Product Refreshment

8 May 2014 By VPTS, PTTPM

Product Refreshment

8 May 2014 Montien Riverside Hotel

By VPTS, PTTPM


HDPE

LLDPE

LDPE

Polyethylene Products

High pressure Tubular

Process

LyondellBasell Technology

Capacity 300,000 MTA

Gas Phase Process

Univation Technology


Slurry Process

Mitsui Technology



HDPE Process Technology

Capacity : 850,000 MTA Catalyst : Zigler-Natta Comonomer : Propylene, Butene

InnoPlus HDPE : CX -Slurry Polymerization process by Mitsui Technology

Advantages :

• WIDE PRODUCT RANGE

• QUALITY UNIFORMITY

• Excellent products Quality

Film : Film impact strength , Tear Strength

Monofilament : High tenacity and processability

Blow molding : Stiffness, Environmental stress

cracking resistance (ESCR) • LOW ASH CONTENT

• LOW PRESS POLYMERIZATION


InnoPlus LLDPE : Gas Phase Unipol process by Univation Technology

Advantages : • Broadest range of densities and melt indexes (MFI)

with both narrow and broad molecular weight distributions of product capabilities.

• Tougher, clearer, better-performing polyethylene resins especially Film Application. (Narrow MWD)

Capacity : 400,000 MTA Catalyst : Ziegler Natta, Metallocene Comonomer : Butene (C4), Hexene (C6)

LLDPE Process Technology

http://ch-team/sites/qsystem/dcm/PE/MPE/TSP/DCM/W-TSP-001-V1.pdf

http://ch-team/sites/qsystem/dcm/PE/MPE/TSP/DCM/P-TSP-001-V2.pdf






LLDPE Classification

1. Catalyst types :

2. Co-monomer :

- C4 - Butene

- C6 - Hexene

- C8 - Octene

Co-monomer

Ziegler-Natta Metallocene

Introduction for LLDPE


LDPE Process Technology

Capacity : 300,000 MTA

InnoPlus LDPE : LyondellBasell, Lupotech TS (Tubular Process)

Advantages :

• Provide good film surfaces and good optical film properties

• Products very low gel level

• High purity


>>> InnoPlus HDPE Nomenclature

• General Structure HD 7000 F

Application

MFR range Article Application Article Application

F Film H Thermoform

J Injection JP, C Cap (Pass Organoleptic test)

B Blow molding

S Monofilament

Internal Code

Grade Name

Additive Package








Example : InnoPlus LLDPE

C4 comonomer

- LL8420A

- LL7410D/D1/ D2

C6 comonomer

-LL9640U / UP

- LL9641U / UP

C6 comonomer/ metallocene

-LL7910A

- LL7810A -LL7835A

LL7410D

Polymer Type : LL = LLDPE

Grade Name

Application :

7 = Film, 8 = Injection, 9 = Rotational Molding

6 = wire & cable

Additive Package :

A = None Slip & Antiblock

D = With High Slip & Antiblock

D1 = With Low Slip & Antiblock

D2 = Very High Slip & Antiblock

G1 = Low gel with Low Slip & Antiblock

U = UV Stabilizer

UP = Power with UV stabilizer

Comonomer & Catalyst :

4 = C4-ZN, 6 = C6-ZN, 9,8 = C6-Metallocene

Melt Index :

MI for Injection

MI x 10 for film & Roto

>>> InnoPlus LLDPE Nomenclature


InnoPlus LD2426K Melt Flow Rate :

D = 0.2-0.35

F = 0.6-0.9

H = 1.7-2.2

K = 3.4-4.6

T = 33-39

Density , eg. 0.924

Additive Package :

0 = None Slip & Antiblock

6 = With Slip & Antiblock

Internal code

Polymer Type : LD = LDPE

>>> InnoPlus LDPE Nomenclature

Grade Name


Basic Properties Background

1. Melt Flow Rate (MFR) is the output rate (flow) in grams that occurs in 10 and a load of total mass of 2.16 kg at a temperature of 190°C (some use different weights and some even different “Load” @ 5 or 21.6 kg).

Key Basic Properties of InnoPlus Products

Low Molecular Weight High MFR

High Molecular Weight Low MFR

“MFR” refer to “Molecular weight” which affects on: 1. Properties 2. Melt Processability








Basic Properties Background

Key Basic Properties of InnoPlus Products

2. Density is the mass per unit volume of plastic . Density is depend on “molecular chain orientation”

“High density - high melting point - high Stiffness - high strength.

“Low density” - high impact - high ESCR - Soft - Clarity








“By Application”

- Film

- Injection & Masterbatch Carrier

- Blow Molding & Tube

- Monofilament

- Wire & Cable

- Foam & Bubble sheet



- Film



- Monofilament

- Wire & Cable



“HDPE” Film Application

• Industrial film Industrial bag Liner film Plastic sheet

• General purpose film Shopping bag Disposal waste bag Re-sealable bag Bag-on-roll Industrial film

• Thin film Shopping bag Disposal waste bag Re-sealable bag Bag-on-roll Plastic glove

HDPE HD6000F HD7000F HD8000F

MFR 190, 2.16Kg 0.16 0.04 0.03

Density 0.956 0.956 0.950

Application Thin film General purpose

film

Wide film,

Industrial film


LLDPE Grade LL7410A LL7410D LL7410D1 LL7410G1 LL7410D2 LL7420D LL7420D1 LL7810A*

MFR 190, 2.16Kg 1 1 1 1 1 2 2 1

Density 0.918 0.921 0.921 0.921 0.921 0.921 0.921 0.918

Slip/AB No High Low Low Very High High Low No

Remark Very low gel

mLL- High performance

“LLDPE” Film Application

*HVP Product

Packaging Film

Agricultural Film Frozen Food Film

Ice Bag


LLDPE Grade LL7420A LL7428A LL7910A* LL7835A*

MFR 190, 2.16Kg 2 2.8 1 3.5

Density 0.918 0.921 0.918 0.920

Slip / AB No No No No

Remark mLL- Easy Processing

mLL- High performance

Stretch Wrap Film : Machine Wrap & Hand wrap


*HVP Product


Blown Film : Air quench Blown Film : Water quench

Item Air quench Water quench

Antiblock/Slip content Low High

Recommend grade

LLDPE with D1 Series and G1

e.g. InnoPlus LL7410D1, LL7420D1, LL7410G1

LLDPE with D/ D2 Series e.g.

InnoPlus LL7410D, LL7410D2, LL7420D

Recommended Grade by Process



Item Hand-Wrapping Machine-Wrapping

Recommend grade

InnoPlus LL7420A, LL7428A

Or Blend with InnoPlus LL7910A

InnoPlus LL7835A



Cast Film


Item High clarity High clarity & low gel

Recommend grade InnoPlus LL7410D1

LL7410G1



Lamination Film


LDPE LD2420D LD2420F

MFR 190 , 2.16Kg 0.27 0.75

Density 0.922 0.922

Slip/Antiblock No No

Application Heavy Duty film, Shrink film, Agriculture film

“LDPE” Film Application

Shrink Film Agricultural Film


LDPE LD2420H LD2426H LD2420K LD2426K LD2026K

MFR 190, 2.16Kg 1.9 1.9 4.0 4.0 4.0

Density 0.924 0.924 0.924 0.924 0.920

Slip/AB No Yes No Yes Yes

Application General purpose film, Lamination film, Zip bag,

Light Duty Shrink film

“LDPE” Film Application


22


Additive Content

InnoPlus LLDPE InnoPlus LDPE

GradeSlip

(ppm.)

Antiblock

(ppm.)

LL7410D 800 5,000

LL7410D1 700 700

LL7410G1 500 1800

LL7410D2 1,500 5,000

LL7420D 800 5,000

LL7420D1 800 1,500

GradeSlip

(ppm.)

Antiblock

(ppm.)

LD2426H 500 1000

LD2426K 600 1800

LD2026K 600 1500



- Film



- Monofilament

- Wire & Cable



HDPE

HD1100J HD1600J HD2208J HD2218J HD2308J HD2408J

MFR 190, 2.16Kg

18 12 3.7 4.0 6 7

Density 0.958 0.958 0.961 0.954 0.962 0.964

Feature High flow Low flow / UV added

• High flow • Low flow

Masterbatch carrier Toys Housewares

Pallet Crate Garbage bin

“HDPE” Injection Application


Properties Unit HD2218J HD2208J

MFR @ 2.16 kg/190 C g/10min 4 3.7

Density g/cm3 0.954 0.961

UV - Yes Yes

• UV stabilized resin • Suitable for outdoor durable application • Excellent mechanical properties (High impact resistance)

“HDPE” Injection Application

InnoPlus HD2218J



- Film



- Monofilament

- Wire & Cable



• Drinking water bottle • Milk bottle • Beverage bottle

Food containers

HDPE

HD4200B HD5200B

MFR 190, 2.16Kg 0.67 0.45

Density 0.966 0.966

ESCR; 25% Igepal 25 30

Application Food Containers

“HDPE” Blow Molding Application


“HDPE” Blow Molding Application

• Personal care container • Cosmetic bottle • Shampoo bottle • Detergent bottle • Lubricant oil containers

Chemical Containers

HDPE

HD6200B HD6600B

MFR 190, 2.16Kg 0.45 0.40

Density 0.962 0.957

ESCR; 25% Igepal 60 400

Application Chemical containers

/ Food container


LDPE

LD2420D LD2420F LD2420H

MFR 190, 2.16Kg 0.27 0.75 1.9

Density 0.922 0.922 0.924

Slip/AB No No No

Application Cosmetic tube, small bottle

“LDPE” Blow & Tube Application



- Film



- Monofilament

- Wire & Cable



1. Filament Process

2. Flat Yarn Process

31

Monofilament Process


Grade MFR

(g/10min) Density (g/cm3)

Characteristic Application

HD5000S 0.8 0.954 Excellent tenacity, good process

ability, high production rate Ropes, Fishing nets, Agricultural nets, Tarpaulins,

Woven sack HD5001S

0.8

0.954

Excellent thermal stability

“HDPE” Monofilament Application









- Film



- Monofilament

- Wire & Cable



“LLDPE & LDPE” Wire & Cable Application

LLDPE LDPE

LL6420A LD2420H LD2420K

MFR 190C, 2.16Kg 1 1.9 4

Density 0.918 0.923 0.924

Application Base resin for PE Crosslinked

for Low voltage power cable.

Base resin for PE Crosslinked for Medium voltage power cable



- Film



- Monofilament

- Wire & Cable



“LDPE” Foam and Bubble sheet Application

LDPE

LD2420H LD2426H LD2420K LD2426K LD2026K

MFR 190, 2.16Kg 1.9 1.9 4.0 4.0 4.0

Density 0.924 0.924 0.924 0.924 0.920

Slip/AB No Yes No Yes Yes

Application Foam application eg. Foam net, Thermal Insulators Foam, Cap

liner, Bubble sheet


Thank You







Product Refreshment

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