetric nature of the wave functions, Slater rules and Born-Oppenheimer
approximation.
UNIT- III STATISTICAL THERMODYNAMICS-I
Aims of statistical thermodynamics, definitions of state of a system, ensembles and
their types, micro and macro states, thermodynamic probability. Derivation of Boltzmann
distribution law. Quantum statistics – derivation of Fermi-Dirac and Bose-Einstein statistics.
Comparison of Maxwell-Boltzmann, Bose-Einstein and Fermi-Dirac statistics, bosons and
fermions. Problems on distribution laws-photon gas and electron gas. Boltzmann-Planck
equation
SRNMC Regulations-2018 Syllabus
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UNIT- IV CATALYSIS
Catalysis - Types, characteristics and theory of catalysis. Heterogeneous catalysis-
kinetics, retardation and effect of temperature. Mechanism of Heterogeneous catalysis-
Langmuir – Heinshelwood and Langmuir – Rideal- mechanism- Classification of catalysis.
Enzyme catalysis – -characteristics- factors governing the rate of enzyme reaction-
Mechanism and its kinetics (Michaelis Menten equation), Line weaver - Burk plot and
Eadie’s plot. Acid–Base catalysis –Mechanism and its kinetics. Hammett and Bronsted
equation, Acidity function. .
UNIT-V MOLECULAR SPECTROSCOPY-I
Electromagnetic spectrum. Types of molecular energies. Absorption and emission of
radiation. Einstein’s coefficient-induced emission and absorption. Rotational spectra of rigid
diatomic molecules-isotope effect in rotational spectra. Microwave spectrometer.
Informations derived from rotational spectra.
Infrared spectroscopy: Vibrational energy of diatomic molecule-infrared selection
rules-diatomic vibrating rotator. Vibrations of polyatomic molecules - overtone, combination
and difference bands. Concept of group frequencies - coupling interaction. Fermi resonance-
FT-IR.
Text books
Text Book- 1
Title of the book : Introductory Quantum chemistry
Name of the Author : A.K.Chandra
Publisher : Tata McGraw –Hill Publishing Company Limited,New Delhi.
Edition/Year : 4 /2002
Text book-2
Title of the book : Principles of Physical chemistry
Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania
Publication : Vishal publishing Co,New Delhi.
Edition/ year : 45 /2012
Text Book- 3
Title of the book : Advanced Physical chemistry
Name of the Author : Gurdeep Raj
Publisher : Goel Publishing Co,Meerut.
Edition/Year : 30 /2004
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Text Book- 4
Title of the book : Fundamentals of molecular spectroscopy
Name of the Author : Colin N. Banwell and Elaine M.McCash
Publisher : Tata McGraw- Hill Publishing Company Limited
Edition/Year : 4/2003
Unit- I & II (From Text Book-1)
Chapter -3(Page No.39-55)
Chapter -4(Page No.82-101)
Chapter -5(Page No.109-120)
Chapter -6(Page No.142-148)
Chapter -7(Page No.183-209)
Unit-III (From Text Book-3) Chapter – 3 (Page No.254-262,281-293)
Unit -IV (From text book 3)
Chapter-15(Page No.841-872)
Unit- V (From Text book-2 & 4) Chapter-2&3(Page No. 31-98)
Chapter-4(Page No. 100-126)
Reference Books
Reference Book-1
Title of the book : Quantum chemistry
Name of the Author : R.K.Prasad
Publisher : New Age International Publishers, New Delhi
Edition/Year : 3 /2006
Reference Book-2
Title of the book : Molecular structure and spectroscopy
Name of the Author : G.Aruldhas
Publisher : PHI Learning (P) Limited, New Delhi
Edition/Year : 2 /2009
Reference Book-3
Title of the book : Physical chemistry of surfaces
Name of the Author : A.W.Adamson,
Publisher : John Wiley&sons,New York
Edition/Year : 5 /1990
Prepared by : 1. Ms. M. SELVAMARIAMMAL
2. Ms. K. BUVANESWARI
Signature :
SRNMC Regulations-2018 Syllabus
38
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHE21
Semester : II No. of Hours allotted: 5/ week
Subject : Paper IX Major Elective –II (a) No. of Credits : 4
Title of the Paper : ANALYTICAL CHEMISTRY
Objectives:
To enable the students
to learn the principle of electro analytical methods & spectro analytical methods.
to gain knowledge on the basic concepts of error analysis
UNIT-I PRECIPITATION TECHNIQUES
Introduction-properties of precipitates and precipitating reagents –colloidal
precipitates, Coprecipitation-post precipitation –precipitates from homogeneous solution –
surface adsorption –drying and ignition of precipitates –application of gravimetric methods
UNIT-II ERROR ANALYSIS
Error analysis: Classification of errors-accuracy and precision-minimization of errors-
significant figures-significant figures in computation-statistical treatment of data: mean,
median, standard deviations, variance, relative standard deviation –spread, errors-standard
deviation of computed results-Student’s t-test, F-test-comparison of the means of two
samples-Q test- correlation and regression: linear regression (least square analysis).
UNIT-III ELECTRO ANALYTICAL METHODS
Electro analytical techniques: Electrogravimetry, theory of eletrogravimetric analysis-
electrolytic separation and determination of metal ions.Coulometry: Electrolytic cell-working
electrodes-auxiliary electrode and reference electrode- coulometric titrations Voltammetry:
Cyclic voltammetry – stripping voltammetry - chronopoteniometry. Amperometry:
Amperometric titrations.
SRNMC Regulations-2018 Syllabus
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UNIT-IV THERMOANALYTICAL METHODS
Thermal analysis, theory and principles of DTA and TGA- factors affecting the
position of DT and TG traces-application of DTA and TGA to the thermal behavior of the
following compounds-crystalline coppersulphate, calcium oxalate monohydrate, calcium
acetate monohydrate, zinc hexafluosilicate-complementary nature of DTA and TGA-
principle and application of DSC-determination of degree of conversion of high alumina
cement-purity determination-phase transition study –in forensic laboratory.
UNIT-V SPECTROANALYTICAL METHODS
Colorimetry: Beer and Lambert’s law-terminology-condition for a satisfactory
colorimetric analysis-method of colour measurement or comparison-principles of
colorimetric determinations of NH3, Cr, Cu, Fe, Mn-simultaneous spectrophotometer
determination of Cr and Mn.
Nephelometry and turbidimetry:principle-determination of sulphate and phosphate-
fluorimetry: principle-application of fluorimetry in the determination of Cd,Ca,and Zn and
determination of codeine and morphine in a mixture-flame spectrometry: theory-
interferences-AAS-applications in the determination of Mg+2
and Ca+2
in tap water ,V in
lubricating oil, trace lead in a ferrous alloy and trace elements in contaminated soil.
Text books
Text Book- 1
Title of the book : Elements of analytical chemistry
Name of the Author : R.Gopalan
Publisher : Sultan Chand & sons, New Delhi
Edition/Year : 3/2003
Text Book- 2
Title of the book : Instrumental method of chemical analysis
Name of the Author : Gurdeep chatwal
Publisher : Himalaya publishing House
Edition/Year : 5/2012
Unit-I (From Text Book-1)
Chapter 9(Page No 121 to134)
Unit-II (From Text Book-1)
Chapter 4(Page No 28 to 37)
Unit-III (From Text Book-1)
Chapter 10(Page No 139 to 145,148 to 150)
(From Text Book-2)
Chapter 28(Page No 2.541 to 2.545)
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Unit-IV (From Text Book-2)
Chapter 41(Page No 2.701 to 2.759)
Unit-V (From Text Book-2)
Chapter 5(Page No 2.107 to 2.112)
Chapter 13 to 16(Page No 2.389 to 2.398, 2.349 to 2.416, 2.367)
Reference Books
Reference Book-1,
Title of the book : Fundamentals of Analytical Chemistry,
Name of the Author : D.A.Skoog, D.M.West and F.J.Hollar
Publisher : Harcourt College Publishers,
Edition/Year : 7/1996
Reference Book-2
Title of the book : Instrumental Methods of Analysis
Name of the Author : H.H.Williard,L.L.Merritt and J.A.Dean
Publisher : East-West press New Delhi
Edition/Year : 1 /1988
Reference Book- 3
Title of the book : Analytical chemistry
Name of the Author : U.N Dash
Publisher : Sultan Chand & sons, New Delhi
Edition/Year : 3/2013
Reference Book-4
Title of the book : Vogel’s Text Book of Quantitative Chemical Analysis
Name of the Author : J. Bassett et al
Publisher : ELBS, Longmann, U.K
Edition/Year : 5/ 1997
Reference Book-4
Title of the book : Analytical chemistry
Name of the Author : J. G.Dick
Publisher : Tata-McGraw Hill
Edition/Year : 1/ 1973
Prepared by : Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
41
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018 -2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHE22
Semester : II No. of Hours allotted : 5 / week
Subject : Paper IX-Major Elective –II (b) No. of Credits : 4
Title of the Paper : INDUSTRIAL CHEMISTRY
Objectives:
To enable the students
To understand the principle and importance of chemical technology
To utilize the raw materials in chemical industry
To get the awareness about the pollution and its control
UNIT-I PRINCIPLES AND IMPORTANCE OF CHEMICAL PROCESS INDUSTRY
Introduction – importance of chemical industry – new developments in chemical
technology – classification of technological processes – unit process and unit operation –
batch and continuous process – Indian chemical industry today – basic principles of
homogeneous and heterogeneous non catalytic processes.
UNIT-II RAW MATERIALS AND ENERGY FOR CHEMICAL INDUSTRY
Raw materials-Characteristics of raw materials and their resources- methods of raw
material concentration –integral utilization of raw materials
Energy for chemical industry-power and fuels-classification of fuels, coal, fuel gases
and liquid fuels-petroleum-cracking-chemical corrosion-types of corrosion and preventive
measures
UNIT-III Water Pollution and its Control
Introduction – types of water –soft and hard water-softening of water– water
pollution – sources of water pollution – water pollutants – classification – physical, chemical
and biological – inorganic pollutants and toxic metals – organic pollutants – -pesticides and
fertilizers – suspended particles – water quality – ill effects of water pollutants – water
pollution control – water treatment – primary, secondary and tertiary treatment – desalination
– reverse osmosis – sewage and industrial waste water treatment.
SRNMC Regulations-2018 Syllabus
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UNIT-IV SMALL SCALE CHEMICAL INDUSTRIES
Electro-thermal and electro-chemical industries: Electric furnace – classification -
manufacture of calcium carbide- Electrolytic manufacturing and refining of aluminium -
process and theory of electroplating.
Oils, fats and waxes: Manufacturing of soyabean oil-Analysis of oils,fats and waxes-
manufacture of soap by batch process - detergent (cationic ,anionic and non-ionic) –
preparation, properties and uses of potassium chlorate . .
UNIT-V LARGE SCALE CHEMICAL INDUSTRIES
Manufacturing process - raw materials - composition and uses of products in Portland
cement – ceramics - plastics(Polyethylene, PVC) -- synthetic fibres (Nylon66, Nylon 6,
Terylene) - natural Rubber- Refining of crude rubber - Vulcanization of rubber and Synthetic
rubbers (BunaS, Neoprene) - fertilizers(Nitrogen and phosphate)- Organic insecticides
(DDT,BHC)
Text Book- 1
Title of the book : ChemicalTechnology,Vol.1.
Name of the Author : I.Mukhlyonov(ed.),
Publisher : Mir publication, Moscow
Edition/Year : 3/1979
Text Book- 2
Title of the book : Enviromental Chemistry
Name of the Author : A.K.De
Publisher : New age International (P) Limited
Edition/Year : 6/2006
Text book-3
Title of the book : Industrial chemistry
Name of the Author : B.K Sharma
Publisher : Goel publishing house.
Edition/Year : 13 /2008
Text book-4
Title of the book : Outlines of Chemical Technology
Name of the Author : M.Gopala Rao Drydens
Publisher : East-West Press
Edition/Year : 3/2001
Text Book- 5
Title of the book : Polymer Science
Name of the Author : V.R.Gowarikar, N.V.Viswanathan and Jayadev Sreedher,
Publisher : Wiley Eastern Ltd., New Delhi
Edition/Year : 4 /1986
SRNMC Regulations-2018 Syllabus
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Unit-I (From Text Book-1)
Chapter 2(Page No 20-25,68-89)
Chapter 3(Page No90-118)
Chapter 4(Page No 136-158)
Chapter 5(Page No159-230)
(From textbook -4)
Chapter 1(Page No.)
Unit-II (From Text Book-1)
Chapter 7(page no.287-307,316-320)
(From Text Book-2)
Chapter 12(page no292-295)
Unit-III (From Text Book-2) Chapter -12 &13 (Page No. 197-292)
Unit-IV (From Text Book-1) Chapter -7 (Page No. 245 to 285)
Unit-V (From Text Book- 5 &3 ) Chapter 9 (Page No 215 to 220)
Reference Books
Reference Book-1
Title of the book : Chemical process industries
Name of the Author : R.Norris shreve & J.A.Brink
Publisher : McGraw Hill
Edition/Year : 4/1977
Reference Book-3
Title of the book : Hand book of industrial Chemistry
Name of the Author : James A.Kent
Publisher : CBS Publishers & Distributors PVT. Ltd.
Edition/Year : 9/ 1997
Prepared by : Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
44
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHC2P1
Semester : II No. of Hours allotted : 10 / week
Subject : Paper X Practical - II No. of Credits : 4
Title of the Paper : ORGANIC CHEMISTRY PRACTICAL
Objectives :
To enable the students
to estimate the organic compounds quantitatively
to prepare organic compounds by two stage preparation
to separate and analyze the given organic mixture into two different components
QUALITATIVE ANALYSIS
Separation and analysis of two component mixtures. Identification of the
components and preparation of solid derivative.
QUANTITATIVE ANALYSIS
a. Estimation of glucose by Lane and Eynon method
b. Estimation of glucose by Bertrand method
c. Estimation of glycine.
d. Estimation of formaldehyde.
e. Estimation of ethylmethyl ketone
f. Estimation of acetone
g. Estimation of ascorbic acid
ORGANIC PREPARATIONS: (ONLY FOR CLASS WORK)
About 5 (five) two stage preparations:
a. p-Nitroaniline from acetanilide
b. Anthranilic acid from phthalimide
c. m-Nitrobenzoic acid from methyl benzoate
d. Benzanilide from benzophenone.
e. Acetylsalicylic acid from salicylic acid
SRNMC Regulations-2018 Syllabus
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Reference books
Reference book-1:
Title of the book : Small Scale Preparations
Name of the Author : A.I. Vogel
Publisher : ELSB
Edition/Year : 2/1966
Reference book -2
Title of the book : Basic principles of practical Chemistry
Name of the Author : V.Venkateswaran, R.Veerasamy, A.R Kulandaivelu
Publisher : Sultan chand & sons Publishers, New Delhi
Edition/Year : 1/1995
Reference book -3
Title of the book : A Laboratory Manual of Organic Chemistry
Name of the Author : S. Murugan
Publisher : Bharathi Press
Edition/Year : 3/ 1988
Reference book -4
Title of the book : Advanced experimental Chemistry
Name of the Author : J.N Gurtu and R.Kapoor
Publisher : S.Chand and company limited
Edition/Year : 2/ 1982
Prepared by: Ms. K. RAJASULOCHANA
Signature :
SRNMC Regulations-2018 Syllabus
46
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
Programme : M.Sc ., Chemistry Subject Code : P18CHC31
Semester : III No.of Hours alloted : 5 / week
Subject : Core Paper No of Credits : 5
Title of the Paper : ORGANIC CHEMISTRY - III
REACTIONS, REAGENTS AND SPECTROSCOPY
Objectives:
To enable the students
to understand the concept of Oxidation and reduction
to know the application of reagents in organic synthesis
to apply 1H NMR and
13C NMR technique in elucidating the structure and
identification of organic molecules.
to apply the principle of ORD and CD in elucidating the structure of organic
molecules.
to know the chemistry of vitamins.
UNIT-I OXIDATION AND REDUCTION
Elimination of hydrogen and aromatization reactions – catalytic dehydrogenation –
mechanism and application of stereochemical aspect of the following oxidation – reduction
reactions : Oxidation reaction involving CrO3, SeO2, OsO4, lead tetra acetate, periodic acid,
N- bromosuccinimide, H2O2 - Oppenauer oxidation.
Catalytic hydrogenation – reaction involving lithium aluminium hydride, tri
isobutoxy aluminium hydride - DIBAL and sodium borohydride - Birch reduction –
Meerwein-Pondorf-Verley reduction – Wolff-Kishner reduction — Hydroboration.
UNIT -II REAGENTS IN ORGANIC SYNTHESIS AND FREE RADICALS
Gilman’s reagent (lithium dimethylcuprate), lithium diisopropylamide(LDA),
Dicyclohexylcarbodiimide, 1,3-dithiane,Woodward and Prevost hydroxylation, Merrifield
resin, phase transfer catalysts, Peterson’s synthesis and Baker’s yeast.
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Free radicals: Free radical reactions – halogenations, addition, oxidation, reduction
and rearrangement reactions – Barton, Sandmeyer, Gomberg, Bachmann, Ullmann, Pschorr
and Hundsdiecker reactions.
UNIT- III 1H NMR SPECTROSCOPY
1H NMR spectroscopy: Origin of NMR spectra – chemical shift, chemical shift
parameters – internal standards – factors affecting chemical shift, anisotropic effect, – NMR
concept of aromaticity – spin-spin coupling – coupling constant – first and second order
spectra– influence of stereochemical factors on chemical shift of protons – simplification of
complex spectra – deuterium substitution – spin decoupling and spin tickling – double
resonance – shift reagents – lanthanide shift reagents, chiral resolving reagents – Nuclear
overhauser effect – CIDNP.
UNIT -IV 13
C NMR SPECTROSCOPY
Natural abundance – H decoupling - Off-resonance decoupling – line intensities –
chemical shift equivalence - elementary study of alpha, beta and gamma effects -
hybridization of carbon - calculation of chemical shifts for aromatic and aliphatic
compounds , DEPT 13
C spectra - 13
C correlation spectroscopy - COSY, HETCOR, NOESY
and Inadequate.
Application: Application of spectral studies to characterize the organic compounds
UNIT- V CHIRO- OPTICAL TECHNIQUES AND VITAMINS
ORD and CD – principle - Cotton effect - type of ORD curves - α-haloketone rule -
octant rule - applications to determine the configuration and conformation of simple
monocyclic and bicyclic ketones-comparison of ORD and CD.
Vitamins : Introduction, classification, Structural elucidation of vitamin A, B1, B2, B6,
C, D2 and H
Text Books
Text book-1
Title of the book : Reaction mechanism and reagents in organic chemistry
Name of the Author : G.R.Chatwal
Publisher : Himalaya publishing house,
Edition/Year : 5 / 2012
Text Book- 2
Title of the book : Reactions, Rearrangements and Reagents
Name of the Author : Somorendra Nath Sanyal
Publisher : Bharati Bhawan Publishers
Edition/Year : reprint / 2000
SRNMC Regulations-2018 Syllabus
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Text Book- 3
Title of the book : Elementary organic spectroscopy principles and chemical
applications Name of the Author : Y.R.Sharma
Publisher : S.Chand and company Ltd, New Delhi
Edition/Year : Reprint / 2012
Text Book- 4 Title of the book : Organic spectroscopy – principles and applications
Name of the Author : Jag Mohan,
Publisher : Narosa Publishing House,
Edition/Year : 2/ 2003.
Unit-I (From Text Book-1) Chapter-17 (Page No.17.12-17, 27-48,56-70,91)
(From Text Book-2)
Chapter-2 (Page No.96-97, 146-148, 152-154)
Chapter-3 (Page No.199-202, 210-234, 237-246).
Unit-II (From Text Book-1)
Chapter-17 (Page No.17.23-26)
(From Text Book-2)
Chapter-2 (Page No.91-94, 167-170, 177-180)
Chapter-3 (Page No.206-209)
Unit-III (From Text Book-3) Chapter-5 (Page No.182-221,230-233)
(From Text Book-4)
Chapter-4 (Page No.187-197,203-256,269-288,296-306)
Unit-IV (From Text Book-4) Chapter-4 (Page No.307-326)
Unit-V (From Text Book-4) Chapter-5 (Page No.440-445,457-460)
Chapter-6 (Page No.473-481)
Reference books
Reference book1
Title of the book : Organic reaction mechanism
Name of the Author : V.K Ahluwalia
Publisher : Narosa publishing House New Delhi
Edition/Year : 3 /2007
Reference Book-2
Title of the book : Organic Spectroscopy,
Name of the Author : William Kemp,
Publisher : ELBS,
Edition/Year : 3 /2008,
Reference Book-3
Title of the book : Spectrometric Identification of Organic Compounds,
Name of the Author : Robert M.Silverstein, Francis X. Webster,
Publisher : John Wiley and Sons Inc.,
Edition/Year : 6 / 2010.
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Reference Book-4
Title of the book : Spectroscopy of Organic Compounds,
Name of the Author : P.S.Kalsi,
Publisher : New Age International Publishers,
Edition/Year : 6 / 2009.
Reference Book-5
Title of the book : Organic Chemistry of Natural Products volume I ,
Name of the Author : Gurdeep R. Chatwal,
Publisher : Himalaya PublishingHouse.
Edition/Year : 1 / 2007
Reference Book-6
Title of the book : Organic Chemistry of Natural Products volume II,
Name of the Author : Gurdeep R. Chatwal
Publisher : Himalaya PublishingHouse.
Edition/Year : 4 /2007
Reference Book-7
Title of the book : ORD and CD in Chemistry and Biochemistry
Name of the Author : P. Crabbe
Publisher : Academic Press,
Edition/Year : 2 / 1972
Prepared by : Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
50
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHC32
Semester : III No. of Hours allotted: 5 / week
Subject : Core -Paper - XII No. of Credits : 5
Title of the Paper : INORGANIC CHEMISTRY III
INORGANIC SPECTROSCOPY AND NANO CHEMISTRY
Objectives:
To enable the students
to have an indepth study of spectral applications to the structural elucidation of
inorganic compounds.
to have an exposure to the nano technology
to understand the concept of molecular rearrangements reaction in coordination
Complexes.
UNIT- I ELECTRONIC SPECTRA OF TRANSITION METAL COMPLEXES
Types of electronic transition- d-d transition- charge transfer transition.- L-S
coupling- Microstates –Term symbol-selection rules – mechanism of breakdown of selection
rules- bandwidths and shapes- Jahn Teller effect –Orgel diagram --Tanabo-sugano diagram
for various dn
configuration-Racah parameter- evaluation of 10Dq -Nephelauxetic ratio( β)
for Co(III)and Cr(III) complexes.
UNIT- II APPLICATION OF SPECTROSCOPY TO THE STUDY OF INORGANIC
COMPOUNDS
Mossbauer spectroscopy
Mossbauer effect- resonance absorption-Doppler effect- Doppler velocity –isomer
shift-magnetic hyperfine splitting-application of Mossbauer spectroscopy in the study of iron
and tin complexes.
NMR Spectroscopy: Multinuclear NMR- 31
P, 19
F and 15
N NMR – introduction –
application in structural problem-(ClF3, SF4, PF5, BrF5, P4S3, PF3 (NH2)2 )- evaluation of rate
constants –NMR of fluxional molecules –NMR of paramagnetic molecules- contact shifts
and shift reagents.
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ESR Spectroscopy: Principle –presentation of the spectrum –hyperfine splitting-
evaluation of g values –factors affecting the magnitude of g- values-zero field splitting –
Kramer's degeneracy---application of ESR in the study of transition of metal complex (bis
salicylaldiamine)copper(II), Mn2+
complex.
UNIT-III NANOCHEMISTRY
Basic idea of nanoscience–dimensional in nano structures-,0D,1D,2D and 3D ,
synthesis of nano materials -chemical method, sol gel , chemical vapour deposition- ball
milling-plasma arcing- electrodeposition- thermolysis
Carbon nanotubes: Types of carbon nano tubes- structure, properties and applications of
single walled carbon nano tubes.
Nano Shells: Introduction-types- properties and applications in Ion selective film, gold
nanoshell for blood Immunoassay - cancer detection and therapy.
Nano polymers: Conductive polymer and block copolymer.
Applications of nano materials- Insulation material-machine tools-high power magnets-motor
vehicle and aircrafts.
UNIT– IV REACTION MECHANISM OF COORDINATION COMPOUNDS
Substitution reactions of octahedral complexes- factors affecting reactivity octahedral
of complexes–labile–inert complexes–mechanism of acid hydrolysis, base hydrolysis and
anation reactions. substitution reactions in square planar complexes–factors affecting
reactivity of square planar complexes – The trans effect and its applications– electron transfer
reactions–outer sphere and inner sphere electron transfer mechanisms- complementary and
non complementary reactions.
UNIT-V MOLECULAR REARRANGEMENTS AND METAL CLUSTERS
Molecular rearrangement of four coordinated complex- six coordinated
complexes- -hydrolysis of amino acid ester, - Aldol condensation-imine formation, hydrolysis
and substituent exchange – the template effect and macro cyclic ligands.
Metal clusters: Structure and bonding of dinuclear clusters [Re2Cl8]4-
, trinuclear
clusters [Fe3(CO)12] tetranuclear clusters [Fe4(CO)12], hexanuclear clusters [Os6(CO)18] 2-
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Text books
Text Book- 1
Title of the book : Inorganic Chemistry-principles of structure and reactivity
Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,
Publisher : Harper Collins College Publishers
Edition/Year : 4/1993
Text Book-2
Title of the book : Concise inorganic chemistry
Name of the Author : J. D Lee
Publisher : Black well science Ltd
Edition/Year : 5/1996
Text Book-3
Title of the book : .Spectroscopy
Name of the Author : B.K Sharma
Publisher : Geol Publishing House,Meerut
Edition/Year : 17/2005
Text Book- 4
Title of the book : NanoTechnology
Name of the Author : Mick Wilson
Publisher : Overseas Press India Private Limited
Edition/Year : 1/2008
Text Book-5
Title of the book : An Introduction to Inorganic Chemistry.
Name of the Author : K.F. Purcell and J.C Koltz ,
Publisher : W.B Saunders company,
Edition/Year : 1 /1980
Unit-I (From Text Book-1)
Chapter 11 (Page No 433 to 459)
(From Text Book-2)
Chapter 32 (Page No 938 to 970 )
Unit-II (From Text Book-3)
Chapter 14 (Page No 737 to760)
Unit-III (From Text Book-4)
Chapter 3 (Page No 59 to 81)
Unit IV (From Text Book -1)
Chapter 13 (page No 538 to 555, 558-559)
Unit V (From Text Book -5)
Chapter (Page No 757 to 762, 783 to 791)
(From Text Book-1)
Chapter 16 (Page No 807 to 813)
SRNMC Regulations-2018 Syllabus
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Reference Books
Reference Book-1
Title of the book : Physical Methods in Inorganic Chemistry
Name of the Author : R.S.Drago
Publisher : W.B.Saunder company, London
Edition/Year : 1/1977
Reference Book -2
Title of the book : Introduction to Nanotechnology
Name of the Author : Charles P.Poolee Jr. and Franck Owens,
Publisher : John-Wiley and Sons
Edition/Year : 1/2006
Reference Book -3
Title of the book : Nano: the Essentials
Name of the Author : T.Pradeep
Publisher : Mc Graw-Hill Education,Delhi.
Edition/Year : 1 /2008
Reference Book-4
Title of the book : Advanced Inorganic chemistry
Name of the Author : F. A Cotton and Wilkinson
Publisher : John Wiley and sons
Edition/Year : 4/ 1998
Reference Book-5
Title of the book : Concepts and Model of Inorganic chemistry
Name of the Author : B. Dougles,D.H. Daniel and J.J Alexander
Publisher : John Wiley & Sons
Edition/Year : 2/1983
Prepared by : 1. Ms. K. BUVANESWARI
2. Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
54
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after )
SYLLABUS
Programme : M.Sc. Chemistry Subject Code : P18CHC33
Semester : III No. of Hours allotted: 5 / week
Subject : Core Paper VIII No. of Credits : 5
Title of the Paper : PHYSICAL CHEMISTRY – III
GROUP THEORY AND MOLECULAR SPECTROSCOPY-II
Objectives:
To enable the learners to
to have an idea of symmetries of molecules and their fundamental concepts.
to apply the group theory to spectroscopy and molecular problems.
to have an insight into the principles of molecular spectroscopy.
to get a clear idea about various spectroscopic technique and their applications.
to learn the concept of partition functions and theories of heat capacities of solids.
UNIT-I GROUP THEORY
Molecular symmetry elements and symmetry operations. Matrix algebra- types of
matrices, matrix representation for symmetry operations (E,Cn,Sn,i, σ) and transformatuon
matrices. Group-definition and properties of a group, subgroup, isomorphic group and
classes. Group multiplication table for C2Vand C3V point groups. Representation of a group
- reducible and irreducible representations.
Great Orthogonality theorem. Construction of a character tables- C2V, C3V, C2h and
D2d. Standard reduction formula. Direct product – definition and its applications.
UNIT-II APPLICATION OF GROUP THEORY TO SPECTROSCOPY AND
MOLECULAR PROBLEMS
Definition of molecular vibration, symmetry of normal mode analysis to water,
formaldehyde, ammonia, trans-N2F2 and ethylene molecule. Selection rules for IR and Raman
spectra. Selection rules for electronic transition in simple molecules like ethylene,
formaldehyde and benzene.
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Group theory applied to hybridization (BCl3, PCl5, XeF4, SF6 and CH4). Simplication
for molecular orbital calculation- SALC procedure - HMO theory and delocalization energy
for cyclopropenyl cation ,butadiene and benzene systems.
UNIT-III MOLECULAR SPECTROSCOPY-II
Raman spectroscopy: Theories of Raman scattering, Rotational and vibrational
Raman spectra. Mutual exclusion principle- Laser Raman spectra. Electronic spectra of
diatomic and polyatomic molecules. Intensity of vibrational electronic spectra - Franck
Condon principle -rotational fine structure of electronic vibrational spectra. Fortrat parabola.
Dissociation and predissociation spectra.
NQR : Principles and applications –quadruple moment and electrical field, nuclear
quadruple resonance, nuclear quadruple coupling in atoms and molecules. Identification of
ionic character and hybridization.
UNIT-IV SPIN RESONANCE SPECTROSCOPY
NMR: Magnetic properties of nuclei, resonance condition, NMR instrumentation.
Chemical shift, spin-spin splitting, relaxation processes, line shape and line width. Double
resonance technique, ENDOR, Nuclear overhauser effect, FT-NMR spectroscopy and
lanthanide shift reagents.
Photo electron spectroscopy – principle, XPS of elements, chemical shift, Koopman’s
theorem, XPS of O2 molecule, valence electron photoelectron spectroscopy. UPS spectrum
of N2 and O2 molecule. Application of photoelectron spectroscopy.
UNIT- V STATISTICAL THERMODYNAMICS-II
Partition functions: Translational, rotational, vibrational and electronic partition
functions of a diatomic molecule. Relationship between partition function and
thermodynamic function: internal energy, pressure, enthalpy, entropy, heat capacity,
Helmholtz free energy, Gibbs free energy and equilibrium constant. Sackur –Tetrode
equation. Population inversion. Einstein’s and Debye’s theories of heat capacities of solids.
Text books
Text Book- 1
Title of the book : Symmetry and spectroscopy of molecules
Name of the Author : K. Veera Reeddy
Publisher : New Age International Publishers
Edition/Year : 1 /2007
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Text Book- 2
Title of the book : Group Theory in Chemistry
Name of the Author : V.Ramakrishnan and M.S. Gopinathan
Publisher : Vishal Publications
Edition/Year : 2/1996
Text Book- 3
Title of the book : Fundamentals of molecular spectroscopy
Name of the Author : Colin N. Banwell and Elaine M.McCash
Publisher : Tata McGraw- Hill Publishing Company Limited
Edition/Year : 4/2003
Text book-4
Title of the book : Principles of Physical chemistry
Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania
Publication : Vishal publishing Co,New Delhi.
Edition/ year : 45 /2012
Text Book- 5
Title of the book : Advanced Physical chemistry
Name of the Author : Gurdeep Raj
Publisher : Goel Publishing Co,Meerut.
Edition/Year : 30 /2004
Unit I (From Text book 1)
Chapter-2(Page No. 21-47)
Chapter-4(Page No. 127-143)
Chapter-5(Page No. 144-172)
Chapter-6(Page No. 185-211)
Unit II (From Text book 1)
Chapter-7(Page No. 212-225)
(From Text book 2)
Chapter-5(Page No. 62-98)
Unit III (From Text book 4)
Chapter-4(Page No. 2.83-2.99)
Unit IV (From Text book 3)
Chapter-7 (Page No. 199-219)
(From Text book-4)
Chapter-7 (page No. 416-420)
(From Text book 4)
Chapter-7(Page No. 2.185-2.210)
Chapter-10(Page No. 2.245-2.267)
Unit V (From text book 5)
Chapter -3 (Page No.262-271)
Chapter -4 (Page No. 304-311)
SRNMC Regulations-2018 Syllabus
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Reference Books
Reference Book-1
Title of the book : Group Theory and its applications to chemistry
Name of the Author : K.V.Raman
Publisher : Tata McGraw- Hill Publishing company limited
Edition/Year : 1 /1990
Reference Book-2
Title of the book : Chemical applications of Group Theory
Name of the Author : F.A. Cotton
Publisher : John Wiley & Sons,New york
Edition/Year : 3 /1999
Reference Book-3
Title of the book : A Simple approach to group theory in chemistry
Name of the Author : S. Swarnalakshmi,T. Saroja,R.M.Ezhilarasi
Publisher : Universities Press Private Ltd
Edition/Year : 1 /2008
Reference Book-4
Title of the book : Molecular structure and spectroscopy
Name of the Author : G.Aruldhas
Publisher : PHI Learning (P) Limited, New Delhi
Edition/Year : 2 /2009
Prepared by : Ms. M. SELVAMARIAMMAL
Signature
SRNMC Regulations-2018 Syllabus
58
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHE31
Semester : III No. of Hours allotted: 5 / week
Subject : Paper XIV - Major Elective III (a) No. of Credits : 4
Title of the Paper : COMPUTER APPLICATIONS
Objectives:
To enable the learners to
to study the basic concepts of VB and its application in chemistry.
to know about basic concepts of internet.
UNIT-1 BASIC CONCEPT OF VB
Introduction to visual basic-the integrated development environment-the menu bar,tool
bar,the project explorer,the tool box,the properties of window,the form designer,the form lay
out,the immediate window,the elements of the interface-programming an application
common properties,common methods and common events-customising the environment.
Working with Forms: The appearance of form – the start up form – loading,
showing and hiding forms – elementary concepts of drag and drop operations.
Variables – declaring variables – variable types – strings, numeric and data
variables- scope and life forms of variables – constants.
UNIT- II THE LANGUAGE FORMS AND BASIC ACTIVE CONTROLS
Control flow statements: If… Then and If… Then…Else. Loop statements : DO…
Loop,For…Next and While – Wend – nested control statement – the Exit statement.
Arrays: Declaring arrays – specifying arrays – multi dimensional arrays.
Procedures: Subroutines, functions, calling procedures – arrangements – arguments passing
mechanism – using optional arguments – functions returning arrays.
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UNIT-III APPLICATIONS OF VB IN CHEMISTRY
Writing Simple programs in Chemistry:
1. Calculation of molecular weight of organic compound,
2. Ionic strength of an electrolyte,
3. Different velocities of a gas,
4. NMR frequency values of nuclei,
5. Average rate constant,
6. Unit cell dimensions,
7. Thermodynamic parameters,
8. Reduced mass,
9. Empirical formula of an organic compound containing C,H and O,
10. Normality, molality and molarity of a solution,
11. Half life period of a radioactive material,
12. Surface tension and
13. Temperature in Kelvin scale into Celsius and vice-versa.
Practical : (Class work only)
Construcion of programs in VB language, compiling, debugging and making
executive files, printing the output.
Running Simple VB programs in Chemistry to calculate/ determine the above
problems.
UNIT- IV BASIC CONCEPTS OF COMMUNICATION SYSTEMS
Communication systems: Satellites – RADAR – optical fibers – advantages and
disadvantages – ISDN – distributed systems – advantages and disadvantages.
Telecommunications: analog and digital signals – types and needs of modulations –
MODEMS – Telecommunication software.
Computer networks: An overview – communication processors – protocols – network
architecture.
Practicals (Class work only)
1. Salient features of Windows and MS Word for typing texts and equations in
Chemistry – tabular columns – advanced concepts.
2. Basic concept of creating and accessing databases using MS Access.
3. Significance of Chemdraw – drawing chemical structures and pasting them in the
text.
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UNIT- V BASIC CONCEPTS OF INTERNET AND APPLICATIONS IN
CHEMISTRY
Internet: History of internet – the working way of internet – getting connected to
internet, internet protocols – internet addressing –domain names- internet services. Internet:
characterization – advantages – drawbacks – need for internet – extranet.
www: Web Pages–homepages –web browsers –search engines –internet chat –
chatting on web.
E-mail : Introduction – working way – mailing basics – e-mail ethics – advantages
and disadvantages – creating e-mail – receiving and sending e-mails.
.Applications of internet in Chemistry: Websites in Literature survey in chemistry –
popular websites in chemistry – data bases in chemistry - URLS – WAIS – downloading the
attachment / PDF files – opening ,browsing and searching a website literature searching
online.
Practicals (Class work only)
Creating e-mail id, sending and receiving e- mail, attachment files, PDF files.Opening,
browsing and searching a website – down loading– literature survey in chemistry – online
searching.
Unit I to V Study material will be provided
Reference Book-1
Title of the book : Mastering Visual Basic 6
Name of the Author : Evangelos Petroutsos
Publisher : BPB Publication
Edition/Year : 1/1998
Reference Book-2
Title of the book : Visual Basic 6 Super Bible
Name of the Author : David Jung, Pierre Boutqukin, John D. Conley III, Loren Eidahl
Publisher : First Indian Edition, Techmedia, New Delhi, 1999.
Edition/Year : 1/1999
Reference Book-3
Title of the book : Visual Basic 6.
Name of the Author : Gary Cornell,
Publisher : Tata-McGraw Hill, New Delhi
Edition/Year : 1/ 1998
Prepared by : Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
61
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR- 626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHE32
Semester : III No. of Hours allotted : 5 / week
Subject : Paper XIV Major Elective – III (b) No. of Credits : 4
Title of the Paper : PHARMACEUTICAL CHEMISTRY
Objectives:
To enable the learners
to know the fundamentals of medicinal chemistry.
to learn uses of antibiotics and steroids.
to understand the concept of chemotherapy and its agents.
UNIT-I FUNDAMENTALS OF MEDICINAL CHEMISTRY
Definitions of Medicinal Chemistry, Pharmacology and molecular pharmacology,
pharmacodynamics, pharmacophore, pharmacodynamics agents - Structure Activity
Relationship (QSAR) – Hansch approach – account of physiological effects by hydroxyl,
aldehyde, ketone, acidic, nitro, nitrite, nitrile groups and unsaturation - drug receptors ,
mechanism of drug action on enzymes, gene function, biological membranes.
UNIT-II MEDICINALLY USEFUL ANTIBIOTICS AND ANTIMALARIALS
Classification of antibiotics - Structural features and SAR of the following
antibiotics - penicillin G, cephalosphorin and their semisynthetic analogs (β-lactam),
streptomycin (amino glycoside), terramycin (tetracycline), erythromycin(macrolide) ,
chloramphenicol and Rifamycin.
UNIT-III CHEMOTHERAPEUTIC AGENTS
Antineoplasticagents: Classification and synthesis of Cyclophosphamide,
Clorambucil, Busulfan, Decarbazine, Methotrexate, 6-Mercaptopurine, 5-fluorouracil and
cisplatin, Antitubercular drugs: Classification and Synthesis of Isoniazid, Rifampicin,
Pyrazinamine, Ethambutol and Ethionamide.Anti malarial drugs: Classification and synthesis
of Chloroquin, Primaquine, Amaodiaquine. Diuretics: Classification and Synthesis of
Fursemide, Acetazolamide, Chlorothiazide.
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UNIT-IV SYNTHESIS AND THERAPEUTIC ACTION OF CERTAIN DRUGS
Antihypertensive drugs: Nifedipine, Captopril, Sodiumnitroprusside, clonidine,
methyldopa and guanothidine. Antihistamines: H1-Antagonists: Pheniramine, Mepyramine,
Promethazine, H2- Antagonists: Cimetidine, Ranitidine and fomotidine.
UNIT- V SYNTHESIS AND THERAPEUTIC ACTION OF DRUGS
Anti-inflammatory drugs: Antipyratics & Non-narcotic analgesics: Aspirin, sodium
salicylate, paracetamol, phenylbutazone, oxyphenylbutazone, ibuprofen, Mephenamicacid,
Diclofenac sodium (preparation,structure and therapeutic uses only).CNS Stimulant drugs:
Amphetamine, Caffeine, Theobromine, Theophylline (structure and therapeutic uses only).
CNS Depressent drugs: Phenelazine, Imipramine, Amitriptyline, Desipramine (structure and
therapeutic uses only).
Text books
Text Book- 1
Title of the book : Pharmaceutical chemistry-organic
Name of the Author : G.R.Chatwal
Publisher : Himalaya Publishing House
Edition/Year : 3/2007
Text Book- 2
Title of the book : A Textbook of Pharmaceutical Chemistry
Name of the Author : Jayashree Ghosh
Publisher : S.Chand& Company Ltd
Edition/Year : 2/1996
Text Book- 3
Title of the book : Medicinal chemistry
Name of the Author : G.R.Chatwal
Publisher : Himalaya Publishing House
Edition/Year : 2/2006
Text Book- 4
Title of the book : Text book of Pharmaceutical Organic chemistry
Name of the Author : Mohammad Ali
Publisher : CBS Publishers & distributors
Edition/Year : 1 /2006
Unit-I (From Text Book-1)
Chapter – 1 (Page No. 5-7)
Chapter – 3 (Page No. 41-45, 50-56, 62,63)
Chapter – 5 (Page No. 94-97)
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Unit-II (From Text Book-2)
Chapter – 23 (Page No.242-265)
Unit-III (From Text Book- 3)
Chapter – 31 (Page No 316-333, 283 to291, 264 to271)
Chapter – 25 (Page No 250 to 257)
Unit-IV (From Text Book- 3)
Chapter – 19 (Page No 214 to224)
Unit-V (From Text Book-2)
Chapter – 13 (Page No.175-179)
(From Text Book-4)
Chapter – 16 (Page No.174-176)
Reference Books
Reference Book-1
Title of the book : Medicinal Chemistry
Name of the Author : Sriram.D,Yogeeswari
Publisher : PESL
Edition/Year : 2/2010
Reference Book-2
Title of the book : Medicinal Chemistry
Name of the Author : Kar.Ashutosh
Publisher : New age International Publishing House
Edition/Year : 5/2010
Reference Book-3
Title of the book : Introductory Medicinal Chemistry..
Name of the Author : J.B Taylor and P.D Kennewell
Publisher : Ellisworth publishers
Edition/Year : 1/1985
Prepared by : Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
64
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018--2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHC3P1
Semester : III No. of Hours allotted : 10 / week
Subject : Paper XV PRACTICAL III No. of Credits : 4
Title of the Paper: PHYSICAL CHEMISTRY PRACTICAL
Objectives:
To enable the learners
To know about the practical applications of conductometry.
To appreciate the application of potentiometric technique in the quantitative analysis.
To understand the concepts of adsorption and Chemical kinetics by carrying out
experiments.
I. CONDUCTOMETRIC EXPERIMENTS
i. Double displacement & acid base titrations
a) NH4Cl-NaOH-Mixture of CH3COOH &HCl.
b) NH4Cl- NaOH- Mixture of NH4Cl &HCl.
ii. Precipitation titration
a) Na2CO3-Pb (NO3)2 – Na2CO3
b) K2SO4 – BaCl2 – K2SO4.
iii. Determination of dissociation constant of weak acids.
II ADSORPTION EXPERIMENTS
i. Adsorption of oxalic acid/ Acetic acid on charcoal.
III KINETIC EXPERIMENTS
i. Perdisulphate and iodide ion reaction: Study of primary salt effect and
determination of concentration of given KNO3.
ii. Kinetics of alkaline hydrolysis of ester by conductometric method.
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IV POTENTIOMETRIC EXPERIMENTS
i. Precipitation titration : Ag vs. halide mixture
ii. Redox titrations : a) permanganate vs iodide ion
b) ceric ammonium sulphate vs. ferrous ion
iii. Determination of dissociation constant of weak acids and pH of
Buffer solutions
iv Determination of solubility product of sparingly soluble salts.
V Titrations using pH meter
Determination of first, second and third dissociation constants of phosphoric acid.
References:
Reference Book-1
Title of the book : Advanced Practical Physical Chemistry
Name of the Author : J.B. Yadav
Publisher : Goel Publications, Meerut
Edition/Year : 6/1986
Reference Book-2
Title of the book : Practical physical Chemistry
Name of the Author : B.Viswanathan
Publisher : Vivas Book private limited
Edition/Year : 1/2005
Prepared by : Ms. M. SELVAMARIAMMAL
Signature :
SRNMC Regulations-2018 Syllabus
66
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
Programme : M.Sc . Chemistry Subject Code : P18CHC41
Semester : IV No.of Hours alloted : 5 / week
Subject : Paper XVI -Core Paper No of Credits : 5
Title of the Paper: ORGANIC CHEMISTRY -IV
MOLECULAR REARRANGEMENTS AND SYNTHETIC METHODS
Objectives:
To enable the learners
to know about the various types of molecular rearrangements.
to understanding the fundamental concept of photochemistry and pericyclic reactions
to know about alkaloids and steroids.
to get insight into the principle of green chemistry.
to know the synthetic utility of reagents.
UNIT-I MOLECULAR REARRANGEMENTS
Mechanism of the following rearrangement reactions: Wagner – Meerwein, Pinacol-
pinacolone, Demjanov, Beckmann, Hofmann, Curtius, Wolff, Baeyer-Villeger, Stevens,
Sommelet-Hauser, Favorskii, Benzil-benzilic acid, Claisen, Cope, Fries, Dienone-phenol and
Benzidine rearrangement – photo Fries rearrangements.
UNIT-II PHOTOCHEMISTRY AND PERICYCLIC REACTIONS
Basic principles of photochemistry - Jablonskii diagram – Norrish type-I and
Norrish type-II reactions – Paternò–Büchi reaction – photochemistry of olefins and dienes ,
cis, trans isomerisation - photosensitization - photoreduction .
Pericyclic reactions: Types of pericyclic reactions-– electrocyclic reactions – cyclo addition
reactions and sigmatropic rearrangements –applications of conservation of orbital symmetry-
correlation diagram approach (butadiene and hexatriene), Frontier molecular approach,
Huckel-Mobius approach to the above reactions.
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UNIT- III STEROIDS,HARMONES AND ALKALOIDS
Steroids and Harmones: Classification – structural elucidation of cholesterol,– male
sex harmones – androsterone and testosterone – female sex harmones – oestrone, equilenin
and progesterone
Alkaloids: General methods of structural determination – Hofmann, Emde and Von
Braun degradations. Structural elucidation of quinine, reserpine, morphine (synthesis not
required) and lysergic acid
UNIT- IV GREEN CHEMISTRY
Twelve basic principles of green chemistry, green starting materials, green catalyst
(zeolites as solid acid catalyst)and reagents (molecular oxygen ,tetrabutylammonium
tribromide), green solvents – applications of supercritical fluids, ionic liquids and water –
solvent free techniques.
Non-conventional microwave heating - interaction of microwave radiation with the
material-difference between conventional heating and microwave heating. Dielectric
polarization-dipolar polarization-applications and advantages of microwave heating over
conventional heating.
UNIT-V SYNTHETIC METHODS
Planning a synthesis- molecular history- starting materials-Relay approach and
convergent approach to total synthesis- Retro synthetic analysis of simple organic compounds
- functional group inter conversions -use of activating and blocking groups in synthesis -
stereo selective problems of geometrical and optical isomerism- steric crowding–
Regioselectivity – Diastereoselectivity – Enantioselectivity - Umpolung synthesis - Robinson
annelation – A schematic analysis of the total synthesis of the following compounds:, trans-
9-methyl -1-decalone and 2,4-dimethyl-2-hydroxy pentanoic acid, Isonootkatone.
Text books
Text book-1
Title of the book : Organic reaction mechanism
Name of the Author : V.K Ahluwalia
Publisher : Narosa publishing House New Delhi
Edition/Year : 3 /2007
Text Book- 2
Title of the book : Reactions, Rearrangements and Reagents
Name of the Author : Somorendra Nath Sanyal
Publisher : Bharati Bhawan Publishers
Edition/Year : 3 / 2000
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Text Book- 3
Title of the book : Photochemistry and Pericyclic Reactions
Name of the Author : Jagdamba Singh and Jayasingh
Publisher : New age international (p) limited, New Delhi.
Edition/Year : 3 / 2012
Text Book- 4
Title of the book : New trends in Green chemistry
Name of the Author : V.K Ahluwalia and Kidwai ,
Publisher : Anamaya publishing house, New Delhi.
Edition/Year : 1 / 2004
Text Book- 5
Title of the book : Organic Synthesis,.
Name of the Author : R.E. Ireland,
Publisher : prentice-Hall of India Pvt. Ltd ,
Edition/Year : 2 reprint /1998
Text book-6
Title of the book : Organic chemistry of natural products Vol-I&vol-II
Name of the Author : G.R.Chatwal,
Publisher : Himalaya publishing House New Delhi,
Edition/Year : 4 & 5 /2007, 2009
Unit-I (From Text Book-1)
Chapter 6 (Page No.398-413, 415-424, 434-440,454-460)
(From Text Book-2)
Chapter 2 (Page No.89-94, 107-109,121-133, 172-174, 180-187)
Unit-II (From Text Book-3)
Chapter 6 (Page No.160-183)
Chapter 7 (Page No.184-212, 218-223)
Chapter 8 (Page No.251-257)
Chapter 9 (Page No.262-264)
Chapter 10 (Page No.270-282)
Chapter 1 (Page No.1-16)
Chapter 2 (Page No.17-34)
Chapter 3 (Page No.58-87)
Unit-III (From Text Book-6)
Chapter 4 (Page No.4.1-4.25,4.59-4.68,4.76-4.82,4.90-4.92,4.95-4.96)
Chapter 3 (Page No.3.6-3.19, 3.66-76, 3.109-117, 3.123-137, )
Unit-IV (From Text Book-4) Chapter 1&2 (Page No.1-4)
Chapter 3 (Page No.5-14)
Chapter 6 (Page No.22-26)
Chapter 7(Page No.27-28)
Chapter 8 (Page No.39-50)
Chapter 9 (Page No.59-71)
Unit-V (From Text Book-5) Chapter 2(Page No.17-52)
Chapter 3 (Page No.55-56,81-87)
SRNMC Regulations-2018 Syllabus
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Reference Books
Reference Book-1
Title of the book : Organic Chemistry,Vol II ,
Name of the Author : I.L.Finar
Publisher : ELBS Longmann
Edition/Year : 5 / 1975
Reference Book-2
Title of the book : Advanced Organic Chemistry,.
Name of the Author : Jerry March
Publisher : John Wiley and Sons,
Edition/Year : 4 / 2000
Reference Book-3
Title of the book : Green chemistry (Environmental Benign Reactions)
Name of the Autho : V.K Ahluwalia ,
Publisher : Aru Books India. New Delhi.
Edition/Year : 1 /2006
Reference Book-4
Title of the book : Green Chemistry (Environmental Friendly Alternatives)
Name of the Author : R.Sanghi and M.M. Srivastava,
Publisher : Narosa publishing House, New Delhi.
Edition/Year : 1 /2006
Reference Book-5
Title of the book : Reaction Mechanism in Organic Chemistry,
Name of the Author : S.M .Mukherji and Singh
Publisher : Macmillan India Ltd
Edition/Year : Reprint / 2007
Reference Book-6
Title of the book : Pericyclic Reactions,
Name of the Author : Sankarraman ,
Publisher : Wiley VCH.
Edition/Year : 2/2005
Reference Book-8
Title of the book : Organic Chemistry of Natural Products volume II,
Name of the Author : Gurdeep R. Chatwal
Publisher : Himalaya PublishingHouse.
Edition/Year : 4/2007
Reference Book-9
Title of the book : The Chemistry of Steroids,
Name of the Author : W.Klyne
Publisher : Reinhold
Edition/Year : 1 / 1957
Prepared by : Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
70
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHC42
Semester : IV No. of hours allotted: 5 / week
Subject : Core Paper XVII No. of Credits : 5
Title of the Paper : INORGANIC CHEMISTRY -IV
NUCLEAR AND ORGANOMETALLIC CHEMISTRY
Objectives:
To enable the students
To have a complete study of f-block elements.
To have an idea about various analytical techniques.
To learn principles and applications in nuclear chemistry.
UNIT- I STRUCTURE OF NUCLEUS AND RADIOACTIVE DECAY
Composition of the nucleus –nuclear Size, shape and density-principle, radial
and magnetic quantum numbers n/p ratio- stability of nucleus packing fraction--mass defect
and binding energy.Radioactive decay: Group displacement law – decay series – rate of
disintegration -half life period -average life period – secular and transient equilibria -
theories of alpha decay, beta decay, gamma emission, internal conversion and electron
capture - Auger effect.
UNIT- II NUCLEAR FISSION AND FUSION AND APPLICATION RADIOACTIVE
ISOTOPES
Bethe's notation of nuclear process - nuclear reaction energies (Q-values) – fission
-energy release in nuclear fission-mass distribution of fission products-theory of nuclear
fission -fissile and fertile isotopes – energy from nuclear fusion-thermonuclear reaction in
stars - nuclear reactor--breeder reactor- waste disposal management.Applications of
radioactive isotopes: - chemical investigations-age determination-medical field-agriculture
and analytical techniques.
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UNIT-III CHEMISTRY OF LANTHANIDES AND ACTINIDES
Position of lanthanides and actinides in periodic table – occurrence, extraction of
lanthanides from monazite sand -ion exchange and solvent extraction method. -Electronic
configuration-properties of lanthanides-oxidation state-lanthanide contraction and its
consequences-color of lanthanides ions- magnetic properties of lanthanides. Actinides:
separation of actinide elements-separation of Pu from fission products-electronic
configuration- oxidation state-comparison of lanthanides and actinides.
UNIT- IV ANALYTICAL METHODS
Electro analytical Techniques: Electrogravimetry, Theory of electro gravimetric
analysis - electrolytic separation and determination of metal ions. Coulometry - Coulometric
titrations. Voltametry: Cyclic voltammetry.Amperometry: Amperometric titrations. Thermo
analytical Methods: Principle and applications of TGA and DTA. Spectro analytical
Methods: principle and applications of – Fluorimetry , Nepheometry , Turbidimetry - Flame
photometry and Atomic absorptions spectroscopy .
UNIT – V COMPLEXES OF П- ACCEPTOR LIGANDS
Synthesis, structure and bonding in metal carbonyls and nitrosyls – Applications of
IR spectroscopy in metal carbonyls - EAN rule.Isolobal relationship. Synthesis, properties,
structure and bonding in ferrocene- olefin and acetylene complexes.
Catalysis using organometallic compounds: Oxidative addition – reductive elimination –
insertion reaction Catalytic mechanism in the following Reactions: hydrogenation of olefins
(Wilkinson catalyst) - hydroformylation (Oxoprocess) – acetic acid from methanol –
oxidation of alkenes to aldehydes and Ketones (Wacker process) – olefin polymerization
(Ziegler – Natta) – Cyclo oligomerisation of acetylenes (Reppe’s or Wilke’s catalysts).
Text books
Text Book- 1
Title of the book : Essential of Nuclear Chemistry
Name of the Author : H.I .Arnikar
Publisher : Wiley Eastern Ltd.,New Delhi
Edition/Year : 3/1987
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Text Book- 2
Title of the book : Nuclear Chemistry
Name of the Author : U.N.Dash
Publisher : Sultan Chand and Sons, New Delhi
Edition/Year : 1/1991
Text Book- 3
Title of the book : Selected Topics in Inorganic Chemistry
Name of the Author : Wahid U.Malik et al
Publisher : S.Chand and Company Ltd.
Edition/Year : 7/2007
Text Book- 4
Title of the book : Instrumental Methods of chemical Analysis
Name of the Author : Gurdeep R.Chatwal
Publisher : Himalaya Publishing House
Edition/Year : 5/2008
Text Book- 5
Title of the book : Advanced Inorganic Chemistry Vol II
Name of the Author : Satya Prakash
Publisher : S.Chand & Company LTD
Edition/Year : 17/2000
Text Book- 6
Title of the book : Inorganic Chemistry.
Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,
Publisher : Harper Collins College Publishers
Edition/Year : 4/1993
Unit I (From Text book-2)
Chapter - 1 (section 1.5 to 1.6.4, 1.8.1, 1.8.2)
Chapter - 3 (section 3.2 to3.3, 3.6.1, 3.6.2,)
Chapter - 5 (Page no 195 to 201, 214 to 227)
Unit II (From Text book -1)
Chapter 5(section 5.1 to 5.2.6, 5.7 to 5.7.3, 5.9, 5.10)
Chapter 6 (section6.2, 6.3 6.9)
Chapter 7 (section 7.8.1, 7.11)
Chapter 10 (section 10.7.1.10.7.3 to 10.7.6)
Unit-III (From Text Book-3)
Chapter 9 and 10 (274 to 331)
Unit IV (From Text Book -4)
Chapter 26 to29 (Page No 2.523 to 2.549)
Chapter 41 (Page No 2.701, 2.719 to 2.738)
Chapter 13 to 16 (Page No 2.340 to 2.415)
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Unit-V (From Text Book-5)
Chapter 13(Page No 370 to 405)
(From Text Book-6)
Chapter 15(Page No 630-639,647-653,662-665,669-673, 706-712, 714-715,718)
Reference Books
Reference Book-1
Title of the book : Source Book on Atomic Energy
Name of the Author : S.Glasstone,
Publisher : Van Nostrand Reinhold Company, New York
Edition/Year : 3/1967
Reference Book-2
Title of the book : Fundamentals of Analytical Chemistry,
Name of the Author : D.A .Skoog and D.M. Weat
Publisher : Saunders college Puplishing co Philadelphia
Edition/Year : 1 /1982
Reference Book-2
Title of the book : Instrumental Methods of Analysis
Name of the Author : H.H..Willard, LL.Merritt and J.A.Dean,
Publisher : East- West press., New Delhi
Edition/Year : 1 /1988
Reference Book-4
Title of the book : Concepts and Model of Inorganic chemistry
Name of the Author : B.E Dougles,D.H. Daniel and J.J Alexander
Publisher : John Wiley & Sons
Edition/Year : 2/1983
Reference Book-5
Title of the book : Organometallic Chemistry
Name of the Author : R.C Mehrotra& Animgh singh
Publisher : John Wiley & Sons
Edition/Year : 2/1983
Reference Book-5 Title of the book : Advanced Inorganic chemistry
Name of the Author : F. A cotton & G. Wilkinson
Publisher : John Wiley & Sons
Edition/Year : 5/1988
Reference Book-5 Title of the book : Analytical Chemistry
Name of the Author : U.N.Dash
Publisher : Sultan Chand and Sons, New Delhi
Edition/Year : 1/2001
Prepared by : 1. Ms. K. BUVANESWARI
2. Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
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SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHC43
Semester : IV No. of Hours allotted: 5 /week
Subject : Core Paper XVIII No. of Credits : 5
Title of the Paper : PHYSICAL CHEMISTRY -IV
CHEMICAL KINETICS, SURFACE, BIOPHYSICAL AND
PHOTOCHEMISTRY
Objectives:
To enable the students
to get themselves exposed to kinetics and mechanisms of chemical reactions.
to derive advance knowledge on solids and surface phenomena.
to learn concepts of non-equilibrium thermodynamics and bio-energetics.
to understand the fundamental concepts of photochemistry and radiation chemistry
UNIT - I CHEMICAL KINETICS I
Chain reactions and its general characteristics. Study of kinetics of chain reactions
like H2-Br2 reaction, decomposition of acetaldehyde and N2O5. Study of H2-O2 explosive
reactions.Unimolecular reaction rate theories – the simple Lindemann treatment,
Hishelwood’s theory, Rice, Ramsperger and Kassel(RRK) theory, Marcus theory or Rice,
Ramsperger, Kassel and Marcus (RRKM) theory and Slater’s theory. Principle of
microscopic reversibility and detailed balancing, Kinetic isotope effect. Reactions in solution
– influence of solvent dielectric constant, ionic strength (Bronsted- Bjerrum equation –
primary and secondary salt effects).
UNIT- II CHEMICAL KINETICS II
Fast reactions techniques – chemical relaxation methods, temperature and pressure
jump methods, ultrasonic absorption technique, reactions in flow system, continuous and
stopped flow, shock wave tube methods; chemical kinetics in crossed molecular beams and
Flash photolysis.
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UNIT - III SURFACE CHEMISTRY
Introduction- adsorption of gases on solids- physisorption and chemisorptions –
adsorption isotherms- Freundlich-Langmuir, BET and Temkin adsorption isotherms – surface
tension-Gibbs adsorption isotherm-surface area determination–monolayer-preparation of LB
films – micelles - critical micellar concentration (CMC)-structure- reverse micelles-micro
emulsion.
UNIT - IV BIOPHYSICAL AND SUPRAMOLECULAR CHEMISTRY
Basic concept of non-equilibrium thermodynamics- Phenomenological Laws-
Onsager reciprocal relations – transformation properties of fluxes and forces.Its application to
biological systems.- entropy production due to heat flow- High energy metabolites – ATP
and its role in bioenergetics, -coupled reaction. Biophysical applications of Mossbauer Effect,
NMR imaging.– Enzyme models- molecular asymmetry- Molecular recognition. .
UNIT - V PHOTO CHEMISTRY AND RADIATION CHEMISTRY
Physical properties of the electronically excited molecules – excited state dipole
moments, pKa and redox potentials –photo physical processes in electronically excited
molecules – Fluorescence, phosphorescence and other deactivating processes. Stern - Volmer
equation and its applications – electronic energy transfer mechanisms – photosensitization
and chemiluminescence, Experimental techniques in photochemistry – light sources –
chemical actinometry – elementary aspects of photosynthesis, photochemical conversion and
storage of solar energy. Radiation chemistry : source of high energy – interaction of high
energy radiation with matter – radiolysis of water. Experimental techniques of radiation
chemistry- Dosimeter .
Text Book- 1
Title of the book : Chemical Kinetics
Name of the Author : K.J.Laidler
Publisher : Pearson Education Private Ltd, Delhi
Edition/Year : 3 /2004
Text Book- 2
Title of the book : Fast Reactions
Name of the Author : J.N.Bradley
Publisher : Clarendon Press Oxford
Edition/Year : 1/1975
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Text Book- 3
Title of the book : Advanced Physical chemistry
Name of the Author : Gurdeep Raj
Publisher : Goel Publishing Co,Meerut.
Edition/Year : 30 /2004
Text Book- 4
Title of the book : Fundamentals of Biochemistry
Name of the Author : J.N.Jain
Publisher : S.Chand & Company Ltd, New Delhi
Edition/year : 6 / 2005
Text Book- 5
Title of the book : Fundamentals of Photochemisty
Name of the Author : K.K. Rohatgi Mukherjee
Publisher : New Age International (P) Limited
Edition/Year : 2 /2006
Text Book- 6
Title of the book : Essential of Nuclear chemistry
Name of the Author : H.J.Arnikar
Publisher : New Age International Publishers
Edition/Year : 4 /2005
Unit-I (From Text Book-1)
Chapter-3(Page No.59-61)
Chapter-4(Page No.129-131)
Chapter-5(Page No.150-167)
Chapter-6(Page No.191-201)
Unit-II (From Text book-2)
Chapter-4(Page No.33-36)
Chapter-5(Page No.47-52)
Chapter-8(Page No.79-85)
Chapter-9(Page No.89-90)
Chapter-11(Page No.112-115)
Unit-III (From Text book-3)
Chapter-16(Page No. 873-880, 882-894. 905-909)
Chapter-17(Page No. 952-954, 1017-1021, 1028-1030)
Unit-IV (From Text book-4)
Chapter-20(Page No. 348-366)
Unit- V (From text book -5)
Chapter - 4 (Section 4.7 to 4.9)
Chapter - 5 (section 5.1)
Chapter - 9 (section 9.5)
Chapter -10 (section 10.1)
(From text book -6)
Chapter -11 (section 11.1 to 11.7.5)
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Reference Book-1
Title of the book : Advanced Physical chemistry
Name of the Author : D.N. Bajpai
Publisher : S.Chand &Company Ltd, New Delhi.
Edition/Year : 1 /1992
Reference Book-2
Title of the book : Principles of Physical chemistry
Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania
Publication : Vishal publishing Co,New Delhi.
Edition/ year : 45 /2012
Reference Book-3
Title of the book : Physical chemistry on Surfaces
Name of the Author : A.W.Adamson
Publisher : John Wiley &Sons, New York
Edition/Year : 5 /1990
Reference Book-4
Title of the book : Principles of Biochemistry
Name of the Author : A.L.Lehninger
Publisher : CBS Publication,New Delhi
Edition/year : 1 /1984
Reference Book-5
Title of the book : Advanced Physical chemistry
Name of the Author : D.N. Bajpai
Publisher : S.Chand &Company Ltd, New Delhi.
Edition/Year : 1 /1992
Reference Book-6
Title of the book : Bioorganic,bioinorganicand supramolecular chemistry
Name of the Author : P.S. Kalsi & J.P.Kalsi
Publisher : New age international publishers
Edition/Year : 2 /Reprinted 2011.
Prepared by : Ms. M. SELVAMARIAMMAL
Signature :
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SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR- 626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P18CHE41
Semester : IV No. of Hours allotted: 5 / week
Subject : paper XIX Major Elective IV (a) No. of Credits : 4
Title of the Paper : INTRODUCTION TO NANOSCIENCE
Objectives:
to understand the basic concept of nano science.
to study the synthesis and applications of nano chemistry.
to know about the characterization of nano materials.
UNIT- I GENERAL INTRODUCTION
Forms of Matter –Crystal structures –electronic properties of atoms and solids –
surface energy and surface tension – defining nanodimensional materials – 0D, 1D and 2D
nanostructures – size dependence of properties – special properties resulting from
nanodimensionality – potential use of nanomaterials.
UNIT- II SYNTHESIS OF NANOMATERIALS
General approaches – nucleation process – sizes of the crystal – influence of
nucleation rate on the size of the crystal – chemical methods – Sol-gel techniques – control of
grain size – Coprecipitation - hydrolysis – sonochemical method – colloidal precipitation –
bottom up and top down approaches – kinetically confined synthesis of nanoparticles.
UNIT- III PRINCIPLE AND INSTRUMENTATION
Spectrophotometry,XRD, EXAFS, XPS, SEM, TEM, AFM –application to
nanomaterials characterization.
UNIT- IV OPTICAL PROPERTIES OF NANOMATERIALS
UV-Vis, IR absorption – photoluminescence and stimulated emission – nonlinear
optical mixing – photo conductivity Magnetic properties: concepts of dia-, para-, and ferro-
magnetism – exchange correlation – exchange interaction. Electrical properties: electrical
conductivity – Hall effect – charge carrier density – activation energy; electronic properties –
field emission properties.
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UNIT- V BIOLOGICAL NANOMATERIALS
Sizes of building blocks – proteins – DNA double nanowire – enzymes – protein
synthesis – Micelles and vesicles – Biomimetic nanostructures – Worm micelles and Vesicles
from block copolymers.
Text books
Text Book- 1
Title of the book : Introduction to Nanotechnology
Name of the Author : C.P. Poole
Publisher : John Wiley & Sons, INC.
Edition/Year : 1 /2012
Text Book- 2
Title of the book : Nano: the Essentials
Name of the Author : T. Pradeep
Publisher : Mc Grow-Hill Education, Delhi.
Edition/Year : 1 /2008
Text Book- 3
Title of the book : Nanotechnology
Name of the Author : Mick Wilson
Publisher : Overseas India pvt Ltd
Edition/Year : 1/2008
Unit-I (From Text Book-1)
Chapter – 2 (Page No. 8-21)
Unit-II (From Text Book-3)
Chapter – 3 (Page No.56-70)
Unit-III (From Text Book-2) Chapter – 2 (Page No. 15-75)
Unit-IV&V (From Text Book-1)
Chapter – 4 (Page No.80-93)
Chapter – 12 (Page No.310-329)
Reference Book-1
Title of the book : The Chemistry of Nano Materials
Name of the Author : C.N.R.Rao
Publisher : Wiley-VCH –Verlag Gmoh and co
Edition/Year : volumes 1 and 2 /1980
Reference Book-2 Title of the book : NanoTechnology
Name of the Author : S.Shanmugam
Publisher : NJP Publisher
Edition/Year : 1/2011
Prepared by : Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
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SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR- 626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc., Chemistry Subject Code : P18CHE42
Semester : IV No. of Hours allotted: 5 / week
Subject : paper XIX Major Elective IV (b) No. of Credits : 4
Title of the Paper : POLYMER CHEMISTRY
Objectives:
To enable the students
To understand the chemistry of polymerization.
To study about the utility of polymers in various field.
To know about the processing of polymers.
UNIT- I CLASSIFICATION OF POLYMERS AND CHEMISTRY OF
POLYMERISATION
Classification of polymers: linear polymers, non-linear or branched polymers,
cross - linked polymers, homo chain hetero chain, homopolymers co-polymers block
polymers and graft polymers. Chemistry of polymerisation: Types of polymerization –
mechanism of chain growth, free radical, ionic, co-ordination, ring opening, metathetical and
group transfer polymerization, polyaddition and polycondensation polymerisations.
UNIT- II INDIVIDUAL POLYMERS
Individual polymers: Monomers required general methods of preparation,
repeating units and uses of the following polymers and resins- polyethylene, polystyrene,
polyacryloniltrile-polymethylmethacrylate-polyvinylchloride-polytetrafluoroethylene
polybutadienes-polychloroprene-polyesters-polycarbonates-polyimides-polyamides (Kevlar)-
polyurethanes- polyethylene glycols, Resins: phenol - formaldehyde, urea- formaldehyde,
melamine – formaldehyde and epoxy resins.
UNIT- III PROPERTIES OF POLYMERS
Intrinsic properties – processing properties – basic idea of isomerism of polymers –
configuration of polymer chain – geometrical structure - syndiotatic, isotatic and atatic
polymers.Glass transition temperature: Definition –factors affecting glass transition
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temperature – relationships between glass transition temperature and (a) molecular weight,
(b) meltingpoint and (c) plasticizer – importance of glass transition temperature – heat
distortion temperature.Molecular weight and size of polymers: Number average, weight
average, sedimentation and viscosity average molecular weights – molecular weights and
degree of polymerisation– poly dispersity – molecular weight distribution in polymers – size
of polymer molecules – kinetics of polymerization.
UNIT- IV POLYMERISATION TECHNIQUES, DEGRADATION AND USES OF
POLYMERS
Polymerisation Techniques: Bulk, solution, suspension, emulsion, melt
condensation and interfacial polycondensation polymerizations. Degradation: Types of
degradation – thermal, mechanical, ultrasonic and photodegradation – photo stabilizers –
oxidative degradation – antioxidants – hydrolytic degradation. Uses of polymers in
electronics and biomedicine.
UNIT -V POLYMER PROCESSING
Polymer processing: plastics (thermo and thermosetting), elastomers, fibres,
compounding, plasticizers, colorants, flame retardants. Compression and injection mouldings
– film extrusion and calendaring – die casting and rotational casting- thermo forming –
reinforcing.
Text Book- 1
Title of the book : Polymer Science
Name of the Author : V.R.Gowarikar, N.V.Viswanathan and Jayadev Sreedher,
Publisher : Wiley Eastern Ltd., New Delhi
Edition/Year : 4 /1986
Text Book- 2
Title of the book : Principles of Polymer science
Name of the Author : N.V.Sastry
Publisher : Narosa Publishing House
Edition/Year : 2 / 2005
Text Book- 3
Title of the book : Polymer chemistry
Name of the Author : Alka.l.Gupta
Publisher : Pragati Prakashan educational Publishers.
Edition/Year : 4 / 2015
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Unit-I (From Text Book - 1) Chapter – 1 (Page No 12-14)
Chapter – 2 (Page No 15-71)
Unit-II (From Text Book-1)
Chapter – 9 (Page No 215-257)
Unit-III (From Text Book-1&2)
Chapter – 3 (Page no 86 to 97)
Chapter – 6 (Page No150 to172)
Unit-IV (From Text Book-1& 3)
Chapter – 1 (Page no 61 to 67)
Chapter – 10 (Page no 263 to289)
Unit-V (From Text Book -2)
Chapter 4– (Page No.140 to 161)
Chapter 6– (Page No.238)
Reference Books
Reference Book-1
Title of the book : Text book of polymer science
Name of the Author : F.W.Billmeyer
Publisher : JohnWiley and sons,New York
Edition/Year : 3/1984
Reference Book-2
Title of the book : Text book of polymer chemistry
Name of the Author : B.K.Sharma
Publisher : Goel pub,House, Meerut.
Edition/Year : 1/1989
Reference Book-3
Title of the book : Text book of introductory polymer chemistry
Name of the Author : G.S.Mistra
Publisher : New Age International pub, New Delhi
Edition/Year : 1/2005
Prepared by : Ms. V. SOUNDARANAYAKI
Signature :
SRNMC Regulations-2018 Syllabus
83
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc .,Chemistry Subject Code : P18CHPT41
Semester : IV No. of Hours allotted: 10 / week
Subject : Paper XX No. of Credits : 4
Title of the Paper : PROJECT WORK AND VIVA-VOCE
Objectives:
To enable the students
To develop the ability of the students to prepare a project.
To get clear idea about the new concepts in our field apart from the syllabus.
REGULATIONS FOR THE PROJECT REPORT
Evaluation method for project:
Max. Marks Credits
Internal External
Project Evaluation 40 40
Viva Voce 20
Total 100 4
1. 50% of the aggregate (Project Evaluation + Viva Voce+ Internal)
2. No separate pass minimum for internal.
3. 27 marks out of 60 is the pass minimum for the External.
Internal examiners are the respective supervisors.
Viva voce examination to be evaluated by the external examiner.
The report of the project must be in the prescribed form. It should be typed neatly in
MS word. The font size of the letter should be 13 points with double space.
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The format of the project should have the following components.
First page should contain:
Title of the project report.
Name of the candidate
Register number.
Name of the supervisor.
Address of the institution
Month and year of submission.
1. Contents.
2. Declaration by candidate
3. Certificate by supervisor
4. Acknowledgement
5. Preface
6. Chapter 1 – Preliminaries.
7. Other chapters
8. References
The number of pages in the project may be 40 to 50
Each page should contain at least 18 lines.
Two copies of the project report should be submitted.
Prepared by : Ms. K. BUVANESWARI
Signature :
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SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2018-2019 and after)
SYLLABUS
Programme : M.Sc .,Chemistry Subject Code : P18CHX41
Semester : IV No. of Credits : 3
Subject : Paper XX
Title of the Paper : MODEL PAPER FOR NET/SET EXAMINATION- CHEMICAL
SCIENCES
Objectives:
To enable the students
to create an awareness of the NET/SET Examination
to make the students prepared for NET / SET Examinations
UNIT-I
i) Periodic properties – Atomic radius – ionic radius, ionization potential, electron
affinity and electronegativity – Their significance in chemical bonding.
ii) VB theory, MO theory – applications – Comparision of VB and MO theories –
VSEPR theory –Bond order – Bond energy – Bond length Bond polarity – Partial
ionic character of bonds – The conceptof multi-centre bond – Electron deficient
compounds – Hydrogen bond – Its influences.
iii) Non aqueous solvents – A general study of typical reactions in non aqueous
media – comparison with reactions in aqueous media.
iv) Nuclear – chemistry – Nuclear structure – Nuclear forces –Nuclear stability –
Nuclear modes – Modes of Radioactivity decay. Nuclear Reaction- fission and
fusion
v) Orgnometallic compounds – Metallecences – Arene complexes – Non aromatic
olefins and acetylenes complexes – catalysis by organometallic compounds
Wilkinson’s catalyst – Oxoprocess –wacker process – Ziegler – Natta catalysis.
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UNIT- II
i) Optical activity and concept of chirality – Different kinds of optically active
compounds – Absolute configuration - R and S Notations– Methods with more
than one chiral center – Asymmetric synthesis.
ii) Geometrical isomerism resulting from double bonds – The E.Z. system of
nomenclature –Geometrical isomerism of monocyclic compounds and fused ring
systems – Stereospecific and stereo selective reactions with examples.
iii) Organic reaction mechanisms – Aliphatic nucleophilic substituion SN1 and SN2
– stereo chemistry of nucleophilic reaction –Elimination reactions E1, E2, E1cB
Mechanism – dehydration of alcohols – dehydro halogenation – cope
elemination.
iv) Reagents in organic synthesis - DCC, DDQ ,selenium dioxide ,phase transfer
catalyst, LDA – Rearrangements:- Lossen, Schmitts, Baeyer – Villiger, Pinacol –
Pinacolene, Benzoil –Benzilic acid, Benzidine, Favorski and fries rearrangements
– sigmatropic rearragements – claisen and cope rearragements. Pericyclic
reactions, selection rules – orbital symmetry – Electrocyclic reactions – cyclic
additions - sigmatropic reactions.
UNIT-III
i) The old quantum theory – black body radiation – Photo electric effect –
Hydrogen spectrum – Compton effect- de Broglie equation – Heisenberg’s
uncertainty principle – Postulates of quantum mechanics – Schrödinger
equation – Operator algebra – Linear and Hermitian operators –Eigen
functions and Eigen values – Hamiltonian operators – Angular momentum.
ii) Symmetry elements and symmetry operations – Point groups – reducible and
irreducible representations, characters tables – Orthogonality theorem and its
consequences. Symmetry selection rule for IR and Raman spectra -
symmetries of normal modes of vibration – symmetry applied to MO theory
and orbital hybridization.
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iii) Thermodynamic equations of state – closed and open systems – partial molar
quantities –chemical potential with temperature and pressure – third law of
thermodynamics. Fugacity – methods of determination – activity and activity
co-efficient – Maxwell’s distribution of molecular velocities – derivation of
expression for average, most probable and root mean square velocities –
Microstates Macro states – partial functions – Sacker tetrode equation.
iv) Hammett acidity function –Acid base catalysis Bronsted relation- Enzyme
catalysis – Michaelis Menton Law – influence of PH and temperature. Surface
phenomenon – Heterogeneous catalysis – Adsorption isotherms.
v) Electrolytic conductance – applications – solubility product – Inter ionic
attraction theory – Debye- Huckel – Onsager equation – equivalent
conductivity of electrolytes. Electrode potentials – Electrochemical cells –
electrode – electrolyte interface – electrical double layer electro capillary
phenomena – electro kinetic Phenomena – Membrane potential – Polarisation
–Butler-Volmer equation.
UNIT-IV
i) UV Spectroscopy: Principle - absorption spectra of conjugated dienes – α,β -
unsaturated carbonyl compounds – Woodward- Fieser rules - Scott’s rules for
aromatic carbonyls.
ii) IR Spectroscopy: Molecular vibrations – vibrational frequency - factors
influencing group frequencies – quantitative studies.
iii) 1H NMR spectroscopy: Theory of NMR – chemical shift- factors affecting
chemical shift, spin-spin coupling – coupling constant – spin-spin splitting –
simplification of complex spectra –double resonance – lanthanide shift reagents,
chiral resolving reagents – nuclear overhauser effect – NMR concept of
aromaticity.
iv) Mossbauer Spectroscopy: Mossbauer effect- resonance absorption-Doppler effect-
Doppler velocity –isomer shift-magnetic hyperfine splitting-application of
Mossbauer spectroscopy in the study of iron and tin complexes.
v) ESR Spectroscopy: Principle –presentation of the spectrum –hyperfine splitting-
evaluation of g values –factors affecting the magnitude of g –values-Zero field
splitting –Kramer's degeneracy---application of ESR in the study of transition of
metal complex
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UNIT- V
i) Basic idea of nanoscience–Dimensional control in nano structures-,1D,2D and 3D
nano structures , synthesis of nano materials -chemical method, sol gel -Chemical
vapour deposition- Ball milling-plasma Arcing- electrodeposition- Thermolysis
ii) Carbon nanotubes: structure and characterization of single walled carbon nano
tubes-properties and applications of nano tubes.
iii) Nano polymers:Conductive polymer and Block copolymer.
iv) Twelve basic principles of green chemistry, green starting materials, green catalyst
and reagents -green solvents –applications of supercritical fluids, ionic liquids and
water – solvent free techniques- Non-conventional microwave heating - interaction
of microwave radiation with the material-difference between conventional heating
and microwave heating.
Text Book:1
Title of the book : Inorganic Chemistry.
Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,
Publisher : Harper Collins College Publishers
Edition/Year : 4/2006
Text book-2
Title of the book : Principles of Physical chemistry
Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania
Publication : Vishal publishing Co,New Delhi.
Edition/ year : 45 /2012
Text book-3
Title of the book : Reaction mechanism and reagents in organic chemistry
Name of the Author : G.R.Chatwal
Publisher : Himalaya publishing house,
Edition/Year : 5 / 2012
Text Book- 4
Title of the book : Elementary organic spectroscopy principles and
chemical applications Name of the Author : Y.R.Sharma
Publisher : S.Chand and company Ltd, New Delhi
Edition/Year : Reprint / 2012
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Reference Book:1
CSIR-UGC NET/JRF/SET Chemical sciences - Hemant Kulshrestha, Ajay Taneja,
2010,Upkar’s Publication.
Reference Book:2
CSIR-UGC NET/JRF/SET Chemical sciences - Helder, Trueman’s Specific series(2012)
Prepared by : Ms. K. BUVANESWARI
Signature :
CHAIRMAN DEAN