LETTER OF TRANSMITTAL - New Jerseynj.gov/dep/fenimore/docs/2-13-001-0-braen-stone-sparta...August 18, 2014 The Conti Group Attn: Kevin Conaboy 2045 Lincoln Highway Edison, NJ 08817-3334

LETTER OF TRANSMITTAL

412 Mount Kemble Ave. | Morristown | NJ | 07962 | USA | Tel +1.973.407.1000

louisberger.com

TRANSMITTAL 035

To: Kevin Conaboy, Project Manager

The Conti Group 2045 Lincoln Highway Edison, NJ 08817-3334 732.520.5000

Project: NJDEP – Fenimore Partial Landfill Closure Project

Re: Submittal Review

From: Christopher Corliss, P.E. CC: Paula Walshe, Jesse Robbins, Mike Alexander, Robert Hayton Date: September 15, 2014

CONTI

SUBMITTAL NO.

REV.

COPIES SPEC. SECTION

DESCRIPTION STATUS

2.13-001-0 0 1 2.13 Braen Stone/Sparta Clean Fill Certificate and Analytical Data

NET

2.13-002-0 0 1 2.13 Coarse Aggregate #2 (2-1/2” Stone)

NET

2.13-003-0 0 1 2.13 Coarse Aggregate #3 (1-1/2” Stone)

NET

2.13-004-0 0 1 2.13 Coarse Aggregate #57 (3/4” Stone)

NET

2.20-001-0 0 1 2.20 Riprap Stone (d50 = 4”, 9” and 12”)

NET

NET – No Exceptions Taken MCN – Make Corrections Noted AR – Amend & Resubmit R – Rejected TANSS – Take Action Noted on Sub-Consultant Stamp Remarks:

Project: Fenimore Partial Landfill Closure LBG Project No.: 2002101.024 Contractor: Conti Submittal No. & Description: Transmittal 035 – 2.13-001-0 Braen Stone

(Sparta) Clean Fill Cert Transmittal 061 – 2.13-001-0 Braen Stone/Sparta

Analytical Data Spec. Section: 2.13 Coarse Aggregate

Page 1 of 1

The Contractor is responsible for determining and verifying all

quantities, dimensions, specified performance criteria, installation requirements, materials, catalog numbers and similar data with respect thereto and reviewing and coordinating each shop drawing or sample with other shop drawings and samples and with the requirements of the work and the contract documents.

This check is for conformance with the design concept of the

project in accordance with the Contract Specifications and Drawings. This check does not relieve the contractor from compliance with the requirements of the Contract Documents.

The Contractor is responsible for the means, methods, techniques,

sequences and procedures of construction and the safety precautions and programs incident thereto and this review does not extend to them.

X NO EXCEPTIONS TAKEN

MAKE CORRECTIONS NOTED

AMEND & RESUBMIT

REJECTED

TAKE ACTION NOTED ON SUB-CONSULTANT STAMP

Date: 09/15/14 By: ___

LOUIS BERGER

Engineer Review Comments

No. 035

DATE:

JOB #: Contract # A-82790

RE: Fenimore Landfill

TO:

Morristown, NJ 07962-1946

WE ARE SENDING YOU: X Attached via Fed Ex Hand Delivery X Email

Geotech Borings Chemical Data Site Map Bid Documents

Plans X Mtrl Data Misc. Work Scope QUOTATION REQUEST (SEE BELOW)

COPIES

1

1

1

1

THESE ARE TRANSMITTED AS CHECKED BELOW:

For your use As requested Strictly Confidential

X For review and comment

REMARKS:

COPY TO: PW, JR, MA - DEP SIGNED: Kevin Conaboy

The Conti Group LETTER OF TRANSMITTAL

Phone - (732) 520-5000

Fax - (732) 520-5199

Edison, NJ 08817

2045 Lincoln Highway

Submittal 2.13-002-0; Coarse Aggregate #2 (2-1/2" Stone)

August 18, 2014

DATE

Maureen Rabbit, P.E.

412 Mount Kemble Ave

PO Box 1946

REVISION

8/18/2014

8/18/2014

8/18/2014

DESCRIPTION

0

0

0

08/18/2014

Submittal 2.13-003-0; Coarse Aggregate #3 (1/1/2" Stone)

Submittal 2.13-001-0; Braen Stone/Sparta Clean Fill Certificate

Submittal 2.13-004-0; Coarse Aggregate #57 (3/4" Stone)

August 18, 2014

The Conti Group

Attn: Kevin Conaboy


Edison, NJ 08817-3334

Re: Material Pre-Certification-

Fenimore Landfill

Roxbury, NJ

Dear Madam/Sir,

This is to certify that the Material supplied to the above referenced project, was be

extracted, blended, and/or manufactured from one of the following virgin material sources:

granite-gneiss stone deposit; naturally occurring overburden soil material and/or glacial deposit of

sand & gravel. These materials quarried are located on Block 51; Lot 35, Borough of Sparta,

Sussex County, New Jersey. This is commonly known as 217 Limecrest Road of Lafayette. To the

best of our knowledge this material contained no hazardous or contaminated materials prior to

shipment. Mine Registration Number 003975.

If we can be of any further assistance, please contact us at the number listed.

Respectfully,

Braen Stone of Sparta

Russ Berger

Director of Quality Control

Cc: File

No. 061

DATE:

JOB #: Contract # A-82790

RE: Fenimore Landfill

TO: Maureen Rabbit, P.E.

The Louis Berger Group, Inc.

412 Mount Kemble Ave

PO Box 1946

Morristown, NJ 07962-1946

WE ARE SENDING YOU: X Attached via Fed Ex Hand Delivery X Email

Geotech Borings Chemical Data Site Map Bid Documents

Plans X Mtrl Data Samples Letter QUOTATION REQUEST (SEE BELOW)

COPIES

1

THESE ARE TRANSMITTED AS CHECKED BELOW:

For your use As requested Strictly Confidential

X For review and comment

REMARKS:

COPY TO: JR, MA - DEP SIGNED: Kevin Conaboy

Submittal 2.13-001-0; Braen Stone/Sparta Analytical Data

Addendum to previous 2.13-001-0 Clean Fill Cert

Analytical Data submitted to accompany previously submitted Clean Fill Certification

0

DATE REVISION

9/11/2014

DESCRIPTION

The Conti Group LETTER OF TRANSMITTAL

Phone - (732) 520-5000

Fax - (732) 520-5199

Edison, NJ 08817


September 11, 2014

APLAQUA PRO-TECH LABORATORIESCertified Environmental Testing

Brian Wood

Laboratory Director

Project: Sparta Quarry

ANALYTICAL RESULTS

REDUCED DELIVERABLES FORMAT

APL WORK ORDER NUMBER: 4080683

All Results meet the requirements of the National Environmental Laboratory Accreditation Conference and/or

State specific certifications as applicable.

Braenstone Of Sparta

NELAC National Environmental Laboratory Accreditation Conference NJDEP #07010 / NYDOH #11634 / PADEP #68-02903

1275 Bloomfield Ave., Bldg. 6, Fairfield, New Jersey 07004(t) 973.227.0422 (f) 973.227.2813 (w) www.aquaprotechlabs.com

CONTENTS

1. Chain of Custody 4

2. Methodology Summary 5

3. Abbreviations and Qualifiers 6

4. Conformance/Non-Conformance Summary 7

5. Positive Results Summary 8

6. PCB Results 9

6.1. Blank Results 106.2. Sample Results 136.3. Surrogate Recoveries 166.4. Spike/Duplicate Results 176.5. Blank Summary 186.6. Sequence/RT Summary 196.7. Initial Calibration 206.8. Continuing Calibration 24

7. GC Results 36

7.1. Blank Results 377.2. Sample Results 407.3. Surrogate Recoveries 437.4. Spike/Duplicate Results 447.5. Blank Summary 457.6. Initial Calibration 467.7. Continuing Calibration 48

8. Mercury Results 51

8.1. Blank Results 528.2. Sample Results 538.3. Spike/Duplicate Results 548.4. Blank Summary 558.5. Sequence Summary 568.6. Continuing Calibration 57

9. Metal Results 58

9.1. Blank Results 599.2. Sample Results 609.3. Spike/Duplicate Results 619.4. Blank Summary 649.5. Sequence Summary 659.6. Continuing Calibration 67

10. Pesticide Results 73

10.1. Blank Results 7410.2. Sample Results 77

APL 2 of 162Aqua Pro-Tech LaboratoriesCommitted to Excellence in ChemistryPN: 4080683

sections1

23

45

67

89

1011

1213

10.3. Surrogate Recoveries 8010.4. Spike/Duplicate Results 8110.5. Blank Summary 8210.6. Sequence/RT Summary 8310.7. Initial Calibration 8410.8. Continuing Calibration 86

11. Semivolatile Results 94

11.1. Blank Results 9511.2. Sample Results 10111.3. Surrogate Recoveries 10711.4. Spike/Duplicate Results 10811.5. Blank Summary 10911.6. Sequence/Tune Summary 11011.7. Initial Calibration 11611.8. Continuing Calibration 12011.9. Internal Standard Summary 130

12. Volatile Results 131

12.1. Blank Results 13212.2. Sample Results 13712.3. Surrogate Recoveries 14312.4. Spike/Duplicate Results 14412.5. Blank Summary 14512.6. Sequence/Tune Summary 14612.7. Initial Calibration 15012.8. Continuing Calibration 15412.9. Internal Standard Summary 159

13. General Chemistry 160

13.1. General Chemistry Results 161


sections1

23

45

67

89

1011

1213


11.

Aqua Pro-Tech Laboratories Methodology Summary

Methodology Summary

Extractable Petroleum Hydrocarbons:

Gas Chromatography/Flame Ionization Detector

New Jersey Department of Environmental Protection Site Remediation Program Extractable Petroleum

Hydrocarbons Methodology (Version 3.0).

USEPA SW-846 Test Methods for Evaluating Solid Waste Physical/Chemical Methods Update III, Method 8015B or

NJDEP Office of Quality Assurance Quantitation of Semi-Volatile Petroleum Products in Water, Soil and Sediment

OQA-QAM-025, Revision 6.

Metals:

Inductively-Coupled Plasma Atomic Emission Spectrometry or Inductively-Coupled Plasma Mass

Spectroscopy

Water Samples-USEPA Methods for the Analysis of Water and Wastes, Method 200.7 or 200.8.

Soil Samples-USEPA Methods for Evaluating Solid Waste Physical/Chemical Methods Update III, Method 6010B.

Mercury:

Cold Vapor Atomic Absorption Spectrometry

Water Samples-USEPA Methods for the Analysis of Water and Wastes, Method 245.1.

Soil Samples-USEPA SW-846 Test Methods for Evaluating Solid Waste Physical/Chemical Methods Update III,

Method 7171A.

Volatile Organic Compounds:

Purge and Trap Gas Chromatography/Mass Spectroscopy

Drinking Water Samples-USEPA Methods for the Determination of Organic Compounds in Drinking Water,

Method 524.2.

Water Samples-USEPA Methods for the Analysis of Water and Wastes, Method 624.


Method 8260B.

Semi-Volatile Organic Compounds:

Gas Chromatography/Mass Spectroscopy



Method 8270C.

Pesticides:

Gas Chromatography/Electron Capture Detector



Method 8081A.

Polychlorinated Biphenyls (PCBs):

Gas Chromatography/Electron Capture Detector



Method 8082

General Chemistry Methods:

Various general chemistry methods are taken from ^Standard Methods for the Examination of Water and

Wastewater, 19th Edition_.

Specific method citations can be found on the Analytical Results Summary page of this report listed under 'Method'.


22.

Aqua Pro-Tech Laboratories Data Reporting Abbreviations and Qualifiers

Data Reporting Abbreviations and Qualifiers

MDL:

Method Detection Limit. The minimum reportable concentration of a substance that can be measured

and reported with 99% confidence that the analyte concentration is greater than zero. The value is

calculated from the analysis of seven replicates of a spike sample. On analytical reports this value is

corrected for percent moisture and any concentration or dilution factors.

RL:

Reporting Limit. The Concentration of the lowest calibration standard that was included in the initial

calibration of the instrument. On analytical reports this value is corrected for percent moisture and any

concentration or dilution factors.

Concentration (Conc) / Result:

If the compound is detected, the measured concentration is reported. If this column is left blank, or

contains a 'less than' (<) symbol, the compound was not detected.

Tentatively Identified Compound (TIC):

A TIC is a non-targeted compound, not included in the calibration, identified by a mass spectral library

search.

Qualifiers:

U: Indicates the compound was analyzed for but was not detected.

J: Indicates an estimated value. All tentatively identified compounds (TICs) and results below the RL

receive this qualifier.

B: Indicates the analyte was found in the method blank as well as the sample.

N: Used when reporting a specific tentatively identified compound.

E: Indicates that the concentration of the compound exceeds the calibration range of the

instrument. The results of a diluted analysis will also be reported. The results of the dilution

should be used for those compounds exceeding the calibration range in the undiluted analysis.


33.

ANALYSIS: Inorganics (6010B / 7471A / General Chemistry)

ANALYSIS: EPH (NJDEP-EPH-CAT2)

ANALYSIS: PCB (8082)

ANALYSIS: PESTICIDES (8081)COMMENTS:

COMMENTS:Sample 4080683-01 passed all QC criteria.

The matrix spike (B4H2206-MS1) and matrix spike duplicate (B4H2206-MSD1) failed the QC criteria for 4,4'-DDT (low). However, this compound passed all QC criteria for the blank spike (B4H2206-BS1).

QUALITY CONTROLConformance/Non-Conformance Summary (Various Methods)

COMMENTS:Method 6010B:Several metals failed the QC criteria for the matrix spike (B4H2641-MS1) and matrix spike duplicate (B4H2641-MSD1) (low and high). However, these metals passed all QC criteria for the blank spike (B4H2641-BS1).Method 7471A:Sample 4080683-01 passed all QC criteria.General Chemistry:Sample 4080683-01 passed all QC criteria.

COMMENTS:Sample 4080683-01 passed all QC criteria.

ANALYSIS: VOLATILES BY GC/MS (8260B)

ANALYSIS: SEMI-VOLATILES BY GC/MS (8270C)COMMENTS:

Reviewed By: (SK)Brian Wood - Laboratory Director Date

Sample 4080683-01 passed all QC criteria.

The continuing calibration (S4H2807-CCV1) and blank spike (B4H2829-BS1) failed the QC criteria for 1,1-Dichloroethene (high). However, this compound was not detected in the sample.

COMMENTS:

9/9/2014


44.

Positive Results Only SummaryAPLAQUA PRO-TECH LABORATORIESCertified Environmental Testing

QUARRY FINES4080683-01 (Soil) Sample Name:

SW 846 6010B - Total Metals

Analyte Result MDLQual Dilution AnalyzedRL Units

2.64 1 8/29/14 16:366470 0.391Aluminum mg/kg dry

0.528 1 8/29/14 16:3627.0 0.0404Barium mg/kg dry

0.0264 1 8/29/14 16:360.166 0.00197Beryllium mg/kg dry

26.4 1 8/29/14 16:355810 2.39Calcium mg/kg dry

0.264 1 8/29/14 16:3619.7 0.0122Chromium mg/kg dry

0.211 1 8/29/14 16:364.22 0.0212Cobalt mg/kg dry

0.264 1 8/29/14 16:368.33 0.0470Copper mg/kg dry

5.28 1 8/29/14 16:3512000 0.155Iron mg/kg dry

0.528 1 8/29/14 16:361.62 0.151Lead mg/kg dry

52.8 1 8/29/14 16:354320 25.4Magnesium mg/kg dry

0.264 1 8/29/14 16:36174 0.0114Manganese mg/kg dry

0.132 1 8/29/14 16:369.70 0.0592Nickel mg/kg dry

106 1 8/29/14 16:352230 4.96Potassium mg/kg dry

52.8 1 8/29/14 16:35203 4.04Sodium mg/kg dry

0.528 1 8/29/14 16:361.66 0.133Thallium mg/kg dry

0.528 1 8/29/14 16:3618.4 0.143Vanadium mg/kg dry

0.792 1 8/29/14 16:3624.5 0.0452Zinc mg/kg dry

SW 846 8260B - Volatile Organics - GC/MS


1 8/28/14 19:590.00618 JTIC_unknown mg/kg dry

SW 846 8270C - Semivolatile Organics - GC/MS


1 8/26/14 1:250.510 JTIC_Erucylamide mg/kg dry

1 8/26/14 1:250.355 J, BTIC_Pentadecane mg/kg dry


55.

PCBs


Work Order: 4080683




66.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

5B01217.D

08/22/14 19:42

S4H2506

B4H2205

08/22/14 07:51

Sonication GC

Project:

4080683Client Sample ID: Blank

B4H2205-BLK1Lab Sample ID:

Init/Final Vol: 15 g / 10 mL

Soil

Braenstone Of Sparta Sparta Quarry

PCBs - SW 846 8082

CAS NO. QRLMDLCONC. (mg/kg wet)COMPOUND

12674-11-2 UAroclor-1016 ND 0.00108 0.0330

11104-28-2 UAroclor-1221 ND 0.00711 0.0330

11141-16-5 UAroclor-1232 ND 0.00186 0.0330

53469-21-9 UAroclor-1242 ND 0.00255 0.0330

12672-29-6 UAroclor-1248 ND 0.00180 0.0330

11097-69-1 UAroclor-1254 ND 0.000694 0.0330

11096-82-5 UAroclor-1260 ND 0.00125 0.0330

37324-23-5 UAroclor-1262 ND 0.00265 0.0330

11100-14-4 UAroclor-1268 ND 0.00186 0.0330


66.1.

Quantitation Report (QT Reviewed)

Signal #1 : G:\HPCHEM\GCECD5\DATA\20140822\5B01217.D\ECD1A.CH Vial: 1 Signal #2 : G:\HPCHEM\GCECD5\DATA\20140822\5B01217.D\ECD2B.CH Acq On : 22 Aug 2014 19:42 Operator: gch Sample : B4H2205-BLK1 Inst : GCECD-5 Misc : Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Aug 25 13:54 2014 Quant Results File: 80820711.RES

Quant Method : G:\HPCHEM\G...\80820711.M (Chemstation Integrator) Title : PCBs by EPA Method 8082 Last Update : Wed Aug 13 17:11:32 2014 Response via : Initial Calibration DataAcq Meth : runPCB.M

Volume Inj. : 2ul Signal #1 Phase : RTx-50 Signal #2 Phase: RTx-CLPesticides II Signal #1 Info : 30M x 0.53mm x 0. Signal #2 Info : 30M x 0.53mm x 0.42um

Compound RT#1 RT#2 Resp#1 Resp#2 ug/kg ug/kg -------------------------------------------------------------------------

System Monitoring Compounds 1) S TCMX 4.54 5.27 299.8E6 337.0E6 37.317 39.182 Spiked Amount 50.000 Range 36 - 149 Recovery = 74.63% 78.36% 2) S Decachlorobiphen 16.65 20.19f 200.6E6 241.9E6 23.531 28.897 Spiked Amount 50.000 Range 39 - 137 Recovery = 47.06% 57.79%

Target Compounds Sum Aroclor-1016 (1) 0 0 N.D. N.D. Average Aroclor-1016 (1) 0.000 0.000

Sum Aroclor-1221 (1) 0 0 N.D. N.D. Average Aroclor-1221 (1) 0.000 0.000








-----------------------------------------------------------------------------(f)=RT Delta > 1/2 Window (#)=Amounts differ by > 25% (m)=manual int.5B01217.D 80820711.M Fri Aug 29 15:25:36 2014 SS Page 1


66.1.


Signal #1 : G:\HPCHEM\GCECD5\DATA\20140822\5B01217.D\ECD1A.CH Vial: 1 Signal #2 : G:\HPCHEM\GCECD5\DATA\20140822\5B01217.D\ECD2B.CH Acq On : 22 Aug 2014 19:42 Operator: gch Sample : B4H2205-BLK1 Inst : GCECD-5 Misc : Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Aug 25 13:54 2014 Quant Results File: 80820711.RES

Quant Method : G:\HPCHEM\G...\80820711.M (Chemstation Integrator) Title : PCBs by EPA Method 8082 Last Update : Wed Aug 13 17:11:32 2014 Response via : Multiple Level Calibration DataAcq Meth : runPCB.M


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00

0

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

Time

Response_ 5B01217.D\ECD1A

4.5

4

16.6

5D

ecachlo

ro

TC

MX

4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time

Response_ 5B01217.D\ECD2B

5.2

7

20.1

9D

eca

ch

loro

TC

MX

#2

5B01217.D 80820711.M Fri Aug 29 15:25:36 2014 SS Page 2


66.1.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

5B01244.D

08/23/14 07:13

S4H2506

B4H2205

08/22/14 07:51

Sonication GC

Project:

4080683

Client Sample ID: QUARRY FINES

4080683-01Lab Sample ID:


1Dilution:

Percent Solids: 94.67

Soil

08/21/14 09:35


Sparta Quarry

PCBs - SW 846 8082

CAS NO. QRLMDLCONC. (mg/kg dry)COMPOUND

12674-11-2 UAroclor-1016 ND 0.00114 0.0349

11104-28-2 UAroclor-1221 ND 0.00751 0.0349

11141-16-5 UAroclor-1232 ND 0.00197 0.0349

53469-21-9 UAroclor-1242 ND 0.00269 0.0349

12672-29-6 UAroclor-1248 ND 0.00191 0.0349

11097-69-1 UAroclor-1254 ND 0.000733 0.0349

11096-82-5 UAroclor-1260 ND 0.00132 0.0349

37324-23-5 UAroclor-1262 ND 0.00280 0.0349

11100-14-4 UAroclor-1268 ND 0.00196 0.0349

ND - Indicates compound analyzed for but not detected

J - Indicates estimated value

B - Indicates compound found in associated blank

E - Concentration exceeds highest calibration standard

D - Indicates result is based on a dilution

P - Greater than 25% diff. between 2 GC columns.

MDL - Minimum detection limit

RL - Reporting limit


66.2.


Signal #1 : G:\HPCHEM\GCECD5\DATA\20140822\5B01244.D\ECD1A.CH Vial: 80 Signal #2 : G:\HPCHEM\GCECD5\DATA\20140822\5B01244.D\ECD2B.CH Acq On : 23 Aug 2014 7:13 Operator: gch Sample : 4080683-01 Inst : GCECD-5 Misc : Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Aug 25 15:49 2014 Quant Results File: 80820711.RES




System Monitoring Compounds 1) S TCMX 4.54 5.28 381.2E6 418.3E6 47.441 48.642 Spiked Amount 50.000 Range 36 - 149 Recovery = 94.88% 97.28% 2) S Decachlorobiphen 16.66 20.20f 210.3E6 263.3E6 24.666 31.454 # Spiked Amount 50.000 Range 39 - 137 Recovery = 49.33% 62.91%

Target Compounds Sum Aroclor-1016 (1) 0 0 N.D. N.D. Average Aroclor-1016 (1) 0.000 0.000









-----------------------------------------------------------------------------(f)=RT Delta > 1/2 Window (#)=Amounts differ by > 25% (m)=manual int.5B01244.D 80820711.M Tue Sep 09 12:05:23 2014 SS Page 1


66.2.


Signal #1 : G:\HPCHEM\GCECD5\DATA\20140822\5B01244.D\ECD1A.CH Vial: 80 Signal #2 : G:\HPCHEM\GCECD5\DATA\20140822\5B01244.D\ECD2B.CH Acq On : 23 Aug 2014 7:13 Operator: gch Sample : 4080683-01 Inst : GCECD-5 Misc : Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Aug 25 15:49 2014 Quant Results File: 80820711.RES



4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


4.5

4

16.6

5D

ecachlo

ro

TC

MX

4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

1.4e+07

Time


5.2

7

20.2

0D

eca

ch

loro

TC

MX

#2

5B01244.D 80820711.M Tue Sep 09 12:05:24 2014 SS Page 2


66.2.

SURROGATE RECOVERIESAnalysis Class: PCBs

Method:

File ID

Matrix: Soil

Lab Number DCB[2C]TCMX DCB TCMX[2C]

SW 846 8082

4080683-01 5B01244.D 94.9 49.3 97.3 62.9

B4H2205-BLK1 5B01217.D 74.6 47.1 78.4 57.8

* - Outside of QC Limits

Surrogate Limits Lo Limit Hi Limit

DCB[2C]

TCMX

DCB

TCMX[2C]

Tetrachloro-m-xylene

Decachlorobiphenyl

Tetrachloro-m-xylene [2C]

Decachlorobiphenyl [2C]

36 149

39

36

39

137

149

137


66.3.

PCBs - Quality Control

Aqua Pro-Tech Laboratories

Batch B4H2205 Prepared: 08/22/2014Method: SW 846 8082

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source0.333 60-13094.8mg/kg wetAroclor-1016B4H2205-BS1 0.316

0.333 60-130114mg/kg wetAroclor-1260B4H2205-BS1 0.381

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source0.369 60-14093.8mg/kg dryAroclor-1016B4H2205-MS1 4080477-01 ND0.347

0.369 60-14085.1mg/kg dryAroclor-1260B4H2205-MS1 4080477-01 ND0.314

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source0.369 3060-14083.6 11.6mg/kg dryAroclor-1016B4H2205-MSD1 4080477-01 ND0.309

0.369 3060-14084.5 0.688mg/kg dryAroclor-1260B4H2205-MSD1 4080477-01 ND0.312


NC - Outside the recovery criteria but Spike Amount <1/4 amount found in Source Sample


66.4.

METHOD BLANK SUMMARY

B4H2205Batch ID:

Extraction DateLab Number Sample Id

B4H2205-BLK1 BLK1 8/22/2014

B4H2205-BS1 BS1 8/22/2014

B4H2205-MS1 MS1 8/22/2014

B4H2205-MSD1 MSD1 8/22/2014

4080683-01 QUARRY FINES 8/22/2014


66.5.

SURROGATE RT DRIFT REPORT

Analysis Class: PCBs

Lab Number File ID

Sequence : S4H2506

RT Ref RT Drift RT Ref RT Drift RT Ref RT Drift RT Ref RT Drift

DCB[2C]TCMX[2C]DCBTCMX

B4H2205-BLK1 5B01217.D 4.54 16.65 5.27 20.19 0.0020.195.2716.664.54 0.00 0.00 0.00

4080683-01 5B01244.D 4.54 16.66 5.28 20.2 0.0020.25.2816.664.54 0.00 0.00 0.00

Surrogate


Decachlorobiphenyl



0.10

0.10

0.10

0.10

Limit

DCB[2C]

TCMX[2C]

DCB

TCMX DISS = Dissolved Analysis


66.6.

Response Factor Report HP G1530A

Method : G:\HPCHEM\GCECD5\METHODS\80820711.M (Chemstation Integrator) Title : PCBs by EPA Method 8082 Last Update : Mon Jul 28 17:30:33 2014

Calibration Files 50 =5B00001.D 250 =5B00002.D 500 =5B00369.D 1000 =5B00346.D 2000 =5B00005.D

Compound 50 250 500 1000 2000 Avg %RSD---------------------------------------------------------------------------

1) S TCMX 7.424 7.850 7.972 8.320 8.608 8.035 E6 5.64 2) S Decachlorobiphenyl 9.323 8.485 8.550 8.240 8.024 8.525 E6 5.78 3) L3 Aroclor-1016 (1) 1.110 1.434 1.344 1.284 1.243 1.283 E5 9.39 4) L3 Aroclor-1016 (2) 2.827 2.708 2.607 2.544 2.510 2.639 E5 4.90 5) L3 Aroclor-1016 (3) 1.665 1.672 1.635 1.613 1.595 1.636 E5 2.01 6) L3 Aroclor-1016 (4) 5.255 4.845 4.826 4.888 4.962 4.955 E5 3.54 7) L3 Aroclor-1016 (5) 1.893 2.119 2.086 2.074 2.063 2.047 E5 4.33 8) L4 Aroclor-1221 (1) 5.797 5.797 E4 0.00 9) L4 Aroclor-1221 (2) 1.814 1.814 E4 0.00 10) L4 Aroclor-1221 (3) 7.352 7.352 E4 0.00 11) L5 Aroclor-1232 (1) 9.550 9.550 E3 0.00 12) L5 Aroclor-1232 (2) 3.744 3.744 E4 0.00 13) L5 Aroclor-1232 (3) 1.079 1.079 E5 0.00 14) L5 Aroclor-1232 (4) 9.411 9.411 E4 0.00 15) L6 Aroclor-1242 (1) 9.653 9.653 E4 0.00 16) L6 Aroclor-1242 (2) 1.806 1.806 E5 0.00 17) L6 Aroclor-1242 (3) 3.512 3.512 E5 0.00 18) L6 Aroclor-1242 (4) 1.414 1.414 E5 0.00 19) L6 Aroclor-1242 (5) 8.185 8.185 E4 0.00 20) L7 Aroclor-1248 (1) 9.393 9.393 E4 0.00 21) L7 Aroclor-1248 (2) 2.230 2.230 E5 0.00 22) L7 Aroclor-1248 (3) 1.785 1.785 E5 0.00 23) L7 Aroclor-1248 (4) 2.725 2.725 E5 0.00 24) L8 Aroclor-1254 (1) 3.196 3.196 E5 0.00 25) L8 Aroclor-1254 (2) 2.089 2.089 E5 0.00 26) L8 Aroclor-1254 (3) 2.519 2.519 E5 0.00 27) L8 Aroclor-1254 (4) 3.569 3.569 E5 0.00 28) L9 Aroclor-1260 (1) 3.187 2.976 3.015 2.931 2.958 3.013 E5 3.38 29) L9 Aroclor-1260 (2) 5.135 4.924 4.750 4.700 4.696 4.841 E5 3.90 30) L9 Aroclor-1260 (3) 5.694 5.391 5.466 5.281 5.140 5.394 E5 3.85 31) L9 Aroclor-1260 (4) 6.321 6.035 6.061 6.201 6.059 6.135 E5 2.00 32) L9 Aroclor-1260 (5) 3.462 3.472 3.222 3.428 3.441 3.405 E5 3.04 33) L1 Aroclor-1262 (1) 9.555 9.555 E5 0.00 34) L1 Aroclor-1262 (2) 1.732 1.732 E5 0.00 35) L1 Aroclor-1262 (3) 3.728 3.728 E5 0.00 36) L2 Aroclor-1268 (1) 9.337 9.337 E5 0.00 37) L2 Aroclor-1268 (2) 2.147 2.147 E6 0.00 38) L2 Aroclor-1268 (3) 6.823 6.823 E5 0.00

Signal #2 Calibration Files 50 =5B00001.D 250 =5B00002.D 500 =5B00369.D 1000 =5B00346.D 2000 =5B00005.D Compound 50 250 500 1000 2000 Avg %RSD---------------------------------------------------------------------------

1) S TCMX 8.368 8.132 8.492 8.839 9.170 8.600 E6 4.75 2) S Decachlorobiphenyl 8.599 8.137 8.119 8.555 8.441 8.370 E6 2.73 3) L3 Aroclor-1016 (1) 1.473 1.419 1.374 1.343 1.295 1.381 E5 4.96 4) L3 Aroclor-1016 (2) 3.109 3.034 2.915 2.749 2.649 2.891 E5 6.63 5) L3 Aroclor-1016 (3) 2.244 2.069 2.034 2.061 1.873 2.056 E5 6.41 6) L3 Aroclor-1016 (4) 5.769 5.568 5.541 5.562 6.018 5.692 E5 3.60 7) L3 Aroclor-1016 (5) 2.332 2.305 2.257 2.155 2.553 2.320 E5 6.32 8) L4 Aroclor-1221 (1) 1.892 1.892 E4 0.00 9) L4 Aroclor-1221 (2) 7.836 7.836 E4 0.00 10) L4 Aroclor-1221 (3) 1.881 1.881 E5 0.00 11) L5 Aroclor-1232 (1) 3.769 3.769 E4 0.00 12) L5 Aroclor-1232 (2) 4.162 4.162 E4 0.00 13) L5 Aroclor-1232 (3) 1.243 1.243 E5 0.00 14) L5 Aroclor-1232 (4) 1.194 1.194 E5 0.00 15) L6 Aroclor-1242 (1) 1.132 1.132 E5 0.00 16) L6 Aroclor-1242 (2) 2.118 2.118 E5 0.00

80820711.M Tue Jul 29 16:20:44 2014 SS Page 1(#) = Out of Range


66.7.

Response Factor Report HP G1530A

Method : G:\HPCHEM\GCECD5\METHODS\80820711.M (Chemstation Integrator) Title : PCBs by EPA Method 8082 Last Update : Mon Jul 28 17:30:33 2014

Calibration Files 50 =5B00001.D 250 =5B00002.D 500 =5B00369.D 1000 =5B00346.D 2000 =5B00005.D

Compound 50 250 500 1000 2000 Avg %RSD---------------------------------------------------------------------------

17) L6 Aroclor-1242 (3) 4.274 4.274 E5 0.00 18) L6 Aroclor-1242 (4) 1.692 1.692 E5 0.00 19) L6 Aroclor-1242 (5) 1.054 1.054 E5 0.00 20) L7 Aroclor-1248 (1) 1.122 1.122 E5 0.00 21) L7 Aroclor-1248 (2) 2.681 2.681 E5 0.00 22) L7 Aroclor-1248 (3) 9.440 9.440 E4 0.00 23) L7 Aroclor-1248 (4) 6.208 6.208 E4 0.00 24) L8 Aroclor-1254 (1) 2.186 2.186 E5 0.00 25) L8 Aroclor-1254 (2) 2.411 2.411 E5 0.00 26) L8 Aroclor-1254 (3) 1.817 1.817 E5 0.00 27) L8 Aroclor-1254 (4) 3.014 3.014 E5 0.00 28) L9 Aroclor-1260 (1) 3.911 3.606 3.463 3.392 3.313 3.537 E5 6.65 29) L9 Aroclor-1260 (2) 4.240 3.905 3.962 3.781 3.750 3.928 E5 4.97 30) L9 Aroclor-1260 (3) 4.068 3.753 3.868 3.715 3.679 3.817 E5 4.13 31) L9 Aroclor-1260 (4) 3.071 3.113 3.194 2.989 2.871 3.048 E5 4.06 32) L9 Aroclor-1260 (5) 6.493 6.388 6.490 6.557 6.440 6.474 E5 0.98 33) L1 Aroclor-1262 (1) 4.789 4.789 E5 0.00 34) L1 Aroclor-1262 (2) 4.699 4.699 E5 0.00 35) L1 Aroclor-1262 (3) 1.015 1.015 E6 0.00 36) L2 Aroclor-1268 (1) 9.635 9.635 E5 0.00 37) L2 Aroclor-1268 (2) 3.843 3.843 E5 0.00 38) L2 Aroclor-1268 (3) 2.147 2.147 E6 0.00

80820711.M Tue Jul 29 16:20:44 2014 SS Page 2(#) = Out of Range


66.7.

Compound List Report HP G1530A

Method : G:\HPCHEM\GCECD5\METHODS\80820711.M (Chemstation Integrator) Title : PCBs by EPA Method 8082 Last Update : Mon Jul 28 17:30:33 2014 Response via : Initial Calibration Total Cpnds : 77

PK# Type Compound Name Exp_RT Rel_RT Cal A/H ID -------------------------------------------------------------------------- 1 S TCMX 4.57 1.000 A A B 2 S Decachlorobiphenyl 16.71 1.000 A A B 3 L3 Aroclor-1016 (1) 5.18 1.000 A A B 4 L3 Aroclor-1016 (2) 5.85 1.000 A A B 5 L3 Aroclor-1016 (3) 6.25 1.000 A A B 6 L3 Aroclor-1016 (4) 6.77 1.000 A A B 7 L3 Aroclor-1016 (5) 7.04 1.000 A A B 8 L4 Aroclor-1221 (1) 3.76 1.000 A A B 9 L4 Aroclor-1221 (2) 4.37 1.000 A A B 10 L4 Aroclor-1221 (3) 4.89 1.000 A A B 11 L5 Aroclor-1232 (1) 4.36 1.000 A A B 12 L5 Aroclor-1232 (2) 4.88 1.000 A A B 13 L5 Aroclor-1232 (3) 5.23 1.000 A A B 14 L5 Aroclor-1232 (4) 5.89 1.000 A A B 15 L6 Aroclor-1242 (1) 5.23 1.000 A A B 16 L6 Aroclor-1242 (2) 5.89 1.000 A A B 17 L6 Aroclor-1242 (3) 6.82 1.000 A A B 18 L6 Aroclor-1242 (4) 7.09 1.000 A A B 19 L6 Aroclor-1242 (5) 7.23 1.000 A A B 20 L7 Aroclor-1248 (1) 5.82 1.000 A A B 21 L7 Aroclor-1248 (2) 6.74 1.000 A A B 22 L7 Aroclor-1248 (3) 7.40 1.000 A A B 23 L7 Aroclor-1248 (4) 7.87 1.000 A A B 24 L8 Aroclor-1254 (1) 10.12 1.000 A A B 25 L8 Aroclor-1254 (2) 10.75 1.000 A A B 26 L8 Aroclor-1254 (3) 11.16 1.000 A A B 27 L8 Aroclor-1254 (4) 11.80 1.000 A A B 28 L9 Aroclor-1260 (1) 10.56 1.000 A A B 29 L9 Aroclor-1260 (2) 11.19 1.000 A A B 30 L9 Aroclor-1260 (3) 11.82 1.000 A A B 31 L9 Aroclor-1260 (4) 13.36 1.000 A A B 32 L9 Aroclor-1260 (5) 14.01 1.000 A A B 33 L1 Aroclor-1262 (1) 13.43 1.000 A A B 34 L1 Aroclor-1262 (2) 14.92 1.000 A A B 35 L1 Aroclor-1262 (3) 15.55 1.000 A A B 36 L2 Aroclor-1268 (1) 14.70 1.000 A A B 37 L2 Aroclor-1268 (2) 16.29 1.000 A A B 38 L2 Aroclor-1268 (3) 16.81 1.000 A A B 39 Signal #2 34.78 1.000 A A B 40 S TCMX #2 5.29 1.000 A A B 41 S Decachlorobiphenyl #2 20.29 1.000 A A B 42 L3 Aroclor-1016 (1) #2 6.29 1.000 A A B 43 L3 Aroclor-1016 (2) #2 7.16 1.000 A A B 44 L3 Aroclor-1016 (3) #2 7.70 1.000 A A B 45 L3 Aroclor-1016 (4) #2 8.18 1.000 A A B 46 L3 Aroclor-1016 (5) #2 8.48 1.000 A A B 47 L4 Aroclor-1221 (1) #2 5.15 1.000 A A B 48 L4 Aroclor-1221 (2) #2 5.94 1.000 A A B 49 L4 Aroclor-1221 (3) #2 6.37 1.000 A A B 50 L5 Aroclor-1232 (1) #2 4.46 1.000 A A B 51 L5 Aroclor-1232 (2) #2 5.93 1.000 A A B 52 L5 Aroclor-1232 (3) #2 6.37 1.000 A A B 53 L5 Aroclor-1232 (4) #2 7.24 1.000 A A B 54 L6 Aroclor-1242 (1) #2 6.37 1.000 A A B 55 L6 Aroclor-1242 (2) #2 7.24 1.000 A A B 56 L6 Aroclor-1242 (3) #2 8.27 1.000 A A B 57 L6 Aroclor-1242 (4) #2 8.57 1.000 A A B 58 L6 Aroclor-1242 (5) #2 8.81 1.000 A A B 59 L7 Aroclor-1248 (1) #2 7.16 1.000 A A B 60 L7 Aroclor-1248 (2) #2 8.17 1.000 A A B 61 L7 Aroclor-1248 (3) #2 8.47 1.000 A A B 62 L7 Aroclor-1248 (4) #2 8.72 1.000 A A B 63 L8 Aroclor-1254 (1) #2 10.50 1.000 A A B 64 L8 Aroclor-1254 (2) #2 10.93 1.000 A A B 65 L8 Aroclor-1254 (3) #2 11.74 1.000 A A B 66 L8 Aroclor-1254 (4) #2 12.01 1.000 A A B

80820711.M Tue Jul 29 16:20:43 2014 Page 1


66.7.

67 L9 Aroclor-1260 (1) #2 12.46 1.000 A A B 68 L9 Aroclor-1260 (2) #2 12.94 1.000 A A B 69 L9 Aroclor-1260 (3) #2 13.31 1.000 A A B 70 L9 Aroclor-1260 (4) #2 14.69 1.000 A A B 71 L9 Aroclor-1260 (5) #2 15.27 1.000 A A B 72 L1 Aroclor-1262 (1) #2 14.10 1.000 A A B 73 L1 Aroclor-1262 (2) #2 14.80 1.000 A A B 74 L1 Aroclor-1262 (3) #2 15.38 1.000 A A B 75 L2 Aroclor-1268 (1) #2 17.22 1.000 A A B 76 L2 Aroclor-1268 (2) #2 18.13 1.000 A A B 77 L2 Aroclor-1268 (3) #2 19.36 1.000 A A B

Cal A = Average L = Linear LO = Linear w/origin Q = Quad QO = Quad w/origin A/H = Area or Height ID R = R.T. B = R.T. & Q Q = Qvalue L = Largest A = All -------------------------------------------------------------------------- 80820711.M Tue Jul 29 16:20:43 2014 SS

80820711.M Tue Jul 29 16:20:43 2014 Page 2


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Signal #1 : G:\HPCHEM\GCECD5\DATA\20140822\5B01216.D\ECD1A.CH Vial: 96 Signal #2 : G:\HPCHEM\GCECD5\DATA\20140822\5B01216.D\ECD2B.CH Acq On : 22 Aug 2014 19:17 Operator: gch Sample : SEQ-CCV Inst : GCECD-5 Misc : Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Aug 25 13:53 2014 Quant Results File: 80820711.RES




System Monitoring Compounds 1) S TCMX 4.54 5.27 336.4E6 346.8E6 41.863m 40.329m Spiked Amount 50.000 Range 36 - 149 Recovery = 83.73% 80.66% 2) S Decachlorobiphen 16.66 20.19f 187.4E6 255.3E6 21.989 30.506m# Spiked Amount 50.000 Range 39 - 137 Recovery = 43.98% 61.01%

Target Compounds 3) L3 Aroclor-1016 (1) 5.16 6.27 66379092 59941482 517.363 434.170 4) L3 Aroclor-1016 (2) 5.82 7.14 117.0E6 118.9E6 443.459 411.218 5) L3 Aroclor-1016 (3) 6.21 7.68 73395695 87205995 448.553 424.061m 6) L3 Aroclor-1016 (4) 6.73 8.15 229.5E6 262.6E6 463.217 461.372 7) L3 Aroclor-1016 (5) 7.01 8.45 96545332 118.9E6 471.633 512.637 Sum Aroclor-1016 (1) 582.9E6 647.6E6 2344.226 2243.457Average Aroclor-1016 (1) 468.845 448.691






28) L9 Aroclor-1260 (1) 10.51 12.42 142.2E6 166.4E6 472.068 470.348 29) L9 Aroclor-1260 (2) 11.14 12.90 216.2E6 188.5E6 446.633 479.988 30) L9 Aroclor-1260 (3) 11.78 13.28 243.6E6 177.1E6 451.657 464.034 31) L9 Aroclor-1260 (4) 13.31 14.65 246.9E6 130.4E6 402.436m 427.943 32) L9 Aroclor-1260 (5) 13.96 15.23 134.5E6 261.1E6 394.944m 403.355m Sum Aroclor-1260 (1) 983.5E6 923.5E6 2167.739 2245.669Average Aroclor-1260 (1) 433.548 449.134



-----------------------------------------------------------------------------(f)=RT Delta > 1/2 Window (#)=Amounts differ by > 25% (m)=manual int.5B01216.D 80820711.M Tue Aug 26 11:04:45 2014 SS Page 1


66.8.





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5B01216.D 80820711.M Tue Aug 26 11:04:45 2014 SS Page 2


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System Monitoring Compounds 1) S TCMX 4.54 5.28 323.5E6 351.7E6 40.259 40.897 Spiked Amount 50.000 Range 36 - 149 Recovery = 80.52% 81.79% 2) S Decachlorobiphen 16.66 20.20f 194.1E6 274.0E6 22.769 32.732m# Spiked Amount 50.000 Range 39 - 137 Recovery = 45.54% 65.46%

Target Compounds 3) L3 Aroclor-1016 (1) 5.16 6.27 63871035 63709001 497.815 461.459 4) L3 Aroclor-1016 (2) 5.82 7.14 125.2E6 125.6E6 474.561 434.282 5) L3 Aroclor-1016 (3) 6.21 7.68 78275242 92359810 478.374 449.123m 6) L3 Aroclor-1016 (4) 6.73 8.15 246.6E6 278.2E6 497.598 488.711 7) L3 Aroclor-1016 (5) 7.01 8.46 103.4E6 125.2E6 505.315 539.530 Sum Aroclor-1016 (1) 617.4E6 685.0E6 2453.663 2373.106Average Aroclor-1016 (1) 490.733 474.621






28) L9 Aroclor-1260 (1) 10.51 12.43 150.2E6 173.2E6 498.613 489.807 29) L9 Aroclor-1260 (2) 11.14 12.91 227.0E6 198.7E6 469.024 505.830 30) L9 Aroclor-1260 (3) 11.78 13.28 255.3E6 183.8E6 473.208 481.622 31) L9 Aroclor-1260 (4) 13.31 14.65 250.2E6 134.2E6 407.872 440.180 32) L9 Aroclor-1260 (5) 13.96 15.23 140.6E6 269.5E6 412.851m 416.361 Sum Aroclor-1260 (1) 1023.4E6 959.4E6 2261.567 2333.801Average Aroclor-1260 (1) 452.313 466.760



-----------------------------------------------------------------------------(f)=RT Delta > 1/2 Window (#)=Amounts differ by > 25% (m)=manual int.5B01238.D 80820711.M Tue Aug 26 11:04:52 2014 SS Page 1


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5B01238.D 80820711.M Tue Aug 26 11:04:52 2014 SS Page 2


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System Monitoring Compounds 1) S TCMX 4.54 5.28 348.1E6 360.9E6 43.322 41.969 Spiked Amount 50.000 Range 36 - 149 Recovery = 86.64% 83.94% 2) S Decachlorobiphen 16.66 20.20f 194.1E6 265.3E6 22.765 31.694m# Spiked Amount 50.000 Range 39 - 137 Recovery = 45.53% 63.39%

Target Compounds 3) L3 Aroclor-1016 (1) 5.16 6.27 65691793 65626524 512.006 475.348 4) L3 Aroclor-1016 (2) 5.82 7.14 130.4E6 128.8E6 493.989 445.383 5) L3 Aroclor-1016 (3) 6.21 7.68 80887663 97710455 494.340 475.142m 6) L3 Aroclor-1016 (4) 6.73 8.15 272.1E6 286.2E6 549.060 502.819 7) L3 Aroclor-1016 (5) 7.01 8.46 106.7E6 127.6E6 521.210 549.880 Sum Aroclor-1016 (1) 655.7E6 705.9E6 2570.605 2448.572Average Aroclor-1016 (1) 514.121 489.714






28) L9 Aroclor-1260 (1) 10.52 12.43 151.0E6 168.4E6 501.145 476.098 29) L9 Aroclor-1260 (2) 11.14 12.91 228.2E6 193.6E6 471.355 492.855 30) L9 Aroclor-1260 (3) 11.78 13.28 254.1E6 177.1E6 471.035 464.060 31) L9 Aroclor-1260 (4) 13.31 14.65 247.7E6 136.6E6 403.737 448.056 32) L9 Aroclor-1260 (5) 13.96 15.23 141.2E6 263.8E6 414.639m 407.574 Sum Aroclor-1260 (1) 1022.2E6 939.5E6 2261.911 2288.642Average Aroclor-1260 (1) 452.382 457.728



-----------------------------------------------------------------------------(f)=RT Delta > 1/2 Window (#)=Amounts differ by > 25% (m)=manual int.5B01248.D 80820711.M Fri Aug 29 15:25:47 2014 SS Page 1


66.8.





4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00

0

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

Time


4.5

4

5.1

5

5.8

2

6.2

1

6.7

3 7

.00

10.

51

11.

14

11.

77

13.

31

13.

96

16.

65D

ecac

hlor

o

Aroc

lor-

12

Aroc

lor-

12

Aroc

lor-

12

Aroc

lor-

12

Aroc

lor-

12

Aroc

lor-

10Ar

oclo

r-10

Aroc

lor-

10

Aroc

lor-

10

Aroc

lor-

10

TCM

X

4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


5.2

7

6.2

7 7.1

4

7.6

8

8.1

5 8

.45

12.

42

12.

90 1

3.28

14.

65

15.

23

20.

20D

ecac

hlor

o

Aroc

lor-

12

Aroc

lor-

12

Aroc

lor-

12Ar

oclo

r-12

Aroc

lor-

12

Aroc

lor-

10Ar

oclo

r-10

Aroc

lor-

10

Aroc

lor-

10

Aroc

lor-

10

TCM

X #2

5B01248.D 80820711.M Fri Aug 29 15:25:47 2014 SS Page 2


66.8.

GC


Work Order: 4080683




77.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

E04717.D

08/25/14 22:31

S4H2709

B4H2502

08/25/14 08:28

Microwave Extraction

Project:




Soil


Extractable Petroleum Hydrocarbons Category 2 - NJDEP-EPH-CAT2


NJDEP-EPH2 UTotal EPH ND 10.0 20.0


77.1.


Data File : G:\HPCHEM\GCFID3\DATA\20140825\E04717.D Vial: 19 Acq On : 25 Aug 2014 10:31 pm Operator: bw Sample : B4H2502-BLK1 Inst : GCFID-3 Misc : Multiplr: 1.00 IntFile : EVENTS.E Quant Time: Aug 27 13:56 2014 Quant Results File: ALIP626.RES

Quant Method : G:\HPCHEM\G...\ALIP626.M (Chemstation Integrator) Title : Extractable Petroleum Hydrocarbons Aliphatics Last Update : Wed Jul 30 16:31:12 2014 Response via : Initial Calibration DataAcq Meth : EPHALIP.M

Volume Inj. : 2ul Signal Phase : RTx-50 Signal Info : 30M x 0.53mm x 0.50um

Compound R.T. Response Conc Units-------------------------------------------------------------------------

Target Compounds 9) o-Terphenyl 12.98 730188 51.013 mg/L 11) Chlorooctadecane 13.83 605203 53.303 mg/L

-----------------------------------------------------------------------------(f)=RT Delta > 1/2 Window (m)=manual int.E04717.D ALIP626.M Wed Aug 27 14:02:32 2014 SS Page 1


77.1.


Data File : G:\HPCHEM\GCFID3\DATA\20140825\E04717.D Vial: 19 Acq On : 25 Aug 2014 10:31 pm Operator: bw Sample : B4H2502-BLK1 Inst : GCFID-3 Misc : Multiplr: 1.00 IntFile : EVENTS.E Quant Time: Aug 27 13:56 2014 Quant Results File: ALIP626.RES

Quant Method : G:\HPCHEM\G...\ALIP626.M (Chemstation Integrator) Title : Extractable Petroleum Hydrocarbons Aliphatics Last Update : Wed Jul 30 16:31:12 2014 Response via : Multiple Level Calibration DataAcq Meth : EPHALIP.M


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00

0

5000

10000

15000

20000

25000

30000

35000

40000

45000

50000

55000

60000

65000

Time

Response_ E04717.D\FID2B

12.9

7

13.8

3C

hlo

roocta

o-T

erp

heny

E04717.D ALIP626.M Wed Aug 27 14:02:32 2014 SS Page 2


77.1.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

E04715.D

08/25/14 21:25

S4H2709

B4H2502

08/25/14 08:28

Microwave Extraction

Project:

4080683




1Dilution:


Soil

08/21/14 09:35


Sparta Quarry

Extractable Petroleum Hydrocarbons Category 2 - NJDEP-EPH-CAT2


NJDEP-EPH2 UTotal EPH ND 10.6 21.1










77.2.


Data File : G:\HPCHEM\GCFID3\DATA\20140825\E04715.D Vial: 17 Acq On : 25 Aug 2014 9:25 pm Operator: bw Sample : 4080683-01 Inst : GCFID-3 Misc : Multiplr: 1.00 IntFile : EVENTS.E Quant Time: Aug 27 13:55 2014 Quant Results File: ALIP626.RES




Target Compounds 9) o-Terphenyl 12.97 605365 42.293 mg/L 11) Chlorooctadecane 13.83 507586 44.706 mg/L



77.2.


Data File : G:\HPCHEM\GCFID3\DATA\20140825\E04715.D Vial: 17 Acq On : 25 Aug 2014 9:25 pm Operator: bw Sample : 4080683-01 Inst : GCFID-3 Misc : Multiplr: 1.00 IntFile : EVENTS.E Quant Time: Aug 27 13:55 2014 Quant Results File: ALIP626.RES



4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00

0

5000

10000

15000

20000

25000

30000

35000

40000

45000

50000

55000

Time


12.9

7

13.8

3C

hlo

roocta

o-T

erp

heny



77.2.

SURROGATE RECOVERIESAnalysis Class: GC

Method:

File ID

Matrix: Soil

Lab Number 1-COD O-TPL

NJDEP-EPH-CAT2

4080683-01 E04715.D 89.4 84.6



1-COD

O-TPL

1-Chlorooctadecane

o-Terphenyl

40 140

40 140


77.3.

Extractable Petroleum Hydrocarbons Category 2 - Quality Control


Batch B4H2502 Prepared: 08/25/2014Method: NJDEP-EPH-CAT2

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source360 40-14068.3mg/kg wetTotal EPHB4H2502-BS1 246

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source360 2540-14078.1 13.5mg/kg wetTotal EPHB4H2502-BSD1 281

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source438 40-14076.7mg/kg dryTotal EPHB4H2502-MS1 4080567-01 59.3395




77.4.


B4H2502Batch ID:


B4H2502-BLK1 BLK1 8/25/2014

B4H2502-BS1 BS1 8/25/2014

B4H2502-BSD1 BSD1 8/25/2014

B4H2502-MS1 MS1 8/25/2014

4080683-01 QUARRY FINES 8/25/2014


77.5.

Compound List Report GCFID-3

Method : G:\HPCHEM\GCFID3\METHODS\ALIP626.M (Chemstation Integrator) Title : Extractable Petroleum Hydrocarbons Aliphatics Last Update : Fri Aug 09 14:46:15 2013 Response via : Initial Calibration Total Cpnds : 25

PK# Type Compound Name Exp_RT Rel_RT Cal A/H ID -------------------------------------------------------------------------- 1 n-Nonane 3.04 1.000 A A B 2 n-Decane 4.46 1.000 A A B 3 n-Dodecane 7.25 1.000 A A B 4 C9-C12 Aliphatics 6.20 1.000 A A B 5 n-Tetradecane 9.08 1.000 A A B 6 n-Hexadecane 10.51 1.000 A A B 7 C12-C16 Aliphatics 9.90 1.000 A A B 8 n-Octadecane 11.74 1.000 A A B 9 o-Terphenyl 12.40 1.000 A A B 10 n-Eicosane 12.84 1.000 A A B 11 Chlorooctadecane 13.30 1.000 A A B 12 n-Heneicosane 13.36 1.000 A A B 13 C16-C21 Aliphatics 13.35 1.000 A A B 14 n-Docosane 13.84 1.000 A A B 15 n-Tetracosane 14.77 1.000 A A B 16 n-Hexacosane 15.62 1.000 A A B 17 n-Octacosane 16.41 1.000 A A B 18 n-Triacontane 17.16 1.000 A A B 19 n-Dotriacontane 17.95 1.000 A A B 20 n-Tetratricontane 18.86 1.000 A A B 21 n-Hexatriacontane 20.00 1.000 A A B 22 n-Octatriacontane 21.51 1.000 A A B 23 n-Tetracontane 23.55 1.000 A A B 24 C21-C40 Aliphatics 19.75 1.000 A A B 25 Total EPH 16.00 1.000 A A B

Cal A = Average L = Linear LO = Linear w/origin Q = Quad QO = Quad w/origin A/H = Area or Height ID R = R.T. B = R.T. & Q Q = Qvalue L = Largest A = All -------------------------------------------------------------------------- ALIP626.M Mon Aug 12 14:25:18 2013 SS

ALIP626.M Mon Aug 12 14:25:18 2013 Page 1


77.6.

Response Factor Report GCFID-3

Method : G:\HPCHEM\GCFID3\METHODS\ALIP626.M (Chemstation Integrator) Title : Extractable Petroleum Hydrocarbons Aliphatics Last Update : Fri Aug 09 14:46:15 2013

Calibration Files 25 =E0006.D 50 =E0007.D 100 =E0008.D 200 =E0009.D 300 =E0001.D

Compound 25 50 100 200 300 Avg %RSD---------------------------------------------------------------------------

1) n-Nonane 1.429 1.321 1.408 1.284 1.270 1.342 E4 5.39 2) n-Decane 1.343 1.221 1.314 1.174 1.172 1.245 E4 6.40 3) n-Dodecane 1.257 1.179 1.292 1.163 1.162 1.211 E4 4.96 4) C9-C12 Aliphatics 0.933 1.295 1.350 1.249 1.320 1.230 E4 13.81 5) n-Tetradecane 1.204 1.174 1.293 1.167 1.165 1.200 E4 4.53 6) n-Hexadecane 1.281 1.215 1.331 1.191 1.183 1.240 E4 5.15 7) C12-C16 Aliphatics 1.582 1.372 1.396 1.300 1.221 1.374 E4 9.80 8) n-Octadecane 1.365 1.282 1.378 1.231 1.219 1.295 E4 5.69 9) o-Terphenyl 1.547 1.376 1.362 1.440 1.431 E4 5.89 10) n-Eicosane 1.428 1.331 1.415 1.262 1.249 1.337 E4 6.24 11) Chlorooctadecane 1.240 1.081 1.074 1.146 1.135 E4 6.75 12) n-Heneicosane 1.599 1.501 1.568 1.429 1.393 1.498 E4 5.87 13) C16-C21 Aliphatics 1.601 1.380 1.466 1.343 1.384 1.435 E4 7.19 14) n-Docosane 1.439 1.344 1.417 1.269 1.255 1.345 E4 6.21 15) n-Tetracosane 1.455 1.352 1.419 1.277 1.265 1.354 E4 6.21 16) n-Hexacosane 1.479 1.370 1.429 1.292 1.282 1.370 E4 6.22 17) n-Octacosane 1.483 1.367 1.421 1.289 1.284 1.369 E4 6.26 18) n-Triacontane 1.489 1.365 1.420 1.289 1.292 1.371 E4 6.24 19) n-Dotriacontane 1.499 1.366 1.427 1.295 1.304 1.378 E4 6.23 20) n-Tetratricontane 1.536 1.397 1.473 1.345 1.376 1.426 E4 5.45 21) n-Hexatriacontane 1.535 1.398 1.502 1.420 1.528 1.477 E4 4.31 22) n-Octatriacontane 1.636 1.494 1.657 1.677 1.865 1.666 E4 7.98 23) n-Tetracontane 1.793 1.636 1.862 1.906 2.070 1.854 E4 8.55 24) C21-C40 Aliphatics 2.114 1.803 1.905 1.607 1.652 1.816 E4 11.26 25) Total EPH 1.988 1.873 1.790 1.512 1.524 1.737 E4 12.21

ALIP626.M Mon Aug 12 14:25:19 2013 SS Page 1(#) = Out of Range


77.6.

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77.7.


Data File : G:\HPCHEM\GCFID3\DATA\20140825\E04699.D Vial: 1 Acq On : 25 Aug 2014 11:56 am Operator: bw Sample : SEQ-CCV Inst : GCFID-3 Misc : Multiplr: 1.00 IntFile : EVENTS.E Quant Time: Aug 27 13:51 2014 Quant Results File: ALIP626.RES




Target Compounds 1) n-Nonane 3.57 1598349 119.068 mg/L m 2) n-Decane 5.09 1480597 118.954 mg/L m 3) n-Dodecane 7.75 1457634 120.394 mg/L 5) n-Tetradecane 9.58 1445553 120.420 mg/L 6) n-Hexadecane 11.01 1454711 117.295 mg/L 7) C12-C16 Aliphatics 9.58 1445553 105.209 mg/L 8) n-Octadecane 12.25 1487088 114.851 mg/L 10) n-Eicosane 13.36 1509321 112.879 mg/L 12) n-Heneicosane 13.87 1705546 113.851 mg/L 14) n-Docosane 14.36 1499588 111.501 mg/L 15) n-Tetracosane 15.29 1499112 110.742 mg/L 16) n-Hexacosane 16.14 1509802 110.167 mg/L 17) n-Octacosane 16.93 1511733 110.430 mg/L 18) n-Triacontane 17.72 1507753 109.961 mg/L 19) n-Dotriacontane 18.58 1508795 109.482 mg/L 20) n-Tetratricontane 19.60 1538396 107.900 mg/L 21) n-Hexatriacontane 20.87 1486319 100.651 mg/L 22) n-Octatriacontane 22.55 1457456 87.496 mg/L 23) n-Tetracontane 24.82 1364951 73.637 mg/L 25) Total EPH 13.87 31415956 1808.300 mg/L m



77.7.


Data File : G:\HPCHEM\GCFID3\DATA\20140825\E04699.D Vial: 1 Acq On : 25 Aug 2014 11:56 am Operator: bw Sample : SEQ-CCV Inst : GCFID-3 Misc : Multiplr: 1.00 IntFile : EVENTS.E Quant Time: Aug 27 13:51 2014 Quant Results File: ALIP626.RES



4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00

0

10000

20000

30000

40000

50000

60000

70000

80000

90000

100000

110000

120000

130000

140000

150000

Time


3.57

5.0

9

7.7

5

9.5

7 11.

01

12.

25

13.

87

14.

36

15.

29

16.

14

16.

93

17.

72

18.

58

19.

60

20.

87

22.

55

24.

82n-

Tetra

con

n-O

ctat

ria

n-H

exat

ria

n-Te

tratri

n-D

otria

co

n-Tr

iaco

nt

n-O

ctac

osa

n-H

exac

osa

n-Te

traco

s

n-D

ocos

ane

n-H

enei

cos

Tota

l EPH

n-Ei

cosa

ne

n-O

ctad

eca

n-H

exad

eca

n-Te

trade

cC

12-C

16 A

l

n-D

odec

ane

n-D

ecan

e

n-N

onan

e



77.7.

MERCURY


Work Order: 4080683




88.

ANALYSIS DATA SHEET

Work Order: 4080683

Project:

Client:

Mercury


Sparta Quarry

Total Metals Soil (mg/kg wet)

Lab Number MethodQAnalyte Concentration RL Analyst AnalyzedDFExtract

0.0208 09/03/14 10:25NDMercury ASB4I0320-BLK1 0.6 / 25 SW 846 7471AU1


88.1.

ANALYSIS DATA SHEET

Work Order: 4080683

Project:

Client:

Mercury


Sparta Quarry

Soil (mg/kg dry)

Lab Number MethodQAnalyte Concentration RL Analyst AnalyzedDFExtract

Total Metals

10.0220 09/03/14 11:57NDMercury AS4080683-01 0.6 / 25 SW 846 7471AU


88.2.

Total Metals - Quality Control


Batch B4I0320 Prepared: 09/03/2014Method: SW 846 7471A

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source0.417 80-12097.5mg/kg wetMercuryB4I0320-BS1 0.406

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source35mg/kg dryMercuryB4I0320-DUP1 4080581-01 0.0148ND

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source0.477 75-12592.6mg/kg dryMercuryB4I0320-MS1 4080581-01 0.01480.456

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source0.477 3575-125108 15.3mg/kg dryMercuryB4I0320-MSD1 4080581-01 0.01480.531




88.3.


B4I0320Batch ID:


B4I0320-BLK1 BLK1 9/3/2014

B4I0320-BS1 BS1 9/3/2014

B4I0320-DUP1 DUP1 9/3/2014

B4I0320-MS1 MS1 9/3/2014

B4I0320-MSD1 MSD1 9/3/2014

4080683-01 QUARRY FINES 9/3/2014


88.4.

ANALYSIS SEQUENCE SUMMARY

Work Order:

Project:

Instrument:Sequence:

Client:

Laboratory: Aqua Pro-Tech Laboratories


S4I0307 Mercury Analyzer

Sparta Quarry

4080683

Sample Name Lab Sample ID Analysis Date/TimeFileID

S4I0307-ICV1Initial Cal Check 09/03/14 10:14mercimp-013

S4I0307-ICB1Initial Cal Blank 09/03/14 10:18mercimp-014

B4I0320-BS1LCS 09/03/14 10:21mercimp-015

B4I0320-BLK1Blank 09/03/14 10:25mercimp-016

B4I0320-DUP1Duplicate 09/03/14 10:34mercimp-018

B4I0320-MS1Matrix Spike 09/03/14 10:40mercimp-019

B4I0320-MSD1Matrix Spike Dup 09/03/14 10:43mercimp-020

S4I0307-CCV1Calibration Check 09/03/14 11:00mercimp-025

S4I0307-CCB1Calibration Blank 09/03/14 11:04mercimp-026



4080683-01QUARRY FINES 09/03/14 11:57mercimp-042




88.5.

SW 846 7471A

INITIAL AND CONTINUING CALIBRATION CHECK

Mercury Analyzer

Sequence: S4I0307


4080683

Client:

Work Order:

Project:

Instrument

Sparta Quarry

Analyte True Found %R UnitsLab Sample ID Control Limit

99.410.0 9.94 ug/LS4I0307-ICV1 Mercury +/-20.00%

10410.0 10.4 ug/LS4I0307-CCV1 Mercury +/-20.00%




88.6.

METALS


Work Order: 4080683




99.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Prep Date:

Prep Method:

08/26/14 17:14

Hot Block ICP Soil

Project:

4080683

Client Sample ID: Blank



Soil

CAS NO. RLDilution Analyzed Method Sequence/Batch


Sparta Quarry

Analyte UnitsConc.

Total Metals

7429-90-5 ND 2.5008/29/14 13:21 SW 846 6010BAluminum S4H2909/B4H26411 mg/kg wet

7440-36-0 ND 0.50008/29/14 13:21 SW 846 6010BAntimony S4H2909/B4H26411 mg/kg wet

7440-38-2 ND 0.50008/29/14 13:21 SW 846 6010BArsenic S4H2909/B4H26411 mg/kg wet

7440-39-3 ND 0.50008/29/14 13:21 SW 846 6010BBarium S4H2909/B4H26411 mg/kg wet

7440-41-7 ND 0.025008/29/14 13:21 SW 846 6010BBeryllium S4H2909/B4H26411 mg/kg wet

7440-43-9 ND 0.050008/29/14 13:21 SW 846 6010BCadmium S4H2909/B4H26411 mg/kg wet

7440-70-2 ND 25.008/29/14 13:20 SW 846 6010BCalcium S4H2909/B4H26411 mg/kg wet

7440-47-3 ND 0.25008/29/14 13:21 SW 846 6010BChromium S4H2909/B4H26411 mg/kg wet

7440-48-4 ND 0.20008/29/14 13:21 SW 846 6010BCobalt S4H2909/B4H26411 mg/kg wet

7440-50-8 ND 0.25008/29/14 13:21 SW 846 6010BCopper S4H2909/B4H26411 mg/kg wet

7439-89-6 ND 5.0008/29/14 13:21 SW 846 6010BIron S4H2909/B4H26411 mg/kg wet

7439-92-1 ND 0.50008/29/14 13:21 SW 846 6010BLead S4H2909/B4H26411 mg/kg wet

7439-95-4 ND 50.008/29/14 13:20 SW 846 6010BMagnesium S4H2909/B4H26411 mg/kg wet

7439-96-5 ND 0.25008/29/14 13:21 SW 846 6010BManganese S4H2909/B4H26411 mg/kg wet

7440-02-0 ND 0.12508/29/14 13:21 SW 846 6010BNickel S4H2909/B4H26411 mg/kg wet

7440-09-7 ND 10008/29/14 13:20 SW 846 6010BPotassium S4H2909/B4H26411 mg/kg wet

7782-49-2 ND 0.62508/29/14 13:21 SW 846 6010BSelenium S4H2909/B4H26411 mg/kg wet

7440-22-4 ND 0.50008/29/14 13:21 SW 846 6010BSilver S4H2909/B4H26411 mg/kg wet

7440-23-5 ND 50.008/29/14 13:20 SW 846 6010BSodium S4H2909/B4H26411 mg/kg wet

7440-28-0 ND 0.50008/29/14 13:21 SW 846 6010BThallium S4H2909/B4H26411 mg/kg wet

7440-62-2 ND 0.50008/29/14 13:21 SW 846 6010BVanadium S4H2909/B4H26411 mg/kg wet

7440-66-6 ND 0.75008/29/14 13:21 SW 846 6010BZinc S4H2909/B4H26411 mg/kg wet







99.1.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled: Prep Date:

Prep Method:

08/26/14 17:14

Hot Block ICP Soil

Project:

4080683





Soil

08/21/14 09:35


Sparta Quarry

CAS NO. RLAnalyte Dilution Analyzed Method Sequence/BatchConc. Units

Total Metals

7429-90-5 6470 2.641 08/29/14 16:36 SW 846 6010BAluminum S4H2912/B4H2641mg/kg dry7440-36-0 ND 0.5281 08/29/14 16:36 SW 846 6010BAntimony S4H2912/B4H2641mg/kg dry7440-38-2 ND 0.5281 08/29/14 16:36 SW 846 6010BArsenic S4H2912/B4H2641mg/kg dry7440-39-3 27.0 0.5281 08/29/14 16:36 SW 846 6010BBarium S4H2912/B4H2641mg/kg dry7440-41-7 0.166 0.02641 08/29/14 16:36 SW 846 6010BBeryllium S4H2912/B4H2641mg/kg dry7440-43-9 ND 0.05281 08/29/14 16:36 SW 846 6010BCadmium S4H2912/B4H2641mg/kg dry7440-70-2 5810 26.41 08/29/14 16:35 SW 846 6010BCalcium S4H2912/B4H2641mg/kg dry7440-47-3 19.7 0.2641 08/29/14 16:36 SW 846 6010BChromium S4H2912/B4H2641mg/kg dry7440-48-4 4.22 0.2111 08/29/14 16:36 SW 846 6010BCobalt S4H2912/B4H2641mg/kg dry7440-50-8 8.33 0.2641 08/29/14 16:36 SW 846 6010BCopper S4H2912/B4H2641mg/kg dry7439-89-6 12000 5.281 08/29/14 16:35 SW 846 6010BIron S4H2912/B4H2641mg/kg dry7439-92-1 1.62 0.5281 08/29/14 16:36 SW 846 6010BLead S4H2912/B4H2641mg/kg dry7439-95-4 4320 52.81 08/29/14 16:35 SW 846 6010BMagnesium S4H2912/B4H2641mg/kg dry7439-96-5 174 0.2641 08/29/14 16:36 SW 846 6010BManganese S4H2912/B4H2641mg/kg dry7440-02-0 9.70 0.1321 08/29/14 16:36 SW 846 6010BNickel S4H2912/B4H2641mg/kg dry7440-09-7 2230 1061 08/29/14 16:35 SW 846 6010BPotassium S4H2912/B4H2641mg/kg dry7782-49-2 ND 0.6601 08/29/14 16:36 SW 846 6010BSelenium S4H2912/B4H2641mg/kg dry7440-22-4 ND 0.5281 08/29/14 16:36 SW 846 6010BSilver S4H2912/B4H2641mg/kg dry7440-23-5 203 52.81 08/29/14 16:35 SW 846 6010BSodium S4H2912/B4H2641mg/kg dry7440-28-0 1.66 0.5281 08/29/14 16:36 SW 846 6010BThallium S4H2912/B4H2641mg/kg dry7440-62-2 18.4 0.5281 08/29/14 16:36 SW 846 6010BVanadium S4H2912/B4H2641mg/kg dry7440-66-6 24.5 0.7921 08/29/14 16:36 SW 846 6010BZinc S4H2912/B4H2641mg/kg dry








99.2.



Batch B4H2641 Prepared: 08/26/2014Method: SW 846 6010B

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source5000 80-120103mg/kg wetAluminumB4H2641-BS1 5170

12.5 80-12095.6mg/kg wetAntimonyB4H2641-BS1 11.9

12.5 80-12090.3mg/kg wetArsenicB4H2641-BS1 11.3

12.5 80-12095.9mg/kg wetBariumB4H2641-BS1 12.0

12.5 80-120101mg/kg wetBerylliumB4H2641-BS1 12.6

12.5 80-120106mg/kg wetCadmiumB4H2641-BS1 13.3

3120 80-120109mg/kg wetCalciumB4H2641-BS1 3420

12.5 80-12096.1mg/kg wetChromiumB4H2641-BS1 12.0

12.5 80-12094.9mg/kg wetCobaltB4H2641-BS1 11.9

12.5 80-120102mg/kg wetCopperB4H2641-BS1 12.8

7500 80-120103mg/kg wetIronB4H2641-BS1 7690

12.5 80-12094.9mg/kg wetLeadB4H2641-BS1 11.9

3120 80-120110mg/kg wetMagnesiumB4H2641-BS1 3450

12.5 80-120101mg/kg wetManganeseB4H2641-BS1 12.6

12.5 80-12094.2mg/kg wetNickelB4H2641-BS1 11.8

3120 80-120102mg/kg wetPotassiumB4H2641-BS1 3180

12.5 80-120108mg/kg wetSeleniumB4H2641-BS1 13.5

12.5 80-120102mg/kg wetSilverB4H2641-BS1 12.8

3120 80-120104mg/kg wetSodiumB4H2641-BS1 3250

12.5 80-12092.9mg/kg wetThalliumB4H2641-BS1 11.6

12.5 80-12098.5mg/kg wetVanadiumB4H2641-BS1 12.3

12.5 80-120105mg/kg wetZincB4H2641-BS1 13.2

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source205.95mg/kg dryAluminumB4H2641-DUP1 4080801-03 1380013000

20mg/kg dryAntimonyB4H2641-DUP1 4080801-03 NDND

20mg/kg dryArsenicB4H2641-DUP1 4080801-03 NDND

205.73mg/kg dryBariumB4H2641-DUP1 4080801-03 71.267.3

200.195mg/kg dryBerylliumB4H2641-DUP1 4080801-03 0.6420.641

2023.9*mg/kg dryCadmiumB4H2641-DUP1 4080801-03 0.1250.159

2010.5mg/kg dryCalciumB4H2641-DUP1 4080801-03 1520013700

206.28mg/kg dryChromiumB4H2641-DUP1 4080801-03 16.317.4

206.94mg/kg dryCobaltB4H2641-DUP1 4080801-03 7.407.93

205.96mg/kg dryCopperB4H2641-DUP1 4080801-03 25.323.8

202.13mg/kg dryLeadB4H2641-DUP1 4080801-03 32.433.1

2010.3mg/kg dryMagnesiumB4H2641-DUP1 4080801-03 53104790

205.17mg/kg dryManganeseB4H2641-DUP1 4080801-03 413435

209.26mg/kg dryNickelB4H2641-DUP1 4080801-03 16.017.6

2013.3mg/kg dryPotassiumB4H2641-DUP1 4080801-03 23302040

20mg/kg drySeleniumB4H2641-DUP1 4080801-03 NDND

20mg/kg drySilverB4H2641-DUP1 4080801-03 0.341ND

206.99mg/kg drySodiumB4H2641-DUP1 4080801-03 22102060

2038.4*mg/kg dryThalliumB4H2641-DUP1 4080801-03 0.8800.596

2013.4mg/kg dryVanadiumB4H2641-DUP1 4080801-03 20.818.2

206.80mg/kg dryZincB4H2641-DUP1 4080801-03 61.457.4

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source2060.1*mg/kg dryIronB4H2641-DUP2 4080801-03 2010037400




99.3.



Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source5180 75-12576.7mg/kg dryAluminumB4H2641-MS1 4080801-03 1380017800

13.0 75-12516.4*mg/kg dryAntimonyB4H2641-MS1 4080801-03 ND2.12

13.0 75-12550.9*mg/kg dryArsenicB4H2641-MS1 4080801-03 ND6.60

13.0 75-125126(NC)mg/kg dryBariumB4H2641-MS1 4080801-03 71.287.5

13.0 75-12571.2*mg/kg dryBerylliumB4H2641-MS1 4080801-03 0.6429.86

13.0 75-12580.3mg/kg dryCadmiumB4H2641-MS1 4080801-03 0.12510.5

3240 75-125109mg/kg dryCalciumB4H2641-MS1 4080801-03 1520018700

13.0 75-12560.3*mg/kg dryChromiumB4H2641-MS1 4080801-03 16.324.1

13.0 75-12561.7*mg/kg dryCobaltB4H2641-MS1 4080801-03 7.4015.4

13.0 75-125149*mg/kg dryCopperB4H2641-MS1 4080801-03 25.344.6

13.0 75-12543.5*mg/kg dryLeadB4H2641-MS1 4080801-03 32.438.0

3240 75-12557.5*mg/kg dryMagnesiumB4H2641-MS1 4080801-03 53107180

13.0 75-125-394(NC)mg/kg dryManganeseB4H2641-MS1 4080801-03 413362

13.0 75-12556.0*mg/kg dryNickelB4H2641-MS1 4080801-03 16.023.3

3240 75-12580.5mg/kg dryPotassiumB4H2641-MS1 4080801-03 23304940

13.0 75-12557.0*mg/kg drySeleniumB4H2641-MS1 4080801-03 ND7.39

13.0 75-12553.6*mg/kg drySilverB4H2641-MS1 4080801-03 0.3417.29

3240 75-12578.2mg/kg drySodiumB4H2641-MS1 4080801-03 22104740

13.0 75-12561.0*mg/kg dryThalliumB4H2641-MS1 4080801-03 0.8808.79

13.0 75-12561.8*mg/kg dryVanadiumB4H2641-MS1 4080801-03 20.828.8

13.0 75-12572.4(NC)mg/kg dryZincB4H2641-MS1 4080801-03 61.470.8

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source7770 75-125236*mg/kg dryIronB4H2641-MS2 4080801-03 2010038500

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source5180 2075-12594.3 4.98mg/kg dryAluminumB4H2641-MSD1 4080801-03 1380018700

13.0 2075-12516.3* 0.0479mg/kg dryAntimonyB4H2641-MSD1 4080801-03 ND2.12

13.0 2075-12555.7* 9.00mg/kg dryArsenicB4H2641-MSD1 4080801-03 ND7.22

13.0 2075-125161(NC) 5.01mg/kg dryBariumB4H2641-MSD1 4080801-03 71.292.0

13.0 2075-12574.6* 4.45mg/kg dryBerylliumB4H2641-MSD1 4080801-03 0.64210.3

13.0 2075-12585.3 6.00mg/kg dryCadmiumB4H2641-MSD1 4080801-03 0.12511.2

3240 2075-125137(NC) 4.82mg/kg dryCalciumB4H2641-MSD1 4080801-03 1520019600

13.0 2075-12569.0* 4.60mg/kg dryChromiumB4H2641-MSD1 4080801-03 16.325.3

13.0 2075-12568.7* 5.75mg/kg dryCobaltB4H2641-MSD1 4080801-03 7.4016.3

13.0 2075-125168* 5.39mg/kg dryCopperB4H2641-MSD1 4080801-03 25.347.1

13.0 2075-12560.5* 5.63mg/kg dryLeadB4H2641-MSD1 4080801-03 32.440.2

3240 2075-12568.2* 4.69mg/kg dryMagnesiumB4H2641-MSD1 4080801-03 53107520

13.0 2075-125-262(NC) 4.61mg/kg dryManganeseB4H2641-MSD1 4080801-03 413379

13.0 2075-12566.7* 5.78mg/kg dryNickelB4H2641-MSD1 4080801-03 16.024.7

3240 2075-12591.4 6.92mg/kg dryPotassiumB4H2641-MSD1 4080801-03 23305290

13.0 2075-12554.9* 3.69mg/kg drySeleniumB4H2641-MSD1 4080801-03 ND7.12

13.0 2075-12556.0* 4.18mg/kg drySilverB4H2641-MSD1 4080801-03 0.3417.60

3240 2075-12587.3 6.04mg/kg drySodiumB4H2641-MSD1 4080801-03 22105030

13.0 2075-12562.7* 2.46mg/kg dryThalliumB4H2641-MSD1 4080801-03 0.8809.01

13.0 2075-12575.2 5.87mg/kg dryVanadiumB4H2641-MSD1 4080801-03 20.830.5

13.0 2075-12597.1 4.43mg/kg dryZincB4H2641-MSD1 4080801-03 61.474.0

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source7770 2075-125257* 4.13mg/kg dryIronB4H2641-MSD2 4080801-03 2010040100




99.3.



Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source200 75-12567.7*mg/LAluminumB4H2641-PS1 4080801-03 534669

0.500 75-12597.3mg/LAntimonyB4H2641-PS1 4080801-03 ND0.476

0.500 75-12586.7mg/LArsenicB4H2641-PS1 4080801-03 ND0.392

0.500 75-12533.9(NC)mg/LBariumB4H2641-PS1 4080801-03 2.752.92

0.500 75-12592.2mg/LBerylliumB4H2641-PS1 4080801-03 0.02480.486

0.500 75-125108mg/LCadmiumB4H2641-PS1 4080801-03 0.004840.543

125 75-12547.3(NC)mg/LCalciumB4H2641-PS1 4080801-03 586646

0.500 75-12576.8mg/LChromiumB4H2641-PS1 4080801-03 0.6301.01

0.500 75-12581.4mg/LCobaltB4H2641-PS1 4080801-03 0.2850.692

0.500 75-12589.4mg/LCopperB4H2641-PS1 4080801-03 0.9751.42

0.500 75-12563.9*mg/LLeadB4H2641-PS1 4080801-03 1.251.57

125 75-12578.8mg/LMagnesiumB4H2641-PS1 4080801-03 205304

0.500 75-125-271(NC)mg/LManganeseB4H2641-PS1 4080801-03 16.014.6

0.500 75-12572.6*mg/LNickelB4H2641-PS1 4080801-03 0.6180.981

125 75-125103mg/LPotassiumB4H2641-PS1 4080801-03 89.9219

0.500 75-12587.5mg/LSeleniumB4H2641-PS1 4080801-03 ND0.419

0.500 75-125235*mg/LSilverB4H2641-PS1 4080801-03 ND1.19

125 75-125101mg/LSodiumB4H2641-PS1 4080801-03 85.1211

0.500 75-12583.0mg/LThalliumB4H2641-PS1 4080801-03 0.03390.449

0.500 75-12567.2*mg/LVanadiumB4H2641-PS1 4080801-03 0.8021.14

0.500 75-12533.3(NC)mg/LZincB4H2641-PS1 4080801-03 2.372.54

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source300 75-125151*mg/LIronB4H2641-PS2 4080801-03 7771230

Batch S4H2909 Prepared: 08/26/2014Method: SW 846 6010B

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source1012.8*mg/kg dryAluminumS4H2909-SRD1 4080801-03 1380015700

10mg/kg dryAntimonyS4H2909-SRD1 4080801-03 NDND

10mg/kg dryArsenicS4H2909-SRD1 4080801-03 NDND

1015.0*mg/kg dryBariumS4H2909-SRD1 4080801-03 71.282.8

1010.6*mg/kg dryBerylliumS4H2909-SRD1 4080801-03 0.6420.714

10mg/kg dryCadmiumS4H2909-SRD1 4080801-03 0.125ND

1019.0*mg/kg dryCalciumS4H2909-SRD1 4080801-03 1520018400

1016.0*mg/kg dryChromiumS4H2909-SRD1 4080801-03 16.319.2

1018.2*mg/kg dryCobaltS4H2909-SRD1 4080801-03 7.408.87

107.21mg/kg dryCopperS4H2909-SRD1 4080801-03 25.327.2

1023.1*mg/kg dryIronS4H2909-SRD1 4080801-03 2010025400

1016.2*mg/kg dryLeadS4H2909-SRD1 4080801-03 32.438.1

1018.7*mg/kg dryMagnesiumS4H2909-SRD1 4080801-03 53106410

1017.1*mg/kg dryManganeseS4H2909-SRD1 4080801-03 413491

1018.9*mg/kg dryNickelS4H2909-SRD1 4080801-03 16.019.4

104.64mg/kg dryPotassiumS4H2909-SRD1 4080801-03 23302440

10mg/kg drySeleniumS4H2909-SRD1 4080801-03 NDND

10mg/kg drySilverS4H2909-SRD1 4080801-03 0.341ND

109.30mg/kg drySodiumS4H2909-SRD1 4080801-03 22102420

10mg/kg dryThalliumS4H2909-SRD1 4080801-03 0.880ND

1023.2*mg/kg dryVanadiumS4H2909-SRD1 4080801-03 20.826.3

1029.4*mg/kg dryZincS4H2909-SRD1 4080801-03 61.482.6




99.3.


B4H2641Batch ID:


B4H2641-BLK1 BLK1 8/26/2014

B4H2641-BS1 BS1 8/26/2014

B4H2641-DUP1 DUP1 8/26/2014

B4H2641-DUP2 DUP2 8/26/2014

B4H2641-MS1 MS1 8/26/2014

B4H2641-MS2 MS2 8/26/2014

B4H2641-MSD1 MSD1 8/26/2014

B4H2641-MSD2 MSD2 8/26/2014

B4H2641-PS1 PS1 8/26/2014

B4H2641-PS2 PS2 8/26/2014

4080683-01 QUARRY FINES 8/26/2014


99.4.


Work Order:

Project:


Client:



S4H2909 ICP

Sparta Quarry

4080683


S4H2909-ICV1Initial Cal Check 08/29/14 10:152014_08_29_SOIL_QC_x-001

S4H2909-ICV2Initial Cal Check 08/29/14 10:212014_08_29_SOIL_QC_x-002

S4H2909-ICB1Initial Cal Blank 08/29/14 10:242014_08_29_SOIL_QC_x-003

S4H2909-IFA1Interference Check A 08/29/14 10:262014_08_29_SOIL_QC_x-004

S4H2909-IFB1Interference Check B 08/29/14 10:302014_08_29_SOIL_QC_x-005

B4H2641-BLK1Blank 08/29/14 13:202014_08_29_SOIL_QC_x-006

B4H2641-BS1LCS 08/29/14 13:232014_08_29_SOIL_QC_x-007

S4H2909-SRD1Serial Dilution 08/29/14 13:262014_08_29_SOIL_QC_x-008

B4H2641-DUP1Duplicate 08/29/14 13:332014_08_29_SOIL_QC_x-010

B4H2641-MS1Matrix Spike 08/29/14 13:382014_08_29_SOIL_QC_x-011

B4H2641-MSD1Matrix Spike Dup 08/29/14 13:422014_08_29_SOIL_QC_x-012

B4H2641-PS1Post Spike 08/29/14 13:462014_08_29_SOIL_QC_x-013

S4H2909-CCV1Calibration Check 08/29/14 13:572014_08_29_SOIL_QC_x-014


S4H2909-CCB1Calibration Blank 08/29/14 14:022014_08_29_SOIL_QC_x-016

B4H2641-DUP2Duplicate 08/29/14 14:142014_08_29_SOIL_QC_x-017

B4H2641-MS2Matrix Spike 08/29/14 14:172014_08_29_SOIL_QC_x-018

B4H2641-MSD2Matrix Spike Dup 08/29/14 14:202014_08_29_SOIL_QC_x-019

B4H2641-PS2Post Spike 08/29/14 14:232014_08_29_SOIL_QC_x-020












99.5.


Work Order:

Project:


Client:



S4H2912 ICP

Sparta Quarry

4080683


S4H2912-ICV1Initial Cal Check 08/29/14 10:152014_08_29_SOIL_x-001

S4H2912-ICV2Initial Cal Check 08/29/14 10:212014_08_29_SOIL_x-002

S4H2912-ICB1Initial Cal Blank 08/29/14 10:242014_08_29_SOIL_x-003

S4H2912-IFA1Interference Check A 08/29/14 10:262014_08_29_SOIL_x-004

S4H2912-IFB1Interference Check B 08/29/14 10:302014_08_29_SOIL_x-005

4080683-01QUARRY FINES 08/29/14 16:352014_08_29_SOIL_x-010

S4H2912-CCV1Calibration Check 08/29/14 16:542014_08_29_SOIL_x-013

S4H2912-CCV2Calibration Check 08/29/14 16:562014_08_29_SOIL_x-014

S4H2912-CCB1Calibration Blank 08/29/14 16:592014_08_29_SOIL_x-015


99.5.

SW 846 6010B


ICP

Sequence: S4H2909


4080683

Client:

Work Order:

Project:

Instrument

Sparta Quarry


96.91.00 0.969 mg/LS4H2909-ICV1 Antimony +/-10.00%

96.91.00 0.969 mg/LArsenic +/-10.00%

1011.00 1.01 mg/LBarium +/-10.00%

1031.00 1.03 mg/LBeryllium +/-10.00%

1051.00 1.05 mg/LCadmium +/-10.00%

98.81.00 0.988 mg/LChromium +/-10.00%

1021.00 1.02 mg/LCobalt +/-10.00%

1021.00 1.02 mg/LCopper +/-10.00%

1011.00 1.01 mg/LLead +/-10.00%

1031.00 1.03 mg/LManganese +/-10.00%

1001.00 1.00 mg/LNickel +/-10.00%

98.01.00 0.980 mg/LSelenium +/-10.00%

1041.00 1.04 mg/LSilver +/-10.00%

1021.00 1.02 mg/LThallium +/-10.00%

1011.00 1.01 mg/LVanadium +/-10.00%

95.81.00 0.958 mg/LZinc +/-10.00%

99.3100 99.3 mg/LS4H2909-ICV2 Aluminum +/-10.00%

99.4100 99.4 mg/LCalcium +/-10.00%

92.720.0 18.5 mg/LIron +/-10.00%

102100 102 mg/LMagnesium +/-10.00%

98.4100 98.4 mg/LPotassium +/-10.00%

105100 105 mg/LSodium +/-10.00%

97.01.00 0.970 mg/LS4H2909-CCV1 Antimony +/-10.00%

98.91.00 0.989 mg/LArsenic +/-10.00%

98.71.00 0.987 mg/LBarium +/-10.00%

1011.00 1.01 mg/LBeryllium +/-10.00%

1051.00 1.05 mg/LCadmium +/-10.00%

98.91.00 0.989 mg/LChromium +/-10.00%

99.01.00 0.990 mg/LCobalt +/-10.00%

97.51.00 0.975 mg/LCopper +/-10.00%

1011.00 1.01 mg/LLead +/-10.00%

99.31.00 0.993 mg/LManganese +/-10.00%

99.31.00 0.993 mg/LNickel +/-10.00%

98.81.00 0.988 mg/LSelenium +/-10.00%

1011.00 1.01 mg/LSilver +/-10.00%

97.91.00 0.979 mg/LThallium +/-10.00%

97.51.00 0.975 mg/LVanadium +/-10.00%


99.6.

SW 846 6010B


ICP

Sequence: S4H2909


4080683

Client:

Work Order:

Project:

Instrument

Sparta Quarry


1021.00 1.02 mg/LS4H2909-CCV1 Zinc +/-10.00%

97.8100 97.8 mg/LS4H2909-CCV2 Aluminum +/-10.00%

102100 102 mg/LCalcium +/-10.00%

10140.0 40.5 mg/LIron +/-10.00%

102100 102 mg/LMagnesium +/-10.00%

97.0100 97.0 mg/LPotassium +/-10.00%

102100 102 mg/LSodium +/-10.00%


98.91.00 0.989 mg/LArsenic +/-10.00%

98.11.00 0.981 mg/LBarium +/-10.00%

1001.00 1.00 mg/LBeryllium +/-10.00%

1051.00 1.05 mg/LCadmium +/-10.00%

98.01.00 0.980 mg/LChromium +/-10.00%

98.41.00 0.984 mg/LCobalt +/-10.00%

96.71.00 0.967 mg/LCopper +/-10.00%

99.71.00 0.997 mg/LLead +/-10.00%

98.81.00 0.988 mg/LManganese +/-10.00%

98.81.00 0.988 mg/LNickel +/-10.00%

1001.00 1.00 mg/LSelenium +/-10.00%

1001.00 1.00 mg/LSilver +/-10.00%

97.91.00 0.979 mg/LThallium +/-10.00%

96.91.00 0.969 mg/LVanadium +/-10.00%

1011.00 1.01 mg/LZinc +/-10.00%


104100 104 mg/LCalcium +/-10.00%

99.540.0 39.8 mg/LIron +/-10.00%

104100 104 mg/LMagnesium +/-10.00%

95.0100 95.0 mg/LPotassium +/-10.00%

103100 103 mg/LSodium +/-10.00%


1001.00 1.00 mg/LArsenic +/-10.00%

99.91.00 0.999 mg/LBarium +/-10.00%

1011.00 1.01 mg/LBeryllium +/-10.00%

1061.00 1.06 mg/LCadmium +/-10.00%

99.71.00 0.997 mg/LChromium +/-10.00%

1001.00 1.00 mg/LCobalt +/-10.00%

99.01.00 0.990 mg/LCopper +/-10.00%


99.6.

SW 846 6010B


ICP

Sequence: S4H2909


4080683

Client:

Work Order:

Project:

Instrument

Sparta Quarry


1021.00 1.02 mg/LS4H2909-CCV5 Lead +/-10.00%

99.71.00 0.997 mg/LManganese +/-10.00%

1001.00 1.00 mg/LNickel +/-10.00%

1001.00 1.00 mg/LSelenium +/-10.00%

1031.00 1.03 mg/LSilver +/-10.00%

98.21.00 0.982 mg/LThallium +/-10.00%

99.01.00 0.990 mg/LVanadium +/-10.00%

1031.00 1.03 mg/LZinc +/-10.00%


101100 101 mg/LCalcium +/-10.00%

10440.0 41.6 mg/LIron +/-10.00%

102100 102 mg/LMagnesium +/-10.00%

98.4100 98.4 mg/LPotassium +/-10.00%

103100 103 mg/LSodium +/-10.00%

95.81.00 0.958 mg/LS4H2909-CCV7 Aluminum +/-10.00%

97.51.00 0.975 mg/LAntimony +/-10.00%

99.41.00 0.994 mg/LArsenic +/-10.00%

99.41.00 0.994 mg/LBarium +/-10.00%

1011.00 1.01 mg/LBeryllium +/-10.00%

1061.00 1.06 mg/LCadmium +/-10.00%

1011.00 1.01 mg/LCalcium +/-10.00%

99.31.00 0.993 mg/LChromium +/-10.00%

99.61.00 0.996 mg/LCobalt +/-10.00%

99.11.00 0.991 mg/LCopper +/-10.00%

1011.00 1.01 mg/LIron +/-10.00%

1011.00 1.01 mg/LLead +/-10.00%

1021.00 1.02 mg/LMagnesium +/-10.00%

99.41.00 0.994 mg/LManganese +/-10.00%

99.71.00 0.997 mg/LNickel +/-10.00%

89.810.0 8.98 mg/LPotassium +/-10.00%

1011.00 1.01 mg/LSelenium +/-10.00%

1021.00 1.02 mg/LSilver +/-10.00%

1031.00 1.03 mg/LSodium +/-10.00%

99.11.00 0.991 mg/LThallium +/-10.00%

98.61.00 0.986 mg/LVanadium +/-10.00%

1011.00 1.01 mg/LZinc +/-10.00%



99.6.

SW 846 6010B


ICP

Sequence: S4H2909


4080683

Client:

Work Order:

Project:

Instrument

Sparta Quarry


105100 105 mg/LS4H2909-CCV8 Calcium +/-10.00%

10440.0 41.4 mg/LIron +/-10.00%

105100 105 mg/LMagnesium +/-10.00%

98.4100 98.4 mg/LPotassium +/-10.00%

105100 105 mg/LSodium +/-10.00%


99.6.

SW 846 6010B


ICP

Sequence: S4H2912


4080683

Client:

Work Order:

Project:

Instrument

Sparta Quarry


96.91.00 0.969 mg/LS4H2912-ICV1 Antimony +/-10.00%

96.91.00 0.969 mg/LArsenic +/-10.00%

1011.00 1.01 mg/LBarium +/-10.00%

1031.00 1.03 mg/LBeryllium +/-10.00%

1051.00 1.05 mg/LCadmium +/-10.00%

98.81.00 0.988 mg/LChromium +/-10.00%

1021.00 1.02 mg/LCobalt +/-10.00%

1021.00 1.02 mg/LCopper +/-10.00%

1011.00 1.01 mg/LLead +/-10.00%

1031.00 1.03 mg/LManganese +/-10.00%

1001.00 1.00 mg/LNickel +/-10.00%

98.01.00 0.980 mg/LSelenium +/-10.00%

1041.00 1.04 mg/LSilver +/-10.00%

1021.00 1.02 mg/LThallium +/-10.00%

1011.00 1.01 mg/LVanadium +/-10.00%

95.81.00 0.958 mg/LZinc +/-10.00%

99.3100 99.3 mg/LS4H2912-ICV2 Aluminum +/-10.00%

99.4100 99.4 mg/LCalcium +/-10.00%

92.720.0 18.5 mg/LIron +/-10.00%

102100 102 mg/LMagnesium +/-10.00%

98.4100 98.4 mg/LPotassium +/-10.00%

105100 105 mg/LSodium +/-10.00%


96.71.00 0.967 mg/LArsenic +/-10.00%

95.91.00 0.959 mg/LBarium +/-10.00%

98.01.00 0.980 mg/LBeryllium +/-10.00%

1031.00 1.03 mg/LCadmium +/-10.00%

95.71.00 0.957 mg/LChromium +/-10.00%

96.91.00 0.969 mg/LCobalt +/-10.00%

95.01.00 0.950 mg/LCopper +/-10.00%

98.01.00 0.980 mg/LLead +/-10.00%

96.81.00 0.968 mg/LManganese +/-10.00%

97.01.00 0.970 mg/LNickel +/-10.00%

99.91.00 0.999 mg/LSelenium +/-10.00%

98.51.00 0.985 mg/LSilver +/-10.00%

95.71.00 0.957 mg/LThallium +/-10.00%

94.71.00 0.947 mg/LVanadium +/-10.00%


99.6.

SW 846 6010B


ICP

Sequence: S4H2912


4080683

Client:

Work Order:

Project:

Instrument

Sparta Quarry


97.91.00 0.979 mg/LS4H2912-CCV1 Zinc +/-10.00%


102100 102 mg/LCalcium +/-10.00%

10640.0 42.6 mg/LIron +/-10.00%

103100 103 mg/LMagnesium +/-10.00%

99.2100 99.2 mg/LPotassium +/-10.00%

103100 103 mg/LSodium +/-10.00%


99.6.

PESTICIDES


Work Order: 4080683




1010.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

2T05619.D

08/28/14 15:48

S4H2911

B4H2206

08/22/14 07:53

Sonication GC

Project:




Soil


Pesticides - SW 846 8081A


72-54-8 U4,4'-DDD ND 0.00140 0.00330

72-55-9 U4,4'-DDE ND 0.00146 0.00330

50-29-3 U4,4'-DDT ND 0.00164 0.00330

309-00-2 UAldrin ND 0.00162 0.00330

319-84-6 Ualpha-BHC ND 0.00162 0.00330

319-85-7 Ubeta-BHC ND 0.00337 0.00330

57-74-9 UChlordane ND 0.00174 0.00330

319-86-8 Udelta-BHC ND 0.00140 0.00330

60-57-1 UDieldrin ND 0.00162 0.00330

959-98-8 UEndosulfan I ND 0.00102 0.00330

33213-65-9 UEndosulfan II ND 0.00155 0.00330

1031-07-8 UEndosulfan sulfate ND 0.00164 0.00330

72-20-8 UEndrin ND 0.00162 0.00330

7421-93-4 UEndrin aldehyde ND 0.00184 0.00330

53494-70-5 UEndrin ketone ND 0.00173 0.00330

58-89-9 Ugamma-BHC (Lindane) ND 0.00162 0.00330

76-44-8 UHeptachlor ND 0.00148 0.00330

1024-57-3 UHeptachlor Epoxide ND 0.00180 0.00330

72-43-5 UMethoxychlor ND 0.00138 0.00330

8001-35-2 UToxaphene ND 0.0202 0.0660


1010.1.


Signal #1 : G:\HPCHEM\GCECD2\DATA\08282014\2T05619.D\ECD1A.CH Vial: 4 Signal #2 : G:\HPCHEM\GCECD2\DATA\08282014\2T05619.D\ECD2B.CH Acq On : 28 Aug 2014 15:48 Operator: sdp Sample : B4H2206-BLK1 Inst : GCECD-2 Misc : Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Aug 29 14:11 2014 Quant Results File: 80810825.RES

Quant Method : G:\HPCHEM\G...\80810825.M (Chemstation Integrator) Title : Pesticides by EPA Method 8081 Last Update : Mon Aug 25 16:17:55 2014 Response via : Initial Calibration DataAcq Meth : 8081PEST.M



System Monitoring Compounds 1) S TCMX 2.43 2.62 5700651 3309908 34.576 32.563 Spiked Amount 50.000 Range 37 - 126 Recovery = 69.15% 65.13% 20) S Decachlorobiphen 14.28 16.89 5778989 3552252 28.440 30.468 Spiked Amount 50.000 Range 46 - 130 Recovery = 56.88% 60.94%

Target Compounds Sum Chlordane (gamma) 0 0 N.D. N.D. Average Chlordane (gamma) 0.000 0.000

Sum Toxaphene (1) 0 0 N.D. N.D. Average Toxaphene (1) 0.000 0.000

-----------------------------------------------------------------------------(f)=RT Delta > 1/2 Window (#)=Amounts differ by > 25% (m)=manual int.2T05619.D 80810825.M Fri Aug 29 14:48:09 2014 SS Page 1


1010.1.


Signal #1 : G:\HPCHEM\GCECD2\DATA\08282014\2T05619.D\ECD1A.CH Vial: 4 Signal #2 : G:\HPCHEM\GCECD2\DATA\08282014\2T05619.D\ECD2B.CH Acq On : 28 Aug 2014 15:48 Operator: sdp Sample : B4H2206-BLK1 Inst : GCECD-2 Misc : Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Aug 29 14:11 2014 Quant Results File: 80810825.RES

Quant Method : G:\HPCHEM\G...\80810825.M (Chemstation Integrator) Title : Pesticides by EPA Method 8081 Last Update : Mon Aug 25 16:17:55 2014 Response via : Multiple Level Calibration DataAcq Meth : 8081PEST.M


2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00

20000

40000

60000

80000

100000

120000

140000

160000

180000

200000

220000

240000

Time

Response_ 2T05619.D\ECD1A

2.4

3

14.2

7D

ecachlo

ro

TC

MX

2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00

20000

40000

60000

80000

100000

120000

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160000

Time

Response_ 2T05619.D\ECD2B

2.6

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eca

ch

loro

TC

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#2

2T05619.D 80810825.M Fri Aug 29 14:48:10 2014 SS Page 2


1010.1.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

2T05700.D

09/04/14 16:28

S4I0813

B4H2206

08/22/14 07:53

Sonication GC

Project:

4080683




1Dilution:


Soil

08/21/14 09:35


Sparta Quarry

Pesticides - SW 846 8081A


72-54-8 U4,4'-DDD ND 0.00148 0.00349

72-55-9 U4,4'-DDE ND 0.00154 0.00349

50-29-3 U4,4'-DDT ND 0.00173 0.00349

309-00-2 UAldrin ND 0.00171 0.00349

319-84-6 Ualpha-BHC ND 0.00171 0.00349

319-85-7 Ubeta-BHC ND 0.00356 0.00349

57-74-9 UChlordane ND 0.00184 0.00349

319-86-8 Udelta-BHC ND 0.00148 0.00349

60-57-1 UDieldrin ND 0.00171 0.00349

959-98-8 UEndosulfan I ND 0.00108 0.00349

33213-65-9 UEndosulfan II ND 0.00164 0.00349

1031-07-8 UEndosulfan sulfate ND 0.00173 0.00349

72-20-8 UEndrin ND 0.00171 0.00349

7421-93-4 UEndrin aldehyde ND 0.00194 0.00349

53494-70-5 UEndrin ketone ND 0.00183 0.00349

58-89-9 Ugamma-BHC (Lindane) ND 0.00171 0.00349

76-44-8 UHeptachlor ND 0.00156 0.00349

1024-57-3 UHeptachlor Epoxide ND 0.00190 0.00349

72-43-5 UMethoxychlor ND 0.00146 0.00349

8001-35-2 UToxaphene ND 0.0213 0.0697










1010.2.


Signal #1 : G:\HPCHEM\GCECD2\DATA\09042014\2T05700.D\ECD1A.CH Vial: 12 Signal #2 : G:\HPCHEM\GCECD2\DATA\09042014\2T05700.D\ECD2B.CH Acq On : 4 Sep 2014 16:28 Operator: sdp Sample : 4080683-01 Inst : GCECD-2 Misc : B4H2206 Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Sep 8 12:56 2014 Quant Results File: 80810825.RES

Quant Method : G:\HPCHEM\G...\80810825.M (Chemstation Integrator) Title : Pesticides by EPA Method 8081 Last Update : Fri Aug 29 14:11:21 2014 Response via : Initial Calibration DataAcq Meth : 8081PEST.M



System Monitoring Compounds 1) S TCMX 2.42 2.62 5232544 2448190 31.737 24.086 Spiked Amount 50.000 Range 37 - 126 Recovery = 63.47% 48.17% 20) S Decachlorobiphen 14.24 16.87 8353194 5246791 41.108 45.002m Spiked Amount 50.000 Range 46 - 130 Recovery = 82.22% 90.00%

Target Compounds Sum Chlordane (gamma) 0 0 N.D. N.D. Average Chlordane (gamma) 0.000 0.000


-----------------------------------------------------------------------------(f)=RT Delta > 1/2 Window (#)=Amounts differ by > 25% (m)=manual int.2T05700.D 80810825.M Mon Sep 08 13:39:51 2014 SS Page 1


1010.2.


Signal #1 : G:\HPCHEM\GCECD2\DATA\09042014\2T05700.D\ECD1A.CH Vial: 12 Signal #2 : G:\HPCHEM\GCECD2\DATA\09042014\2T05700.D\ECD2B.CH Acq On : 4 Sep 2014 16:28 Operator: sdp Sample : 4080683-01 Inst : GCECD-2 Misc : B4H2206 Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Sep 8 12:56 2014 Quant Results File: 80810825.RES

Quant Method : G:\HPCHEM\G...\80810825.M (Chemstation Integrator) Title : Pesticides by EPA Method 8081 Last Update : Fri Aug 29 14:11:21 2014 Response via : Multiple Level Calibration DataAcq Meth : 8081PEST.M


2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00

0

20000

40000

60000

80000

100000

120000

140000

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180000

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220000

Time


2.4

2

14.2

4D

ecachlo

ro

TC

MX

2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00

0

20000

40000

60000

80000

100000

120000

140000

160000

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2.6

2

16.8

7D

eca

ch

loro

TC

MX

#2

2T05700.D 80810825.M Mon Sep 08 13:39:51 2014 SS Page 2


1010.2.

SURROGATE RECOVERIESAnalysis Class: PESTICIDES

Method:

File ID

Matrix: Soil

Lab Number DCB[2C]TCMX DCB TCMX[2C]

SW 846 8081A

4080683-01 2T05700.D 63.5 82.2 48.2 90.0

B4H2206-BLK1 2T05619.D 69.2 56.9 65.1 60.9



DCB[2C]

TCMX

DCB

TCMX[2C]


Decachlorobiphenyl



37 126

46

37

46

130

126

130


1010.3.

Pesticides - Quality Control


Batch B4H2206 Prepared: 08/22/2014Method: SW 846 8081A

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source0.0333 56-16278.5mg/kg wet4,4'-DDDB4H2206-BS1 0.0262

0.0333 71-14292.3mg/kg wet4,4'-DDEB4H2206-BS1 0.0308

0.0333 60-13576.6mg/kg wet4,4'-DDTB4H2206-BS1 0.0255

0.0333 38-19886.5mg/kg wetAldrinB4H2206-BS1 0.0288

0.0333 56-14195.3mg/kg wetalpha-BHCB4H2206-BS1 0.0318

0.0333 69-13293.4mg/kg wetbeta-BHCB4H2206-BS1 0.0311

0.0333 45-16990.8mg/kg wetdelta-BHCB4H2206-BS1 0.0303

0.0333 36-11878.4mg/kg wetDieldrinB4H2206-BS1 0.0261

0.0333 61-12486.1mg/kg wetEndosulfan IB4H2206-BS1 0.0287

0.0333 58-12368.8mg/kg wetEndosulfan IIB4H2206-BS1 0.0229

0.0333 69-13671.8mg/kg wetEndosulfan sulfateB4H2206-BS1 0.0239

0.0333 63-13181.2mg/kg wetEndrinB4H2206-BS1 0.0271

0.0333 26-21558.1mg/kg wetEndrin aldehydeB4H2206-BS1 0.0194

0.0333 63-14665.9mg/kg wetEndrin ketoneB4H2206-BS1 0.0220

0.0333 67-12595.1mg/kg wetgamma-BHC (Lindane)B4H2206-BS1 0.0317

0.0333 48-14490.6mg/kg wetHeptachlorB4H2206-BS1 0.0302

0.0333 61-12270.2mg/kg wetHeptachlor EpoxideB4H2206-BS1 0.0234

0.0333 68-17571.8mg/kg wetMethoxychlorB4H2206-BS1 0.0239

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source0.0369 60-14056.3*mg/kg dry4,4'-DDTB4H2206-MS1 4080477-01 ND0.0208

0.0369 60-14063.9mg/kg dryAldrinB4H2206-MS1 4080477-01 ND0.0236

0.0369 60-14064.2mg/kg dryDieldrinB4H2206-MS1 4080477-01 ND0.0237

0.0369 60-14063.7mg/kg dryEndrinB4H2206-MS1 4080477-01 ND0.0235

0.0369 60-14069.1mg/kg drygamma-BHC (Lindane)B4H2206-MS1 4080477-01 ND0.0255

0.0369 60-14090.9mg/kg dryHeptachlorB4H2206-MS1 4080477-01 ND0.0336

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source0.0369 2560-14050.4* 11.0mg/kg dry4,4'-DDTB4H2206-MSD1 4080477-01 ND0.0186

0.0369 2560-14067.3 5.22mg/kg dryAldrinB4H2206-MSD1 4080477-01 ND0.0249

0.0369 2560-14062.5 2.75mg/kg dryDieldrinB4H2206-MSD1 4080477-01 ND0.0231

0.0369 2560-14061.7 3.25mg/kg dryEndrinB4H2206-MSD1 4080477-01 ND0.0228

0.0369 2560-14066.0 4.53mg/kg drygamma-BHC (Lindane)B4H2206-MSD1 4080477-01 ND0.0244

0.0369 2560-14079.8 13.0mg/kg dryHeptachlorB4H2206-MSD1 4080477-01 ND0.0295




1010.4.


B4H2206Batch ID:


B4H2206-BLK1 BLK1 8/22/2014

B4H2206-BS1 BS1 8/22/2014

B4H2206-MS1 MS1 8/22/2014

B4H2206-MSD1 MSD1 8/22/2014

4080683-01 QUARRY FINES 8/22/2014


1010.5.

SURROGATE RT DRIFT REPORT

Analysis Class: PESTICIDES

Lab Number File ID

Sequence : S4H2911



B4H2206-BLK1 2T05619.D 2.43 14.28 2.62 16.89 0.0016.892.6214.262.42 0.01 0.00 0.00

Lab Number File ID

Sequence : S4I0813



4080683-01 2T05700.D 2.42 14.24 2.62 16.87 0.0016.872.6214.242.42 0.00 0.00 0.00

Surrogate


Decachlorobiphenyl



0.10

0.10

0.10

0.10

Limit

DCB[2C]

TCMX[2C]

DCB

TCMX DISS = Dissolved Analysis


1010.6.

Response Factor Report GCECD-2

Method : G:\HPCHEM\GCECD2\METHODS\80810825.M (Chemstation Integrator) Title : Pesticides by EPA Method 8081 Last Update : Mon Aug 25 16:17:55 2014

Calibration Files 2 =2T05541.D 5 =2T05542.D 10 =2T05543.D 25 =2T05544.D 50 =2T05545.D 100 =2T05546.D

Compound 2 5 10 25 50 100 Avg %RSD---------------------------------------------------------------------------

1) S TCMX 1.744 1.894 1.221 1.759 1.681 1.593 1.649 E5 14.06 2) alpha-BHC 2.011 2.392 1.601 2.383 2.309 2.200 2.149 E5 14.13 3) M gamma-BHC (Lindane) 2.039 2.277 1.527 2.268 2.175 2.047 2.056 E5 13.55 4) M Heptachlor 2.248 2.472 1.661 2.337 2.231 2.078 2.171 E5 12.97 5) beta-BHC 1.172 1.257 0.819 1.162 1.102 1.041 1.092 E5 13.94 6) delta-BHC 1.992 2.144 1.421 2.183 2.123 2.061 1.987 E5 14.36 7) M Aldrin 1.790 2.044 1.400 2.096 2.039 1.931 1.883 E5 13.83 8) Heptachlor epoxide 1.930 2.138 1.418 2.058 1.968 1.829 1.890 E5 13.45 9) Endosulfan I 1.892 2.226 1.309 1.819 1.745 1.564 1.759 E5 17.61 10) 4,4'-DDE 1.866 1.876 1.306 1.745 1.656 1.514 1.661 E5 13.27 11) M Dieldrin 1.719 1.950 1.331 1.980 1.950 1.851 1.797 E5 13.78 12) M Endrin 1.673 1.814 1.254 1.829 1.799 1.694 1.677 E5 12.95 13) 4,4'-DDD 1.268 1.527 0.984 1.478 1.491 1.456 1.368 E5 15.25 14) Endosulfan II 1.876 2.229 1.407 1.915 1.836 1.735 1.833 E5 14.55 15) M 4,4'-DDT 1.244 1.606 0.994 1.572 1.609 1.562 1.431 E5 17.82 16) Endrin aldehyde 1.576 1.608 1.125 1.554 1.251 1.429 1.424 E5 13.81 17) Endosulfan sulfate 1.725 1.758 1.193 1.634 1.578 1.520 1.568 E5 13.00 18) Methoxychlor 9.022 9.940 6.858 9.886 9.581 8.900 9.031 E4 12.72 19) Endrin ketone 1.781 2.106 1.471 1.985 1.923 1.835 1.850 E5 11.77 20) S Decachlorobiphenyl 2.144 2.267 1.563 2.191 2.125 1.901 2.032 E5 12.81 21) L1 Chlordane (gamma) 2.022 2.213 1.471 2.062 1.982 1.857 1.934 E5 13.18 22) L1 Chlordane (alpha) 1.956 2.188 1.459 2.037 1.948 1.811 1.900 E5 13.09 23) L2 Toxaphene (1) 0.000 0 -1.00

Signal #2 Calibration Files 2 =2T05541.D 5 =2T05542.D 10 =2T05543.D 25 =2T05544.D 50 =2T05545.D 100 =2T05546.D Compound 2 5 10 25 50 100 Avg %RSD---------------------------------------------------------------------------

1) S TCMX 1.012 1.149 0.744 1.112 1.059 1.024 1.016 E5 14.10 2) alpha-BHC 1.170 1.418 0.971 1.542 1.542 1.508 1.359 E5 17.38 3) M gamma-BHC (Lindane) 1.203 1.387 0.955 1.491 1.475 1.427 1.323 E5 15.73 4) M Heptachlor 1.432 1.596 1.092 1.632 1.619 1.552 1.487 E5 13.91 5) beta-BHC 7.294 7.788 5.198 7.522 7.208 6.956 6.994 E4 13.22 6) delta-BHC 1.113 1.227 0.826 1.300 1.286 1.272 1.171 E5 15.54 7) M Aldrin 1.083 1.256 0.871 1.355 1.354 1.320 1.206 E5 16.03 8) Heptachlor epoxide 1.183 1.338 0.913 1.343 1.319 1.266 1.227 E5 13.47 9) Endosulfan I 1.171 1.294 0.883 1.312 1.297 1.255 1.202 E5 13.69 10) 4,4'-DDE 1.009 1.145 0.782 1.218 1.235 1.209 1.100 E5 16.04 11) M Dieldrin 1.004 1.177 0.808 1.261 1.289 1.261 1.133 E5 16.81 12) M Endrin 0.954 1.092 0.744 1.116 1.132 1.104 1.024 E5 14.80 13) 4,4'-DDD 7.027 7.972 5.381 8.768 9.319 9.240 7.951 E4 19.21 14) Endosulfan II 1.147 1.261 0.865 1.258 1.242 1.204 1.163 E5 13.09 15) M 4,4'-DDT 0.636 0.794 0.596 0.932 0.998 1.012 0.828 E5 21.96 16) Endrin aldehyde 0.970 1.006 0.683 0.952 0.772 0.947 0.888 E5 14.55 17) Endosulfan sulfate 1.031 1.010 0.748 1.056 1.062 1.055 0.994 E5 12.28 18) Methoxychlor 5.499 7.340 4.467 6.657 6.555 6.254 6.129 E4 16.48 19) Endrin ketone 1.071 1.201 0.839 1.274 1.304 1.267 1.159 E5 15.35 20) S Decachlorobiphenyl 1.209 1.376 0.885 1.243 1.177 1.105 1.166 E5 14.07 21) L1 Chlordane (gamma) 1.255 1.365 0.928 1.339 1.323 1.266 1.246 E5 12.94 22) L1 Chlordane (alpha) 1.183 1.328 0.902 1.301 1.273 1.209 1.199 E5 12.99 23) L2 Toxaphene (1) 0.000 0 -1.00

80810825.M Tue Aug 26 09:39:09 2014 SS Page 1(#) = Out of Range


1010.7.

Compound List Report GCECD-2

Method : G:\HPCHEM\GCECD2\METHODS\80810825.M (Chemstation Integrator) Title : Pesticides by EPA Method 8081 Last Update : Mon Aug 25 16:17:55 2014 Response via : Initial Calibration Total Cpnds : 47

PK# Type Compound Name Exp_RT Rel_RT Cal A/H ID -------------------------------------------------------------------------- 1 S TCMX 2.43 1.000 A A B 2 alpha-BHC 3.01 1.000 A A B 3 M gamma-BHC (Lindane) 3.40 1.000 A A B 4 M Heptachlor 4.08 1.000 A A B 5 beta-BHC 3.52 1.000 A A B 6 delta-BHC 3.78 1.000 A A B 7 M Aldrin 4.57 1.000 A A B 8 Heptachlor epoxide 5.67 1.000 A A B 9 Endosulfan I 6.44 1.000 A A B 10 4,4'-DDE 6.44 1.000 A A B 11 M Dieldrin 6.96 1.000 A A B 12 M Endrin 7.46 1.000 A A B 13 4,4'-DDD 7.76 1.000 A A B 14 Endosulfan II 7.97 1.000 A A B 15 M 4,4'-DDT 8.41 1.000 A A B 16 Endrin aldehyde 8.98 1.000 A A B 17 Endosulfan sulfate 10.04 1.000 A A B 18 Methoxychlor 9.71 1.000 A A B 19 Endrin ketone 10.75 1.000 A A B 20 S Decachlorobiphenyl 14.28 1.000 A A B 21 L1 Chlordane (gamma) 5.92 1.000 A A B 22 L1 Chlordane (alpha) 6.19 1.000 A A B 23 L2 Toxaphene (1) 11.20 1.000 A A B 24 Signal #2 35.00 1.000 A A B 25 S TCMX #2 2.63 1.000 A A B 26 alpha-BHC #2 3.46 1.000 A A B 27 M gamma-BHC (Lindane) #2 4.05 1.000 A A B 28 M Heptachlor #2 4.83 1.000 A A B 29 beta-BHC #2 4.21 1.000 A A B 30 delta-BHC #2 4.75 1.000 A A B 31 M Aldrin #2 5.47 1.000 A A B 32 Heptachlor epoxide #2 6.72 1.000 A A B 33 Endosulfan I #2 7.61 1.000 A A B 34 4,4'-DDE #2 7.99 1.000 A A B 35 M Dieldrin #2 8.27 1.000 A A B 36 M Endrin #2 9.01 1.000 A A B 37 4,4'-DDD #2 9.45 1.000 A A B 38 Endosulfan II #2 9.57 1.000 A A B 39 M 4,4'-DDT #2 10.25 1.000 L A B 40 Endrin aldehyde #2 10.49 1.000 A A B 41 Endosulfan sulfate #2 11.31 1.000 A A B 42 Methoxychlor #2 12.60 1.000 A A B 43 Endrin ketone #2 13.06 1.000 A A B 44 S Decachlorobiphenyl #2 16.91 1.000 A A B 45 L1 Chlordane (gamma) #2 7.15 1.000 A A B 46 L1 Chlordane (alpha) #2 7.50 1.000 A A B 47 L2 Toxaphene (1) #2 14.63 1.000 A A B

Cal A = Average L = Linear LO = Linear w/origin Q = Quad QO = Quad w/origin A/H = Area or Height ID R = R.T. B = R.T. & Q Q = Qvalue L = Largest A = All -------------------------------------------------------------------------- 80810825.M Tue Aug 26 09:39:08 2014 SS

80810825.M Tue Aug 26 09:39:08 2014 Page 1


1010.7.

CALIBRATION VERIFICATION SUMMARY

Client:

Work Order:


4080683

RT WINDOW

FROM TOCF CF %D

Individual Mix Compound

S4H2911-CCV1(1)Lab Sample ID (X50pp): Init. Calib. Date(s): 08/25/2014

Date Analyzed:2T05618.DFile ID: 08/28/2014 14:51

Column 1

Aldrin 04.56 04.46 04.66 9.00171446188335

alpha-BHC 03.00 02.90 03.10 3.60207185214945

beta-BHC 03.52 03.42 03.62 11.9096251109205

delta-BHC 03.77 03.67 03.87 4.40189915198742

Dieldrin 06.95 06.85 07.05 14.90152974179677

Endosulfan I 06.42 06.32 06.52 6.70164178175919

Endosulfan II 07.96 07.86 08.06 25.20137031183305

Endosulfan sulfate 10.03 09.93 10.13 26.70114978156787

Endrin 07.45 07.35 07.55 14.30143711167716

Endrin aldehyde 08.96 08.86 09.06 25.70105788142381

Endrin ketone 10.73 10.63 10.83 21.70144863185008

gamma-BHC (Lindane) 03.40 03.30 03.50 4.80195601205560

4,4'-DDT 08.39 08.29 08.49 12.50125197143138

4,4'-DDE 06.42 06.32 06.52 1.90169172166078

4,4'-DDD 07.74 07.64 07.84 14.50116866136753

Methoxychlor 09.70 09.60 09.80 19.807245490312

Heptachlor Epoxide 05.66 05.56 05.76 16.80157173189019

Heptachlor 04.08 03.98 04.18 8.60198339217112

Chlordane 06.18 06.08 06.28 18.30156561191703

Pesticide Average 10.73 10.63 10.83 14.10150883175731

13.75Average %D:

* - Outside of QC limits


1010.8.


Client:

Work Order:


4080683

RT WINDOW

FROM TOCF CF %D


S4H2911-CCV1(2)Lab Sample ID (X50pp): Init. Calib. Date(s): 08/25/2014


Column 2

Aldrin [2C] 05.46 05.36 05.56 4.20125646120617

alpha-BHC [2C] 03.45 03.35 03.55 11.90152072135885

beta-BHC [2C] 04.20 04.10 04.30 9.406339569943

delta-BHC [2C] 04.74 04.64 04.84 6.30124475117076

Dieldrin [2C] 08.26 08.16 08.36 2.60116258113341

Endosulfan I [2C] 07.59 07.49 07.69 4.40114841120187

Endosulfan II [2C] 09.56 09.46 09.66 7.30107738116268

Endosulfan sulfate [2C] 11.29 11.19 11.39 4.209516299358

Endrin [2C] 09.00 08.90 09.10 3.20105648102365

Endrin aldehyde [2C] 10.47 10.37 10.57 24.106741588833

Endrin ketone [2C] 13.04 12.94 13.14 4.90110281115928

gamma-BHC [Lindane] [2C] 04.04 03.94 04.14 8.30143225132299

4,4'-DDT [2C] 10.23 10.13 10.33 2.108453582819

4,4'-DDE [2C] 07.97 07.87 08.07 3.00113255109955

4,4'-DDD [2C] 09.44 09.34 09.54 5.508386079513

Methoxychlor [2C] 12.58 12.48 12.68 11.405430961289

Heptachlor Epoxide [2C] 06.70 06.60 06.80 4.40117254122690

Heptachlor [2C] 04.82 04.72 04.92 2.30152080148707

Chlordane [2C] 07.48 07.38 07.58 4.50116713122263

Pesticide Average [2C] 13.04 12.94 13.14 1.40110778112312

6.53Average %D:



1010.8.


Signal #1 : G:\HPCHEM\GCECD2\DATA\08282014\2T05618.D\ECD1A.CH Vial: 3 Signal #2 : G:\HPCHEM\GCECD2\DATA\08282014\2T05618.D\ECD2B.CH Acq On : 28 Aug 2014 14:51 Operator: sdp Sample : SEQ-CCV@X50ppb Inst : GCECD-2 Misc : Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Aug 29 14:10 2014 Quant Results File: 80810825.RES

Quant Method : G:\HPCHEM\G...\80810825.M (Chemstation Integrator) Title : Pesticides by EPA Method 8081 Last Update : Mon Aug 25 16:17:55 2014 Response via : Initial Calibration DataAcq Meth : 8081PEST.M




Target Compounds 2) alpha-BHC 3.00 3.45 10359267 7603573 48.195 55.956 3) M gamma-BHC (Linda 3.40 4.04 9780058 7161235 47.578 54.129 4) M Heptachlor 4.08 4.82 9916942 7604000 45.677 51.134 5) beta-BHC 3.52 4.20 4812533 3169768 44.069 45.319 6) delta-BHC 3.77 4.74 9495767 6223752 47.779 53.160 7) M Aldrin 4.56 5.46 8572273 6282313 45.516 52.085 8) Heptachlor epoxi 5.66 6.70 7858672 5862716 41.576 47.785 9) Endosulfan I 6.42 7.59 8208915 5742068 46.663m 47.776 10) 4,4'-DDE 6.42 7.97 8458610 5662734 50.932m 51.500 11) M Dieldrin 6.95 8.26 7648702 5812897 42.569 51.287 12) M Endrin 7.45 9.00 7185547 5282388 42.843 51.604 13) 4,4'-DDD 7.74 9.44 5843308 4192993 42.729 52.734 14) Endosulfan II 7.96 9.56 6851529 5386912 37.378 46.332 15) M 4,4'-DDT 8.39 10.23 6259867 4226726 43.733 42.973 16) Endrin aldehyde 8.96 10.47 5289419 3370755 37.150m 37.945 17) Endosulfan sulfa 10.03 11.29 5748884 4758092 36.667 47.889 #18) Methoxychlor 9.70 12.58 3622675 2715448 40.113 44.306 19) Endrin ketone 10.73 13.04 7243132 5514060 39.150 47.564 21) L1 Chlordane (gamma 5.91 7.14 7995522 5950151 41.338 47.754 22) L1 Chlordane (alpha 6.18 7.48 7660579 5721150 40.321 47.706 Sum Chlordane (gamma) 15656101 11671301 81.660 95.460Average Chlordane (gamma) 40.830 47.730


-----------------------------------------------------------------------------(f)=RT Delta > 1/2 Window (#)=Amounts differ by > 25% (m)=manual int.2T05618.D 80810825.M Fri Aug 29 14:48:08 2014 SS Page 1


1010.8.


Signal #1 : G:\HPCHEM\GCECD2\DATA\08282014\2T05618.D\ECD1A.CH Vial: 3 Signal #2 : G:\HPCHEM\GCECD2\DATA\08282014\2T05618.D\ECD2B.CH Acq On : 28 Aug 2014 14:51 Operator: sdp Sample : SEQ-CCV@X50ppb Inst : GCECD-2 Misc : Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Aug 29 14:10 2014 Quant Results File: 80810825.RES

Quant Method : G:\HPCHEM\G...\80810825.M (Chemstation Integrator) Title : Pesticides by EPA Method 8081 Last Update : Mon Aug 25 16:17:55 2014 Response via : Multiple Level Calibration DataAcq Meth : 8081PEST.M


2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00

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2.4

2

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3.3

9 3.5

2

3.7

7 4.0

8

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5.6

6

5.9

1

6.1

8

6.4

2

6.9

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7.7

4 7.9

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8.3

9

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9.6

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6D

ecachlo

ro

Endri

n k

et

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Meth

oxychl

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n a

ld

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DT

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DD

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ldri

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DE

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rdane

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rdane

Hepta

chlo

r

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rin

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chlo

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delta-B

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beta

-BH

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ma-B

HC

alp

ha-B

HC

TC

MX

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2.6

2

3.4

5

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0

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4 4.8

2

5.4

6

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0

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4

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8 7.5

9

7.9

7

8.2

5

9.0

0

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3 9.5

6

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3 1

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16.8

9D

eca

ch

loro

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et

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DE

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rdelta-B

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-BH

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alp

ha-B

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TC

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#2

2T05618.D 80810825.M Fri Aug 29 14:48:08 2014 SS Page 2


1010.8.


Client:

Work Order:


4080683

RT WINDOW

FROM TOCF CF %D


S4I0813-CCV1(1)Lab Sample ID (X50pp): Init. Calib. Date(s): 08/25/2014


Column 1

Aldrin 04.55 04.45 04.65 10.70208413188335

alpha-BHC 02.99 02.89 03.09 14.80246689214945

beta-BHC 03.51 03.41 03.61 5.60115280109205

delta-BHC 03.76 03.66 03.86 14.30227179198742

Dieldrin 06.94 06.84 07.04 8.10194148179677

Endosulfan I 06.42 06.32 06.52 1.00177672175919

Endosulfan II 07.94 07.84 08.04 0.60182163183305

Endosulfan sulfate 10.01 09.91 10.11 4.60149588156787

Endrin 07.43 07.33 07.53 11.70187273167716

Endrin aldehyde 08.95 08.85 09.05 13.60123032142381

Endrin ketone 10.71 10.61 10.81 6.80197669185008

gamma-BHC (Lindane) 03.39 03.29 03.49 14.70235677205560

4,4'-DDT 08.38 08.28 08.48 14.70164210143138

4,4'-DDE 06.41 06.31 06.51 4.90174260166078

4,4'-DDD 07.72 07.62 07.82 13.90155820136753

Methoxychlor 09.68 09.58 09.78 1.309148090312

Heptachlor Epoxide 05.65 05.55 05.75 2.70194139189019

Heptachlor 04.07 03.97 04.17 11.60242228217112

Chlordane 06.17 06.07 06.27 1.70194894191703

Pesticide Average 10.71 10.61 10.81 5.90186025175731

8.28Average %D:



1010.8.


Client:

Work Order:


4080683

RT WINDOW

FROM TOCF CF %D


S4I0813-CCV1(2)Lab Sample ID (X50pp): Init. Calib. Date(s): 08/25/2014


Column 2

Aldrin [2C] 05.45 05.35 05.55 27.50153806120617

alpha-BHC [2C] 03.45 03.35 03.55 30.60177513135885

beta-BHC [2C] 04.19 04.09 04.29 8.707603069943

delta-BHC [2C] 04.74 04.64 04.84 23.70144802117076

Dieldrin [2C] 08.24 08.14 08.34 30.50147899113341

Endosulfan I [2C] 07.58 07.48 07.68 18.80142734120187

Endosulfan II [2C] 09.55 09.45 09.65 18.80138070116268

Endosulfan sulfate [2C] 11.27 11.17 11.37 16.4011564699358

Endrin [2C] 08.99 08.89 09.09 30.90134025102365

Endrin aldehyde [2C] 10.46 10.36 10.56 0.808953988833

Endrin ketone [2C] 13.02 12.92 13.12 25.70145667115928

gamma-BHC [Lindane] [2C] 04.03 03.93 04.13 28.10169471132299

4,4'-DDT [2C] 10.22 10.12 10.32 21.6010067482819

4,4'-DDE [2C] 07.96 07.86 08.06 29.10141916109955

4,4'-DDD [2C] 09.42 09.32 09.52 34.5010692579513

Methoxychlor [2C] 12.56 12.46 12.66 19.907349061289

Heptachlor Epoxide [2C] 06.69 06.59 06.79 13.20138883122690

Heptachlor [2C] 04.82 04.72 04.92 19.40177621148707

Chlordane [2C] 07.47 07.37 07.57 17.20143347122263

Pesticide Average [2C] 13.02 12.92 13.12 21.10135994112312

21.86Average %D:



1010.8.


Signal #1 : G:\HPCHEM\GCECD2\DATA\09042014\2T05691.D\ECD1A.CH Vial: 3 Signal #2 : G:\HPCHEM\GCECD2\DATA\09042014\2T05691.D\ECD2B.CH Acq On : 4 Sep 2014 12:37 Operator: sdp Sample : SEQ-CCV@X50ppb Inst : GCECD-2 Misc : Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Sep 4 15:13 2014 Quant Results File: 80810825.RES

Quant Method : G:\HPCHEM\G...\80810825.M (Chemstation Integrator) Title : Pesticides by EPA Method 8081 Last Update : Fri Aug 29 14:11:21 2014 Response via : Initial Calibration DataAcq Meth : 8081PEST.M




Target Compounds 2) alpha-BHC 2.99 3.45 12334470 8875633 57.384 65.317 3) M gamma-BHC (Linda 3.39 4.03 11783857 8473546 57.326 64.049 4) M Heptachlor 4.07 4.82 12111402 8881048 55.784 59.722 5) beta-BHC 3.51 4.19 5763995 3801502 52.781 54.352 6) delta-BHC 3.76 4.74 11358958 7240086 57.154 61.841 7) M Aldrin 4.55 5.45 10420643 7690285 55.330 63.758 8) Heptachlor epoxi 5.65 6.69 9706927 6944140 51.354 56.599 9) Endosulfan I 6.42 7.58 8883608 7136695 50.498m 59.380 10) 4,4'-DDE 6.41 7.96 8712990 7095776 52.463m 64.533 11) M Dieldrin 6.94 8.24 9707419 7394964 54.027 65.245 12) M Endrin 7.43 8.99 9363642 6701268 55.830 65.465 13) 4,4'-DDD 7.72 9.42 7790996 5346243 56.971 67.238 14) Endosulfan II 7.94 9.55 9108138 6903512 49.688 59.376 15) M 4,4'-DDT 8.38 10.22 8210481 5033693 57.361 50.789 16) Endrin aldehyde 8.95 10.46 6151579 4476958 43.205 50.398 17) Endosulfan sulfa 10.01 11.27 7479401 5782304 47.704 58.197 18) Methoxychlor 9.68 12.56 4574018 3674490 50.647 59.954 19) Endrin ketone 10.71 13.02 9883435 7283363 53.422 62.826 21) L1 Chlordane (gamma 5.90 7.13 10143461 7380895 52.443 59.237 22) L1 Chlordane (alpha 6.17 7.47 9345965 6953840 49.192 57.984 Sum Chlordane (gamma) 19489427 14334735 101.636 117.221Average Chlordane (gamma) 50.818 58.611


-----------------------------------------------------------------------------(f)=RT Delta > 1/2 Window (#)=Amounts differ by > 25% (m)=manual int.2T05691.D 80810825.M Mon Sep 08 13:39:29 2014 SS Page 1


1010.8.


Signal #1 : G:\HPCHEM\GCECD2\DATA\09042014\2T05691.D\ECD1A.CH Vial: 3 Signal #2 : G:\HPCHEM\GCECD2\DATA\09042014\2T05691.D\ECD2B.CH Acq On : 4 Sep 2014 12:37 Operator: sdp Sample : SEQ-CCV@X50ppb Inst : GCECD-2 Misc : Multiplr: 1.00 IntFile Signal #1: EVENTS.E IntFile Signal #2: EVENTS2.E Quant Time: Sep 4 15:13 2014 Quant Results File: 80810825.RES

Quant Method : G:\HPCHEM\G...\80810825.M (Chemstation Integrator) Title : Pesticides by EPA Method 8081 Last Update : Fri Aug 29 14:11:21 2014 Response via : Multiple Level Calibration DataAcq Meth : 8081PEST.M


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250000

300000

350000

400000

450000

500000

550000

Time


2.4

2

2.9

9

3.3

9 3.5

1

3.7

6 4.0

7

4.5

5

5.6

5

5.9

0

6.1

7

6.4

1 6.4

2

6.9

4

7.4

3

7.7

2 7.9

4

8.3

7

8.9

5

9.6

8

10.0

1

10.7

1

14.2

4D

ecachlo

ro

Endri

n k

et

Endosulfan

Meth

oxychl

Endri

n a

ld

4,4

'-D

DT

Endosulfan

4,4

'-D

DD

Endrin

Die

ldri

n

Endosulfan

4,4

'-D

DE

Chlo

rdane

Chlo

rdane

Hepta

chlo

r

Ald

rin

Hepta

chlo

r

delta-B

HC

beta

-BH

Cgam

ma-B

HC

alp

ha-B

HC

TC

MX

2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00

0

50000

100000

150000

200000

250000

300000

350000

Time


2.6

2

3.4

5

4.0

3 4.1

9

4.7

3 4.8

1

5.4

5

6.6

9

7.1

3

7.4

7 7.5

8

7.9

6

8.2

4

8.9

8

9.4

2 9.5

4

10.2

2

10.4

5 11.2

7

12.5

6

13.0

2

16.8

7D

eca

ch

loro

Endri

n k

et

Meth

oxychl

Endosulfan

Endri

n a

ld4,4

'-D

DT

#

Endosulfan

4,4

'-D

DD

#

Endri

n #

2

Die

ldri

n #

4,4

'-D

DE

#

Endosulfan

Chlo

rdane

Chlo

rdane

Hepta

chlo

r

Ald

rin #

2

Hepta

chlo

rdelta-B

HC

beta

-BH

C #

gam

ma-B

HC

alp

ha-B

HC

TC

MX

#2

2T05691.D 80810825.M Mon Sep 08 13:39:30 2014 SS Page 2


1010.8.

SEMIVOLATILES


Work Order: 4080683




1111.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

CS03614.D

08/25/14 21:02

S4H2610

B4H2204

08/22/14 07:44

Sonication MS

Project:




Soil


Semivolatile Organics - GC/MS - SW 846 8270C


95-94-3 U1,2,4,5-Tetrachlorobenzene ND 0.0444 0.133

122-66-7 U1,2-Diphenylhydrazine ND 0.0140 0.133

58-90-2 U2,3,4,6-Tetrachlorophenol ND 0.00899 0.133

95-95-4 U2,4,5-Trichlorophenol ND 0.00966 0.133


120-83-2 U2,4-Dichlorophenol ND 0.0138 0.133

105-67-9 U2,4-Dimethylphenol ND 0.0213 0.133

51-28-5 U2,4-Dinitrophenol ND 0.0149 0.667

121-14-2 U2,4-Dinitrotoluene ND 0.0210 0.133


91-58-7 U2-Chloronaphthalene ND 0.0208 0.133

95-57-8 U2-Chlorophenol ND 0.0143 0.133

91-57-6 U2-Methylnaphthalene ND 0.0225 0.133

95-48-7 U2-Methylphenol ND 0.0145 0.133

88-74-4 U2-Nitroaniline ND 0.0150 0.133

88-75-5 U2-Nitrophenol ND 0.0269 0.133

91-94-1 U3,3'-Dichlorobenzidine ND 0.0806 0.333

106-44-5 U3+4-Methylphenol ND 0.0208 0.133


534-52-1 U4,6-Dinitro-2-methylphenol ND 0.0192 0.333

101-55-3 U4-Bromophenyl-phenyl ether ND 0.0256 0.133

59-50-7 U4-Chloro-3-methylphenol ND 0.0207 0.133

106-47-8 U4-Chloroaniline ND 0.0178 0.133

7005-72-3 U4-Chlorophenyl phenyl ether ND 0.0156 0.133


100-02-7 U4-Nitrophenol ND 0.0201 0.133

83-32-9 UAcenaphthene ND 0.0172 0.133

208-96-8 UAcenaphthylene ND 0.0196 0.133

98-86-2 UAcetophenone ND 0.0290 0.133

120-12-7 UAnthracene ND 0.0180 0.133

1912-24-9 UAtrazine ND 0.0611 0.133


1111.1.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

CS03614.D

08/25/14 21:02

S4H2610

B4H2204

08/22/14 07:44

Sonication MS

Project:




Soil




100-52-7 UBenzaldehyde ND 0.0410 0.133

92-87-5 UBenzidine ND 0.304 0.333

56-55-3 UBenzo(a)anthracene ND 0.0151 0.133

50-32-8 UBenzo(a)pyrene ND 0.0117 0.133

205-99-2 UBenzo(b)fluoranthene ND 0.0227 0.133

191-24-2 UBenzo(g,h,i)perylene ND 0.0268 0.133

207-08-9 UBenzo(k)fluoranthene ND 0.0244 0.133

100-51-6 UBenzyl alcohol ND 0.0238 0.133

92-52-4 UBiphenyl ND 0.0204 0.133

111-91-1 Ubis(2-chloroethoxy)methane ND 0.0262 0.133

111-44-4 Ubis(2-chloroethyl)ether ND 0.0123 0.133

108-60-1 Ubis(2-chloroisopropyl)ether ND 0.0257 0.133

117-81-7 Ubis(2-ethylhexyl)phthalate ND 0.0170 0.133

85-68-7 UButylbenzylphthalate ND 0.0214 0.133

105-60-2 UCaprolactam ND 0.0122 0.133

86-74-8 UCarbazole ND 0.0200 0.333

218-01-9 UChrysene ND 0.0236 0.133

53-70-3 UDibenzo(a,h)anthracene ND 0.0234 0.133

132-64-9 UDibenzofuran ND 0.0215 0.133

84-66-2 UDiethylphthalate ND 0.0199 0.133

131-11-3 UDimethylphthalate ND 0.0171 0.133

84-74-2 UDi-n-butylphthalate ND 0.0211 0.133

117-84-0 UDi-n-octylphthalate ND 0.0289 0.133

206-44-0 UFluoranthene ND 0.0183 0.133

86-73-7 UFluorene ND 0.0211 0.133

118-74-1 UHexachlorobenzene ND 0.0253 0.133

87-68-3 UHexachlorobutadiene ND 0.0302 0.133

77-47-4 UHexachlorocyclopentadiene ND 0.0327 0.333

67-72-1 UHexachloroethane ND 0.00906 0.133

193-39-5 UIndeno(1,2,3-cd)pyrene ND 0.0274 0.133

78-59-1 UIsophorone ND 0.0308 0.133


1111.1.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

CS03614.D

08/25/14 21:02

S4H2610

B4H2204

08/22/14 07:44

Sonication MS

Project:




Soil




91-20-3 UNaphthalene ND 0.0145 0.133

98-95-3 UNitrobenzene ND 0.0200 0.133

621-64-7 Un-Nitroso-di-n-propylamine ND 0.0176 0.133

86-30-6 Un-Nitrosodiphenylamine ND 0.0200 0.133

87-86-5 UPentachlorophenol ND 0.0117 0.333

85-01-8 UPhenanthrene ND 0.0176 0.133

108-95-2 UPhenol ND 0.0196 0.133

129-00-0 UPyrene ND 0.0168 0.133


1111.1.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

CS03614.D

08/25/14 21:02

S4H2610

B4H2204

08/22/14 07:44

Sonication MS

Project:




Soil



CAS NO. TENTATIVELY IDENTIFIED COMPOUNDS CONC. (mg/kg wet) QRT

000629-62-9 Pentadecane 0.418 J11.1

Sum of Tentatively Identified Compounds 0.42


1111.1.

Quantitation Report (QT/LSC Reviewed)

Data File : G:\HPCHEM\C\DATA\20140825\CS03614.D Vial: 15 Acq On : 25 Aug 2014 21:02 Operator: gch Sample : B4H2204-BLK1 Inst : GCMS-C Misc : Multiplr: 1.00 MS Integration Params: rteint.p

Quant Time: Aug 26 13:01 2014 Quant Results File: 0401ABNS.RES

Quant Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C Last Update : Fri Aug 15 12:32:42 2014 Response via : Initial Calibration DataAcq Meth : RUN8270

Internal Standards R.T. QIon Response Conc Units Dev(Min)------------------------------------------------------------------------- 1) 1,4-Dichlorobenzene-d4 6.27 152 583459 40.00 ug/kg -0.03 19) Naphthalene-d8 8.27 136 2057975 40.00 ug/kg -0.04 36) Acenaphthene-d10 11.04 164 1185421 40.00 ug/kg -0.05 59) Phenanthrene-d10 13.41 188 1917205 40.00 ug/kg -0.05 73) Chrysene-d12 17.56 240 2005391 40.00 ug/kg -0.04 82) Perylene-d12 19.20 264 1760124 40.00 ug/kg -0.04

System Monitoring Compounds 2) 2-Fluorophenol 4.37 112 1551796 68.74 ug/kg -0.08 Spiked Amount 100.000 Range 24 - 97 Recovery = 68.74% 5) Phenol-d6 5.95 99 1578654 61.87 ug/kg -0.03 Spiked Amount 100.000 Range 30 - 92 Recovery = 61.87% 20) Nitrobenzene-d5 7.21 82 607100 24.84 ug/kg -0.02 Spiked Amount 50.000 Range 25 - 93 Recovery = 49.68% 41) 2-Fluorobiphenyl 10.02 172 1570604 32.83 ug/kg -0.05 Spiked Amount 50.000 Range 35 - 92 Recovery = 65.66% 63) 2,4,6-Tribromophenol 12.35 330 287705 57.19 ug/kg -0.04 Spiked Amount 100.000 Range 29 - 105 Recovery = 57.19% 76) p-Terphenyl-d14 16.00 244 1647841 30.29 ug/kg -0.04 Spiked Amount 50.000 Range 27 - 92 Recovery = 60.58%

Target Compounds Qvalue

-------------------------------------------------------------------------(#) = qualifier out of range (m) = manual integrationCS03614.D 0401ABNS.M Tue Aug 26 13:44:16 2014 SS Page 1


1111.1.

Quantitation Report

Data File : G:\HPCHEM\C\DATA\20140825\CS03614.D Vial: 15 Acq On : 25 Aug 2014 21:02 Operator: gch Sample : B4H2204-BLK1 Inst : GCMS-C Misc : Multiplr: 1.00 MS Integration Params: rteint.p Quant Time: Aug 26 13:01 2014 Quant Results File: 0401ABNS.RES

Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C Last Update : Fri Aug 15 12:32:42 2014 Response via : Initial Calibration

4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.000

200000

400000

600000

800000

1000000

1200000

1400000

1600000

1800000

2000000

2200000

2400000

2600000

2800000

3000000

3200000

3400000

3600000

3800000

4000000

4200000

4400000

4600000

4800000

5000000

Time-->

Abundance TIC: CS03614.D

Pery

lene-d

12,I

Chry

sene-d

12,I

p-T

erp

henyl-

d14,S

Phenanth

rene-d

10,I

2,4

,6-T

ribro

mophenol,S

Acenaphth

ene-d

10,I

2-F

luoro

bip

henyl,S

Naphth

ale

ne-d

8,I

Nitro

benzene-d

5,S

1,4

-Dic

hlo

robenzene-d

4,I

Phenol-

d6,S

2-F

luoro

phenol,S

CS03614.D 0401ABNS.M Tue Aug 26 13:44:16 2014 SS Page 2


1111.1.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

CS03622.D

08/26/14 01:25

S4H2610

B4H2204

08/22/14 07:44

Sonication MS

Project:

4080683




1Dilution:


Soil

08/21/14 09:35


Sparta Quarry



95-94-3 U1,2,4,5-Tetrachlorobenzene ND 0.0469 0.140

122-66-7 U1,2-Diphenylhydrazine ND 0.0148 0.140

58-90-2 U2,3,4,6-Tetrachlorophenol ND 0.00950 0.140



120-83-2 U2,4-Dichlorophenol ND 0.0146 0.140

105-67-9 U2,4-Dimethylphenol ND 0.0225 0.140

51-28-5 U2,4-Dinitrophenol ND 0.0158 0.705



91-58-7 U2-Chloronaphthalene ND 0.0220 0.140

95-57-8 U2-Chlorophenol ND 0.0151 0.140

91-57-6 U2-Methylnaphthalene ND 0.0238 0.140

95-48-7 U2-Methylphenol ND 0.0153 0.140


88-75-5 U2-Nitrophenol ND 0.0284 0.140

91-94-1 U3,3'-Dichlorobenzidine ND 0.0851 0.352

106-44-5 U3+4-Methylphenol ND 0.0220 0.140


534-52-1 U4,6-Dinitro-2-methylphenol ND 0.0203 0.352

101-55-3 U4-Bromophenyl-phenyl ether ND 0.0270 0.140

59-50-7 U4-Chloro-3-methylphenol ND 0.0219 0.140

106-47-8 U4-Chloroaniline ND 0.0188 0.140

7005-72-3 U4-Chlorophenyl phenyl ether ND 0.0165 0.140


100-02-7 U4-Nitrophenol ND 0.0212 0.140










1111.2.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

CS03622.D

08/26/14 01:25

S4H2610

B4H2204

08/22/14 07:44

Sonication MS

Project:

4080683




1Dilution:


Soil

08/21/14 09:35


Sparta Quarry



83-32-9 UAcenaphthene ND 0.0182 0.140

208-96-8 UAcenaphthylene ND 0.0207 0.140

98-86-2 UAcetophenone ND 0.0307 0.140

120-12-7 UAnthracene ND 0.0191 0.140

1912-24-9 UAtrazine ND 0.0646 0.140

100-52-7 UBenzaldehyde ND 0.0433 0.140

92-87-5 UBenzidine ND 0.322 0.352

56-55-3 UBenzo(a)anthracene ND 0.0159 0.140

50-32-8 UBenzo(a)pyrene ND 0.0124 0.140

205-99-2 UBenzo(b)fluoranthene ND 0.0240 0.140

191-24-2 UBenzo(g,h,i)perylene ND 0.0284 0.140

207-08-9 UBenzo(k)fluoranthene ND 0.0257 0.140

100-51-6 UBenzyl alcohol ND 0.0252 0.140

92-52-4 UBiphenyl ND 0.0216 0.140

111-91-1 Ubis(2-chloroethoxy)methane ND 0.0277 0.140

111-44-4 Ubis(2-chloroethyl)ether ND 0.0130 0.140

108-60-1 Ubis(2-chloroisopropyl)ether ND 0.0272 0.140

117-81-7 Ubis(2-ethylhexyl)phthalate ND 0.0180 0.140

85-68-7 UButylbenzylphthalate ND 0.0226 0.140

105-60-2 UCaprolactam ND 0.0129 0.140

86-74-8 UCarbazole ND 0.0211 0.352

218-01-9 UChrysene ND 0.0250 0.140

53-70-3 UDibenzo(a,h)anthracene ND 0.0248 0.140

132-64-9 UDibenzofuran ND 0.0227 0.140

84-66-2 UDiethylphthalate ND 0.0210 0.140

131-11-3 UDimethylphthalate ND 0.0181 0.140










1111.2.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

CS03622.D

08/26/14 01:25

S4H2610

B4H2204

08/22/14 07:44

Sonication MS

Project:

4080683




1Dilution:


Soil

08/21/14 09:35


Sparta Quarry



84-74-2 UDi-n-butylphthalate ND 0.0223 0.140

117-84-0 UDi-n-octylphthalate ND 0.0305 0.140

206-44-0 UFluoranthene ND 0.0193 0.140

86-73-7 UFluorene ND 0.0223 0.140

118-74-1 UHexachlorobenzene ND 0.0267 0.140

87-68-3 UHexachlorobutadiene ND 0.0319 0.140

77-47-4 UHexachlorocyclopentadiene ND 0.0345 0.352

67-72-1 UHexachloroethane ND 0.00957 0.140

193-39-5 UIndeno(1,2,3-cd)pyrene ND 0.0289 0.140

78-59-1 UIsophorone ND 0.0325 0.140

91-20-3 UNaphthalene ND 0.0153 0.140

98-95-3 UNitrobenzene ND 0.0212 0.140

621-64-7 Un-Nitroso-di-n-propylamine ND 0.0186 0.140

86-30-6 Un-Nitrosodiphenylamine ND 0.0212 0.140

87-86-5 UPentachlorophenol ND 0.0124 0.352

85-01-8 UPhenanthrene ND 0.0186 0.140

108-95-2 UPhenol ND 0.0208 0.140

129-00-0 UPyrene ND 0.0178 0.140










1111.2.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

CS03622.D

08/26/14 01:25

S4H2610

B4H2204

08/22/14 07:44

Sonication MS

Project:

4080683




1Dilution:


Soil

08/21/14 09:35


Sparta Quarry


CAS NO. TENTATIVELY IDENTIFIED COMPOUNDS CONC. (mg/kg dry) QRT

000112-84-5 Erucylamide 0.510 J18.62

000629-62-9 Pentadecane 0.355 J, B11.1






1111.2.


Data File : G:\HPCHEM\C\DATA\20140825\CS03622.D Vial: 23 Acq On : 26 Aug 2014 1:25 Operator: gch Sample : 4080683-01 Inst : GCMS-C Misc : B4H2204 Multiplr: 1.00 MS Integration Params: rteint.p


Quant Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C Last Update : Fri Aug 15 12:32:42 2014 Response via : Initial Calibration DataAcq Meth : RUN8270


System Monitoring Compounds 2) 2-Fluorophenol 4.37 112 1298222 58.58 ug/kg -0.08 Spiked Amount 100.000 Range 24 - 97 Recovery = 58.58% 5) Phenol-d6 5.96 99 1313184 52.43 ug/kg -0.02 Spiked Amount 100.000 Range 30 - 92 Recovery = 52.43% 20) Nitrobenzene-d5 7.22 82 488756 19.41 ug/kg -0.01 Spiked Amount 50.000 Range 25 - 93 Recovery = 38.82% 41) 2-Fluorobiphenyl 10.02 172 1393367 28.85 ug/kg -0.05 Spiked Amount 50.000 Range 35 - 92 Recovery = 57.70% 63) 2,4,6-Tribromophenol 12.35 330 274376 52.06 ug/kg -0.05 Spiked Amount 100.000 Range 29 - 105 Recovery = 52.06% 76) p-Terphenyl-d14 16.00 244 1590059 27.55 ug/kg -0.05 Spiked Amount 50.000 Range 27 - 92 Recovery = 55.10%




1111.2.

Quantitation Report

Data File : G:\HPCHEM\C\DATA\20140825\CS03622.D Vial: 23 Acq On : 26 Aug 2014 1:25 Operator: gch Sample : 4080683-01 Inst : GCMS-C Misc : B4H2204 Multiplr: 1.00 MS Integration Params: rteint.p Quant Time: Aug 26 13:16 2014 Quant Results File: 0401ABNS.RES


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.000

200000

400000

600000

800000

1000000

1200000

1400000

1600000

1800000

2000000

2200000

2400000

2600000

2800000

3000000

3200000

3400000

3600000

3800000

4000000

4200000

4400000

4600000

Time-->


Pery

lene-d

12,IC

hry

sene-d

12,I

p-T

erp

henyl-

d14,S

Phenanth

rene-d

10,I

2,4

,6-T

ribro

mophenol,S

Acenaphth

ene-d

10,I

2-F

luoro

bip

henyl,S

Naphth

ale

ne-d

8,I

Nitro

benzene-d

5,S

1,4

-Dic

hlo

robenzene-d

4,I

Phenol-

d6,S

2-F

luoro

phenol,S



1111.2.

SURROGATE RECOVERIESAnalysis Class: SEMIVOLATILES

Method:

File ID

Matrix: Soil

Lab Number 2FP PHN-D6 TBPNBZ FPB TER-D14

SW 846 8270C

4080683-01 CS03622.D 38.8 57.7 55.1 58.6 52.4 52.1

B4H2204-BLK1 CS03614.D 49.7 65.7 60.6 68.7 61.9 57.2



2FP

PHN-D6

TBP

NBZ

FPB

TER-D14

Nitrobenzene-d5

2-Fluorobiphenyl

p-Terphenyl-d14

2-Fluorophenol

Phenol-d6

2,4,6-Tribromophenol

25 93

35

27

24

30

29

92

92

97

92

105


1111.3.

Semivolatile Organics - GC/MS - Quality Control


Batch B4H2204 Prepared: 08/22/2014Method: SW 846 8270C

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source3.33 56-12175.1mg/kg wet2,4-DinitrotolueneB4H2204-BS1 2.50

3.33 38-11061.5mg/kg wet2-ChlorophenolB4H2204-BS1 2.05

3.33 57-11562.6mg/kg wet4-Chloro-3-methylphenolB4H2204-BS1 2.09

3.33 50-104102mg/kg wet4-NitrophenolB4H2204-BS1 3.41

3.33 59-11570.8mg/kg wetAcenaphthyleneB4H2204-BS1 2.36

3.33 46-13664.9mg/kg wetn-Nitroso-di-n-propylamineB4H2204-BS1 2.16

3.33 47-10777.7mg/kg wetPentachlorophenolB4H2204-BS1 2.59

3.33 40-10160.6mg/kg wetPhenolB4H2204-BS1 2.02

3.33 41-11179.9mg/kg wetPyreneB4H2204-BS1 2.66

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source3.52 50-9993.2mg/kg dry2,4-DinitrotolueneB4H2204-MS1 4080683-01 ND3.28

3.52 37-9269.6mg/kg dry2-ChlorophenolB4H2204-MS1 4080683-01 ND2.45

3.52 46-9272.6mg/kg dry4-Chloro-3-methylphenolB4H2204-MS1 4080683-01 ND2.56

3.52 29-12868.3mg/kg dry4-NitrophenolB4H2204-MS1 4080683-01 ND2.41

3.52 48-10481.6mg/kg dryAcenaphthyleneB4H2204-MS1 4080683-01 ND2.87

3.52 38-12383.2mg/kg dryn-Nitroso-di-n-propylamineB4H2204-MS1 4080683-01 ND2.93

3.52 22-7856.5mg/kg dryPentachlorophenolB4H2204-MS1 4080683-01 ND1.99

3.52 28-9869.8mg/kg dryPhenolB4H2204-MS1 4080683-01 ND2.46

3.52 45-10593.1mg/kg dryPyreneB4H2204-MS1 4080683-01 ND3.28

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source3.52 2550-9982.9 11.7mg/kg dry2,4-DinitrotolueneB4H2204-MSD1 4080683-01 ND2.92

3.52 2537-9259.6 15.5mg/kg dry2-ChlorophenolB4H2204-MSD1 4080683-01 ND2.10

3.52 2546-9263.3 13.7mg/kg dry4-Chloro-3-methylphenolB4H2204-MSD1 4080683-01 ND2.23

3.52 2529-12859.4 13.9mg/kg dry4-NitrophenolB4H2204-MSD1 4080683-01 ND2.09

3.52 2548-10472.8 11.5mg/kg dryAcenaphthyleneB4H2204-MSD1 4080683-01 ND2.56

3.52 2538-12371.9 14.5mg/kg dryn-Nitroso-di-n-propylamineB4H2204-MSD1 4080683-01 ND2.53

3.52 2522-7856.8 0.459mg/kg dryPentachlorophenolB4H2204-MSD1 4080683-01 ND2.00

3.52 2528-9858.9 16.9mg/kg dryPhenolB4H2204-MSD1 4080683-01 ND2.07

3.52 2545-10585.2 8.84mg/kg dryPyreneB4H2204-MSD1 4080683-01 ND3.00




1111.4.


B4H2204Batch ID:


B4H2204-BLK1 BLK1 8/22/2014

B4H2204-BS1 BS1 8/22/2014

B4H2204-MS1 MS1 8/22/2014

B4H2204-MSD1 MSD1 8/22/2014

4080683-01 QUARRY FINES 8/22/2014


1111.5.

INSTRUMENT PERFORMANCE CHECK

Work Order:

Injection Date:

Project:

Instrument ID:

Lab File ID:

Client:

Injection Time:

CS01611.D

GCMS-C

Sequence: S4D0406

Lab Sample ID: S4D0406-TUN1

4080683

04/01/2014

14:48


Sparta Quarry

m/z ION ABUNDANCE CRITERIA % RELATIVE ABUNDANCE PASS/FAIL

51 5030 - 60% of 198 PASS

68 0Less than 2% of 69 PASS

69 41.6Less than 100% of 198 PASS


127 46.940 - 60% of 198 PASS


198 100Base peak, 100% relative abundance PASS

199 7.725 - 9% of 198 PASS

275 27.310 - 30% of 198 PASS

365 2.111 - 100% of 198 PASS

441 850.01 - 99.9% of 443 PASS

442 48.640 - 100% of 198 PASS

443 19.617 - 23% of 442 PASS

Samples Associated with Tune

Client ID Sample ID File ID Date Analyzed Time Analyzed

Cal Standard S4D0406-CAL1 CS01612.D 04/01/2014 15:09.00









1111.6.

DFTPP

Data File : G:\HPCHEM\C\DATA\04012014\CS01611.D Vial: 2 Acq On : 1 Apr 2014 14:48 Operator: gch Sample : SEQ-TUN Inst : GCMS-C Misc : Multiplr: 1.00 MS Integration Params: rteint.p Method : G:\HPCHEM\9\METHODS\0403ABNW.M (RTE Integrator) Title : ABN's by EPA Method 625

2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.000

200000

400000

600000

800000

1000000

1200000

1400000

1600000

1800000

Time-->


20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 440 460 480 500 520 5400

20000

40000

60000

80000

100000

120000

140000

160000

180000

m/z-->

Abundance Average of 4.164 to 4.175 min.: CS01611.D (-)198

255

51 44277 127

275110

224

29616793148 365323 423346240 40236 383182 512488465 531

Spectrum Information: Average of 4.164 to 4.175 min.

| Target | Rel. to | Lower | Upper | Rel. | Raw | Result || Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |----------------------------------------------------------------------| 51 | 198 | 30 | 60 | 50.0 | 92597 | PASS || 68 | 69 | 0.00 | 2 | 0.0 | 0 | PASS || 69 | 198 | 0.00 | 100 | 41.6 | 77016 | PASS || 70 | 69 | 0.00 | 2 | 0.5 | 365 | PASS || 127 | 198 | 40 | 60 | 46.9 | 86944 | PASS || 197 | 198 | 0.00 | 1 | 0.0 | 0 | PASS || 198 | 198 | 100 | 100 | 100.0 | 185195 | PASS || 199 | 198 | 5 | 9 | 7.7 | 14291 | PASS || 275 | 198 | 10 | 30 | 27.3 | 50525 | PASS || 365 | 198 | 1 | 100 | 2.1 | 3908 | PASS || 441 | 443 | 0.01 | 100 | 85.0 | 15011 | PASS || 442 | 198 | 40 | 100 | 48.6 | 90048 | PASS || 443 | 442 | 17 | 23 | 19.6 | 17664 | PASS |----------------------------------------------------------------------

CS01611.D 0403ABNW.M Thu Apr 10 10:57:49 2014 SS


1111.6.


Work Order:

Injection Date:

Project:

Instrument ID:

Lab File ID:

Client:

Injection Time:

CS03601.D

GCMS-C

Sequence: S4H2610

Lab Sample ID: S4H2610-TUN1

4080683

08/25/2014

14:07


Sparta Quarry


51 35.430 - 60% of 198 PASS




127 4240 - 60% of 198 PASS



199 6.925 - 9% of 198 PASS

275 19.610 - 30% of 198 PASS

365 1.381 - 100% of 198 PASS

441 72.80.01 - 99.9% of 443 PASS

442 60.440 - 100% of 198 PASS

443 19.917 - 23% of 442 PASS



Calibration Check S4H2610-CCV1 CS03602.D 08/25/2014 14:24.00

LCS B4H2204-BS1 CS03613.D 08/25/2014 20:29.00

Blank B4H2204-BLK1 CS03614.D 08/25/2014 21:02.00

QUARRY FINES 4080683-01 CS03622.D 08/26/2014 1:25.00


1111.6.

DFTPP

Data File : G:\HPCHEM\C\DATA\20140825\CS03601.D Vial: 2 Acq On : 25 Aug 2014 14:07 Operator: gch Sample : SEQ-TUN Inst : GCMS-C Misc : Multiplr: 1.00 MS Integration Params: rteint.p Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C

1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.600

200000

400000

600000

800000

1000000

1200000

1400000

Time-->


20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 440 460 480 500 520 540 5600

10000

20000

30000

40000

50000

60000

70000

80000

m/z-->

Abundance Average of 3.778 to 3.813 min.: CS03601.D198

442

25577 127

51

110

275

224

167 296 42393 323 36514836 346 403182 239 383 525 549



CS03601.D 0401ABNS.M Tue Aug 26 13:43:28 2014 SS


1111.6.


Work Order:

Injection Date:

Project:

Instrument ID:

Lab File ID:

Client:

Injection Time:

CS03624.D

GCMS-C

Sequence: S4H2712


4080683

08/26/2014

3:17


Sparta Quarry


51 32.930 - 60% of 198 PASS




127 42.940 - 60% of 198 PASS



199 7.235 - 9% of 198 PASS

275 21.410 - 30% of 198 PASS

365 1.061 - 100% of 198 PASS

441 68.30.01 - 99.9% of 443 PASS

442 75.240 - 100% of 198 PASS

443 20.217 - 23% of 442 PASS



Calibration Check S4H2712-CCV1 CS03625.D 08/26/2014 3:34.00

Matrix Spike B4H2204-MS1 CS03628.D 08/26/2014 5:11.00

Matrix Spike Dup B4H2204-MSD1 CS03629.D 08/26/2014 5:43.00


1111.6.

DFTPP

Data File : G:\HPCHEM\C\DATA\20140825\CS03624.D Vial: 2 Acq On : 26 Aug 2014 3:17 Operator: gch Sample : SEQ-TUN Inst : GCMS-C Misc : Multiplr: 1.00 MS Integration Params: rteint.p Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C

2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.600

200000

400000

600000

800000

1000000

1200000

1400000

1600000

Time-->


40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 440 460 4800

20000

40000

60000

80000

100000

120000

140000

160000

180000

m/z-->

Abundance Average of 3.806 to 3.817 min.: CS03624.D (-)198

442

255127

77

51

110275

224

167 296 42393 180148 323 365211 242 3526438 403383310 338 479463



CS03624.D 0401ABNS.M Wed Aug 27 23:33:38 2014 SS


1111.6.

Response Factor Report GCMS-C

Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C Last Update : Mon Apr 07 09:59:54 2014 Response via : Initial Calibration

Calibration Files 5 =CS01613.D 10 =CS01614.D 20 =CS01615.D 50 =CS01634.D 60 =CS01618.D 80 =CS01619.D

Compound 5 10 20 50 60 80 Avg %RSD-------------------------------------------------------------------------

1) I 1,4-Dichlorobenzene-d ----------------ISTD---------------------- 2) S 2-Fluorophenol 1.498 1.439 1.704 1.628 1.513 1.543 1.548 5.77 3) Benzaldehyde 0.746 0.692 0.546 0.568 0.536 0.584 0.647 18.79 4) Aniline 0.684 0.821 0.607 0.636 0.651 0.722 0.687 11.19 5) S Phenol-d6 1.556 1.611 1.852 1.797 1.722 1.722 1.749 8.30 6) M C Phenol 1.884 1.690 2.043 1.889 1.831 1.841 1.874 5.74 7) bis(2-Chloroethyl)e 1.516 1.283 1.694 1.807 1.568 1.526 1.594 11.22 8) M 2-Chlorophenol 1.579 1.408 1.583 1.473 1.390 1.393 1.479 5.76 9) 1,3-Dichlorobenzene 1.914 1.649 1.844 1.634 1.536 1.512 1.731 11.52 10) M C 1,4-Dichlorobenzene 1.952 1.762 1.787 1.594 1.564 1.533 1.785 15.29 11) Benzyl Alcohol 0.807 0.780 0.725 0.735 0.785 0.806 0.775 4.20 12) 1,2-Dichlorobenzene 1.703 1.570 1.707 1.532 1.477 1.434 1.604 8.53 13) 2-Methylphenol 1.404 1.247 1.530 1.202 1.184 1.179 1.339 13.69 14) bis(2-Chloroisoprop 3.251 2.834 3.167 2.819 2.685 2.566 2.981 11.73 15) Acetophenone 1.987 1.912 2.110 1.909 1.837 1.803 1.925 5.25 16) 3+4-Methylphenol 1.612 1.254 1.435 1.355 1.292 1.265 1.405 11.24 17) M P n-Nitroso-di-n-prop 0.112 0.128 0.139 0.147 0.137 0.151 0.135 9.86 18) Hexachloroethane 0.762 0.661 0.677 0.621 0.589 0.590 0.675 13.26

19) I Naphthalene-d8 ----------------ISTD---------------------- 20) S Nitrobenzene-d5 0.506 0.445 0.533 0.446 0.440 0.440 0.475 8.68 21) Nitrobenzene 0.497 0.421 0.478 0.421 0.403 0.404 0.433 8.80 22) Isophorone 0.843 0.736 0.835 0.698 0.679 0.673 0.769 12.49 23) C 2-Nitrophenol 0.190 0.177 0.246 0.219 0.221 0.215 0.208 11.73 24) 2,4-Dimethylphenol 0.442 0.379 0.401 0.325 0.317 0.311 0.357 14.22 25) bis(2-Chloroethoxy) 0.447 0.449 0.515 0.441 0.428 0.423 0.448 6.99 26) C 2,4-Dichlorophenol 0.344 0.288 0.352 0.298 0.310 0.307 0.310 9.29 27) Benzoic Acid 0.133 0.165 0.202 0.183 0.185 0.195 0.177 14.19 28) M 1,2,4-Trichlorobenz 0.405 0.362 0.397 0.336 0.326 0.328 0.369 11.32 29) Naphthalene 1.388 1.172 1.262 1.025 0.982 0.933 1.184 18.63 30) 2,6-Dichlorophenol 0.360 0.322 0.342 0.305 0.301 0.306 0.331 9.13 31) 4-Chloroaniline 0.297 0.255 0.268 0.178 0.174 0.182 0.233 22.88 32) C Hexachlorobutadiene 0.269 0.227 0.247 0.210 0.205 0.192 0.236 16.14 33) Caprolactam 0.100 0.094 0.107 0.103 0.100 0.097 0.102 6.07 34) M C 4-Chloro-3-methylph 0.317 0.275 0.384 0.326 0.316 0.323 0.332 11.80 35) 2-Methylnaphthalene 0.995 0.849 0.900 0.758 0.720 0.683 0.853 16.86

36) I Acenaphthene-d10 ----------------ISTD---------------------- 37) P Hexachlorocyclopent 0.205 0.110 0.178 0.202 0.200 0.204 0.183 20.23 38) 1,2,4,5-Tetrachloro 0.383 0.362 0.378 0.313 0.311 0.313 0.356 12.95 39) C 2,4,6-Trichlorophen 0.423 0.378 0.424 0.367 0.375 0.353 0.395 8.68 40) 2,4,5-Trichlorophen 0.349 0.329 0.412 0.364 0.373 0.349 0.381 14.21 41) S 2-Fluorobiphenyl 1.783 1.739 1.790 1.419 1.379 1.291 1.614 15.04 42) Biphenyl 1.861 1.640 1.708 1.357 1.320 1.224 1.589 18.69 43) 2-Chloronaphthalene 1.315 1.229 1.287 1.068 1.023 1.007 1.193 13.57 44) 2-Nitroaniline 0.383 0.409 0.450 0.415 0.412 0.420 0.424 7.52 45) Dimethylphthalate 1.475 1.373 1.520 1.285 1.246 1.213 1.404 12.76 46) Acenaphthylene 2.044 1.770 1.900 1.545 1.504 1.401 1.796 19.75 47) 2,6-Dinitrotoluene 0.310 0.271 0.343 0.302 0.300 0.284 0.305 8.06 48) 3-Nitroaniline 0.075 0.075 0.070 0.050 0.050 0.055 0.064 18.61 49) M C Acenaphthene 1.430 1.351 1.401 1.125 1.110 1.062 1.312 17.58 50) P 2,4-Dinitrophenol 0.085 0.038 0.058 0.098 0.107 0.125 0.085 37.78 51) Dibenzofuran 1.937 1.765 1.947 1.550 1.502 1.404 1.741 14.95 52) M P 4-Nitrophenol 0.111 0.136 0.095 0.129 0.135 0.130 0.123 13.50 53) M 2,4-Dinitrotoluene 0.350 0.361 0.400 0.401 0.396 0.390 0.361 16.71 54) 2,3,4,6-Tetrachloro 0.234 0.229 0.303 0.249 0.270 0.246 0.260 10.83 55) Fluorene 1.582 1.399 1.554 1.264 1.234 1.163 1.422 15.34 56) Diethylphthalate 1.457 1.298 1.417 1.186 1.153 1.080 1.332 16.88 57) 4-Chlorophenyl phen 0.789 0.712 0.773 0.657 0.637 0.611 0.727 14.48

0401ABNS.M Thu Apr 10 12:32:17 2014 SS Page 1(#) = Out of Range ### Number of calibration levels exceeded format ###


1111.7.

Response Factor Report GCMS-C

Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C Last Update : Mon Apr 07 09:59:54 2014 Response via : Initial Calibration

Calibration Files 5 =CS01613.D 10 =CS01614.D 20 =CS01615.D 50 =CS01634.D 60 =CS01618.D 80 =CS01619.D

Compound 5 10 20 50 60 80 Avg %RSD-------------------------------------------------------------------------

58) 4-Nitroaniline 0.103 0.084 0.098 0.099 0.098 0.083 0.093 9.28

59) I Phenanthrene-d10 ----------------ISTD---------------------- 60) 4,6-Dinitro-2-methy 0.144 0.071 0.123 0.133 0.136 0.141 0.125 21.80 61) n-Nitrosodiphenylam 0.601 0.597 0.602 0.481 0.453 0.444 0.547 15.55 62) 1,2-Diphenylhydrazi 1.053 0.951 1.003 0.821 0.767 0.791 0.938 16.29 63) S 2,4,6-Tribromopheno 0.093 0.097 0.126 0.109 0.098 0.103 0.105 10.56 64) 4-Bromophenyl-pheny 0.264 0.257 0.287 0.230 0.225 0.218 0.254 11.98 65) Hexachlorobenzene 0.306 0.266 0.287 0.236 0.222 0.223 0.271 18.67 66) Atrazine 0.148 0.126 0.111 0.066 0.071 0.152 0.112 33.11 67) M C Pentachlorophenol 0.052 0.060 0.083 0.086 0.084 0.091 0.076 20.94 68) Phenanthrene 1.439 1.243 1.360 1.068 0.995 0.964 1.238 19.47 69) Anthracene 1.449 1.263 1.411 1.131 1.035 0.985 1.260 17.29 70) Carbazole 0.343 0.240 0.256 0.282 0.257 0.245 0.270 14.15 71) Di-n-butylphthalate 1.529 1.407 1.537 1.237 1.161 1.093 1.391 17.42 72) C Fluoranthene 1.590 1.353 1.465 1.183 1.118 1.077 1.331 15.58

73) I Chrysene-d12 ----------------ISTD---------------------- 74) Benzidine 0.018 0.017 0.015 0.016 0.017 0.015 0.016 8.78 75) M Pyrene 1.450 1.299 1.495 1.217 1.149 1.141 1.336 13.62 76) S p-Terphenyl-d14 1.215 1.042 1.230 1.004 0.955 0.924 1.085 12.45 77) Butylbenzylphthalat 0.621 0.593 0.680 0.598 0.566 0.558 0.615 8.44 78) Benzo(a)anthracene 1.279 1.175 1.325 1.090 1.046 1.032 1.206 14.03 79) 3,3'-Dichlorobenzid 0.264 0.217 0.222 0.202 0.206 0.219 0.222 10.04 80) Chrysene 1.463 1.206 1.347 1.106 1.050 1.021 1.266 18.93 81) bis(2-Ethylhexyl)ph 0.935 0.826 0.978 0.826 0.778 0.756 0.867 10.61

82) I Perylene-d12 ----------------ISTD---------------------- 83) C Di-n-octylphthalate 1.506 1.378 1.496 1.207 1.115 1.008 1.344 18.26 84) Benzo(b)fluoranthen 1.284 1.293 1.339 1.189 1.144 1.176 1.265 8.10 85) Benzo(k)fluoranthen 1.558 1.221 1.364 1.037 1.068 0.955 1.276 22.64 86) C Benzo(a)pyrene 1.355 1.249 1.357 1.089 1.024 0.993 1.219 15.21 87) Indeno(1,2,3-cd)pyr 1.781 1.648 1.759 1.449 1.381 1.341 1.620 14.66 88) Dibenzo(a,h)anthrac 1.499 1.357 1.439 1.189 1.150 1.119 1.334 13.83 89) Benzo(g,h,i)perylen 1.520 1.394 1.527 1.300 1.245 1.226 1.416 12.35

0401ABNS.M Thu Apr 10 12:32:18 2014 SS Page 2(#) = Out of Range ### Number of calibration levels exceeded format ###


1111.7.

Compound List Report GCMS-C

Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C Last Update : Mon Apr 07 09:59:54 2014 Response via : Initial Calibration Total Cpnds : 89

PK# Compound Name QIon Exp_RT Rel_RT Cal #Qual A/H ID -------------------------------------------------------------------------- 1 I 1,4-Dichlorobenzene-d4 152 6.80 1.000 A 2 A B 2 S 2-Fluorophenol 112 4.86 0.714 A 3 A B 3 Benzaldehyde 77 6.15 0.905 A 3 A B 4 Aniline 93 6.32 0.929 A 2 A B 5 S Phenol-d6 99 6.39 0.940 A 2 A B 6 M C Phenol 94 6.41 0.943 A 2 A B 7 bis(2-Chloroethyl)ether 93 6.45 0.948 A 2 A B 8 M 2-Chlorophenol 128 6.51 0.957 A 2 A B 9 1,3-Dichlorobenzene 146 6.71 0.987 A 3 A B 10 M C 1,4-Dichlorobenzene 146 6.82 1.003 A 3 A B 11 Benzyl Alcohol 108 7.10 1.044 A 2 A B 12 1,2-Dichlorobenzene 146 7.06 1.038 A 3 A B 13 2-Methylphenol 108 7.33 1.078 A 2 A B 14 bis(2-Chloroisopropyl)ether 45 7.29 1.072 A 2 A B 15 Acetophenone 105 7.48 1.100 A 2 A B 16 3+4-Methylphenol 108 7.59 1.116 A 2 A B 17 M P n-Nitroso-di-n-propylamine 70 7.51 1.104 A 2 A B 18 Hexachloroethane 117 7.56 1.112 A 3 A B

19 I Naphthalene-d8 136 8.80 1.000 A 3 A B 20 S Nitrobenzene-d5 82 7.71 0.875 A 2 A B 21 Nitrobenzene 77 7.74 0.879 A 2 A B 22 Isophorone 82 8.12 0.923 A 2 A B 23 C 2-Nitrophenol 139 8.24 0.936 A 2 A B 24 2,4-Dimethylphenol 107 8.39 0.953 A 3 A B 25 bis(2-Chloroethoxy)methane 93 8.50 0.966 A 2 A B 26 C 2,4-Dichlorophenol 162 8.66 0.984 A 2 A B 27 Benzoic Acid 105 8.75 0.994 A 2 A B 28 M 1,2,4-Trichlorobenzene 180 8.73 0.992 A 2 A B 29 Naphthalene 128 8.83 1.003 A 3 A B 30 2,6-Dichlorophenol 162 8.99 1.021 A 2 A B 31 4-Chloroaniline 127 9.15 1.039 A 2 A B 32 C Hexachlorobutadiene 225 9.05 1.028 A 3 A B 33 Caprolactam 113 9.63 1.094 A 2 A B 34 M C 4-Chloro-3-methylphenol 107 9.87 1.121 A 2 A B 35 2-Methylnaphthalene 142 9.95 1.130 A 2 A B

36 I Acenaphthene-d10 164 11.59 1.000 A 2 A B 37 P Hexachlorocyclopentadiene 237 10.20 0.879 A 2 A B 38 1,2,4,5-Tetrachlorobenzene 216 10.23 0.882 A 2 A B 39 C 2,4,6-Trichlorophenol 196 10.47 0.903 A 3 A B 40 2,4,5-Trichlorophenol 196 10.56 0.911 A 3 A B 41 S 2-Fluorobiphenyl 172 10.56 0.911 A 2 A B 42 Biphenyl 154 10.71 0.924 A 2 A B 43 2-Chloronaphthalene 162 10.73 0.925 A 2 A B 44 2-Nitroaniline 138 10.97 0.946 A 2 A B 45 Dimethylphthalate 163 11.26 0.971 A 2 A B 46 Acenaphthylene 152 11.37 0.980 A 2 A B 47 2,6-Dinitrotoluene 165 11.35 0.979 A 2 A B 48 3-Nitroaniline 138 11.68 1.008 A 2 A B 49 M C Acenaphthene 153 11.65 1.005 A 2 A B 50 P 2,4-Dinitrophenol 184 11.85 1.022 QO 1 A B 51 Dibenzofuran 168 11.94 1.029 A 2 A B 52 M P 4-Nitrophenol 65 12.09 1.043 A 2 A B 53 M 2,4-Dinitrotoluene 165 12.02 1.036 A 2 A B 54 2,3,4,6-Tetrachlorophenol 232 12.19 1.051 A 2 A B 55 Fluorene 166 12.48 1.077 A 2 A B 56 Diethylphthalate 149 12.39 1.068 A 2 A B 57 4-Chlorophenyl phenyl ether 204 12.51 1.079 A 2 A B 58 4-Nitroaniline 138 12.69 1.094 A 2 A B

59 I Phenanthrene-d10 188 13.97 1.000 A 2 A B 60 4,6-Dinitro-2-methylphenol 198 12.68 0.908 LO 2 A B 61 n-Nitrosodiphenylamine 169 12.72 0.911 A 2 A B 62 1,2-Diphenylhydrazine 77 12.76 0.914 A 2 A B 63 S 2,4,6-Tribromophenol 330 12.89 0.923 A 2 A B

0401ABNS.M Thu Apr 10 12:33:19 2014 Page 1


1111.7.

64 4-Bromophenyl-phenyl ether 248 13.28 0.951 A 2 A B 65 Hexachlorobenzene 284 13.37 0.958 A 2 A B 66 Atrazine 200 13.63 0.976 QO 2 A B 67 M C Pentachlorophenol 266 13.73 0.983 A 2 A B 68 Phenanthrene 178 14.01 1.003 A 2 A B 69 Anthracene 178 14.09 1.009 A 2 A B 70 Carbazole 167 14.41 1.032 A 2 A B 71 Di-n-butylphthalate 149 15.01 1.074 A 2 A B 72 C Fluoranthene 202 15.91 1.139 A 2 A B

73 I Chrysene-d12 240 18.05 1.000 A 2 A B 74 Benzidine 184 16.24 0.899 A 2 A B 75 M Pyrene 202 16.26 0.901 A 2 A B 76 S p-Terphenyl-d14 244 16.56 0.918 A 2 A B 77 Butylbenzylphthalate 149 17.35 0.961 A 2 A B 78 Benzo(a)anthracene 228 18.03 0.999 A 2 A B 79 3,3'-Dichlorobenzidine 252 18.04 0.999 A 2 A B 80 Chrysene 228 18.08 1.002 A 2 A B 81 bis(2-Ethylhexyl)phthalate 149 18.14 1.005 A 2 A B

82 I Perylene-d12 264 19.67 1.000 A 2 A B 83 C Di-n-octylphthalate 149 18.87 0.959 A 1 A B 84 Benzo(b)fluoranthene 252 19.26 0.979 A 3 A B 85 Benzo(k)fluoranthene 252 19.29 0.981 QO 3 A B 86 C Benzo(a)pyrene 252 19.61 0.997 A 3 A B 87 Indeno(1,2,3-cd)pyrene 276 21.08 1.071 A 2 A B 88 Dibenzo(a,h)anthracene 278 21.08 1.071 A 2 A B 89 Benzo(g,h,i)perylene 276 21.46 1.091 A 2 A B

Cal A = Average L = Linear LO = Linear w/origin Q = Quad QO = Quad w/origin #Qual = number of qualifiers A/H = Area or Height ID R = R.T. B = R.T. & Q Q = Qvalue L = Largest A = All -------------------------------------------------------------------------- 0401ABNS.M Thu Apr 10 12:33:18 2014 SS

0401ABNS.M Thu Apr 10 12:33:19 2014 Page 2


1111.7.


S4H2610-CCV1 8/25/14 14:24

SW 846 8270C

Factor result Limit(s)Analyte

Response

result

Expected

CCV ID: Analyzed:

% Drift1,2,4,5-Tetrachlorobenzene 44.780.3187976 50.00 10

1,2-Diphenylhydrazine 43.240.8109831 50.00 14

2,3,4,6-Tetrachlorophenol 48.390.2516068 50.00 3

2,4,5-Trichlorophenol 51.380.3910047 50.00 3

2,4,6-Trichlorophenol 50.730.4002628 30 (CCC) 50.00 1

2,4-Dichlorophenol 44.850.2278638 30 (CCC) 50.00 10

2,4-Dimethylphenol 46.360.3307844 50.00 7

2,4-Dinitrophenol 50.029.567303E-02 0.05 (SPCC) 50.00 0

2,4-Dinitrotoluene 56.970.4117559 50.00 14

2,6-Dinitrotoluene 50.300.3072982 50.00 1

2-Chloronaphthalene 42.551.015615 50.00 15

2-Chlorophenol 48.821.444281 50.00 2

2-Methylnaphthalene 73.660.8357151 75.20 2

2-Methylphenol 49.061.314164 50.00 2

2-Nitroaniline 52.530.4457731 50.00 5

2-Nitrophenol 53.690.2494617 30 (CCC) 50.00 7

3+4-Methylphenol 48.611.366213 50.00 3

3-Nitroaniline 42.845.977223E-02 50.00 14

4,6-Dinitro-2-methylphenol 54.720.1506244 50.00 9

4-Bromophenyl-phenyl ether 42.890.2175497 50.00 14

4-Chloro-3-methylphenol 46.180.3067933 30 (CCC) 50.00 8

4-Chloroaniline 53.960.1966727 50.00 8

4-Chlorophenyl phenyl ether 40.140.5836672 50.00 20

4-Nitroaniline 49.169.121121E-02 50.00 2

4-Nitrophenol 34.368.430126E-02 0.05 (SPCC) 50.00 31

Acenaphthene 47.211.039126 30 (CCC) 50.00 6

Acenaphthylene 42.341.521209 50.00 15

Acetophenone 43.941.691786 50.00 12

Anthracene 47.171.189058 50.00 6

Atrazine 51.087.491727E-02 50.00 2

Benzaldehyde 41.500.5368985 50.00 17

Benzo(a)anthracene 48.641.173064 50.00 3

Benzo(a)pyrene 50.621.046719 30 (CCC) 50.00 1

Benzo(b)fluoranthene 46.551.094748 50.00 7

Benzo(g,h,i)perylene 48.801.22659 50.00 2

Benzo(k)fluoranthene 43.460.9509188 50.00 13

Benzyl alcohol 58.570.9074683 50.00 17

Biphenyl 47.031.218454 50.00 6

bis(2-chloroethoxy)methane 50.840.4551085 50.00 2

bis(2-chloroethyl)ether 54.211.727907 50.00 8

bis(2-chloroisopropyl)ether 43.042.298058 50.00 14

bis(2-ethylhexyl)phthalate 51.540.8937612 50.00 3

Butylbenzylphthalate 55.010.6763329 50.00 10

Caprolactam 43.258.812643E-02 50.00 14

Carbazole 49.350.3708413 50.00 1

Chrysene 47.261.196771 50.00 5

Dibenzo(a,h)anthracene 44.751.032351 50.00 11


1111.8.


S4H2610-CCV1 8/25/14 14:24

SW 846 8270C


Response

result

Expected

CCV ID: Analyzed:

% DriftDibenzofuran 45.891.598265 50.00 8

Diethylphthalate 40.741.085561 50.00 19

Dimethylphthalate 43.291.215638 50.00 13

Di-n-butylphthalate 45.431.263912 50.00 9

Di-n-octylphthalate 48.821.473393 30 (CCC) 50.00 2

Fluoranthene 45.541.212383 30 (CCC) 50.00 9

Fluorene 42.021.195533 50.00 16

Hexachlorobenzene 43.240.1970317 50.00 14

Hexachlorobutadiene 48.660.173865 30 (CCC) 50.00 3

Hexachlorocyclopentadiene 43.160.1582153 0.05 (SPCC) 50.00 14

Hexachloroethane 44.780.5368228 50.00 10

Indeno(1,2,3-cd)pyrene 43.941.220819 50.00 12

Isophorone 45.940.7063213 50.00 8

Naphthalene 41.280.9772187 50.00 17

Nitrobenzene 49.720.4306904 50.00 1

n-Nitroso-di-n-propylamine 59.280.1596629 0.05 (SPCC) 50.00 19

n-Nitrosodiphenylamine 40.710.4456253 30 (CCC) 50.00 19

Pentachlorophenol 45.196.889896E-02 30 (CCC) 50.00 10

Phenanthrene 43.951.088573 50.00 12

Phenol 49.751.86413 30 (CCC) 50.00 1

Pyrene 54.681.461539 50.00 9


1111.8.


Data File : G:\HPCHEM\C\DATA\20140825\CS03602.D Vial: 3 Acq On : 25 Aug 2014 14:24 Operator: gch Sample : SEQ-CCV Inst : GCMS-C Misc : Multiplr: 1.00 MS Integration Params: rteint.p


Quant Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C Last Update : Tue Aug 26 13:21:02 2014 Response via : Initial Calibration DataAcq Meth : RUN8270


System Monitoring Compounds 2) 2-Fluorophenol 4.37 112 1269259 50.04 ug/kg -0.07 Spiked Amount 100.000 Range 24 - 97 Recovery = 50.04% 5) Phenol-d6 5.93 99 1561181 54.46 ug/kg -0.06 Spiked Amount 100.000 Range 30 - 92 Recovery = 54.46% 20) Nitrobenzene-d5 7.19 82 1120123 43.06 ug/kg -0.04 Spiked Amount 50.000 Range 25 - 93 Recovery = 86.12% 41) 2-Fluorobiphenyl 10.03 172 2118402 41.25 ug/kg -0.04 Spiked Amount 50.000 Range 35 - 92 Recovery = 82.50% 63) 2,4,6-Tribromophenol 12.36 330 243278 49.67 ug/kg -0.04 Spiked Amount 100.000 Range 29 - 105 Recovery = 49.67% 76) p-Terphenyl-d14 16.01 244 2146393 47.18 ug/kg -0.04 Spiked Amount 50.000 Range 27 - 92 Recovery = 94.36%#

Target Compounds Qvalue 3) Benzaldehyde 5.64 77 439942 41.50 ug/kg 68 4) Aniline 5.92 93 493999m 43.88 ug/kg 6) Phenol 5.95 94 1527494 49.75 ug/kg 83 7) bis(2-Chloroethyl)ether 5.93 93 1415871 54.21 ug/kg# 55 8) 2-Chlorophenol 6.00 128 1183464 48.82 ug/kg 87 9) 1,3-Dichlorobenzene 6.17 146 1344331 47.38 ug/kg 97 10) 1,4-Dichlorobenzene 6.28 146 1331768 45.52 ug/kg 98 11) Benzyl Alcohol 6.62 108 743592 58.57 ug/kg 91 12) 1,2-Dichlorobenzene 6.52 146 1302613 49.55 ug/kg 95 13) 2-Methylphenol 6.87 108 1076844 49.06 ug/kg 95 14) bis(2-Chloroisopropyl)ethe 6.77 45 1883060 43.04 ug/kg 94 15) Acetophenone 6.98 105 1386273 43.94 ug/kg 96 16) 3+4-Methylphenol 7.14 108 1119494 48.61 ug/kg 94 17) n-Nitroso-di-n-propylamine 7.02 70 130830 59.28 ug/kg 73 18) Hexachloroethane 7.01 117 439880 44.78 ug/kg# 76 21) Nitrobenzene 7.22 77 1179073 49.72 ug/kg 71 22) Isophorone 7.62 82 1933650 45.94 ug/kg# 83 23) 2-Nitrophenol 7.73 139 682935 53.69 ug/kg 68 24) 2,4-Dimethylphenol 7.92 107 905567 46.36 ug/kg 83 25) bis(2-Chloroethoxy)methane 8.00 93 1245921 50.84 ug/kg 76 26) 2,4-Dichlorophenol 8.20 162 623808 44.85 ug/kg 97 27) Benzoic Acid 8.46 105 632499m 65.24 ug/kg 28) 1,2,4-Trichlorobenzene 8.21 180 942833 46.64 ug/kg 96 29) Naphthalene 8.30 128 2675268 41.28 ug/kg 95 30) 2,6-Dichlorophenol 8.49 162 867265 47.93 ug/kg 94 31) 4-Chloroaniline 8.64 127 538418m 53.96 ug/kg 32) Hexachlorobutadiene 8.52 225 475979 48.66 ug/kg 99 33) Caprolactam 9.22 113 241258 43.25 ug/kg 94 34) 4-Chloro-3-methylphenol 9.43 107 839888 46.18 ug/kg 95 35) 2-Methylnaphthalene 9.42 142 3440976 73.66 ug/kg 84 37) Hexachlorocyclopentadiene 9.66 237 251658 43.16 ug/kg 97 38) 1,2,4,5-Tetrachlorobenzene 9.71 216 507081 44.78 ug/kg 97 39) 2,4,6-Trichlorophenol 9.97 196 636660 50.73 ug/kg 99 40) 2,4,5-Trichlorophenol 10.11 196 621934 51.38 ug/kg 95 42) Biphenyl 10.18 154 1938079 47.03 ug/kg 86 43) 2-Chloronaphthalene 10.20 162 1615442 42.55 ug/kg 92-------------------------------------------------------------------------(#) = qualifier out of range (m) = manual integrationCS03602.D 0401ABNS.M Tue Aug 26 13:43:52 2014 SS Page 1


1111.8.




Quant Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C Last Update : Tue Aug 26 13:21:02 2014 Response via : Initial Calibration DataAcq Meth : RUN8270

Compound R.T. QIon Response Conc Unit Qvalue------------------------------------------------------------------------- 44) 2-Nitroaniline 10.49 138 709049 52.53 ug/kg 95 45) Dimethylphthalate 10.75 163 1933600 43.29 ug/kg 79 46) Acenaphthylene 10.82 152 2419642 42.34 ug/kg 97 47) 2,6-Dinitrotoluene 10.87 165 488790 50.30 ug/kg# 46 48) 3-Nitroaniline 11.26 138 95074 42.84 ug/kg 92 49) Acenaphthene 11.11 153 1652839 47.21 ug/kg 94 50) 2,4-Dinitrophenol 11.41 184 152178m 50.02 ug/kg 51) Dibenzofuran 11.39 168 2542208 45.89 ug/kg 98 52) 4-Nitrophenol 11.77 65 134090m 34.36 ug/kg 53) 2,4-Dinitrotoluene 11.54 165 654941 56.97 ug/kg 93 54) 2,3,4,6-Tetrachlorophenol 11.68 232 400207 48.39 ug/kg 99 55) Fluorene 11.94 166 1901621 42.02 ug/kg 96 56) Diethylphthalate 11.88 149 1726698 40.74 ug/kg# 87 57) 4-Chlorophenyl phenyl ethe 11.96 204 928384 40.14 ug/kg 73 58) 4-Nitroaniline 12.35 138 145081m 49.16 ug/kg 60) 4,6-Dinitro-2-methylphenol 12.22 198 351439 54.72 ug/kg# 41 61) n-Nitrosodiphenylamine 12.19 169 1039739 40.71 ug/kg 92 62) 1,2-Diphenylhydrazine 12.22 77 1892197 43.24 ug/kg# 79 64) 4-Bromophenyl-phenyl ether 12.73 248 507590 42.89 ug/kg 74 65) Hexachlorobenzene 12.83 284 459717 43.24 ug/kg 98 66) Atrazine 13.12 200 174798m 51.08 ug/kg 67) Pentachlorophenol 13.23 266 160756 45.19 ug/kg 99 68) Phenanthrene 13.46 178 2539873 43.95 ug/kg 98 69) Anthracene 13.54 178 2774326 47.17 ug/kg 98 70) Carbazole 13.93 167 865252m 49.35 ug/kg 71) Di-n-butylphthalate 14.47 149 2948978 45.43 ug/kg 97 72) Fluoranthene 15.35 202 2828748 45.54 ug/kg 94 74) Benzidine 16.01 184 25915 37.82 ug/kg# 93 75) Pyrene 15.69 202 3063299 54.68 ug/kg 92 77) Butylbenzylphthalate 16.83 149 1417554 55.01 ug/kg# 78 78) Benzo(a)anthracene 17.56 228 2458673 48.64 ug/kg 94 79) 3,3'-Dichlorobenzidine 17.59 252 465874 50.14 ug/kg 95 80) Chrysene 17.61 228 2508362 47.26 ug/kg 93 81) bis(2-Ethylhexyl)phthalate 17.68 149 1873271 51.54 ug/kg 99 83) Di-n-octylphthalate 18.44 149 3088146 48.82 ug/kg 98 84) Benzo(b)fluoranthene 18.84 252 2575550 46.55 ug/kg 94 85) Benzo(k)fluoranthene 18.87 252 2237172m 43.46 ug/kg 86) Benzo(a)pyrene 19.15 252 2462556 50.62 ug/kg 93 87) Indeno(1,2,3-cd)pyrene 20.42 276 2872151 43.94 ug/kg# 89 88) Dibenzo(a,h)anthracene 20.41 278 2428752 44.75 ug/kg 94 89) Benzo(g,h,i)perylene 20.75 276 2885727 48.80 ug/kg 97



1111.8.

Quantitation Report

Data File : G:\HPCHEM\C\DATA\20140825\CS03602.D Vial: 3 Acq On : 25 Aug 2014 14:24 Operator: gch Sample : SEQ-CCV Inst : GCMS-C Misc : Multiplr: 1.00 MS Integration Params: rteint.p Quant Time: Aug 26 13:22 2014 Quant Results File: 0401ABNS.RES


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

Time-->


Benzo(g

,h,i)p

ery

lene

Indeno(1

,2,3

-cd)p

yre

ne

Dib

enzo(a

,h)a

nth

racene

Pery

lene-d

12,I

Benzo(a

)pyre

ne,C

Benzo(k

)flu

ora

nth

ene

Benzo(b

)flu

ora

nth

ene

Di-

n-o

cty

lphth

ala

te,C

bis

(2-E

thylh

exyl)phth

ala

teC

hry

sene

3,3

'-D

ichlo

robenzid

ine

Chry

sene-d

12,I

Benzo(a

)anth

racene

Buty

lbenzylp

hth

ala

te

Benzid

ine

p-T

erp

henyl-

d14,S

Pyre

ne,M

Flu

ora

nth

ene,C

Di-

n-b

uty

lphth

ala

te

Carb

azole

Anth

racene

Phenanth

rene

Phenanth

rene-d

10,I

Penta

chlo

rophenol,M

CA

trazin

e

Hexachlo

robenzene

4-B

rom

ophenyl-

phenyl eth

er

2,4

,6-T

ribro

mophenol,S

4-N

itro

anili

ne

1,2

-Dip

henylh

ydra

zin

e4,6

-Din

itro

-2-m

eth

ylp

henol

n-N

itro

sodip

henyla

min

e4-C

hlo

rophenyl phenyl eth

er

Flu

ore

ne

Die

thylp

hth

ala

te4-N

itro

phenol,M

P2,3

,4,6

-Tetr

achlo

rophenol

2,4

-Din

itro

tolu

ene,M

2,4

-Din

itro

phenol,P

Dib

enzofu

ran

3-N

itro

anili

ne

Acenaphth

ene,M

CA

cenaphth

ene-d

10,I

2,6

-Din

itro

tolu

ene

Acenaphth

yle

ne

Dim

eth

ylp

hth

ala

te

2-N

itro

anili

ne

2-C

hlo

ronaphth

ale

ne

Bip

henyl

2,4

,5-T

richlo

rophenol

2-F

luoro

bip

henyl,S

2,4

,6-T

richlo

rophenol,C

1,2

,4,5

-Tetr

achlo

robenzene

Hexachlo

rocyclo

penta

die

ne,P

4-C

hlo

ro-3

-meth

ylp

henol,M

C2-M

eth

yln

aphth

ale

ne

Capro

lacta

m

4-C

hlo

roanili

ne

Hexachlo

robuta

die

ne,C

2,6

-Dic

hlo

rophenol

Benzoic

Acid

Naphth

ale

ne

Naphth

ale

ne-d

8,I

1,2

,4-T

richlo

robenzene,M

2,4

-Dic

hlo

rophenol,C

bis

(2-C

hlo

roeth

oxy)m

eth

ane

2,4

-Dim

eth

ylp

henol

2-N

itro

phenol,C

Isophoro

ne

Nitro

benzene

Nitro

benzene-d

5,S

3+

4-M

eth

ylp

henol

n-N

itro

so-d

i-n-p

ropyla

min

e,M

PH

exachlo

roeth

ane

Aceto

phenone

2-M

eth

ylp

henol

bis

(2-C

hlo

rois

opro

pyl)

eth

er

Benzyl A

lcohol

1,2

-Dic

hlo

robenzene

1,4

-Dic

hlo

robenzene,M

C1,4

-Dic

hlo

robenzene-d

4,I

1,3

-Dic

hlo

robenzene

2-C

hlo

rophenol,M

Phenol,M

Cbis

(2-C

hlo

roeth

yl)

eth

er

Phenol-

d6,S

Anili

ne

Benzald

ehyde

2-F

luoro

phenol,S



1111.8.


S4H2712-CCV1 8/26/14 3:34

SW 846 8270C


Response

result

Expected

CCV ID: Analyzed:

% Drift1,2,4,5-Tetrachlorobenzene 44.550.3172049 50.00 11

1,2-Diphenylhydrazine 44.530.8351571 50.00 11

2,3,4,6-Tetrachlorophenol 51.970.2701778 50.00 4

2,4,5-Trichlorophenol 50.240.382352 50.00 0

2,4,6-Trichlorophenol 50.840.4011561 30 (CCC) 50.00 2

2,4-Dichlorophenol 43.640.2707463 30 (CCC) 50.00 13

2,4-Dimethylphenol 48.830.3484352 50.00 2

2,4-Dinitrophenol 18.372.343245E-02 0.05 (SPCC) 50.00 63

2,4-Dinitrotoluene 52.280.3778859 50.00 5

2,6-Dinitrotoluene 49.580.3028891 50.00 1

2-Chloronaphthalene 44.551.063228 50.00 11

2-Chlorophenol 50.031.479996 50.00 0

2-Methylnaphthalene 76.900.8723899 75.20 2

2-Methylphenol 50.501.352809 50.00 1

2-Nitroaniline 51.490.4369596 50.00 3

2-Nitrophenol 51.110.2123162 30 (CCC) 50.00 2

3+4-Methylphenol 48.691.368358 50.00 3

3-Nitroaniline 59.568.761434E-02 50.00 19

4,6-Dinitro-2-methylphenol 33.513.570968E-02 50.00 33

4-Bromophenyl-phenyl ether 43.400.220164 50.00 13

4-Chloro-3-methylphenol 46.460.3087045 30 (CCC) 50.00 7

4-Chloroaniline 54.810.2555998 50.00 10

4-Chlorophenyl phenyl ether 42.140.6127845 50.00 16

4-Nitroaniline 51.249.507002E-02 50.00 2

4-Nitrophenol 36.608.978805E-02 0.05 (SPCC) 50.00 27

Acenaphthene 40.831.071647 30 (CCC) 50.00 18

Acenaphthylene 43.581.565555 50.00 13

Acetophenone 45.681.758903 50.00 9

Anthracene 48.951.233849 50.00 2

Atrazine 59.768.764407E-02 50.00 20

Benzaldehyde 51.250.6630762 50.00 3

Benzo(a)anthracene 50.241.21164 50.00 0

Benzo(a)pyrene 44.601.087482 30 (CCC) 50.00 11

Benzo(b)fluoranthene 42.631.078699 50.00 15

Benzo(g,h,i)perylene 34.080.8566601 50.00 32

Benzo(k)fluoranthene 54.101.136942 50.00 8

Benzyl alcohol 59.740.9255794 50.00 19

Biphenyl 41.261.311115 50.00 17

bis(2-chloroethoxy)methane 50.130.4487171 50.00 0

bis(2-chloroethyl)ether 50.951.623951 50.00 2

bis(2-chloroisopropyl)ether 43.772.336952 50.00 12

bis(2-ethylhexyl)phthalate 51.940.9006112 50.00 4

Butylbenzylphthalate 56.550.695256 50.00 13

Caprolactam 54.900.1118594 50.00 10

Carbazole 54.690.2958297 50.00 9

Chrysene 47.311.19795 50.00 5

Dibenzo(a,h)anthracene 37.010.8537627 50.00 26


1111.8.


S4H2712-CCV1 8/26/14 3:34

SW 846 8270C


Response

result

Expected

CCV ID: Analyzed:

% DriftDibenzofuran 47.471.653234 50.00 5

Diethylphthalate 43.011.146217 50.00 14

Dimethylphthalate 44.231.242033 50.00 12

Di-n-butylphthalate 46.631.297161 50.00 7

Di-n-octylphthalate 55.161.541094 30 (CCC) 50.00 10

Fluoranthene 47.261.258285 30 (CCC) 50.00 5

Fluorene 44.421.263677 50.00 11

Hexachlorobenzene 43.790.1995715 50.00 12

Hexachlorobutadiene 45.870.176494 30 (CCC) 50.00 8

Hexachlorocyclopentadiene 18.212.897159E-02 0.05 (SPCC) 50.00 64

Hexachloroethane 45.100.4466444 50.00 10

Indeno(1,2,3-cd)pyrene 35.420.9839351 50.00 29

Isophorone 45.300.6964667 50.00 9

Naphthalene 42.681.010409 50.00 15

Nitrobenzene 48.690.4218023 50.00 3

n-Nitroso-di-n-propylamine 55.340.1490512 0.05 (SPCC) 50.00 11

n-Nitrosodiphenylamine 51.780.566762 30 (CCC) 50.00 4

Pentachlorophenol 48.140.07339 30 (CCC) 50.00 4

Phenanthrene 44.781.109003 50.00 10

Phenol 49.531.855959 30 (CCC) 50.00 1

Pyrene 54.581.458892 50.00 9


1111.8.




Quant Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C Last Update : Wed Aug 27 23:05:13 2014 Response via : Initial Calibration DataAcq Meth : RUN8270


System Monitoring Compounds 2) 2-Fluorophenol 4.41 112 1043168 50.16 ug/kg -0.04 Spiked Amount 100.000 Range 24 - 97 Recovery = 50.16% 5) Phenol-d6 5.93 99 1324557 56.35 ug/kg -0.05 Spiked Amount 100.000 Range 30 - 92 Recovery = 56.35% 20) Nitrobenzene-d5 7.19 82 938361 43.20 ug/kg -0.04 Spiked Amount 50.000 Range 25 - 93 Recovery = 86.40% 41) 2-Fluorobiphenyl 10.03 172 1820535 43.16 ug/kg -0.04 Spiked Amount 50.000 Range 35 - 92 Recovery = 86.32% 63) 2,4,6-Tribromophenol 12.35 330 210221 50.07 ug/kg -0.04 Spiked Amount 100.000 Range 29 - 105 Recovery = 50.07% 76) p-Terphenyl-d14 16.00 244 1880104 47.20 ug/kg -0.04 Spiked Amount 50.000 Range 27 - 92 Recovery = 94.40%#

Target Compounds Qvalue 3) Benzaldehyde 5.63 77 445501 51.25 ug/kg 69 4) Aniline 5.80 93 1095194m 89.44 ug/kg 6) Phenol 5.96 94 1246963 49.53 ug/kg 80 7) bis(2-Chloroethyl)ether 5.93 93 1091084 50.95 ug/kg 58 8) 2-Chlorophenol 6.00 128 994365 50.03 ug/kg 86 9) 1,3-Dichlorobenzene 6.16 146 1099908 47.28 ug/kg 98 10) 1,4-Dichlorobenzene 6.29 146 1083802 45.18 ug/kg 98 11) Benzyl Alcohol 6.62 108 621869 59.74 ug/kg 92 12) 1,2-Dichlorobenzene 6.52 146 1059828 49.16 ug/kg 95 13) 2-Methylphenol 6.86 108 908912 50.50 ug/kg 94 14) bis(2-Chloroisopropyl)ethe 6.77 45 1570128 43.77 ug/kg 93 15) Acetophenone 6.97 105 1181754 45.68 ug/kg 97 16) 3+4-Methylphenol 7.14 108 919359 48.69 ug/kg# 89 17) n-Nitroso-di-n-propylamine 7.01 70 100143 55.34 ug/kg 79 18) Hexachloroethane 7.00 117 300087 45.10 ug/kg# 76 21) Nitrobenzene 7.22 77 964268 48.69 ug/kg 73 22) Isophorone 7.62 82 1592169 45.30 ug/kg# 83 23) 2-Nitrophenol 7.73 139 485369 51.11 ug/kg 69 24) 2,4-Dimethylphenol 7.92 107 796546 48.83 ug/kg 82 25) bis(2-Chloroethoxy)methane 8.00 93 1025797 50.13 ug/kg 78 26) 2,4-Dichlorophenol 8.20 162 618944 43.64 ug/kg 94 27) Benzoic Acid 8.40 105 374637m 46.27 ug/kg 28) 1,2,4-Trichlorobenzene 8.21 180 805037 47.69 ug/kg 98 29) Naphthalene 8.30 128 2309863 42.68 ug/kg 95 30) 2,6-Dichlorophenol 8.49 162 713125 47.19 ug/kg 94 31) 4-Chloroaniline 8.58 127 584318m 54.81 ug/kg 32) Hexachlorobutadiene 8.51 225 403477 45.87 ug/kg 99 33) Caprolactam 9.21 113 255718 54.90 ug/kg 97 34) 4-Chloro-3-methylphenol 9.43 107 705719 46.46 ug/kg 98 35) 2-Methylnaphthalene 9.42 142 2999489 76.90 ug/kg 84 37) Hexachlorocyclopentadiene 9.65 237 37852 18.21 ug/kg 93 38) 1,2,4,5-Tetrachlorobenzene 9.70 216 414435 44.55 ug/kg 98 39) 2,4,6-Trichlorophenol 9.97 196 524119 50.84 ug/kg 98 40) 2,4,5-Trichlorophenol 10.10 196 499551 50.24 ug/kg 97 42) Biphenyl 10.17 154 1713000 41.26 ug/kg 86 43) 2-Chloronaphthalene 10.19 162 1389130 44.55 ug/kg 92-------------------------------------------------------------------------(#) = qualifier out of range (m) = manual integrationCS03625.D 0401ABNS.M Wed Aug 27 23:34:21 2014 SS Page 1


1111.8.




Quant Method : G:\HPCHEM\C\METHODS\0401ABNS.M (RTE Integrator) Title : BNA Extractables GC/MS 8270C Last Update : Wed Aug 27 23:05:13 2014 Response via : Initial Calibration DataAcq Meth : RUN8270

Compound R.T. QIon Response Conc Unit Qvalue------------------------------------------------------------------------- 44) 2-Nitroaniline 10.47 138 570897 51.49 ug/kg 98 45) Dimethylphthalate 10.74 163 1622742 44.23 ug/kg 80 46) Acenaphthylene 10.82 152 2045431 43.58 ug/kg 97 47) 2,6-Dinitrotoluene 10.86 165 395731 49.58 ug/kg# 46 48) 3-Nitroaniline 11.21 138 114470m 59.56 ug/kg 49) Acenaphthene 11.10 153 1400129 40.83 ug/kg 94 50) 2,4-Dinitrophenol 11.64 184 30615m 18.37 ug/kg 51) Dibenzofuran 11.39 168 2159986 47.47 ug/kg 98 52) 4-Nitrophenol 11.77 65 117310m 36.60 ug/kg 53) 2,4-Dinitrotoluene 11.54 165 493716 52.28 ug/kg 92 54) 2,3,4,6-Tetrachlorophenol 11.68 232 352993 51.97 ug/kg 93 55) Fluorene 11.93 166 1651021 44.42 ug/kg 96 56) Diethylphthalate 11.87 149 1497557 43.01 ug/kg 88 57) 4-Chlorophenyl phenyl ethe 11.96 204 800616 42.14 ug/kg 73 58) 4-Nitroaniline 12.33 138 124211m 51.24 ug/kg 60) 4,6-Dinitro-2-methylphenol 12.24 198 71414m 33.51 ug/kg 61) n-Nitrosodiphenylamine 12.19 169 1133439 51.78 ug/kg 89 62) 1,2-Diphenylhydrazine 12.22 77 1670189 44.53 ug/kg# 76 64) 4-Bromophenyl-phenyl ether 12.72 248 440295 43.40 ug/kg 73 65) Hexachlorobenzene 12.82 284 399113 43.79 ug/kg 99 66) Atrazine 13.11 200 175275 59.76 ug/kg 88 67) Pentachlorophenol 13.22 266 146769 48.14 ug/kg 93 68) Phenanthrene 13.45 178 2217839 44.78 ug/kg 97 69) Anthracene 13.53 178 2467513 48.95 ug/kg 95 70) Carbazole 13.89 167 591615 54.69 ug/kg 96 71) Di-n-butylphthalate 14.46 149 2594128 46.63 ug/kg 96 72) Fluoranthene 15.34 202 2516381 47.26 ug/kg 94 74) Benzidine 15.77 184 22379m 37.30 ug/kg 75) Pyrene 15.69 202 2677160 54.58 ug/kg 92 77) Butylbenzylphthalate 16.83 149 1275839 56.55 ug/kg# 78 78) Benzo(a)anthracene 17.55 228 2223437 50.24 ug/kg 94 79) 3,3'-Dichlorobenzidine 17.58 252 456396m 56.11 ug/kg 80) Chrysene 17.61 228 2198315 47.31 ug/kg 93 81) bis(2-Ethylhexyl)phthalate 17.68 149 1652679 51.94 ug/kg 98 83) Di-n-octylphthalate 18.43 149 2828005 55.16 ug/kg 97 84) Benzo(b)fluoranthene 18.83 252 2056930 42.63 ug/kg 92 85) Benzo(k)fluoranthene 18.86 252 2167993 54.10 ug/kg 92 86) Benzo(a)pyrene 19.15 252 2073678 44.60 ug/kg 92 87) Indeno(1,2,3-cd)pyrene 20.40 276 1876229 35.42 ug/kg# 88 88) Dibenzo(a,h)anthracene 20.39 278 1628008 37.01 ug/kg 90 89) Benzo(g,h,i)perylene 20.73 276 1633533 34.08 ug/kg 97

-------------------------------------------------------------------------(#) = qualifier out of range (m) = manual integrationCS03625.D 0401ABNS.M Wed Aug 27 23:34:21 2014 SS Page 2


1111.8.

Quantitation Report

Data File : G:\HPCHEM\C\DATA\20140825\CS03625.D Vial: 3 Acq On : 26 Aug 2014 3:34 Operator: gch Sample : SEQ-CCV Inst : GCMS-C Misc : Multiplr: 1.00 MS Integration Params: rteint.p Quant Time: Aug 27 23:07 2014 Quant Results File: 0401ABNS.RES


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.000

200000

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1000000

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2000000

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2400000

2600000

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3000000

3200000

3400000

3600000

3800000

4000000

4200000

4400000

4600000

4800000

5000000

5200000

5400000

5600000

5800000

6000000

6200000

Time-->


Benzo(g

,h,i)p

ery

lene

Indeno(1

,2,3

-cd)p

yre

ne

Dib

enzo(a

,h)a

nth

racene

Pery

lene-d

12,I

Benzo(a

)pyre

ne,C

Benzo(k

)flu

ora

nth

ene

Benzo(b

)flu

ora

nth

ene

Di-

n-o

cty

lphth

ala

te,C

bis

(2-E

thylh

exyl)phth

ala

teC

hry

sene

3,3

'-D

ichlo

robenzid

ine

Chry

sene-d

12,I

Benzo(a

)anth

racene

Buty

lbenzylp

hth

ala

te

p-T

erp

henyl-

d14,S

Benzid

ine

Pyre

ne,M

Flu

ora

nth

ene,C

Di-

n-b

uty

lphth

ala

te

Carb

azole

Anth

racene

Phenanth

rene

Phenanth

rene-d

10,I

Penta

chlo

rophenol,M

CAtr

azin

e

Hexachlo

robenzene

4-B

rom

ophenyl-

phenyl eth

er

2,4

,6-T

ribro

mophenol,S

4-N

itro

anili

ne

4,6

-Din

itro

-2-m

eth

ylp

henol

1,2

-Dip

henylh

ydra

zin

en-N

itro

sodip

henyla

min

e4-C

hlo

rophenyl phenyl eth

er

Flu

ore

ne

Die

thylp

hth

ala

te4-N

itro

phenol,M

P2,3

,4,6

-Tetr

achlo

rophenol

2,4

-Din

itro

phenol,P

2,4

-Din

itro

tolu

ene,M

Dib

enzofu

ran

3-N

itro

anili

ne

Acenaphth

ene,M

CA

cenaphth

ene-d

10,I

2,6

-Din

itro

tolu

ene

Acenaphth

yle

ne

Dim

eth

ylp

hth

ala

te

2-N

itro

anili

ne

2-C

hlo

ronaphth

ale

ne

Bip

henyl

2,4

,5-T

richlo

rophenol

2-F

luoro

bip

henyl,S

2,4

,6-T

richlo

rophenol,C

1,2

,4,5

-Tetr

achlo

robenzene

Hexachlo

rocyclo

penta

die

ne,P

4-C

hlo

ro-3

-meth

ylp

henol,M

C2-M

eth

yln

aphth

ale

ne

Capro

lacta

m

4-C

hlo

roanili

ne

Hexachlo

robuta

die

ne,C

2,6

-Dic

hlo

rophenol

Benzoic

Acid

Naphth

ale

ne

Naphth

ale

ne-d

8,I

1,2

,4-T

richlo

robenzene,M

2,4

-Dic

hlo

rophenol,C

bis

(2-C

hlo

roeth

oxy)m

eth

ane

2,4

-Dim

eth

ylp

henol

2-N

itro

phenol,C

Isophoro

ne

Nitro

benzene

Nitro

benzene-d

5,S

3+

4-M

eth

ylp

henol

n-N

itro

so-d

i-n-p

ropyla

min

e,M

PH

exachlo

roeth

ane

Aceto

phenone

2-M

eth

ylp

henol

bis

(2-C

hlo

rois

opro

pyl)

eth

er

Benzyl A

lcohol

1,2

-Dic

hlo

robenzene

1,4

-Dic

hlo

robenzene,M

C1,4

-Dic

hlo

robenzene-d

4,I

1,3

-Dic

hlo

robenzene

2-C

hlo

rophenol,M

Phenol,M

CP

henol-

d6,S

bis

(2-C

hlo

roeth

yl)

eth

er

Anili

ne

Benzald

ehyde

2-F

luoro

phenol,S

CS03625.D 0401ABNS.M Wed Aug 27 23:34:21 2014 SS Page 3


1111.8.

INTERNAL STANDARD REPORT

RtAreaRtAreaRtAreaRtAreaRtAreaArea Rt

Analysis Batch: S4H2610Analysis Class: SEMIVOLATILES

File IDLab Number

PER-D12CHR-D12PHE-D10ACE-D10DCB-D4 NAP-D8

B4H2204-BLK1 CS03614.D 6.27 8.27 11.04 13.41 17.56 19.2583459 17601242005391191720511854212057975

4080683-01 CS03622.D 6.27 8.26 11.04 13.41 17.56 19.2572727 17505722127045200859511967452120516

Reference Std ID

RT Limit

0.50

0.50

0.50

0.50

0.50

0.50

Ref RT

19.2

17.57

13.41

11.05

8.27

6.26

941,057.00 - 3,764,228.00

838,376.50 - 3,353,506.00

933,285.50 - 3,733,142.00

636,242.00 - 2,544,968.00

1,095,054.00 - 4,380,216.00

327,765.50 - 1,311,062.00

1882114

1676753

1272484

2190108

655531

Area LimitRef AreaInternal Standard

DCB-D4

Perylene-d12PER-D12

Chrysene-d12CHR-D12

Phenanthrene-d10PHE-D10

Acenaphthene-d10ACE-D10

Naphthalene-d8NAP-D8

1,4-Dichlorobenzene-d4

1866571

S4H2610-CCV1



1111.9.

VOLATILES


Work Order: 4080683




1212.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

1V10665.D

08/28/14 14:54

S4H2807

B4H2829

08/28/14 14:54

PURGE & TRAP SOIL EPA 5035A

Project:




Soil


Volatile Organics - GC/MS - SW 846 8260B


71-55-6 U1,1,1-Trichloroethane ND 0.00131 0.00500

79-34-5 U1,1,2,2-Tetrachloroethane ND 0.000820 0.00500

76-13-1 U1,1,2-Trichloro-1,2,2 Trifluoroethane ND 0.00105 0.00500


75-34-3 U1,1-Dichloroethane ND 0.000720 0.00500

75-35-4 U1,1-Dichloroethene ND 0.000850 0.00500

87-61-6 U1,2,3-Trichlorobenzene ND 0.000550 0.00500


96-12-8 U1,2-Dibromo-3-chloropropane ND 0.00151 0.00500

106-93-4 U1,2-Dibromoethane ND 0.000610 0.00500

95-50-1 U1,2-Dichlorobenzene ND 0.000440 0.00500


78-87-5 U1,2-Dichloropropane ND 0.000510 0.00500



78-93-3 U2-Butanone ND 0.00416 0.00500

591-78-6 U2-Hexanone ND 0.00294 0.00500

108-10-1 U4-Methyl-2-pentanone ND 0.00160 0.00500

67-64-1 UAcetone ND 0.00340 0.0400

71-43-2 UBenzene ND 0.000670 0.00500

74-97-5 UBromochloromethane ND 0.000680 0.00500

75-27-4 UBromodichloromethane ND 0.00142 0.00500

75-25-2 UBromoform ND 0.000840 0.00500

74-83-9 UBromomethane ND 0.000890 0.00500

75-15-0 UCarbon disulfide ND 0.000360 0.00500

56-23-5 UCarbon Tetrachloride ND 0.000890 0.00500

108-90-7 UChlorobenzene ND 0.000310 0.00500

124-48-1 UChlorodibromomethane ND 0.000600 0.00500

75-00-3 UChloroethane ND 0.00177 0.00500

67-66-3 UChloroform ND 0.00121 0.00500

74-87-3 UChloromethane ND 0.000680 0.00500


1212.1.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

1V10665.D

08/28/14 14:54

S4H2807

B4H2829

08/28/14 14:54


Project:




Soil




156-59-2 Ucis-1,2-Dichloroethene ND 0.000740 0.00500

10061-01-5 Ucis-1,3-Dichloropropene ND 0.000480 0.00500

110-82-7 UCyclohexane ND 0.00107 0.00500

75-71-8 UDichlorodifluoromethane ND 0.00106 0.00500

100-41-4 UEthylBenzene ND 0.000280 0.00500

98-82-8 UIsopropylbenzene ND 0.000170 0.00500

179601-23-1 Um+p-Xylenes ND 0.000710 0.0100

79-20-9 UMethyl Acetate ND 0.00120 0.00500

1634-04-4 UMethyl tert-Butyl Ether ND 0.000780 0.00500

108-87-2 UMethylcyclohexane ND 0.000820 0.00500

75-09-2 UMethylene Chloride ND 0.00288 0.0400

95-47-6 Uo-Xylene ND 0.000240 0.00500

100-42-5 UStyrene ND 0.000240 0.00500

75-65-0 Utert-Butyl alcohol ND 0.00928 0.0500

127-18-4 UTetrachloroethene ND 0.000190 0.00500

108-88-3 UToluene ND 0.000180 0.00500

TOT-XYL UTotal Xylenes ND 0.000240 0.00500

156-60-5 Utrans-1,2-Dichloroethene ND 0.000700 0.00500

10061-02-6 Utrans-1,3-Dichloropropene ND 0.000630 0.00500

79-01-6 UTrichloroethene ND 0.000280 0.00500

75-69-4 UTrichlorofluoromethane ND 0.000990 0.00500

75-01-4 UVinyl chloride ND 0.000540 0.00500


1212.1.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

1V10665.D

08/28/14 14:54

S4H2807

B4H2829

08/28/14 14:54


Project:




Soil



CAS NO. TENTATIVELY IDENTIFIED COMPOUNDS CONC. (mg/kg wet) QRT



1212.1.


Data File : G:\HPCHEM\1\DATA\08282014\1V10665.D Vial: 24 Acq On : 28 Aug 2014 14:54 Operator: omd Sample : B4H2829-BLK1 Inst : GCMS-1 Misc : soil Multiplr: 1.00 MS Integration Params: RTEINT.P

Quant Time: Sep 2 13:06 2014 Quant Results File: 0328WC1.RES

Quant Method : G:\HPCHEM\1\METHODS\0328WC1.M (RTE Integrator) Title : VOC's by EPA Method 8260 Last Update : Thu May 29 15:49:59 2014 Response via : Initial Calibration DataAcq Meth : VOCRUN1

Internal Standards R.T. QIon Response Conc Units Dev(Min)------------------------------------------------------------------------- 1) Pentafluorobenzene 6.72 168 708382 50.00 ug/kg 0.03 33) 1,4-Difluorobenzene 8.22 114 1363754 50.00 ug/kg 0.02 52) Chlorobenzene-d5 13.44 82 734355 50.00 ug/kg 0.00 74) 1,4-Dichlorobenzene-d4 17.43 152 657253 50.00 ug/kg 0.02

System Monitoring Compounds 26) Dibromofluoromethane 6.57 113 509460 58.74 ug/kg 0.01 Spiked Amount 50.000 Range 59 - 147 Recovery = 117.48% 43) Toluene-d8 10.90 98 1476021 49.95 ug/kg 0.05 Spiked Amount 50.000 Range 66 - 134 Recovery = 99.90% 62) 4-Bromofluorobenzene 15.50 95 720682 53.61 ug/kg 0.01 Spiked Amount 50.000 Range 64 - 125 Recovery = 107.22%


-------------------------------------------------------------------------(#) = qualifier out of range (m) = manual integration1V10665.D 0328WC1.M Tue Sep 02 15:15:06 2014 SS Page 1


1212.1.

Quantitation Report

Data File : G:\HPCHEM\1\DATA\08282014\1V10665.D Vial: 24 Acq On : 28 Aug 2014 14:54 Operator: omd Sample : B4H2829-BLK1 Inst : GCMS-1 Misc : soil Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Sep 2 13:06 2014 Quant Results File: 0328WC1.RES

Method : G:\HPCHEM\1\METHODS\0328WC1.M (RTE Integrator) Title : VOC's by EPA Method 8260 Last Update : Thu May 29 15:49:59 2014 Response via : Initial Calibration

2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00

0

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

1700000

1800000

Time-->

Abundance TIC: 1V10665.D

1,4

-Dic

hlo

robenzene-d

4,I

4-B

rom

ofluoro

benzene,S

Chlo

robenzene-d

5,I

Tolu

ene-d

8,S

1,4

-Diflu

oro

benzene,I

Penta

fluoro

benzene,I

Dib

rom

ofluoro

meth

ane,S

1V10665.D 0328WC1.M Tue Sep 02 15:15:07 2014 SS Page 2


1212.1.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

1V10675.D

08/28/14 19:59

S4H2807

B4H2829

08/28/14 19:59


Project:

4080683




1Dilution:


Soil

08/21/14 09:35


Sparta Quarry




79-34-5 U1,1,2,2-Tetrachloroethane ND 0.000866 0.00528

76-13-1 U1,1,2-Trichloro-1,2,2 Trifluoroethane ND 0.00111 0.00528



75-35-4 U1,1-Dichloroethene ND 0.000898 0.00528



96-12-8 U1,2-Dibromo-3-chloropropane ND 0.00160 0.00528

106-93-4 U1,2-Dibromoethane ND 0.000644 0.00528



78-87-5 U1,2-Dichloropropane ND 0.000539 0.00528



78-93-3 U2-Butanone ND 0.00439 0.00528

591-78-6 U2-Hexanone ND 0.00311 0.00528

108-10-1 U4-Methyl-2-pentanone ND 0.00169 0.00528

67-64-1 UAcetone ND 0.00359 0.0423

71-43-2 UBenzene ND 0.000708 0.00528

74-97-5 UBromochloromethane ND 0.000718 0.00528

75-27-4 UBromodichloromethane ND 0.00150 0.00528

75-25-2 UBromoform ND 0.000887 0.00528

74-83-9 UBromomethane ND 0.000940 0.00528

75-15-0 UCarbon disulfide ND 0.000380 0.00528

56-23-5 UCarbon Tetrachloride ND 0.000940 0.00528










1212.2.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

1V10675.D

08/28/14 19:59

S4H2807

B4H2829

08/28/14 19:59


Project:

4080683




1Dilution:


Soil

08/21/14 09:35


Sparta Quarry



108-90-7 UChlorobenzene ND 0.000327 0.00528

124-48-1 UChlorodibromomethane ND 0.000634 0.00528

75-00-3 UChloroethane ND 0.00187 0.00528

67-66-3 UChloroform ND 0.00128 0.00528

74-87-3 UChloromethane ND 0.000718 0.00528

156-59-2 Ucis-1,2-Dichloroethene ND 0.000782 0.00528

10061-01-5 Ucis-1,3-Dichloropropene ND 0.000507 0.00528

110-82-7 UCyclohexane ND 0.00113 0.00528

75-71-8 UDichlorodifluoromethane ND 0.00112 0.00528

100-41-4 UEthylBenzene ND 0.000296 0.00528

98-82-8 UIsopropylbenzene ND 0.000180 0.00528

179601-23-1 Um+p-Xylenes ND 0.000750 0.0106

79-20-9 UMethyl Acetate ND 0.00127 0.00528

1634-04-4 UMethyl tert-Butyl Ether ND 0.000824 0.00528

108-87-2 UMethylcyclohexane ND 0.000866 0.00528

75-09-2 UMethylene Chloride ND 0.00304 0.0423

95-47-6 Uo-Xylene ND 0.000254 0.00528

100-42-5 UStyrene ND 0.000254 0.00528

75-65-0 Utert-Butyl alcohol ND 0.00980 0.0528

127-18-4 UTetrachloroethene ND 0.000201 0.00528

108-88-3 UToluene ND 0.000190 0.00528

TOT-XYL UTotal Xylenes ND 0.000254 0.00528

156-60-5 Utrans-1,2-Dichloroethene ND 0.000739 0.00528

10061-02-6 Utrans-1,3-Dichloropropene ND 0.000665 0.00528

79-01-6 UTrichloroethene ND 0.000296 0.00528

75-69-4 UTrichlorofluoromethane ND 0.00105 0.00528










1212.2.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

1V10675.D

08/28/14 19:59

S4H2807

B4H2829

08/28/14 19:59


Project:

4080683




1Dilution:


Soil

08/21/14 09:35


Sparta Quarry



75-01-4 UVinyl chloride ND 0.000570 0.00528










1212.2.

ANALYSIS DATA SHEET

Client:

Work Order:

Matrix:

Date Sampled:

Prep Batch:

Sequence:

File ID:Prep Date:

Analyzed:

Prep Method:

1V10675.D

08/28/14 19:59

S4H2807

B4H2829

08/28/14 19:59


Project:

4080683




1Dilution:


Soil

08/21/14 09:35


Sparta Quarry


CAS NO. TENTATIVELY IDENTIFIED COMPOUNDS CONC. (mg/kg dry) QRT

NA unknown 0.00618 J7.22






1212.2.


Data File : G:\HPCHEM\1\DATA\08282014\1V10675.D Vial: 34 Acq On : 28 Aug 2014 19:59 Operator: omd Sample : 4080683-01 Inst : GCMS-1 Misc : soil 5.0g Multiplr: 1.00 MS Integration Params: RTEINT.P

Quant Time: Sep 2 15:11 2014 Quant Results File: 0328WC1.RES





-------------------------------------------------------------------------(#) = qualifier out of range (m) = manual integration1V10675.D 0328WC1.M Tue Sep 02 15:15:09 2014 SS Page 1


1212.2.

Quantitation Report

Data File : G:\HPCHEM\1\DATA\08282014\1V10675.D Vial: 34 Acq On : 28 Aug 2014 19:59 Operator: omd Sample : 4080683-01 Inst : GCMS-1 Misc : soil 5.0g Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Sep 2 15:11 2014 Quant Results File: 0328WC1.RES


2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00

0

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

1700000

Time-->


1,4

-Dic

hlo

robenzene-d

4,I

4-B

rom

ofluoro

benzene,S

Chlo

robenzene-d

5,I

Tolu

ene-d

8,S

1,4

-Diflu

oro

benzene,I

Penta

fluoro

benzene,I

Dib

rom

ofluoro

meth

ane,S

1V10675.D 0328WC1.M Tue Sep 02 15:15:09 2014 SS Page 2


1212.2.

SURROGATE RECOVERIESAnalysis Class: VOLATILES

Method:

File ID

Matrix: Soil

Lab Number DBF TOL-d8 BFB

SW 846 8260B

4080683-01 1V10675.D 103 102 104

B4H2829-BLK1 1V10665.D 117 99.9 107



DBF

TOL-d8

BFB

Dibromofluoromethane

Toluene-d8

4-Bromofluorobenzene

59 147

66

64

134

125


1212.3.

Volatile Organics - GC/MS - Quality Control


Batch B4H2829 Prepared: 08/28/2014Method: SW 846 8260B

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source200 60-120128*ug/kg1,1-DichloroetheneB4H2829-BS1 256

200 60-120120ug/kgBenzeneB4H2829-BS1 239

200 60-120104ug/kgChlorobenzeneB4H2829-BS1 208

200 60-120108ug/kgTolueneB4H2829-BS1 216

200 60-120114ug/kgTrichloroetheneB4H2829-BS1 229

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source200 57-136102ug/kg1,1-DichloroetheneB4H2829-MS1 4080862-01 ND204

200 59-12590.9ug/kgBenzeneB4H2829-MS1 4080862-01 ND182

200 55-12492.8ug/kgChlorobenzeneB4H2829-MS1 4080862-01 ND186

200 55-12695.8ug/kgTolueneB4H2829-MS1 4080862-01 ND192

200 53-122102ug/kgTrichloroetheneB4H2829-MS1 4080862-01 ND204

Result Units Level

Spike

Result

Source %REC %REC

Limits

RPD RPD

LimitAnalyteLab Number Source200 2557-13699.2 2.95ug/kg1,1-DichloroetheneB4H2829-MSD1 4080862-01 ND198

200 2559-12588.7 2.47ug/kgBenzeneB4H2829-MSD1 4080862-01 ND177

200 2555-12489.0 4.20ug/kgChlorobenzeneB4H2829-MSD1 4080862-01 ND178

200 2555-12693.3 2.71ug/kgTolueneB4H2829-MSD1 4080862-01 ND187

200 2553-12299.7 2.28ug/kgTrichloroetheneB4H2829-MSD1 4080862-01 ND199




1212.4.

VOLATILE METHOD BLANK SUMMARY

B4H2829Batch ID: GCMS-1Instrument:

Sequence ID: S4H2807

Sample Id Analyzed FileIDLab Number

B4H2829-BLK1 BLK1 08/28/2014 14:54 1V10665.D

B4H2829-MSD1 MSD1 08/29/2014 1:04 1V10685.D

B4H2829-MS1 MS1 08/29/2014 0:34 1V10684.D

B4H2829-BS1 BS1 08/28/2014 14:23 1V10664.D

4080683-01 QUARRY FINES 08/28/2014 19:59 1V10675.D


1212.5.


Work Order:

Injection Date:

Project:

Instrument ID:

Lab File ID:

Client:

Injection Time:

1V09222.D

GCMS-1

Sequence: S4D0312

Lab Sample ID: S4D0312-TUN1

4080683

03/31/2014

12:23


Sparta Quarry


50 16.115 - 40% of 95 PASS

75 41.530 - 60% of 95 PASS


96 6.765 - 9% of 95 PASS


174 75.450 - 100% of 95 PASS

175 7.365 - 9% of 174 PASS

176 95.795 - 101% of 174 PASS

177 6.695 - 9% of 176 PASS



Cal Standard S4D0312-CAL1 1V09225.D 03/31/2014 13:55.00







1212.6.

Data File : G:\HPCHEM\1\DATA\03312014\1V09222.D Vial: 51 Acq On : 31 Mar 2014 12:23 Operator: omd Sample : SEQ-TUN Inst : GCMS-1 Misc : soil Multiplr: 1.00 MS Integration Params: RTEINT.P Method : G:\HPCHEM\1\METHODS\0328WC1.M (RTE Integrator) Title : VOC's by EPA Method 8260

13.60 13.80 14.00 14.20 14.40 14.60 14.80 15.00 15.20 15.40 15.60 15.80 16.00 16.20 16.40 16.60 16.80 17.00 17.20 17.400

200000

400000

600000

800000

1000000

1200000

1400000

1600000

1800000

2000000

Time-->


30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 2000

50000

100000

150000

200000

250000

300000

m/z-->

Abundance Average of 15.474 to 15.504 min.: 1V09222.D (-)

95

174

75

50

698737 62 815745 143104 119 130 155148113 180137 161 200125

AutoFind: Scans 947, 948, 949; Background Corrected with Scan 942

| Target | Rel. to | Lower | Upper | Rel. | Raw | Result || Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |----------------------------------------------------------------------| 50 | 95 | 15 | 40 | 16.1 | 45985 | PASS || 75 | 95 | 30 | 60 | 41.5 | 118577 | PASS || 95 | 95 | 100 | 100 | 100.0 | 286012 | PASS || 96 | 95 | 5 | 9 | 6.8 | 19325 | PASS || 173 | 174 | 0.00 | 2 | 0.0 | 0 | PASS || 174 | 95 | 50 | 100 | 75.4 | 215619 | PASS || 175 | 174 | 5 | 9 | 7.4 | 15871 | PASS || 176 | 174 | 95 | 101 | 95.7 | 206280 | PASS || 177 | 176 | 5 | 9 | 6.7 | 13808 | PASS |----------------------------------------------------------------------

1V09222.D 0328WC1.M Thu Apr 03 17:22:07 2014 SS


1212.6.


Work Order:

Injection Date:

Project:

Instrument ID:

Lab File ID:

Client:

Injection Time:

1V10662.D

GCMS-1

Sequence: S4H2807


4080683

08/28/2014

13:21


Sparta Quarry


50 19.115 - 40% of 95 PASS

75 44.330 - 60% of 95 PASS


96 6.695 - 9% of 95 PASS


174 80.850 - 100% of 95 PASS

175 7.315 - 9% of 174 PASS

176 96.495 - 101% of 174 PASS

177 6.545 - 9% of 176 PASS



Calibration Check S4H2807-CCV1 1V10663.D 08/28/2014 13:52.00

LCS B4H2829-BS1 1V10664.D 08/28/2014 14:23.00

Blank B4H2829-BLK1 1V10665.D 08/28/2014 14:54.00

QUARRY FINES 4080683-01 1V10675.D 08/28/2014 19:59.00

Matrix Spike B4H2829-MS1 1V10684.D 08/29/2014 0:34.00

Matrix Spike Dup B4H2829-MSD1 1V10685.D 08/29/2014 1:04.00


1212.6.

Data File : G:\HPCHEM\1\DATA\08282014\1V10662.D Vial: 21 Acq On : 28 Aug 2014 13:21 Operator: omd Sample : SEQ-TUN Inst : GCMS-1 Misc : soil Multiplr: 1.00 MS Integration Params: RTEINT.P Method : G:\HPCHEM\1\METHODS\0328WC1.M (RTE Integrator) Title : VOC's by EPA Method 8260

13.60 13.80 14.00 14.20 14.40 14.60 14.80 15.00 15.20 15.40 15.60 15.80 16.00 16.20 16.40 16.60 16.80 17.00 17.20 17.400

200000

400000

600000

800000

1000000

1200000

1400000

1600000

Time-->


30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 1850

50000

100000

150000

200000

m/z-->

Abundance Average of 15.482 to 15.512 min.: 1V10662.D (-)

95

174

75

50

69

8737 61 815645 143117104 130 148 155137

AutoFind: Scans 949, 950, 951; Background Corrected with Scan 944

| Target | Rel. to | Lower | Upper | Rel. | Raw | Result || Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |----------------------------------------------------------------------| 50 | 95 | 15 | 40 | 19.1 | 44653 | PASS || 75 | 95 | 30 | 60 | 44.3 | 103587 | PASS || 95 | 95 | 100 | 100 | 100.0 | 233771 | PASS || 96 | 95 | 5 | 9 | 6.7 | 15629 | PASS || 173 | 174 | 0.00 | 2 | 0.3 | 561 | PASS || 174 | 95 | 50 | 100 | 80.8 | 188928 | PASS || 175 | 174 | 5 | 9 | 7.3 | 13810 | PASS || 176 | 174 | 95 | 101 | 96.4 | 182037 | PASS || 177 | 176 | 5 | 9 | 6.5 | 11906 | PASS |----------------------------------------------------------------------

1V10662.D 0328WC1.M Tue Sep 02 15:24:21 2014 SS


1212.6.

Response Factor Report GCMS-1

Method : G:\HPCHEM\1\METHODS\0328WC1.M (RTE Integrator) Title : VOC's by EPA Method 8260 Last Update : Tue Apr 01 08:57:57 2014 Response via : Initial Calibration

Calibration Files 5 =1V09225.D 40 =1V09226.D 80 =1V09227.D 120 =1V09228.D 200 =1V09229.D 400 =1V09230.D

Compound 5 40 80 120 200 400 Avg %RSD-------------------------------------------------------------------------

1) I Pentafluorobenzene ----------------ISTD---------------------- 2) Dichlorodifluoromet 0.143 0.125 0.134 0.128 0.125 0.124 0.130 5.69 3) P Chloromethane 0.268 0.243 0.244 0.246 0.246 0.249 0.249 3.84 4) Acrolein 0.012 0.010 0.013 0.011 0.009 0.011 12.41 5) C Vinyl Chloride 0.329 0.306 0.296 0.289 0.294 0.284 0.300 5.38# 6) Bromomethane 0.352 0.272 0.274 0.211 0.148 0.252 30.47 7) Chloroethane 0.296 0.277 0.262 0.226 0.215 0.255 13.34 8) Trichlorofluorometh 0.609 0.587 0.579 0.573 0.546 0.514 0.568 5.89 9) 1,1,2-Trichloro-1,2 0.424 0.427 0.421 0.418 0.392 0.356 0.406 6.84 10) Acetone 0.101 0.088 0.106 0.083 0.071 0.090 15.60 11) C 1,1-Dichloroethene 0.650 0.624 0.621 0.604 0.572 0.503 0.596 8.73# 12) tert-Butyl Alcohol 0.033 0.029 0.037 0.029 0.025 0.031 15.56 13) Methyl Acetate 0.253 0.203 0.182 0.231 0.196 0.180 0.208 13.88 14) Methylene Chloride 0.573 0.510 0.510 0.468 0.410 0.494 12.22 15) Carbon Disulfide 1.523 1.491 1.468 1.442 1.362 1.159 1.407 9.48 16) Acrylonitrile 0.118 0.101 0.092 0.112 0.093 0.083 0.100 13.24 17) Methyl tert-Butyl E 1.159 1.023 0.943 1.057 0.924 0.833 0.990 11.55 18) trans-1,2-Dichloroe 0.658 0.606 0.586 0.580 0.557 0.496 0.580 9.22 19) P 1,1-Dichloroethane 0.776 0.776 0.761 0.761 0.732 0.664 0.745 5.77 20) Vinyl Acetate 0.000 -1.00 21) 2-Butanone 0.126 0.103 0.133 0.105 0.094 0.112 14.66 22) 2,2-Dichloropropane 0.668 0.628 0.617 0.611 0.593 0.569 0.614 5.45 23) cis-1,2-Dichloroeth 0.742 0.670 0.657 0.657 0.628 0.577 0.655 8.25 24) C Chloroform 0.917 0.777 0.767 0.769 0.742 0.707 0.780 9.20# 25) Bromochloromethane 0.367 0.337 0.318 0.342 0.312 0.292 0.328 7.95 26) S Dibromofluoromethan 0.633 0.616 0.595 0.626 0.607 0.596 0.612 2.55 27) Cyclohexane 0.507 0.372 0.359 0.363 0.354 0.336 0.382 16.38 28) 1,1,1-Trichloroetha 0.624 0.602 0.594 0.603 0.596 0.581 0.600 2.36 29) 1,1-Dichloropropene 0.650 0.602 0.588 0.591 0.583 0.545 0.593 5.75 30) Carbon Tetrachlorid 0.507 0.508 0.517 0.516 0.511 0.498 0.509 1.35 31) 1,2-Dichloroethane 0.505 0.442 0.420 0.460 0.424 0.405 0.443 8.13 32) Benzene 1.683 1.576 1.550 1.551 1.485 1.354 1.533 7.11

33) I 1,4-Difluorobenzene ----------------ISTD---------------------- 34) Trichloroethene 0.272 0.251 0.251 0.249 0.241 0.233 0.249 5.34 35) Methylcyclohexane 0.277 0.252 0.249 0.233 0.230 0.210 0.242 9.41 36) C 1,2-Dichloropropane 0.256 0.244 0.238 0.236 0.224 0.212 0.235 6.55# 37) Bromodichloromethan 0.359 0.332 0.323 0.332 0.306 0.294 0.324 6.97 38) p-Dioxane 0.226 0.112 0.074 0.044 0.022 0.095 84.13 39) Dibromomethane 0.164 0.139 0.133 0.147 0.131 0.130 0.141 9.38 40) 2-Chloroethylvinyl 0.128 0.116 0.104 0.122 0.105 0.102 0.113 9.50 41) 4-Methyl-2-Pentanon 0.210 0.164 0.143 0.180 0.143 0.130 0.162 18.28 42) cis-1,3-Dichloropro 0.424 0.390 0.374 0.386 0.350 0.332 0.376 8.55 43) S Toluene-d8 1.100 1.095 1.079 1.087 1.061 1.079 1.084 1.31 44) C Toluene 0.996 0.946 0.913 0.888 0.821 0.746 0.885 10.16# 45) trans-1,3-Dichlorop 0.366 0.332 0.315 0.336 0.300 0.283 0.322 9.06 46) 1,1,2-Trichloroetha 0.201 0.183 0.169 0.185 0.160 0.152 0.175 10.32 47) 2-Hexanone 0.142 0.116 0.103 0.129 0.102 0.095 0.115 15.78 48) 1,3-Dichloropropane 0.373 0.323 0.303 0.334 0.292 0.275 0.317 10.97 49) Tetrachloroethene 0.259 0.254 0.251 0.248 0.241 0.242 0.249 2.84 50) Dibromochloromethan 0.239 0.226 0.215 0.233 0.210 0.204 0.221 6.19 51) 1,2-Dibromoethane 0.214 0.187 0.173 0.198 0.172 0.164 0.185 10.19

52) I Chlorobenzene-d5 ----------------ISTD---------------------- 53) C Chlorobenzene 1.267 1.208 1.196 1.167 1.121 1.054 1.169 6.35# 54) 1,1,1,2-Tetrachloro 0.455 0.429 0.426 0.430 0.423 0.412 0.429 3.37 55) C Ethylbenzene 2.326 2.178 2.101 2.011 1.901 1.686 2.034 10.99# 56) m+p-Xylenes 0.869 0.815 0.804 0.783 0.760 0.714 0.791 6.63 57) o-Xylene 1.846 1.757 1.678 1.598 1.507 1.372 1.626 10.57

0328WC1.M Thu Apr 03 18:25:18 2014 SS Page 1(#) = Out of Range


1212.7.

Response Factor Report GCMS-1

Method : G:\HPCHEM\1\METHODS\0328WC1.M (RTE Integrator) Title : VOC's by EPA Method 8260 Last Update : Tue Apr 01 08:57:57 2014 Response via : Initial Calibration

Calibration Files 5 =1V09225.D 40 =1V09226.D 80 =1V09227.D 120 =1V09228.D 200 =1V09229.D 400 =1V09230.D

Compound 5 40 80 120 200 400 Avg %RSD-------------------------------------------------------------------------

58) Styrene 1.434 1.357 1.317 1.298 1.243 1.146 1.299 7.58 59) Isopropylbenzene 2.210 2.122 2.031 1.928 1.841 1.630 1.960 10.65 60) P Bromoform 0.285 0.271 0.250 0.285 0.252 0.246 0.265 6.80 61) P 1,1,2,2-Tetrachloro 0.566 0.482 0.433 0.488 0.408 0.375 0.459 14.81 62) S 4-Bromofluorobenzen 0.917 0.935 0.918 0.923 0.900 0.900 0.915 1.47 63) 1,2,3-Trichloroprop 0.131 0.120 0.105 0.123 0.104 0.100 0.114 11.09 64) n-Propylbenzene 2.714 2.551 2.434 2.301 2.120 1.872 2.332 13.03 65) Bromobenzene 0.898 0.846 0.798 0.803 0.752 0.698 0.799 8.74 66) 2-Chlorotoluene 1.676 1.551 1.503 1.436 1.363 1.239 1.461 10.42 67) 4-Chlorotoluene 1.859 1.699 1.610 1.551 1.449 1.317 1.581 12.01 68) 1,3,5-Trimethylbenz 1.769 1.678 1.633 1.546 1.455 1.326 1.568 10.24 69) tert-Butylbenzene 1.494 1.434 1.392 1.331 1.265 1.176 1.349 8.58 70) 1,2,4-Trimethylbenz 1.756 1.647 1.573 1.511 1.412 1.287 1.531 10.93 71) sec-Butylbenzene 2.439 2.374 2.254 2.122 1.978 1.735 2.150 12.24 72) 4-Isopropyltoluene 1.858 1.798 1.753 1.682 1.572 1.423 1.681 9.54 73) 1,3-Dichlorobenzene 1.062 0.973 0.942 0.917 0.868 0.808 0.928 9.43

74) I 1,4-Dichlorobenzene-d ----------------ISTD---------------------- 75) 1,4-Dichlorobenzene 1.146 1.047 1.032 1.042 1.000 0.943 1.035 6.45 76) n-Butylbenzene 2.181 2.048 2.006 1.863 1.792 1.622 1.919 10.43 77) 1,2-Dichlorobenzene 1.017 0.963 0.943 0.939 0.898 0.849 0.935 6.12 78) 1,2-Dibromo-3-chlor 0.079 0.078 0.070 0.084 0.074 0.070 0.076 7.41 79) 1,2,4-Trichlorobenz 0.691 0.645 0.630 0.626 0.607 0.600 0.633 5.14 80) Hexachlorobutadiene 0.356 0.339 0.341 0.329 0.326 0.340 0.339 3.10 81) Naphthalene 1.460 1.247 1.130 1.292 1.124 1.084 1.223 11.51 82) 1,2,3-Trichlorobenz 0.625 0.556 0.539 0.556 0.522 0.524 0.554 6.91 83) Indan 0.000 -1.00

0328WC1.M Thu Apr 03 18:25:18 2014 SS Page 2(#) = Out of Range


1212.7.

Compound List Report GCMS-1

Method : G:\HPCHEM\1\METHODS\0328WC1.M (RTE Integrator) Title : VOC's by EPA Method 8260 Last Update : Tue Apr 01 08:57:57 2014 Response via : Initial Calibration Total Cpnds : 83

PK# Compound Name QIon Exp_RT Rel_RT Cal #Qual A/H ID -------------------------------------------------------------------------- 1 I Pentafluorobenzene 168 6.73 1.000 A 2 A B 2 Dichlorodifluoromethane 85 1.54 0.228 A 1 A B 3 P Chloromethane 50 1.70 0.252 A 1 A B 4 Acrolein 56 2.81 0.418 A 1 A B 5 C Vinyl Chloride 62 1.79 0.266 A 1 A B 6 Bromomethane 94 2.09 0.310 A 2 A B 7 Chloroethane 64 2.17 0.323 A 1 A B 8 Trichlorofluoromethane 101 2.41 0.358 A 1 A B 9 1,1,2-Trichloro-1,2,2 Trifluor 101 2.93 0.436 A 2 A B 10 Acetone 43 2.96 0.440 A 1 A B 11 C 1,1-Dichloroethene 61 2.93 0.436 A 2 A B 12 tert-Butyl Alcohol 59 3.60 0.534 A 2 A B 13 Methyl Acetate 43 3.32 0.493 A 1 A B 14 Methylene Chloride 84 3.51 0.521 A 2 A B 15 Carbon Disulfide 76 3.18 0.473 A 1 A B 16 Acrylonitrile 53 3.79 0.563 A 2 A B 17 Methyl tert-Butyl Ether 73 3.85 0.572 A 1 A B 18 trans-1,2-Dichloroethene 61 3.87 0.574 A 2 A B 19 P 1,1-Dichloroethane 63 4.51 0.669 A 2 A B 20 Vinyl Acetate 43 2.73 0.405 A 1 A B 21 2-Butanone 43 5.50 0.817 A 1 A B 22 2,2-Dichloropropane 77 5.53 0.821 A 1 A B 23 cis-1,2-Dichloroethene 61 5.52 0.819 A 1 A B 24 C Chloroform 83 6.26 0.929 A 1 A B 25 Bromochloromethane 49 6.01 0.892 A 2 A B 26 S Dibromofluoromethane 113 6.60 0.980 A 2 A B 27 Cyclohexane 56 6.72 0.998 A 2 A B 28 1,1,1-Trichloroethane 97 6.57 0.976 A 2 A B 29 1,1-Dichloropropene 75 6.91 1.026 A 2 A B 30 Carbon Tetrachloride 117 6.88 1.022 A 2 A B 31 1,2-Dichloroethane 62 7.45 1.106 A 1 A B 32 Benzene 78 7.30 1.084 A 1 A B

33 I 1,4-Difluorobenzene 114 8.22 1.000 A 2 A B 34 Trichloroethene 130 8.62 1.049 A 2 A B 35 Methylcyclohexane 83 9.05 1.101 A 2 A B 36 C 1,2-Dichloropropane 63 9.11 1.108 A 2 A B 37 Bromodichloromethane 83 9.63 1.171 A 1 A B 38 p-Dioxane 88 8.22 1.000 A 2 A B 39 Dibromomethane 174 9.27 1.128 A 2 A B 40 2-Chloroethylvinyl Ether 63 10.21 1.241 A 1 A B 41 4-Methyl-2-Pentanone 43 10.73 1.305 A 2 A B 42 cis-1,3-Dichloropropene 75 10.45 1.270 A 2 A B 43 S Toluene-d8 98 10.89 1.324 A 2 A B 44 C Toluene 91 11.03 1.341 A 1 A B 45 trans-1,3-Dichloropropene 75 11.49 1.397 A 2 A B 46 1,1,2-Trichloroethane 97 11.83 1.438 A 1 A B 47 2-Hexanone 43 12.23 1.487 A 2 A B 48 1,3-Dichloropropane 76 12.09 1.471 A 1 A B 49 Tetrachloroethene 166 11.92 1.449 A 2 A B 50 Dibromochloromethane 129 12.45 1.514 A 1 A B 51 1,2-Dibromoethane 107 12.63 1.536 A 1 A B

52 I Chlorobenzene-d5 82 13.48 1.000 A 2 A B 53 C Chlorobenzene 112 13.54 1.004 A 1 A B 54 1,1,1,2-Tetrachloroethane 131 13.72 1.018 A 2 A B 55 C Ethylbenzene 91 13.73 1.019 A 1 A B 56 m+p-Xylenes 106 13.97 1.036 A 2 A B 57 o-Xylene 91 14.61 1.084 A 2 A B 58 Styrene 104 14.66 1.087 A 2 A B 59 Isopropylbenzene 105 15.25 1.131 A 1 A B 60 P Bromoform 173 14.94 1.108 A 2 A B 61 P 1,1,2,2-Tetrachloroethane 83 15.79 1.171 A 1 A B 62 S 4-Bromofluorobenzene 95 15.53 1.152 A 2 A B 63 1,2,3-Trichloropropane 110 15.86 1.177 A 1 A B 64 n-Propylbenzene 91 15.95 1.183 A 2 A B

0328WC1.M Thu Apr 03 18:25:18 2014 Page 1


1212.7.

65 Bromobenzene 77 15.73 1.167 A 2 A B 66 2-Chlorotoluene 91 16.07 1.192 A 2 A B 67 4-Chlorotoluene 91 16.28 1.208 A 2 A B 68 1,3,5-Trimethylbenzene 105 16.28 1.208 A 1 A B 69 tert-Butylbenzene 119 16.79 1.245 A 2 A B 70 1,2,4-Trimethylbenzene 105 16.89 1.253 A 1 A B 71 sec-Butylbenzene 105 17.16 1.273 A 2 A B 72 4-Isopropyltoluene 119 17.43 1.293 A 2 A B 73 1,3-Dichlorobenzene 146 17.34 1.286 A 2 A B

74 I 1,4-Dichlorobenzene-d4 152 17.47 1.000 A 2 A B 75 1,4-Dichlorobenzene 146 17.52 1.003 A 2 A B 76 n-Butylbenzene 91 18.11 1.037 A 2 A B 77 1,2-Dichlorobenzene 146 18.08 1.035 A 2 A B 78 1,2-Dibromo-3-chloropropane 75 19.39 1.110 A 2 A B 79 1,2,4-Trichlorobenzene 180 20.75 1.188 A 2 A B 80 Hexachlorobutadiene 225 21.03 1.204 A 2 A B 81 Naphthalene 128 21.18 1.212 A 2 A B 82 1,2,3-Trichlorobenzene 180 21.54 1.233 A 2 A B 83 Indan 117 16.18 0.926 A 2 A B

Cal A = Average L = Linear LO = Linear w/origin Q = Quad QO = Quad w/origin #Qual = number of qualifiers A/H = Area or Height ID R = R.T. B = R.T. & Q Q = Qvalue L = Largest A = All -------------------------------------------------------------------------- 0328WC1.M Thu Apr 03 18:25:17 2014 SS

0328WC1.M Thu Apr 03 18:25:18 2014 Page 2


1212.7.


S4H2807-CCV1 8/28/14 13:52

SW 846 8260B


Response

result

Expected

CCV ID: Analyzed:

% Drift1,1,1,2-Tetrachloroethane 216.410.4644553 200.00 8

1,1,1-Trichloroethane 255.670.7670114 200.00 28

1,1,2,2-Tetrachloroethane 202.400.4641618 0.3 (SPCC) 200.00 1

1,1,2-Trichloro-1,2,2 Trifluoroethane 414.710.4212713 400.00 4

1,1,2-Trichloroethane 223.390.1955149 200.00 12

1,1-Dichloroethane 264.950.986922 0.1 (SPCC) 200.00 32

1,1-Dichloroethene 262.300.7812012 30 (CCC) 200.00 31*

1,2,3-Trichlorobenzene 223.280.5274979 200.00 12

1,2,3-Trichloropropane 195.020.1110992 200.00 2

1,2,4-Trichlorobenzene 228.690.7238924 200.00 14

1,2,4-Trimethylbenzene 195.561.754083 200.00 2

1,2-Dibromo-3-chloropropane 206.817.849464E-02 200.00 3

1,2-Dibromoethane 220.910.2040635 200.00 10

1,2-Dichlorobenzene 211.750.989899 200.00 6

1,2-Dichloroethane 265.740.5884092 200.00 33

1,2-Dichloropropane 251.040.2950377 30 (CCC) 200.00 26

1,3,5-Trimethylbenzene 198.701.825103 200.00 1


1,3-Dichloropropane 222.600.3524176 200.00 11


2-Butanone 279.690.156832 200.00 40

2-Hexanone 260.460.1491709 200.00 30

4-Isopropyltoluene 203.541.71085 200.00 2

4-Methyl-2-pentanone 254.680.2059783 200.00 27

Acetone 321.310.1237029 200.00 61

Benzene 237.281.818769 200.00 19

Bromochloromethane 284.290.4663774 200.00 42

Bromodichloromethane 223.990.3631951 200.00 12

Bromoform 207.970.2752735 0.1 (SPCC) 200.00 4

Bromomethane 156.130.1703549 200.00 22

Carbon disulfide 171.951.209991 200.00 14

Carbon Tetrachloride 255.710.6513619 200.00 28

Chlorobenzene 204.651.196082 0.3 (SPCC) 200.00 2

Chlorodibromomethane 229.280.2534233 200.00 15

Chloroethane 226.570.2441383 200.00 13

Chloroform 242.980.9472318 30 (CCC) 200.00 21

Chloromethane 194.090.2418947 0.1 (SPCC) 200.00 3

cis-1,2-Dichloroethene 265.120.868372 200.00 33

cis-1,3-Dichloropropene 226.520.4259854 200.00 13

Cyclohexane 227.820.4349795 200.00 14

Dichlorodifluoromethane 197.620.1281635 200.00 1

EthylBenzene 201.552.049634 30 (CCC) 200.00 1

Isopropylbenzene 197.811.938805 200.00 1

m+p-Xylenes 405.570.8017314 400.00 1

Methyl Acetate 283.090.2937953 200.00 42

Methyl tert-Butyl Ether 217.931.078568 200.00 9

Methylcyclohexane 195.470.2364148 200.00 2


1212.8.


S4H2807-CCV1 8/28/14 13:52

SW 846 8260B


Response

result

Expected

CCV ID: Analyzed:

% DriftMethylene Chloride 272.960.6083902 200.00 36

Naphthalene 209.091.27827 200.00 5

n-Butylbenzene 198.781.906892 200.00 1

n-Propylbenzene 190.762.224259 200.00 5

o-Xylene 194.511.581726 200.00 3

p-Dioxane 94.289.98248E-03 2,000.00 95

sec-Butylbenzene 197.152.119501 200.00 1

Styrene 198.941.292412 200.00 1

tert-Butyl alcohol 2,437.823.743166E-02 2,000.00 22

tert-Butylbenzene 202.121.596892 200.00 1

Tetrachloroethene 228.760.2848577 200.00 14

Toluene 208.260.92139 30 (CCC) 200.00 4

trans-1,2-Dichloroethene 256.720.7451218 200.00 28

trans-1,3-Dichloropropene 229.400.3693076 200.00 15

Trichloroethene 220.140.274452 200.00 10

Trichlorofluoromethane 224.400.6372279 200.00 12

Vinyl chloride 209.030.3132528 30 (CCC) 200.00 5


1212.8.


Data File : G:\HPCHEM\1\DATA\08282014\1V10663.D Vial: 22 Acq On : 28 Aug 2014 13:52 Operator: omd Sample : SEQ-CCV@200 Inst : GCMS-1 Misc : soil Multiplr: 1.00 MS Integration Params: RTEINT.P

Quant Time: Aug 28 14:22 2014 Quant Results File: 0328WC1.RES




Target Compounds Qvalue 2) Dichlorodifluoromethane 1.54 85 358384 197.62 ug/kg 96 3) Chloromethane 1.69 50 676411 194.09 ug/kg 93 4) Acrolein 2.81 56 93575 608.59 ug/kg 92 5) Vinyl Chloride 1.78 62 875950 209.03 ug/kg 97 6) Bromomethane 2.03 94 476364 156.13 ug/kg 94 7) Chloroethane 2.14 64 682685 226.57 ug/kg 97 8) Trichlorofluoromethane 2.37 101 1781883 224.40 ug/kg 93 9) 1,1,2-Trichloro-1,2,2 Trif 2.91 101 2356005 414.71 ug/kg 87 10) Acetone 2.95 43 345911 321.31 ug/kg 84 11) 1,1-Dichloroethene 2.91 61 2184476 262.30 ug/kg 89 12) tert-Butyl Alcohol 3.61 59 1046703 2437.82 ug/kg 97 13) Methyl Acetate 3.31 43 821541 283.09 ug/kg 98 14) Methylene Chloride 3.49 84 1701244 272.96 ug/kg 97 15) Carbon Disulfide 3.16 76 3383503 171.95 ug/kg 95 16) Acrylonitrile 3.78 53 344896 247.52 ug/kg 95 17) Methyl tert-Butyl Ether 3.83 73 3016004 217.93 ug/kg 91 18) trans-1,2-Dichloroethene 3.84 61 2083587 256.72 ug/kg 94 19) 1,1-Dichloroethane 4.48 63 2759734 264.95 ug/kg 96 21) 2-Butanone 5.49 43 438550 279.69 ug/kg 95 22) 2,2-Dichloropropane 5.49 77 2227938 259.32 ug/kg 98 23) cis-1,2-Dichloroethene 5.49 61 2428232 265.12 ug/kg 85 24) Chloroform 6.22 83 2648748 242.98 ug/kg 99 25) Bromochloromethane 5.99 49 1304133 284.29 ug/kg 88 27) Cyclohexane 6.67 56 1216335 227.82 ug/kg 98 28) 1,1,1-Trichloroethane 6.54 97 2144797 255.67 ug/kg 97 29) 1,1-Dichloropropene 6.89 75 2009173 242.30 ug/kg 92 30) Carbon Tetrachloride 6.86 117 1821406 255.71 ug/kg 99 31) 1,2-Dichloroethane 7.41 62 1645371 265.74 ug/kg 100 32) Benzene 7.26 78 5085832 237.28 ug/kg 99 34) Trichloroethene 8.62 130 1480361 220.14 ug/kg 90 35) Methylcyclohexane 9.04 83 1275193 195.47 ug/kg 94 36) 1,2-Dichloropropane 9.12 63 1591398 251.04 ug/kg 98 37) Bromodichloromethane 9.62 83 1959031 223.99 ug/kg 99 38) p-Dioxane 8.20 88 242718 94.28 ug/kg# 30 39) Dibromomethane 9.26 174 849565 224.01 ug/kg 65 40) 2-Chloroethylvinyl Ether 10.22 63 234728 77.19 ug/kg 81 41) 4-Methyl-2-Pentanone 10.74 43 1111022 254.68 ug/kg 97 42) cis-1,3-Dichloropropene 10.44 75 2297714 226.52 ug/kg 96 44) Toluene 11.02 91 4969867 208.26 ug/kg 94 45) trans-1,3-Dichloropropene 11.50 75 1992001 229.40 ug/kg 93 46) 1,1,2-Trichloroethane 11.82 97 1054584 223.39 ug/kg 99 47) 2-Hexanone 12.24 43 804610 260.46 ug/kg 96 48) 1,3-Dichloropropane 12.09 76 1900898 222.60 ug/kg 97 49) Tetrachloroethene 11.93 166 1536488 228.76 ug/kg 98-------------------------------------------------------------------------(#) = qualifier out of range (m) = manual integration1V10663.D 0328WC1.M Thu Aug 28 15:03:03 2014 SS Page 1


1212.8.


Data File : G:\HPCHEM\1\DATA\08282014\1V10663.D Vial: 22 Acq On : 28 Aug 2014 13:52 Operator: omd Sample : SEQ-CCV@200 Inst : GCMS-1 Misc : soil Multiplr: 1.00 MS Integration Params: RTEINT.P

Quant Time: Aug 28 14:22 2014 Quant Results File: 0328WC1.RES


Compound R.T. QIon Response Conc Unit Qvalue------------------------------------------------------------------------- 50) Dibromochloromethane 12.46 129 1366935 229.28 ug/kg 99 51) 1,2-Dibromoethane 12.64 107 1100694 220.91 ug/kg# 88 53) Chlorobenzene 13.50 112 3407438 204.65 ug/kg 99 54) 1,1,1,2-Tetrachloroethane 13.68 131 1323155 216.41 ug/kg 93 55) Ethylbenzene 13.70 91 5839062 201.55 ug/kg 97 56) m+p-Xylenes 13.94 106 4567996 405.57 ug/kg 99 57) o-Xylene 14.57 91 4506072 194.51 ug/kg 98 58) Styrene 14.62 104 3681865 198.94 ug/kg 93 59) Isopropylbenzene 15.21 105 5523329 197.81 ug/kg# 86 60) Bromoform 14.90 173 784208 207.97 ug/kg 96 61) 1,1,2,2-Tetrachloroethane 15.75 83 1322319 202.40 ug/kg 96 63) 1,2,3-Trichloropropane 15.84 110 316503 195.02 ug/kg 96 64) n-Propylbenzene 15.91 91 6336540 190.76 ug/kg# 97 65) Bromobenzene 15.69 77 2291526 201.35 ug/kg 84 66) 2-Chlorotoluene 16.03 91 3977715 191.08 ug/kg 92 67) 4-Chlorotoluene 16.26 91 4452306 197.73 ug/kg# 96 68) 1,3,5-Trimethylbenzene 16.24 105 4437628 198.70 ug/kg 97 69) tert-Butylbenzene 16.75 119 3882747 202.12 ug/kg 85 70) 1,2,4-Trimethylbenzene 16.85 105 4264947 195.56 ug/kg 99 71) sec-Butylbenzene 17.12 105 6038101 197.15 ug/kg# 95 72) 4-Isopropyltoluene 17.40 119 4873924 203.54 ug/kg# 93 73) 1,3-Dichlorobenzene 17.30 146 2690909 203.49 ug/kg 92 75) 1,4-Dichlorobenzene 17.48 146 2628341 208.85 ug/kg# 90 76) n-Butylbenzene 18.07 91 4636494 198.78 ug/kg 92 77) 1,2-Dichlorobenzene 18.06 146 2406880 211.75 ug/kg 93 78) 1,2-Dibromo-3-chloropropan 19.36 75 190855 206.81 ug/kg 75 79) 1,2,4-Trichlorobenzene 20.70 180 1760101 228.69 ug/kg 94 80) Hexachlorobutadiene 20.96 225 1026715 249.45 ug/kg 96 81) Naphthalene 21.13 128 3108038 209.09 ug/kg 97 82) 1,2,3-Trichlorobenzene 21.49 180 1502753 223.28 ug/kg 97

-------------------------------------------------------------------------(#) = qualifier out of range (m) = manual integration1V10663.D 0328WC1.M Thu Aug 28 15:03:03 2014 SS Page 2


1212.8.

Quantitation Report

Data File : G:\HPCHEM\1\DATA\08282014\1V10663.D Vial: 22 Acq On : 28 Aug 2014 13:52 Operator: omd Sample : SEQ-CCV@200 Inst : GCMS-1 Misc : soil Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Aug 28 14:22 2014 Quant Results File: 0328WC1.RES


2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

Time-->


1,2

,3-T

richlo

robenzene

Naphth

ale

ne

Hexachlo

robuta

die

ne

1,2

,4-T

richlo

robenzene

1,2

-Dib

rom

o-3

-chlo

ropro

pane

n-B

uty

lbenzene

1,2

-Dic

hlo

robenzene

1,4

-Dic

hlo

robenzene

1,4

-Dic

hlo

robenzene-d

4,I

4-I

sopro

pyltolu

ene

1,3

-Dic

hlo

robenzene

sec-B

uty

lbenzene

1,2

,4-T

rim

eth

ylb

enzene

tert

-Buty

lbenzene

4-C

hlo

roto

luene

1,3

,5-T

rim

eth

ylb

enzene

2-C

hlo

roto

luene

n-P

ropylb

enzene

1,2

,3-T

richlo

ropro

pane

1,1

,2,2

-Tetr

achlo

roeth

ane,PB

rom

obenzene

4-B

rom

ofluoro

benzene,S

Isopro

pylb

enzene

Bro

mofo

rm,P

Sty

rene

o-X

yle

ne

m+

p-X

yle

nes

Eth

ylb

enzene,C

1,1

,1,2

-Tetr

achlo

roeth

ane

Chlo

robenzene,C

Chlo

robenzene-d

5,I

1,2

-Dib

rom

oeth

ane

Dib

rom

ochlo

rom

eth

ane

2-H

exanone

1,3

-Dic

hlo

ropro

pane

Tetr

achlo

roeth

ene

1,1

,2-T

richlo

roeth

ane

trans-1

,3-D

ichlo

ropro

pene

Tolu

ene,C

Tolu

ene-d

8,S

4-M

eth

yl-2-P

enta

none

cis

-1,3

-Dic

hlo

ropro

pene

2-C

hlo

roeth

ylv

inyl E

ther

Bro

modic

hlo

rom

eth

ane

Dib

rom

om

eth

ane

1,2

-Dic

hlo

ropro

pane,C

Me

thylc

yclo

he

xa

ne

Tri

chlo

roeth

ene

1,4

-Diflu

oro

benzene,I

p-D

ioxane

1,2

-Dic

hlo

roeth

ane

Benzene

1,1

-Dic

hlo

ropro

pene

Carb

on T

etr

achlo

ride

Penta

fluoro

benzene,I

Cyclo

hexane

Dib

rom

ofluoro

meth

ane,S

1,1

,1-T

richlo

roeth

ane

Chlo

rofo

rm,C

Bro

mochlo

rom

eth

ane

2-B

uta

none

2,2

-Dic

hlo

ropro

pane

cis

-1,2

-Dic

hlo

roeth

ene

1,1

-Dic

hlo

roeth

ane,P

trans-1

,2-D

ichlo

roeth

ene

Meth

yl te

rt-B

uty

l E

ther

Acry

lonitrile

tert

-Buty

l A

lcohol

Meth

yle

ne C

hlo

ride

Meth

yl A

ceta

teC

arb

on D

isulfid

eA

ceto

ne

1,1

,2-T

richlo

ro-1

,2,2

Tri

fluoro

eth

ane

1,1

-Dic

hlo

roeth

ene, C

Acro

lein

Tri

chlo

rofluoro

meth

ane

Chlo

roeth

ane

Bro

mom

eth

ane

Vin

yl C

hlo

ride,C

Chlo

rom

eth

ane,P

Dic

hlo

rodiflu

oro

meth

ane

1V10663.D 0328WC1.M Thu Aug 28 15:03:03 2014 SS Page 3


1212.8.

INTERNAL STANDARD REPORT

RtAreaRtAreaRtAreaRtAreaRtAreaArea Rt

Analysis Batch: S4H2807Analysis Class: VOLATILES

File IDLab Number

DCB-D4CHB-D5PFB DFB

B4H2829-BLK1 1V10665.D 6.72 8.22 13.44 17.43708382 6572537343551363754

4080683-01 1V10675.D 6.7 8.2 13.43 17.43737250 6283326983951256558

Reference Std ID

RT Limit

0.50

0.50

0.50

0.50

Ref RT

17.43

13.44

8.22

6.71

303,930.00 - 1,215,720.00

356,104.00 - 1,424,416.00

674,235.00 - 2,696,940.00

349,538.00 - 1,398,152.00

712208

1348470

699076

Area LimitRef AreaInternal Standard

PFB

1,4-Dichlorobenzene-d4DCB-D4

Chlorobenzene-d5CHB-D5

1,4-DifluorobenzeneDFB

Pentafluorobenzene

607860

S4H2807-CCV1



1212.9.

GENERAL CHEMISTRY


Work Order: 4080683




1313.

ANALYSIS DATA SHEET

GENERAL CHEMISTRY


Work Order: 4080683

Project:

Client:

Sparta Quarry

4080683-01 (Soil) QUARRY FINES

Analyte AnalyzedQDFRLUnitsConcentrationMethod

10.264ND Umg/kg dryCyanide 08/27/2014 10:00SW 846 9010B

194.7 %Percent Solids 08/22/2014 10:02Gravimetric


1313.1.

General Chemistry - Quality Control


Cyanide Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit

Batch B4H2717 Prepared & Analyzed: 08/27/201

ND 0.250 mg/kg wetB4H2717-BLK1

2.38 0.250 2.50 85-11595.0mg/kg wetB4H2717-BS1

ND 0.270 ND 20mg/kg dryB4H2717-DUP1 Source: 4080810-16

2.48 0.270 2.70 ND 75-12592.0mg/kg dryB4H2717-MS1 Source: 4080810-16

2.51 0.270 2.70 ND 2075-12593.0 1.08mg/kg dryB4H2717-MSD1 Source: 4080810-16


1313.1.