1 ICP Test Report Certification Packet Company name: Littelfuse, Inc. Product Series: Polyswitch Product #: 1206L380SLWR Issue Date: October 18, 2011 It is hereby certified by Littelfuse, Inc. that there is neither RoHS (EU Directive 2002/95/EC)-restricted substance nor such use, for materials to be used for unit parts, for packing/packaging materials, and for additives and the like in the manufacturing processes. In addition, it is hereby reported to you that the parts and sub-materials, the materials to be used for unit parts, the packing/packaging materials, and the additives and the like in the manufacturing processes, are all composed of the following components. Issued by: <Global EHS Engineer> (1) Parts, sub-materials and unit parts This document covers the Polyswitch RoHS-Compliant series products manufactured by Littelfuse, Inc. < Raw Materials Used Please see Table 1 (2) The ICP data on all measurable substances Please see appropriate pages as identifed in Table 1 Remarks:. Form 585-047 Rev. A 2/21/06
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1
ICP Test Report Certification Packet
Company name : Littelfuse, Inc. Product Series: Polyswitch Product #: 1206L380SLWR
Issue Date: October 18, 2011 It is hereby certified by Littelfuse, Inc. that there is neither RoHS (EU Directive 2002/95/EC)-restricted substance nor such use, for materials to be used for unit parts, for packing/packaging materials, and for additives and the like in the manufacturing processes. In addition, it is hereby reported to you that the parts and sub-materials, the materials to be used for unit parts, the packing/packaging materials, and the additives and the like in the manufacturing processes, are all composed of the following components.
Issued by:
<Global EHS Engineer>
(1) Parts, sub-materials and unit parts This document covers the Polyswitch RoHS-Compliant series products manufactured by Littelfuse, Inc. < Raw Materials Used
Please see Table 1 (2) The ICP data on all measurable substances Please see appropriate pages as identifed in Table 1
Remarks:.
Form 585-047 Rev. A 2/21/06
2
Table 1: List of Raw Materials covered by this report
Total Parts Raw Material Part
Number Raw Material Description Page(s) 1 HDPE/LR5900 Polyethylene 3-12 2 N/A Ceramici filler 13-20 3 N/A Nickel Copper Foil 21-27 4 N/A Copper 28-32 5 N/A Tin 33-37 6 ZSR-150W Ink Acrylic- White 38-43 7 ZSR-150W Ink Acrylic - White (Phthalates) 44-47 8 N/A Prepreg (PP) 48-53
Validit nownFor QueSPtease u ith scs
t Itt||lIttt||l
Test Report No.: CE/2011122921Dale: 201110?,24 P a g e : 1 o f 1 0
EQUISTAR CHEMICALS, LPONE HOUSTON CENTER, SUITE 1600, 1221 IJCKINNEY ST, P. O. BOX 2583 HOUSTON,fExAx7t252-25A3
The following sample(s) was/wer submltted and identified by/on behatfofthe client as:
Sample DescriptionStyl€/ltem No.Sample Receiving DateTesting Period
POLYETHYLENEHDPE/LRsgOO2011t02t1A201 1 t O2t 1 I r O 201 1 tOZ24
Test Result(s) : Please refer to next page(s)
re l r csk bsrsn@odendb€cm@ Ll;irt1.'r...i irF, */{ilt ;11j1}..:1r . /.il:i3r.1-1\.: 3d;+:t. , ,ti U{!.n3d@hd€s3dbyh€ . .mFny ' r b i 6db6GgEE lcod Ibnsds
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scsTest Report No.:CEnO11n2921 Dalet2l l l t \2t24 page:2 of 1O
EQUISTAR CHEMICALS. LPOI]E HOUSTON CENTER, SUITE 1600, 1221 I.I|CKINNEY ST, P. O, BOX 2583 HOUSTON,rExAr< 77252-2583
Test Resultlsl
PART NAME No.1
Test ltom (s): Unit Method MDL RosultNo.'l
Cadmium (Cd) mgikg With reference to IEC 6232t: 20(E andperformed by ICP-AES.
2 n .d .
Lead (Pb) mg/Kg With reference to tEC 62321: 2008 andperformed by ICP-AES.
2 n.d.
Mercury (Hg) mg/Kg With reference to IEC 6232'1: 2008 andperfomed by ICP-AES.
2 n.d.
Hexavalent Chromium CrCy'l) byalkaline extraction
mg/Kg With reference to IEC 62321: 2008 andperformed by W-VIS.
o/o With reference to EN'14372. Analysiswas performed by GC/MS.
0.003 n.d.
DIDP (Di-isodecyl phthalate) (CASNo.:026761-4G0)
% With reference to EN 1 4372. Analysiswas performed by GC/irS.
0.01 n .d .
DINP (Di-isononyl phthalate) (CASNo.:02855312-0)
With referonce to EN 14372. Analysiswas performed by GC/MS.
0.01 n.d.
ONOP (Di-n-octyl phthalate) (CASNo.:000117-84-0)
% f,,/ith reference to EN 14372. Analysisl€s perfomed by GC/MS.
0.003 n.d.
DBP (Dibutyl phthalate) (CAS No.:000084-74-2)
% lL/ith reference to EN 14372. Analysisi.as performed by GC/l\rS.
0.003 n . d .
n lh 3 rar €pdldar ody b ik smpr6G)cdd rhs r6i.@n €nd b tscom@nyhr;tr.iir+q.t|11r,:rl11fr,:i!1;li'.e4.,1-.r++la1r:E-j::iJ..1.t:.,rli!.1
vsub ]d l o tG6m€cMd i66ds *
rd'ons. f 3ry h3cmFntsso6,3rb.,crcadd 0d 63 uid.r rh. t'
l[| |lI|t[l]|lll
WHITE POWDER
Test Report No.: CEn011l22g21 Da'.e:2011t'z24 page: 3 of 1O
EQUISTAR CHEMICALS, LPONE HOUSTON CENTER, SUITE 1600, 122'1 MCKINNEY ST, P. O. BOX2583 HOUSTON,rEx,x77252-25A3
Test ltem (s): Unit Mothod i,DL Re6ultNo.t
HalogenHalogen-Fluoine (F) (CAS No-014762-94-8)
mg/Kg With reference to BS EN 14582'2007.Analysis was pertomed by lC.
50 n.o.
Halogen-Chlo.ine (Cl) (CAS No.:022537 -15-1)
mg/Kg With reference to BS EN U5A22007 .Analysis was performed by lC.
50 n.d.
Halogen-Bromine (Br) (CAS No.:010097-32-2)
msik9 With reference to BS EN 14582''2cn7.Analysis was performed by lC.
50 n.d-
Halogenlodine (l) (CAS No.:01436244€)
mgfts with reference to Bs EN 14582:2007 .Analysis was perfo.med by lC.
50 n.d.
Sum of PBB9
mgikg With feference to IEC 62321: 2008 andpeformed by cC/lVS.
n.d.Monobromobiphenyl n.d.Dibromobiphenyl n.d.Tribromobiphenyl 5 n.d.Tetrabrcmobiphenyl 5 n.d.Pentabromobiphenyl 5 n.d.Hexabromobiphenyl 5 n . d .Heptabromobiphenyl 5 n.d-Octabromobiphenyl 5 n.d-Nonabromobiphenyl 5 n.d-Decabromobiphenyl 5 n.d-Sum of PBDES n . d .Monobromodiphenyl ether 5 n . d .Dibromodiph€nyl ether 5 n . d .Tribromodiphenyl ether 5 n.d.Tehabromodiphenyl ether 5 n.d.Pentabromodiphenyl ether 5 n.d.Hexabromodiphenyl ether 5 n.o,Hoptabromodiphenyl ether 5 n.d.Oclabromodiphenyl ether n.o.Nonabromodiphenyl other 5 n.d.Decabromodiphenyl ether n.d.
nlful€3l€p.nd€ro^91otbgampl€l'1ededThsla*rc@d€mdberecmpsny r I rj I :r.: . .1:t-t!- rr!fi1,; :;l!lrllij:9rf /-$F-h\1.1|- A r+:_. - i:,i,riq,ftsddn€[email protected]]condlbnso'sior 6odrdd 6n.r dddrB.ft s4
n s i b i t y 6 l o i s c e i l l d 6 s f u m e if t t r r ! f u a d d | ' g a 6 n s u e $ a b n o t b 3 E p d u d a e p l ' n l u l ' f u U l
Test Report No.: CE12011n2921 Date 2011t02,24 paoe:4 of 1O
EOUISTAR CHEMICALS, LPONE HOUSTON CENTER, SUITE 1600, 1221TEXAX 77252-25A3
MCKINNEY ST, P. O. BOX 2583 HOUSTON,llm tll l]|ltt
L€l' b{d Th s r3d cPd €md b€ repdc m F r y r l l l r j t J r l l i l i ! ' ] l l ! ! : J i ; i n l l : : l { , - l i t s : h , l . ] : : m + r . 7 ! : r r i i q ,}Ed@frsdssdby'hecomp5dys6jodfoi,G*3E]cod1trsolsfor 66d,mc ftim.l doorn.ds suq ha rmbroi d ,'b rydsAtdion and judsddd cs6ddn y and w th n he his ol Cr€d s nsib e t r r ] g f u a d d | ' g d b n s u n e i b g , m n o l b e € p d U d a c e p l ' n f u r . w ] f u dt44oll.sndonol|| i6@ds1ol
PFOS Refer€nce Information : Dirocfive 2OO6/,t2ZEC({} lray not be pleced on the marker or used as a substance or constituent of preparations in a concentrationequalto or higherthan 0.005 % by mass.(2) May not be plac€d on the market in semi-finished products or articles, or parts thereof, if the concentration ofPFOS isequalto of higherthan 0.1 % by mass calculated with reference tothe mass of structuEllv ormicrostruclurally distinct parts that contain PFos or, for textiles or other coated matedals, if lhe amount of pFosis equalto or higher than 1pg/m'?ofthe coated material.
I : i r + ! ' 1 { i s6o?P}e t , ,
Menbs or rh. scs G/oup 66s 5A)
Test Report No.: CE12011t22921 Date:2011|t02t24 page: 5 of iO
EOUISTAR CHEMICALS, LPONE HOUSTON CENTER, SUITE 1600, 1221 IVCKINNEY ST, P. O, BOX 2583 HOUSTON,rExlJ< 77252-2583
l lllllltIltltll
ICP.AES
Sample Material Digestion Acid
$eel, copper, aluminum, soldor Aqua regia, HNO3, HCl, HF, HrO,
Glass HNOy'HF
Gold, platinum, palladium, ceramic Aqua regia
Silver HN03
Pla6tic HrSO4, HrOr, HNOr, HCI
Others Any acid to total digeslion
cmFiv , r+Jr l i t ! r , . ! i t . x ! { , i , ; i r l t iq i f . i ! i t+ r r { : td , l r i I , r l : , l r tE tft9ddumdccsebyb6comts
$ b l e d l o T 6 f r 6 d d c m d i o B f u Eodamit don a! juffidEr d 55w5 d
i^db.j€p6du.6d€ic.pli iu|l ihod
1) Thes€ s€mples were dissotved tota y by pre-conditioning methoct according to betowflow cnan_( Cr- test method excluded )
2) Name of the person who made measurement: Climbgreatyang3) Name of the person in charge of measurement Troy Ch€ng
' r r , i r l ! r e l r r . ! i+s610r l ,e
Acid dig€stion by suitable aciddepended on different samolematerial {as below table)
Microwave digestion wilh
HNO3/HCI/HF
Add appropriate amolnt ofdigestion reagent
Heat to appropriate
tempe€ture to extract
Cool, filter digestate
through filter1) Alkal iFusion2) HCltodissolve
Add diphenyl-cabazide for
color development
measuae the absodance
at 540 nm by UV-VIS
Membo o/r^e 5cs6,o!p665 sAr
Test Report No.: CE12011122921Dai.e : 201110?,24 P a g e : 6 o f 1 0
EQUISTAR CHEMICALS, LPONE HOUSTON CENTER, SUITE 1600, 1221 MCKINNEY ST, P, O. BOX2583 HOUSTON,fExrx 77252-2583
Analwcal flow chart of halogen content1) Name ofthe person who made measurement Rita Chen2) Name of the person in charge of measureftent Troy Chang
' ith3t*ll€pd'€1€rm|yloibgmp|e1s)le$dThsleslrepod€nm1bBcomFry !:lFritJs .ill i l l r!]}iJ,i;llnl..'ra ,]-ii+.twl. r. :i;li . r i: l.ltqrhdodiad3i3s€dbylhacohpanysuqedb6Gfficondltr3ois
dnt,id w rhn th€ imb or cr€d3 is dbrtEronscrsnradhs&mefrfFir. shre ard obr'gdron5 unk b6 ka nior b6 boodld ded in iu . w rd
Test Report No. : CE12011n2921Oale | 201110?,24 P a g e : 9 o f 1 0
EQUISTAR CHEMICALS, LPONE HOUSTON CENTER, SUITE 1600, 1221 MCKINNEY ST, P, O. BOX 2583 HOUSTOIT,rExN< 77252-2583
Analytical flow chart of Soxhlet extraction (LC/MS) procedure
1) Name ofthe person who made measurement: Lydia Fu
2) Name ofthe person in charge of measurement Shinjyh Chen
rTest ltems: PFOS/PFOA , Benzotriazote
Sample pretreatmenvseparation
I
tfl[It]rIl ]t
UAEI
comFry i.riJ:ii,i r. . .l:ll iej:' .r!1;lrt r-i4!riJr9* - ril++ q1\r f I F-.r'-! ui.c,1h€ fu3a3ss6dby lh6cdmp5 .ysuq6dbbGa@cond l t r 3o l s
Test Report No. : CE|2O11n2921Date :2011102124Page : 10 of l0
' * EndofReport '*
EQUISTAR CHEMICALS. LPONE HOUSTON CENTER, SUITE 1600, 1221 ITCKINNEY ST, P. O, BOX 2583 HOUSTOI\,rExN< 77252-2583
|l][ttt][tt tl
psGli€dd rh s rod 'eFd ennor bconFny d l r , ! i i i " . . r i - 1 r t 1 : i l 1 ! i , j : n ( r t : t r . , l . - l ' i 1 : 14 r - t \ , , i : j l . r ! , " r c l i : trnseum.m 6 6su6d by rh6 co'p,
FBb ' t s ro bc l d randh3d6un
Test Report No.:CE/2010/84979Date :2010111130 Page : 1 of 8
Thefollowing sample(s) was/wero submitted and identified by/on behalfofthe client as:
Tost Result(s) Please ref6r to next page(s).
ZHUZHOU SANLI CARBIDE MATERIAL CO,, LTD.HUMHOU BUILDING, ZAOSHI. TIANYUAN DISTRICT ZHUZHOU, 4'12007, CHIM
Clr| .d L-c.*.t -frts.i
mPb(s)tesbd rh s bsr rePod 6i^d &compaiy rtl..jnl:rrl n'd" llrlrfiaillJi!!';" tl til l: *crlr;*t:ir1 a l.[r;ir]! '
in"i""1.*',i"lewr;ic".m.y5!!edbbG.isdcond!oisoibi . . " " d . " " f " - d d " ' . " " t s " , b r ^ " o j - . . * a l w " g " - ' r u m s - e.d.." fd*
"fo !"*.d - i**.;
" , i i - a . u ' t " i ' t o cm. *u ,a - ' t a ^y r i . " c *p , r y . oeo iidb €idued -eptni'r shoro,e,i. o 'ra,o"a'n"-un -
'. l!;ntl t!!i +;1i'it I + s6lo?'e
{Arw4D
S!|rdbra
Test Report No. : CE/2010/84979Date : 2010/11/30 Page. 2 of 8
ZHUZHOU SANLI CARBIDE MATERIAL CO., LTD.HUAZHOU BUILDING, ZAOSHI, TIANYUAN DISTRICT ZHUZHOU,412OO7, CHINA
T€6t Result(s)
l l | l | l []t l | trtt
PART NAME NO.'1 BLACK POWDER
Test ltem (s): Unit Method MDLResultNo.l
Cadmium (Cd) mg/K9 With reference to IEC 62321:200a arldpedormed by |CPAES.
n.d.
Lead (Pb) mg/Kg With reference to IEC 62321: 2008 andpedormed by ICP-AES.
n.o.
lrercury (Hg) mg/Kg With reference to IEC 62321: 2008 andpedormed by ICP-AES.
2 n.d.
Hexavalent Chrornium Cr(Vl) byalk€line oxtraction
mg/Kg With reference to IEC 62321 : 2008 andperfomed by UV-VIS.
n.d.
Perfl uorooctane sulfonates (PFOS)PFOS - AcidPFOS - Metal SaltPFOS -Amide
mg/Kg With reference to US EPA 3540C:1 996 method for PFOS Content.Analy6i6 was performed by LC/NIS.
'10 n.d.
PFOA {CAS No.: 000335€7-1) mg/kg With reference to US EPA 3540C:'1 996 method for PFOA Content.Analysis was performed by LC/MS.
1 0 n,d,
HalogenHalogen-Fluoine (F) (CAS No.:0't4762-944\
mS/kS With reference to BS EN 145A2:2007.Analysi6 was performed by lC.
50 n . d .
Halogenchlorine (Cl) (CAS No.:022537-15-1')
50 n.d.
Halogen-Bromine (Br) (CAS No.:01oo97 -32-2)
50 n.o.
Halogen-lodine (l) (CAS No.: 014362-44-8)
50 n.d-
h h ' 3 6 l € p . n d e l m | y b l s $ n p ] e G ) b s i & T h s b d € p o d e i n o | s r .c o o o a i v i i ' ! 1 l f i t ! , 1 ! J U " + - l ! j ! : i l j i L l r ' ; r ' { i i { n r . i l l l 1 . ! i : } } i i l i r I . ' l { r r a ' .
Ib'3 doomsl E ss€d by lhe cdhp,
- l l * : r l : f f i I F F !
Test Report No. iCE/2010/84979Date : 2010/11130P a g e : 3 o f 8
ZHUZHOU SANLI CARBIDE MATERIAL CO., LTD.HUAZHOU BUILDING, ZAOSHI, TIANYUAN DISTRICT ZHUZHOU, 412007. CHIM
rll tt]|l|ltt|l
Test ltem (s): Unit Method MDLResultNo.1
Sum of PBBa
mg/Kg With reference to IEC 62321 i 2008 andperfomed by GC/IVS.
Note :1. mg/kg = ppm i o.1wts/o =2. n.d. = Not Detecled3. MDL = lrethod Detection4. " - " = Not Regulated
1000ppm
Limit
PFOS Refercnce Information : OiJective 2006/122lEC(t) May not be placed on the market or used €s a substance or constituent of preparations in a concentration equal toor higherthan 0.005 % by mass.(2) [,,lay not be placed on the ma*et in semi-f]nished producls or adicles, or pads thereof, if the concentration ofPFOS is equalto or higherthan 0.1 o/o by mass calculated with refeence tothe mass of structurally ormicros'tructurally distinct parts that contain PFOS or, fortextiles or other coated materials, ifthe amount of PFOS isequalto or higher than 1Ug/m'of the coated malerial.
prels) red.d rh s E3r.8pod ennd scomoany tt+ i! ilitl, [r 1',1F.].]Er:-rt ;dlliE': S t,tillri+{alrE g : +il. -nrlrlit&'Th s d@!n.nI 9 ig6d by !1. compa
&q6d 6 r€ms aid condlons 'lrf E Atedoi s d.am ro rh. rmidon or 'abL v.
ptrib '9 's b G cretu and ih s dodm
Test Report
1 )
2')3)
No. : CE/2010/84979Date : 2010/11/30P a g e : 4 o f 8
ZHUZHOU SANLI CARBIDE MATERIAL CO., LTD.HUAZHOU BUILDING, ZAOSHI, TIANYUAN DISTRICT ZHUZHOU, 412007, CHINA
rlllllllll|lttltlt
These samples were dissolved totally by pre-conditioning method according to betow flow chaat.( Cr- test method excluded )
Name of the person who made measurement ClimbgreatYangName ofthe pe6on in charge of measurement Troy Chang
ICP-AES
Sample Material DigestionAcid
Sed, copper, aluminum, solder Aqua regia, HNO3, HCl, HF, HrO,
Glass HNOs/HF
Gold, platinum, palladium, ceramic Aqua r€gia
Salver HNO3
Plastic HrSO1, HrOr, HNO3, HCI
others Any acid to total digestion
n n s E b 3 l E p o d r € l e r o n L y l o t € s a m p b c ) l e 5 b d T h 9 G 3 l . € P o d € n n d *comoad itr ' i !: i+ , 41t' iF l l 'E11il l;1i ' iE " E:_ tl i +d.l l i :-+ 1. . iJ:[ l,] i tt l .Thsb0menlsisedby66comoa[y9'edb]b6era|cond!oisol$
pms6 4 !s b G Cled 'nd rh s dddml h e r l g h G a n d o b g a l m s m d l h e ' '
Itiir r[!i,r!r,.,n I r s610rr4 aD 1r s6 0r2t nt
Acid digestion by suitable aciddeoended on different samDlematerial (as below table)
Add appropriate amount of
digeslion reagent
Heat to appropriate
temperature to extract
Cool, filter digestate
through filter1) AlkaliFusion2) HClto dissolve
Add diphenyl-carbazide for
color development
measur€ the absorbance
€t 540 nm by UV-VIS
Test Report No. : CE2010/84979 Date:2010/11/30
ZHUZHOU SANLI CARBIDE MATERIAL CO,, LTD.HUAZHOU BUILDING, ZAOSHI. TIANYUAN DISTRICT ZHUZHOU.412OO7. CHINA
Analytical flow chart of Soxhlet extraction (LC/MS) procedure
P a g e : 5 o f 8
rfl[tI||]||ttttt]
1) Name of the person who made measurement Lydia Fu
2) Nameofthe person in charge of measurement Shinjyh Chen
rTest ltems: PFOS/PFOA . Benzotriazole
Sample pretrealrnenu6eparation
+
Data
mpreG) €ned rh 3 6' epdd dnnd @compary ' ' r . i t t : r . L l j l l . #h ' t 9 l ! , r 1 ! r f ; iE i . t 611 ! l i l 1 l r , . 4 r r i . - t , [ r ] i a t ! .rh 3 @m6nl s ised by h6 company $bjed b rs 6ed codd r oi3 or s
s!q6d b rehs eid coidtuns br E tuemd s drav. ro s€ rmturoi or 'ab It
-Lfl r i fE tif;]t,.t , + 3m 01,
Test Report No. : CE2010/84979 Date:2010/11/30 Page: 6 of I
ZHUZHOU SANLI CARBIDE MATERIAL CO,. LTD.HUMHOU BUILDING, ZAOSHI, TIANYUAN DISTRICT ZHUZHOU,412007, CHINA
t||tum ||t||]
Analytical flow chart of halogen content'l) Nameofthe Derson who made measurement Rita Chen2) Name of the person in charge of measurement Troy Chang
nrreG) resd rh s bd '@on onnd scdmpaiy t r i r i rn i? r , r . rL l { ' i ' 1 r r t :1 r r i , r r ! ' r ta . t . r l i f {1 ! r r r , , * : r r i i l - r r , r l i r i !4 .r h s d o d f i m l c s d b y h 6 c o m p a n y s q e d b c e i g d c o n d ! o B d s .
Sample pretreatment / Separation
Weighting and putting sample in cell
Orygen Bomb Combustion / Absorption
Dilution to fixed volume
Analysis was performed by lC
Membe' or rhe scs Goup 15cs sA)
Test Report No. : CE/2010/B4979Date r 2010/1 1/30 Page : 7 of 8
ZHUZHOU SANLI CARBIDE MATERIAL CO., LTD.HUAZHOU BUILDING, ZAOSHI, TIANYUAN DISTRICT ZHUZHOU. 412007. CHINA
tfi]|||| ||tlttl
Analytcal flow chart1) Name ofthe person who made measuremenl Roman Wong2) Name ofthe person in chafge of measurement: Troy Chang
r Te6t ltems: PBB/PBDE, TBBP-A-bis
FiBttesling pocess -----' Oplionalsc€en process ..-- Confimalion process - '>
Screen analysis
Sample extraction/Soxhlet method
concentrate/Dilute Exfacted solution
PBB/PBDE: Analysis by GC/MSTBBP.A-bis : Analysis by HPLC/DAD/IVIS
lssue Report
pelslr.sbd hE re$ rpdd 6^idr becomrany i i + ! t ! ; o , , f i l , r l i { i r r 1J i ! n t ! l , i l cF . r t i , i r * { r 1 r - i =F i : 1 , , . . . - r , l i , l t ! t !
Atunrn 3 drawn io h€ Lmrdon or l'ab 'Vinbm^'frer on.nd luisd.!on sussdon t add w r , r i r he mGdo$ i sns i pssb ' r l a ro bogdadd lh3do tum
Filter
ZHUZHOU SANLI CARBIDE MATERIAL CO., LTO.HUAZHOU BUILDING, ZAOSHI. TIANYUAN DISTRICT ZHUZHOU. 412007. CHINA
Test Report No. : CE/2010/84979Date.2010/11130P a g e : 8 o f 8
" End of Report -
flrm tt||tflrl[fl
prels) resbd rh s Es repod 6idd bec o m r a i y t J i , ' , i i 4 . ! J { i , i i r . r , f j 1 l i 1 , r i q n . l " . l i l ^ l r , e a i 1 r l . - : r J 1 t r ! | .Th s @men s iged by 6e cmpa
lbjsd to r€ms aid coid{o.s br E ars on 3dEmroh€Lmrdonofuab'V
Applicant: Littelfuse Inc. Date : Feb 01, 2011 LIMA Technology Center, Lipa City,
Malvar, Batangas
Sample Description:
One (1) group of submitted samples said to be : Part Description : Nickel/Copper foil (for RLD) Date Sample Received : Jan 28, 2011 Date Test Started : Jan 28, 2011
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
(Ⅲ) Test Method: Testing Item Testing Method Reporting Limit
Cadmium (Cd) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Lead (Pb) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Mercury (Hg) content
With reference to IEC 62321 edition 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Chromium VI (Cr6+) content
With reference to IEC 62321 edition 1.0:2008 in annex C, by alkaline digestion and determined by UV-Vis spectrophotometer.
1 ppm
Polybrominated Biphenyls (PBBs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MSD and further HPLC confirmation when necessary.
5 ppm
Polybrominated Diphenyl Ethers (PBDEs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MSD and further HPLC confirmation when necessary.
5 ppm
Halogen Content With reference to EN 14582:2007 by calorimetric bomb with oxygen and determined by ion chromatography
50 ppm
Remark: Reporting limit = Quantitation limit of analyte in sample
Applicant: Littelfuse, Inc. Date : Feb 10, 2011 LIMA Technology Center,
Lipa City, Malvar, Batangas
Sample Description: One (1) group of submitted samples said to be : Part Description : Plated copper(for SMD) Date Sample Received : Feb 01, 2011 Date Test Started : Feb 08, 2011
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
Cadmium (Cd) content ND Lead (Pb) content ND Mercury (Hg) content ND Chromium VI (Cr6+) content (mg/kg with 50cm2) Negative (< 0.02)
Remarks: ppm = Parts per million based on weight of tested sample = mg/kg ND = Not detected < = Less than mg/kg with 50cm2 = milligram per kilogram with 50 square centimetre Negative = A negative test result indicated positive observation
was not found at the time of testing.
Responsibility Of Chemist :Irene Chiou / Kevin Liu / Cathy Chen
Date Sample Received : Feb 01, 2011 Testing Period : Feb 08, 2011 To Feb 09, 2011
(Ⅲ) Test Method: Testing Item Testing Method Reporting Limit
Cadmium (Cd) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Lead (Pb) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Mercury (Hg) content
With reference to IEC 62321 edition 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Chromium VI (Cr6+) content
With reference to IEC 62321 edition 1.0:2008 in annex B, by boiling water extraction and determined by UV-Vis spectrophotometer.
0.02 mg/kg with 50cm2
Remark: Reporting limit = Quantitation limit of analyte in sample
Applicant: Littelfuse Inc. Date : Feb 10, 2011 LIMA Technology Center,
Lipa City, Malvar, Batangas
Sample Description: One (1) group of submitted samples said to be : Part Description : Tin(for SMD) Date Sample Received : Feb 01, 2011 Date Test Started : Feb 08, 2011
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
Chromium VI (Cr6+) content (mg/kg with 50cm2) Negative
(< 0.02)(#)
Remarks: ppm = Parts per million based on weight of tested sample = mg/kg ND = Not detected < = Less than mg/kg with 50cm2 = milligram per kilogram with 50 square centimetre Negative = A negative test result indicated positive observation
was not found at the time of testing. # = Due to the insufficient sample area, reduced total sample
surface of 10 cm2 was used and the dilution factor was adjusted accordingly.
Responsibility Of Chemist :Irene Chiou / Kevin Liu / Cathy Chen
Date Sample Received : Feb 01, 2011 Testing Period : Feb 08, 2011 To Feb 09, 2011
(Ⅲ) Test Method: Testing Item Testing Method Reporting Limit
Cadmium (Cd) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Lead (Pb) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Mercury (Hg) content
With reference to IEC 62321 edition 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Chromium VI (Cr6+) content
With reference to IEC 62321 edition 1.0:2008 in annex B, by boiling water extraction and determined by UV-Vis spectrophotometer.
0.02 mg/kg with 50cm2
Remark: Reporting limit = Quantitation limit of analyte in sample
Applicant: Littelfuse Inc. Date : Feb 08, 2011 LIMA Technology Center,
Lipa City, Malvar, Batangas
Sample Description: One (1) group of submitted samples said to be : Part Description : Ink (Acrylic) white(for SMD) Date Sample Received : Jan 28, 2011 Date Test Started : Jan 28, 2011
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
The above limits were quoted from 2002/95/EC and amendment 2005/618/EC for homogeneous material.
(Ⅲ) Test Method:
Testing Item Testing Method Reporting Limit
Cadmium (Cd) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Lead (Pb) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Mercury (Hg) content
With reference to IEC 62321 edition 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Chromium VI (Cr6+) content
With reference to IEC 62321 edition 1.0:2008 in annex C, by alkaline digestion and determined by UV-Vis spectrophotometer.
1 ppm
Polybrominated Biphenyls (PBBs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MSD and further HPLC confirmation when necessary.
5 ppm
Polybrominated Diphenyl Ethers (PBDEs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MSD and further HPLC confirmation when necessary.
5 ppm
Halogen Content With reference to EN 14582:2007 by calorimetric bomb with oxygen and determined by ion chromatography
50 ppm
Remark: Reporting limit = Quantitation limit of analyte in sample
it4(No ) : cE/2010/e2827 Es(Date) | 2o1o/os/24F * ( P a g e ) : l o f a
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3. I , iDL = Method Detect ion Lisir ( t l i4F t f l in fF{d )
i ii rhB sn rcFn @, mt ro s€ $md€o knd.rhL kn rc@d cnid b 4dklfBie!8 , rlti8€sRt69ifja2lt ILe i " fiSaaEi]}iit =6;1 !1 , T lliirrllqts .frLr€nR.FdL]gdby$e6Fryu#bca,coiddofudkeFi
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( C S N o . : 0 2 5 6 3 ? - 9 9 _ 4 )
4+us EPA Js4oct*. t^^1aFtft/X'i*d, i * : r l . / t r i i th reference ro US EPA3540C n€thod. Analys is sas per fornedby @/MS.
5
1, lrilR., +fi / Phtbalatesf , f :F&PX*T{F / BBP(Benry l buty l p l tnala re) (cAsN o - : 0 0 0 0 8 5 - 6 8 - ? )
+txN 143?2, 'r{Ria,EtrA/f :*&Ania. / l v i th .e fe rence to EN 143?2.Ana lys is was per io rmed by GC/MS.
0 , 0 0 3
I IX:F{{:aE& / DBP (DibutylP h t h a l a t e ) ( c A s N o . : 0 0 0 0 8 4 - 7 4 - 2 )
++Er{ u3?2, ',rF.{E.l{ A/f :*&}f,xl< . / S i t n r e f e r e n c e t o E N 1 4 3 ? 2 .Ana lys is was per lo r f ted 6y cc l t l s .
0 , 0 0 3
DEHP (Di_ (2-€thy lh€xyl )P h r h a r a t e . ) ( c A s N o . : 0 0 0 1 r 7 - 3 1 7 )
t-+Ftr r43? 2. 4fi.{EE{.A /f :*aihxlz - . / l i i n r e f e r e n c e t o n { 1 4 3 7 2 .Analys is vas per forned by cc/ i ls .
0 . 0 0 3
, i f : tsS:**aE / DrDP (Di-i s o d € c y l p h r h a l a t e ) ( C A S N o . :
026761- . r0 0 )
4*rli rt37z. ,x*.fq.lfdlf t*d,'d.xlz ' . / s i !h re fe ren .e to EN l , t3?2.
Ana lys is was pe . fo .oed by @/MS.
0 , 0 1
f iX:?*:4+!6 / DrNP (Di-i s o n o n y l f h t h a l a i € ) ( c A S N o . :
0 2 8 5 5 3 - 1 2 0 )
++rN u37z,,,{*r*8.,rff4,/f *61*,!j<. / { i th re fe rence to EN 14372.
Ana lys is was p€r fo rn€d by GC/MS.
0 . 0 1
,tf:F6:ra+FE / DNoP (Di-n-o c t y l f h r h a l a r € ) ( o \ s N o . :
0 0 0 r r 7 - 8 4 - 0 )
++EN 14372, 'x f,, {€ a },f d, / fr:*d, i* l< - . / $ i t h r e f e r e n c e r o E N 1 4 3 7 2 .
Applicant: Littelfuse Inc. LIMA Technology Center, Lipa City, Malvar, Batangas
Date : Feb 08, 2011
Sample Description: One (1) group of submitted samples said to be : Part Description : PP-HF(for SMD) Date Sample Received : Jan 28, 2011 Date Test Started : Jan 28, 2011
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
The above limits were quoted from 2002/95/EC and amendment 2005/618/EC for homogeneous material.
(Ⅲ) Test Method:
Testing Item Testing Method Reporting Limit
Cadmium (Cd) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Lead (Pb) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Mercury (Hg) content
With reference to IEC 62321 edition 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Chromium VI (Cr6+) content
With reference to IEC 62321 edition 1.0:2008 in annex C, by alkaline digestion and determined by UV-Vis spectrophotometer.
1 ppm
Polybrominated Biphenyls (PBBs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MSD and further HPLC confirmation when necessary.
5 ppm
Polybrominated Diphenyl Ethers (PBDEs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MSD and further HPLC confirmation when necessary.
5 ppm
Halogen Content With reference to EN 14582:2007 by calorimetric bomb with oxygen and determined by ion chromatography
50 ppm
Remark: Reporting limit = Quantitation limit of analyte in sample