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Welcome to 3.091 Lecture 23 November 5, 2004
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Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile

Mar 16, 2020

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Page 1: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile

Welcome to 3.091 Lecture 23

November 5, 2004

Page 2: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile
Page 3: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile
Page 4: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile
Page 5: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile
Page 6: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile
Page 7: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile
Page 8: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile
Page 9: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile

diffusion in molten

ferrous alloys

Page 10: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile

helium ingress into various oxide glasses

Page 11: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile

helium ingress into various oxide glasses

Page 12: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile

same glass different gases

Page 13: Welcome to 3 · 2019-09-13 · Welcome to 3.091 Lecture 23 November 5, 2004 . diffusion in molten ferrous alloys . helium ingress into various oxide glasses . ... * PbO is volatile

catalytic converters for automobiles

x

º H2O, CO2

º CO2

* NOx º N2, O2, CO2

* Rh for NOx

why unleaded gasoline?

* (C2H5)4

function: 3-way catalyst promoting conversion of HCs, CO, and NO

* hydrocarbons * CO

GM tried over 1500 catalyst formulations before settling on the present combination:

* Pt-Pd for hydrocarbons and CO

Pb (tetraethyl lead) burns to produce PbO * PbO is volatile and on the catalyst will decompose to Pb * Pb alloys with precious metals poisoning them