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Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Number 1
Kit Safety Data Sheet
Product Name: Trichrome Stain Kit
Product Code: R40217 Component Safety Data Sheets for Kit
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product Name 95% EthanolCat No. R40132, R40217, R40219Synonyms No information available.Recommended Use Laboratory chemicals
Emergency Telephone Number Carechem 24: +44 (0) 1865 407333
2. HAZARDS IDENTIFICATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC.
R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
3. COMPOSITION/INFORMATION ON INGREDIENTS Haz/Non-haz
Remel12076 Santa Fe DriveLenexa, KS 66215 United StatesTelephone: 1-800-255-6730Fax:1-800-621-8251
According to EC Directive 1907/2006/EC
Creation Date 01-Nov-2011
Entity / Business Name Oxoid Ltd.Wade RoadBasingstoke, Hants, UKRG24 8PWTelephone: +44 (0) 1256 841144
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_____________________________________________________________________________________________ For the full text of the R phrases mentioned in this Section, see Section 16
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes Ingestion Get medical attention. Clean mouth with water and drink afterwards plenty of water. Do not
induce vomiting. Inhalation Move to fresh air. Get medical attention if symptoms occur.. Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaCO2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire Specific Hazards Arising from the ChemicalFlammable. Keep product and empty container away from heat and sources of ignition. Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Flash Point 17°C / 62.6°F Method Closed cup Autoignition Temperature 363°C / 685.4°F Explosion Limits Lower 3.3 vol % Upper 19.0 vol %
Component Switzerland Poland Norway Ireland Denmark Australia Methyl alcohol Skin
STEL: 800 ppm 15 Minuten
STEL: 1040 mg/m3 15 Minuten
MAK: 200 ppm 8 Stunden
MAK: 260 mg/m3 8 Stunden
NDSCh: 300 mg/m3 15 minutach
NDS: 100 mg/m3 8 godzinach
TWA: 100 ppm 8 timer
TWA: 130 mg/m3 8 timer
STEL: 150 ppm 15 minutter.
STEL: 162.5 mg/m3 15 minutter.
Skin
TWA: 200 ppm 8 hr. TWA: 260 mg/m3 8
hr. Skin
TWA: 200 ppm 8 timer
TWA: 260 mg/m3 8 timer Skin
STEL: 250 ppm STEL: 328 mg/m3
TWA: 200 ppm TWA: 262 mg/m3
Occupational exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas Personal Protective Equipment Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Eye Protection Tightly fitting safety goggles Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure Hand Protection Protective gloves
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice Environmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance ColourlesspH No information available. Boiling Point/Range 78°C / 172.4°FMelting Point/Range No information available.Flash Point 17°C / 62.6°FMethod Closed cupExplosion Limits Lower 3.3 vol % Upper 19.0 vol %
10. STABILITY AND REACTIVITY
Stability Stable under recommended storage conditions. Conditions to Avoid Heat, flames and sparks. Incompatible Materials Strong oxidizing agents
_____________________________________________________________________________________________ Hazardous Decomposition Products Carbon oxides Hazardous Polymerization No information available Hazardous Reactions . None under normal processing.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity Product Information Harmful by inhalation, in contact with skin and if swallowed
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationEthyl alcohol 7060 mg/kg ( Rat ) 20000 ppm/10H ( Rat )
Methyl alcohol 5628 mg/kg ( Rat ) 15800 mg/kg ( Rabbit ) 64000 ppm ( Rat ) 4 h 83.2 mg/L ( Rat ) 4 h
Chronic Toxicity Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component IARC UK Ethyl alcohol Group 1
IARC: (International Agency for Research on Cancer)IARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 2A - Probably Carcinogenic to HumansGroup 2B - Possibly Carcinogenic to Humans
Sensitization No information available. Neurological Effects No information available. Mutagenic Effects No information available. Reproductive Effects No information available. Developmental Effects No information available. Target Organs Blood, Liver, Respiratory system, Central nervous system (CNS), Eyes, Reproductive System,
14. TRANSPORT INFORMATION Proper Shipping Name ETHANOL SOLUTION
IATA UN-No UN1170 Hazard Class 3 Packing Group II Proper Shipping Name ETHANOL SOLUTION
15. REGULATORY INFORMATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC Labelling
R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
S-phrase(s)S 7 - Keep container tightly closedS16 - Keep away from sources of ignition. No smokingS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS28A - After contact with skin, wash immediately with plenty of waterS45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL Ethyl alcohol 200-578-6 - X X - X X X X XMethyl alcohol 200-659-6 - X X - X X X X X
16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowedR23/24/25 - Toxic by inhalation, in contact with skin and if swallowedR39/23/24/25 - Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
Prepared By Regulatory Affairs Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Summary "***", and red text indicates revision Restrictions on use No information available. Training advice No information available. Literary reference No information available. Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product Name 70% EthanolCat No. R40135, R40217, R2740110Synonyms No information available.Recommended Use Laboratory chemicals
Emergency Telephone Number Carechem 24: +44 (0) 1865 407333
2. HAZARDS IDENTIFICATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC.
R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
3. COMPOSITION/INFORMATION ON INGREDIENTS Haz/Non-haz
Remel12076 Santa Fe DriveLenexa, KS 66215 United StatesTelephone: 1-800-255-6730Fax:1-800-621-8251
According to EC Directive 1907/2006/EC
Creation Date 01-Nov-2011
Entity / Business Name Oxoid Ltd.Wade RoadBasingstoke, Hants, UKRG24 8PWTelephone: +44 (0) 1256 841144
11 of 54
11 of 54
_____________________________________________________________________________________________ For the full text of the R phrases mentioned in this Section, see Section 16
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes Ingestion Get medical attention. Clean mouth with water and drink afterwards plenty of water. Do not
induce vomiting. Inhalation Move to fresh air. Get medical attention if symptoms occur.. Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaCO2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire Specific Hazards Arising from the ChemicalFlammable. Keep product and empty container away from heat and sources of ignition. Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Flash Point 21°C / 69.8°F Method Closed cup Autoignition Temperature 363°C / 685.4°F Explosion Limits Lower 3.3 vol % Upper 19.0 vol %
Component Switzerland Poland Norway Ireland Denmark Australia Methyl alcohol Skin
STEL: 800 ppm 15 Minuten
STEL: 1040 mg/m3 15 Minuten
MAK: 200 ppm 8 Stunden
MAK: 260 mg/m3 8 Stunden
NDSCh: 300 mg/m3 15 minutach
NDS: 100 mg/m3 8 godzinach
TWA: 100 ppm 8 timer
TWA: 130 mg/m3 8 timer
STEL: 150 ppm 15 minutter.
STEL: 162.5 mg/m3 15 minutter.
Skin
TWA: 200 ppm 8 hr. TWA: 260 mg/m3 8
hr. Skin
TWA: 200 ppm 8 timer
TWA: 260 mg/m3 8 timer Skin
STEL: 250 ppm STEL: 328 mg/m3
TWA: 200 ppm TWA: 262 mg/m3
Occupational exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas Personal Protective Equipment Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Eye Protection Tightly fitting safety goggles Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure Hand Protection Protective gloves
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice Environmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance Colourless Boiling Point/Range 78.0Melting Point/Range No information available.Flash Point 21°C / 69.8°FMethod Closed cupExplosion Limits Lower 3.3 vol % Upper 19.0 vol %
10. STABILITY AND REACTIVITY
Stability Stable under recommended storage conditions. Conditions to Avoid Heat, flames and sparks. Incompatible Materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides
_____________________________________________________________________________________________ Hazardous Polymerization No information available Hazardous Reactions . None under normal processing.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity Product Information Harmful by inhalation, in contact with skin and if swallowed
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationEthyl alcohol 7060 mg/kg ( Rat ) 20000 ppm/10H ( Rat )
Methyl alcohol 5628 mg/kg ( Rat ) 15800 mg/kg ( Rabbit ) 64000 ppm ( Rat ) 4 h 83.2 mg/L ( Rat ) 4 h
Chronic Toxicity Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component IARC UK Ethyl alcohol Group 1
IARC: (International Agency for Research on Cancer)IARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 2A - Probably Carcinogenic to HumansGroup 2B - Possibly Carcinogenic to Humans
Sensitization No information available. Neurological Effects No information available. Mutagenic Effects No information available. Reproductive Effects No information available. Developmental Effects No information available. Target Organs Blood, Liver, Respiratory system, Central nervous system (CNS), Eyes, Reproductive System,
14. TRANSPORT INFORMATION Proper Shipping Name ETHANOL SOLUTION
IATA UN-No UN1170 Hazard Class 3 Packing Group II Proper Shipping Name ETHANOL SOLUTION
15. REGULATORY INFORMATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC Labelling
R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
S-phrase(s)S 7 - Keep container tightly closedS16 - Keep away from sources of ignition. No smokingS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS28A - After contact with skin, wash immediately with plenty of waterS45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL Ethyl alcohol 200-578-6 - X X - X X X X XMethyl alcohol 200-659-6 - X X - X X X X X
16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowedR23/24/25 - Toxic by inhalation, in contact with skin and if swallowedR39/23/24/25 - Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
Prepared By Regulatory Affairs Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Summary "***", and red text indicates revision Restrictions on use No information available. Training advice No information available. Literary reference No information available. Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product Name Xylene - SCat No. R40133, R40217, R40219Synonyms No information available.Recommended Use Laboratory chemicals
Emergency Telephone Number Carechem 24: +44 (0) 1865 407333
2. HAZARDS IDENTIFICATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC.
R-phrase(s)R10 - FlammableR38 - Irritating to skinR43 - May cause sensitization by skin contactR50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
3. COMPOSITION/INFORMATION ON INGREDIENTS Haz/Non-haz
N; R51-53 For the full text of the R phrases mentioned in this Section, see Section 16
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes Ingestion Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting. Obtain
medical attention. Inhalation Move to fresh air. Get medical attention if symptoms occur.. Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaCO2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire Specific Hazards Arising from the ChemicalFlammable. Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Flash Point 48°C / 118.4°F Method No information available. Autoignition Temperature 255°C / 491°F Explosion Limits Lower 0.7 vol % Upper 6.1 vol %
Personal Precautions Remove all sources of ignition. Avoid contact with skin, eyes and clothing. Use personal
protective equipment. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment and Clean Up
Soak up with inert absorbent material. Clean contaminated surface thoroughly
7. HANDLING AND STORAGE
Handling Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Keep away from open
flames, hot surfaces and sources of ignition. Storage Keep away from heat and sources of ignition. Keep tightly closed in a dry and cool place. Specific use(s) No information available.
Occupational exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas Personal Protective Equipment Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Eye Protection Tightly fitting safety goggles Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure Hand Protection Protective gloves
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice Environmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance Clear - Colourlessodor CitruspH No information available. Boiling Point/Range 175°C / 347°FMelting Point/Range No information available.Flash Point 48°C / 118.4°FExplosion Limits Lower 0.7 vol % Upper 6.1 vol %
10. STABILITY AND REACTIVITY
Stability Stable under recommended storage conditions. Conditions to Avoid Heat, flames and sparks. Exposure to air. Incompatible Materials Strong oxidizing agents
_____________________________________________________________________________________________ Hazardous Decomposition Products Carbon oxides, Thermal decomposition can lead to release of irritating gases and vapors Hazardous Polymerization No information available Hazardous Reactions . None under normal processing.
Butylated hydroxyanisole 2 g/kg ( Rat ) Chronic Toxicity Carcinogenicity This product contains one or more substances which are classified by IARC as carcinogenic to
humans (Group I), probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B)
Component IARC UK
Butylated hydroxyanisole Group 2B IARC: (International Agency for Research on Cancer)IARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 2A - Probably Carcinogenic to HumansGroup 2B - Possibly Carcinogenic to Humans
Sensitization May cause sensitization by skin contact. Neurological Effects No information available. Mutagenic Effects No information available. Reproductive Effects No information available. Developmental Effects No information available. Target Organs No information available.
Ecotoxicity. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Component Freshwater Algae Freshwater Fish Microtox Water FleaD-Limonene 0.619-0.796 mg/L LC50 96 h
35 mg/L LC50 96 h Persistence and Degradability No information available Bioaccumulative Potential No information available. Mobility No information available.
13. DISPOSAL CONSIDERATIONS
Waste from Residues / Unused Products
Dispose of as hazardous waste in compliance with local and national regulations
Contaminated Packaging Dispose of in accordance with local regulations.
14. TRANSPORT INFORMATION
IMDG/IMO UN-No UN2052 Hazard Class 3 Packing Group III Proper Shipping Name DIPENTENE
ADR UN-No UN2052 Hazard Class 3 Packing Group III Proper Shipping Name DIPENTENE
IATA UN-No UN2052 Hazard Class 3 Packing Group III Proper Shipping Name DIPENTENE
The preparation is classified as dangerous in accordance with Directive 1999/45/EC Labelling
R-phrase(s)R10 - FlammableR38 - Irritating to skinR43 - May cause sensitization by skin contactR50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
S-phrase(s)S24 - Avoid contact with skinS37 - Wear suitable glovesS60 - This material and its container must be disposed of as hazardous wasteS61 - Avoid release to the environment. Refer to special instructions/ Safety data sheets
International Inventories
Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL D-Limonene 227-813-5 - X X - X X X X XButylated hydroxyanisole 246-563-8 - X X - X X X X X
16. OTHER INFORMATIONFull text of R-phrases referred to under sections 2 and 3R10 - FlammableR22 - Harmful if swallowedR38 - Irritating to skinR40 - Limited evidence of a carcinogenic effectR43 - May cause sensitization by skin contactR36/37/38 - Irritating to eyes, respiratory system and skinR50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environmentR51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Prepared By Regulatory Affairs Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Summary "***", and red text indicates revision Restrictions on use No information available. Training advice No information available. Literary reference No information available. Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicalsUses advised against No Information available Details of the supplier of the safety data sheet
Classification of the substance or mixture REGULATION (EC) No 1272/2008 Not hazardous
Classification according to EU Directives 67/548/EEC or 1999/45/EC For the full text of the R phrases mentioned in this Section, see Section 16 R-phrase(s) none
For the full text of the R phrases mentioned in this Section, see Section 16
4. FIRST AID MEASURES
Description of first aid measures Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Obtain medical attention. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes. Get medical attention if irritation develops and persists.. Ingestion Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting without
medical advice. Get medical attention. Inhalation Move to fresh air. If symptoms persist, obtain medical attention.. Notes to Physician Treat symptomatically
5. FIRE-FIGHTING MEASURES
Extinguishing media Suitable Extinguishing MediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment Extinguishing media which must not be used for safety reasonsNo information available.
Trichrome (Wheatley) Stain Revision Date 13-Sep-2011
Page 2 / 9
SAFETY DATA SHEET 29 of 54
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_____________________________________________________________________________________________ Special hazards arising from the substance or mixture Thermal decomposition can lead to release of irritating gases and vapors Advice for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Avoid contact with the skin and the eyes. Environmental precautions Prevent further leakage or spillage if safe to do so Methods and material for containment and cleaning up Soak up with inert absorbent material. Clean contaminated surface thoroughly.
7. HANDLING AND STORAGE
Precautions for Safe Handling Ensure adequate ventilation. Avoid contact with skin and eyes. Wear personal protective equipment. Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place Specific End Uses
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure limitsComponent European Union The United Kingdom France Belgium SpainAcetic acid - STEL: 37 mg/m3
_____________________________________________________________________________________________ Component Russia - TWA Slovak Republic Slovenia Sweden Turkey Acetic acid Skin notation
MAC: 5 mg/m310 25
TWA: 10 ppm 8 urah TWA: 25 mg/m3 8 urah
STV: 10 ppm 15 minuter
STV: 25 mg/m3 15 minuter
LLV: 5 ppm 8 timmar. LLV: 13 mg/m3 8
timmar.
TWA: 10 ppm 8 saat TWA: 25 mg/m3 8 saat
Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits
established by the region specific regulatory bodies.Derived No Effect Level (DNEL) No information available.Predicted No Effect Concentration (PNEC)
No information available.
Exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areasPersonal protective equipment Eye Protection Safety glasses with side-shields Hand Protection Protective gloves Skin and body protection Long sleeved clothing Respiratory Protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators
Hygiene Measures Handle in accordance with good industrial hygiene and safety practiceEnvironmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance Dark blue / GreenpH No information available. Boiling Point/Range Not applicableMelting Point/Range No information available.Flash Point Not applicableAutoignition Temperature No information available.
10. STABILITY AND REACTIVITY
Reactivity Chemical Stability Stable under recommended storage conditions.
Trichrome (Wheatley) Stain Revision Date 13-Sep-2011
Page 5 / 9
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_____________________________________________________________________________________________ Possibility of Hazardous Reactions Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions . None under normal processing.. Conditions to Avoid Incompatible products. Incompatible Materials Strong oxidizing agents. Hazardous Decomposition Products None under normal use conditions
11. TOXICOLOGICAL INFORMATION
Information on Toxicological Effects
Acute Toxicity Product Information Product does not present an acute toxicity hazard based on known or supplied
information
Component Information Component LD50 Oral LD50 Dermal LC50 InhalationAcetic acid 3310 mg/kg ( Rat ) 1060 mg/kg ( Rabbit ) 11.4 mg/L ( Rat ) 4 hPhosphotungstic acid 3300 mg/kg ( Rat )C.I. Acid Green 5 2 g/kg ( Rat )Fast green fcf 2 g/kg ( Rat )
Chronic Toxicity Carcinogenicity There are no known carcinogenic chemicals in this product
Sensitization No information available.Mutagenic Effects No information availableReproductive Effects No information available.Developmental Effects No information available.Target Organs Respiratory system, Eyes, Teeth, Skin.Endocrine Disruptor Information None known
_____________________________________________________________________________________________ Contaminated Packaging Empty containers should be taken to local recyclers for disposal 14. TRANSPORT INFORMATION
IMDG/IMO Not regulated
ADR Not regulated
IATA Not regulated
15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture International Inventories
Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL Acetic acid 200-580-7 - X X - X X X X XPhosphotungstic acid 235-087-6 - X X - X X - X XC.I. Acid Green 5 225-906-5 - X X - - X X X -Fast green fcf 219-091-5 - X X - X X X X XDisodium 4,5-dihydroxy-3-phenylazonaphthalene-2,7-disulphonate
224-085-0 - - - - - - - X -
Legend TSCA - United States Toxic Substances Control Act Section 8(b) InventoryEINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical SubstancesDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List PICCS - Philippines Inventory of Chemicals and Chemical SubstancesENCS - Japan Existing and New Chemical SubstancesCHINA - China Inventory of Existing Chemical SubstancesAICS - Inventory of Chemical SubstancesKECL - Existing and Evaluated Chemical Substances
Full text of R-phrases referred to under sections 2 and 3R10 - FlammableR34 - Causes burnsR35 - Causes severe burnsR68 - Possible risk of irreversible effects
Revision Date 13-Sep-2011Revision Summary Not applicableThis safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product Name Acid Ethanol 90%Cat No. R40134, R40217, R40219Synonyms No information available.Recommended Use Laboratory chemicals
Emergency Telephone Number Carechem 24: +44 (0) 1865 407333
2. HAZARDS IDENTIFICATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC.
R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
3. COMPOSITION/INFORMATION ON INGREDIENTS Haz/Non-haz
For the full text of the R phrases mentioned in this Section, see Section 16
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes Ingestion Get medical attention. Clean mouth with water and drink afterwards plenty of water. Do not
induce vomiting. Inhalation Move to fresh air. Get medical attention if symptoms occur.. Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaCO2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire Specific Hazards Arising from the ChemicalFlammable. Keep product and empty container away from heat and sources of ignition. Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Flash Point 18.33°C / 65°F Method Closed cup Autoignition Temperature No information available.
Component Switzerland Poland Norway Ireland Denmark Australia Methyl alcohol Skin
STEL: 800 ppm 15 Minuten
STEL: 1040 mg/m3 15 Minuten
MAK: 200 ppm 8 Stunden
MAK: 260 mg/m3 8 Stunden
NDSCh: 300 mg/m3 15 minutach
NDS: 100 mg/m3 8 godzinach
TWA: 100 ppm 8 timer
TWA: 130 mg/m3 8 timer
STEL: 150 ppm 15 minutter.
STEL: 162.5 mg/m3 15 minutter.
Skin
TWA: 200 ppm 8 hr. TWA: 260 mg/m3 8
hr. Skin
TWA: 200 ppm 8 timer
TWA: 260 mg/m3 8 timer Skin
STEL: 250 ppm STEL: 328 mg/m3
TWA: 200 ppm TWA: 262 mg/m3
Isopropyl alcohol STEL: 400 ppm 15 Minuten
STEL: 1000 mg/m3 15 Minuten
MAK: 200 ppm 8 Stunden
MAK: 500 mg/m3 8 Stunden
NDSCh: 1200 mg/m3 15 minutach
NDS: 900 mg/m3 8 godzinach
TWA: 100 ppm 8 timer
TWA: 245 mg/m3 8 timer
STEL: 150 ppm 15 minutter.
STEL: 306.25 mg/m3 15 minutter.
TWA: 200 ppm 8 hr. STEL: 400 ppm 15
min Skin
TWA: 200 ppm 8 timer
TWA: 490 mg/m3 8 timer
STEL: 500 ppm STEL: 1230 mg/m3
TWA: 400 ppm TWA: 983 mg/m3
Acetic acid STEL: 20 ppm 15 Minuten
STEL: 50 mg/m3 15 Minuten
MAK: 10 ppm 8 Stunden
MAK: 25 mg/m3 8 Stunden
NDSCh: 30 mg/m3 15 minutach
NDS: 15 mg/m3 8 godzinach
TWA: 10 ppm 8 timer
TWA: 25 mg/m3 8 timer
STEL: 20 ppm 15 minutter.
STEL: 37.5 mg/m3 15 minutter.
TWA: 10 ppm 8 hr. TWA: 25 mg/m3 8 hr.
STEL: 15 ppm 15 min
STEL: 37 mg/m3 15 min
TWA: 10 ppm 8 timer
TWA: 25 mg/m3 8 timer
STEL: 15 ppm STEL: 37 mg/m3
TWA: 10 ppm TWA: 25 mg/m3
Occupational exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas Personal Protective Equipment Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Eye Protection Tightly fitting safety goggles Skin and body protection Long sleeved clothing. Chemical resistant apron. Antistatic boots. Impervious gloves. Hand Protection Protective gloves
Hygiene Measures When using, do not eat, drink or smoke. Provide regular cleaning of equipment, work area and
clothing. Environmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance Clear ColourlesspH No information available. Boiling Point/Range No information available.Melting Point/Range No information available.
9. PHYSICAL AND CHEMICAL PROPERTIESFlash Point 18.33°C / 65°FMethod Closed cup
10. STABILITY AND REACTIVITY
Stability Stable under recommended storage conditions. Conditions to Avoid Heat, flames and sparks. Incompatible Materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Hazardous Polymerization No information available Hazardous Reactions . None under normal processing.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity Product Information Harmful by inhalation, in contact with skin and if swallowed
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationEthyl alcohol 7060 mg/kg ( Rat ) 20000 ppm/10H ( Rat )
Methyl alcohol 5628 mg/kg ( Rat ) 15800 mg/kg ( Rabbit ) 64000 ppm ( Rat ) 4 h 83.2 mg/L ( Rat ) 4 h
Isopropyl alcohol 4396 mg/kg ( Rat ) 12800 mg/kg ( Rat ) 12870 mg/kg ( Rabbit )
72.6 mg/L ( Rat ) 4 h
Acetic acid 3310 mg/kg ( Rat ) 1060 mg/kg ( Rabbit ) 11.4 mg/L ( Rat ) 4 h Chronic Toxicity Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component IARC UK Ethyl alcohol Group 1
IARC: (International Agency for Research on Cancer)IARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 2A - Probably Carcinogenic to HumansGroup 2B - Possibly Carcinogenic to Humans
Sensitization No information available. Neurological Effects No information available. Mutagenic Effects No information available. Reproductive Effects No information available. Developmental Effects No information available. Target Organs Blood, Liver, Respiratory system, Central nervous system (CNS), Eyes, Reproductive System,
Gastrointestinal tract (GI), Skin, Optic nerve.
12. ECOLOGICAL INFORMATION
Ecotoxicity.
Component Freshwater Algae Freshwater Fish Microtox Water FleaEthyl alcohol Leucidus idus: LC50 = 8.14
R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
S-phrase(s)S 7 - Keep container tightly closedS16 - Keep away from sources of ignition. No smokingS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS28A - After contact with skin, wash immediately with plenty of waterS45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
International Inventories
Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL Ethyl alcohol 200-578-6 - X X - X X X X XMethyl alcohol 200-659-6 - X X - X X X X XIsopropyl alcohol 200-661-7 - X X - X X X X XAcetic acid 200-580-7 - X X - X X X X X
16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3R10 - FlammableR11 - Highly flammableR35 - Causes severe burnsR36 - Irritating to eyesR67 - Vapors may cause drowsiness and dizzinessR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowedR23/24/25 - Toxic by inhalation, in contact with skin and if swallowedR39/23/24/25 - Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
16. OTHER INFORMATIONPrepared By Regulatory Affairs Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Summary "***", and red text indicates revision Restrictions on use No information available. Training advice No information available. Literary reference No information available. Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
Page 11 / 11 According to EC Directive 1907/2006/EC
Acid Ethanol 90%
47 of 54
47 of 54
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product Name Lugol's IodineCat No. R114353, R21528, R21670, R21671, R40029, R40217Synonyms No information available.Recommended Use Laboratory chemicals
Emergency Telephone Number Carechem 24: +44 (0) 1865 407333
2. HAZARDS IDENTIFICATION
The preparation is non-dangerous in accordance with Directive 1999/45/EC.
R-phrase(s)none
3. COMPOSITION/INFORMATION ON INGREDIENTS Haz/Non-haz
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if
symptoms occur.. Inhalation Move to fresh air Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment Extinguishing media which must not be used for safety reasonsNo information available. Specific Hazards Arising from the ChemicalKeep product and empty container away from heat and sources of ignition Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Flash Point Not applicableMethod No information available. Autoignition Temperature No information available.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Environmental Precautions Prevent further leakage or spillage if safe to do so. Should not be released into the
environment. Methods for Containment and Clean Up
Soak up with inert absorbent material Keep in suitable, closed containers for disposal.
Handling Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Storage Keep container tightly closed in a dry and well-ventilated place. Specific use(s) No information available.
_____________________________________________________________________________________________ Occupational exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas Personal Protective Equipment Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Eye Protection Tightly fitting safety goggles Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure Hand Protection Protective gloves
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice Environmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance Yellow to brownpH No information available. Boiling Point/Range No information available.Melting Point/Range No information available.Flash Point Not applicable
10. STABILITY AND REACTIVITY
Stability Stable under normal conditions. Conditions to Avoid Extremes of temperature and direct sunlight. Incompatible Materials Strong oxidizing agents, Ammonia, Reducing agents Hazardous Decomposition Products None under normal use conditions Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions . None under normal processing.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity Product Information Product does not present an acute toxicity hazard based on known or supplied information
Iodine 14 g/kg ( Rat ) Chronic Toxicity Carcinogenicity There are no known carcinogenic chemicals in this product
Sensitization No information available. Neurological Effects No information available. Mutagenic Effects No information available. Reproductive Effects Experiments have shown reproductive toxicity effects on laboratory animals. Developmental Effects No information available. Target Organs Respiratory system, Central nervous system (CNS), Eyes, Central Vascular System (CVS),
Skin.
12. ECOLOGICAL INFORMATION
EcotoxicityVery toxic to aquatic organisms. However, at the concentration present, this preparation is not expected to present significant adverse environmental effects.
Component Freshwater Algae Freshwater Fish Microtox Water FleaPotassium iodide Onchorhynchus mykiss:
Prepared By Regulatory Affairs Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Summary "***", and red text indicates revision Restrictions on use No information available. Training advice No information available. Literary reference No information available. Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.