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To Our Valued Customer During the past few years we have been asked many a time to respond to customers questionnaires, quality forms, and other related requests for information. In time we had collected a large number of these requests and responded in kind. As our business has evolved the process to assimilate and respond to these questionnaires has become tedious. As a course of action to help recover the cost associated with this, we began requiring our customers to pay for such requests. Regarding that business action, we took it upon ourselves to help and respond with a detailed packet of information that we have found to be asked most frequently. Our hope is that this package of information answers all of your company’s needs. As a supplier of Dry Ice, we want to continue on focusing on our customers utilization of our products better. When we are requested to respond to the information requests, it unavoidable removes our staff from the manufacturing and quality process. We respectfully request that the detailed amount of information enclosed satisfy any of your internal needs. If they do not and there are additional requests required, please be aware there is a fee associated for gathering them. Thank you for your understanding in this matter. Continental will continue adding more data as we see fit. As always, thank for your business. Very truly yours, Mark M Weir Vice President
29

Table of Contents - Continental Carbonic

Feb 09, 2022

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Page 1: Table of Contents - Continental Carbonic

To Our Valued Customer During the past few years we have been asked many a time to respond to customers questionnaires, quality forms, and other related requests for information. In time we had collected a large number of these requests and responded in kind. As our business has evolved the process to assimilate and respond to these questionnaires has become tedious. As a course of action to help recover the cost associated with this, we began requiring our customers to pay for such requests. Regarding that business action, we took it upon ourselves to help and respond with a detailed packet of information that we have found to be asked most frequently. Our hope is that this package of information answers all of your company’s needs. As a supplier of Dry Ice, we want to continue on focusing on our customers utilization of our products better. When we are requested to respond to the information requests, it unavoidable removes our staff from the manufacturing and quality process. We respectfully request that the detailed amount of information enclosed satisfy any of your internal needs. If they do not and there are additional requests required, please be aware there is a fee associated for gathering them. Thank you for your understanding in this matter. Continental will continue adding more data as we see fit. As always, thank for your business. Very truly yours,

Mark M Weir Vice President

Page 2: Table of Contents - Continental Carbonic

Table of Contents: Certificate of Conformance (Carbon Dioxide, Solid / Dry Ice) Continuing Letter of Guarantee for Block Dry Ice Product Continuing Letter of Guarantee for Pelletized Dry Ice Product W9 Information SDS – Carbon Dioxide, Solid / Dry Ice Safe Handling of Dry Ice CUSMA / USMCA / T-MEC Certification of Origin Dry Ice Technical Specifications Typical Frequently Asked Quality Questions Ingredient Criteria Questionnaire Lot Code Explanation

Page 3: Table of Contents - Continental Carbonic

ANNUAL CERTIFICATE OF CONFORMANCE

Food Grade Carbon Dioxide

This certifies that all product labeled as Food Grade Carbon Dioxide provided by Continental Carbonic

Products, Inc. meets or exceeds the Compressed Gas Association’s (“CGA”) G-6.2 Quality Verification

Level H specifications for Food Grade Carbon Dioxide as outlined in the table below.

CHARACTERISTIC CGA G-6.2 QVL H

FOOD

Identification -

Carbon Dioxide (min) 99.5%

Acetaldehyde 0.5 ppm

Carbon Monoxide 10 ppm

Carbonyl Sulfide 0.5 ppm

Nitric Oxide 5 ppm

Oxygen 50 ppm

Sulfur Dioxide 5 ppm

Total Sulfur 0.5 ppm

Total Hydrocarbon Content (as methane)

50 ppm

Hydrogen Sulfide 0.5 ppm

Nonvolatile Residues 10 ppm

Odor/Taste a

Water 20 ppm

a Free of Foreign Odor or Taste

CERTIFIED BY: Andrew Gregory, VP Production DATE: 01-01-21This annual certificate is good for a period of one (1) year.

Page 4: Table of Contents - Continental Carbonic

To whom it may concern:

The pelletized dry ice our company produces is made with food grade liquid carbon

dioxide with no additives. Dry ice is considered Generally Recognized as Safe (GRAS)

by the FDA under FDA 21CFR184.1240. Continental Carbonic meets or exceeds federal

requirements set forth under the U.S. FDA 21CFR184.1240 Carbon Dioxide and the

FDA Food Safety Modernization Act (FSMA), specifically 21CFR117. Continental

Carbonic supports our food safety program through the utilization of a Food Safety Plan,

supporting pre-requisite programs and annual 3rd party GFSI based audits. Primary

elements of the Food Safety Management System include the following:

Prerequisite Programs: Documented prerequisite programs covering material receiving,

pest control, food defense, sanitation, and safe product handling during production,

storage and distribution.

Recall & Traceability: Procedures for the effective retrieval of product including

contact information for responsible parties, requirements for tracing ingredients,

packaging and finished product one-step forward and one-step back.

Allergen Control: Allergens are not present in the manufacturing/processing of dry ice.

An awareness program addressing regulated allergens and ingredients is maintained to

address personnel practices and housekeeping.

The finished liquid carbon dioxide produced by our company and used to produce our

food grade dry ice is tested using specifications and procedures established by the

Compressed Gas Association (CGA) in its Commodity Specification for Carbon Dioxide

CGA G-6.2—2011.

This letter will serve as the Continuing Letter of Guarantee for all pelletized dry ice

unless otherwise notified by supplier, effective January 1, 2021 through December 31,

2021.

Very truly yours,

Andrew Gregory

Vice President, Production

AG/pss

Page 5: Table of Contents - Continental Carbonic

To whom it may concern:

The Undersigned Continental Carbonic Products, Inc. (Seller) hereby represents that the

production process Seller uses in the production of dry ice produces dry ice that as of the

date of shipment the product is not adulterated or misbranded within the meaning of the

Federal Food, Drug and Cosmetic Act, and not an article which may not, under the

provisions of Section 404 or 405 of the Act, be introduced into interstate commerce.

The undersigned further represents that said dry ice is produced in such a manner that it is

not in violation of or adulterated or misbranded within the meaning of any State or

Municipal Act, the provisions which are identical or substantially the same as those in

federal act referenced above.

We certify only that any solid carbon dioxide (dry ice block) supplied which is

represented as containing no additives other than a food grade binding agent does not, to

the best of our knowledge and belief, contain any additive other than the food grade

binding agent, and that any solid carbon dioxide (dry ice block) so represented shall only

be of standard commercial quality.

SELLER MAKES NO WARRANTIES OR GUARANTEES, EXPRESS OR

IMPLIED, EXCEPT AS EXPRESSLY STATED HEREIN. SELLER DOES NOT

WARRANT OR GUARANTEE THAT THE DRY ICE SOLD IS FIT FOR ANY

PARTICULAR PURPOSE OR IS MERCHANTABLE.

This letter shall serve as an annual Continuing Letter of Guarantee for all dry ice block

unless notified by supplier effective January 1, 2021 through December 31, 2021.

This is a continuing representation and is subject to revocation upon receipt of written

notice thereof.

Sincerely,

Andrew Gregory

Vice President, Production

AG/pss

Page 6: Table of Contents - Continental Carbonic

Please find enclosed our W9. Please see our contact information below.

CORPORATE OFFICE: Continental Carbonic Products, Inc. 3985 E. Harrison Avenue Decatur, IL 62526 800-DRYICE2

REMIT TO ADDRESS: Continental Carbonic Products, Inc. DEPT 3833 PO Box 123833 Dallas, TX 75312-3833 Email: [email protected]

Please visit our website for a complete list of all of our locations: www.continentalcarbonic.com

Page 7: Table of Contents - Continental Carbonic
Page 8: Table of Contents - Continental Carbonic

Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557

Page 1 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14

Material Name

Carbon Dioxide, Solid

Synonyms

DRY ICE; Gas ID 2187

Product Use

Industrial uses.

Restrictions on Use

None known.

Details of the supplier of the safety data sheet

Continental Carbonic Products, Inc.

3985 East Harrison Avenue

Decatur, IL 62526

Phone: 217-428-2068

Emergency Phone #: Outside the US: 703-527-3887 (Call collect)

Fax: 1-800-424-9300 (CHEMTREC)

Classification in accordance with paragraph (d) of 29 CFR 1910.1200.

Simple Asphyxiant

GHS Label Elements

Symbol(s)

None needed according to classification criteria.

Signal Word

Warning

Hazard Statement(s)

May displace oxygen and cause rapid suffocation.

Precautionary Statement(s)

Prevention

None needed according to classification criteria.

Response

None needed according to classification criteria.

Storage

None needed according to classification criteria.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.

Other Hazards

May cause asphyxia. May cause frostbite.

CAS Component Name Percent

124-38-9 Carbon dioxide, solid 100

Section 1 - PRODUCT AND COMPANY IDENTIFICATION

Section 2 - HAZARDS IDENTIFICATION

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

Section 4 - FIRST AID MEASURES

Page 9: Table of Contents - Continental Carbonic

Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557

Page 2 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14

Inhalation

Remove person to fresh air and keep comfortable for breathing. If breathing is difficult, oxygen should be

administered by qualified personnel. If breathing has stopped, start artificial respiration at once. Get medical

attention.

Skin

If frostbite or freezing occur, immediately flush with plenty of lukewarm water (105-115°F; 41-46°C). DO NOT

USE HOT WATER. If warm water is not available, gently wrap affected parts in blankets. Get immediate medical

attention.

Eyes

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

Ingestion

If swallowed, get medical attention.

Most Important Symptoms/Effects

Acute

May cause cryogenic burns, suffocation, frostbite

Delayed

no information on significant adverse effects.

Indication of any immediate medical attention and special treatment needed

For inhalation, consider oxygen.

Extinguishing Media

Suitable Extinguishing Media

Use extinguishing agents appropriate for surrounding fire.

Unsuitable Extinguishing Media

None known.

Special Hazards Arising from the Chemical

Negligible fire hazard.

Hazardous Combustion Products

Oxides of carbon

Fire Fighting Measures

Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire

is out. Use extinguishing agents appropriate for surrounding fire. Evacuation radius: 800 meters (1/2 mile). Avoid

inhalation of material or combustion by-products. Stay upwind and keep out of low areas.

Special Protective Equipment and Precautions for Firefighters

Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against

possible exposure.

Personal Precautions, Protective Equipment and Emergency Procedures

Wear personal protective clothing and equipment, see Section 8.

Methods and Materials for Containment and Cleaning Up

Do not touch spilled material. Stop leak if possible without personal risk. Keep unnecessary people away, isolate

hazard area and deny entry. Ventilate closed spaces before entering. Collect spilled material in appropriate container

for disposal.

Environmental Precautions

Avoid release to the environment. Avoid release to the environment.

Section 5 - FIRE FIGHTING MEASURES

Section 6 - ACCIDENTAL RELEASE MEASURES

Section 7 - HANDLING AND STORAGE

Page 10: Table of Contents - Continental Carbonic

Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557

Page 3 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14

Precautions for Safe Handling

Avoid breathing dust, mist, fumes or vapors. Use only outdoors or in a well-ventilated area. Wear cold insulating

gloves/face shield/eye protection. Wash hands thoroughly after handling.

Conditions for Safe Storage, Including any Incompatibilities

None needed according to classification criteria.

Store in accordance with all current regulations and standards. Store in a well-ventilated area. Keep container tightly

closed. Keep locked up. Keep away from incompatible materials.

Incompatible Materials

combustible materials, oxidizing materials, metal salts, reducing agents, metal carbide, metals, bases

Component Exposure Limits

Carbon dioxide, solid 124-38-9

ACGIH: 5000 ppm TWA

30000 ppm STEL

NIOSH: 5000 ppm TWA ; 9000 mg/m3 TWA

30000 ppm STEL ; 54000 mg/m3 STEL

40000 ppm IDLH

Europe: 5000 ppm TWA ; 9000 mg/m3 TWA

OSHA (US): 5000 ppm TWA ; 9000 mg/m3 TWA

Mexico: 5000 ppm TWA VLE-PPT ; 9000 mg/m3 TWA VLE-PPT

15000 ppm STEL [PPT-CT ]; 27000 mg/m3 STEL [PPT-CT ]

ACGIH - Threshold Limit Values - Biological Exposure Indices (BEI)

There are no biological limit values for any of this product's components.

Engineering Controls

Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.

Individual Protection Measures, such as Personal Protective Equipment

Eye/face protection

Wear splash resistant safety goggles with a faceshield. Contact lenses should not be worn. Provide an emergency

eye wash fountain and quick drench shower in the immediate work area.

Skin Protection

Wear appropriate protective, cold insulating clothing.

Respiratory Protection

The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. 40,000 ppm.

Any supplied-air respirator. Any self-contained breathing apparatus with a full facepiece. Emergency or planned

entry into unknown concentrations or IDLH conditions -. Any self-contained breathing apparatus that has a full

facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a

full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an

auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape -.

Any appropriate escape-type, self-contained breathing apparatus.

Glove Recommendations

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Page 11: Table of Contents - Continental Carbonic

Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557

Page 4 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14

Wear insulated gloves.

Appearance white flakes Physical State solid

Odor Not available Color white

Odor Threshold 0.14 ppm (Recognition

Arsine )

pH

Not available

Melting Point -70 °C (-94 °F ) Boiling Point -79 °C (-110 °F )

Boiling Point Range Not available Freezing point Not available

Evaporation Rate Not available Flammability (solid, gas) Not available

Autoignition

Temperature

Not available

Flash Point

(Not flammable )

Lower Explosive

Limit

Not available

Decomposition temperature

Not available

Upper Explosive

Limit

Not available

Vapor Pressure

569 mmHg @ -82 °C

Vapor Density

(air=1)

1.5

Specific Gravity (water=1)

1.56 at -79 °C

Water Solubility

1.6 % Partition coefficient: n-

octanol/water

Not available

Viscosity Not available Kinematic viscosity Not available

Solubility (Other) Not available Density 1.4 to 1.6 g/cm3

Physical Form

flakes

Sublimation -78.5 °C (-109 °F

Atmospheric pressure )

Molecular Formula CO2 Molecular Weight 44.01

Solvent Solubility

Soluble

Hydrocarbons, organic solvents

Reactivity

No reactivity hazard is expected.

Chemical Stability

Stable at normal temperatures and pressure.

Possibility of Hazardous Reactions

Will not polymerize.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Section 10 - STABILITY AND REACTIVITY

Page 12: Table of Contents - Continental Carbonic

Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557

Page 5 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14

Conditions to Avoid

Protect from physical damage and heat. Containers may rupture or explode if exposed to heat. Avoid contact with

water or moisture.

Incompatible Materials

combustible materials, oxidizing materials, metal salts, reducing agents, metal carbide, metals, bases

Hazardous decomposition products

Oxides of carbon

Information on Likely Routes of Exposure

Inhalation

ringing in the ears, nausea, irregular heartbeat, headache, drowsiness, dizziness, loss of coordination, tingling

sensation, visual disturbances, suffocation, convulsions, coma

Skin Contact

blisters, frostbite

Eye Contact

irritation, blurred vision, frostbite

Ingestion

frostbite

Acute and Chronic Toxicity

Component Analysis - LD50/LC50

The components of this material have been reviewed in various sources and no selected endpoints have been

identified.

Product Toxicity Data

Acute Toxicity Estimate

No data available.

Immediate Effects

May cause cryogenic burns, suffocation, frostbite

Delayed Effects

no information on significant adverse effects.

Irritation/Corrosivity Data

May cause cryogenic burns.

Respiratory Sensitization

No data available.

Dermal Sensitization

No data available.

Component Carcinogenicity

None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA

Germ Cell Mutagenicity

No data available.

Tumorigenic Data

No data available

Reproductive Toxicity

No data available.

Specific Target Organ Toxicity - Single Exposure

No target organs identified.

Specific Target Organ Toxicity - Repeated Exposure

No target organs identified.

Aspiration hazard

No data available.

Medical Conditions Aggravated by Exposure

Section 11 - TOXICOLOGICAL INFORMATION

Page 13: Table of Contents - Continental Carbonic

Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557

Page 6 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14

None known.

Component Analysis - Aquatic Toxicity

No LOLI ecotoxicity data are available for this product's components.

Persistence and Degradability

No data available.

Bioaccumulative Potential

No data available.

Mobility

No data available.

Disposal Methods

Dispose in accordance with all applicable regulations.

Component Waste Numbers

The U.S. EPA has not published waste numbers for this product's components.

US DOT Information:

Further information: Not regulated as a hazardous material when transported by highway. (Regulated when

transported by aircraft or vessel. )

IMDG Information:

Shipping Name: CARBON DIOXIDE, SOLID

Hazard Class: 9

UN#: UN1845

Required Label(s): 9

International Bulk Chemical Code

This material does not contain any chemicals required by the IBC Code to be identified as dangerous chemicals in

bulk.

U.S. Federal Regulations

None of this products components are listed under SARA Sections 302/304 (40 CFR 355 Appendix A), SARA

Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan.

SARA Section 311/312 (40 CFR 370 Subparts B and C) reporting categories

Simple Asphyxiant

U.S. State Regulations

The following components appear on one or more of the following state hazardous substances lists:

Component CAS CA MA MN NJ PA

Carbon dioxide, solid 124-38-9 Yes Yes Yes Yes Yes

Not listed under California Proposition 65

Canada Regulations

Canadian WHMIS Ingredient Disclosure List (IDL)

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS

Section 14 - TRANSPORT INFORMATION

Section 15 - REGULATORY INFORMATION

Page 14: Table of Contents - Continental Carbonic

Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557

Page 7 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List

is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS

criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL

Carbon dioxide, solid 124-38-9

1 %

Component Analysis - Inventory

Carbon dioxide, solid (124-38-9)

US

CA

EU

AU

PH

JP -

ENCS

JP -

ISHL

KR

KECI -

Annex

1

KR

KECI -

Annex

2

KR -

REACH

CCA

CN

NZ

MX

TW

VN -

NCI

(Draft)

Yes DSL EIN Yes Yes Yes Yes Yes No No Yes Yes Yes Yes Yes

NFPA Ratings

Health: 2 Fire: 0 Reactivity: 0 Other: SA

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe

Summary of Changes

Updated: 02/03/2017

Key / Legend

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU -

Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CA/MA/MN/NJ/PA -

California/Massachusetts/Minnesota/New Jersey/Pennsylvania*; CAS - Chemical Abstracts Service; CERCLA -

Comprehensive Environmental Response, Compensation, and Liability Act; CFR - Code of Federal Regulations

(US); CLP - Classification, Labelling, and Packaging; CN - China; CPR - Controlled Products Regulations; DFG -

Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSD - Dangerous Substance Directive;

DSL - Domestic Substances List; EC – European Commission; EEC - European Economic Community; EIN -

European Inventory of (Existing Commercial Chemical Substances); EINECS - European Inventory of Existing

Commercial Chemical Substances; ENCS - Japan Existing and New Chemical Substance Inventory; EPA -

Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research

on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL -

Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime

Dangerous Goods; ISHL - Japan Industrial Safety and Health Law; IUCLID - International Uniform Chemical

Information Database; JP - Japan; Kow - Octanol/water partition coefficient; KR KECI Annex 1 - Korea Existing

Chemicals Inventory (KECI) / Korea Existing Chemicals List (KECL); KR KECI Annex 2 - Korea Existing

Chemicals Inventory (KECI) / Korea Existing Chemicals List (KECL) , KR - Korea; LD50/LC50 - Lethal Dose/

Lethal Concentration; LEL - Lower Explosive Limit; LLV - Level Limit Value; LOLI - List Of LIsts™ -

ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL -

Maximum Exposure Limits; MX – Mexico; NDSL – Non-Domestic Substance List (Canada); NFPA - National Fire

Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade

Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health

Administration; PEL- Permissible Exposure Limit; PH - Philippines; RCRA - Resource Conservation and Recovery

Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID - European Rail Transport;

SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TCCA – Korea

Toxic Chemicals Control Act; TDG - Transportation of Dangerous Goods; TLV - Threshold Limit Value; TSCA -

Toxic Substances Control Act; TW – Taiwan; TWA - Time Weighted Average; UEL - Upper Explosive Limit;

Section 16 - OTHER INFORMATION

Page 15: Table of Contents - Continental Carbonic

Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557

Page 8 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14

UN/NA - United Nations /North American; US - United States; VLE - Exposure Limit Value (Mexico); VN NCI

(Draft) - Vietnam National Chemicals Inventory (NCI) (Draft); WHMIS - Workplace Hazardous Materials

Information System (Canada) .

Other Information

Disclaimer:

Continental Carbonic Products, Inc. makes no express or implied warranties, guarantees or representations regarding

the product or the information herein, including but not limited to any implied warranty or merchantability or fitness

for use. Continental Carbonic Products, Inc. shall not be liable for any personal injury, property or other damages of

any nature, whether compensatory, consequential, exemplary, or otherwise, resulting from any publication, use or

reliance upon the information herein.

Page 16: Table of Contents - Continental Carbonic

intentional misuse of dry ice may be harmful or fatal.

DRY ICE SAFETY Safe Handling of dry ice

COULD CAUSE SUFFOCATIONDry ice changes to CO2 gas as it sublimates, causing a lack of oxygen. Only use dry ice in open or well-ventilated areas. Do not store in confined spaces such as vehicles or garages and never store near an area where people sleep as suffocation could occur.

DO NOT TOUCHDry ice is a skin and eye irritant. Avoid contact with skin, mouth, eyes and clothing. Dry ice will cause severe burns.

DO NOT EATDry ice is harmful if eaten or swallowed. If ingested, seek medical help immediately.

DO NOT PLACE IN AIRTIGHT CONTAINERSAirtight containers may explode as dry ice converts to CO2 gas.

ive in Excellence In Dry Ice C

CONTINENTAL~ CARBONIC 0

products, inc.

Page 17: Table of Contents - Continental Carbonic

WffiwNw". Internatisnal

CUSMA / USMCA IT.MECCertification of Origin

1. Exporter: (Name, Address, Country, Phone, & Email) 2. Blanket Period (Cannot exceed 12 months)

p7sm. 07101120(Mrv/DDt/Y)

To: 06130121(MM/DDft'Y)

3. Producer: (Name, Address, Country, Phone, & Email)

Continental Carbonic Products, Inc.3985 E. Harrison AveDecatur. lL 62526

4. lmporter: (Name, Address, Country, Phone, & Email)

5. Description of Good(s): Including item, part, or SKUidentification numbers, where applicable, and must tie to thedescriotion in commercial invoice.

6. HS Tariff ClassificationNumber(s) (min.6 digits)

7. OriginCriterion

8. Country of Origin

Solid Carbon Dioxide (Dry lce) 2811.21.00.00 4.2@) US

9. I CERTTFY THAT: The goods described in this document qualify as originating and the information contained in this document istrue and accurate. I assume responsibility for proving such representations and agree to maintain and present upon request or tomake available during a verification visit, documentation necessary to support this certification.

This certification consists of 1 p"q"t, includinq allattachments.

9a. Authorized Signature*:

9b. Name and Title: Lennis Hollenbeck, Controller

ec. Phone: 217 -428-2068 Fax: Email:

9d. Certifier is the: Exnorter S eroducer Q lmoorter QDate:

(rvrvr/DDr/Y)

*This certification of origin must be completed following the instructions then signed and dated by the Ceftifier.

April2o2o rtrr - 49 Avenue N.E., Catgary, Alberta, Canada TzE 8Vz Phone:403-262-277rFaxi 403-262-730l

06/30/2020

Page 18: Table of Contents - Continental Carbonic

Dry Ice Technical Specifications

Physical properties

Property Value

Formula CO2

Molecular Weight 44.01

Appearance Colorless, odorless gas; colorless liquid, or white opaque solid (dry ice)

Density Solid (Dry Ice) 97.5189 lb./ft.3 at -109.3° F

Density Liquid 63.69 lb./ft.3 at 0° F

Density Gas 0.1234 lb./ft.3 at 32° F

Melting Point -69.9° F, 75.1 PSIA

Boiling Point -109.3° F (Sublimes)

Triple Point -69.9° F, 75.1 PSIA

Critical Temperature 87.8° F

Critical Pressure 1069.4 PSIA

Critical Density 28.9519 lb./ft.3

Specific Heat Gas 0.1989 BTU/lb. ° F (60° F)

Specific Heat Liquid 0.53 BTU/lb. ° F (0° F)

Ratio of Heat Capacities 1.3

Latent Heat of Fusion (Triple Point) 85 BTU/lb. (69.9° F)

Latent Heat of Vaporization (Liquiflow)

122 BTU/lb. (0° F)

Latent Heat of Sublimation (Dry Ice) 246 BTU/lb. (-110° F)

Viscosity Gas 0.015 Centipoises (32° F)

Viscosity Liquid 0.14 Centipoises (0° F)

Thermal Conductivity Gas 0.0085 BTU ft./ft.2 ° F Hr. (32° F)

Thermal Conductivity Liquid 0.11 BTU ft./ft.2 ° F Hr. (0° F)

Surface Tension (Liquid) 8.23 Dynes/cm (0° F)

Solubility in H2O 1.79 ft.3 CO2 Gas/ft.3 H2O(32° F)

May 2020

Page 19: Table of Contents - Continental Carbonic

Typical Frequently Asked Quality Questions Product: Carbon Dioxide (Dry Ice) Company Information Company Name Continental Carbonic Products, INC Address 3985 E. Harrison Avenue City Decatur State IL ZIP 62526

Quality Assurance & Recall Contact Contact Name Mr. Ben Centers Title Quality and Safety Specialists Office Phone 937-316-6160 Email [email protected]

FDA REGISTRATION #: 12717876044 Quality System Does your facility currently have a FSMA Compliant Preventive Controls Program in place and that is fully implemented? Yes If yes, has the program been reviewed or updated within the past 12 months? Yes Global Food Safety Initiative (GFSI) Certification: Does your facility have current GFSI Certification? No We follow the guidelines for GFSI, please refer to Continuing Letter of Guarantee. Product Recall: Have you had to recall a product within the last five years? No Do you have Mock Recall program in place? Yes Do you have a documented Quality System in place? Yes

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Good Manufacturing Practices Does your company have a written GMP policy in place? Yes Our Employees are retrained annually, contractors and visitors are to complete upon arrival. Are there hand wash sinks that are easily accessible from each workstation? Yes Sanitation/ Pest Control Is there a Master Sanitation Schedule in place? Yes All areas of the facility are maintained and records are kept by plant personnel. What methods are used to verify the effectiveness of the cleaning processes that are in place and how often is this done (ex. ATP swabs, protein swabs, etc.)? ATP Swabbing, Routinely Is there a pest control program present at your facility? Yes We contract this service out and it is done monthly. Water Please describe the source of water for the plant (i.e. well, city): Our facilities utilize city water. We test our water source annually for physical, chemical and microbiological contaminants. Any problems occurred in the last two years in regards to your water source? No Transportation of Ingredients, Products and Packaging Is there a documented shipping and receiving program in place to ensure the integrity and food safety of all transportation vehicles? Yes Are tamper evident seals being applied and documented on the Bill of Lading by a company employee on all shipments leaving your facility? Yes for Pellet type customers Do you document incoming raw material inspection, including lot # and expiration date? No

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Product Labeling Does your company have a program in place to ensure that any changes to product processes or formulation are reflected on product labels are appropriate? N/A

Does your facility possess the necessary Kosher documents for the Kosher and product produced at your facilities? N/A Does your facility possess the necessary Halal documents or certificate for the product produced at your facilities? N/A If your facility produces Non-GMO product, do you have up-to-date documents that meet Non-GMO? N/A If your facility produces a gluten-free product, do you have the necessary documents? We do not produce a gluten-free product Do you conduct finished product gluten testing and if so, what are your limits (must guarantee product to be < 20 ppm)? Our product is not edible

We do not produce non-vegan food. Does your facility conduct animal testing with your products? No

Are any ingredients or processing aids from animal or insect origin (i.e. bone char, carmine, castoreum, gelatin, etc.) used when making your product? This includes raw materials and processing aids from your supplier(s). No

Does your product contain artificial ingredients, colors, or flavors? No Does your product contain natural flavors/spices? No Does your product contain maltodextrin? No

Do any of the ingredients in your product(s) contain the following or derivatives of the following: Black Pepper, Alliums (i.e. onions, leeks, garlic, etc.), potato, corn, Solanaceae (i.e. tomatoes, peppers, potatoes, eggplants, etc.), cilantro, corn (or corn derivatives), coriander, cumin, ginger, rosemary, MSG, or anise? No

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Food Allergens Does your company have an allergen control program in place? Yes How often is this reviewed and updated? Annually Does your facility have a dedicated system for products that contain allergens? N/A, please refer to Continuing Letter of Guarantee Does your facility use separate scheduling and sanitation as a way to manage products containing an allergen? No Does your facility have documentation of allergen cleaning procedures that explain how to clean allergen effected equipment and visually inspect it for cleanliness? No Is the allergen-cleaning program validated for effectiveness? No Is a dual sign-off required on allergen cleaning documentation? No Microbiological Control Program Do you conduct pathogen testing on any finished products? No Do you have a proper Hold and Release program in place, if you do conduct finished product pathogen testing? No Do you have an environmental microorganism/pathogen monitoring program? Yes This is done quarterly, four per zones and plant air samples. Would you be able to supply us with a pre-shipment sample, so we would be able to conduct our own pathogen testing to make sure it meets our specifications? Yes

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Warehousing / Shipping Are stocked materials being held properly in an organized manner to prevent shipping of non-conforming materials? Yes Is there a program in place to review the condition of stocked materials? No Are defective or out-of-date materials removed from inventory? Yes Is a packing slip generated for each shipment? Yes Is the packing slip checked to verify that the item description, item code, manufacturing date, shelf life, lot number, and quantity are all correct? Yes Does your facility have a stock rotation system in place (i.e. First-in, First-out)? Yes Food Safety Modernization Act (FSMA) Are you compliant with the sanitary transportation of Human & Animal Food Final Rule? Yes Are you compliant with Preventative Controls for Human Food Final Rule? Yes HARPC / FOOD Safety Plan Do you have a validated HARPC Program in Place? Yes Does your HARPC Plan address, Biological, Chemical and Physical hazards? Yes Crisis Management Do you have a written crisis management plan in place? Yes Do you have written contingency plan in place? Yes Metal Detection Does your company perform metal detection on all products that are sold? No The nature of dry ice due to extreme low temperature (-109°F). We have put clamshells on all of our machines where bolts are used. Food Defense Is your facility registered by the US Public Health Security & Bioterrorism Preparedness & Response act of 2002? Yes

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Employee Training Do you have a written employee training program in place? Yes How do you verify competency of your employees following training? Our employees have continuous JTO and auditing of performance. Are all full time, part time, contract and temporary employees trained upon hire? Yes How often do you perform complete refresher training? Annually Other Do you irradiate your products? No Do you test for indicator organisms, such as APC, Coliforms, Yeast and Mold, etc.? Yes We have a 3rd party laboratory for bacteria and mold. It’s done with swabbing. What foreign material controls do you currently have in place (sieve, trays, metal detection, x-ray, etc.)? Due to the low temperature of dry ice, we do not use x-ray.

If foreign material is found, what corrective actions are taken? We move to ensure product will follow our non-conformance policy Is your company inspected by a regulatory body (USDA, FDA, etc.)? Yes We have inspections by the following agencies: OSHA & EPA Are any of the ingredients or products that you sell imported from outside the United States? No Prop 65 Responses: Please see SDS Page 6; section 15 Please explain your numbering/code date below: Our Dry Ice produced and shipped in an insulated container. The containers are marked on all four sides, tracked by digital video throughout manufacturing process. Each container has a sticker showing date / time of production along with a scannable bar code for tracking. See additional information enclosed.

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INGREDIENT CRITERIA QUESTIONNAIRE

CONTAINS / PROCESSED WITH YES* NO TYPE / SOURCE

Recombinant Bovine Growth Hormone (rBGH)

X

Animal Products, Animal Tissue (excluding dairy)

X

Animal Rennet X Method of Microbial Reduction or Lethality Step

X

Irradiation Ethylene Oxide (ETO) Propylene Oxide (PPO) Steam Pasteurization Spray Drying – Time____ Temp_____ Other ______

Microbial Testing or Validation Study

X

Ethoxyquin Treatment X ppm:

Modified Food Starch

X

Source: Process:

Acid Hydrolysis Enzyme Hydrolysis Other

Maltodextrin

X

Source: Process: Acid Hydrolysis Enzyme Hydrolysis

Other Dextrose Equivalent:

Vegetable Gum (e.g. Xanthan, Acacia, etc.)

X

Hydrogenated Oil X Partially Hydrogenated Oil X Palm Oil

X Sustainably Sourced

Not Sustainably Sourced Refined, Bleached, Deodorized (RBD) Oil

X

Refined Sugars (Beet, Cane, Corn, etc.)

X

Artificial Preservatives X Artificial Sweeteners X Artificial Flavors X

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Artificial Colors (e.g. Yellow 5 Tartrazine)

X

Synthetic Ingredients X Chemical Solvents X Process Aids (e.g. Propylene Glycol)

X

Yellow Prussiate of Soda X

Monosodium Glutamate (MSG) X

Added Naturally Occurring

Hydrolyzed Vegetable Protein (HVP) X Grown on land exposed to sewage sludge. X

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ALLERGENS/SENSITIVITIES

Contains the Following Allergen/Sensitivity

Present in

Product (yes*/no)

Present in Other Products

Manufactured on Same Line

(yes/no)

Present in the Same

Manufacturing Plant

(yes/no)

Source of the

Allergen / Sensitivity

Present in Product

Egg No No No N/a Milk/Dairy No No No N/a Wheat No No No N/a Soy/Soybeans (not including refined oil)

No No No N/a

Fin Fish No No No N/a Crustacean Shellfish Examples: Crab, crayfish, lobster, shrimp

No No No N/a

Tree Nuts (not including refined oil)

No No No N/a

Peanuts (not including refined oil)

No No No N/a

Sensitivities N/a Celery or derivatives No No No N/a Mollusks Examples: Clams, mussels, oysters, scallops

No No No N/a

Mustard or derivatives No No No N/a Rye, barley or derivatives No No No N/a Oats or derivatives No No No N/a Seeds (Poppy, Sunflower, Cottonseed, not including refined oil)

No No No N/a

Sesame Seeds or derivatives

No No No N/a

Sulfites No No No

Added ppm: Naturally ccurring ppm:

GENERAL QUESTIONS: (please answer all questions) YES* NO EXPLANATION

Processing:

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Mechanically Processed? X

Chemically Processed? X List Chemicals: CO2

Fermentation? X

Enzyme Modification? X

Other? (Please explain) N/A

Oils and Oleoresins:

Solvent extracted X List Solvents:

CO2 extracted X

Mechanically extracted (cold pressed, etc.) X

Other? (Please explain)

Miscellaneous Information:

Organic Certified? (If yes, please provide certificate) X

Organic Compatible? (i.e. not organic certified, but meets NOP requirements and can be used in organic products, other than 100% organic)

X

Contains GMO (Genetically Modified Material) X

Non-GMO: This ingredient (including processing aids, diluents & carriers) was not derived from a Genetically Engineered source material. (If ingredient complies with the statement given, please mark “Yes”)

X

IP Controlled: This ingredient (including processing aids, diluents & carriers) was not derived from Genetically Engineered source material and a documented IdentityPreserved Program is in place at the manufacture site.

X

PCR Negative: This ingredient (including processing aids, diluents & carriers) will test “negative” if a PCR test is performed

X

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Continental Carbonic Products, Inc.

Lot Code Explanation

Our dry ice is produced and shipped in insulated containers. These containers are marked

with serial numbers on all four sides and are tracked by digital video throughout the

manufacturing process. Each container has a sticker showing date and time of production

(sample photo below) and is tagged with a scannable bar code which is used for tracking.