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MADMACKENZIE SOLUTIONS Performance as Prescribed
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MadMackenzie GreenZyme Power Point_1.26.17

Jan 22, 2018

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Page 1: MadMackenzie GreenZyme Power Point_1.26.17

MADMACKENZIE SOLUTIONS

Performance as Prescribed

Page 2: MadMackenzie GreenZyme Power Point_1.26.17

MadMackenzie Solutions Our Company

Headquartered in Houston, Texas, MadMackenzieSolutions, LLC is an Authorized Agent and supplier ofGreenZyme®, a biologically engineered product used toenhance production efficiencies and maximize oilrecovery.

Trust is the foundation of how we operate; we believe inour product and we believe in our team. In everythingwe do, we pledge to follow through with what we saywe will do and we will never intend to mislead about ourproduct’s capabilities.

Our Moto: Performance as Prescribed

Page 3: MadMackenzie GreenZyme Power Point_1.26.17

MadMackenzie Solutions Our Strategy

Education: Create awareness of GreenZyme technology and the product’s global success as a biological EOR solution.

Client Acquisition: Focus on small-to-large sized Independent Oil Companies operating in the United States; lower 48 land wells.

Create Advocacy: Publicize and distribute new case study data to share product’s latest success stories performing in various well conditions and formation characteristics.

Page 4: MadMackenzie GreenZyme Power Point_1.26.17

EOR will be key to satisfy demand for world oil consumption.

The future of World Oil

Page 5: MadMackenzie GreenZyme Power Point_1.26.17

Chemistry

• Fracturing

• Hot oils

• Acid and caustic

• ASP, polymers

Biology

Physics

• Water-flooding

• Steam -injection

• Microwave

• Radio Frequency

EOR

• Microbes – Living• Enzymes – Non-living

Biological EORLiving = MicrobeMicrobe - single-cell organisms so tiny that millions can fit into the eye of a

needle. Oil-Eating microbe converts oil into carbon dioxide and water.

Non-Living = EnzymeEnzyme - a substance produced by a living organism that acts as a catalyst to bring about specific biochemical reaction.

Catalyst – substance that increases the rate of a chemical reaction without itself undergoing any permanent chemical change.

Page 6: MadMackenzie GreenZyme Power Point_1.26.17

What is GreenZyme®?

GreenZyme is engineered through a proprietaryprocess that involves impregnating a high-protein nutrient solution with the selective DNAof oil-digesting microbes.

The process produces a biological liquid enzymespecifically designed to act as an oil releasingcatalyst.

GreenZyme is the evolution of microbe technology for the purpose of EOR.

Page 7: MadMackenzie GreenZyme Power Point_1.26.17

How does GreenZyme® work?

GreenZyme-wetted surfaces

Catalyst for the release of oil

IFT and Permeability

Oil-wetted and water-wetted surfaces are turned into GreenZyme-wetted surfaces, enhancing the formation’s ability to flow.

GZ releases oil from both sandy and water-wetted surfaces catalytically as an enzyme protein catalyst.

GZ works as a catalyst to reduce IFT and increase permeability, helping to unclog blockages and naturally restore formation pressure.

Page 8: MadMackenzie GreenZyme Power Point_1.26.17

Oil releasing process with GreenZyme catalyst

Solid Solid

Crude Oil

H+

OH-

From a solid covered in crude, to catalytic oil released surface, to finally a protected

GreenZyme-wetted surface.

Solid

Page 9: MadMackenzie GreenZyme Power Point_1.26.17

0

50

100

150

200

250

1995 2012 2014 2018 2020

Typical oil well life expectancy

~~~~~ Daily Production ~~~ ~~~~

Initial highest daily production

80% drop from initial production rate

Typical Production

GreenZyme

Injection #1

GreenZyme

Injection #2

Page 10: MadMackenzie GreenZyme Power Point_1.26.17

COMING TOGETHER IS A BEGINNING; KEEPING TOGETHER IS PROGRESS;

WORKING TOGETHER IS UCCESS.

Dr. Partha Pratim

Methods Biology Non-Living Biology Living Chemistry Physics

Process Used Enzyme Microbe

Acid, alkaline, hot oils, organic,

inorganic, polymers,

surfactants…

Steam injection, waterflooding, hi-

temp, CO₂, N₂, ultra sound, and microwave

Real Catalyst Yes Yes No No

Real DNA Molecules Yes Yes No No

Environmentally Friendly Yes Mostly Yes No Mostly Yes

Use of Simple Pumping Yes No No No

Duration EOR Lasts 18-36+ months 3-4 months 3-6 months 3-6 months

Volume of Oil Increase High Small Average Average

Comparison of EOR Methodologies

Page 11: MadMackenzie GreenZyme Power Point_1.26.17

Why & How GreenZyme® is so successful in oil fields

Formation Unclogging

Contact Angle

Oil Releasing Catalyst

Interfacial Tension (IFT)

Page 12: MadMackenzie GreenZyme Power Point_1.26.17

How GreenZyme® works to release

crude oil in formation

1. Oil-wetted sandy surface to GreenZyme®-water-wetted surface, with surface protection.2. Water-wetted surface to GreenZyme®-water-wetted surface, with surface protection.3. GreenZyme® releases oil from sandy surface catalytically.4. GreenZyme® unclog any formation-blockages.5. GreenZyme® increases permeability, restore formation pressure due to blockages.

1 2 3 45

Oil released by GreenZyme

Page 13: MadMackenzie GreenZyme Power Point_1.26.17

How can GreenZyme® enhance my oil production?

Page 14: MadMackenzie GreenZyme Power Point_1.26.17

• Mature wells with continuous decline

• New wells with rapid decline

• Mobilize oils of various viscosities

• Improve start-up well performance

• Wells with clogging problems

• Waterflooding systems

• Single huff-and-puff wells

• Steam Injection wells

• Chemical Fracturing wells

Applications:

Page 15: MadMackenzie GreenZyme Power Point_1.26.17

• Temperature

• pH

• Salinity

• Radioactive Isotopes

• NORM

• Sulfur

• Hydrogen Sulfide content

• Paraffins

• Asphaltenes (up to 50%)

Unaffected by adverse well conditions such as:

Page 16: MadMackenzie GreenZyme Power Point_1.26.17

Is your well a strong candidate for GreenZyme® EOR?

• Oil service pumping truck capable of up to 5000 psig

• High pressure piston, plunger or triplex pump

• Onsite mixing tanks

• Currently producing at ≥20% of initial start-up daily production average

• Water cut < 80%

• Porosity > 15%• Vertical wells require

4-12 drums

• Horizontal wells require 8-12 drums

• 3 days with well porosity >20%, with little wax.

• 4-5 days if higher oil density

• 6-8 days if reduced porosity and increased wax.

Shut-in TimeHow much GreenZyme?

Good Candidate

Required Equipment

Page 17: MadMackenzie GreenZyme Power Point_1.26.17

GreenZyme® is Effective & Efficient

Product History & Experience

Product Simplicity

Environmentally Friendly

Product Applications

Solution designed to create a natural biochemical reaction that enhances oil production.

Proven product injected in thousands of wells worldwide with many years of experience.

No special equip needed operationally; product is injected directly through the well’s casing-tubing.

GreenZyme solution is a non-pathogenic, nontoxic, and 100% biodegradable.

Can accommodate a wide array of well formations and life cycle’s, with many strong advantages over other EOR methods.

Enzyme EOR Catalyst

Page 18: MadMackenzie GreenZyme Power Point_1.26.17

Publication references about GreenZyme®New Frontiers in EOR Methodologies by Application of Enzymes

SPE 154690: Tarang Jain and Akash Sharma

“The enzyme function of the product is due to the fact that the enzymes seek and release oil, but is not consumed in the releasing

mechanism. After the release of hydrocarbons the enzymes will be attached to the solid surfaces and… are available to interact with new

hydrocarbons and cause the release of oil.”

EOR Pilot Tests with Modified Enzyme [GreenZyme] – Dangang Field, China

Authors: Qing-xian Feng, Xian-ping Ma, Li-hong Zhou, Ding-bo Shao, Xiao-lin Wang and Bao-yan Qin of PetroChina Oilfield Co.

“… [GreenZyme] was applied to the Shengli field in China and increased production was sustained for 180 days producing an additional 10,961

bbl. …With continued development over the next two years, more than 100 wells saw enzyme applications with a success ratio of greater than

88%.”

“GreenZyme® is the EOR of the future: cleaner, safer, and smarter. It is a biodegradable, biological enzyme

derivative. It digests nothing, dissolves nothing, and causes nothing to grow. GreenZyme performs its

biological function in every reservoir.”

~ Olivia Carey, Asset Manager, Operator

EEOR Success in Mann Field, Myanmar

SPE 144231: William K. Ott, Thu Nyo, Win Nyunt Aung, and Aung Thet Khaing

“The environment-friendly enzyme, a biological catalyst, can significantly accelerate (several million reactions per second) release of oil from

grain surfaces in an oil reservoir. In addition, it can change rock wettability from oil-wet to water-wet to GreenZyme-wet, thus reducing

interfacial tension of solids and oil-flow resistance through formation pore spaces. The enzyme works biologically, theoretically never being

consumed, reapplied until diluted by produced water.”

Page 19: MadMackenzie GreenZyme Power Point_1.26.17

Thank you for your time.

Please contact us for more information and learn if GreenZyme EOR is the right

choice for your oil wells.

[email protected]

Office: 281-778-8128

MadMackenzie Solutions

9119 Hwy 6 Suite 230

Missouri City, TX 77459