Welcome to 3.091 Lecture 23 November 5, 2004
catalytic converters for automobiles
x
º H2O, CO2
º CO2
* NOx º N2, O2, CO2
* Rh for NOx
why unleaded gasoline?
* (C2H5)4
function: 3-way catalyst promoting conversion of HCs, CO, and NO
* hydrocarbons * CO
GM tried over 1500 catalyst formulations before settling on the present combination:
* Pt-Pd for hydrocarbons and CO
Pb (tetraethyl lead) burns to produce PbO * PbO is volatile and on the catalyst will decompose to Pb * Pb alloys with precious metals poisoning them