Removal Assessment Report - Appendix G -Lab Data Sheets ...

CompuChem

a division of Liberty Analytical Corp.

February 12. 2002

JOHN JOHNSON

ESC

11911 FREEDOM DRIVE

SUITE 900

RESTON. VA 20190

Subject:

Report of Data-Project: EMERSON AVA. MO Quote#: Q1 877 SDG #: QZ1877

Attn.: JOHN JOHNSON

Enclosed are the results of analytical work performed in accordance with the referenced

account number.

This report covers sample(s) appearing on the attached listing.

Thank you for selecting CompuChem for your sample analysis. If you should have

questions or require additional analytical services, please contact vour representative at

1-800-833-5097.

Sincerely.

CompuChem '

A Division of Libertv Analvtical

Attachment

30225958

1Superfund

Cftl Mnîr^n A wanno - Pin, M r 0751*5 - Tab QiO.07Q.4inn Fav Q1Q-?7Q-4n*;n

SAMPLENUM CLIENTID CASE SDG MATRIX ACCTNUM PROJECTNUM

QZ1877-1 MW-22A Q1877 QZ1877 WA ESC EMERSON AVA, MOQZ1877-2 TRIPBLANK Q1877 QZ1877 WA ESC EMERSON AVA, MO'

RECEIVEDATE

2/8/02

2/8/02

The sample data summary package shall contain data for all samples

in one Sample Delivery Group (SDG) of the Case, as follows:

A. SDG Narrative

B. Tabulated target compound results (Form I)

Tentatively identified compounds (Form I, TIC)

In order by sample.

C. Surrogate spike analysis results (Form II)

By matrix (Water or Soil), and

by concentration (Low, Medium, or High)

D. Spike results MS / MSD / LCS (Form III)

E. Blank data (Form IV)

Tabulated blank results (Form I)

Tentatively identified compounds (Form I, TIC)

F. Internal standard area response and retention time data (Form VIII)

LAB CODE : LIBRTY METHOD:

CASE#:______________ SDG # : ^

• A. SDG Narrative

CompuChema division of Liberty Analytical Corporation

501 Madison Avenue Cary, N.C. 27513Tel: 919/379-4100 Fax: 919/379-4050

SDG NARRATIVE

SDG #QZ1877SAMPLE IDENTIFICATIONS: MW-22A TRIPBLANK

The two water samples listed above were received intact, at 4 degrees C, in sealed shipping containers, on

February 08, 2002. Both samples were submitted for volatile only analysis, and were prepared and analyzed following

SW846 Method 8260B. All pertinent Quality Assurance Notices are included in the narrative section, and all pertinent

Laboratory Notices for SDG # QZ1877 are included in the sample data sections.

Analysis holding time requirements were met for all samples, and sample pH values were both less than 2.0.

The Target Compound List(TCL) analyte cis-l,2-dichloroethene was present at high levels in MW-22A, and based on

screen data this sample was initially analyzed at a 12.5X dilution which met all dilution criteria. For this sample we have

only reported the one diluted run. The screen Reconstructed Ion Chromatogram(RIC) is included in the deliverables

package immediately following the RIC for the sample’s reportable run.

No TCL analytes were identified in TRIPBLANK above the reporting limits.

No Tentatively Identified Compounds (TICs) were searched at the request of the client.

All Bromofluorobenzene (BFB) abundance criteria were met for tunes associated to this SDG. Overall QC criteria were

met for all initial and continuing calibration standards associated to this SDG.

The system monitoring compounds(SMCs) met recovery criteria in the analyses of these samples, and all of the internal

standards met retention time and response criteria in the analyses of these samples.

The associated method blank met all quality control criteria, and did not contain any target analytes above the CRQL.

No duplicate matrix spikes were generated per client request, however the associated Laboratory Control Sample(LCS) met

all accuracy requirements.

Manual quantitations were performed on the process files in some of the the associated initial, and continuing

calibration(s). The reasons have been coded with explanations provided in the notice included in the narrative section of

this SDG.

1 certify that this data package is in compliance with the terms and conditions of the contract, both technically and for

completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package and

in the computer-readable data submitted on diskette has been authorized by the Laboratory Manager or his/her designee, as

verified by the following signature.

Case Reviewer

February 12, 2002

CompuChem GC/MS VOA Batch Sheet - Water IP 250/460/462/475/480B/483

a Division of Liberty Analytical Corp.Method: 'X U O Batch#:-------------------------

SAMPLENUMQZ1877-1

QZ1877-2

WG15711-1

WG15711-2

"WG1_571T-3

WG15711-4

WG15711-5

WG15711 -6

q£Lfc..rL-jJL

CLIENTID | LOGINNUM I pH Timej Date

Y-n-o')MW-22A QZ1877 ! ITRIPBLANK ~QZ1877 t | " L

VBLKNY..................... ' " ' "

VBLKNZ

VBLKOA

VNYLCS

VNZLCS

INST# Operator

Y\'

VOALCS

/<?£?- y_L_

4-

_1_3_ it, i~b

H/T | Volume | Bottle #J Report

r T i _ [ oî

7777777-! J 7.7 “7777:7'Comments

___ ytt,

77!

[)UC 2./'3 A**

TC L 3 cT. S o b

c_ I *Lc.'i’

6/27/01 :rmh

COMPUCHEMWork Group Report (wk02)

08-FEB-02 10:36 AM

WorkGroup: WG15711

Department: 435 MS/VOA ANALYSIS

Sample Client ID Product Matrix RecvDate

QZ1877-1 MW-22A VOA-8260B-25ML Water 08-FEB-02

QZ1877-2 TRIPBLANK VOA-8260B-25ML Water 08-FEB-02

WG15711-1 VBLKNY VOA-8260B-25ML Water 08-FEB-02

WG15711-2 VBLKNZ VOA-8260B-25ML Water 08-FEB-02

WG15711-3 VBLKOA VOA-8260B-25ML Water . 08-FEB-02

WG15711-4 VNYLCS VOA-8260B-25ML Water 08-FEB-02

WG15711-5 VNZLCS VOA-8260B-25ML Water 08-FEB-02

WG15711-6 VOALCS VOA-8260B-25ML Water 08-FEB-02

Comments:

QZ1877-1

QZ1877-2

PPS 985**

PPS 985**

VOC 8260B TCL3CT.SUB**LCS ONLY

TRIP BLK**VOC 8260B TCL3CT.SUB**LCS ONLY

Created: 08-FEB-02

Bottle# Lab Information

Internal Chain ot CustodyReceived By_______ ~Z

Received By________£ e>c ler

—Reeeived~Bv

Received By___________________

Received By___________________

Relinquished Bv Vi Date X-ll -oXRelinquished Bv 2. Date 2->tRelinquished Ry -—

Relinquished Bv Date

Relinquished Bv Date

Relinquished By Date

Relinquished Bv Relinquished Bv c

---- —— Ddlti" I-----------------------Data-

35Date

Date

-Boto-

7-ii

1-itReason

Reason

Reason

Rpppivpd-nv —

Received By_______

RpppjypH Ry

Date.

Date.

“Date-

reason

Reason___

Reason

-Reason^—

5

' CompuChem, a Division of Liberty Analytical Corporation

GC and GC/MS Column and Trap Specifications Table

COLUMNSBrand Name Coating ID Film Thickness Length

Material (mm) (um) (m)

GC Laboratory

Restek RTX-1701 0.53 0.5 30

J & W DB-608 0.53 0.83 30

Restek CLPesticides 0.53 0.5 30

Restek CLPesticides II 0.53 0.42 30

GC Volatiles Laboratory

Restek RTX-1 0.53 0.5 105

Restek RTX-502.2 0.53 0.5 105

GC/MS Volatiles Laboratory

J & W DB-624 0.53 3.0 30/75

J & W DB-624 0.25 1.4 60

J & W DB-624 0.32 1.8 60

Restek RTX-624 0.32 1.8 60

Supelco SPB-624 0.32 1.4 60

Supelco Equity™-624 0.53 3.00 75.00

Zebron ZB-624 0.32 1.8 60

GC/MS Semivolatiles Laboratory

Zebron ZB-5MS| 0.25 0.31 30

J & W DB-5.625 0.32 1.0 30

J & W DB5-MS 0.25 0.25 30

Hewlett Packard HP5-MS 0.25 0.25 30

Optima 5-MS 0.25 0.25 30

Restek. RTX-5 0.32 1.00 30

Restek RTX-5MS 0.25 0.25 30

TRAPSGC and GC/MS Volatiles Laboratory

Tekmar3 * 8 cm of 2,6-diphenylene oxide polymer (Tenax)

* 8 cm of silica gel

* 7 cm of coconut charcoal

* 0.5 cm of silanized glass wool at each end

Tekmar 5 * 1 cm of methyl silicone packing (OV-1 coating)

* 8 cm of 2,6-diphenylene oxide polymer (Tenax)




Supelco K (Vocarb3000) *10 cm of Carbopack B (Graphitized Carbons)

* 6 cm of Carboxen 1000 (Carbon molecular sieves)


Rev. 14 1/21/20026


Notification Regarding Manual Editing/Integration Flags

In some instances, manual adjustments to the software output are necessary to provide accurate data. These

adjustments are performed by the data reviewer, GC/MS operator, or GC chemist. An Extracted Ion Current Profile

(EICP) or a GC chromatographic peak has been provided for the manual integration of each compound to

demonstrate the accuracy of that process. Adjustments are flagged on the quantitation report in the far right column

beyond the FINAL concentration for GC/MS analysis, and in the “Flags” column for GC analysis. The manual

editing/integration flags are:

- Denotes that a manual integration has been performed for this compound. The manual integration was

performed in order to provide the most accurate area count as possible for the peak.

- Denotes that the data reviewer, GC/MS operator, or GC Chemist has chosen an alternate peak within the

retention time window from that chosen by the software for that compound. No manual integration is

performed in choosing an alternate peak. The software still performs the integration.

- Denotes that an alternate peak has been chosen within the retention time window from that chosen by the

software for that compound and also a manual integration of the chosen peak has been performed. The

manual integration was performed in order to provide the most accurate area count possible for the peak.

- Denotes that the data reviewer or GC/MS operator has selected an alternate library search. This is

typically done when an additional tentatively identified compound (TIC) has been added to the number of

peaks searched. No manual integration is performed in choosing an alternate peak. The software still

performs the integration.

- Denotes that an alternate library search has been selected and a manual integration has also been

performed. This is typically done when an additional TIC has been added and the TIC peak also required a

manual integration.

The EPA CLP SOW requires additional explanations for manual editing/integration. In the accompanying raw data

packages, additional codes have been applied to the “M” flag and carry the following meanings;

Ml - The compound was not found by the automatic integration routine.

M2 - The compound was incorrectly integrated by the automatic integration routine.

M3 - The co-eluting compounds were incorrectly integrated by the automatic integration routine.

These codes will appear in the GC/MS and GC data packages.

Robert E. MeiererVice President 7

Revision 5 (10/27/99)


DATA REPORTING QUALIFIERS

On the Form 1, under the column labeled “Q” for qualifier, each result is flagged with the specific data reporting qualifiers listed below, as appropriate. Up to five qualifiers may be reported on Form I for each

compound. The qualifiers used are:

U : This flag indicates the compound was analyzed for but not detected. The Contract Required

Quantitation Limit (CRQL), or reporting limit, will be adjusted to reflect any dilution and, for

soils, the percent moisture.

J : This flag indicates an estimated value. The flag is used as detailed below:

1. When estimating a concentration for tentatively identified compounds (TICs) where a

response factor of 1.0 is assumed for the TIC analyte,

2. When the mass spectral and retention time data indicate the presence of a compound that meets the volatile and semivolatile GC/MS identification criteria, and the result is less than the

CRQL (or Reporting Limit) but greater than zero, and

3. When the retention time data indicate the presence of a compound that meets the

pesticide/Aroclor or other GC or HPLC identification criteria, and the result is less than the

CRQL (or Reporting Limit) but greater than zero. For example, if the CRQL (or Reporting Limit)

is 10 pg/L, but a concentration of 3 pg/L is calculated, it is reported as 3J.

N : This flag indicates presumptive evidence of a compound. This flag is only used for TICs, where

the identification is based on a mass spectral library search. For generic characterization of a TIC

such as ‘chlorinated hydrocarbon’, the N flag is not used.

P : In the EPA’s Contract Laboratory Program (CLP), this flag is used for a pesticide/Aroclor target

analyte, when there is greater than 25% difference for detected concentrations between the two

GC columns. The lower of the two values is reported on Form I and flagged with a P.

For SW-846 GC and HPLC analyses, when the Relative Percent Difference (RPD) is greater than 40% and there is no evidence of chromatographic anomalies or interferences, then the higher of

the two values is reported and flagged with a P. When the RPD is equal to or less than 40%, our

policy is to also report the higher, of the two values, although the choice could be a project

specific issue.

8

DATA REPORTING QUALIFIERS (continued)

C : This flag applies to GC or HPLC results where the identification has been confirmed by GC/MS.

If GC/MS confirmation was attempted but was unsuccessful, this flag is not applied; a laboratory-

defined flag is used instead (see the X/Y/Z qualifier.)

B : This flag is used when the analyte is found in the associated blank as well as in the sample. Itindicates probable blank contamination and warns the data user to take appropriate action. This flag is used for a TIC as well as for a positively identified target compound. The combination of

flags BU or UB is not an allowable policy. Blank contaminants are flagged B only when they are

detected in the sample.

E : This flag identifies, compounds whose concentrations exceed the upper level of the calibration

range of the instrument for that specific analysis. If one or more compounds have a response

greater than the upper level of the calibration range, the sample or extract will be diluted and reanalyzed. All such compounds with a response greater than the upper level of the calibration

range will have the concentration flagged with an E on Form I for the original analysis.

D : If a sample or extract is reanalyzed at a higher dilution factor, for example when theconcentration of an analyte exceeds the upper calibration range, the DL suffix is appended to the

sample number on Form I for the more diluted sample, and all reported concentrations on that

Form I are flagged with the D flag. This flag alerts data users that any discrepancies between the

reported concentrations may be due to dilution of the sample or extract.

NOTE 1: The D flag is not applied to compounds which are not detected in the sample analysis i.e.

compounds reported with the CRQL (or Reporting Limit) and the U flag.

NOTE 2: Separate Form Is are used for reporting the original analysis (Client Sample No. XXXXX) and

the more diluted sample analysis (Client Sample No. XXXXXDL) i.e. the results from both

analyses are not combined on a single Form I.

A : This flag indicates that a TIC is a suspected aldol-condensation product.

X/Y/Z : Other specific flags may be required to properly define the results. If used, the flags will be fully

described in the SDG Narrative. The laboratory-defined flags are limited to X, Y and Z.

9Revision 6 (12-14-00)

Laboratory Notice

Calibration Date(s): 08-FEB-2002 11:14

Instrument ID: 5972hp73

08-FEB-2002 13:15

An initial calibration was analyzed by Method 8260B. Per the methodology, all compounds are to meet a Percent Relative Standard Deviation (%RSD) limit of no more than 15%. Additional calibration options are provided in the method when the RSD exceeds 15%. CompuChem has chosen to apply the option of determining the mean RSD values for all analytes in the initial calibration.

When there are analytes with %RSDs greater than the limit, proof of calibration linearity can be shown if the average of all compounds in the initial calibration meet the same 15% limit. Based on Method 8260B,Sec. 7.3.8.2, and Method 8000B, Sec. 7.5.1.2 requirements, we are providing a list of the compounds which failed to meet the limit, and their associated %RSDs. Finally, the average of all %RSDs from all compounds in the initial calibration is shown, confirming the usability of the initial calibration and any data that follows it.

Compound Name RSD

Bromomethane 15.6Acetone 41.1Methyl acetate 25.4Methylene Chloride 16.2Crotonaldehyde 23.9Bromodichloromethane 15.3^^chloroethyl vinyl ether 58.8^BLuene 15.6^Wiexanone 18.51,2-Dibromo-3-Chloropropane 44.2

Average %RSD for all compounds in the Initial Calibration: 10.3 %

Data Reviewer/ID : /?i

Date: ^LiID'^

10

• B. Form I and Form I - TIC

Organic Analysis Data Sheet (OADS) and Tentatively Identified Compounds (TICs)- All samples in alphanumeric order- Matrix Spike/Matrix Spike Duplicate- Laboratory Control Sample(s)

FORM 1 CLIENT SAMPLE NO.

VOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: COMPUCHEM Method: 8260BMW-22A

Lab Code: LIBRTY Case No. : SAS No.: SDG No.: QZ1877

Matrix: (soil/water) WATER Lab Sample ID QZ1877-1

Sample wt/vol: 25 (g/ml)' ML Lab File ID: QZ1877-1RA73

Level: (low/med) LOW Date Received 02/08/02

% Moisture: not dec. Date Analyzed 02/11/02

GC Column: ZB-624 ID: 0.32 (mm) Dilution Factor: 12.5

Soil Extract Volume: (uL) Soil Aliauot Volume:

CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kg) UG/L Q

74- 87-3-------- Chloromethane75- 01-4-------- Vinyl Chloride74- 83-9-------- Bromome thane75- 00-3-------- Chloroe t hane__75-35-4---------1,1-Dichloroethene75-15-0---------Carbon disulfide__________67-64-1---------Acetone____ ____75-09-2---------Methylene Chloride ~156-60-5--------trans-1,2 -D‘i chloroe thene_75-34-3---------1,1-Dichloroethane156-59-2--------cis-1,2-Dichloroethene78- 93-3-------- 2 -butanone67-66-3---------Chloroform ______ ________71-55-6---------1,1,1 -Trichloroethane56-23-5---------Carbon Tetrachloride71-43-2---------Benzene ______ ______107- 06-2-------1,2-Dichloroethane79- 01-6-------- Trichloroethene78- 87-5--------1,2-Dichloropropane75-27-4---------Bromodichloromethane10061-01-5----- cis-1,3-Dichloropropene 108- 10-1-------4 - Methyl-2 -pentanone108-88-3--------Toluene____________________10061-02-6----- 1 rans-1,3-Dichloropropene79- 00-5--------1,1,2- Trichloroethane_____127-18-4--------Tetrachloroethene591-78-6--------2 - hexanone_______ _________124-48-1--------Dibromochloromethane ~108-90-7--------Chlorobenzene100-41-4--------Ethylbenzene108-38-3--------m, p-Xylene95-47-6---------o-Xylene100-42-5--------Styrene

UUuuuuJBUJU

uuuuuuJBUUUUuuuJBUUUUuuu

FORM I VOA

12

FORM 1VOLATILE ORGANICS ANALYSIS DATA SHEET

CLIENT SAMPLE NO.

Lab Name: COMPUCHEM

Lab Code: LIBRTY Case No.:

Matrix: (soil/water) WATER

Sample wt/vol: 25 (g/ml)' ML

Level: (low/med) LOW

% Moisture: not dec.

GC Column: ZB-624 ID: 0.32 (mm)

Soil Extract Volume : ______ (uL)

Method: 8260BMW-22A

SAS No.: SDG No.: QZ1877

Lab Sample ID: QZ1877-1

Lab File ID: QZ1877-1RA73

Date Received: 02/08/02

Date Analyzed: 02/11/02

Dilution Factor: 12.5

Soil Aliquot Volume: (uL

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

75-25-2--------- Bromof orm 6 U79-34-5---------1,1,2,2 - Tetrachloroe thane 6 U1330-20-7-------Xylene (total) 6 U

FORM I VOA

FORM 1 CLIENT SAMPLE NO.

VOLATILE ORGANICS ANALYSIS DATA SHEET

^^Lab Name: COMPUCHEM

Lab Code: LIBRTY

Method 8260BTRIPBLANK

Case No. : SAS No. SDG No.: QZ1877


Sample wt/vol: 25 (g/ml)' ML Lab File ID: QZ1877-2A73




Soil Extract Volume: (uL) Soil Aliquot Volume:

CONCENTRATION UNITS:CAS NO. COMPOUND (ug'/L or ug/Kg) UG/L Q

74-87-3--------- Chloromethane 0.5 U75-01-4--------- Vinyl Chloride 0.5 U74-83-9---------B r omome thane 0.5 U75-00-3---------Chloroet hane 0.5 U75-35-4--------- 1,1-Dichloroethene 0.5 U75-15-0--------- Carbon disulfide 0.5 U67-64-1--------- Acetone 2 JB75-09-2--------- Methylene Chloride 0.2 J156-60-5--------trans-1,2 - Diehl oroethene 0.5 U75-34-3--------- 1,1-Dichloroethane 0.5 U156-59-2-------- cis-1,2-Dichloroethene 0.5 U78-93-3--------- 2-butanone 3 U67-66-3--------- Chloroform 0.5 U71-55-6--------- 1,1,1 -Trichloroethane 0.5 u56-23-5--------- Carbon Tetrachloride 0.5 u71-43-2--------- Benzene 0.5 u107-06-2--------1,2 -Dichloroe thane 0.5 u79-01-6--------- Trichloroethene 0.5 u78-87-5--------- 1,2-Dichloropropane 0.5 u75-27-4--------- Bromodichloromethane 0.5 u10061-01-5------cis-1,3-Dichloropropene 0.5 u108-10-1-------- 4-Methyl-2 -pentanone 3 u108-88-3-------- Toluene 0.2 JB10061-02-6------trans-1,3-Dichloropropene 0.5 U79-00-5--------- 1,1,2-Trichloroethane 0.5 u127-18-4-------- Tetrachloroethene 0.5 u591-78-6--------2 - hexanone 3 u124-48-1-------- Dibromochloromethane 0.5 u108-90-7-------- Chlorobenzene 0.03 J100-41-4-------- Ethylbenzene 0.5 u108-38-3--------m,p-Xylene 1 u95-47-6--------- o-Xylene 0.5 u100-42-5-------- Styrene 0.5 u

FORM I VOA

14


CLIENT SAMPLE NO.

Lab Name: COMPUCHEM



Sample wt/vol: 25 (g/ml) ML



GC Column: ZB-624 .ID: 0.32 (mm)

Soil Extract Volume: ______ (uL)

Method: 8260BTRIPBLANK



Lab File ID: QZ1877-2A73






75-25-2--------- Bromof orm 0.5 U79-34-5---------1,1,2,2 -Tet rachloroe thane 0.5 U1330-20-7-------Xylene (total) 0.5 U

FORM I VOA


CLIENT SAMPLE NO.

|Lab Name: COMPUCHEM

Lab Code: LIBRTY

Matrix: (soil/water)

Sample wt/vol:

Level: (low/med)


GC Column: ZB-624

Soil Extract Volume:

Case No. :

WATER

25 (g/ml)' ML

LOW

ID: 0.32 (mm)

_______ (uL)

CAS NO. COMPOUND

Method: 8260BVLILCS


Lab Sample ID: WG15582-5

Lab File ID: WG15582-5A73CT

Date Received:



Soil Aliquot Volume:

CONCENTRATION UNITS:(ug/L or ug/Kg) UG/L Q

74-87-3--------- Chloromethane 575-01-4--------- Vinyl Chloride 574-83-9--------- Bromomethane 575-00-3---------Chi oroe thane 575-35-4--------- 1,1 -Dichloroethene 675-15-0--------- Carbon disulfide 567-64-1--------- Acetone 17 B75-09-2---------Methylene Chloride 4156-60-5--------trans-1,2-Dichloroethene 575-34-3--------- 1,1-Dichloroe thane 5156-59-2--------cis-1,2-Dichloroethene 578-93-3--------- 2 -butanone 1767-66-3--------- Chloroform 571-55-6---------1,1,1 -Trichloroe thane 656-23-5--------- Carbon Tetrachloride 671-43-2--------- Benzene 5 B107-06-2--------1,2-Dichloroethane 579-01-6---------Tr ichloroethene 5 B78-87-5--------- 1,2-Dichloropropane 575-27-4--------- Bromodichloromethane 410061-01-5------cis-1,3-Dichloropropene 5108-10-1--------4-Methyl-2-pentanone 19108-88-3--------Toluene 5 B10061-02-6------trans-1,3-Dichloropropene 579-00-5--------- 1,1,2-Trichloroethane 4127-18-4--------Tetrachloroethene 5 B591-78-6--------2 - hexanone 21

. 124-48-1--------Dibromochloromethane 4108-90-7--------Chlorobenzene 5100-41-4--------Ethylbenzene 5108-38-3--------m,p-Xylene 11 B95-47-6--------- o-Xylene 5100-42-5--------Styrene 5

16

(uL

FORM I VOA


CLIENT SAMPLE NO.

Lab Name: COMPUCHEM



Sample wt/vol: 2 5 (g/ml)' ML




Soil Extract Volume:(uL)

Method: 826OBVLILCS




Date Received:





75-25-2--------- Bromof orm 479-34-5---------1,1,2,2-Tetrachloroethane 41330-20-7-------Xylene (total) 17 B

FORM I VOA

(uL

17

• C. Form IISurrogate spike analysis

- By level (low, medium, high) -

FORM 2WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY

Lab Name: COMPUCHEM Contract: 8260B

Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QZ1877

| CLIENT | SAMPLE NO.1 = = ==========

01|VBLKLI02 jVLILCS

03|TRIPBLANK04 j MW-22A

05 |

SMCl(DBF)#

9198.

115118

SMC2 (DCE)#

8788

111115

SMC3 | SMC4 |TOT (TOL)#j (BFB)#|OUT

====== 1 ==== = =l= = =100 I 90 I 0103 j 92 | 0100 | 101 j 0108 j 99 | 0

06 j 1 107 j08 j 1 109 | 1 110 | 1 111 112 | 1 113 |14 | 1 115 j 1 116 | 1 117 j 1 118 | 1 119 | 1 120 | 1 1211 1 122 | 1 123 |24 j 1 125 | 1 126 I 1 127 | 1 128 | 1 1

QCSMCl (DBF) = Dibromofluoromethane SMC2 (DCE) = 1,2-Dichloroethane-d4 SMC3 (TOL) = Toluene-d8 SMC4 (BFB) = Bromofluorobenzene

# Column to be used to flag recovery values

* Values outside of contract required QC limits

D System Monitoring Compound diluted out

LIMITS(65-150)(59-150)(61-145)(63-143)

page 1 of 1 FORM II VOA

Matrix Spike/Matrix Spike Duplicate results - By level (low, medium, high) -

Laboratory Control Sample(s)

• D. Form III

20

3AWATER VOLATILE LAB CONTROL SAMPLE

Lab Name: COMPUCHEM


Contract: 8260B

SAS No.:

VLILCS

SDG No.: QZ1877

COMPOUND

SPIKEADDED(ug/L)

LCSCONCENTRATION

(ug/L)

LCS%

REC #

QC.LIMITSREC.

1,1-Dichloroethene 5.00 5.50 110 50-150Benzene 5.00 5.09 102 76-134Trichloroethene 5.00 5.26 105 71-143Toluene 5.00 4.72 94 70-137Chlorobenzene 5.00 4.98 100 74-136

# Column to be used to flag recovery and RPD values with an asterisk

* Values outside of QC limits

Spike Recovery: 0 out of 5 outside limits

COMMENTS:

FORM III VOA-121

• E. Form IV

Method Blank ResultsForm IV, Form I, and Form I - TIC

Method blank summary, OADS, and TICs

- In chronological order of analysis

CLIENT SAMPLE NOFORM 4VOLATILE METHOD BLANK SUMMARY





GC Column: ZB-624 ID: 0.32

Instrument ID: 5972HP73

(mm)

Contract:

SAS No.:

8260BVBLKLI

SDG No.: QZ1877


Time Analyzed: 0935

Heated Purge: (Y/N) N

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:

01020304050607080910 11 121314151617181920 21 222324252627282930

SAMPLE NO.

VLILCSTRIPBLANKMW-22A

LABSAMPLE ID

WG15582- 5QZ1877-2QZ1877-1

LABFILE ID

WG15582-5A73QZ1877-2A73QZ1877-1RA73

TIMEANALYZED

1017 ' 16461922

/

COMMENTS:

e 1 of 1FORM IV VOA

23

FORM 1 CLIENT SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: COMPUCHEM

Lab Code: LIBRTY


Sample wt/vol:

Level: (low/med)


GC Column: ZB-624


Case No.:

WATER

25 (g/ml)' ML

LOW

ID: 0.32 (mm)

_______ (uL)

Method: 8260BVBLKLI




Date Received:





74-87-3--------- Chloromethane 0.5 U75-01-4--------- Vinyl Chloride 0.5 U74-83-9--------- Bromome thane 0.5 U75-00-3--------- Chi oroe thane 0.5 U75-35-4---------1,1-Diehl oroe thene 0.5 U75-15-0--------- Carbon disulfide 0.5 U67-64-1-- ------ Acetone 1 J75-09-2--------- Methylene Chloride 0.5 U156-60-5--------trans-1,2-Dichloroethene 0.5 U75-34-3--------- 1,1 - Dichloroe thane 0.5 U156-59-2--------cis-1,2-Dichloroethene 0.5 U78-93-3--------- 2 -butanone 3 U67-66-3--- ----- Chloroform 0.5 U71-55-6---------1,1,1-Trichloroe thane 0.5 U56-23-5--------- Carbon Tetrachloride 0.5 U71-43-2--------- Benzene 0.06 J107-06-2--------1,2-Dichloroethane 0.5 U79-01-6------ ' - -Trichloroethene 0.03 J78-87-5--------- 1,2-Dichloropropane 0.5 U75-27-4---------Bromodichlorome thane 0.5 U10061-01-5------cis-1,3-Dichloropropene 0.5 U108-10-1-------- 4 - Methyl -2 - pentanone 3 U108-88-3-------- Toluene 0.1 J10061-02-6----- trans-1,3-Dichloropropene79-00-5---------1,1,2-Trichloroethane

0.5 0.5

UU

127-18-4--------Tetrachloroethene 0.04 J591-78-6-------- 2 - hexanone 3 u124-48-1--------Dibromochlorome thane 0.5 u108-90-7--------Chlorobenzene 0.5 u100-41-4--------Ethylbenzene 0.5 u108-38-3-------- m,p-Xylene 0.06 J95-47-6--------- o-Xylene 0.5 u100-42-5--------Styrene 0.5 u

FORM I VOA

(uL

24


CLIENT SAMPLE NO.

Lab Name: COMPUCHEM

Lab Code: LIBRTY Case No.1







Method: 8260BVBLKLI




Date Received:





75-25-2---------Bromoform 0.5 U79-34-5---------1,1,2,2-Tetrachloroethane 0.5 U1330-20-7-------Xylene (total) 0.07 J

FORM I VOA

(uL

25

Internal standard area and retention time data(VOA and SV only)

F. Form VIII

26

FORM 8VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY

}Lab Name: COMPUCHEM


Lab File ID (Standard): CS020211A73



Contract: 8260B



Time Analyzed: 0838


01020304050607080910 11 121314151617181920

12 HOUR STD UPPER LIMIT LOWER LIMIT

CLIENT SAMPLE NO.

VBLKLIVLILCSTRIPBLANKMW-22A

ISI(FBZ) AREA #

19493638987297468

192058180905151859166793

RT #

10.3210.829.82

10.3210.3110.32 10.31

IS2(CBZ) AREA #

13039026078065195

127336122235108692115604

RT #

13.1613.6612.66

13.1613.1613.1513.15

IS3(DCB) AREA #

6654613309233273

61339584685187456817

RT #

14.8615.3614.36

14.8514.8614.8614.85

*

151 (FBZ)152 (CBZ)153 (DCB)

Fluorobenzene Chlorobenzene-d5 1,4-Dichlorobenzene-d4

AREA UPPER LIMIT = +100% of internal standard area AREA LOWER LIMIT = - 50% of internal standard area RT UPPER LIMIT = + 0.50 minutes of internal standard RT RT LOWER LIMIT = - 0.50 minutes of internal standard RT

# Column used to* Values outside

page 1 of 1

flag values outside QC limits with an asterisk, of QC limits.

FORM VIII VOA

27

The sample data package shall include data for all analyses of all samples

in one Sample Delivery Group (SDG), including field samples, dilutions,

reanalyses, blanks, matrix spikes, matrix spike duplicates, and laboratory

control samples. The sample data package consists of the following:

A. SDG Narrative

B. Chain-of-Custody Documentation

C. SDG Data

LAB CODE : LIBRTY

CASE #:

METHOD:

SDG#: ft&KI-?

28

A. SDG Narrative


501 Madison Avenue Cary, N.C. 27513Tel: 919/379-4100 Fax: 919/379-4050

SDG NARRATIVE SDG #QZ1877

SAMPLE IDENTIFICATIONS: MW-22A TRIPBLANK

The two water samples listed above were received intact, at 4 degrees C, in sealed shipping containers, on

SW846 Method 8260B. All pertinent Quality Assurance Notices are included in the narrative section, and all pertinent

Laboratory Notices for SDG # QZ1877 are included in the sample data sections.

Analysis holding time requirements were met for all samples, and sample pH values were both less than 2.0.

The Target Compound List(TCL) analyte cis-l,2-dichloroethene was present at high levels in MW-22A, and based on

screen data this sample was initially analyzed at a 12.5X dilution which met all dilution criteria. For this sample we have

only reported the one diluted run. The screen Reconstructed Ion Chromatogram(RIC) is included in the deliverables

package immediately following the RIC for the sample’s reportable run.

No TCL analytes were identified in TRIPBLANK above the reporting limits.

No Tentatively Identified Compounds (TICs) were searched at the request of the client.

All Bromofluorobenzene (BFB) abundance criteria were met for tunes associated to this SDG. Overall QC criteria were

met for all initial and continuing calibration standards associated to this SDG.

The system monitoring compounds(SMCs) met recovery criteria in the analyses of these samples, and all of the internal

standards met retention time and response criteria in the analyses of these samples.

The associated method blank met all quality control criteria, and did not contain any target analytes above the CRQL.

No duplicate matrix spikes were generated per client request, however the associated Laboratory Control Sample(LCS) met

all accuracy requirements.

Manual quantitations were performed on the process files in some of the the associated initial, and continuing

calibration(s). The reasons have been coded with explanations provided in the notice included in the narrative section of

this SDG.

I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for

completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package and

in the computer-readable data submitted on diskette has been authorized by the Laboratory Manager or his/her designee, as

verified by the following signature.

February 08, 2002. Both samples were submitted for volatile only analysis, and were prepared and analyzed following

Rc„

Case Reviewer

February 12, 2002

30

CompuChema Division of Liberty Analytical Corp.

GC/MS VOA Batch Sheet - Water IP 250/460/462/475/480B/483

Method: \o O •; c;^ Batch #:

CO

SAMPLENUM CLIENTID LOGINNUM pH Time Date 1 INST# Operator 1 H/T | Volume! Bottle # Report Comments

QZ1877-1 MW-22A QZ1877 1 IV4L 3/1-07 7^ 7H>3 j focu,' 1 Dui-- QZ1877-2 TRIPBLANK QZ1877 _1__ i URla L 1 5^1 _ L _

WG15711-1 VBLKNY 1

WG15711-2 VBLKNZ 1WG15711-3 VBLKOA

WG15711-4 VNYLCS

WG15711-5 VNZLCS

WG15711-6 VOALCS rt/1 ^

___________1 I4LZ. J--H-0 l. __A3 fLl*.

—— — --------- 1------------- ________ ______

-------------

rj”' 1‘Mti'

\7-IPT-

ft'T 2- TCL 3 cT. Sojj

oue V'5/0’- "‘''76/27/01 :rmh

COMPUCHEMWork Group Report (wk02)

08-FEB-02 10:36 AM

WorkGroup: WG15711

Department: 435 MSA/OA ANALYSIS Created: 08-FEB-02

Sample Client ID Product Matrix RecvDate Bottle# Lab Information

QZ1877-1 MW-22A VOA-8260B-25ML Water 08-FEB-02

QZ1877-2 TRIPBLANK VOA-8260B-25ML Water 08-FEB-02

WG15711-1 VBLKNY VOA-8260B-25ML Water 08-FEB-02

WG15711-2 VBLKNZ VOA-8260B-25ML Water 08-FEB-02

WG15711-3 VBLKOA VOA-8260B-25ML Water 08-FEB-02

WG15711-4 VNYLCS VOA-8260B-25ML Water 08-FEB-02

WG15711-5 VNZLCS VOA-8260B-25ML Water 08-FEB-02

WG15711-6 VOALCS VOA-8260B-25ML Water 08-FEB-02

Comments:

QZ1877-1 PPS 985**VOC 8260B TCL3CT.SUB**LCS ONLY

QZ1877-2 PPS 985**TRIP BLK**VOC 8260B TCL3CT.SUB**LCS ONLY

Relinquished Bv Date O.-ll-o'Xinternal cnam or uustoay

Received By f*1 ? Date 2~" Reason

Relinquished Bv />n Z Date 2 -1 ( Received By C <beier 3 6 Date >-// Reason 57 e fa l,&

Relinquished By.

Relinquished By.

^Relinquished By.

elinquished By.

Relinquished By.

Relinquished By.

- Date-.

Dale.

Date.

Date _

Daltr Date'

Kueeivud Dy

Received By

Received By

Rpi-oiwcrLBy.Received By

Received Bu

32

CompuChem, a Division of Liberty Analytical Corporation

GC and GC/MS Column and Trap Specifications Table

COLUMNSBrand Name Coating ID Film Thickness Length

Material (mm) (um) (m)

GC Laboratory

Restek RTX-1701 0.53 0.5 30

J & W DB-608 0.53 0.83 30

Restek CLPesticides 0.53 0.5 30

Restek CLPesticides II 0.53 0.42 30

GC Volatiles Laboratory

Restek RTX-1 0.53 0.5 105

Restek RTX-502.2 0.53 0.5 105

GC/MS Volatiles Laboratory

J & W DB-624 0.53 3.0 30/75

J & W DB-624 0.25 1.4 60

J & W DB-624 0.32 1.8 60

Restek RTX-624 0.32 1.8 60

Supelco SPB-624 0.32 1.4 60

Supelco Equity™-624 0.53 3.00 75.00

Zebron ZB-624 0.32 1.8 60

GC/MS Semivolatiles Laboratory

Zebron ZB-5MS| 0.25 0.31 30

J & W DB-5.625 0.32 1.0 30

J & W DB5-MS 0.25 0.25 30

Hewlett Packard HP5-MS 0.25 0.25 30

Optima 5-MS 0.25 0.25 30

Restek RTX-5 0.32 1.00 30

Restek RTX-5MS 0.25 0.25 30

TRAPSGC and GC/MS Volatiles Laboratory

Tekmar 3 * 8 cm of 2,6-diphenylene oxide polymer (Tenax)




Tekmar 5 * 1 cm of methyl silicone packing (OV-1 coating)

* 8 cm of 2,6-diphenylene oxide polymer (Tenax)




Supelco K (Vocarb3000) * 10 cm of Carbopack B (Graphitized Carbons)



Rev. 14 1/21/2002 33


Notification Regarding Manual Editing/Integration Flags

In some instances, manual adjustments to the software output are necessary to provide accurate data. These

adjustments are performed by the data reviewer, GC/MS operator, or GC chemist. An Extracted Ion Current Profile

(EICP) or a GC chromatographic peak has been provided for the manual integration of each compound to

demonstrate the accuracy of that process. Adjustments are flagged on the quantitation report in the far right column

beyond the FINAL concentration for GC/MS analysis, and in the “Flags” column for GC analysis. The manual

editing/integration flags are:

- Denotes that a manual integration has been performed for this compound. The manual integration was

performed in order to provide the most accurate area count as possible for the peak.

- Denotes that the data reviewer, GC/MS operator, or GC Chemist has chosen an alternate peak within the

retention time window from that chosen by the software for that compound. No manual integration is

performed in choosing an alternate peak. The software still performs the integration.

- Denotes that an alternate peak has been chosen within the retention time window from that chosen by the

software for that compound and also a manual integration of the chosen peak has been performed. The

manual integration was performed in order to provide the most accurate area count possible for the peak.

- Denotes that the data reviewer or GC/MS operator has selected an alternate library search. This is

typically done when an additional tentatively identified compound (TIC) has been added to the number of

peaks searched. No manual integration is performed in choosing an alternate peak. The software still

performs the integration.

- Denotes that an alternate library search has been selected and a manual integration has also been

performed. This is typically done when an additional TIC has been added and the TIC peak also required a

manual integration.

The EPA CLP SOW requires additional explanations for manual editing/integration. In the accompanying raw data

packages, additional codes have been applied to the “M” flag and carry the following meanings;

Ml - The compound was not found by the automatic integration routine.

M2 - The compound was incorrectly integrated by the automatic integration routine.

M3 - The co-eluting compounds were incorrectly integrated by the automatic integration routine.

These codes will appear in the GC/MS and GC data packages.

Robert E. MeiererVice President

M

H

MH

ML

Revision 5 (10/27/99)

34

CompuChema division of Libert}' Analytical Corporation

DATA REPORTING QUALIFIERS

On the Form 1, under the column labeled “Q” for qualifier, each result is flagged with the specific data reporting qualifiers listed below, as appropriate. Up to five qualifiers may be reported on Form I for each

compound. The qualifiers used are:

U : This flag indicates the compound was analyzed for but not detected. The Contract Required

Quantitation Limit (CRQL), or reporting limit, will be adjusted to reflect any dilution and, for

soils, the percent moisture.

J : This flag indicates an estimated value. The flag is used as detailed below:

1. When estimating a concentration for tentatively identified compounds (TICs) where a

response factor of 1.0 is assumed for the TIC analyte,

2. When the mass spectral and retention time data indicate the presence of a compound that meets the volatile and semivolatile GC/MS identification criteria, and the result is less than the

CRQL (or Reporting Limit) but greater than zero, and

3. When the retention time data indicate the presence of a compound that meets the

pesticide/Aroclor or other GC or HPLC identification criteria, and the result is less than the

CRQL (or Reporting Limit) but greater than zero. For example, if the CRQL (or Reporting Limit)

is 10 pg/L, but a concentration of 3 pg/L is calculated, it is reported as 3J.

N : This flag indicates presumptive evidence of a compound. This flag is only used for TICs, where

the identification is based on a mass spectral library search. For generic characterization of a TIC

such as ‘chlorinated hydrocarbon’, the N flag is not used.

P : In the EPA’s Contract Laboratory Program (CLP), this flag is used for a pesticide/Aroclor target

analyte, when there is greater than 25% difference for detected concentrations between the two

GC columns. The lower of the two values is reported on Form I and flagged with a P.

For SW-846 GC and HPLC analyses, when the Relative Percent Difference (RPD) is greater than 40% and there is no evidence of chromatographic anomalies or interferences, then the higher of

the two values is reported and flagged with a P. When the RPD is equal to or less than 40%, our

policy is to also report the higher of the two values, although the choice could be a project

specific issue.

35

DATA REPORTING QUALIFIERS (continued)

C : This flag applies to GC or HPLC results where the identification has been confirmed by GC/MS.

If GC/MS confirmation was attempted but was unsuccessful, this flag is not applied; a laboratory- defined flag is used instead (see the X/Y/Z qualifier.)

B : This flag is used when the analyte is found in the associated blank as well as in the sample. Itindicates probable blank contamination and warns the data user to take appropriate action. This flag is used for a TIC as well as for a positively identified target compound. The combination of

flags BU or UB is not an allowable policy. Blank contaminants are flagged B only when they are

detected in the sample.

E : This flag identifies compounds whose concentrations exceed the upper level of the calibration

range of the instrument for that specific analysis. If one or more compounds have a response

greater than the upper level of the calibration range, the sample or extract will be diluted and reanalyzed. All such compounds with a response greater than the upper level of the calibration

range will have the concentration flagged with an E on Form I for the original analysis.

D : If a sample or extract is reanalyzed at a higher dilution factor, for example when the

concentration of an analyte exceeds the upper calibration range, the DL suffix is appended to the

sample number on Form I for the more diluted sample, and all reported concentrations on that

Form I are flagged with the D flag. This flag alerts data users that any discrepancies between the

reported concentrations may be due to dilution of the sample or extract.

NOTE 1: The D flag is not applied to compounds which are not detected in the sample analysis i.e.

compounds reported with the CRQL (or Reporting Limit) and the U flag.

NOTE 2: Separate Form Is are used for reporting the original analysis (Client Sample No. XXXXX) and the more diluted sample analysis (Client Sample No. XXXXXDL) i.e. the results from both

analyses are not combined on a single Form I.

A : This flag indicates that a TIC is a suspected aldol-condensation product.

X/Y/Z : Other specific flags may be required to properly define the results. If used, the flags will be fully

described in the SDG Narrative. The laboratory-defined flags are limited to X, Y and Z.

36Revision 6 (12-14-00)

Laboratory Notice

Calibration Date(s): 08-FEB-2002 11:14

Instrument ID: 5972hp73

08-FEB-2002 13:15

An initial calibration was analyzed by Method 8260B. Per the methodology, all compounds are to meet a Percent Relative Standard Deviation (%RSD) limit of no more than 15%. Additional calibration options are provided in the method when the RSD exceeds 15%. CompuChem has chosen to apply the option of determining the mean RSD values for all analytes in the initial calibration.

When there are analytes with %RSDs greater than the limit, proof of calibration linearity can be shown if the average of all compounds in the initial calibration meet the same 15% limit. Based on Method 8260B,Sec. 7.3.8.2, and Method 8000B, Sec. 7.5.1.2 requirements, we are providing a list of the compounds which failed to meet the limit, and their associated %RSDs. Finally, the average of all %RSDs from all compounds in the initial calibration is shown, confirming the usability of the initial calibration and any data that follows it.

Compound Name RSD

Bromomethane 15.6Acetone 41.1Methyl acetate 25.4Methylene Chloride 16.2Crotonaldehyde 23.9Bromodichloromethane 15.3

^cchloroethyl vinyl ether 58.8^■Luene 15.6^Fhexanone 18.51,2-Dibromo-3-Chloropropane 44.2

Average %RSD for all compounds in the Initial Calibration: 10.3 %

Data Reviewer/ID: /

Date : 2-M lj b~t~

37

• B. Chains-of-Custody

The laboratory shall include a copy of the Chain-

of-Custody (CoC) documentation for all of the

samples in the SDG. The CoC documents shall be

arranged in increasing Client Sample ID number

order, considering both letters and numbers.

COMPUCHEM

Login Chain of Custody Report (In01) Page: 1 of 1Feb. 08, 2002 11:13 AM

Login Number: QZ1877

Account: ESC Environmental Strategies Corporation

Project: EMERSON AVA, MO 139359/2

Case: Q1877

Laboratory Client Collect Receive DueSample Number Sample Number Date Date PR Date Comments

QZ1877-1 MW-22A 06-FEB-02 08-FEB-02 g 12-FEB-02 PPS 985**VOC 8260B TCL3CT.SUB**LCS ONLY

Water S VOA-8260B-25ML Hold: 20-FEB-02 40ml vial 3 Bottles

6Z1877-2 TRIPBLANK 06-FEB-02 08-FEB-02 9 12-FEB-02 PPS 985**TRIP BLK**VOC8260B TCL3CT.SUB**LCSONLY

Water S VOA-8260B-25ML Hold: 20-FEB-02 40ml vial 1 Bottles

CompuChem order log - in verification

a division of Liberty Analytical Corp.

Were all sample IDs correctly entered?

Were all analyses entered into LIM system?

Were the correct methods entered into LIM system?

Is the receiving log header complete?

Were all blank lines z'ed out?

Was TAT correctly entered?

Was QC designated?

^jîe field COC complete (signed, dated, etc.)?

Were all comments/issues recorded on COC?

Was temperature recorded on log-in sheet and COC?

Was EDD folder and PPS established?

(g?/ No / NA

es-- / No / NA

:ei / No / NA

Yak I No / NA

/ No / NA

Yes / No / NA

s) / No / NA

es) / No / NA

(ifes)/ No / NA

Were all pH's readings recorded on log-in sheet and COC? Yes / No /

es)/ No / NA

es / No

Signature JtiP Date cp/f (,

CORRECTIVE ACTION

(

C. SDG Data

1. QC Summary

2. Sample Data

3. Standards Data

4. Raw QC Data

LAB CODE : LIBRTY METHOD:

CASE # :______________ SDG # : '

• 1. QC Summary

a. Surrogate Recovery Summary (Form II VOA)

b. Spike Summary - MS / MSD / LCS

(Form III VOA)

c. Method Blank Summary (Form IV VOA)

d. GC/MS Instrument Performance Check

(Form V VOA)

e. Internal Standard Area and RT Summary

(Form VIII VOA)

a. Surrogate Recovery Summary

(Form II VO A)

45

FORM 2WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY

Lab Name: COMPUCHEM Contract: 826OB


| CLIENT SMCl 1 SMC2 1 SMC3 SMC4 |tot|| SAMPLE NO.1

(DBF)# 1I(DCE)# 1 (TOL)# (BFB)# j OUT j

1 1i011VBLKLI 91

11 87

11 100 90 1 °l

02 jVLILCS 98 1 88 1 103 92 1 0103|TRIPBLANK 115 1 111 1 100 101 1 0104 j MW-22A05 j

118 11

115 11

108 99 1 011 1

06 | 1 1 1 107 | 1 1 1 108 | 1 1 1 109 | 1 1 1 110 | 1 1 1 111 1 1 1 1 112 | 1 1 1 113 I 1 1 1 114 | 1 1 1 115 | 1 1 1 116 | 1 1 1 117 | 1 1 1 118 | 1 1 1 119 | 1 1 1 120 | 1 1 I 121 I 1 1 122 | 1 1 1 123 | 1 1 1 124 | 1 1 1 125 | 1 1 1 126 | 1 1 1 127 | 1 1 1 128 | 1 1 1 1

SMCl (DBF) SMC2 (DCE) SMC3 (TOL) SMC4 (BFB)

Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 Bromofluorobenzene

QC LIMITS (65-150) (59-150) (61-145) (63-143)

# Column to be used to flag recovery values

* Values outside of contract required QC limits

D System Monitoring Compound diluted out

page 1 of 1 FORM II VOA

b. Spike Summary - MS / MSD / LCS (Form III VO A)

3AWATER VOLATILE LAB CONTROL SAMPLE

Lab Name: COMPUCHEM


Contract: 8260B

SAS No.:

VLILCS

SDG No.: QZ1877

COMPOUND

SPIKEADDED(ug/L)

. LCSCONCENTRATION

(ug/L)

LCS%

REC #

QC.LIMITSREC.

1,1-Dichloroethene 5.00 5.50 110 50-150Benzene 5.00 5.09 102 76-134Trichloroethene 5.00 5.26 105 71-143Toluene 5.00 4.72 94 70-137Chlorobenzene 5.00 4.98 100 74-136

# Column to be used to flag recovery and RPD values with an asterisk

* Values outside of QC limits

Spike Recovery: 0 out of 5 outside limits 1

COMMENTS:

FORM III VOA-148

c. Method Blank Summary (Form IV VO A)

If more than a single form is necessary, forms shall be

arranged in chronological order by date of analysis of the

blanks, by instrument.

CLIENT SAMPLE NOFORM 4VOLATILE METHOD BLANK SUMMARY

Lab Name: COMPUCHEM Contract:

Lab Code: LIBRTY Case No.: SAS No.:


Date Analyzed: 02/11/02 .



8260BVBLKLI

SDG No.: QZ1877


Time Analyzed: 0935


THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:

LAB LAB TIMESAMPLE NO. SAMPLE ID ■ FILE ID ANALYZED

01 VLILCS WG15582-5 WG15582-5A73 101702 TRIPBLANK QZ1877-2 QZ1877-2A73 164603 MW-22A QZ1877-1 QZ1877-1RA73 1922040506070809101112131415161718192021222324252627282930

COMMENTS:

ge 1 of 1FORM IV VOA

d. GC/MS Instrument Performance Check (Form V VOA)


arranged in chronological order, by instrument.

51

FORM 5VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK

BROMOFLUOROBENZENE (BFB)



Lab File ID: BF020208A73


GC Column: ZB-624 ID: 0.32

Contract: 8260B

SAS No. : SDG No. QZ1877

BFB Injection Date: 02/08/02

BFB Injection Time: 0808

(mm) Heated Purge: (Y/N) N

% RELATIVEm/e ION ABUNDANCE CRITERIA ABUNDANCE

50 15.0 - 40.0% of mass 95 27.575 30.0 - 60.0% of mass 95 55.095 ■ Base Peak, 100% relative abundance 100.096 5.0 - 9.0% of mass 95 6.7

173 Less than 2.0% of mass 174 0.1 ( 0.2)1174 50.0 - 100.0% of mass 95 74.2175 5.0 - 9.0% of mass 174 5.6 ( 7.5)1176 95.0 - 101.0% of mass 174 71.2 ( 95.9)1177 5.0 - 9.0% of mass 176 4.7 ( 6.7)2

1-Value is % mass 174 2-Value is % mass 176

THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

EPA LAB LAB DATE TIMESAMPLE NO. SAMPLE ID FILE ID ANALYZED ANALYZED

01 VSTD005 VSTD005 CU020208A73 02/08/02 111402 VSTD001 VSTD001 CV020208A73 02/08/02 115603 VSTD0.5 VSTD0.5 CW020208A73 02/08/02 122304 VSTD010 VSTD010 CX020208A73 02/08/02 124905 VSTD025 VSTD025 CY020208A73 02/08/02 13150607080910111213141516171819202122

page 1 of 1FORM V VOA

52

FORM 5VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK

BROMOFLUOROBENZENE (BFB)


Lab Code: LIBRTY Case No.:.

Lab File ID: BF020211A73



Contract: 8260B


BFB Injection Date: 02/11/02

BFB Injection Time: 0738


% RELATIVEm/e ION ABUNDANCE CRITERIA ABUNDANCE

50 15.0 - 40.0% of mass 95 ' . 25.875 30.0 - 60.0% of mass 95 53.895 Base Peak, 100% relative abundance 100.096 5.0 - 9.0% of mass 95 6.8

173 Less than 2.0% of mass 174 0.0 1 0.0)1174 50.0 - 100.0% of mass 95 70.7175 5.0 - 9.0% of mass 174 5.6 1 7.9)1176 95.0 - 101.0% of mass 174 69.6 ( 98.5)1177 5.0 - 9.0% of mass 176 4.7 ( 6.8)2

1-Value is % mass 174 2-Value is % mass 176

THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

page

010203040506

EPASAMPLE NO.

VSTD005VBLKLIVLILCSTRIPBLANKMW-22A

LABSAMPLE ID

VSTD005WG15582-2 WG15582- 5 QZ1877-2 QZ1877-1

LABFILE ID

CS020211A73 WG15582-2A73CT WG15582-5A73CT QZ1877-2A73 QZ1877-1RA73

DATEANALYZED

02/11/0202/11/0202/11/0202/11/0202/11/02

TIMEANALYZED

08380935101716461922

07080910111213141516171819202122

FORM V VOA

53

Internal Standard Area and RT Summary (Form VIII VO A)


arranged in chronological order, by instrument.

54

FORM 8VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY

|Lab Name: COMPUCHEM - Contract: 8260B


Lab File ID (Standard): CS020211A73 Date Analyzed: 02/11/02

Instrument ID: 5972HP73 Time Analyzed: 0838

GC Column: ZB-624 ID: 0.32 (mm) Heated Purge: (Y/N) N

0102030405

12 HOUR STD UPPER LIMIT LOWER LIMIT

CLIENT SAMPLE NO.

VBLKLIVLILCSTRIPBLANKMW-22A

IS1(FBZ) AREA #

19493638987297468

192058180905151859166793

RT #

10.32 10.829.82

10.3210.3110.32 10.31

IS2(CBZ) AREA #

130390 ' 260780

65195

127336122235108692115604

RT #

13.1613.6612.66

13.1613.1613.1513.15

IS3(DCB) AREA #

6654613309233273

61339584685187456817

RT #

14.8615.3614.36

14.8514.8614.8614.85

06A 07

08

1011121314151617181920

151 (FBZ)152 (CBZ)153 (DCB)

FluorobenzeneChlorobenzene-d51,4-Dichlorobenzene-d4

AREA UPPER LIMIT = +100% of internal standard area AREA LOWER LIMIT = - 50% of internal standard area RT UPPER LIMIT = + 0.50 minutes of internal standard RT RT LOWER LIMIT = - 0.50 minutes of internal standard RT

# Column* Values

page 1 of 1

used to.flag values outside QC limits with an asterisk, outside of QC limits.

FORM VIII VOA

55

2. Sample DataSample data shall be arranged in packets with the Organic Analysis

Data Sheet (Form I VOA, and-Form I VOA-TIC), followed by the raw data

for volatile samples. These sample packets shall be placed in increasing

Client Sample ID number order, considering both letters and numbers.

a. Target Analyte Results (Form I VOA)

Tabulated results (identification and quantitation) shall be included.

b. Tentatively Identified Compounds (Form I VOA-TIC)

Lists the client specified number of organic compounds that are

non-surrogate/non-intemal standard compounds and are not listed

on the target compound list. This form shall be included even

if no compounds are found.

c. Reconstructed Ion Chromatograms

Include for each sample or sample extract, including dilutions and

reanalyses. The RIC shall contain the following header information:

Client Sample ID number, date and time of analysis, GC/MS

instrument identifier, lab file identifier, and analyst ID.

d. Quantitation Report showing calculations for target analytes

- Include a printout of the Enhanced Ion Current Profile (EICP) for

all manual changes to all compounds, internal standards, and

surrogate compounds.

e. Copies of raw spectra and copies of background-subtracted

mass spectra of target analytes identified in the sample.

- The spectra shall include the following information: Client Sample

ID number, Lab file ID, date and time of analysis, and instrument ID.

- The compound name must be clearly marked.

f. Quantitation Report showing calculations for TICs

g. Copies of mass spectra of organic compounds not listed

on the target compound list (TICs) with associated

best-match spectra.

- The spectra shall be labeled as follows: Client Sample ID number,

lab file ID, date and time of analysis, and instrument ID.

- The compound name must be clearly marked. s


CLIENT SAMPLE NO.

ab Name: COMPUCHEM

Lab Code: LIBRTY


Sample wt/vol:

Level: (low/med)


GC Column: ZB-624


Case No.:

WATER

25 (g/ml)' ML

LOW

ID: 0.32 (mm)

___(uL)

Method: 8260BMW-22A









74- 87-3-------- Chloromethane75- 01-4-------- Vinyl Chloride74- 83-9-------- Bromome thane75- 00-3-------- Chloroethane ______75-35-4---------1,1 -Dichloroethene75-15-0---------Carbon disulfide67-64-1--------- Acetone____ _______________75-09-2---------Methylene Chloride ~156-60-5--------trans-1,2 -Dichloroethene_75-34-3---------1,1-Dichloroethane156-59-2--------cis-1,2 -Dichloroethene78- 93-3-------- 2 -butanone67-66-3---------Chloroform______ _________71-55-6---------1,1,1 -Trichloroethane56-23-5--------- Carbon Tetrachloride______71-43-2--------- Benzene ______ ____________107- 06-2------- 1,2-Dichloroethane79- 01-6-------- Trichloroethene78- 87-5-------- 1,2-Dichloropropane_______75-27-4---------Bromodichlorome thane10061-01-5------cis-1,3-Dichloropropene__108- 10-1------- 4 - Methyl -2 - pentanone108-88-3--------Toluene ___________10061-02-6------trans-1,3-Dichloropropene79- 00-5-------- 1,1,2 -Trichloroethane127-18-4--------Tetrachloroethene591-78-6--------2 - hexanone_________________124-48-1--------Dibromochloromethane ~108-90-7--------Chlorobenzene _____100-41-4--------Ethylbenzene108-38-3--------m, p-Xylene95-47-6---------o-Xylene___________________100-42-5--------Styrene

UUUUuuJBUJU

UUUuuuJBUUUUUUUJBUUUUUUU

FORM I VOA

57


CLIENT SAMPLE NO.


Lab Code: LIBRTY


Sample wt/vol:

Level: (low/med)


GC Column: ZB-624


Case No.:

WATER

25 (g/ml)' ML

LOW

ID: 0.32 (mm)

_______ (uL)

Method: 8260BMW-22A









75-25-2--------- Bromoform 6 U79-34-5---------1,1,2,2 -Tetrachloroe thane 6 U1330-20-7-------Xylene (total) 6 u

/

FORM I VOA

58

Y <xl0^6)

CDin

Data File: /chem/5972hp73.i/DF020211A73.b/QZ1877-lRA73.d

Date : ll-FEB-2002 19:22

Client ID: MW-22A

Sample Info:

Purge Volume: 25.0

Column phase: ZB-624

Instrument: 5972hp73.i

Operator: 2323

Column diameter: 0.32

<x!0A6>

Data File: /chem/5972hp73. iZDF020211A73.b/QZ1877-lA73.d

Date : ll-FEB-2002 18:46

Client ID: HW-22A

Sample Info: 50X DILUTION SCREEN OF MW-22A

Purge Volume: 25,0


oCD


Operator: 2423

Column diameter: 0,32

Data File: /chem/5972hp73.i/DF020211A73.b/QZ1877-1RA73.dReport Date: 12-Feb-2002 10:30

CompuChem

Data file Lab Smp Id Inj Date Operator Smp Info Misc Info

SW846 UPDATE III METHOD 8260B QUANT & RATIO REPORT /chem/5972hp73.i/DF020211A73,b/QZ1877-lRA73.d QZ1877-1 Client Smp ID: MW-22All-FEB-2002 19:222323 Inst ID: 5972hp73.i

Comment Method Meth Date Cal Date Als bottle Dil Factor IntegratorTarget Version: 3.50

/chem/5972hp73.i/DF020211A73.b/W8260-B-25MLv6.m 12-Feb-2002 10:11 hubbard Quant Type: ISTD 08-FEB-2002 13:15 Cal File: CY020208A73.d2112.50000HP RTE Compound Sublist: TCL3CT.sub

Concentration Formula: Amt * DF * 1/( Vo) * CpndVariable

Name Value Description

DF 12.50000Vo 25.00000DF 12.50000

Dilution Factor volume of water dilution factor

d Variable Local Compound Variable

\

Compounds

QUANT SIG

MASS RT EXP RT REL RT RESPONSE

CONCENTRATIONS

ON-COLUMN FINAL

( ng) ( ug/L)

* 1 Fluorobenzene 96 10.311 10.320 (1.000) 166793 125.000

* 2 Chlorobenzene-d5 117 13.154 13.164 (1.000) 115604 125.000

* 3 1,4 -Dichlorobenzene-d4 152 14.846 14.856 (1.000) 56817 125.000

$ 4 Dibromofluoromethane 113 9.494 9.503 (0.921) 65461 147.538 73 . 77

<?v 5 1,2-Dichloroethane-d4 65 9.927 9.946 (0.963) 66987 143 . 560 71.78

<* 6 Toluene-d8 98 11.924 11.934 (0.906) 166376 135.554 67.78

$ 7 Bromofluorobenzene 95 14.000 14.010 (0.943) 65294 123.856 61.93

9 Chloromethane 50 Compound Not Detected.

10 Vinyl Chloride 62 Compound Not Detected.

11 Bromomethane 94 Compound Not Detected.

12 Chloroethane 64 Compound Not Detected.

16 1,1-Dichloroethene 96 Compound Not Detected

21 Carbon disulfide 76 Compound Not Detected

18 Acetone 43 6.572 6.591 (0.637) 3201 36.5852 18.29

24 Methylene Chloride 84 Compound Not Detected

27 trans‘1,2-Dichloroethene 96 7.585 7.604 (0.736) 717 1.97322 0.987

30 1,1-Dichloroethane 63 Compound Not Detected

Dt

Data File: /chem/5972hp73.i/DF020211A73.b/QZ1877-1RA73.dReport Date: 12-Feb-2002 10:30

Compounds

QUANT SIG

MASS RT EX P RT 1REL RT

34 cis-1,2-Dichloroethene 96 8.914 8.923 (0.864)

37 2-butanone 43 Compound Not Detected

42 Chloroform 83 Compound Not Detected

43 1,1,1-Trichloroethane 97 Compound Not Detected

48 Carbon Tetrachloride 117 Compound Not Detected

51 Benzene 78 Compound Not Detected


53 Trichloroethene 130 10.724 10.743 (1.040)

55 1,2-Dichloropropane 63 Compound Not Detected

59 Bromodichloromethane 83 Compound Not Detected

61 cis-1,3-Dichloropropene 75 Compound Not Detected

62 4-Methyl- 2-pentanone 43 Compound Not Detected

63 Toluene 92 Compound Not Detected

64 trans-1,3-Dichloropropene 75 Compound Not Detected


68 Tetrachloroethene 164 12.475 12.475 (0.948)

69 2-hexanone 43 Compound Not Detected

70 Dibromochloromethane 129 Compound Not Detected

72 Chlorobenzene 112 Compound Not Detected

75 Ethylbenzene 106 Compound Not Detected

76 m,p-Xylene 106 Compound Not Detected

77 o-Xylene 106 Compound Not Detected

78 Styrene 104 Compound Not Detected

79 Bromoform 173 Compound Not Detected

mk 1,1,2,2-Tetrachloroethane 83 Compound Not Detected

m Xylene (total) 106 Compound Not Detected

CONCENTRATIONS

ON-COLUMN FINAL

( ng) ( ug/L)

411.755 205.9

8.93237 4.47(a)

8.54892 4.27(a)

QC Flag Legend

a - Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).

Data File: 7chem75972hp73.i/,DF020211A73.b/QZ1877-lRA73.d

Date : il-FEB-2002 19:22

Client ID: HW-22A

ample Info:

Purge Volume: 25.0


Operator: 2323



18 Acetone - Concentration: 18.29 ug/L


Date : ll-FEB-2002 19:22

Client ID: MW-22A

' Sample Info;

Purge Volume

Column phase

25.0

ZB-624

Operator: 2323



27 trans-l,2-Dichloroethene Concentration: 0.987 ug/L

''-44Scan 513 <7.585 min) of QZ1877-lRA73.d

z6196m^ £8

36 39 42 45 48 51 54 57 60 63 66 69 72 75 78 81 84 87 90 93 96_______________________________________________________________ m/z___________________________________________________________________

&

»

400

360

320

280

240

20060

20

80

40

0

Scan 513 <7.585 min) of QZ1877-lRA73.d <Subtracted)^1

41

3N ■\

9&\ f»

36 39 42 45 48 51 54 57 60 63 66 69 72 75 78 81 84 87 90 93 96_______________________________________________________________ m/z___________________________________________________________________

10.09.0

8.07.0

~ 6.0ro 5.0

X 4,0

> 3.0

2.0 1.0

0.0

27 trans-l,2-Djchloroethene <Reference Spectrum)

/38 v Z*9III,.

z64 /74 94\

36 39 42 45 48 51 54 57 60 63 66 69 72 75 78 81 84 87 90 93 96

_______________________________________________________________ m/z______________________________________________________

100

80

60

40

20

£ -20

-80

-100

Scan 513 <7.585 min) of QZ1877-lRA73.d <X DIFFERENCE)

^441\

6^

36 39 42 45 48 51 54 57 60 63 66 69 72 75 78 81 84 87 90 93 96_____________________________________________________________________ m/z_______

Data File: /chem/5972hp73.i,'DF020211A73.b2QZ1877-lRA73.d

Date : ll-FEB-2002 19:22

Client ID: MW-22A

FSample Info:

Purge Volume

Column phase

25.0

ZB-624


Operator: 2323


34 cis-i,2-Dichloroethene Concentration: 205.9 ug/L

5


Date : ll-FEB-2002 19:22

Client ID: HW-22A

ample Info;

Purge Volume: 25.0


Operator; 2323

Column diameter; 0.32


53 Trichloroethene

1.8

1.61.4

1.21.0

0.80.60.4

0.20.0

Concentration: 4.47 ug/L

Scan 832 <10.724 min) of QZ1877-iRA73.d^95

6<\^

44^z47 ^2

82\

54\

13;N

36

40 50 60 70 80 90 100 110_____________________________m/z_____________________________________

120 130

m.

1.8- 1.6- 1.4-

1.2- 1.0- $.8-

6- .4-

0.2 0.0

•37

/

ll. I

Scan 832 <10*724 min) of QZ1877-lRA73*d. (Subtracted)

^-95

z47

B2\

94\

13;

36

40 50 60 70 80 90 100m/z________________________

110 120 130

10.09.0

8.07.0

6.05.0

4.0

3.0

2.0 1.0 0.0

100

80

60

40

20

* 0 £ -20

/37

53 Trichloroethene (Reference Spectrum)—95

6C\^

I I ,

^2

/70 ^2B2

lii..

94\

''TL30

4^36

. I40

-80

-100

V■37

40

50 60 70 80 90 100 110m/z

Scan 832 <10.724 min) of QZ1877-lRA73.d <X DIFFERENCE)

120

^9 8<\^ ysz 94\^ y''97

50 60 70 80 90 100 110____________________________m/z_____________________

120

130

4^36i • 1

130

Data File: 7chem,'5972hp73.i/DF020211A73.b/QZ1877-lRA73.d

Date : ll-FEB-2002 19:22

Client ID: MW-22A

■Sample Info:

Furge Volume: 25.0


Operator: 2323



68 Tetrachloroethene Concentration: 4.27 ug/L


Lab Name: COMPUCHEM Method : 8260BTRIPBLANK

Lab Code: LIBRTY Case No. : SAS No. : SDG No.: QZ1877


Sample wt/vol: 25 (g/ml)' ML Lab File ID: QZ1877-2A73


% Moisture: not dec. Date- Analyzed 02/11/02




74-87-3--------- Chloromethane 0.5 U75-01-4--------- Vinyl Chloride 0.5 U74-83-9--------- Bromome thane 0.5 U75-00-3--------- Chloroe thane 0.5 U75-35-4---------lf 1-Di chloroe thene 0.5 U75-15-0--------- Carbon disulfide 0.5 U67-64-1--------- Acetone 2 JB75-09-2--------- Methylene Chloride 0.2 J156-60-5--------trans-1,2-Dichloroethene 0.5 U75-34-3--------- 1,1-Dichloroethane 0.5 U156-59-2--------cis-1,2-Dichloroethene 0.5 U78-93-3--------- 2 -butanone 3 U67-66-3--------- Chloroform 0.5 U71-55-6---------1,1,1-Trichloroe thane 0.5 U56-23-5--------- Carbon Tetrachloride 0.5 U71-43-2--------- Benzene 0.5 U107-06-2--------1,2-Dichloroethane 0.5 U79-01-6--------- Trichloroe thene 0.5 U78-87-5--------- 1,2-Dichloropropane 0.5 U75-27-4--------- Bromodichloromethane 0.5 u10061-01-5------cis-1,3-Dichloropropene 0.5 u108-10-1-------- 4 -Methyl - 2 -pentanone 3 u108-88-3--------Toluene 0.2 JB10061-02-6----- trans-1,3-Dichloropropene79-00-5---------1,1,2 - Trichloroe thane

0.5 0.5

UU

127-18-4--------Tetrachloroethene 0.5 U591-78-6-------- 2 - hexanone 3 U124-48-1--------Dibromochloromethane 0.5 U108-90-7--------Chlorobenzene 0.03 J100-41-4--------Ethylbenzene 0.5 u108-38-3--------m,p-Xylene 1 u95-47-6--------- o-Xylene 0.5 u100-42-5-------- Styrene 0.5 u

FORM I VOA

63

FORM 1 CLIENT SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET __________ ■

TRIPBLANKLab Name: COMPUCHEM

Lab Code: LIBRTY

Method : 8260B

Case No. : SAS No. : SDG NO.: QZ1877


Sample wt/vol: 25 (g/ml) • ML Lab File ID: QZ1877-2A73




Soil Extract Volume: (uL) Soil Aliquot Volume:


75-25-2--------- Bromoform 0.5 U79-34-5---------1,1,2,2 - Tetrachloroethane 0.5 U1330-20-7-------Xylene (total) 0.5 U

FORM I VOA

G9

Y <xl<r5>

or~

Sample Info:

Purge Volume: 25.0 Operator; 2423

Column phase: ZB-624 Column diameter: 0,32

Data File: /chem/5972hp73.i/DF020211A73.b/QZ1877-2A73.d

Date : ll-FEB-2002 16;46Client ID: TRIPBLANK Instrument: 5972hp73.i

Data File: /chem/5972hp73.i/DF020211A73,b/QZ1877-2A73.d Report Date: 12-Feb-2002 10:30

CompuChem


SW846 UPDATE III METHOD 8260B QUANT & RATIO REPORT /chem/5972hp73.i/DF020211A73.b/QZ1877-2A73.d QZ1877-2 Client Smp ID: TRIPBLANKll-FEB-2002 16:462423 Inst ID: 5972hp73.i

CommentMethod Meth Date Cal Date Als bottle Dil Factor Integrator

/chem/5972hp73.i/DF020211A73 12-Feb-2002 10:11 hubbard 08-FEB-2002 13:15 171.00000 HP RTE

Target Version: 3.50

b/W8260-B-25MLv6.mQuant Type: ISTDCal File: CY020208A73.d

Compound Sublist: TCL3CT.sub


Name Value

DF 1.00000•Vo 25.00000DF 1.00000

Description


Variable Local Compound Variable

CONCENTRATIONS

Compounds

QUANT SIG

MASS RT EXP RT ;REL RT RESPONSE

ON-COLUMN

( ng)

FINAL

( ug/L)

* 1 Fluorobenzene 96 10.320 10.320 (1.000) 151859 125.000

* 2 Chlorobenzene-d5 117 13.154 13.164 Ci .ooo) 108692 125.000

* 3 1,4-Dichlorobenzene-d4 152 14.856 14.856 (1.000) 51874 125.000

$ 4 Dibromofluoromethane 113 9.494 9.503 (0.920) 58031 143.654 5.75

$ 5 1,2-Dichloroethane-d4 65 9.936 9 . 946 (0.963) 58873 138.578 5.54

s 6 Toluene-d8 98 11.924 11 . 934 (0.906) 144916 125.578 5.02

$ 7 Bromofluorobenzene 95 14.010 14.010 (0.943 ) 60892 126.512 5.06




12 Chloroethane 64 Compound Not Detected,

16 1,1-Dichloroethene 96 Compound Not Detected,

21 Carbon disulfide ' 76 Compound Not Detected.

18 Acetone 43 6.581 6.591 (0.638) 3560 44.6896 1.79

24 Methylene Chloride 84 7.240 7.240 (0.702) 1554 4.41393 0.177

27 trans-1,2-Dichloroethene 96 Compound Not Detected.

71

Data File: /chem/5972hp73.i/DF020211A73.b/QZ1877-2A73.d Report Date: 12-Feb-2002 10:30

w^pounds

QUANT SIG

MASS RT EXP RT REL RT


34 cis-1,2-Dichloroethene 96 Compound Not Detected

37 2-butanone 43 CompoUnd Not Detected

42 Chloroform 83 Compound Not Detected


46 Carbon Tetrachloride 117 Compound Not Detected

51 Benzene 78 Compound Not Detected


53 Trichloroethene 130 Compound Not Detected

55 1,2-Dichloropropane 63 Compound Not Detected

59 Bromodichloromethane 83 Compound Not Detected

61 cis-l,3-Dichloropropene 75 Compound Not Detected

62 4 -Methyl-2-pentanone 43 Compound Not Detected

63 Toluene 92 11.983 11.993 (0.911)

64 trans-l,3-Dichloropropene 75 Compound Not Detected


68 Tetrachloroethene 164 Compound Not Detected

69 2-hexanone 43 Compound Not Detected

70 Dibromochloromethane 129 Compound Not Detected

72 Chlorobenzene 112 13.183 13.183 (1.002)

75 Ethylbenzene 106 Compound Not Detected

76 m,p-Xylene 106 Compound Not Detected

77 o-Xylene 106 Compound Not Detected

78 Styrene 104 Compound Not Detected

Bromoform 173 Compound Not Detected

| 1,1,2,2-Tetrachloroethane 83 Compound Not Detected

W Xylene (total) 106 Compound Not Detected

RESPONSE

CONCENTRATIONS

ON-COLUMN FINAL

( ng) ( ug/L)

6.13770 0.246 (a)

0.72432 0.0290(a)

QC Flag Legend


72


Date : ll-FEB-2002 16:46

Client ID: TRIPBLANK

ample Info:

Purge Volume

Column phase

25.0

ZB-624

Operator; 2423


Instrument: 5972hp73,i

18 Acetone Concentration: 1.79 ug/L


Date : ll-FEB-2002 16:46


Sample Info:

Purge Volume: 25.0

Column phase: 2B-624

Operator: 2423



24 Methylene Chloride Concentration: 0.177 ug/L


Date : li-FEB-2002 16:46


^Sample Info:

Purge Volume

Column phase

25.0

ZB-624


Operator: 2423


63 Toluene Concentration: 0.246 ugZL


Date : ll-FEB-2002 16:46


I Sample Info:

Purge Volume: 25.0



Operator: 2423


72 Chlorobenzene Concentration: 0.0290 ug/L

. Standards Data

a. Initial Calibration Data (Form VI VO A)

b. Continuing Calibration Data (Form VII VOA)

a. Initial Calibration Data(Form VIVOA)

If more than one instrument is used, forms shall be

arranged in order by instrument. Multiple initial calibrations

from the same instrument shall be in chronological order.

Within each initial calibration, the standards are in order by

level, from lowest to highest.

(1) Reconstructed Ion Chromatograms and quantitation

reports for the initial (five-point) calibration.

Spectra not required.

(2) EICPs displaying each manual integration.

78

FORM 6VOLATILE INITIAL CALIBRATION DATA

Lab Name: COMPUCHEM

'Lab Code: LIBRTY Case No.:


Column: ZB-624 ID: 0.32 (mm)

Contract:

SAS No.:

Calibration

Calibration

LAB FILE ID: RFO.5: CW020208A73RF1: CV020208A73 RF5:RF10: CX020208A73 RF25: CY020208A73

8260B

SDG No.:

Date(s) : 02/08/02

Time(s): 1114

CU020208A73

| COMPOUND 1| RFO

15 |

1RF1 |

1 _RF5

11 RF10 RF25

|Chloromethane o525 j

0 .570 j

0 . 530 I 0 . 435 | 0 . 426|Vinyl Chloride o 435 | 0 . 482 j 0 . 449 j 0 . 389 | 0 . 398| Bromomethane o 364 j 0 . 344 | 0 . 299 j 0 . 276 j 0 . 248|Chloroethane o 239 | 0 . 282 j 0 . 230 | 0 . 204 j 0 . 20011,1-Dichloroethene 1 o 205 | 0 . 241 j 0 . 222 j 0 . 203 | 0 . 208| Carbon disulfide o 914 j 1. 044 j 0 . 990 j 0 . 893 j 0 . 923I Acetone o 103 j 0 . 085 | 0 . 049 | 0 . 050 | 0 . 041|Methylene Chloride 1 0 325 j 0 . 352 j 0 . 272 j 0 . 260 | 0 . 240|trans-1,2-Dichloroethene o 263 | 0 . 305 j 0 . 277 j 0 . 260 j 0 . 25811,1-Dichloroethane 1 0 542 j 0 . 639 | .0 . 584 | 0 . 549 | 0 . 533|cis-1,2-Dichloroethene o 258 | 0 . 302 j 0 . 281 j 0 . 266 j 0 . 262| 2-butanone o 079 | 0 . 080 | 0 056 | 0 . 067 | 0 062|Chloroform o 690 j 0 785 | 0 627 j 0 . 602 j 0 572

1,1-Trichloroethane 1 o 516 j 0 589 j 0 573 j 0 533 j 0 536Birbon Tetrachloride 1 0 431 j 0 518 | 0 490 | 0 452 j 0 466ffenzene 1 009 | 1. 187 | 1 081 j 1 039 1 05211,2-Dichloroethane o 384 j 0 439 j 0 388 j 0 406 0 377|Trichloroethene 0 259 | 0. 322 j 0 282 j 0 273 0. 27611,2-Dichloropropane 1 0 242 | 0 275 | 0 246 j 0 245 0 237|Bromodichloromethane 1 0 475 j 0 528 j 0 388 | 0 396 0 374|cis-1,3-Dichloropropene 1 0 303 j 0 373 | 0 355 j 0 376 0 373|4-Methyl-2-pentanone 1 0 175 | 0. 213 | 0 188 | 0 228 0 234|Toluene 1 116 j 1 320 | 1 002 | 0 913 0 942|trans-1,3-Dichloropropene 1 0 393 j 0 504 | 0 4511 0 460 0 468|1,1,2-Trichloroethane 1 0 194 | 0 243 j 0 210 j 0 224 0 212|Tetrachloroethene o 420 j 0 478 | 0 4111 0 387 0 418| 2-hexanone o 104 j 0 139 j 0 126 j 0 164 0 165|Dibromochloromethane o 342 | 0 396 j 0 320 | 0 338 0 .342|Chlorobenzene 1 0 959 | 1 065 | 0 997 j 0 947 0 993|Ethylbenzene 1 0 .449 j 0 581 j 0 533 | 0 .514 0 .540|m,p-Xylene 1 0 .588 | 0 693 | 0 .692 j 0 .641 0 .688|o-Xylene 1 0 541 j 0 674 j 0 . 641 j 0 .612 0 . 642|Styrene 1 0 .764 j 0 978 j 0 .970 | 0 966 1 . 018|Bromoform 0 .148 | 0 195 | 0 . 166 j 0 .191 0 .19311,1,2,2-Tetrachloroethane 0 .502 j 0 569 j 0 .495 | 0 .520 0 .523|Xylene (total) 1 0 . 541 j 0 .674 j 0 . 6411 0 .612 0 .642

| Dibromofluoromethane 0 .302 | 0 373 | 0 .332 | 0 .331 0 .325|1,2-Dichloroethane-d4 1 0 .341 | 0 .396 | 0 .337 j 0 .353 0 .322|Toluene-d8 1 1 . 175 j 1 .432 | 1 .388 j 1 .290 1 .351|Bromofluorobenzene 1 1

1

. 176 j

11 .2511

11 .162 |

11 . 080 1 .130

QZ1877

02/08/02

1315

FORM VI VOA

79


Lab Name: COMPUCHEM

Lab Code-: LIBRTY Case No.:



Contract: 8260B

SAS No.:

Calibration Date(s)

Calibration Time(s)

SDG No.:

02/08/02

1114

COMPOUND CURVE|COEFFICENT|1 A1 11 I

%RSD | MAXOR R~2 j OR

1

%RSD | R~2 j

Chloromethane AVRG1 1 | 0.49734884|

112.727| 90.000 j

Vinyl Chloride AVRG | 0.43075157j 8.891j 30.000 j

Bromomethane AVRG | 0.30617166 j 15.603 j 90.000 j

Chloroethane AVRG | 0.23113523 j 14.143 j 90.000 |1,1-Dichloroethene AVRG j 0.21593456 j 7.458 j 30.000 j

Carbon disulfide AVRG j 0.95291495 j 6.580 | 90.000 j

Acetone AVRG j 0.06557117 j 41.085 j 90.000 j

Methylene Chloride AVRG |'0.28979772 j 16.177 j 90.000 j

trans-1,2-Dichloroethene AVRG | 0.27231704 | 7.199 j 90.000 |1,1-Dichloroethane AVRG j 0.56932195 j 7.620 j 90.000 j

cis-1,2-Dichloroethene AVRG j 0.27392395 j 6.602 j 90.000 j

2-butanone AVRG j 0.06890000 j 14.944 | 90.000 |Chloroform AVRG j 0.65495978j 12.934 | 30.000 j

1,1,1-Trichloroethane AVRG j 0.54941606 | 5.505 j 90.000 j

£arbon Tetrachloride AVRG j 0.47148989| 7.164j 90.000 |

snzene AVRG j1.07371979 j 6.381j 90.000 jW, 2-Dichloroethane AVRG | 0.39897219 j 6.211j 90.000 j

Trichloroethene AVRG | 0.28240970 j 8.484 | 90.000 j

1,2-Dichloropropane AVRG | 0.24916397 j 6.039 j 30.000 j

Bromodichloromethane AVRG j 0.43213271j 15.328 j 90.000 j

cis-1,3-Dichloropropene AVRG | 0.35614252j 8.633 j 90.000 j

4-Methyl-2-pentanone AVRG jo.20787994 j 12.230 j 90.000 j

Toluene AVRG j1.05884484| 15.645 j 30.000 |trans-1,3-Dichloropropene 1,1,2-Trichloroethane

AVRGAVRG

| 0.45521867| j 0.21665506 j

8.829 j8.331j

90.000 j 90.000 j

Tetrachloroethene AVRG j 0.42282656 j 7.907 | 90.000 |2-hexanone AVRG j 0.13958014 | 18.474 j 90.000 j

Dibromochloromethane AVRG j 0.34767603 j 8.186 j 90.000 |Chlorobenzene AVRG j 0.99234847 j 4.642 j 90.000 jEthylbenzene AVRG j 0.52354157 j 9.183 | 30.000 j

m,p-Xylene AVRG | 0.66050747| 6.922 j 90.000 |o-Xylene AVRG j 0.62192266 j 8.109 j 90.000j

Styrene AVRG j 0.93932362 j 10.671j 90.000 jBromoform AVRG j 0.17853832 j 11.562 | 90.000 j

1,1,2,2-Tetrachloroethane Xylene (total)

AVRGAVRG

j 0.52204896|| 0.62192266 j

5.564 j8.109 |

90.000 j 90.000 j

1 | 1Dibromofluoromethane AVRG

1 1 “ | 0.33251524|

17.758| 90.000 j

1,2-Dichloroethane-d4 AVRG j 0.34969586| 8.042 | 90.000 |Toluene-d8 AVRG j1.32713732 | 7.512 j 90.000 |Bromofluorobenzene AVRG j1.15981607 j 5.419 j 90.000 j

1 1 1FORM VI VOA

QZ1877

02/08/02

1315

80


Lab Name: COMPUCHEM

*Lab Code: LIBRTY Case No.:



Contract: 8260B

SAS No.: SDG No.:

Calibration Date(s): 02/08/02

Calibration Time(s): 1114

| Average %RSD test result.

| Calculate Average %RSD: 10.84448051 j Maximum Average %RSD: 15.00000000

|Note: Passes Average %RSD Test.

FORM VI VOA

v

QZ1877

02/08/02

1315

81

<xl0~5>

cm

00

Sample Info:

Purge Volume: 25.0 Operator: 2421

Column phase: ZB-624 Column diameter; 0.32

Data File: /chem/5972hp73.i/DF020208A73.b/CW020208A73.d

Date : 08-FEB-2002 12:23

Client ID: VSTD0.5 - Instrument: 5972hp73.i

)ata File: /chem/5972hp73.i/DF020208A73,b/CW020208A73.ddeport Date: ll-Feb-2002 12:38

CompuChem

)ata file jab Smp Id Cnj Date Operator 5mp Info -lisc Info

SW846 UPDATE III METHOD 826OB QUANT & RATIO REPORT /chem/5972hp73.i/DF020208A73,b/CW020208A73.d VSTD0.5 Client Smp ID: VSTDO.508-FEB-2002 12:232421 Inst ID: 5972hp73.i

Tomment Method 'Ieth Date Pal Date ^ls bottle Dil Factor Cntegrator

/chem/5972hp73.i/DF020208A73.b/W8260-B-25MLv6.m ll-Feb-2002 12:38 hubbard Quant Type: ISTD 08 - FEB-2002 12:23 Cal File: CW020208A73.d6 Calibration Sample, Level:1.00000 HP RTE

Target Version: 3.50Processing Host: dante

Compound Sublist: all.sub

1

loncentration Formula.- Amt * DF * 1/( Vo) * CpndVariable


DF 1.00000 Dilution FactorVo 25.00000 volume of waterDF 1.00000 dilution factor

Variable Local Compound Variable

AMOUNTS

Compounds

QUANT SIG


CAL-AMT

( ng)

ON-COL

( ng)

* 1 Pluorobenzene 96 10.309 10.309 (1 - 000) 175707 125.000

* 2 Chlorobenzene-dS 117 13.152 13.152 (1.000) 118643 125.000


$ 4 Dibromofluoromethane 113 9.492 9.492 (0.921) 5299 12 . 5000 11.24

^ 5 1,2-Dichloroethane-d4 6 5 9 . 935 9.935 (0.964) 5990 12.5000 11.91

5 6 Toluene-d8 98 11.922 13.922 (0.906) 13940 12.5000 11 . 03

5 7 Bromofluorobenzene 95 14.008 14.008 (0.943) 6455 12.5000 12.29

a Dichlorodifluoromethane B5 3.402 3.402 (0.330) 6547 12 . 5000 11.75

9 Chloromethane 50 3.825 3.825 (0.371) 9223 12.5000 12 . 11

10 Vinyl Chloride 62 4.071 4.071 (0.395) 7648 12.5000 11.94

n B romome thane 94 4.828 4.628 (0.468) 6399 12.5000 13 . 56

12 Chloroethane 64 5.035 5.035 (0.488) 4204 12.5000 11.95

13 Trichlorofluoromethane 101 5.497 5.497 (0.533) 9464 12 . 5000 11.24

14 Diethylether 74 6.048 6.048 (0.587) 14233 125.000 120.8

15 Acrolein 56 6.324 6.324 (0.613) 3573 125.000 125.4

jtp-ft'ZA U 5 t~

83

Data File: /chem/5972hp73.i/DF020208A73.b/CW020208A73.dReport Date-. ll-Feb-2002 12:38

AMOUNTS

QUANT SIG CAL-AMT ON-COL

Compounds MASS RT EXP RT REL RT RESPONSE ( ng) ( ng)

16 1,1-Dichloroethene 96 6.442 6.442 (0.625) 3601 12.5000 11.50

17 1,1,1-trichloro-2,2,2-trifluo 117 6.363 , 6.363 (0.617) 3131 12 . 5000 12.28

20 1,1,2 -trichloro-1,2,2-trifluo 85 6.403 6.403 (0.621) 3409 12.5000 11.64

18 Acetone 43 6.580 6.580 (0.638) 9064 62.5000 81.63

19 lodomethane 142 6.727 6.727 (0.653) 7974 12 . 5000 11.50

21 Carbon disulfide 76 6.836 6.836 (0.663) 16070 12 . 5000 11.63

22 3-Chloropropene 39 7.032 7.032 (0.682) 9296 12.5000 11.45

23 Acetonitrile 41 7.032 7.032 (0.682) 11771 12 . 5000 12.25

163 Methyl acetate 43 7.062 7.062 (0.685) 3533 12.5000 15.18


25 Acrylonitrile S3 7.613 7.613 (0.738) 7040 125.000 120.2

26 tert-butyl alcohol 59 7.377 7.377 (0.716) 1932 125.000 121.0

27 trana-l,2-Dichloroethene 96 7.603 7.603 (0.738) 4617 12.5000 11.67

28 Methyl-tert-butyl ether 73 7.554 7.554 (0.733) 8823 12.5000 11.63

29 n-hexane 57 7.888 7.888 (0.765) 5898 12.5000 12.03

30 1,1-Dichloroethane 63 8.183 8.183 (0.794) 9523 12.5000 11.52

32 Vinyl acetate 43 8.183 8.183 (0.794) 19223 25.0000 22.19

33 Isopropyl ether 45 i 8.154 8.154 (0.791) 19049 12.5000 11.34

35 2,2-Dichloropropane 77 8.902 8.902 (0.864) 8551 12 . 5000 11.30

34 cis-1,2-Dichloroethene 96 8.912 8.912 (0.864) 4539 12.5000 11.51

3l Chloroprene 53 8.272 8.272 (0.802) 8511 12.5000 11.05

37 2-butanone 43 8.912 8.912 (0.864) 6975 62.5000 69.08

36 Propionitrile 54 9.030 9.030 (0.876) 13143 625.000 599.6

■k£8 Methyl acrylate 55 9.00U 9.000 (0.873) 18585 125.000 112.9

Methacrylonitrile 41 9,187 9.187 (0.891) 15317 125.000 109.5

40 Bromochloromethane 128 9.226 9.226 (0.895) 1856 12.5000 11.62

42 Chloroform 83 9.285 9.285 (0.901) 12118 12.5000 12 .31

41 Tetrahydrofuran 42 9.266 9.266 (0.899) 2831 50.0000 51.26

43 1,1,1-Trichloroethane 97 9.512 9.512 (0.923) 9075 12 . 5000 ,11.54

45 Pentafluorobenzene 168 9.453 9.453 (0.917) 9882 12.5000 11.23

44 Cyclohexane 84 9.561 9.561 (0.927) 4882 12.5000 11.32

46 1-chlorobutane 56 9.610 9.610 (0.932) 13283 12.5000 11.05

SO Isobutyl alcohol 43 9.797 9.797 (0.950) 4232 625.000 666.8

47 1,1-dichloropropene 75 9.699 9.699 (0.941) 6073 12.5000 11.02

48 Carbon Tetrachloride 117 9.718 9.718 (0.943) 7566 12.5000 11.22

Si Benzene 78 9.994 9.994 (0.969) 17728 12.500C 11.54

49 1,2-Dichloroethane 62 10.033 10.033 (0.973) 6745 12.5000 11.88

S2 Crotonaldehyde 41 10.358 10.358 (1.005) 4065 125.000 119.2

S3 Trichloroethene 130 10.722 10.722 (1.040) 4548 12.5000 11.24

S4 Methylcyclohexane 83 10.909 10.909 (1.058) 5222 12.5000 11.10

SS 1,2-Dichloropropane 63 10.997 10.997 (1.067) 4244 12.5000 11.87

S6 Dibromomethane 174 11.155 11.155 (1.082) 2276 12.5000 12.60

SB Methylmethacrylate 69 11.007 11.007 (1.068) 11457 125.000 108.4

S7 1,4-dioxane 88 11.116 11.116 (1.078) 808 625.000 622.5

S9 Bromodichloromethane 83 11.273 11.273 (1.094) 8344 12.5000 12.81

60 2-chloroethyl vinyl ether 83 11.499 11.499 (1.11S) 843 125.000 72.12

61 cis-1,3-Dichloropropene 75 11.686 11.686 (1.134) 5327 12.5000 11.02

Data File: /chera/5972hp73.i/DF020208A73.b/CW020208A73.dReport Date: ll-Feb-2002 12:38

Compounds

QUANT SIG

MASS RT EXP RT REL RT RBSPONSB

CAL-AMT

( ng)

ON-COL

( ng)

62 4-Methyl- 2-pentanone 43 11.775 11.775 (0.895) 10400 62.5000 57.02

63 Toluene 92 11.991 11.991 (0.912) 13242 12.5000 12.17

64 trans-1,3-Dichloropropene 75 12.178 12.178 (0.926) 4666 12.5000 10.94

66 Bthylmethacrylate 69 12.168 12.168 (0.925) 26788 125.000 106.8

65 1,1,2-Trichloroethane 97 12.355 12.355 (0.939) 2303 12.5000 11.25

67 1,3-Dichloropropane 76 12.503 12.503 (0.951) 4592 12.5000 11.81

68 Tetrachloroethene 164 12.473 12.473 (0.948) 4979 12.5000 12.03

69 2-hexanone 43 12.503 12.503 (0.951) 6186 62.5000 52.97

70 Dibromochloromethane 129 12.719 12.719 (0.967) 4059 12.5000 12.13

71 1,2-Dibromoethane 107 12.827 12.827 (0.975) 2462 12.5000 11.90

73 1-Chlorohexane ■ 55 13.073 13.073 (0.994) 6071 12.5000 11.40

72 Chlorobenzene 112 13.182 13.182 (1.002) 11380 12.5000 11.90

74 1,1,1,2-Tetrachloroethane 131 13.231 13.231 (1.006) 3954 12.5000 10.79

75 Bthylbenzene 106 13.221 13.221 (1.005) 5332 12.5000 10.78

76 m,p-Xylene 106 13.300 13.300 (1.Oil) 13964 25.0000 22.37

77 o-Xylene 106 - 13.605 13.60S (1.034) 6415 12.5000 10.93

78 Styrene 104 13.615 13.615 (1.035) 9063 12.5000 10.56

79 Bromoform 173 13.821 13.821 (1.051) 1759 12.5000 10.92

81 Isopropyl Benzene 105 13.851 13.851 (1.053) 20985 12.5000 11.54

80 cis-1,4-dichloro-2-butene 75 13 . 920 13.920 (1.058) 33204 500.000 449.9


84 Bromobenzene 156 14.146 14.146 (1.076) 4483 12.5000 11.37

83 1,2,3-Trichloropropane 110 14.146 14.146 (1.076) 744 12.5000 11.15

trans-1,4-dichloro-2-butene 53 14.116 14.116 (1.073) 38036 500.000 451.2

m6 n-Propyl Benzene 91 14.146 14.146 (0.952) 30806 12.5000 11.61^^87

2-Chlorotoluene 126 14.254 14.254 (0.960) 4274 12.5000 11.12

89 1,3,5-Trimethyl Benzene 105 14.244 14.244 (0.959) 14904 12.5000 11.36

88 4-Chlorotoluene 126 14.323 14.323 (0.964) 4175 12.5000 11.30

91 tert-Butyl Benzene 119 14.500 14.500 (0.976) 13741 12.5000 11.38

90 Pentachloroethane 167 14.569 14.569 (0.981) 2220 12.5000 11.82


93 sec-Butyl Benzene 105 14.658 14.65B (0.987) 19390 12.5000 11.64

94 1,3-Dichlorobenzene 146 14.805 14.805 (0.997) 8689 12.5000 11.88

95 p-Isopropyl Toluene 119 14.736 14.736 (0.992) 15262 12.5000 11.28


97 Benzyl Chloride 91 14.963 14.963 (1.007) 4042 12 . S000 10.43

99 n-Butyl Benzene 91 15.041 15.041 (1.013) 14808 12.5000 10.88


100 1,2-diethylbenzene 119 15.130 15.130 (1.019) 9478 12.5000 12.20

101 1,2-Dibromo-3-Chicropropane 75 15.799 15.799 (1.064) 950 12.5000 16.21

102 1,2,4-Trichlorobenzene 180 16.507 16.507 (1.111) 4661 12.5000 11.96

io: Hexachlorobutadiene 225 16.586 16.586 (1.117) .3279 12.5000 11.95

104 Naphthalene 128 16.793 16.793 (1.130) 4545 12.5000 10.92


M 106 1,2-Dichloroethene (total) 96 9156 25.0000 23.18

M 107 Xylene (total) 106 20379 12.5000 34.71

(x!0~5)

CO00

Sample Infoi


Column phase: ZB-624 Column diameter: 0.32

Data File: /chem/5972hp73.i/DF020208A73.b/CV020208A73.d

Date : 08-FEB-2002 11:56Client ID: VSTD001 Instrument: 5972hp73.i

Data File: /chem/5972hp73.i/DF020208A73,b/CV020208A73.dReport Date: ll-Feb-2002 12:38

CompuChem

Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Version: Processing Host:

SW846 UPDATE III METHOD 826OB QUANT & RATIO REPORT /chem/5972hp73.i/DF020208A73.b/CV020208A73.d VSTD001 Client Smp ID: VSTD00108-FEB-2002 11:562421 Inst ID: 5972hp73.i

/chem/5972hp73.i/DF020208A73,b/W8260-B-25MLv6.m ll-Feb-2002:12:38 hubbard Quant Type: ISTD08-FEB-2002 11:56 Cal File: CV020208A73.d5 Calibration Sample, Level:1.00000HP RTE Compound Sublist: all.sub

3.50 dante



DF Vo DF

Tid Variable

1.0000025.000001.00000


Local Compound Variable

AMOUNTS

Compounds

QUANT SIG


CAL-AMT

( ng)

ON-COL

( ng)

* 1 Pluorobenzene 96 10.314 10.314 (1.000) 153374 125.000

* 2 Chlorobenzene-dS 117 13 .158 13.158 (1.000) 105059 125.000



$ 5 1,2-Dichloroethane-d4 65 9.931 9.931 (0.963) 12138 25.0000 27.01

$ 6 Toluene-d8 98 11.928 11.928 (0.907) 30085 25.0000 25.39

$ 7 Bromofluorobenzene 95 14.004 14 . 004 (0.943) 13052 25.0000 2 5.93

8 Dichlorodifluoromethane 85 3.407 3 .407 (0.330) 12859 25.0000 25.66

9 Chloromethane 50 3.821 3 . 821 (0.370) 17493 25.0000 25.92

10 Vinyl Chloride 62 4.067 . 4.067 (0.394) 14802 25.0000 25.90

11 Bromomethane 94 4.824 4.824 (0.46a) 10545 25.0000 26.74

12 Chloroethane 64 5.031 5.031 (0.488) 8637 25.0000 27.51

13 Trichlorofluoromethane 101 5 . 503 5.503 (0.534) 19077 25.0000 24.70

14 Diethylether 74 6.044 6.044 (0.586) 28516 250.000 272.7

IS Acrolein 56 6.330 6.330 (0.614) . 6918 250.000 278.7

X' M I b

87

Data File: /chetn/5 972hp73 . i/DF020208A73 .b/CV020208A73 .dReport Date: ll-Feb-2002 12:38

QUANT SIG

Compounds MASS RT

16 1,1-Dichloroethene 96 6.448

17 1,1,l-trichloro-2,2,2-trifluo 117 6.359

20 1,1,2-trichloro-1,2,2 -trifluo 85 6.398

18 Acetone 43 6 . ■ 3 5

19 Iodoraethane 142 6.733

21 Carbon disulfide 76 6.831

22 3-Chloropropene 39 7.028

23 Acetonitrile 11 7.028

163 Methyl acetate 43 7.058

24 Methylene Chloride 84 7.235

2 5 Acrylonitrile 53 7.609

26 tert-butyl alcohol 59 7.392

27 trans-1,2-Dichloroethene 96 7.599

2S Methyl-tert-butyl ether 73 7.559

29 n-hexane 57 7.894

30 1,1-Dichloroethane 63 8.179

32 Vinyl acetate 43 .8.189

33 Isopropyl ether 45 8.160

35 2,2-Dichloropropane 77 8.898

34 cis-1,2-Dichloroethene 96 8.917

31 Chloroprene 53 8.278

37 2-butanone 43 8.917

36 Propionitrile 54 9.025

^3 8 Methyl acrylate 55 8.996

w* Methacrylonitrile 41 9.193

■^4 0 Bromochloromethane 128 9.222

42 Chloroform 83 9.291

41 Tetrahydrofuran 42 9.271

43 1,1,1-Trichloroethane 97 9 . 508

4b Pentafluorobenzene 168 9.448

44 Cyclohexane 84 9.557

46 1 -chlorobutane 56 9.606

50 Isobutyl alcohol 43 9 . 793

47 1,1-dichloropropene 75 9.704

48 Carbon Tet rach1oride 117 9.714

51 Benzene 78 9 . 990

49 1,2-Dichloroethane 62 10.029

52 Crotonaldehyde 41 10.354

53 Trichloroethene 130 10.728

.54 Methylcyclohexane 83 10.914

55 1,2-Dichloropropane 63 10.993

56 Dibromomethane 174 11.151

58 Methylmethacrylate 69 11.013

57 1,4-dioxane 88 11.Ill

59 Bromodichloromethane 83 11.269

60 2-chloroethyl vinyl ether 63 11 .495

61 cis-1, 3-Dichloropropene 75 11.682

AMOUNTS

CAL-AMT ON-COL

RBL RT RESPONSE ( ng) ( ng)

.(0.625) 7403 25.0000 26.03

(0.617) 5909 25.0000 26.33

(0.620) 6848 25.0000 25.90

(0.63B) 12991 125.000 158.3

(0.653) 15364 25.0000 24.42

(0.662) 32032 25.0000 25.66

(0.681) 19089 25.0000 25.83

(0.681) 22272 25.0000 26.30

(0.684) 5333 25.0000 29.40

(0.701) 10791 25.0000 28.19

(0.738) 14392 250.000 276.2

(0.717) 3919 250.000 276.8

(0.737) 9349 25.0000 26.21

(0.733) 18804 25.0000 27.44

(0.765) 11485 25.0000 26.35

(0.793) 19596 25.0000 26.12

(0.794) 43267 50 . 0000 54.17

(0.791) 40378 25.0000 26.31

(0.863) 17684 25.0000 25.53

(0.865) 9276 25.0000 25.92

(0.803) 18128 25.0000 25.50

(0.865) 12199 125.000 146.1

(0.875) 27237 1250.00 1395

(0.872) 40519 250.000 269.1

' (0.891) 35191 250.000 271.3(M)

(0.894) 3853 25.0000 26.70

(0.901) 24082 25.0000 27.80

(0.899) 5518 100.000 115.9

(0.922) 18072 25.0000 25.36

(0.916) 20664 25.0000 25.59

(0.927) 10388 25.0000 26.36

(0.931) 29549 25.0000 26.63

(0.949) 7313 1250.00 1366

(0.941) 13031 25.0000 25.56

(0.942) 15888 25.0090 25.69

(0.969) 36415 25.0000 26.17

(0.972) 13469 25.0000 26.53

(1.004) 8608 250.000 282.6

(1.040) 9892 25.0000 26.68

(1.058) 11261 25.0000 25.96

(1.066) 8446 25.0000 26.40

(1.081) 4221 25.0000 ) 26.88

(1.068) 26222 250.000 266.6

(1.077) 1421 1250.00 1252

Jl .093) 16183 25.0000 28.82

(1.114) 2632 250.000 212.9

(1.133) 11452 25.0000 25.62

83

EXP RT

6.448

6.359

6.398

6.58S

6.733

6.831

7.028

7.028

7.058

7.235

7.609

7.392

7.599

7.559

7.894

8.179

8.189

8.160

8.898

8.917

8.278

8.917

9.025

8.996

9.193

9.222

9.291

9.271

9.508

9.448

9.557

9.606

9.793

9.704

9.714

9.990

10.029

10.354

10.728

10.914

10 .'993

11.151

11.013

11 . Ill

11.269

11 .495

11.682

Data File: /chem/5972hp73.i/DF020208A73.b/CV020208A73.dReport Date: ll-Feb-2002 12:38

AMOUNTS


Compounds MASS RT EXP RT RBL RT RESPONSE ( ng) ( ng)

62 4-Methyl-2-pentanone 43 11.780 11.780 (0.895) 22349 125.000 132.5

63 Toluene 92 11.987 .11.987 (0.911) 27746 25.0000 28.43


66 Bthylmethacrylate 69 12.164 12.164 (0.924) 62265 250.000 261.3




69 2-hexanone 43 12.499 12.499 (0.950) 14574 125.000 131.0


71 1,2-Dibromoethane 107 12.833 12.833 (0.975) 5017 25.0000 26.73

73 1-Chlorohexane 55 13.079 13.079 (0.994) 12739 25.0000 25.86

72 Chlorobenzene 112 13.177 13.177 (1.001) 22383 25.0000 25.82


75 Ethylbenzene 106 13.217 13.217 (1.004) 12211 25.0000 26.08

76 m,p-Xylene 106 13.296 13.296 (1.010) 29118 50.0000 50.03

77 o-Xylene 106 13.601 13.601 (1.034) 14165 25.0000 25,63

78 Styrene 104 13.610 13 . 610 (1.034) 20558 25.0000 25.11

79 Bromoforra 173 13.827 13.827 (1.051) 4095 25.0000 27.02


80 cis-l,4-dichloro-2-butene 75 13 . 915 13.915 (1.058) 74625 1000.00 1087

82 1,1,2,2-Tetrachloroethane .83 14.092 14.092 (0.949) 5939 25.0000 26.75

84 B romobenz ene 156 14.152 14.152 (1.076) 9490 25.0000 26.00


trano-1,4-dichloro-2-butene 53 14.112 14.112 (1.073) 83490 1000.00 1066

n-Propyl Benzene 91 14.142 14.142 (0.952) 67573 25.0000 25.87

87 2-Chlorotoluene 126 14.260 14.260 (0.960) 9977' 25.0000 25.88


88 4-Chlorotoluene 126 14.329 14.329 (0.965) 9439 25.0000 25.66


90 Pentachloroethane 167 14.57S 14.575 (0.981) 4657 25.0000 25.41

92 1,2,4-Trimethyl Benzene 105 14,535 14.535 (0.979) 32523 25.0000 25.26

93 sec-Butyl Benzene 105 14.653 14.653 (0.987) 42158 25.0000 25.74




97 Benzyl Chloride 91 14.958 14.958 (1.007) 10352 25.0000 25.97

99 n-Butyl Benzene 91 15.047 15.047 (1.013) 35913 25.0000 26.07

98 1,2-Dichlorobenzene 146 15.175 15 . 175 (1.022) 15768 25.0000 27.02

100 1,2-diethylbenzene 119 15.126 15.126 (1.019) 20621 25.0000 27.59

101 1,2-Dibromo-3-Chloropropane 75 15.804 15.804 (1.064) 1622 25.0000 34.19


103 Hexachlorobutadiene 225 16.592 16.592 (1.117) 7390 25.0000 27.74

104 Naphthalene 128 16.798 16.798 (1.131) 11320 25.0000 26.92



M 107 Xylene (total) 106 43283 25.0000 78.32

Data File: /chem/5972hp73.i/DF020208A73,b/CV020208A73.dReport Date: ll-Feb-2002 12:38

Flag Legend

M - Compound response manually integrated.

Data File: /chem/5972hp73.i/DFO2O2O8A73.b/CVO2O2O0A?3.d Injection Date: 08-FEB-2002 11:56 Instrument: 5972hp73.i Client Sample ID: VSTD001

<9vOTX>

Instrument; 5972hp73.i

Operator: 2421


7chem/5972hp73.i7DF020208A73.b/CU020208A73.d

Data File: 7chem/5972hp73.i/DF020208A73.b/CU020208A73.d

Date : 08-FEB-2002 11;14

Client ID: VSTD005

Sample Info:

Purge Volume: 25.0


CM<7>

18 20

Data File: /chem/5972hp73.i/DF020208A73.b/CU020208A73.dReport Date: ll-Feb-2002 12:38

CompuChem


SW846 UPDATE III METHOD 8260B QUANT & RATIO REPORT /chem/5972hp73.i/DF020208A73,b/CU020208A73.d VSTD005 Client Smp ID: VSTD00508-FEB-2002 11:142421 Inst ID: 5972hp73.i

Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Version: Processing Host:

/chem/5972hp73.i/DF020208A73.b/W8260-B-25MLv6.m ll-Feb-2002 12:38 hubbard Quant Type: ISTD

2002 11:14 Cal File: CU020208A73.dCalibration Sample, Level:

08-FEB 41.00000 HP RTE

3.50 dante

Compound Sublist: all.sub

3



DF Vo DF

d Variable

1.0000025.000001.00000



AMOUNTS



* 1 Pluorobenzene 96 1 0.308 10.308 (1.000) 166592 125.000

* 2 Chlorobenzene-d5 117 13.151 13,151 (1.000) 110670 125.000


$ 4 Dibromofluoromethane 113 9.491 9.491 (0.921) 55277. 125.000 125.0


$ 6 Toluene-dS 98 11.922 11.922 (0.906) 153599 125.000 125.0

$ 7 Broraofluorobenzene 95 14.007 14.007 (0.943) 62279 125.000 125.0

e Dichlorodifluoromethane 85 3 . 401 3.401 (0.330) 66228 125.000 125.0

9 Chloromethane 50 3 . 824 3.824 (0.371) 88279 125.000 125.0

10 Vinyl Chloride 62 4.070 4.070 (0.395) 74822 125.000 125.0

11 Bromomethane 94 4.818 4.818 (0.467) 49805 125.000 125.0

12 Chloroethane 64 5.024 5.024 (0.487) 38342 125.000 125.0

13 Trichlorofluoromethane 101 5 . 506 5 . 506 (0.534) 106141 125.000 125.0

14 Diethylether 74 6.038 6.038 (0.SS6) 129058 1250.00 1250

IS Acrolein 56 6.323 6.323 (0.613) 29827 1250.00 1250

Al'Hb v

93

Data File: /chem/5972hp73.i/DF020208A73,b/CU020208A73.dReport Date: ll-Feb-2002 12:38



16 1,1-Dichloroethene 96 6.451 6.451 (0.626) 37023 125.000 125.0

17 1,1,l-trichloro-2,2,2 -trifluo 117 6.362 s 6.362 (0.617) 28860 125.000 125.0

20 1,1,2-trichloro-1,2,2-trifluo 85 6.402 6.402 (0.621) 34600 125.000 125.0

18 Acetone 43 6.569 6.569 (0.637) 40898 625.000 625.0

19 Iodomethane 142 6.736 6.736 (0.654) 87402 125.000 125.0

21 Carbon disulfide 76 6.835 6.835 (0.663) 164955 125.000 125.0

22 3-Chloropropene 39 7.022 7.022 (0.681) 96974 125.000 125.0

23 Acetonitrile 41 7.022 7.022 (0.681) 109033 125.000 125.0

163 Methyl acetate 43 7.051 7.051 (0.684) 20294 125.000 125.0


25 Acrylonitrile 53 7.612 7.612 (0.738) 63317 1250.00 1250

26 tert-butyl alcohol 59 7.376 7.376 (0.716) 17159 1250.00 1250

27 trans-1,2-Dichloroethene 96 7.592 7.592 (0.737) 46092 125.000 125.0


29 n-hexane 57 7.888 7.888 (0.765) 55986 125.000 125.0

30 1,1-Dichloroethene 63 8.183 8.183 (0.794) 97289 125.000 125.0

32 Vinyl acetate 43 8.183 8.183 (0.794) 198804 250.000 250.0

33 Isopropyl ether 45 8.163 8.163 (0.792) 197384 125.000 125.0


34 cia-l,2-Dichloroethene 96 8.911 8.911 (0.864) 46812 125.000 125.0

31 Chloroprene 53 8.281 8.281 (0.803) 94590 125.000 125.0

37 2-butanone 43 8.911 8.911 (0.864) 47124 625.000 625.0

36 Propionitrile 54 9.019 9.019 (0.875) 117123 6250.00 6250

ma Methyl acrylate 55 8.989 8.989 (0.872) 188870 1250.00 1250

Methacrylonitrile 41 9.186 9.186 (0.891) 161087 1250.00 1250 ("o

Bromochloromethane 128 9.226 9.226 (0.895) 18267 125.000 125.0

42 Chloroform 83 9.285 9.285 (0.901) 104410 125.000 12 5.0


43 1,1,1-Trichloroethane 97 9.511 9.511 (0.923 ) 95397 125.000 125.0


44 Cyclohexane 84 9.560 9.560 (0.927) 50592 125.000 125.0

46 1-chlorobutane 56 9.609 9.609 (0.932) 140817 125.000 125,0

50 Isobutyl alcohol 43 9.777 9.777 (0.948) 32992 6250.00 6250



5i Benzene 78 9.9e3 9.983 (0.968) 180126 125.000 125.0

49 1,2-Dichloroethane 62 10.032 10.032 (0.973) 64722 125.000 125.0

52 Crotonaldehyde 41 10.347 10.347 (1.004) 35963 1250.00 1250

53 Trichloroethene 130 10.731 10.731 (1.041) 46970 125.000 125.0

54 Methylcyclohexane 83 10.918 10.918 (1.059) 56638 125.000 125.0

55 1,2-Dichloropropane 63 10.997 10.997 (1.067) 40998 125 : 000 125.0

56 Dibromomethane 174 11.154 11.154 (1.082) 19724 125.000 125.0

58 Methylmethacrylate 69 11.006 11.006 (1.068) 124723 1250.00 1250

57 1,4-dioxane 88 11.115 11.115 (1.078) 7698 6250.00 6250

59 Bromodichloromethane 83 11.272 11.272 (1.094) 64577 125.000 125.0

6C 2-chloroothy] vinyl ether 63 11.498 11.498 (1.115) 19272 1250.00 1250


2.1 n6



Compounds MASS RT EXP RT REL RT RBSPONSB ( ng) ( ng)


63 Toluene 92 11.990 .11.990 (0.912) 110902 125.000 125.0

64 trana-l,3-Dichloropropene 75 12.177 12.177 (0.926) 49872 125.000 125.0

66 B t hy line thacry late 69 12.158 12.158 (0.924) 299473 1250.00 1250




69 2-hexanone 43 12.492 12.492 (0.9S0) 69785 625.000 625.0


71 1,2-Dibromoethane 107 12.827 12.827 (0.975) 22999 125.000 125.0

73 1-Chlorohexane 55 13.073 13.073 (0.994) 62630 125.000 125.0

72 Chlorobenzene 112 13.181 13.181 (1.002) 110372 125.000 125.0


75 Ethylbenzene 106 13.220 13.220 (1.005) 58991 125.000 125.0

76 m,p-Xylene 106 13.299 13.299 (1.011) 153159 250.000 250.0

77 o-Xylene 106 13.604 13.604 (1.034) 7093'5 125.000 125.0

78 Styrene 104 13.614 13.614 (1.035) 107369 125.000 125.0

79 Broraoform 173 13.820 13.820 (1.051) 18346 125.000 125.0


80 cis-1,4-dichloro-2-butene 75 13.919 13.919 (1.058) 329986 5000.00 5000


84 Bromobenzene 156 14.145 14.145 (1.076) 46153 125.000 12 5.0


trana-1,4-dichloro-2-butene 53 14.116 14.116 (1.073) 384929 5000.00 5000

w n-Propyl Benzene 91 14.145 14.145 (0.952) 323953 125.000 125.0

87 2-Chlorotoluene 126 14.253 14.253 (0.960) 47771 125.000 125.0


88 4-Chlorotoluene 126 14.322 14 .322 (0.9S4) 46009 125.000 125.0


90 Pentachloroethane 167 14.578 14.578 (0.981) 23153 125.000 125.0


93 sec-Butyl Benzene 1C5 14.657 14.657 (0.987) 204191 125.000 125.0



96 .1,4-Dichlorobenzene 146 14.873 14.873 (1.001) 82754 125.000 125.0

97 Benzyl Chloride 91 14.962 14.962 (1.007) 49226 125.000 125.0

99 n-Butyl Benzene 91 15.040 15.040 (1.013) 169433 125.000 125.0

98 1,2-Dichlorobenzene 146 IS.168 15.168 (1.021) 68934 125.000 125.0

100 1,2-diethylbenzene 119 15.119 15.119 (1.018) 86042 125.000 125.0

101 1,2-Dibrorao-3-Chloropropane 75 15.798 15.798 (1.064) 3853 125.000 125.0

102 1,2,4-Trichlorobenzene 180 16.506 16.506 (1.Ill) 45355 125.000 125.0


104 Naphthalene 128 16.792 16.792 (1.130) 49856 125.000 125.0

105 1,2,3-Trichlorobenzene 180 17.038 17.038 (1•147) 3 5 2 4 5 125.000 125.0


M 107 Xylene (total) 106 224094 125.000 394.9


Flag Legend

M - Compound response manually integrated.

96

Data File: /chem/5972hp73.i/DF020208A73.b/CU020208A73.d Injection Date: O0-FEB-2OO2 11:14 Instrument: 5972hp73.i Cl Lent Sample ID: VSTD005L^^ntmtnd: Methacry lomtnle

timber: 126-98-?

(xlOfc)

Data File: Xchem/5972hp73.i/DF020208A73.b/CX020208A73.d

Date : 08-FEB-2002 12:49

Client ID: VSTDOIO

Sample Info:

Purge Volume: 25.0


oo(D


Operator: 2421


Data File: /chem/5972hp73.i/DF020208A73.b/CX020208A73.dReport Date: ll-Feb-2002 12:38

CompuChem

SW846 UPDATE III METHOD 8260B QUANT & RATIO REPORT Data file : /chem/5972hp73.i/DF020208A73.b/CX020208A73.d Lab Smp Id: VSTD010 Client Smp ID: VSTD010Inj Date : 08-FEB-2002 12:49Operator : 2421 Inst ID: 5972hp73.iSmp Info :Misc Info :Comment :Method : /chem/5972hp73.i/DF020208A73,b/W8260-B-25MLv6.mMeth Date : ll-Feb-2002 12:38 hubbard Quant Type: ISTDCal Date : 08-FEB-2002 12:49 Cal File: CX020208A73.dAls bottle: 7 Calibration Sample, Level: 4Dil Factor: 1.00000Integrator: HP RTE Compound Sublist: all.subTarget Version: 3.50Processing Host: dante



tDF Vo DF

nd Variable

1.0000025.000001.00000



AMOUNTS

Compounds

QUANT SIG


CAL-AMT

( ng)

ON-COL

( ng)

* 1 Fluorobenzene 96 10.315 10.315 (1.000) 167338 125.000

* 2 Ch1oroben z ene-d 5 117 13.159 13.159 (1.000) 117858 125.000

★ 3 1,4-Dichlorobenzene-d4 152 14.851 14.851 (1.000) 59971 125.000



$ 6 Toluene-d8 98 11.929 11.929 (0.907) 304071 250.000 244.1

S 7 Bromofluorobenzene 95 14.005 14.005 (0.943) 129574 250.000 231.4

8 Dichlorodifluoromethane 85 3.398 3.398 (0.329) 112980 250.000 221.1

9 Chloromethane 50 3.821 3.821 (0.370) /145647 250.000 211.2

10 Vinyl Chloride 62 4.067 4.067 (0.394) ■ 130227 250.000 221.6

il Bromomethane 94 4.815 4.815 (0.467) 92352 250.000 215.1

12 Chloroethane 64 5.022 5.022 (0.487) 68331 250.000 213.8

13 Trichiorofluoromethane 101 5.504 5.504 (0.534) 169085 250.000 219.4

14 Diethylether 74 6.035 6.035 (0.585) 281395 2500.00 2506

15 Acrolein 56 6.330 6.330 (0.614) 69393 2500.00 2543

0-z-

99

Data File: /chem/5972hp73.i/DF020208A73,b/CX020208A73.dReport Date: ll-FeD-2002 12:38

AMOUNTS

Compounds

QUANT SIG


CAL-AMT

( ng)

ON-COL

( ng)

16 1,1-Dichloroethene 96 6.448 6.448 (0.625) 67825 250.000 232.6



18 Acetone 43 6.576 6.576 (0.638) 83664 1250.00 871.1

19 Iodomethane 142 6.734 6.734 (0.653) 165839 250.000 250.9


22 3-Chloropropene 39 7.029 7.029 (0.681) 184899 250.000 241.7

23 Acetonitrile 41 7.029 7.029 (0.681) 208946 250.000 233.4

163 Methyl acetate 43 7.058 7.058 (0.684) 43641 250.000 207.9


25 Acrylonitrile S3 7.609 7.609 (0.738) 146340 2500.00 2592

26 tert-butyl alcohol 59 7.383 7.383 (0.716) 42612 2500.00 2720



29 n-hexane 57 7.885 7.685 (0.764) 100828 250.000 223 . 6

30 1,1-Dichloroethane 63 8.180 8.180 (0.793) 183609 250.000 237.1

32 Vinyl acetate 43 8.190 8.190 (0.794) 447236 500.000 530.9

33 Isopropyl ether 45 8.160 6.160 (0.791) 411898 250.000 255.5

35 2,2 -Dich1oropropane • 77 8.898 8.898 (0.863) 162344 250.000 230.9


31 Chloroprene 53 8.278 8.278 (0.803) 182627 250.000 249.3

37 2-butanone 43 8.908 8.908 (0.864) 111690 1250.00 1182

36 Propionitrile 54 9.026 9.026 (0.875) 277375 12500.0 13080

Methyl acrylate 55 8.997 8.997 (0.872) 453641 2500.00 2785

m Methacrylonitrile 41 9.193 9.193 (0.891) 385057 2500.00 2781^^0

Bromochloromethane 128 9.223 9.223 (0.894) 39108 250.000 255.3

42 Chloroform 83 9.292 9.292 (0.901) 201312 250.000 222.5


43 1,1,1-Trichloroethane 97 9.508 9 . 508 (0.922) 178281 250.000 240.9'


44 Cyclohexane 84 9.557 9.557 (0.927) 93373 250.000 232.7

46 1-chlorobutane 56 9.617 9.617 (0.932) 275974 250.000 243.3

50 Isobutyl alcohol 43 9.784 9.784 (0.948) 89280 12500.0 14130



51 Benzene 78 9.990 9.990 (0.969) 347758 250.000 240.7

49 1,2-Dichloroethane 62 10.030 10.030 (0.972) 135846 250.000 251.0

52 Crotonaldehyde 41 10.345 10 . 345 (1.003) 59514 2500.00 1963


54 Methylcyclohexane 83 10.915 10.915 (1.058) 106167 2 S 0.000 240.0

55 1, 2-Dichloropropane 63 10.994 10.994 (1.066) 82159 250.000 243.4

56 Dibromomethane 174 11.151 11.151 (1.081) 42251 250.000 246.7

58 Methylmethacrylate 69 11.014 11.014 (1.068) 303346 2500.00 2867

57 1,4-dioxane 88 11.112 11.112 (1.077) 18758 12500.0 14400


60 2-chloroethyl vinyl ether 63 11.496 11.496 (1.114) 62086 2500.00 4265


100

Data File: /chem/5972hp73.i/DF020208A73.b/CX020208A73.dReport Date: ll-Feb-2002 12:38

AMOUNTS

Compounds

62 4-Methyl-2-pentanone

63 Toluene

64 trans-1,3-Dichloropropene

66 Ethylmethacrylate

65 1,1,2-Trichloroethane

67 1,3-Dichloropropane

68 Tetrachloroethene

69 2-hexanone

70 Dibromochloromethane

71 1,2-Dibromoethane

73 1-Chlorohexane

72 chlorobenzene

74 l,l,l,2-Tetrachloroethane

75 Ethylbenzene

76 m,p-Xylene

77 o-Xylene

78 Styrene

79 Bromoform

81 Isopropyl Benzene

80 cis-1,4-dichloro-2-butene

82 l, l,2,2-Tetrachloroethane

84 Bromobenzene

1,2,3-Trichloropropane

trans-1,4-dichloro-2-butene

86 n-Propyl Benzene

87 2-Chlorotoluene

89 1,3,5-Trimethyl Benzene

88 4-Chlorotoluene

91 tert-'Butyl Benzene

90 Pentachloroethane


93 aec-Butyl Benzene

94 1,3-Dichlorobenzene

95 p-Isopropyl Toluene


97 Benzyl Chloride

99 n-Butyl Benzene


100 1,2-diethylbenzene

101 l,2-Dibromo-3 -Chloropropane

102 .,2,4-Trichlorobenzene

103 Hexachlorobutadiene

104 Naphthalene

105 1,2,3-Trichlorobenzene

M 106 1,2-Dichloroethene (total)

M 107-Xylene (total)

QUANT SIG

MASS RT EXP RT REL RT

43 11.771 ,11.771 (0.895)

92 11.988 11.988 (0.911)

75 12.175 12.175 (0.925)

69 12.165 12.165 (0.924)

97 12.362 12.362 (0.939)

76 12.499 12.499 (0.950)

164 12.470 12.470 (0.948)

43 12 .499 12.499 (0.950)

129 12.716 12.716 (0.966)

107 12.834 12.834 (0.975)

55 13.080 13 . 080 (0.994)

112 13.178 13.178 (1.001)

131 13.227 13.227 (1.005)

106 13.218 13.218 (1.004)

106 13.296 13 .296 (1.010)

106 13.601 13.601 (1.034)

104 13.611 13 . 611 (1.034)

173 13.818 13.818 (1.050)

105 13.847 13.847 (1.052)

75 13.916 13.916 (1.058)

83 14.093 14.093 (0.949)

156 14.152 14.152 (1.076)

110 14.142 14.142 (1.075)

53 14.113 14.113 (1.073)

91 14.142 14.142 (0.952)

126 14.261 14.261 (0.960)

105 14.241 14.241 (0.959)

126 14.329 14.329 (0.965)

119 14.497 14.497 (0.976)

167 14.575 14.575 (0.981)

105 14.536 14.536 (0.979)

105 14.654 14.654 (0.987)

146 14.811 14.811 (0.997)

119 14.733 14.733 (0.992)

146 14.871 14.871 (1.001)

91 14.959 14.959 (1.007)

91 15.038 15.038 (1.013)

146 15.176 15.176 (1.022)

119 15.126 15.126 (1.019)

75 15.795 IS.795 (1.064)

180 16.514 16.514 (1.112)

225 16.592 16.592 (1.117)

128 16.799 16.799 (1.131)

180 17.035 17.035 (1.147)

96

106

CAL-AMT ON-COL

RBSPONSB ,( ng) ( ng)

269360 1250.00 1419

215190 250.000 209.8

108336 250.000 254.2

747166 2500.00 2856

52805 250.000 257.2

95581 250.000 248.1

91313 250.000 228.4

193448 1250.00 1539

79717 250.000 242.3

54365 250.000 260.7

122201 250.000 235.4

223248 250.000 238.6

88138 250.000 244.1

121269 250.000 247.6

302245 500.000 490.4

144286 250.000 248.0

227684 250.000 262.6

45049 250.000 273.0

412862 250.000 233 . 6

806165 10000.0 10750

62440 250.000 249.5

96549 250.000 247.3

16198 250.000 245.7

934030 10000.0 10840

671405 250.000 235.9

91583 250.000 225.3

332244 250.000 236.1

91599 250.000 232.3

304997 250.000 235.6

49458 250.000 243.3

335261 250.000 238.3

412150 250.000 231.9

178789 250.000 229.8

332014 250.000 230.5

174641 250.000 231.9

118104 250.000 271.1

330143 250.000 228.4

151038 250.000 232.2

171330 250.000 212.0

9147 250.000 160.0

98937 250.000 236.6

58215 250.000 205.7

124254 250.000 267.1

79983 250.000 236.2

175749 500.000 475.0

446531 250.000 767.6

(xl0~7>

Sample Info:



Data Filet /chem/5972hp73.i/DF020208A73.b/CY020208A73.d

Date : 08-FEB-2002 13:15

Client ID: VSTD025 Instrument: 5972hp73.i

102

Data File: /chem/5972hp73.i/DF020208A73.b/CY020208A73.dReport Date: ll-Feb-2002 12:38

CompuChem

Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Version: 3.50Processing Host: dante

SW846 UPDATE III METHOD 82 /chem/5972hp73.i/DF020208A73. VSTD02508-FEB-2002 13:15 2421

6OB QUANT & RATIO REPORT b/CY02 020 8A7 3.d Client Smp ID: VSTD025

Inst ID: 5972hp73.i

/chem/5972hp73.i/DF020208A73. ll-Feb-2002 12:38 hubbard 08 - FEB-2002 13:15 81.00000 HP RTE

b/W8260-B-25MLv6.m Quant Type: ISTD Cal File: CY020208A73.d Calibration Sample, Level: 5

Compound Sublistall. sub



*DFVoDF

nd Variable

1.0000025.000001.00000



AMOUNTS


Compounds MASS ' RT EXP RT REL RT RBSPONSE ( ng) ( ng)

* 1 Fluorobenzene 96 10.31-7 10.317 (1.000) 195835 125 . 000

* 2 Chlorobenzene-d5 117 13.160 13.160 (1.000) 131600 125.000

* 3 1,4-Dichlorobenzene-d4 152 14.852 14.852 (1.000) 6S303 125.000

$ 4 Dibroraofluoromethane 113 9.490 9.490 (0.920) 318174 625.000 610.8

$ 5 1,2-Dichloroethane-d4 65 9 . 933 9.933 (0.963) 314843 625.000 574.7

$ 6 Toluene-d8 98 11.930 11.930 (0.907) 888977 625.000 636.3(A)

$ 7 B romo f1uoroben z ene 95 ' 14.006 14.006 (0.943) 368984 625.000 ■ 609.0

8 Dichlorodifluoromethane 85 3 . 400 3 . 400 (0.330) 352145 625.000 595.7

9 Chloromethane 50 3 . 823 3 . 823 (0.371) 417583 625.000 535.9

10 Vinyl Chloride 62 4.069 4.069 (0.394) 389413 625.000 577.0

11 Bromomethane 94 4.787 4 . 787 (0.464) 242832 625.000 506.2

12 Chloroethane 64 5.013 5.013 (0.486) 196346 625.000 542.2

13 Trichlorofluoromethane 101 5.495 5.495 (0.533) 498657 625.000 565.9

14 Diethylether 74 6.037 6.037 (0.585) 751984 6250.00 5821

15 Acrolein 56 6.332 6.332 (0.614) 188436 6250.00 5968

103


Compounds

QUANT SIG


CAL-AMT

( ng)

ON-COL

( ng)

16 1,1-Dichloroethene 96 6.450 6.450 (0.625) 204153 625.000 603.5

17 1,1,1-1richloro-2,2,2 -trifluo 117 6.351 . 6.351 (0.616) 159571 625.000 590.6

2o 1,1,2 -1richloro-1,2,2-trifluo 65 6.391 6.391 (0.619) 186446 625.000 597.3

18 Acetone 43 6.5,3 6.578 (0.638) 200173 ■ 3125.00 1949

19 Iodomethane 142 6.735 6.735 (0.653) 492508 625.000 634.4(A)


22 3-Chloropropene 39 7.030 7.030 {0.681) 531881 625.000 600.0

23 Acetonitrile 41 7.030 7.030 (0.681) 611359 625.000 591.4

163 Methyl acetate 43 7.050 7.050 (0.683) 111370 625.000 479.7


25 Acrylonitrile . 53 7.611 7.611 (0.738) 390508 6250.00 5975 .

26 tert-butyl alcohol 59 7.385 7.385 (0.716) 119630 6250.00 6469'A)


28 Methyl-tert-butyl ether 73 7.562 7.562 (0.733) 521319 625.000 612 . 9

29 n-hexane 57 7.886 7.886 (0.764) 347561 625.000 651.6(A)

30 1,l-Dichloroethane 63 8.181 8.181 (0.793) 522081 625.000 585.3

32 Vinyl acetate 43 8.191 8 . 191* (0.794) 1273981 1250.00 1284(A)

33 Isopropyl ether 45 8.162 8.162 (0.791) 1182078 625.000 626.3(A)



31 Chloroprene 53 8.280 8.280 (0.803) 554583 625.000 642.4 (A)

37 2-butanone 43 8.910 8.910 (0.864) 304766 3125.00 2823

36 Propionitrile 54 9.028 9.028 (0.875) 739481 31250.0 30080

Methyl acrylate 55 8.998 8.998 (0.872) 1230980 6250.00 6414(A)

m- Methacrylonitrile 41 9.195 9.195 (0.891) 1037610 6250.00 6373(A)

40 Bromochloromethane 128 9.224 9.224 (0.894) 104823 625.000 592.3

42 Chloroform 83 9.293 9.293 (0.901) 559892 625.000 545.6

41 Tetrahydrofuran 42 9.254 9.254 (0.897) 140618 2500.00 2326


45 Pentafluorobenzene 168 ^9.441 9.441 (0.915) 625515 625.000 641.8(A)

44 Cyclohexane 84 9.559 9.559 (0.927) 292954 625.000 62 4.0

46 1-chlorobutane 56 9.608 9.608 (0.931) 825703 625.000 622 . 6

50 Isobutyl alcohol 43 9.785 9.785 (0.948) 251356 31250.0 33400(A)

47 1,1-dichloropropene 75 9.657 9.697 (0.940) 380835 625.000 627.5(A)

48 Ca rbon Te t ra ch 1 o r i de 117 9 . 716 9.716 (0.942) 456590 625.000 618.1

51 Benzene 78 9.992 9 . 992 (0.969) 1030275 625 . 000 612 . 5

49 1,2-Dichloroethane 62 10.031 10.031 (0.972) 369623 625.000 591.3

52 Crotonaldehyde 41 10.346 10.346 (1.003) 146536 6250.00 4431

S3 Trichloroethene 130 10.730 10.730 (1.040) 270392 625.000 611.1

S4 Methylcyclohexane 83 10.917 10.917 (1.058) 361356 625.000 682.2 (A)


56 Dibromomethane 174 11 . 153 11.153 (1.081) 120700 625.000 606.6

58 Methylmethacrylate 69 11.005 11.005 (1.067) 850230 6250.00 6733 (A)

57 1,4-dioxane 88 11.114 11 . 114 (1.077) 50259 31250.0 32620 (A)


60 2-chloroethyl vinyl ether 63 11.497 11.497 (1.114) 243719 6250.00 11370(A)

61 cie-1,3 -Dicnloropropene 75 11.684 11.684 (1.133) 364842 625.000 653.9 (A)

104


AMOUNTS


Compounds MASS RT EXP' RT RBL RT RBSPONSB ( ng) ( ng)

62 4-Methyl-2-pentanone 43 11.773 11.773 (0.695) 770893 3125.00 3522(A)

63 Toluene 92 11.989 , 11.989 (0.911) 620224 625.000 556.4

64 trana-1,3-Dichloropropene 75 12.176 12.176 (0.925) 308068 625.000 842.8(A)

66 Bthyloethacrylate 69 12.166 12.166 (0.924) 2091776 6250.00 6959(A)


67 1,3-bichloropropane 76 12.501 12.501 (0.950) 255705 625.000 600.3

68 Tetrachloroethane 164 12.471 12.471 (0.948) 275235 625.000 618.3

69 2-hexanone 43 12 . 501 12.501 (0.950) 541696 3125.00 3686(A)

70 Dibromochlorotne thane 129 12.717 12.717 (0.966) 225283 625.000 615.5

71 1,2-bibromoethane 107 12.835 12.835 (0.975) 155318 625.000 658.1(A)

73 1-Chlorohexane 55 13.081 13.081 (0.994) 379985 625.000 649.2(A)

72 Chlorobenzene 112 13.180 13 . 180 (1.001) 653322 625.000 625.3(A)

74 1,1,X,2-Tetrachloroethane 131 13.229 13.229 (1.005) 255753 625.000 632.4(A)

75 Bthylbenzene 106 13.219 13.219 (1.004) 355081 625.000 644.2(A)

76 0,p-Xylene 106 13.298 13.298 (1.010) 905499 1250.00 1302(A)

77 o-Xylene 106 13.603 13.603 (1.034) 422234 625.000 644.9(A)

78 Styrene 104 13.613 13.613 (1:034) 669995 625.000 677.5(A)

79 Broraoform 173 13.819 13.819 (1.050) 126766 625.000 674.4(A)

81 Isopropyl Benzene 105 13.849 13.849 (1.052) 1260362 625.000 635.9 (A)

80 cis-1,4-dichloro-2-butene 75 13.918 13.918 (1.058) 2169983 25000.0 25670 (A)

82 1,1,2,2-Tetrachloroethane 83 14.095 14.095 (0.949) 170926 625.000 626.7 (A)

84 Broraobenzene 156 14.154 14.154 (1.075) 275225 625.000 630.1 (A)


trane-l,4-dichloro-2-butene 53 14.114 14.114 (1.073) 2393446 25000.0 24900

n-Propyl Benzene 91 14.144 14.144 (0.952) 1968895 625.000 633.2 (A)

2-Chlorotoluene 126 14.252 14.252 (0.960) 274751 625.000 621.5

89 1,3,5-Trimethyl Benzene 105 14.242 14.242 (0.959) 991455 625.000 642.5(A)

88 4-Chlorotoluene 126 14.331 14.331 (0.965) 271684 625.000 631.2(A)

91 tert-Butyl Benzene 119 14.498 14.498 (0.976) 937144 625.000 656.5(A)

90 Pentachloroethane 167 14.577 14.577 (0.981) 141561 625.000 636.5(A)

92 1,2,4-Trimethyl Benzene 105 14.528 14.528 (0.978) 982733 625.000 638.0 (A)

93 sec-Butyl Benzene 105 14.656 14.656 (0.987) 1265987 625.000 648.1 (A)

94 1,3-Dichlorobenzene 146 14.813 14.813 ■ (0.997) 512358 625.000 608.7

95 p-Isopropyl Toluene 119 14.734 14.734 (0.992) 1028699 625.000 649.5(A)

96 1,4-Dichlorobenzene 146 14.872 14.872 (1.001) 505743 625.000 618.3.

97 Benzyl Chloride 91 14.961 14.961 (1.007) 331749 625.000 683.2(A)

99 n-Butyl Benzene 91 15.039 15.039 (1.013) 1032242 625.000 649.3(A)


100 1,2-diethylbenzene 119 IS . 128 15.128 (1.019) 483957 625.000 563.6

101 1,2-Dibromo-3-Chloropropane 75 15.797 15.797 (1.064) 25660 625.000 442.3

102 1,2,4-Trichlorobenzene 180 16.505 16.505 (1.111) 285800 625.000 627.0(A)


104 Naphthalene 128 16.800 16.800 (1.131) 350025 625.000 676.6(A)


M 106 1,2-Dichloroethene (total) 96 509297 . 1250.00 1190

M 107 Xylene (total) 106 1327733 625.000 2028(A)

105


# Flag Legend

Target compound detected but, quantitated amount exceeded maximum amount.

106

COMPUCHEM a division of Liberty Analytical Corp DATE JJ ¥ / 2- INITIAL TIME OF TUNE_ ?Q g _____ SHIFT/S(A)_^____(B)(C)GC/MS VOLATILE RUN LOG TIME TUNE EXPIRES 3.0Og LINKER /METHOD 8 - JSL

Lot # 5 S’Z.Sel. The presence of the Chemist’s employee ID number, or signature, on this run log attests that strict compliance with the method’s SOP has

occurred. Any SOP deviations require documentation by the responsible chemist together with the chemist’s initials and the initials of the

lab supervisor and a QA department representative, signify ing approval of the deviation. 10/5/01 :dce

b. Continuing Calibration Data (Form VII VO A)

If more than one instrument is used, forms shall be

arranged in order by instrument. If multiple continuing

calibrations from the same instrument are used, they shall be in

chronological order.

(1) Reconstructed Ion Chromatograms and quantitation

reports for all continuing (12-hour) calibrations.

Spectra not required.

(2) EICPs displaying each manual integration.

108

FORM 7BVOLATILE CALIBRATION VERIFICATION SUMMARY

Lab Name: COMPUCHEM



Lab File ID: CS020211A73

Contract: 8260B


Calibration Date: 02/11/02 Time: 0838

Init. Calib. Date(s): 02/08/02 02/08/02

Init. Calib. Times: 1114 1315


RRF5COMPOUND j RRF OR OR

MIN j %D OR iMAX %D OR |jAMOUNT AMOUNT RRF j %DRIFT |ADRIFT 1

Chloromethane |0.4970000 0.4755150 0.1 | -4.32 1 90.00 |Vinyl Chloride j 0.4310000 0.4689744 0.001 8.81 j 20.00 j

Bromome thane I 0.3060000 0.2787479 0.001 -8.90| 90.00|Chloroethane |0.2310000 0.2268283 0.001 -1.80| 90.00 j

1,1-Dichloroethene I 0.2160000 0.2214624 0.001 2.53 j 20.00|Carbon disulfide I 0.9530000 0.9139512’ 0.001 -4.10| 90.00 j

Acetone 10.0660000 0.0583925 0.001 -11.53 j 90.00 j

Methylene Chloride |0.2900000 0.2418281 0.001 -16.61| 90.00|trans-1,2-Dichloroethene I 0.2730000 0.2585874 0.001 — 5.2 8 j 90.00 j

1,1-Dichloroethane I 0.5690000 0.5193448 0.1 -8.73 j 90.00|cis-1,2-Dichloroethene |0.2740000 0.2619116 0.001 -4.41j 90.00 j

*2 -butanone j 0.0690000 0.0634619 0.001 -8.03 j 90.00 j®iloroform I 0.6550000 0.5756300 0.001 -12.12 | 20.00^, 1,1-Trichloroethane |0.5490000 0.5917327 0.001 7.78 j 90.00Carbon Tetrachloride I 0.4710000 0.5139636 0.001 9.12 | 90.00Benzene I 1.0740000 1.0439478 0.001 — 2.80 j 90.001,2-Dichloroethane I 0.3990000 0.3887173 0.001 -2.58| 90.00Trichloroethene |0.2820000 0.2689395 0.001 —4.63 j 90.001,2-Dichloropropane |0.2490000 0.2170815 0.001 -12.82 | 20.00Bromodichloromethane |0.4320000 0.3650480 0.001 -15.50 j 90.00cis-1,3-Dichloropropene |0.3560000 0.3375159 0.001 -5.19| 90.004-Methyl-2-pentanone I 0.2080000 0.2015722 0.001 -3.09 j 90.00Toluene |1.0590000 0.8893704 0.001 -16.02| 20.00trans-1,3-Dichloropropene i0.4550000 0.4634711 0.001 1.86 | 90.001,1,2-Trichloroethane I 0.2170000 0.1999693 0.001 -7.85| 90.00Tetrachloroethene I 0.4230000 0.3935041 0.001 -6.97| 90.002-hexanone I 0.1400000 0.1393266 0.001 -0.48 j 90.00Dibromochloromethane |0.3480000 0.3033822 0.001 -12.82 j 90.00Chlorobenzene I 0.9920000 0.9152389 0.3 -7.74| 90.00Ethylbenzene |0.5230000 0.4879132 0.001 -6.71j 20.00m,p-Xylene I 0.6600000 0.6118682 0.001 — 7.2 9 j 90.00o-Xylene I 0.6220000 0.5783036 0.001 -7.02| 90.00Styrene 10.9390000 0.8849605 0.001 -5.76 j 90.00Bromoform I 0.1790000 0.1673825 0.1 -6.49| 90.001,1,2,2-Tetrachloroethane I 0.5220000 0.4527244 0.3 -13.27| 90.00Xylene (total) I 0.6220000 0.5783036 0.001 -7.02 j 90.00

Dibromofluoromethane I 0.3330000 0.3157139 0.001

II II

1 II

U1 II

I-1 II

VO II

II

II

II

90.001,2-Dichloroethane-d4 I 0.3500000 0.3310522 0.001 -5.41| 90.00gpluene-d8 I 1.3270000 1.3390597 0.001 0.911 90.00^Fomofluorobenzene I 1.1600000 1.0642713 0.001 - 8.2 5 j 90.00" 1 1

CURVTYPE

AVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRGAVRG

AVRGAVRGAVRGAVRG

FORM VII VOA 109

<x!0^6>

Sample Info:

Purge Volume: 25+0 Operator: 2423


Data File: /chem/5S72hp73.i/DF0202iiA73.b/CS020211A73.d

Date ; ll-FEB-2002 08:33Client ID: VSTD005 Instrument: 5972hp73.i

110

Data File: /chem/5972hp73.i/DF020211A73.b/CS020211A73.dReport Date: 12-Feb-2002 10:14

CompuChem


SW846 UPDATE III METHOD 8260B QUANT & RATIO REPORT /chem/5972hp73.i/DF020211A73.b/CS020211A73.d VSTD005 Client Smp ID: VSTD00511-FEB-2002 08:382423 Inst ID: 5972hp73.i

Comment Method Meth Date Cal Date Als bottle Dil Factor IntegratorTarget Version: 3.50Processing Host: dante

/chem/5972hp73.i/DF020211A73.b/W8260-B-25MLv6.m 12-Feb-2002 10:11 hubbard Quant Type: ISTD 08-FEB-2002‘13:15 Cal File: CY020208A73.d2 Continuing Calibration Sample1.00000HP RTE Compound Sublist: all.sub



DFVoDF

d Variable

1.0000025.000001.00000



AMOUNTS

Compounds

QUANT SIG

MASS RT EXP RT REL RT RESPONSE rCAL-AMT

( ng)

ON-COL

( ng)

* 1 Fluorobenzene 96 10.320 10.320 (1.000) 194936 125.000

* 2 Chlorobenzene-d5 117 13.164 13.164 (1.000) 130390 125.000

♦ 3 1,4-Dichlorobenzene-d4 152 14.656 14.856 (1.000) 66546 125.000

cV 4 Dibromofluoromethane 113 9.503 9.503 (0.921) 61544 125.000 118.7

5 1,2-Dichloroethane-d4 65 9.946 9.946 (0.964) 64534 125.000 118.3

cV 6 Toluene-'d8 96 11 . 934 11 . 934 (0.907) 174600 125.000 126.1


8 Dichlorodifluoromethane 85 3 .413 3 .413 (0.331) 69658 125.000 152.4

9 Chloromethane 50 3 . 836 3.836 (0.372) 92695 125.000 119 . 5

10 Vinyl Chloride 62 4.082 4.082 (0.396) 91420 125.000 136.1

11 Bromomethane 94 4.830 4 . 830 (0.468) 54338 125.000 113.8

12 Chloroethane 64 5.037 5.037 (0.488) 44217 125.000 122.7

13 Trichlorofluoromethane 101 5.519 5.519 (0.535) 135753 125.000 154.8

14 Diethylether 74 6.050 6.050 (0.586) 148789 1250.00 1157

15 Acrolein 56 6.335 6.335 (0.614) 34995 1250.00 1113

0

Data File: /chem/5972hp73.i/DF020211A73,b/CS020211A73.dReport Date: 12-Feb-2002 10:14

QUANT SIG

Compounds MASS

16 1,1-Dichloroethene 96

17 1,1,1 -trichloro-2,2,2- trifluo 117

20 1,1,2 -trichloro-1,2,2-trifluo 85

18 Acetone 43

19 Iodomethane 142

21 Carbon disulfide 76

22 3 -Chloropropene 39

23 Acetonitrile 41

163 Methyl acetate 43

24 Methylene Chloride 84

25 Acrylonitrile 53

26 tert-butyl alcohol 59

27 trans-1,2-Dichloroethene 96

28 Methyl-tert-butyl ether 73

29 n-hexane 57

30 1,1-Dichloroethane 63

32 Vinyl acetate 43

33 Isopropyl ether 45

35 2,2-Dichloropropane 77

34 cis-1,2-Dichloroethene 96

31 Chloroprene 53

37 2-butanone 43

36 Propionitrile 54

38 Methyl acrylate 55

Methacrylonitrile 41

Bromochloromethane 128

42 Chloroform 83

41 Tetrahydrofuran 42

43 1,1,1-Trichloroethane 97

45 Pentafluorobenzene 168

44 Cyclohexane 84

46 1 -chlorobutane 56

50 Ioobutyl alcohol 43

47 1,1-dichloropropene 75

48 Carbon Tetrachloride 117

51 Benzene 78

49 1,2-Dichloroethane 62

52 Crotonaldehyde 41

53 Trichloroethene 130

54 Methylcyclohexane 83

55 1,2-Dichloropropane 63

56 Dibromomethane 174

58 Methylmethacrylate 69

57 1,4-dioxane 88

59 Bromodichloromethane 83

60 2-chloroethyl vinyl ether 63

61 cis-1,3-Dichloropropene 75

AMOUNTS

CAL-AMT ON-COL

EXP RT REL RT RESPONSE ( ng) ( ng)

6.453 (0.62S) 43171 125.000 128.2

6.365 (0.617) 38788 125.000 144.2

6.414 (0.622) 44764 125.000 144 . 1

6 . 591 (0.639) 56914 625.000 556.6

6.739 (0.653) 91006 125.000 117.8

6.837 (0.662) 178162 125.000 119.9

7.034 (0.682) 102203 125.000 115.8

7.034 (0.682) 111300 125.000 108.2

7.063 (0.684) 23837 125.000 103.2

7.240 (0.702) 47141 125 . 000 104.3

7.624 (0.739) 68933 1250.00 1060

7.388 (0.716) 25651 1250.00 1393

7.604 (0.737) 50408 125 . 000 116.7

7.565 (0.733) 111773 125.000 132.0

7.900 (0.765) 99494 125.000 187.4

8.195 (0.794) 101239 125.000 114.0

6.205 (0.796) 225057 250 : 000 227.8

8 . 175 (0.792) 208508 125.000 111 . 0

8.903 (0.863) 106189 125.000 131.7

8 . 923 (0.865) 51056 125.000 119.5

8.283 (0.803) 111583 125.000 129.8

8.913 (0.864 ) 61855 625.000 575.7

9.041 (0.876) 137649 6250.00 5625

9.002 (0.872) 215961 1250.00 1130

9.198 (0.891) 182512 1250.00 1126

9.238 (0.895) 20769 125.000 117.9

9.297 (0.901) 112211 125.000 109.9

9.267 (0.898) 30544 500.000 507.7

9 . 523 (0.923) 115350 125.000 134 . 6

9.454 (0.916) 124605 125.000 128.4

9.572 (0.928) 65107 125.000 139.3

9.621 (0.932) 157469 125.000 119.3

■9.799 (0.949) 45724 6250.00 6104

9.710 (0.941) 73762 125.000 122 . 1

9.730 (0.943) 100190 125.000 136.3

9.995 (0.969) 203503 125.000 121 . 5

10.045 (0.973) 75775 125.000 121.8

10.359 (1.004) 44000 1250.00 1337

10.743 (1.041) 52426 125.000 119.0

10.920 (1.050) 75150 125.000 142 . 5

11.009 (1.067) 42317 125.000 108.9

11.156 (1.081) 21946 125.000 110.8

11.019 (1.068) 149325 1250.00 1188

11 . 117 (1.077) 10027 6250.00 6537

11.284 (1.093) 71161 125.000 105.6

11 . 501 (1.114) 37604 1250.00 1763

11.688 (1.133) 65794 125.000 118.5

RT

6.453

6.365

6.414

6.591

6.739

6.837

7.034

7.034

7.063

7.240

7.624

7.388

7.604

7.565

7.900

8.195

8.205

8.175

8.903

8 . 923

8.283

8.913

9.041

9.002

9.198

9.238

9.297

9.267

9.523

9.454

9.572

9.621

9.799

9.710

9.730

9.995

10.045

10.359

10.743

10.920

11.009

11.156

11.019

11.117

11.284

11.501

11.688

Data File: /chem/5972hp73.i/DF020211A73,b/CS020211A73.dReport Date: 12-Feb-2002 10:14

Compounds

62 4-Methyl -2-pentanone

63 Toluene

64 trans-l,3-Dichloropropene

66 Ethyltnethacrylate

65 1,1,2-Trichloroethane

67 1,3-Dichloropropane

68 Tetrachloroethene

69 2-hexanone

70 Dibrotnochloromethane

71 1,2-Dibromoethane

73 1 -Chlorohexane

72 Chlorobenzene

74 1,1,1,2-Tetrachloroethane

75 Ethylbenzene

76 m,p-Xyiene

77 o-Xylene

78 Styrene

79 Bromoform

81 Isopropyl Benzene

80 cis-1,4-dichloro-2-butene

82 1,1,2,2-Tetrachloroethane

84 Bromobenzene

83 1,2,3'Trichloropropane

85 trans-1,4-dichloro-2-butene

n-Propyl Benzene

2-Chlorotoluene


88 4-Chlorotoluene

91 tert-Butyl Benzene

90 Pentachloroethane


93 sec-Butyl Benzene


95 p-Isopropyl Toluene


97 Benzyl Chloride

99 n-Butyl Benzene


100 1,2-diethylbenzene

101 1 , 2-Dibromo-3-Chloropropane


103 Hexachlorobutadiene

104 Naphthalene


M 106 1,2-Dichloroethene (total)

M 107 Xylene (total)

QUANT SIG

MASS RT EXP RT RBL RT

43 11.786 11.786 (0.695)

92 11.993 11.993 '0.911)

75 12.180 12.180 (0.925)

69 12.170 12.170 (0.924)

97 12.367 12.367 (0.939)

76 12.514 12.514 (0.951)

164 12.475 12.475 (0.948)

43 12.504 12.504 (0.950)

129 12.721 12 . 721 (0.966)

107 12.839 12.839 (0.975)

55 13 . 085 13.085 (0.994)

112 13 .183 13.183 (1.001)

131 13 . 232 13 . 232 (1.005)

106 13.223 13 .223 (1.004)

106 13.301 13.301 (1.010)

106 13.606 13.606 (1.034)

104 13 .616 13 . 616 (1.034)

173 13.823 13 . 823 (1.050)

105 13.852 13.852 (1.052)

75 13.921 13.921 (1.056)

83 14.096 14.098 (0.949)

156 14.157 14.157 (1.075)

110 14.147 14 . 147 (1.075)

53 14.118 14.118 (1.073)

91 14.147 14.147 (0.952)

126 14.265 14.265 (0.960)

105 14.256 14.256 (0.960)

126 14.334 14.334 (0.965)

119 14.511 14.511 (0.977)

167 14.580 14.580 (0.981)

105 14 . 541 14.541 (0.979)

105 14 .659 14.659 (0.987)

146 14.816 14 .816 (0.997)

119 14.748 14 . 748 (0.993)

146 14.876 14.876 (1.001)

91 14.964 14.964 (1.007)

91 15.053 15.053 (1.013)

146 15.181 IS.181 (1.022)

119 15.131 15.131 (1.019)

75 15.800 15.800 (1.064)

180 16 . 519 16.519 (1.112)

225 16.597 16.597 (1.117)

128 16.804 16.804 (1.131)

180 17.050 17.050 (1.148)

96

106

AMOUNTS

CAL-AMT ON-COL

RESPONSE ( ng) ( ng)

131415 625.000 606.0

115965 12S.000 105.0

60432 125.000 127.3

362141 1250.00 1216

26074 125.000 115.4

46676 125.000 110.6

51309 125.000 116.3

90834 625 . 000 623.9

39558 125.000 109.1

27979 125.000 119.7

75527 125.000 130.2

119338 125.000 115.3

47913 125 . 000 119.6

63619 125.000 116.5

159563 250.000 231.6

75405 125.000 116.2

115390 125.000 117.8

21825 125.000 117.2

223307 125.000 116.3

445200 5000.00 5316

30127 125.000 108.4

49229 125 . 000 113.8

8 53 B 125.000 119.0

543513 5000.00 5708

355266 125.000 112.1

49215 125.000 109.2

179273 125.000 114.0

47043 125.000 107.3

168704 125.000 116.0

25466 125.000 112.4

177713 125.000 113.2

227284 125.000 114 . 2

92484 125.000 107.8

183057 125 . 000 113 . 4

88956 125.000 106.7

63706 125.000 128.7

178318 125.000 110.1

78836 125.000 110.3

95504 125.000 109.1

5768 125.000 97.56

50503 125.000 108.7

38805 125.000 124.1

64836 125.000 123.0

41922 125.000 112.3

101464 250.000 238.2

234968 125.000 362.2

113

COMPUCHEM a division of Liberty Analytical Corp DATE 2 /11 IgX- INITIAL TIME OF TUNE 7 3 8 SHIFT/S(A)_ _(B)_ _(C)_____

GC/MS VOLATILE RUN LOG TIME TUNE EXPIRES / ? 3 $ LINKER/METHOD

aE1 ;EE>.••O

PREVENTIVE MAINTENANCE /?0^C__________________________________—--------------------- —1—1---

c . <T".E; ,vFILEN4M^| : *•;••iT.r.E -D •

i;-^DATE^3;: TIME - ; CLIEp;U)ft7 . .’pCASE/SDG#: •.AMOUNTINJECTED

; CHEMIST ; COMMENTS(ETC.)/DlSPOSmON

1 u*n3 / a ;ii 7 3$ 'SfB — 3-ul ScD-LCJ)

2 <-Woait ft"? 3 7 '7 $3$ \JS~ Dot. *0 -— Ts»vil

3 7 / / 93< V *.\r 1015

4/ / / icH Nj LXLCb . ' A7<f / £ ^

5 Pî-'SDAFPi / / / 0 c3 m<rf______ I.SÎ6 -1 / / / Ou?-X 1 rvi /7 Paî 7 / / usl> phoj- tW

8 f t' °i OT-fHi / / / 1^1 fA L*J ' A Kot-1

9/ / / /TV) muj -'i7 /W

10 / / / fn U - 3L Tr-vrl

11 aaî'^73A

/ \ VU aiu-t5 0-nn(12

h ■ ID ^17 »» L.J / / / iHc% mP-& T//W) /

13 3 / / 7 5*114 r^XWV?-^73 / / iS& U „ 074 37

15 a^m-Lf)73/ / / i<27 -

16 7^73/ / iSSH U"7

17 QM17-W71 / / \U0-o (J-Vi

18 OZIS77-2/973 7 / 1 (<?h6s 't'&ip bt<ink Q2/Sf 77

19 / / / my MtU'ZH a,5 ca 0x1*11 *n£/oS 4 / - f ' ' <i20 UjL>iss%^7^73 a / / m3 /"1CJ- 34*^50 1 1 ‘1-

21 ot/J&S- iVa?3 l / / /y/1 rg^ ~ I/

22 ' a 2 1^77- 1^73 0 ' / hho Ai U)-7-'7~f) 62 l 37*1 Sooul /23 Cp l£A7'!> // / / MU' Mu-7/A l

2mL Z'bi •2£_ / V

--------- --.

l3jtji. id a

Lot #

Tune

"?*Q ?

Analytical

MB /o

Int. Std.

r;

SUPERVISOR APPROVAL

DATE ■?'//■ Zo->

The presence of the Chemist’s employee ID number, or signature, on this run log attests that strict compliance with Lite method's SOP has

occurred. Any SOP deviations require documentation by the responsible chemist together with the chemist's initials and the initials of the

lab supervisor and a QA department representative, signifying approval of the deviation 10/5/01 dec

4. Raw QC Data

a. BFB Data

b. Blank Data

c. Laboratory Control Sample Data

d. Matrix Spike Data

e. Matrix Spike Duplicate Data

BFB Data

' Bar Graph spec<mm and Tabulated RelatiV(

■ Mass listing

Reconstructed ion chromatogram

Abundances

116

Data File: /chem/5972hp73.i/DF020208A73.b/BF020208A73.d

Date ; 08-FEB-2002 08:08

Client ID: BFB I nstrument: 5972hp73. i

Sample Info:

Volume Injected <uL): 2.0 Operator: 2421


1 bromof luorobenzene

m/z

X RELATIVE

m/e ION ABUNDANCE CRITERIA ABUNDANCE

+-----

1 95 1 Base Peak, 100X relative abundance 1 100.00 1

1 50 1 15.00 - 40.00X of mass 95 1 27.46 l

i 75 1 30.00 - 60.00X of mass 95 1 55.02 1

1 96 1 5.00 - 9.00X of mass 95 1 6.72 1

1 173 1 Less than 2.00X of mass 174 1 0.14 < 0.20) 1

1 174 1 50.00 - 100.00X of mass 95 1 74.22 1

1 175 1 5.00 - 9.00X of mass 174 1 5.55 ( 7.48) 1

1 176 1 95.00 - 101.00X of mass 174 1 71.20 < 95.93) 1

1 177

+-----

1 5.00 - 9.00X of mass 176 1 4.74 < 6.66) 1

117

Data File: /chem/5972hp73*i/DF020208A73*b/BF020208A73*d

Date : 08-FEB-2002 08:08

Client ID: BFB Instrument: 5972hp73*i

Sample Info:

Volume Injected <uL>: 2*0


Operator: 2421

Column diameter: 0*32

Data File: BF020208A73*d

Spectrum: Avg* Scans 328-330 < 7*77), Background Scan 322

Location of Maximum: 95*00

Number of points: 89

m/z Y n/z Y m/z Y m/z Y

111 36.00 946 1 64.00 187 1 93.00 2413 1 150.00 60 1

1 37.00 4683 1 65.00 170 1 94.00 5763 1 153.00 42

1 38.00 3459 1 67.00 168 1 95.00 49048 1 155.00 142 1

1 39.00 1280 1 68.00 6859 1 96.00 3294 1 157.00 40 1

1 40.00 11 1 69.00 6339 1 97.00 109 1 159.00 35 1

* *

1 41.00 74 1 70.00 399 1 104.00 283 161.00 47 1

1 43.00 182 1 72.00 274 1 105.00 101 1 172.00 86 1

1 44*00 418 1 73.00 2138 1 106.00 273 173.00 71 1

1 45.00 630 1 74.00 9257 1 115.00 39 1 174.00 36400 1

1 47.00 691 1 75.00 26984 1 116.00 187 1 175.00 2723 1

*

1 48.00 682 1 76.00 2184 1 117.00 321 1 176.00 34920 1

1 49.00 3032 1 77.00 470 118.00 192 1 177.00 2326

1 50*00 13469 1 78.00 203 1 119.00 318 1 192.00 35

1 51.00 4312 1 79.00 2153 1 128.00 210 1 193.00 69 1

1 52.00 204 1 80.00 586 1 129.00 51 1 207.00 132 1

1 11 55.00 325 1 81.00 2244 1 130.00 165 1 208.00 41 1

1 56.00 1132 1 82.00 492 1 135.00 127 1 209.00 8 1

1 57.00 1961 1 83.00 33 1 137.00 37 1 253.00 33 1

1 58.00 41 1 86.00 42 1 141.00 549 1 269.00 27 1

l

1

60.00 675 1

1

87.00 1716 1 143.00 510 1 281.00 65 1

11 61.00 2921 1 88.00 1757 1 146.00 39 1 1

1 62.00 2982 1 91.00 270 1 147.00 82 1 1

1

4—

63.00 2068 1 92.00 1664 1 148.00 133 1 1

j

118

(SvOTX)

Sample Info:

Volume Injected <uL>: 2.0 Operator: 2421

Data File; /chem/5972hp73. i/DF020208A73.b,'BF020208A73.d

Date : 08-FEB-2002 08:08

Client ID: BFB Instrument: 5972hp73.i

119

Volume Injected CuL): 2.0

Column phase:' ZB-624

1 bromofluorobenzene

Data File: /chem/'5972hp73.i/DF020211A73.b/BF020211A73.d

Date : ll-FEB-2002 07:38

Client ID: BFB

'Sample Info;

Operator: 2423



120

Data File: 7chem/5972hp73.i/DF020211873.b/BF020211A73.d

Date ; li-FEB-2002 07:38

Client ID: BFB

ample Info:

Volume Injected <uL): 2.0


Operator: 2423



Data File: BF020211A73.d

Spectrum: Avg. Scans 328-330 ( 7.77), Background Scan 322

Location of Maximum: 95.00

Humber of points: 93

#

rn/z Y m/z Y m/z Y m/z Y

** * * *

1 36.00 871 1 67.00 206 1 97.00 176 1 153.00 37 1

1 37.00 4172 1 68.00 6550 1 103.00 86 1 155.00 127 1

1 38.00 3424 1 69.00 6414 1 104.00 313 1 157.00 41 1

1 39.00 979 1 70.00 459 1 105.00 152 1 161.00 82 1

1 40.00 24 1 72.00 358 1 106.00 264 1 165.00 34 1

*1 * * *

1 41.00 66 1 73.00 2204 1 107.00 122 1 174.00 36664 1

1 44.00 490 1 74.00 9422 1 115.00 174 1 175.00 2904 1

1 45.00 677 1 75.00 27896 1 116.00 213 1 176.00 36104 1

J 47.00 690 I 76.00 2306 1 117.00 298 1 177.00 2457 1

1 48.00 588 1

*

77.00 353 1 118.00 226 1 178.00 129 1

* *

1 49.00 2841 1 78.00 153 1 119.00 202 1 179.00 41 1

1 50.00 13360 1 79.00 2029 1 126.00 46 1 192.00 43 1

1 51.00 4056 1 80.00 631 1 128.00 280 1 195.00 43 1

1 52.00 124 1 81.00 1915 1 129.00 44 l 208.00 35 1

1

*

54.00 37 1

*

82.00 569 1 130.00 181 1 209.00 89 1

* *

l 55.00 182 1 86.00 34 1 131.00 116 1 253.00 3 1

1 56.00 1055 1 87,00 2111 1 133.00 122 1 267.00 17 1

1 57.00 1983 1 88.00 1765 1 137.00 91 1 269.00 115 1

1 58.00 98 1 91.00 212 1 141.00 523 1 270.00 38 1

1 60.00 600 1 92.00 1564 1 142.00 33 1 281.00 31 1

1 1 1 1 11 61.00 2718 1 93.00 2163 1 143.00 569 1 232.00 26 1

1 62.00 2757 1 94.00 5701 1 146.00 97 1 1

1 63.00 2002 1 95.00 51872 1 148.00 95 1 1

1

+-'

64.00 249 1 96.00 3502 1 149.00 85 1 1

121

<x!0"5>

Data File: /chem75972hp73.i/DF0202iiA73.b/BF020211A73.d

Date : ll-FEB-2002 07:38Client ID: EFB Instrument: 5972hp73.i

Sample Info: ,

Volume Injected <uL>: 2.0


2.7-i

2.6-;

2.5-i

2.4-

2.3-

2.2:

2.1-

Operator: 2423


7chem/5972hp73.i/DF020211A73.b/BF020211A73. d

122

b. Blank Data

Arranged by type of blank (method, storage,

instrument) in chronological order, by instrument.

Shall include:

- Tabulated Results (Form I VO A)

- Tentatively Identified Compounds (Form I VOA-TIC)

- Reconstructed Ion Chromatogram and quantitation report.

- Target compound spectra with lab-generated standard

spectra.

- Quantitation/Calculation of TIC concentrations.

- GC/MS library search spectra for TICs.


CLIENT SAMPLE NO.

Lab Name: COMPUCHEM

Lab Code: LIBRTY


Sample wt/vol:

Level: (low/med)

% Moisture': not dec.

GC Column: ZB-624


Case No.:

WATER

2 5 (g/ml)' ML

LOW

ID: 0.32 (mm)

_______ (uL)

Method: 8260BVBLKLI




Date Received:



Soil Aliquot Volume: ■


74-87-3---------Chlorome thane 0.5 U75-01-4--------- Vinyl Chloride 0.5 U74-83-9---------Bromome thane 0.5 U75-00-3---------Chloroe thane 0.5 u75-35-4--------- 1,1-Dichloroethene 0.5 u75-15-0--------- Carbon disulfide 0.5 u67-64-1--------- Acetone 1 J75-09-2--------- Methylene Chloride 0.5 u156-60-5--------trans-1,2-Dichloroethene 0.5 u75-34-3--------- 1,1-Dichloroethane 0.5 u156-59-2--------cis-1,2 - Di chloroe thene 0.5 u78-93-3--------- 2-butanone 3 u67-66-3--------- Chloroform 0.5 u71-55-6---------1,1,1 -Tri chloroe thane 0.5 u56-23-5--------- Carbon Tetrachloride 0.5 u71-43-2--------- Benzene 0.06 J107-06-2--------1,2 - Di chloroe thane 0 •. 5 u79-01-6---------Trichloroe thene 0.03 J78-87-5--------- 1,2-Dichloropropane 0.5 u75-27-4--------- Bromodi chlorome thane 0.5 u10061-01-5------cis-1,3-Dichloropropene 0.5 u108-10-1-------- 4-Methyl-2-pentanone 3 u108-88-3--:------Toluene 0.1 J10061-02-6----- trans-1,3-Dichloropropene79-00-5---------1,1,2 - Tri chloroe thane

0.5 0.5

uu

127-18-4--------Tetrachloroe thene 0.04 J591-78-6-------- 2 - hexanone 3 u124-48-1---- 1-- Dibromochloromethane 0.5 u108-90-7-------- Chlorobenzene 0.5 u100-41-4-------- Ethylbenzene 0.5 u108-38-3-------- m,p-Xylene 0.06 J95-47-6---------o-Xylene 0.5 u100-42-5-------- Styrene 0.5 u

FORM I VOA

(uL

124


Lab Name: COMPUCHEM








Method: 8260BVBLKLI




Date Received:





75-25-2---------Bromoform 0.5 U79-34-5---------1,1,2,2-Tetrachloroethane 0.5 U1330-20-7-------Xylene (total) 0.07 J

FORM I VOA

(uL

125

(xlO^)


Operator: 2423


Zchem/5972hp73.i7DF020211A73.bZWG15582-2A73CY.d

Data File: /chemZ5972hp73*i/BF020211A73.b/WG15582~2A73CT.d

Date : ll-FEB-2002 09:35

Client ID: VBLKLI

Sample Info:

Purge Volume: 25.0


20

126

Data File: /chem/5972hp73.i/DF020211A73,b/WG15582-2A73CT.d Report Date: 12-Feb-2002 10:30

CompuChem


SW846 UPDATE III METHOD 8260B QUANT & RATIO REPORT /chem/5972hp73.i/DF020211A73,b/WG15582-2A73CT.d WG15582-2 ' Client Smp ID: VBLKLIll-FEB-2002 09:352423 Inst ID: 5972hp73.i

Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator

/chem/5972hp73.i/DF020211A73 12-Feb-2002 10:11 hubbard 08-FEB-2002 13:15 31.00000 HP RTE

Target Version: 3.50

.b/W8260-B-25MLv6.m Quant Type: ISTD Cal File: CY020208A73.d QC Sample: BLANK




DF 1.00000 Dilution FactorVo 25.00000 volume of waterDF 1.00000 dilution factor

tId Variable Local Compound Variable

CONCENTRATIONS

QUANT SIG ON-COLUMN FINAL

Compounds MASS RT EXP RT REL RT RESPONSE ( ng) ( ug/L)

* 1 Fluorobenzene 96 10.316 10.320 (1.000) 192058 125.000

* 2 Chlorobenzene-d5 117 13.159 13.164 (1.000) 127336 125.000

* 3 1,4-Dichlorobenzene -d4 152 14.052 14.856 (1.000) 61339 125.000

$ 4 Dibromofluoromethane 113 9.499 9.503 (0.921) 58102 . 113.725 4.55

£v 5 1,2-Dichloroethane- d4 65 9.942 9.946 (0.964) 58232 108.380 4.34

$ 6 Toluene-d8 98 11.929 11.934 (0.907) 169053 125.045 5.00

$ 7 Brotnof luorobenzene 95 14.006 14.010 (0.943) 63802 112.103 ‘4.48




12 Chloroethane 64 Compound Not Detected.

16 1,1-Dichloroethene 96 Compound Not Detected.

21 Carbon disulfide 76 Compound Not Detected.

18 Acetone 43 6.587 6.591 (0.639) 3354 33 .2911 1.33

24 Methylene Chloride 84 Compound Not Detected.

27 trans-1,2-Dichloroethene 96 Compound Not Detected.

ill JP 7_

127

Data File: /chem/5972hp73.i/DF020211A73.b/WG15582-2A73CT.d Report Date: 12-Feb-2002 10:30

CONCENTRATIONS

Compounds

QUANT SIG


ON-COLUMN

( ng)

FINAL

( ug/L)

30 1,1-Dichloroethane 63 Compound Not Detected.

34 cis-1,2-Dichloroethene 96 Compound Not Detected.

37 2-butanone 43 Compound Not Detected.

42 Chloroform 83 Compound Not Detected.

43 1,1,1 -Trichloroethane 97 Compound Not Detected.

48 Carbon Tetrachloride 117 Compound Not Detected.

51 Benzene 78 9.991 9.995 (0.969) 2426 1.47054 0.0588(a)

49 1,2-Dichloroethane 62 Compound Not Detected.

53 Trichloroethene 130 10.739 10.743 (1.041) 350 0.80661 0.0323(a)

55 1,2-Dichloropropane 63 Compound Not Detected.

59 Bromodichloromethane 83 Compound Not Detected.

61 cis-1,3-Dichloropropene 75 Compound Not Detected.

62 4 - Methyl-2-pentanone 43 Compound Not Detected.

63 Toluene 92 11.989 11.993 (0.911) 2713 2.51522 0.101(a)

64 trans-1,3-Dichloropropene 75 Compound Not Detected.

65 1,1,2-Trichloroethane 97 Compound Not Detected.

68 Tetrachloroethene 164 12.480 12.475 (0.948) 445 1.03313 0.0413(a)

69 2-hexanone 43 Compound Not Detected.

70 Dibromochloromethane 129 Compound Not Detected.

72 Chlorobenzene 112 Compound Not Detected.

75 Ethylbenzene 106 Compound Not Detected.

76 m,p-Xylene . 106 13.297 13.301 (1.010) 1079 1.60362 0.0641(a)

77 o-Xylene 106 Compound Not Detected.

78 Styrene 104 Compound Not Detected.

A Bromoform 173 Compound Not Detected.

w 1, 1,2,2 -Tetirachloroethane 83 Compound Not Detected.

M 107 Xylene (total) 106 1079 1.70311 0.0681(a)

QC Flag Legend


128

Client ID:.VBLKLI Instrument: 5972hp73.i

Data File: 7chem/5972hp73.i/DF020211A73.b/UG15582-2A73CT.d

Date : ll-FEB-2002 09:35

"Sample Info:

Purge Volume: 25.0


Operator: 2423


18 Acetone . Concentration: 1.33 ug/L

Data File: Zchem,'5972hp73.i/DF020211A73.b/WG15582-2A73CT.d

Date : ll-FEB-2002 09:35

Client ID: VBLKLI Instrument: 5972hp73.i

'Sample Info:

Purge Volume: 25.0


Operator: 2423


51 Benzene , Concentration: 0.0588 ug/L

130

FSample Info:



Data File: /chem/5972hp73.i/DF020211A73.b/WG15582-2A73CT.d

Date : ll-FEB-2002 09:35

Client ID: VBLKLI Instrument; 5972hp73.i

53 Trichloroethene Concentration: 0.0323 ug/L

400

360

320

280

240

200

160

12080

40

0

44-"'Scan 834 <10.739 min) of WG15582-2A73CT.d

^/9513'

6<\^

78\

°\

34

40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125________________________________________________________________m/z___________________________________________________________

130 135

240

210

180

150

120

^^90

30

0

Scan 834 <10.739 min) of WG15582-2A73CT.d Subtracted)95"^

y&0

■ yAZ y£0

A30

40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125________________________________________________________________ m/z____________________________________________________

130 135

10.0

9.0

8.07.0

~ 6.0rol 5.0

!< 4.0

> 3.0

2.0 1.0 0.0

53 Trichloroethene <Reference Spectrum)95—

^/60

47\

I I

,70 82

lii..

^/99

40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125__________________________________________ '_____________________ m/z____________________________________________________________

130 135

100

80

60

40

20

0

t -20om

Scan 834 <10.739 min) of UG15582-2A73CT.d <X DIFFERENCE)

-80

-100

43^ 50v^

^60

''■l I'li'i

lJ-40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125

________________________________________________________________m/z____________________________________________________________


Date : ll-FEB-2002 09:35

#Client ID: VBLKLI

ample Info:

Purge Volume: 25,0


63 Toluene


Operator: 2423


Concentration: 0.101 ug/L

100

80

60

40

20

0l -20o

-80

-100

7

Scan 961 <11.989 min) of WG15582-2A73CT.d <X DIFFERENCE)

/77 207

.. . . . . . . . . I'

-13 £

Data File: /chem/5972hp73. i/DF020211A73.b/'WG15582-2A73CT.d

Date : ll-FEB-2002 09:35

Client ID: VBLKLI

(Sample Info:

Purge Volume: 25.0

Column phase; ZB-624

Operator: 2423



68 Tetrachloroethene Concentration: 0.0413 ugZL

Scan 1011 <12.480 min) of UG15582-2A73CT.d <Subtracted)

<Qp

360

320

280

240

200

160

O

80

40

0

166^"

31

^9

94\

3N 68

40 50 60 70 80 90 100 110 120 130

_______n/z_______140 150 160 170 180 190 200

10.0

9.0

8.07.0

6.0

5-°

'x 4.0

> 3.0

2.0

1.0

0.0

47\z59

8*\

68 Tetrachloroethene (Reference Spectrum)

^31

34\

V8

166^

40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190

________________________ ;____________________ n/z_____'___________ ______ ________ ________________200

100

80

60

40

20

* 0 t -20

o

' t-~$o

-100-

Scan 1011 <12.480 min) of WG15582-2A73CT.d <X DIFFERENCE)

^27S\ 9N

z433

r 'i i

i: i40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190

________________________________________________________ n/z200


Date : ll-FEB-2002 09:35

Client ID: VBLKLI

rSample Info:

Purge Volume: 25.0


Operator: 2423



76 m,p-Xylene' . Concentration: 0.0641 ug/L

Laboratory Control Sample Data

- Tabulated Results (Form I VOA)

- Reconstructed Ion Chromatogram andquantitation report


CLIENT SAMPLE NO.

Lab Name: COMPUCHEM

Lab Code: LIBRTY


Sample wt/vol:

Level: (low/med)


GC Column: ZB-624


Case No.:

WATER

2 5 (g/ml)' ML

LOW

ID: 0.32 (mm)

_______ (uL)

Method: 82 6 OBVLILCS




Date Received:





74-87-3---------Chi orome thane 575-01-4--------- Vinyl Chloride 574-83-9--------- Bromomethane 575-00-3---------Chloroe thane 575-35-4--------- 1,1-Dichloroethene 675-15-0--------- Carbon disulfide 567-64-1--------- Acetone 17 B75-09-2--------- Methylene Chloride 4156-60-5--------trans-1,2-Dichloroethene 575-34-3--------- 1,1-Dichloroethane 5156-59-2-------- cis-1,2-Dichloroethene 578-93-3--------- 2 -but anone 1767-66-3--------- Chloroform 571-55-6---------1,1,1-Tri chloroe thane 656-23-5--------- Carbon Tetrachloride 671-43-2--------- Benzene 5 B107-06-2--------1,2 - Dichloroethane 579-01-6---------Tr i chloroe thene 5 B78-87-5--------- 1,2-Dichloropropane 575-27-4--------- Bromodichlorome thane 410061-01-5------cis-1,3-Dichloropropene 5108-10-1--------4 - Me thy 1 - 2 -pent anone 19108-88-3--------Toluene 5 B10061-02-6------trans-1,3-Dichloropropene 579-00-5---------1,1,2 -Tri chloroe thane 4127-18-4--------Tetrachloroethene 5 B591-78-6--------2 - hexanone 21124-48-1--------Dibromochlorome thane 4108-90-7--------Chlorobenzene 5100-41-4--------Ethylbenzene 5108-38-3--------m, p-Xylene 11 B95-47-6--------- o-Xylene 5100-42-5--------Styrene 5

FORM I VOA

(uL

136


CLIENT SAMPLE NO.

Lab Name: COMPUCHEMf

Method : 82 6 OBVLILCS

Lab Code: LIBRTY Case No. : SAS No. : SDG No.: QZ1877

Matrix: (soil/water) WATER Lab Sample ID WG15582-5

Sample wt/vol: 25 (g/ml)' ML Lab File ID: WG15582-5A73CT

Level: (low/med) LOW Date Received





75-25-2---------Bromof orm 479-34-5---------1,1,2,2-Tetrachloroethane. 41330-20-7-------Xylene (total) 17 B

FORM I VOA

(uL

137

<xlOA6>

OOCOData File: /chem/5972hp73.i/DF020211A73.b/WG15582-5A73CT.d

Date : il-FEB-2002 10:17 tH

Client ID: VLILCS Instrument: 5972hp73,i ■

Sample.Info:



/SDa'tfa File : /chem/5972hp73 . i/DF020211A73 .b/WG15582-5A73CT.d <:~>Refeort Date: 12-Feb-2002 10:29

CompuChem


SW846 UPDATE III METHOD 8260B QUANT & RATIO REPORT /chem/5972hp73.i/DF020211A73.b/WG15582-5A73CT.d WG15582-5 Client Smp ID: VLILCSll-FEB-2002 10:172423 Inst ID: 5972hp73.i

Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator

/chem/5972hp73.i/DF020211A73.b/W8260-B-25MLv6.m 12-Feb-2002 10:11 hubbard Quant Type: ISTD 08-FEB-2002 13:15 Cal File: CY020208A73.d

QC Sample: LCS1.00000 HP RTE

Target Version: 3.50Processing Host: dante




DF 1.00000Vo 25.00000DF 1.00000


Id Variable Local Compound Variable

CONCENTRATIONS

QUANT SIG ON-COLUMN FINAL


* 1 Fluorobenzene 96 10.311 10.320 (1.000) 180905 125.000

* 2 Chlorobenzene-dS 117 13.164 13.164 (1.000) 122235 125.000


s 4 Dibromofluoromethane 113 9.495 9.503 (0.921) 58925 122.447 4.90

5 5 1,2-Dichloroethane-d4 65 9.937 9.946 (0.964) 55954 110 . 561 4.42

$ 6 Toluene-d8 98 11.925 11.934 (0.906) 166917 128.617 5.14


9 Chloromethane 50 3 . 827 3 . 836 (0.371) 83085 115.431 4.62

10 Vinyl Chloride 62 4.073 4.082 (0.395) 84050 134.825 5.39

11 Bromomethane 94 4:821 4.830 (0.468) 50726 114.479 4.58

13 Chloroethane 64 5.028 5.037 (0.488) 40815 122 . 015 4.88

16 1,1-Dichloroethene 96 6.454 6.453 (0.626) 43009 137.625 5.50

21 Carbon disulfide 76' 6.838 6.837 (0.663) 173068 125.494 5.02

10 Acetone 43 6.582 6.591 (0.63e) 41214 434.301 17.37


0

Data File: /chem/5972hp73.i/DF020211A73.b/WG15582-5A73CT.d Report Date: 12-Feb-2002 10:29

QUANT SIG

CONCENTRATIONS

ON-COLUMN FINAL



30 1,1-Dichloroethane 63 8.186 8.195 (0.794) 102272 124.125 4.96


37 2-butanone 43 8.914 8.913 (0.864) 43189 433.125 17.33

42 Chloroform 83 9.288 9.297 (0.901) 106999 112.882 4.52

43 1,1,1-Trichloroethane 97 9.514 9.523 (0.923) 115152 144.820 S . 79

48 Carbon Tetrachloride ■ 117 9.721 9.730 (0.943) 105396 154.458 '6.18

51 Benzene 78 9.996 9.995 (0.969) 197744 127.254 5.09

49 1,2-Dichloroethane 62 10.036 10.045 (0.973) 67680 117.213 4.69






63 Toluene 92 ( 11.994 11 . 993 (0.911) 122224 118.043 4 . 72




69 2-hexanone 43 12.495 12.504 (0.949) 71932 527.003 21.08


72 Chlorobenzene 112 13.184 13.183 (1.001) 120875 124.562 4.98

75 Ethylbenzene 106 13.223 13 .223 (1.004) 68613 134.020 5.36

76 m,p-Xylene 106 13.302 13.301 (1.010). 172358 266.851 10.67

77 o-Xylene 106 13.607 13 . 606 (1.034) 79027 129.943 5.20

Styrene 104 13.617 13 .616 (1.034) 116745 127.098 5.08

Bromoform 173 13.824 13 . 823 (1.050) 17910 102.584 4.10


M 107 Xylene (total) 106 251385 413.349 16.53

d. Matrix Spike Data



£ e. Matrix Spike Duplicate Data



142

Removal Assessment Report - Appendix G -Lab Data Sheets ...

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