23

30 m, 0.32 mm ID, 0.32 µm (P/N: 221-75887-30 )

30 m, 0.25 mm ID, 0.25 µm (P/N: 227-36043-01 )

環境　Environmental

有機リン系農薬分析 Organophosphorous Pesticides　SH-Rtx™-OPP2

ConditionsColumns: SH-Rtx™-OPP2, 30 m, 0.32 mm ID, 0.32 μm (P/N: 221-75887-30)Inj. Vol.: 1 µL splitless (hold 1 min)Inj. Temp: 200 °COven Temp: 80 °C (hold 0.5 min) to 280 °C at 12 °C/min (hold 10 min)

Peaks1. Dichlorvos2. Hexamethylphosphoramide3. Mevinphos4. Trichlorfon5. TEPP6. Demeton-O7. Tributyl phosphate (SS)8. Thionazin9. Ethoprop

10. Naled11. Sulfotepp12. Phorate13. Dicrotophos14. Monocrotophos15. Demeton-S16. Terbufos17. Dimethoate18. Diazinon19. Dioxathion20. Fonophos21. Disulfoton22. Phosphamidon isomer　 (breakdown product)23. Dichlorofenthion24. Phosphamidon25. Chlorpyrifos methyl26. Methyl parathion27. Ronnel

EV04

EV05

28. Aspon29. Fenitrothion30. Malathion31. Chlorpyrifos32. Trichloronate33. Parathion-ethyl34. Fenthion35. Merphos36. Chlorfenvinphos37. Crotoxyphos38. Stirofos39. Prothiofos40. Merphos oxone　 (breakdown product)41. Ethion42. Fensulfothion43. Sulprofos44. Carbophenothion45. Famphur46. Triphenyl phosphate (SS)47. EPN48. Phosmet49. Leptophos50. Tri-o-cresyl phosphate51. Azinphos-methyl52. Azinphos-ethyl53. Coumaphos

Carrier Gas: HeDead Time: 1.03 min at 80 °CDetector: FPD, 250 °CNotes: Constant pressure

PCB同族体 PCB Congeners　SH-Rxi™-XLB

Peaks 1. PCB 31 2. PCB 28 3. PCB 52 4. PCB 101 5. PCB 118 6. PCB 153 7. PCB 138 8. PCB 180 9. PCB 194

ConditionsColumn: SH-Rxi™-XLB, 30 m, 0.25 mm ID, 0.25 μm

(P/N: 227-36043-01)Sample: PCB congener standard

Diluent: DichloromethaneConc.: 3.5 ppm

Inj. Vol.: 0.5 μL splitless (hold 1.75 min)Inj. Temp: 300 °CPurge Flow: 50 mL/min

Oven Temp: 40 °C (hold 2 min) to 240 °C at 30 °C/min (hold 2 min) to 340 °C at 10 °C/min (hold 5 min)

Carrier Gas: He, constant fl ow rate 1 mL/minDetector: MS-QP

Transfer Line Temp: 300 °CSource Temp: 280 °CIonization: EIScan Range: 45-550

農薬分析 Pesticides　SH-Rxi™-5MS30 m, 0.25 mm ID, 0.25 µm (P/N: 221-75940-30 )

環境　Environmental

Peaks1. Chloroneb2. Pentachlorobenzene3. alpha-BHC4. Hexachlorobenzene5. Pentachloroanisole6. beta-BHC7. gamma-BHC (Lindane)8. delta-BHC9. Endosulfan ether

10. Heptachlor11. Pentachlorothioanisole12. Aldrin13. 4,4'-Dichlorobenzophenone14. Fenson15. Isodrin16. Heptachlor epoxide (Isomer B)17. Chlorbenside18. trans-Chlordane19. 2,4'-DDE20. Endosulfan I

21. cis-Chlordane22. trans-Nonachlor23. Chlorfenson (Ovex)24. 4,4'-DDE25. Dieldrin26. 2,4'-DDD27. Endrin28. Ethylan (Perthane)29. Endosulfan II30. 4,4'-DDD31. 2,4'-DDT32. cis-Nonachlor33. Endrin aldehyde34. 4,4'-Methoxychlor olefi n35. Endosulfan sulfate36. 4,4'-DDT37. 2,4'-Methoxychlor38. Endrin ketone39. Tetradifon40. Mirex

ConditionsColumn: SH-Rxi™-5MS, 30 m, 0.25 mm ID, 0.25 μm

(P/N: 221-75940-30)Inj. Vol.: 1 µL split (split ratio 50:1)Inj. Temp: 250 °COven Temp: 90 °C (hold 1 min) to 330 °C at

8.5 °C/min (hold 5 min)Carrier Gas: He, constant fl ow rate 1.4 mL/minDetector: MS-QP

Transfer Line Temp: 290 °CSource Temp: 325 °CSolvent Delay Time: 5 minIonization: EI

EV02

EV03 有機塩素系農薬分析 Organophosphorus Pesticides　SH-Rtx™-CLP / SH-Rtx™-CLPⅡ

Peaks1. 2,4,5,6-tetrachloro-m-xylene2. α-BHC (α-HCH)3. γ-BHC (lindane)4. β-BHC (β-HCH)5. δ-BHC (δ-HCH)6. heptachlor7. aldrin8. heptachlor epoxide9. γ-chlordane

10. α-chlordane11. 4,4'-DDE12. endosulfan I13. dieldrin14. endrin15. 4,4'-DDD

16. endosulfan II17. 4,4'-DDT18. endrin aldehyde19. methoxychlor20. endosulfan sulfate21. endrin ketone22. decachlorobiphenyl

ConditionsColumn: SH-Rtx™-CLP, 30 m, 0.32 mm ID, 0.50 μm SH-Rtx™-CLPⅡ, 30 m, 0.32 mm ID, 0.25 μm

)10-76263-722:N/P()03-97857-122:N/P(Oven Temp: 120 °C (hold 1 min) to 300 °C (hold 10 min) at 9 °C/minInj.: DirectInj. Temp: 200 °CDetector: ECD, 300 °C with anode purgeDead time: 1.9 minHead pressure: 8.7 psi (constant)Flow rate: 1.3 mL/min at 120 °C, He

30 m, 0.32 mm ID, 0.50 µm (P/N: 221-75879-30 ) , 30m, 0.32mm ID, 0.25µm, (P/N:227-36267-01)