HQ Nilsson Et Al (2007) Forsmark Site Investigation - Sampling and Analyses of Surface Waters

8/9/2019 HQ Nilsson Et Al (2007) Forsmark Site Investigation - Sampling and Analyses of Surface Waters

http://slidepdf.com/reader/full/hq-nilsson-et-al-2007-forsmark-site-investigation-sampling-and-analyses 1/81

P-07-95

Forsmark site investigation

Sampling and analyses

of surface waters

Results from sampling in the

Forsmark area, July 2005—June 2006

Ann-Chatrin Nilsson, Geosigma ABMicke Borgiel, Sveriges Vattenekologer AB

May 2007

Svensk Kärnbränslehantering AB

Swedish Nuclear Fuel

and Waste Management Co

Box 5864

SE-102 40 Stockholm Sweden

Tel 08-459 84 00

+46 8 459 84 00

Fax 08-661 57 19

+46 8 661 57 19



Tänd ett lager:

P, R eller TR.

Forsmark site investigation

Sampling and analyses

of surface waters

Results from sampling in the

Forsmark area, July 2005—June 2006

Ann-Chatrin Nilsson, Geosigma ABMicke Borgiel, Sveriges Vattenekologer AB

May 2007

Keywords: Kaka, Kakmonster, Mupparna, Kermit.

This report concerns a study which was conducted for SKB. The conclusionsand viewpoints presented in the report are those of the author(s) and do not

necessarily coincide with those of the client.

A pdf version of this document can be downloaded from www.skb.se.

ISSN 1651-4416

SKB P-07-95

Keywords: Surface water, Lakes, Streams, Shallow bays, Deep seawater location,Sampling, Chemical analysis, AP PF 400-05-051.

This report concerns a study which was conducted for SKB. The conclusionsand viewpoints presented in the report are those of the authors and do notnecessarily coincide with those of the client.

Data in SKB’s database can be changed for different reasons. Minor changes

in SKB’s database will not necessarily result in a revised report. Data revisionsmay also be presented as supplements, available at www.skb.se.

A pdf version of this document can be downloaded from www.skb.se.



3

Abstract

A two years and four months long comprehensive chemical investigation campaign of surfacewaters in the Forsmark area commenced in March 2002 and was completed in June 2004.This was followed by a less extensive long-term monitoring programme which was initiatedin July 2004. This report, the forth in the present series, comprises documentation of thefieldwork as well as compilation and tabulation of surface water data obtained during the

period July 2005 to June 2006, i.e. the second year of the monitoring programme.

The sampling during the second year continued from the same eleven sampling objects and atunchanged frequency, once per month. However, one extra sampling object (Lake Biotestsjön)was included in order to check eventual tritium contamination from the nuclear power plant.The sampling focused on streams, lakes and shallow sea bays in order to characterise the surfacewaters of the area. The results obtained included field measurements of ORP (Oxidising-Reducing Potential), pH, dissolved oxygen, electrical conductivity, salinity, measurement depth,

barometric pressure, turbidity, chlorophyll, light penetration, PAR (Photosynthetic ActiveRadiation) and water temperature as well as chemical analyses of major constituents, nutrientsalts, carbon species, trace metals and isotopes.

The report presents ORP-values (Oxidising-Reducing Potential) in diagrams since the start in2002 in order to illustrate the seasonal variation. Furthermore, the tritium contents and possiblecontamination of the sea water is discussed. It is concluded that the tritium contents in the seawater close to the nuclear power plant have decreased to normal values since last year. Onlythe first sample (July 2005) from close to the cooling water outlet in lake Biotestsjön displayeda conspicuously high tritium content of 120 TU. In the following samples the tritium contentmeasured between 9.1 TU and 12.9 TU, which is the expected level.

Fresh waters in the Forsmark area are well buffered with high alkalinity, high pH and highcalcium concentrations. Furthermore, waters recently affected by brackish sea water showhigh sodium chloride concentrations and there is a clear relationship between the movement/alteration of the coastline and the salinity of the water samples collected at the samplinglocations in the area. Generally, the new data confirm the knowledge and conclusions presentedin previous reports from earlier investigation periods.







7

1 Introduction

This document reports the performance and results from the activity Long-term monitoring ofsurface waters performed within the site investigation at Forsmark /1/. The work was conductedaccording to the activity plan and method documentations listed in Table 1-1 and is part of boththe hydrochemistry and the surface ecosystem investigation programmes. Both activity planand method descriptions are SKB’s internal controlling documents. The report treats the secondyear of the long-term surface water monitoring programme (July 2005 to June 2006). Three

previous reports present results from earlier investigations periods, /2/, /3/ and /4/. Furthermore,a detailed evaluation of surface water data from March 2002 to March 2004 is presented in /5/.Original data from the reported activity are stored in the primary database Sicada. Data aretraceable in Sicada by the activity plan number (AP PF 400-05-051). Only data in databases areaccepted for further interpretation and modelling. The data presented in this report are regardedas copies of the original data. Data in the database may be revised, if needed. However, suchrevision of the database will not necessarily result in a revision of this report.

The surface water activities include sampling, chemical analyses and field measurements. Thesampling objects consist of lake waters, stream waters and sea waters from shallow bays in theForsmark area. The sampling locations are presented in Figure 3-1.

Table 1-1.

Controlling documents for performance of the activities.

Activity plan Number Version

Undersökningar i Forsmarksområdet: Långtidsövervakning

av ytvatten juli 2004 – juli 2005.

AP PF 400-05-051 1.0

Method description Number Version

Metodbeskrivning för ytvattenprovtagning vid plats-undersökningar.

SKB MB 900.004 2.0

Measurement system description Number Version

Mätsystembeskrivning för YSI Multiparametersystem förvattenmätningar.

SKB MD 910.003 1.0

Water sampling and measurement procedures are also described in SKB PIR-04-09 “Metodik för provtagningav ekologiska parametrar i hav”, SKB PIR-04-06, “Metodik för provtagning av ekologiska parametrar i sjöar ochvattendrag”, and SKB PIR-04-12, “Översikt över provhanterings- och analysrutiner för vattenprov” (SKB internaldocuments).



9

2 Objectives and scope

The ongoing surface water monitoring programme which started in July 2004, concentrates onsampling locations in the prioritised northwestern part of the Forsmark candidate area /6/ andaims at creating long-term series of data. The main objectives are to obtain further informationon natural variations and also to allow identification of eventual perturbation effects from theongoing investigations. The sampling locations are presented in Figure 3-1.

The monitoring programme includes water sampling and sonde measurements in the differentlake systems; Lake Bolundsfjärden, Lake Eckarfjärden and Lake Labboträsket. Measurementsare being performed also in Lake Norra Bassängen in order to monitor salinity changes. Onesampling location remains in a shallow sea bay (Forslingens grund). Sampling of stream watercontinues at four localities (Kungsträsket, Bolundsskogen, Norr Eckarfjärden, Öster Gunnarsbo)and an electrical conductivity logger is installed in Lilleputt-sundet, also to monitor salinitychanges. Furthermore, due to observed enhanced tritium contents in the surface waters close to

the nuclear power plant, samples for tritium analyses are collected close to the cooling wateroutlet in Lake Biotestsjön.

The monitoring programme included water sampling for chemical analysis as well as directmeasurements of physical and chemical parameters such as ORP (Oxidising- Reducing Potential),

pH, dissolved oxygen, electrical conductivity, salinity, measurement depth, barometric pressure,turbidity, chlorophyll, light penetration, PAR (Photosynthetic Active Radiation) and water tem-

perature. The extent of the sampling varied at different occasions. Analyses of major constituentsand surface water supplements (nutrient salts, chlorophyll etc) were conducted frequently(12 times a year) while extended analyses including also isotopes and trace elements were

performed once per season (four times a year). Some special isotopes (δ37Cl, δ13C, 14C (pmC),87Sr/86Sr, δ34S, U- and Th-isotopes as well as Ra- and Rn-isotopes) were determined only once

a year, in July.



11

3 Sampling locations and sampling scheme

The monitoring programme, which started in July 2004, includes five lakes, one shallow sea bay location and four streams as well as a sampling location close to the outlet of cooling waterfrom the nuclear power plant to investigate eventual tritium contamination.

The sampling locations are presented in Figure 3-1. Table 3-1 lists the id-codes, coordinatesand names together with clarifying comments. The sampling scheme for the period July 2005to June 2006 is given in Table 3-2.

Figure 3-1. Sampling locations within the monitoring programme. One location constitutes an

alternative for a regular sampling position (see Table 3-1).



12

Table 3-1. Sampling locations (Id-code, coordinates, name and comments).

Sampling

locations

Coordinates

(RT90 RHB70)

Name Comments

Lakes

PFM000074 16 29 854, 66 99 393 Labboträsket

PFM000097* 16 31 814, 66 99 868 Norra bassängen

PFM000107 16 32 065, 66 99 031 Bolundsfjärden

PFM102270 Bolundsfjärden, not onthe map in Figure 3-1

Alternativ till PFM00107,använd vid ett tillfälle pågrund av svag is

PFM000117 16 31 946, 66 97 118 Eckarfjärden

Shallow sea bays and deep sea location

PFM000062 16 31 921, 67 00 605 SV Forslingens grund

PFM000082 16 32 528, 67 01 336 Alternative to PFM00062

PFM102269 16 31 405, 67 04 412 Cooling water outlet,Lake Biotestsjön

Check of tritiumcontamination

Streams

PFM000066 16 29 343, 66 99 064 Öster Gunnarsboträsket

PFM000068 16 31 641, 66 98 735 Kungsträsket

PFM000069 16 31 510, 66 98 440 Bolundsskogen

PFM000070 16 32 061, 66 97 319 Norr Eckarfjärden

*Only sonde measurements.

Table 3-2. Surface water sampling scheme from July 2005 to June 2006.

Year Month Week Programme type*

2005 July 28 E+

2005 August 31 M

2005 September 36 M

2005 October 40 E

2005 November 44 M

2005 November 48 M

2005 December 51 M

2006 January 4 E

2006 February 8 M

2006 March 12 M

2006 April 16 E2006 May 20 M

2006 June 24 M

*M = main programme (SKB class 3 including surface water supplements), E = extended programme (SKBclass 5 including surface water supplements), E+ = extended programme and special isotopes (δ 37Cl, δ13C,14C (pmC), 87Sr/86Sr, δ34S, U- and Th-isotopes as well as Ra- and Rn-isotopes).



13

4 Equipment

4.1 Sampling equipmentWater samples were collected using an online pumping setup consisting of an electrical

peristaltic pump system, PPS (ASF Thomas SR 10/100, powered by 12 VDC, 7 Ah cells),connected to 4–8 m long teflon-tubes (FEP 140) of 5 mm inner diameter. A manually operatedregulator (ELFA, DCM 24–40 pwm) was used to adjust the water flow to a maximum of1.3–2.9 litres/minute (depending on tube length, tube diameter and pumping level). Thesampling equipment is presented in Figure 4-1.

4.2 Multiparameter sondes

Field measurements were performed using two multiparameter sondes (YSI 6600 EDS andYSI 600 QS). A terminal (YSI 650 MDS) is connected to each sonde through a cable for loggingdata (Figure 4-2). Calibration of the sondes was carried out according to the measurementsystem description SKB MD 910.003 (SKB internal controlling document, see Table 1-1).

Table 4-1. Parameters measured by the two different YSI sondes.

Parameter YSI 6600 EDS YSI 600 QS

Date/time Yes Yes

Temperature (°C) Yes Yes

pH Yes Yes

Dissolved oxygen (mg/L) Yes Yes

ORP (Redox potential, mV) Yes Yes

Electrical conductivity (mS/cm) Yes Yes

Salinity (ppt) Yes Yes

Depth (m) Yes Yes

Barometric pressure (mm Hg) Yes Yes

Turbidity (NTU) Yes No

Chlorophyll (μg/l) Yes No

Light / PAR* (μmoles s –1 m –2) Yes No

* Photosynthetic Active Radiation



14

4.3 General field equipment

• Ruttner samplers were used as back up if the portable pump system should fail.

• The exact locations of the sampling location positions were found using a GPS (Garmin

172C) with an average accuracy of ± 0.5–1.0 m.

• Water depth was measured using an echo sounder (Plastimo, Echotest, LCD digital sounder)

with an accuracy of ± 0.05 m.

• Water transparency was estimated using a Secchi disc and aqua scope.

• Disposable filters (Millipore, 0.40 µm, Ø = 22 mm) were used together with 60 mL syringes

to filter specific sample portions of the sampled water in the field.

• Stopwatch (GUL), a water-filled plastic bottle (50 mL) and measuring-tape (Hultafors) were

used for flow/runoff estimates in stream waters.• Digital cameras (Nikon Coolpix 5000 and Olympus 400 mju) were used for documentation

of stream waters.

Figure 4-1. Schematic presentation of the peristaltic pump system (PPS).

H2O

Pumptube

offlexible

silicon

Inlet for water

from sampling

point

Teflontube

Bottle for water

sample portion

Outlet water sample

Peristaltic pump

YSI

6600

EDS

Terminal

650-

MDS

YSI 600

QS

Field cable

set 1: 15 m.

set 2: 30 m

PAR-

SENSOR

Figure 4-2. Measurement sondes used in the field investigations.



15

Figure 4-3. Sampling at Kungsträsket (PFM 000068) January 2006.



17

5 Performance

5.1 Presampling preparationsPrior to sampling, the sample bottles were cleaned (according to the routines for respectiveSKB class), labelled and packed in insulated boxes/bags. Acid additions were made in advancein bottles intended for trace metal analyses; these were placed in separate plastic bags to avoidcontamination. The peristaltic pump system (PPS), including the Teflon tubes, was washedusing acid (0.5 M HCl) and rinsed with deionised water before use. The equipment waskept well protected in plastic bags or in tight containers. The Disposable filters (Millipore)were rinsed with MilliQ-water (50 mL) and placed in plastic bags to prevent contamination.Calibration of the sondes was performed according to the measurement system descriptionSKB MD 910.003

5.2 Water sampling

Water samples were collected using a peristaltic pump system, PPS, and Ruttner samplers wereused as backup if the PPS-system should fail. Lake and sea water samples were collected closeto the surface (at 0.5 m depth) and in winter time also from approximately 0.5 m above the lakeor sea bottom in case of ice coverage. Stream water samples were collected at approximately0.1 m depth. The PPS-system and sample bottles were rinsed initially with water from the sam-

pling locations prior to filling, except for bottles with acid additions. To avoid contamination,the field crew was obliged to wear rubber gloves and great care was taken not to contaminate

bottles or equipment. Bottles and samples containing added acid were handled and storedseparately to avoid contaminating other sample portions.

Each sample consists of several sample portions and is labelled with the same sample number.The preparation of the sample portions in the field differs depending on their eventual use.Details on collected sample portions, components to be analysed and sample preparations aresummarised in Table 5-1.

Figure 5-1. Left: Sampling of surface water from below wet and soft ice (Lake Bolunds-fjärden,

April 2006). Right: Filtration of water in the field using a disposable filter.



18

Table 5-1. Filled bottles, components to be analysed and preparation of samples in the field.

Class 3: frequent

Class 5: four times per year (each season)

Class 5+: once a year (July

Bottle

volume (mL)

Number of

bottles

SKB-Label Components Preparation of

sample in field

Filling

instructions

125 1 Green Na, K, Ca, Mg, Li, Sr,S, Si, Br, I

– Fill up

5,000

(Collecting bottle)

1 Green Chlorophyll a, c,Pheopigment,

Alkalinity, pH, Conduc-tivity,

Tot-N, Tot-P,

POP, PON, POC,

Anions (Br, SO4, Cl,F, I),

TOC, DOC, DIC (onlyfor control)

– Fill up

25 2 Green Ammonia, NOx, Silicate Filtering withsyringe/0.40 μmfilter

Fill to mark

50 1 Green TOC – Leave 1 cm

50 2 Green DIC/DOC Filtering withsyringe/0.40 μmfilter

Leave 1 cm

Winkler bottles1 2 Green Oxygen 1 mL Mn(II)reagent + 2 mLalkaline iodinereagent and mix

Flow over x 3

Winkler bottles2 2 Green H2S2 1 mL ZnAc +1 mL 1M NaOHand mix

Flow over x 3

100 1 Red Trace metals – Fill up

5002 1 Red Fe(II)/Fetot2 Filtering withsyringe/0.40 μmfilter

Fill up

500 1 Green Tritium – Flow over x 1

100 1 Green Deuterium, O –18 – Fill up frombottom

1,000 1 Green 34S – Fill up

100 1 Green 37Cl – Fill up

100 1 Green87

Sr/86

Sr – Fill up100 1 Green U- and Th-isotopes – Fill up

500 1 Green Ra- and Rn-isotopes – Fill up

1) Winkler samples only when sonde measurements of oxygen show values below 4 mg/L.2) Included in the comprehensive surface water campaign and only at reduced groundwater conditions.



19

5.3 Field measurements

The multiparameter sondes were used for measurements of pH, water temperature, barometric pressure, ORP, PAR, turbidity, electrical conductivity, salinity, dissolved oxygen and chlorophyll. Light penetration was measured in lakes and at sea locations with a secchi disc accordingto the Swedish standard BIN SR 111. Photo documentation of stream waters was performed to

facilitate evaluation of the investigation data. Photos were taken of each marked out (using awooden stake) stream water sampling location.

In stream waters measurements were performed using a YSI 6600 EDS sonde if the water levelwas high enough, otherwise the smaller YSI 600 QS sonde was used. Chlorophyll, PAR andturbidity data were not reported for streams.

At lake and sea localities the multiple sonde (YSI 6600 EDS) was used to measure a profileat each sampling point. Measurements were conducted at every metre from the surface to the

bottom, see Table 5-2. In addition, PAR was logged just below the surface and during the iceseason above the ice, in the air. PAR measurements were performed at discrete depths and ascontinuous PAR-profile loggings. PAR-profiles were obtained by setting the sonde mode to‘continuous logging’. The sonde was then submerged from surface to bottom and hoisted upagain. The produced PAR-data were used for regression analyses of PAR versus depth.

A simple “floating bottle” method was used to measure water flow/runoff in the streams as acomplement to the regular method using discharge weirs and gauges. The cross-section mean areaof the stream was estimated, forming a rectangle, see Figure 5-3. The time for the bottle (closeto neutral in weight in water) to float the distance (L) from point A to B was measured with astopwatch. This procedure was repeated three times in each stream. The average water velocity(m/s) multiplied with the average area (m2) resulted in a rough water runoff estimate (m3/s).

Table 5-2. Logging depths at sampling locations in lakes and shallow sea bays.

Sampling

locations

Name Sonde logging

depth (m)

0.5 1.0 1.5 2.0 2.5 3.0 4.0 4.5 5.0 6.0 6.5 7.0

Lakes

PFM000074 Labbo-träsket X

PFM000097 Norra bassängen X

PFM000107 Bolunds-fjärden X X

PFM000117 Eckar-fjärden X X X

Shallow sea bays

PFM000062 SV Forslingens

grund

X X X X

PFM000082 Alternative toPFM00062

X X X X X X X X



20

Figure 5-3.

Schematic presentation for estimating water runoff in natural stream waters (see text for

explanation). Sampling location PFM000073 (Söder Bredviken).

Figure 5-2. Measuring a profile (PFM000064) in the ice covered Baltic Sea with the multiple sonde

(YSI 6600 EDS).



21

5.4 Sample treatment and chemical analyses

An overview of sample treatment and analytical methods is given in Appendix 1. The routinesare applicable independently of sampling method or type of sampling object.

5.5 Data handling/post processing

Two field protocols (activity log and sampling protocol) contain meta data (id-code, date, time,sample no., field crew etc.), a few measured data and weather observations as well as commentson field conditions which may influence the analytical results. The field protocols supply basicinformation for creating activities and activity comments in the SKB Sicada database. In addition,the few measured parameters and weather conditions, noted on the sampling protocol, are storedas data tables in Sicada.

Furthermore, eventual deviations from the sampling programme or from the normal routines arealso documented in special reports/comment files. The comment files are stored in the Sicadafile archive, see Table 5-3.

5.5.1 Chemical analytical data

The following routines for quality control and data management are generally applied forhydrochemical analysis data, independently of sampling method or type of sampling object.

Several components are determined by more than one method and/or laboratory. Moreover,duplicate analyses by an independent laboratory are performed as a standard procedure oneach fifth or tenth collected sample. All analytical results are stored in the Sicada database. Theapplied hierarchy path “Hydrochemistry/Hydrochemical investigation/Analyses/Water in thedatabase” contains two types of tables, raw data tables and primary data tables (final data tables).

Data on basic water analyses are inserted into the raw data tables for further evaluation. Theevaluation results in a final reduced data set for each sample. These data sets are compiled in a primary data table named “water composition”. The evaluation is based on:

• Comparison of the results from different laboratories and/or methods. The analyses are

repeated if a large disparity is noted (generally more than 10%).

• Calculation of charge balance errors according to the equation below. Relative errors within

± 10% are considered acceptable in surface waters.

Relative error ( )( ) ( )

( ) ( )∑ ∑

∑ ∑

+

−×=

equivalentsanionsequivalentscations

equivalentsanionsequivalentscations100%

• General expert judgement of plausibility based on earlier results and experience.

Table 5-3. File types stored in the Sicada file archive.

Type of file Example of file name No. per sampling session

Raw data file L580438.dat 1 or 2*

Comments Kommentarer V38.xls 1

Calibration data file 000113CF.txt 1 or 2*

Calibration protocol Stora sonden V38år04.xls 1 or 2*

Photography PFM66.jpg 1–4

Light data file PAR-profiler V38_04.xls 1

* Depending on the number of measuring sondes used.



22

All results from special analyses of trace metals and isotopes are inserted directly into primarydata tables. In those cases where the analyses are repeated or performed by more than one labo-ratory, a “best choice” notation will indicate those results which are considered most reliable.

An overview of the data management is given in Figure 5-4.

5.5.2 Field measurement data

The logged data from sonde measurements are exported digitally from the YSI Terminal650-MDS to the specified Sicada data table. The original raw data file, calibration file andcalibration protocol from each sonde, as well as photographs and comments on sampling andmeasurements, are stored in the Sicada file archive, see Table 5-3.

5.5.3 Other relevant information and data

Information about weather conditions and related parameters during the sampling occasions arecompiled in a separate table in Sicada called “Weather_data” which contains the following columns:

Figure 5-4.

Overview of data management for analytical data.

Water sampleComments on sampling

Insertion of sampling activity & sample no. SICADA

Basic water analysis bySKB

Mobile field laboratory or Äspö chemical laboratory

Basic water analysis byexternal laboratory

Special analysis byexternal laboratory

SICADA- insertion of raw data(- calculation of result, SKB analysis)(- selection of best determ. or aver. calc. SKB analyses)- storage in raw data tables

SICADA- charge balance calculation- quality control- selection of dataset for sample- insertion of comments on controland evaluation- transfer of data to primary datatable

SICADA- Storage in primary data table- QC

Storage of raw data- File system- Binders



23

Air temperature Wind velocity Runoff/Water flow

Cloudiness Wind direction Water depth

Precipitation Light penetration(lakes and sea)

Snow/ice depth

These data are not presented in this report.

5.6 Nonconformities

The only nonconformities that occurred during the reported sampling period involve omittedsampling locations due to, for example, problems with ice. The reasons for deviations from the

programme are compiled in Tables 5-4 and 5-5.



24

T a b l e 5

- 4 . C o l l e c t e d s a m p l e s a n d c o n d u c t e d m e a s u r e m e n t s .

W e e k / y e

a r

2 8 / 0 5

3 1 / 0 5

3 6 / 0 5

4 0 / 0 5

4 4

/ 0 5

4 8 / 0 5

5 1 / 0 5

0 4 / 0 6

0 8 / 0 6

1 2 / 0 6

1 6 / 0 6

2 0 / 0 6

2 4 / 0 6

S u m ( x )

S o n d

Y S I 6 6 0 0

X

X

X

X

X

X

X

X

X

X

X

X

S e a

N a m e

P F M 0 0 0

0 6 2

S V - F o r s l i n g e n

X

X

X

X

X

X

X

X

X

X

1 0

P F M 0 0 0

0 8 2

A l t P F M 0 0 0 0 6 2

X

X

X

3

P F M 1 0 2

2 6 9

C o o l i n g w a t e r o u t l e t

L a k e B i o t e s t e n

X *

X * *

X * *

X * *

X * *

X * *

X * *

7

S t r e a m

P F M 0 0 0

0 6 6

Ö - G u n n a r s b o

X

X

X

E

X

X

X

X

X

X

X

X

X

1 2

P F M 0 0 0

0 6 8

K u n g s t r ä s k e t

X

X

X

X

X

X

X

X

X

X

X

X

X

1 3

P F M 0 0 0

0 6 9

B o l u n d s s k o g e n

X

X

X

X

X

X

X

X

X

X

X

X

X

1 3

P F M 0 0 0

0 7 0

N - E c k a r f j ä r d e n

X

X

X

X

X

X

X

X

X

X

X

X

X

1 3

L a k e s

P F M 0 0 0

0 7 4

L a b b o t r ä s k e t

X

X

X

X

X

X

X

X

X

X

X

X

X

1 3

P F M 0 0 0

0 9 7

N o r r a b a s s ä n g e n

B

X * * *

B

B

B

B

B

B

X * * *

X * * *

B

B

B

3

P F M 0 0 1

0 7

B o l u n d s f j ä r d e n

X

X

X

X

X

X

X

X

X

X

X

X

X

1 3

P F M 0 0 1

1 7

E c k a r f j ä r d e n

X

X

X

X

X

X

X

X

X

X

C

X

X

1 2

S u m ( X )

9

9

8

7

8

8

8

9

1 0

1 0

8

9

9

1 1 2

E x p l a n a

t i o n s a n d a b b r e v i a t i o n s :

X : S a m p

l e t a k e n

* O n l y t r i t i u m ,

d e u t e r i u m a n d 1 8 O

B : N o s a

m p l e , o n l y f i e l d m e a s u r e m e n t s w i t h s o n

d e

* * O n l y t r i t i u m a n d a n i o n s

C : N o s a m p l e ,

d u e t o w e a k i c e

* * * O n l y o x y g e n s a m p l e d u e t o m e a s u r e d l o w o x y g e n v a l u e

E : N o s a

m p l e ,

d r y c o n d i t i o n s , o r t o o l i t t l e w a t e r t o c o l l e c t a n r e p r e s e n t a t i v e s a m p l e



25

T a b l e 5

- 5 . C o m m e n t s o n m e a s u r e m e n t s / w a t e r s a m p l i n g .

W e e k / y e

a r

2 8 / 0 5

3 1 / 0 5

3 6 / 0 5

4 0 / 0 5

4 4

/ 0 5

4 8 / 0 5

5 1 / 0 5

0 4 / 0 6

0 8 / 0 6

1 2 / 0 6

1 6 / 0 6

2 0 / 0 6

2 4 / 0 6

S o n d

Y S I 6 6 0 0

X

X

X

X

X

X

X

X

X

X

X

X

X

S e a

N a m e

P F M 0 0 0

0 6 2

S V - F o r s l i n g e n

J

J

J

J

P F M 0 0 0

0 8 2

A l t P F M 6 2

J

J

U

P F M 1 0 2

2 6 9

C o o l i n g w a t e r o u t l e t

L a k e B i o t e s t e n

S t r e a m

P F M 0 0 0

0 6 6

Ö - G u n n a r s b o

H

H ,

Z

H ,

Z

H

F ,

S

F ,

Z

F

F ,

Z

H

P F M 0 0 0

0 6 8

K u n g s t r ä s k e t

H ,

Z

H

H

H ,

Z

H

F ,

S

F ,

Z

F

F

H

P F M 0 0 0

0 6 9

B o l u n d s s k o g e n

H

F ,

Z

F ,

Z

F ,

Z

F ,

Z

P F M 0 0 0

0 7 0

N - E c k a r f j ä r d e n

H

H

H

H

H

F

F ,

Z

F

F ,

Z

H

L a k e s

P F M 0 0 0

0 7 4

L a b b o t r ä s k e t

Z

Z

Q ,

Z

Z

Z

J

P F M 0 0 0

0 9 7

N o r r a b a s s ä n g e n

Z

Q

J

J ,

Q ,

Z

Q ,

Z

Q ,

Z

P F M 0 0 1

0 7

B o l u n d s f j ä r d e n

J

J

Z

Z

Z

K

J

P F M 0 0 1

1 7

E c k a r f j ä r d e n

U ,

Z

Q ,

Z

Z

E x p l a n a

t i o n s t o c o d e s / a b b r e v i a t i o n s :

F : N o f l o

w e s t i m a t i o n .

H : S t a g n a n t w a t e r o r n e a r l y s t a g n a n t w a t e r - n o

f l o w e s t i m a t i o n ,

f l o w a p p r o x 0 m 3 / s .

J : I n c o r r

e c t P A R - v a l u e s a t o n e o r s e v e r a l d e p t h s ( m a i n l y c a u s e d b y w a v e s o r c l o u d s ) .

K : S a m p

l e t a k e n a t a n o t h e r p o s i t i o n ,

“ c l o s e b y ” ,

d u e t o w e a k i c e ( a p p l i e s o n l y t o s u r f a c e

s a m p l e s ) .

Q : R i s k f o r i n c o r r e c t s o n d e v a l u e s f o r P A R ,

T u r b i d i t y a n d C h l o r o p h y l l , d u e t o p l a n t s a n d

/ o r p a r t i c l e s i n t h e w a t e r .

S : P e r i s t a l t i c p u m p s y s t e m o u t o f o r d e r , s a m p l e

c o l l e c t e d w i t h R u t h n e r - s a m p l e r .

U : I n c o r r e c t s o n d e - d a t a l o g g i n g , n o t e d i n f i e l d p r o t o c o l .

Z : W i n k l e r s a m p l e s ( 2 ) c o l l e c t e d ,

d u e t o l o w o x y

g e n l e v e l .



27

6 Results

6.1 GeneralThe surface water investigation period from July 2005 to June 2006 includes records of 120water analyses (i.e. number of analysed samples) and records of 300 field measurements.Furthermore, the accompanying field documentation is quite extensive. The data are compiledin the attached appendices and stored in the Sicada database where they are traceable by theactivity plan number.

Fresh waters in the Forsmark area are well buffered with high alkalinity, high pH and highcalcium concentrations. In addition, waters recently affected by brackish sea water still showhigh sodium chloride concentrations. The relationship between the position of the coastlineand the salinity of the water samples collected at the sampling locations in the area has beendemonstrated in /3/. Furthermore, a detailed evaluation of surface water data from March 2002

to March 2004 was presented in /5/.The results presented and compiled in this report are restricted to field work performed afterJuly 2005 except for the ORP-measurements which are plotted in diagrams versus date since thestart 2002 to show the seasonal variation. Some of the more thoroughly discussed issues are:

• Check of consistency by comparison between TDS (Total Dissolved Solids) calculated from

water composition and from EC (Electrical Conductivity).

• Improved quality of bromide analyses.

• Tritium result from the additional sampling object (outlet of cooling water into Lake Biotestsjön).

• Seasonal variation of ORP-measurements.

6.2 Water analyses

6.2.1 Major components

The basic water analyses include the major constituents Na, K, Ca, Mg, Sr, S, SO42– , Cl – , Si

and HCO3 – as well as the minor constituents Fe, Li, Mn, Br, F – , I and HS – . Furthermore, batch

measurements of pH and electrical conductivity are included. The basic water analysis dataare compiled together with field measurements of pH and water temperature in Appendix 5,Table A5-1.

The charge balance errors give an indication of the quality and uncertainty of the analyses ofmajor constituents. The errors exceed ± 5% in 23 cases and no case exceeded ± 10% out of120 datasets. Furthermore, duplicate analyses by a second laboratory are conducted regularly.Comparison between results from different laboratories and methods shows acceptable agree-ment in most cases. Generally, the difference in concentrations between laboratories/methodsfor each analysed constituent is less than ± 10%. A constituent showing larger deviation is

bromide; see Figure 6-6.

To provide a rough check of the data, the electrical conductivity values are plotted versus thecorresponding chloride concentrations in Figure 6-1. As shown, the near surface groundwaterdata generally agree well with a thought regression line. Another way to check the consistencyof the data is to calculate TDS (Total Dissolved Solids) from water composition and fromEC (Electrical Conductivity), respectively. A diagram comparing the TDS values is given in

Figure 6-2. The conversion factor between EC and TDS varies (from 5 to 9 according toliterature) depending on water type but should coincide for similar water samples.



28

Sulphate by ion chromatography and sulphate calculated from total sulphur by ICP are

compared in Figure 6-3. As shown, within the analytical error nearly all the sulphur is presentas sulphate.

Total silicon concentrations by ICP, and SiO4 as silicon concentrations (SiO4-Si) by spectrophotometry, are compared in Figure 6-4. The diagram shows very good agreement althoughsomewhat higher total silicon concentrations may be expected/explained.

Figure 6-1. Electrical conductivity versus chloride concentrations. EC_L = Laboratory value,

EC_F = Field value.

Figure 6-2. TDS (Total Dissolved Solids) calculated from EC versus TDS from water composition.

TDS (mg/L) = a×EC(mS/m) where a = 5.6 in sea water and a = 8.5 in fresh water.

0

200

400

600

800

1000

1200

0 500 1000 1500 2000 2500 3000 3500

Chlorid (mg/L)

E l e c t r i c a l c o n d u

c t i v i t y ( m S / m )

EC_L (mS/M)

EC_F (mS/m)

0

1000

2000

3000

4000

5000

6000

0 1000 2000 3000 4000 5000 6000

TDS (mg/L) water composition

T D S ( m g / L ) E C

TDS_EC



29

Bromide

As established earlier /4/, bromide determinations by ion chromatography may be difficult at highchloride concentrations. Selected bromide values (in most cases ICP results) for each sample are

plotted versus the corresponding chloride concentrations in Figure 6-5 as a consistency check.The points do not differ too much from the linear trend and the data are therefore consideredacceptable. A comparison of the analytical results by ion chromatography (IC) and by ICP is

presented in Figure 6-6. As demonstrated, some high bromide concentrations (sea water) by ionchromatography show deviations. However, these data points derive from early analyses beforeOctober 2005. The quality of the bromide analyses by IC have been improved since then afterchange of IC-column.

Figure 6-3. Sulphate (SO4 – by IC) versus sulphate calculated from total sulphur (3×SO4

– S) by ICP.

Figure 6-4. SiO4-Si determined by spectrophotometry versus total Si analysed by ICP.

0

50

100

150

200

250

300

350

400

450

500

0 100 200 300 400 500

SO4 IC (mg/L)

3 x S O

4 – S I C P ( m g / L )

0

1

2

3

4

5

6

7

8

9

10

0 1 2 3 4 5 6 7 8 9 10

Si_ICP (mg/L)

S i O

4 – S i ( m g / L

)



30

Figure 6-5. Bromide versus chloride.

Figure 6-6. Comparison of bromine by ICP technique and bromide by ion chromatography.

0

2

4

6

8

10

12

14

0 500 1000 1500 2000 2500 3000 3500

Chloride (mg/L)

B r o m i d e ( m g / L )

0

5

10

15

20

25

30

0 5 10 15 20 25 30

Br_IC (mg/L)

B r_ I C P ( m g / L )



31

6.2.2 Trace metals

The analyses of trace and rare-earth elements include Al, As, Sc, Cd, Cr, Cu, Co, Hg, Ni, Zn, Pb,V, U, Th , Rb, Y, Zr, Mo, In, Sb, Cs, Ba, La, Hf, Tl, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm,Yb and Lu. The trace element data are compiled in Appendix 5, Table A5-4.

These elements are generally present at low concentrations in the groundwater and the risk forcontamination is high. Especially data on common metals like Al, Cr, Cu, Co, Ni and Zn must

be used with caution. Generally, the distribution of data is location specific but outliers do exist;significantly large deviating concentrations for a sampling location are rejected in the Sicadadatabase.

6.2.3 Surface water supplements

The surface water supplements include NH4-N, NO2-N, NO3-N+NO2-N, NO3-N, tot-N, tot-P,PO4-P, TOC, DOC, DIC and sometimes at a few sampling occasions also dissolved oxygen. Theanalytical data are compiled in Appendix 5, Table A5-2. The DIC values should be used withcare and bicarbonate values (by alkalinity titration) are considered more reliable.

6.2.4 Isotopes

The isotope determinations include the stable isotopes δD, δ18O, 10B/11B, δ34S, δ13C, δ37Cl and87Sr/86Sr as well as the radioactive isotopes Tr (TU), 14C (pmC), 238U, 235U, 234U, 232Th, 230Th,226Ra and 222Rn. The isotope data are compiled in Appendix 5, Table A5-3.

Tritium

It has been suggested that the adjacent nuclear power plant may have influenced the naturalconditions for the tritium and 14C isotopes /4/. Some relation between the presence of these iso-topes and distance from the nuclear power reactors was observed during the previous sampling

period March 2004 to June 2005. In order to better understand the tritium data, repeated tritiumdeterminations from close to the outlet of reactor cooling water commenced in July 2005.Of the seven samples analysed so far, only the first sample collected in July 2005 revealedenhanced tritium concentration (120.7 TU). The latter samples showed normal concentrations

between 8.5 and 12.9 TU. Samples from the regular sampling locations did not measure anyexceptionally high tritium contents during this last year. These circumstances indicate thatcontamination from the nuclear power plant does occur at times.

Uranium isotopes

The ICP analyses of uranium and the converted 238U-determinations are compared in Table 6-3

and the agreement is quite good.

Table 6-3. Comparison of uranium (µg/L) calculated from 238U-determinations and Uranium

(µg/L) by ICP-MS.

Id code Date Sample

no.

238U

(mBq/L)

U (µg/L) calc.

from 238U*

U (µg/L)

ICP

PFM000107 2005-07-11 8938 25.3 2.04 2.17

PFM000062 2005-07-11 8936 7.4 0.60 0.70

PFM000074 2005-07-11 8937 14.9 1.20 1.41

PFM000117 2005-07-11 8935 15.3 1.23 1.23

* 1 ppm U = 12.4 Bq/kg238U



32

6.3 Field measurements

The field measurement data including redox potential, pH, dissolved oxygen, electrical conduc-tivity, salinity, measurement depth, barometric pressure, turbidity, chlorophyll, light penetration,PAR (Photosynthetic Active Radiation) and water temperature are compiled in Appendix 2. ThePAR-profile logs are presented as diagrams including regression constants in Appendix 3. Three

sets of data are of lower quality; 1) water flow data, 2) sonde measurements (YSI 6600 EDS) ofchlorophyll, and 3) turbidity measurements also by the sonde.

• The water flow rate estimations (Appendix 4) by the float method /6/ are of low accuracy

compared to measurements using discharge weirs and gauges. They were performed in orderto allow comparison between early data obtained when there was no other available methodand new data from installed measurement stations.

• The chlorophyll measurements have been problematic, possibly due to the fact that humic

substances and chlorophyll have similar fluorescence in the wavelength used by the sonde.Since the inland waters show high concentrations of humic substances and the sondeinterprets humus as chlorophyll, the amount of chlorophyll tends to be overestimated.

• The turbidity measurements performed in the sea and in lakes often display negative values.

This may be due to bad probe sensitivity in clear waters (turbidity weak waters).

Comments on the low quality of chlorophyll and turbidity data as well as explanations to thesecircumstances are stored in the Sicada database.

6.3.1 Electrical conductivity, pH and dissolved oxygen

pH-measurement

Field measurements of pH are plotted against the corresponding laboratory values in Figure 6-7.The observed disagreement is reasonable considering the change of water temperature and thetime delay prior to the laboratory measurement. However, in some cases, the disagreement seems

to be greater than expected.

Electrical conductivity

Electrical conductivities measured in the field are plotted against the corresponding laboratoryvalues in Figure 6-8. The agreement is good.

Dissolved oxygen

The field measurements of dissolved oxygen were expected to be less reliable, especially at lowconcentration (< 4 mg/L), see evaluation of the equipment (Jämförelse mellan sondmätningaroch laboratorieresultat i Forsmark och Simpevarp 2002 to 2003, Ulf Ericsson, Medins Sjö- och

Åbiologi AB, 2003-06-03). In Figure 6-9 measured oxygen concentrations below 4 mg/L are plotted versus corresponding analytical results. A few laboratory analyses show much higherconcentrations than the ones measured in the field. A possible reason might be contamination byoxygen from the air at the sampling occasion.

6.3.2 ORP-measurements and redox conditions

ORP-measurements (Oxidising-Reducing Potential) have been conducted using themultipurpose measurement sonde in surface waters from lakes, streams and shallow sea bays.The recorded ORP-values (versus Ag/AgCl reference electrode and not Standard HydrogenElectrode (SHE)) should be used with great caution and merely considered as an indication

of the redox conditions in the waters. Factors that may affect certainty/reliability of the ORP-values are short measurement time (10–15 minutes) and complicated redox conditions (mixed potentials etc.).



33

Figure 6-7. Field-pH values versus laboratory-pH values. Field-pH and laboratory-pH values are

measured at prevailing water temperature and at 25°C respectively.

Figure 6-8. Electrical conductivity (25°C). Field measurements versus laboratory values.

Figure 6-9.

Dissolved oxygen. Field measurement versus laboratory analytical results. Values belowdetection limit are plotted as zero. Analyses are performed when the measured values record less than

4 mg/L.

6.5

7

7.5

8

8.5

9

9.5

6.5 7 7.5 8 8.5 9 9.5

pH_L

p H

_ F

0

200

400

600

800

1000

1200

0 200 400 600 800 1000 1200

EC_L (mS/m)

E C_

F ( m S / m )

0

200

400

600

800

1000

1200

0 200 400 600 800 1000 1200

EC_L (mS/m)

E C_

F ( m S / m )



34

Figures 6-10 to 6-12 present the seasonal variation of the ORP-values in lakes, streams andshallow sea bays respectively. As expected, the ORP decreases in the lakes and streams duringwinter time due to ice coverage and low biological production. This phenomenon is less

pronounced in the sea bays. As reported previously /4/, the concentrations of dissolved oxygenand ORP-values were proved to be consistent for the time period December 2002 until October2005 and this is the case also for the eight additional measurement occasions after that period.

Figure 6-10. Seasonal variation of ORP-values in lake waters from start of measurements (December

2002 to June 2006).

Figure 6-11. Seasonal variation of ORP-values in stream waters from start of measurements (December

2002 to June 2006).

-400

-300

-200

-100

0

100

200

300

400

2002-09-01 2003-08-17 2004-08-01 2005-07-17 2006-07-02

Date

O R P ( m V )

PFM000074

PFM000097

PFM000107

PFM000117

-400

-300

-200

-100

0

100

200

300

400

2002-09-01 2003-08-17 2004-08-01 2005-07-17 2006-07-02

Date

O R P ( m V )

PFM000066

PFM000068

PFM000069

PFM000070



35

Figure 6-12. Seasonal variation of ORP-values at sea bay locations from start of measurements

(December 2002 to June 2006).

-400

-300

-200

-100

0

100

200

300

400

2002-09-01 2003-08-17 2004-08-01 2005-07-17 2006-07-02

Date

O R P ( m V )

PFM000062

PFM000063

PFM000064

PFM000065



37

7 Summary and discussion

The chemical investigation routines for surface waters are well established after more than fouryears of field work, reporting and data administration and the second year of the long-termsurface water monitoring programme has passed without any major nonconformities or surprises.

The main experiences and conclusions from surface water sampling and analyses since July2005 are summarised below:

• The statements/findings regarding the character of the surface waters after the fourth year

of sampling and analyses remain unchanged.

• The additional data records from the deep seawater location verify the stable chemical

conditions that are expected in seawater.

• The bromide analyses by ion chromatography have improved after October 2005.

• The sampling for tritium analyses performed close to the outlet of cooling water from the power plant revealed an enhanced value in July 2005 (120.7 TU) but the following samplesshowed normal concentrations. These circumstances indicate that contamination from thenuclear power plant may occur at times.

• The ORP measurements continued to display similar seasonal variation as reported

previously /4/.



39

References

/1/ SKB, 2001. Site investigations. Investigation methods and general execution programme.SKB TR-01-29, Svensk Kärnbränslehantering AB.

/2/ Nilsson A-C, Karlsson S, Borgiel M, 2003. Forsmark site investigation. Samplingand analyses of surface waters. Results from sampling in the Forsmark area, March 2002to March 2003. SKB P-03-27, Svensk Kärnbränslehantering AB.

/3/ Nilsson A-C, Borgiel M, 2004. Forsmark site investigation. Sampling and analyses ofsurface waters. Results from sampling in the Forsmark area, March 2003 to March 2004.SKB P-04-146, Svensk Kärnbränslehantering AB.

/4/ Nilsson A-C, Borgiel M, 2005. Forsmark site investigation. Sampling and analysesof surface waters. Results from sampling in the Forsmark area, March 2004 to June 2005.SKB P-05-274, Svensk Kärnbränslehantering AB.

/5/ Sonesten L, 2004. Evaluation of surface water chemistry data from the Forsmark area.March 2002 to March 2004. SKB R-05-41, Svensk Kärnbränslehantering AB.

/6/ SKB, 2005. Forsmark site investigation. Programme for further investigations of geosphereand biosphere. SKB R-05-14, Svensk Kärnbränslehantering AB.

/7/ Johansson, P-O, 2005. Forsmark site investigation. Manual discharge measurementsin brooks, April 2002 to April 2005. SKB P-05-153, Svensk Kärnbränslehantering AB.



41

A p p e n d i x 1

M e t h

o d s f o r s a m p l i n g a n d a

n a l y s e s

T a b l e A

1 - 1 . S a m p l e h a n d l i n g r o u t i n e s a

n d a n a l y t i c a l m e t h o d s .

C o m p o n

e n t g r o u p

C o m p o n e n t / e l e m e n t

S a m p l e

c o n t a i n e r

( m a t e r i a l )

V o l u m e

( m L )

F i l t e r i n g

P r e p a r a t i o n /

C o n s e r v a t i o n *

A n a l y s i s

m e t h o d

A

n a l y s i s w i t h i n –

o r d e l i v e r y t i m e t o l a b .

A n i o n s 1

H C O 3

p H ( l a b )

c o n d ( l a b )

P l a s t i c

2 5 0

Y e s ( n o t i n t h e

f i e l d )

N o

T i t r a t i o n

P o t . m e a s ,

C o n d . m e a s

T h e s a m e d a y

–

m a x i m u m 2 4

h o u r s

A n i o n s 2

C l , S O 4 ,

B r – ,

F – ,

I –

P l a s t i c

1 0 0


f i e l d )

N o

T i t r a t i o n ( C l – )

I C ( C l – ,

S O 4 ,

B r – ,

F – )

I S E ( F – )

N

o t c r i t i c a l ( m o n t h )

B r , I

P l a s t i c

1 0 0


f i e l d )

N o

I C P M S

N


C a t i o n s ,

S i a n d S

a c c o r d i n

g t o S K B

c l a s s 3

N a ,

K ,

C a ,

M g ,

S ( t o t ) ,

S i ( t o t ) , L i , S r

P l a s t i c ( a t l o w

c o n c . a c i d

w a s h e d b o t t l e s )

1 0 0


f i e l d )

Y e s ( n o t i n t h e f i e l d

,

1 m L H N O 3 )

I C P - A E S

I C P - M S

N


C a t i o n s ,

S i a n d S

a c c o r d i n

g t o S K B

c l a s s 4 a n d 5

N a ,

K ,

C a ,

M g ,

S ( t o t ) ,

S i ( t o t ) , F e ,

M n ,

L i , S r

P l a s t i c ( A c i d

w a s h e d )

1 0 0

Y e s ( i m m e d i a t e l y

i n t h e f i e l d )

Y e s ( 1 m L H N O 3 )

I C P - A E S

I C P - M S

N


F e ( I I ) , F e ( t o t )

F e ( I I ) , F e ( t o t )


w a s h e d )

5 0 0

Y e s

Y e s ( 5 m L H C l ) )

S p e c t r o p h o t o m e t r y

F e r r o z i n e m e t h o d

A s s o o n a s p o s s i b l e

t h

e s a m e d a y

H y d r o g e

n s u l p h i d e

H S -

G l a s s ( W i n k l e r )

A b o u t 1 2 0 × 2

N o

E v 1 m L 1 M N a O H

+

1 m L 1 M Z n A c


I m

m e d i a t e l y o r i f

c o n s e r v e d , a f e w d a y s

E n v i r o n m e n t a l

m e t a l s

A l , A s ,

B a ,

B ,

C d ,

C o ,

C r , C u ,

H g ,

M o ,

N i , P ,

P b ,

V ,

Z n


w a s h e d )

1 0 0

Y e s

Y e s ( 1 m L H N O 3 )

I C P - A E S

I C P - M S

N


L a n t a n o

i d s ,

U ,

T h

a n d s o o

n .

S c ,

R b ,

Y ,

Z r , I , S b ,

C s ,

L a ,

H f , T l , C e ,

P r , N d ,

S m

,

E u ,

G d ,

T b ,

D y ,

H o ,

E r ,

T m ,

Y b ,

L u ,

U ,

T h


w a s h e d )

1 0 0

Y e s

Y e s ( 1 m L H N O 3 )

I C P - A E S

I C P - M S

N


D i s s o l v e

d o r g a n i c

C a r b o n ,

d i s s o l v e d

i n o r g a n i c C a r b o n

D O C ,

D I C

P l a s t i c

2 5 0

2 5

Y e s

F r o z e n ,

t r a n s p o r t e d

i n i s o l a t e d b a g

U V o x i d a t i o n ,

I R

C a r b o n a n a l y s a t o r

S h i m a d z u T O C 5 0 0 0

S h o r t t r a n s p o r t a t i o n

t i m e



42

C o m p o n

e n t g r o u p


S a m p l e

c o n t a i n e r

( m a t e r i a l )

V o l u m e

( m L )

F i l t e r i n g



A n a l y s i s

m e t h o d

A



T o t a l o r g a n i c

C a r b o n

T O C

P l a s t i c

2 5 0

2 5

N o

F r o z e n ,

t r a n s p o r t e d

i n i s o l a t e d b a g


I R

C a r b o n a n a l y s a t o r S h i -

m a d z u T O C 5 0 0 0


t i m e

E n v i r o n m e n t a l

i s o t o p e s

2 H ,

1 8 O

P l a s t i c

1 0 0

N o

– –

M S

N


T r i t i u m ,

C h l o r i n e

- 3 7

3 H ( e n h a n c e d . )

C h l o r i n e - 3 7

P l a s t i c ( d r y b o t t l e )

P l a s t i c

5 0 0

1 0 0

N o N o

– –

L S C

M S

N


C a r b o n i s o t o p e s

1 3 C ,

1 4 C

G l a s s ( b r o w n )

1 0 0 × 2

N o

–

( A ) M S

A

f e w d a y s

S u l p h u r

i s o t o p e s

3 4 S

P l a s t i c

5 0 0 – 1 , 0

0 0

Y e s

–

C o m b u s t i o n ,

M S

N

o l i m i t

S t r o n t i u m - i s o t o p e s

8 7 S r / 8 6 S r

P l a s t i c

1 0 0

Y e s

–

T I M S

D

a y s o r W e e k

U r a n i u m

a n d

T h o r i u m

i s o t o p e s

2 3 4 U ,

2 3 5 U ,

2 3 8 U ,

2 3 2 T h ,

2 3 0 T h ,

P l a s t i c

5 0

N e j

–

C h e m i c a l s e p a r a t .

A l f a / g a m m a s p e c t r o m e t r y

N

o l i m i t

B o r o n i s

o t o p e s

1 0 B

P l a s t i c

1 0 0

Y e s

Y e s ( 1 m L H N O 3 )

I C P - M S

N

o l i m i t

R a d o n a

n d

R a d i u m

i s o t o p e s

2 2 2 R n ,

2 2 6 R a

P l a s t i c

5 0 0

N o

N o

E D A ,

R D - 2 0 0

I m

m e d i a t e t r a n s p o r t

D i s s o l v e

d g a s

( c o n t e n t a n d

c o m p o s i t i o n )

A r , N 2 ,

C O 2 ,

O 2 ,

C H 4 ,

H 2 ,

C O ,

C 2 H 2 ,

C 2 H 4 ,

C 2

H 6 ,

C 3

H 8

C y l i n d e r o f

s t a i n l e s s s t e e l

2 0 0

N o

N o

G C

I m


C o l l o i d s

F i l t e r s e r i e s a n d

f r a c t i o n a t i o n ( s e e b e l o w )

P o l y c a r b o n a t e

f i l t e r

0 . 4

5 ,

0 . 2 a n d

0 . 0

5 µ m

–

N 2 a t m o s p h e r e

I C P - A E S

I C P - M S

I m


H u m i c a

n d f u l v i c

a c i d s

F r a c t i o n a t i o n

F r a c t i o n s a r e

c o l l e c t e d i n p l a s t i c

b o t t l e s

2 5 0

–

N 2 a t m o s p h e r e


I R ( D O C )

I m


A r c h i v e

s a m p l e s

w i t h a c i d

–

P l a s t ( w a s h e d

i n a c i d )

1 0 0 × 2 * *

Y e s

Y e s ( 1 m L H N O 3 )

–

S t o r a g e i n f r e e z e

c o n t a i n e r

A r c h i v e

s a m p l e s

w i t h o u t a c i d

–

P l a s t i c

2 5 0 × 2 * *

Y e s

N o

–


c o n t a i n e r

C a r b o n i s o t o p e s

i n h u m i c

a n d f u l v i c

a c i d s

1 3 C ,

1 4 C ( p m c )

D E A E

c e l l u l o s e ( a n i o n

e x c h a n g e r )

–

–

–

( A ) M S

A

f e w d a y s

N u t r i e n t

s a l t +

s i l i c a t e

N O 2 ,

N O 3 ,

N O 2 + N O 3 ,

N H 4 ,

P O 4 ,

S i O 4

S a m p l e t u b e s ,

p l a s t i c

2 5 × 2

Y e s ( i n t h e

f i e l d )

N o ,

f r o z e n

i m m e d i a t e l y * * *



t i m e



43

C o m p o n

e n t g r o u p


S a m p l e

c o n t a i n e r

( m a t e r i a l )

V o l u m e

( m L )

F i l t e r i n g



A n a l y s i s

m e t h o d

A



T o t a l c o n c e n t r a t i o n s

o f N i t r o g

e n a n d

P h o s p h o r o u s

N - t o t , P - t o t

P l a s t i c

1 0 0

N o

N o ,

f r o z e n

i m m e d i a t e l y * * *



t i m e

P a r t i c u l a t e C a r b o n ,

N i t r o g e n

a n d

P h o s p h o r o u s

P O C ,

P O N ,

P O P

P l a s t i c

1 , 0

0 0

Y e s ( w i t h i n 4 h )

p r e p a r e d f i l t e r s .

B l a n k f i l t e r s

F i l t e r i n g ,

t h e f i l t e r s

a r e f r o z e n i m m e d i a

t e l y

2 f i l t e r s / s a m p l e

E l e m e n t a r - a n a l y s a t o r ( N ,

C )

o w n m e t h o d 9 9 0 1 2 1 ( P )


t i m e

C h l o r o p h y l l

C h l o r o p h y l l a , c a n d

p h e o p i g m e n t

P l a s t i c

1 , 0

0 0 – 2 , 0

0 0

Y e s ( w i t h i n 4 h )

F i l t e r i n g ,

t h e f i l t e r s

a r e f r o z e n i m m e d i a

t e l y


F l u o r o m e t r y


t i m e

O x y g e n

D i s s o l v e d O 2

W i n k l e r , g l a s s

2 × c a 1 2 0

N o

M n ( I I ) r e a g e n t

I o d i d e r e a g e n t

S p e c t r o p h o t o m e t r y S I S

S S - E N 2 5 8 1 3

W

i t h i n 3 d a y s

A r c h i v e

s a m p l e s

f o r s u p p

l e m e n t a r y

r a d i o n u

c l i d e s

P l a s t i c

5 , 0

0 0

N o

5 0 m L H N O 3

–


c o n t a i n e r

*

S u p r a p u r a c i d i s u s e d f o r c o n s e r v a t i o n o f s a

m p l e s .

* * M i n i m u m n u m b e r . T h e n u m b e r o f a r c h i v e s a

m p l e s c a n v a r y d e p e n d i n g o n t h e n u m b

e r o f s i m i l a r s a m p l e s c o l l e c t e d a t t h e s a

m e o c c a s i o n .

* * * T h e s a m p l e i s t r a n s p o r t e d i n f r o z e n c o n d i t i o n t o t h e l a b o r a t o r y .

I t i s p o s s i b l e t h a t t h e

s i l i c a t e c o n c e n t r a t i o n c a n c h a n g e d u e t o p o l y m e r i s a t i o n f o r t h i s r e a s o n .

A b b r e v i a t i o n s a n d d e f i n i t i o n s :

I C

I o n c h r o m a t o g r a p h

I S E

I o n s e l e c t i v e e l e c t r o d e

I C P - A E S

I n d u c t i v e l y C o u p l e d P l a s m a

A t o m i c E m i s s i o n S p e c t r o m e t r y

I C P - M S

I n d u c t i v e l y C o u p l e d P l a s m a

M a s s S p e c t r o m e t r y

I N A A

I n s t r u m e n t a l N e u t r o n A c t i v a t

i o n A n a l y s i s

M S

M a s s S p e c t r o m e t r y

T I M S

T h e r m a l I o n i z a t i o n M a s s S p e c t r o m e t e r

L S C

L i q u i d S c i n t i l l a t i o n C o u n t i n g

( A ) M S

( A c c e l e r a t o r ) M a s s S p e c t r o m

e t r y

G C

G a s C h r o m a t o g r a p h y



44

Table A1-2. Reporting limits and measurement uncertainties.

Component Method Reporting

limits or range

Unit Measurement

uncertainty 2

”Total”

uncertainty 3

HCO3 Alkalinity titration 1 mg/L 4% < 10%

Cl –

Cl –Mohr-titration

IC

> 70

1–100

mg/L 5%

6%

< 10%

10%SO4 IC 1 mg/L 10% 15%

Br – Br –

ICICP

0.20.001

mg/L 9%15%

20%

F – F –

ICPotentiometric

0.1 –

mg/L 10% –

20%

I – ICP 0.001 mg/L 15% 20%

Na ICP 0.1 mg/L 4% 10%

K ICP 0.4 mg/L 6% 15%

Ca ICP 0.1 mg/L 4% 10%

Mg ICP 0.09 mg/L 4% 10%

S(tot) ICP 0.160 mg/L 21% 15%Si(tot) ICP 0.03 mg/L 4% 15%

Sr ICP 0.002 mg/L 4% 15%

Li ICP 0.21 2 mg/L 10% 20%

Fe ICP 0.41 4 mg/L 6% 10%

Mn ICP 0.031 0.1 µg/L 8% 10%

Fe(II), Fe(tot) Spectrophotometry 0.02(DL = 0.005 mg/L)

mg/L 15% (> 30 µg/L) 20%

HS- Spectrophotometry SKB 0.03(DL = 0.002)

mg/L 10% 30% (lowconc.)

NO2 as N Spectrophotometry 0.1 µg/L 2% 20%

NO3 as N Spectrophotometry 0.2 µg/L 5% 20%

NO2+NO3 as N Spectrophotometry 0.2 µg/L 0.2 (0.2–20 µg/L)2% (> 20 µg/L)

20%

NH4 as N Spectrophotometry 0.8

50 (SKB)

µg/L 0.8 (0.8–20 µg/L)5% (> 20 µg/L)

20%

20%

PO4 as P Spectrophotometry 0.7 µg/L 0.7 (0.7–20 µg/L)3% (> 20 µg/L)

20%

SiO4 Spectrophotometry 1 µg/L 3% (> 200 µg/L) –

O2 Jodometrisctitration

0.2–20 mg/L 5% –

Chlorophyll a, cpheopigment4

See table A1-2 0.5 µg/L 5% –

PON4 See table A1-2 0.5 µg/L 5% –

POP4 See table A1-2 0.1 µg/L 5% –

POC4 See table A1-2 1 µg/L 4% –

Tot-N4 See table A1-2 10 µg/L 4% –

Tot-P4 See table A1-2 0.5 µg/L 6% –

Al, Zn ICP 0.2 µg/L 12% 20%5

Ba, Cr, Mo, Pb ICP 0.01 µg/L 7–10% 20%5

Cd, Hg ICP 0.002 µg/L 9 resp 5% 20%5

Co, V ICP 0.005 µg/L 8 resp 5% 20%5

Cu ICP 0.1 µg/L 8% 20%5

Ni ICP 0.05 µg/L 8% 20%s



45

Component Method Reporting

limits or range

Unit Measurement

uncertainty 2

”Total”

uncertainty 3

P ICP 1 µg/L 6% 10%

As 1CP 0.01 µg/L 20% Correct orderof size(lowconc.)

La, Ce, Pr, Nd,Sm, Eu, Gd,Tb, Dy, Ho, Er,Tm, Yb

ICP 0.0051 0.05 µg/L 10% Correct orderof size (lowconc.)

Sc, In, Th ICP 0.051 0.5 µg/L 10% Correct orderof size (lowconc.)

Rb, Zr, Sb,Cs, Tl

ICP 0.0251 0.25 µg/L 10% Correct orderof size (lowconc.)

Y, Hf ICP 0.0051 0.05 µg/L 10% Correct orderof size (lowconc.)

U ICP 0.0011 – µg/L 12% Correct orderof size (lowconc.)

DOC See table A1-1 0.5 mg/L 8% 30%

TOC See table A1-1 0.1 mg/L 10% 30%

δ2H MS 2 ‰ SMOW5 1‰ –

δ18O MS 0.1 ‰ SMOW5 0.2‰ –3H LSC 0.8 eller 0.1 TU6 0.8 eller 0.1 –37Cl MS 0.2‰° (20 mg/L) ‰ SMOC7 – –

δ13C A (MS) – ‰ PDB8 – –14C pmc A (MS) – PMC9 – –

δ34 S MS 0.2‰ ‰ CDT10 0.3‰ –87Sr/86Sr TIMS – No unit

(ratio)11

– –

10B/11B ICP MS – No unit(ratio)11

– –

234U, 235U, 238U,232Th, 230Th222Rn, 226Rn

Alfa spectr.

LSC

0.0005

0.03

Bq/L13

Bq/L

5%

5%

–

–

1. Reporting limits at salinity ≤ 0.4% (520 mS/m) and ≤ 3.5% (3,810 mS/m) respectively.

2. Measurement uncertainty reported by consulted laboratory, generally 95% confidence interval.

3. Estimated total uncertainty by experience (includes effects of sampling and sample handling).

4. Determined only in surface waters and near surface groundwater.5. Per mille deviation13 from SMOW (Standard Mean Oceanic Water).

6. TU = Tritium Units, where one TU corresponds to a Tritium/hydrogen ratio of 10 –18 (1 Bq/L Tritium = 8.45 TU).

7. Per mille deviation13 from SMOC (Standard Mean Oceanic Chloride).

8. Per mille deviation13 from PDB (the standard PeeDee Belemnite).

9. The following relation is valid between pmC (percent modern carbon) and Carbon-14 age:

pmC = 100×e((1,950 – y – 1.03t)/8,274) where y = the year of the C-14 measurement and t = C-14 age.

10. Per mille deviation13 from CDT (the standard Canyon Diablo Troilite).

11. Isotope ratio without unit.

12. The following expressions are applicable to convert activity to concentration, for uranium-238 and thorium-232:1 ppm U = 12.4 Bq/kg238U

1 ppm Th = 3.93 Bq/kg232

Th13. Isotopes are often reported as per mill deviation from a standard. The deviation is calculated as:

δyI = 1,000×(Ksample –Kstandard)/Kstandard, where K = the isotope ratio and yI = 2H, 18O, 37Cl, 13C or 34S etc.



47

A p p e n d i x 2

F i e l d

m e a s u r e m e n t s

I d c o d e

S t a r t d a t e

S t o p d a t e

M e a s

d e p t h

( m )

W a t e r

d e p t h

( m )

S n o

t e m p .

( ° C

)

p H

E C ( m S /

m )

S a l i n i t y

( % )

T u r b *

( N T U )

L i g h t

( µ m o l / m 2 s )

O 2 d i s s .

( m g / L )


( µ g / L )

O R P

( m V )

A t m .

P r e s s u r e

( h P a )

P F M 0 0 0

0 6 2

2 0 0 5 - 0 7 - 1 1 0 8 : 0 0

2 0 0 5 - 0 7 - 1 1 1 9 : 0 0

0 . 5

3 . 5

8 9 3 6

1 6

. 8

7 . 9

4

8 8 2

4 . 9

5

0 . 0

1 4 9 8

1 0 . 3

0 . 8

1 6 1

1 0 3 6 . 9

P F M 0 0 0

0 6 2

2 0 0 5 - 0 7 - 1 1 0 8 : 0 0

2 0 0 5 - 0 7 - 1 1 1 9 : 0 0

1

3 . 5

1 6

. 0

7 . 9

2

8 8 3

4 . 9

5

0 . 1

8 1 8

1 0 . 2

2 . 2

1 6 2

1 0 3 8 . 9

P F M 0 0 0

0 6 2

2 0 0 5 - 0 7 - 1 1 0 8 : 0 0

2 0 0 5 - 0 7 - 1 1 1 9 : 0 0

2

3 . 5

1 5

. 8

7 . 9

2

8 8 4

4 . 9

6

0 . 2

7 3 0

1 0 . 2

1 . 4

1 6 3

1 0 3 9 . 1

P F M 0 0 0

0 6 2

2 0 0 5 - 0 7 - 1 1 0 8 : 0 0

2 0 0 5 - 0 7 - 1 1 1 9 : 0 0

3

3 . 5

1 5

. 6

7 . 9

1

8 8 4

4 . 9

7

0 . 4

3 1 3

1 0 . 2

1 . 8

1 6 3

1 0 3 9 . 1

P F M 0 0 0

0 6 2

2 0 0 5 - 0 8 - 0 1 0 8 : 0 0

2 0 0 5 - 0 8 - 0 1 1 9 : 0 0

0 . 5

3 . 8

8 9 5 3

1 8

. 4

8 . 2

0

9 0 1

5 . 0

6

0 . 5

2 0 8 0

1 0 . 3

1 . 0

1 6 4

1 0 1 3 . 8

P F M 0 0 0

0 6 2

2 0 0 5 - 0 8 - 0 1 0 8 : 0 0

2 0 0 5 - 0 8 - 0 1 1 9 : 0 0

1

3 . 8

1 8

. 2

8 . 2

0

9 0 1

5 . 0

6

0 . 4

9 3 5

1 0 . 3

0 . 7

1 6 4

1 0 1 4 . 4

P F M 0 0 0

0 6 2

2 0 0 5 - 0 8 - 0 1 0 8 : 0 0

2 0 0 5 - 0 8 - 0 1 1 9 : 0 0

2

3 . 8

1 8

. 1

8 . 2

0

9 0 1

5 . 0

6

0 . 6

5 0 6

1 0 . 2

2 . 1

1 6 4

1 0 1 4 . 7

P F M 0 0 0

0 6 2

2 0 0 5 - 0 8 - 0 1 0 8 : 0 0

2 0 0 5 - 0 8 - 0 1 1 9 : 0 0

3

3 . 8

1 8

. 1

8 . 2

0

9 0 1

5 . 0

6

0 . 5

3 1 0

1 0 . 2

2 . 2

1 6 4

1 0 1 5 . 0

P F M 0 0 0

0 6 2

2 0 0 5 - 0 9 - 0 5 0 8 : 0 0

2 0 0 5 - 0 9 - 0 5 1 8 : 3 0

0 . 5

3 . 9

8 9 5 9

1 4

. 4

7 . 8

2

9 1 5

5 . 1

5

– 1 . 6

3 0 3

9 . 6

5

0 . 9

1 8 3

1 0 1 6 . 5

P F M 0 0 0

0 6 2

2 0 0 5 - 0 9 - 0 5 0 8 : 0 0

2 0 0 5 - 0 9 - 0 5 1 8 : 3 0

1

3 . 9

1 4

. 4

7 . 8

4

9 1 5

5 . 1

5

– 1 . 7

2 7 2

9 . 6

4

1 . 1

1 8 3

1 0 1 6 . 6

P F M 0 0 0

0 6 2

2 0 0 5 - 0 9 - 0 5 0 8 : 0 0

2 0 0 5 - 0 9 - 0 5 1 8 : 3 0

2

3 . 9

1 4

. 4

7 . 8

6

9 1 4

5 . 1

5

– 1 . 7

1 8 0

9 . 6

3

1 . 5

1 8 3

1 0 1 8 . 4

P F M 0 0 0

0 6 2

2 0 0 5 - 0 9 - 0 5 0 8 : 0 0

2 0 0 5 - 0 9 - 0 5 1 8 : 3 0

3

3 . 9

1 4

. 4

7 . 8

8

9 1 4

5 . 1

5

– 1 . 6

1 2 5

9 . 6

3

0 . 9

1 8 3

1 0 1 9 . 7

P F M 0 0 0

0 6 2

2 0 0 5 - 1 0 - 0 3 0 8 : 0 0

2 0 0 5 - 1 0 - 0 3 2 0 : 0 0

0 . 5

4 . 1

8 9 7 1

8

. 2

7 . 5

0

9 6 0

5 . 3

9

0 . 2

2 1 2

1 0 . 7

1 . 1

1 6 3

1 0 1 3 . 4

P F M 0 0 0

0 6 2

2 0 0 5 - 1 0 - 0 3 0 8 : 0 0

2 0 0 5 - 1 0 - 0 3 2 0 : 0 0

1

4 . 1

8

. 2

7 . 5

3

9 6 0

5 . 3

9

0 . 2

1 5 9

1 0 . 7

1 . 9

1 6 3

1 0 1 3 . 9

P F M 0 0 0

0 6 2

2 0 0 5 - 1 0 - 0 3 0 8 : 0 0

2 0 0 5 - 1 0 - 0 3 2 0 : 0 0

2

4 . 1

8

. 3

7 . 5

6

9 6 0

5 . 3

9

0 . 1

8 0 . 2

1 0 . 7

2 . 2

1 6 2

1 0 1 4 . 2

P F M 0 0 0

0 6 2

2 0 0 5 - 1 0 - 0 3 0 8 : 0 0

2 0 0 5 - 1 0 - 0 3 2 0 : 0 0

3

4 . 1

8

. 3

7 . 5

7

9 6 1

5 . 4

0

0 . 1

6 1 . 1

1 0 . 7

1 . 5

1 6 1

1 0 1 4 . 5

P F M 0 0 0

0 6 2

2 0 0 5 - 1 0 - 3 1 0 8 : 0 0

2 0 0 5 - 1 0 - 3 1 1 9 : 0 0

0 . 5

3 . 7

8 9 9 6

7

. 1

7 . 5

2

9 4 0

5 . 2

6

0 . 4

1 2 8

1 2 . 4

2 . 2

1 8 6

1 0 0 9 . 2

P F M 0 0 0

0 6 2

2 0 0 5 - 1 0 - 3 1 0 8 : 0 0

2 0 0 5 - 1 0 - 3 1 1 9 : 0 0

1

3 . 7

7

. 1

7 . 5

7

9 4 0

5 . 2

6

0 . 4

9 4 . 4

1 2 . 4

4 . 1

1 8 5

1 0 0 9 . 2

P F M 0 0 0

0 6 2

2 0 0 5 - 1 0 - 3 1 0 8 : 0 0

2 0 0 5 - 1 0 - 3 1 1 9 : 0 0

2

3 . 7

7

. 1

7 . 6

1

9 4 0

5 . 2

6

0 . 3

5 0 . 3

1 2 . 4

3 . 2

1 8 5

1 0 0 9 . 2

P F M 0 0 0

0 6 2

2 0 0 5 - 1 0 - 3 1 0 8 : 0 0

2 0 0 5 - 1 0 - 3 1 1 9 : 0 0

3

3 . 7

7

. 1

7 . 6

9

9 4 0

5 . 2

6

0 . 3

3 5 . 6

1 2 . 4

2 . 8

1 8 3

1 0 0 9 . 6

P F M 0 0 0

0 6 2

2 0 0 5 - 1 1 - 2 8 0 8 : 0 0

2 0 0 5 - 1 1 - 2 8 1 9 : 0 0

0 . 5

3 . 7

1 2 0 1 9

4

. 5

7 . 7

2

9 3 2

5 . 1

8

– 0 . 8

1 9 . 2

1 2 . 2

1 . 8

1 9 2

9 8 0 . 5

P F M 0 0 0

0 6 2

2 0 0 5 - 1 1 - 2 8 0 8 : 0 0

2 0 0 5 - 1 1 - 2 8 1 9 : 0 0

1

3 . 7

4

. 5

7 . 7

6

9 3 5

5 . 2

0

– 1 . 0

1 2 . 7

1 2 . 1

1 . 8

1 9 1

9 8 1 . 0

P F M 0 0 0

0 6 2

2 0 0 5 - 1 1 - 2 8 0 8 : 0 0

2 0 0 5 - 1 1 - 2 8 1 9 : 0 0

2

3 . 7

4

. 5

7 . 8

1

9 3 5

5 . 2

0

– 1 . 0

5 . 3

1 2 . 1

1 . 1

1 9 0

9 8 1 . 2



48

I d c o d e

S t a r t d a t e

S t o p d a t e

M e a s

d e p t h

( m )

W a t e r

d e p t h

( m )

S n o

t e m p .

( ° C

)

p H

E C ( m S /

m )

S a l i n i t y

( % )

T u r b *

( N T U )

L i g h t

( µ m o l / m 2 s )

O 2 d i s s .

( m g / L )


( µ g / L )

O R P

( m V )

A t m .

P r e s s u r e

( h P a )

P F M 0 0 0

0 6 2

2 0 0 5 - 1 1 - 2 8 0 8 : 0 0

2 0 0 5 - 1 1 - 2 8 1 9 : 0 0

3

3 . 7

4

. 5

7 . 8

2

9 3 5

5 . 2

0

– 1 . 0

2 . 6

1 2 . 1

1 . 1

1 8 9

9 8 1 . 4

P F M 0 0 0

0 6 2

2 0 0 5 - 1 2 - 1 9 0 8 : 0 0

2 0 0 5 - 1 2 - 1 9 1 9 : 0 0

0 . 5

4

1 2 0 2 1

2

. 2

7 . 7

9

9 4 6

5 . 2

1

0 . 0

4 3 . 1

1 4 . 2

0 . 0

1 1 1

1 0 0 0 . 7

P F M 0 0 0

0 6 2

2 0 0 5 - 1 2 - 1 9 0 8 : 0 0

2 0 0 5 - 1 2 - 1 9 1 9 : 0 0

1

4

2

. 2

7 . 7

9

9 4 6

5 . 2

1

0 . 0

3 2 . 7

1 4 . 2

0 . 5

1 1 1

1 0 0 0 . 8

P F M 0 0 0

0 6 2

2 0 0 5 - 1 2 - 1 9 0 8 : 0 0

2 0 0 5 - 1 2 - 1 9 1 9 : 0 0

2

4

2

. 2

7 . 8

0

9 4 6

5 . 2

1

0 . 2

1 5 . 3

1 4 . 1

0 . 6

1 1 1

1 0 0 0 . 9

P F M 0 0 0

0 6 2

2 0 0 5 - 1 2 - 1 9 0 8 : 0 0

2 0 0 5 - 1 2 - 1 9 1 9 : 0 0

3

4

2

. 2

7 . 7

9

9 4 6

5 . 2

1

0 . 1

9 . 6

1 4 . 1

0 . 5

1 1 1

1 0 0 0 . 9

P F M 0 0 0

0 6 2

2 0 0 6 - 0 4 - 1 8 0 8 : 0 0

2 0 0 6 - 0 4 - 1 8 1 8 : 3 0

0 . 5

3 . 9

1 2 2 3 4

1

. 2

8 . 0

4

9 2 3

5 . 0

5

– 1 . 0

4 3 2

1 7 . 3

1 . 5

1 5 3

9 9 4 . 0

P F M 0 0 0

0 6 2

2 0 0 6 - 0 4 - 1 8 0 8 : 0 0

2 0 0 6 - 0 4 - 1 8 1 8 : 3 0

1

3 . 9

1

. 2

8 . 0

5

9 2 3

5 . 0

5

– 1 . 0

8 5 6

1 7 . 2

2 . 4

1 5 1

9 9 4 . 3

P F M 0 0 0

0 6 2

2 0 0 6 - 0 4 - 1 8 0 8 : 0 0

2 0 0 6 - 0 4 - 1 8 1 8 : 3 0

2

3 . 9

1

. 2

8 . 0

6

9 2 3

5 . 0

5

– 1 . 0

1 8 3

1 7 . 2

2 . 5

1 5 1

9 9 5 . 1

P F M 0 0 0

0 6 2

2 0 0 6 - 0 4 - 1 8 0 8 : 0 0

2 0 0 6 - 0 4 - 1 8 1 8 : 3 0

3

3 . 9

1

. 2

8 . 0

6

9 2 3

5 . 0

5

– 1 . 0

1 0 0

1 7 . 2

2 . 8

1 5 0

9 9 5 . 1

P F M 0 0 0

0 6 2

2 0 0 6 - 0 5 - 1 5 0 8 : 0 0

2 0 0 6 - 0 5 - 1 5 1 9 : 0 0

0 . 5

3 . 8

1 2 2 4 9

9

. 5

8 . 4

4

8 7 5

4 . 8

9

0 . 0

5 4 2

1 4 . 1

2 . 6

8 6

1 0 1 5 . 1

P F M 0 0 0

0 6 2

2 0 0 6 - 0 5 - 1 5 0 8 : 0 0

2 0 0 6 - 0 5 - 1 5 1 9 : 0 0

1

3 . 8

9

. 5

8 . 4

4

8 7 5

4 . 8

9

0 . 0

5 7 1

1 4 . 1

2 . 8

8 2

1 0 1 5 . 9

P F M 0 0 0

0 6 2

2 0 0 6 - 0 5 - 1 5 0 8 : 0 0

2 0 0 6 - 0 5 - 1 5 1 9 : 0 0

2

3 . 8

9

. 5

8 . 4

5

8 7 4

4 . 8

9

– 0 . 3

3 4 0

1 4 . 1

1 . 0

8 0

1 0 1 6 . 2

P F M 0 0 0

0 6 2

2 0 0 6 - 0 5 - 1 5 0 8 : 0 0

2 0 0 6 - 0 5 - 1 5 1 9 : 0 0

3

3 . 8

9

. 5

8 . 4

6

8 7 5

4 . 8

9

– 0 . 2

1 9 0

1 4 . 1

5 . 4

7 8

1 0 1 6 . 7

P F M 0 0 0

0 6 2

2 0 0 6 - 0 6 - 1 2 0 8 : 0 0

2 0 0 6 - 0 6 - 1 2 1 8 : 3 0

0 . 5

3 . 6

1 2 2 9 7

1 4

. 2

8 . 1

4

8 0 0

4 . 4

6

0 . 7

9 7 7

1 1 . 8

0 . 2

6 4

1 0 2 9 . 7

P F M 0 0 0

0 6 2

2 0 0 6 - 0 6 - 1 2 0 8 : 0 0

2 0 0 6 - 0 6 - 1 2 1 8 : 3 0

1

3 . 6

1 4

. 1

8 . 1

5

8 0 1

4 . 4

6

– 0 . 4

7 1 6

1 1 . 7

0 . 5

5 6

1 0 2 8 . 9

P F M 0 0 0

0 6 2

2 0 0 6 - 0 6 - 1 2 0 8 : 0 0

2 0 0 6 - 0 6 - 1 2 1 8 : 3 0

2

3 . 6

1 3

. 2

8 . 1

5

8 0 3

4 . 4

8

– 0 . 5

4 1 0

1 1 . 9

0 . 5

5 2

1 0 2 8 . 8

P F M 0 0 0

0 6 2

2 0 0 6 - 0 6 - 1 2 0 8 : 0 0

2 0 0 6 - 0 6 - 1 2 1 8 : 3 0

3

3 . 6

1 3

. 0

8 . 1

5

8 0 2

4 . 4

7

– 0 . 5

2 2 2

1 1 . 9

1 . 1

4 8

1 0 2 8 . 6

P F M 0 0 0

0 6 6

2 0 0 5 - 0 7 - 1 2 0 7 : 0 0

2 0 0 5 - 0 7 - 1 2 1 8 : 0 0

0 . 1

0 . 1

8 9 3 4

1 8

. 6

7 . 3

0

3 2 . 6

0 . 1

6

4 . 6

2

– 1 5

1 0 2 5 . 6

P F M 0 0 0

0 6 6

2 0 0 5 - 0 8 - 0 1 0 8 : 0 0

2 0 0 5 - 0 8 - 0 1 1 9 : 0 0

0 . 1

0 . 1

8 9 5 2

1 6

. 3

7 . 5

6

3 1 . 8

0 . 1

5

2 . 5

3

1 7

1 0 0 3 . 7

P F M 0 0 0

0 6 6

2 0 0 5 - 0 9 - 0 5 0 8 : 0 0

2 0 0 5 - 0 9 - 0 5 1 8 : 3 0

0 . 1

0 . 2

8 9 5 5

1 2

. 8

7 . 7

2

3 2 . 0

0 . 1

5

3 . 2

1

– 2 4

1 0 1 2 . 2

P F M 0 0 0

0 6 6

2 0 0 5 - 1 0 - 3 1 0 8 : 0 0

2 0 0 5 - 1 0 - 3 1 1 9 : 0 0

0 . 1

0 . 2

8 9 9 3

7

. 2

7 . 3

9

3 1 . 7

0 . 1

5

6 . 3

7

1 6 8

1 0 0 8 . 1

P F M 0 0 0

0 6 6

2 0 0 5 - 1 1 - 2 8 0 8 : 0 0

2 0 0 5 - 1 1 - 2 8 1 9 : 0 0

0 . 1

0 . 2

1 2 0 1 6

0

. 6

7 . 4

7

3 2 . 2

0 . 1

5

9 . 8

3

1 1 5

9 7 5 . 6

P F M 0 0 0

0 6 6

2 0 0 5 - 1 2 - 1 9 0 8 : 0 0

2 0 0 5 - 1 2 - 1 9 1 9 : 0 0

0 . 1

0 . 4

1 2 0 2 2

– 0

. 1

7 . 2

6

1 4 . 5

0 . 0

7

4 . 8

5

1 2 0

9 9 6 . 0

P F M 0 0 0

0 6 6

2 0 0 6 - 0 1 - 2 3 0 8 : 0 0

2 0 0 6 - 0 1 - 2 3 1 9 : 0 0

0 . 1

0 . 3

1 2 0 4 2

– 0

. 1

7 . 0

9

4 3 . 6

0 . 2

1

0 . 7

0

5 0

1 0 1 6 . 8

P F M 0 0 0

0 6 6

2 0 0 6 - 0 2 - 2 0 0 8 : 0 0

2 0 0 6 - 0 2 - 2 0 1 8 : 3 0

0 . 1

0 . 3

1 2 0 8 1

– 0

. 1

7 . 1

8

4 1 . 1

0 . 1

9

4 . 4

1

7 2

1 0 1 7 . 9

P F M 0 0 0

0 6 6

2 0 0 6 - 0 3 - 2 0 0 8 : 0 0

2 0 0 6 - 0 3 - 2 0 1 9 : 3 0

0 . 1

0 . 2

1 2 0 9 8

– 0

. 1

7 . 0

8

4 2 . 5

0 . 2

0

1 . 7

9

4 2

1 0 0 2 . 5

P F M 0 0 0

0 6 6

2 0 0 6 - 0 4 - 1 8 0 8 : 0 0

2 0 0 6 - 0 4 - 1 8 1 8 : 3 0

0 . 1

0 . 6

1 2 2 3 5

3

. 8

7 . 1

2

2 2 . 9

0 . 1

1

0 . 2

7 . 7

5

1 4 9

9 9 4 . 9

P F M 0 0 0

0 6 6

2 0 0 6 - 0 5 - 1 5 0 8 : 0 0

2 0 0 6 - 0 5 - 1 5 1 9 : 0 0

0 . 1

0 . 2

5

1 2 2 5 3

1 1

. 5

7 . 4

8

3 5 . 0

0 . 1

7

7 . 1

8

5 8

1 0 1 3 . 9



49

I d c o d e

S t a r t d a t e

S t o p d a t e

M e a s

d e p t h

( m )

W a t e r

d e p t h

( m )

S n o

t e m p .

( ° C

)

p H

E C ( m S /

m )

S a l i n i t y

( % )

T u r b *

( N T U )

L i g h t

( µ m o l / m 2 s )

O 2 d i s s .

( m g / L )


( µ g / L )

O R P

( m V )

A t m .

P r e s s u r e

( h P a )

P F M 0 0 0

0 6 6

2 0 0 6 - 0 6 - 1 3 0 7 : 0 0

2 0 0 6 - 0 6 - 1 3 1 6 : 0 0

0 . 1

0 . 3

1 2 2 9 8

1 7

. 8

7 . 4

6

1 7 . 8

0 . 0

8

4 . 6

8

– 2 4

1 0 2 0 . 4

P F M 0 0 0

0 6 8

2 0 0 5 - 0 7 - 1 2 0 7 : 0 0

2 0 0 5 - 0 7 - 1 2 1 8 : 0 0

0 . 1

0 . 5

8 9 3 2

1 6

. 7

7 . 3

8

4 2 . 4

0 . 2

0

3 . 6

1

2 4

1 0 3 9 . 1

P F M 0 0 0

0 6 8

2 0 0 5 - 0 8 - 0 1 0 8 : 0 0

2 0 0 5 - 0 8 - 0 1 1 9 : 0 0

0 . 1

0 . 4

8 9 5 1

1 5

. 5

7 . 5

7

4 5 . 7

0 . 2

2

4 . 8

9

8 4

1 0 0 5 . 0

P F M 0 0 0

0 6 8

2 0 0 5 - 0 9 - 0 5 0 8 : 0 0

2 0 0 5 - 0 9 - 0 5 1 8 : 3 0

0 . 1

0 . 4

8 9 6 0

1 2

. 5

7 . 6

7

4 1 . 2

0 . 2

0

6 . 9

2

1 3 9

1 0 1 3 . 2

P F M 0 0 0

0 6 8

2 0 0 5 - 1 0 - 0 3 0 8 : 0 0

2 0 0 5 - 1 0 - 0 3 2 0 : 0 0

0 . 1

0 . 3

8 9 7 7

1 0

. 2

7 . 3

4

4 9 . 2

0 . 2

4

0 . 4

8

– 5 5

1 0 1 2 . 4

P F M 0 0 0

0 6 8

2 0 0 5 - 1 0 - 3 1 0 8 : 0 0

2 0 0 5 - 1 0 - 3 1 1 9 : 0 0

0 . 1

0 . 6

9 0 0 0

7

. 3

7 . 3

4

3 8 . 6

0 . 1

9

7 . 0

7

1 5 5

1 0 0 7 . 7

P F M 0 0 0

0 6 8

2 0 0 5 - 1 1 - 2 8 0 8 : 0 0

2 0 0 5 - 1 1 - 2 8 1 9 : 0 0

0 . 1

0 . 6

8 9 9 9

1

. 1

7 . 5

2

3 3 . 7

0 . 1

6

9 . 7

8

1 0 0

9 7 6 . 2

P F M 0 0 0

0 6 8

2 0 0 5 - 1 2 - 1 9 0 8 : 0 0

2 0 0 5 - 1 2 - 1 9 1 9 : 0 0

0 . 1

0 . 4

1 2 0 2 7

– 0

. 1

7 . 2

8

1 6 . 4

0 . 0

8

4 . 2

8

1 2 4

9 9 7 . 4

P F M 0 0 0

0 6 8

2 0 0 6 - 0 1 - 2 3 0 8 : 0 0

2 0 0 6 - 0 1 - 2 3 1 9 : 0 0

0 . 1

0 . 5

1 2 0 4 5

– 0

. 1

7 . 0

1

3 9 . 8

0 . 1

9

3 . 1

2

1 5

1 0 1 6 . 6

P F M 0 0 0

0 6 8

2 0 0 6 - 0 2 - 2 0 0 8 : 0 0

2 0 0 6 - 0 2 - 2 0 1 8 : 3 0

0 . 1

0 . 5

1 2 0 8 2

– 0

. 1

7 . 1

1

3 7 . 4

0 . 1

8

4 . 9

3

6 3

1 0 1 7 . 0

P F M 0 0 0

0 6 8

2 0 0 6 - 0 3 - 2 0 0 8 : 0 0

2 0 0 6 - 0 3 - 2 0 1 9 : 3 0

0 . 1

0 . 5

1 2 0 9 1

– 0

. 1

7 . 1

4

3 5 . 6

0 . 1

7

4 . 2

6

6 8

1 0 0 3 . 1

P F M 0 0 0

0 6 8

2 0 0 6 - 0 4 - 1 9 0 7 : 0 0

2 0 0 6 - 0 4 - 1 9 1 8 : 3 0

0 . 1

0 . 9

1 2 2 3 7

2

. 2

7 . 1

3

2 0 . 7

0 . 1

0

0 . 7

7 . 7

2

1 2 7

1 0 1 0 . 5

P F M 0 0 0

0 6 8

2 0 0 6 - 0 5 - 1 5 0 8 : 0 0

2 0 0 6 - 0 5 - 1 5 1 9 : 0 0

0 . 1

0 . 6

1 2 2 5 0

9

. 3

7 . 3

2

3 3 . 2

0 . 1

6

8 . 0

3

7 0

1 0 1 5 . 6

P F M 0 0 0

0 6 8

2 0 0 6 - 0 6 - 1 2 0 8 : 0 0

2 0 0 6 - 0 6 - 1 2 1 8 : 3 0

0 . 1

0 . 4

1 2 3 0 2

1 6

. 8

7 . 4

3

4 1 . 8

0 . 2

0

6 . 4

4

6

1 0 2 4 . 4

P F M 0 0 0

0 6 9

2 0 0 5 - 0 7 - 1 2 0 7 : 0 0

2 0 0 5 - 0 7 - 1 2 1 8 : 0 0

0 . 1

0 . 1

8 9 3 1

1 6

. 6

7 . 5

7

4 2 . 6

0 . 2

1

7 . 2

0

8 8

1 0 2 7 . 3

P F M 0 0 0

0 6 9

2 0 0 5 - 0 8 - 0 1 0 8 : 0 0

2 0 0 5 - 0 8 - 0 1 1 9 : 0 0

0 . 1

0 . 1

8 9 4 7

1 5

. 7

7 . 6

7

3 2 . 9

0 . 1

6

7 . 9

2

9 6

1 0 0 4 . 5

P F M 0 0 0

0 6 9

2 0 0 5 - 0 9 - 0 5 0 8 : 0 0

2 0 0 5 - 0 9 - 0 5 1 8 : 3 0

0 . 1

0 . 1

8 9 5 6

1 2

. 6

7 . 8

0

4 2 . 1

0 . 2

0

8 . 4

9

1 4 4

1 0 1 3 . 3

P F M 0 0 0

0 6 9

2 0 0 5 - 1 0 - 0 3 0 8 : 0 0

2 0 0 5 - 1 0 - 0 3 2 0 : 0 0

0 . 1

0 . 0

5

8 9 7 4

1 0

. 1

7 . 6

6

4 8 . 7

0 . 2

4

7 . 0

4

6 5

1 0 1 3 . 9

P F M 0 0 0

0 6 9

2 0 0 5 - 1 0 - 3 1 0 8 : 0 0

2 0 0 5 - 1 0 - 3 1 1 9 : 0 0

0 . 1

0 . 1

5

8 9 9 5

7

. 3

7 . 3

7

4 4 . 0

0 . 2

1

7 . 8

3

1 6 1

1 0 0 9 . 1

P F M 0 0 0

0 6 9

2 0 0 5 - 1 1 - 2 8 0 8 : 0 0

2 0 0 5 - 1 1 - 2 8 1 9 : 0 0

0 . 1

0 . 2

1 2 0 1 7

1

. 3

7 . 4

9

4 3 . 5

0 . 2

1

8 . 3

2

9 6

9 7 7 . 3

P F M 0 0 0

0 6 9

2 0 0 5 - 1 2 - 1 9 0 8 : 0 0

2 0 0 5 - 1 2 - 1 9 1 9 : 0 0

0 . 1

0 . 3

1 2 0 2 0

– 0

. 1

7 . 3

2

2 8 . 2

0 . 1

3

1 . 9

7

9 5

9 9 7 . 5

P F M 0 0 0

0 6 9

2 0 0 6 - 0 1 - 2 3 0 8 : 0 0

2 0 0 6 - 0 1 - 2 3 1 9 : 0 0

0 . 1

0 . 2

1 2 0 4 3

– 0

. 1

6 . 9

2

5 1 . 3

0 . 2

4

0 . 1

7

– 1 4 7

1 0 1 7 . 3

P F M 0 0 0

0 6 9

2 0 0 6 - 0 2 - 2 0 0 8 : 0 0

2 0 0 6 - 0 2 - 2 0 1 8 : 3 0

0 . 1

0 . 3

1 2 0 7 9

– 0

. 1

7 . 0

2

4 7 . 8

0 . 2

3

1 . 4

8

7

1 0 1 6 . 6

P F M 0 0 0

0 6 9

2 0 0 6 - 0 3 - 2 0 0 8 : 0 0

2 0 0 6 - 0 3 - 2 0 1 9 : 3 0

0 . 1

0 . 3

1 2 0 9 9

– 0

. 1

6 . 9

9

5 0 . 4

0 . 2

4

0 . 8

5

– 4 3

1 0 0 3 . 6

P F M 0 0 0

0 6 9

2 0 0 6 - 0 4 - 1 9 0 7 : 0 0

2 0 0 6 - 0 4 - 1 9 1 8 : 3 0

0 . 1

0 . 6

5

1 2 2 3 0

1

. 9

7 . 0

6

2 6 . 0

0 . 1

2

– 0 . 4

6 . 0

2

1 3 2

1 0 0 3 . 7

P F M 0 0 0

0 6 9

2 0 0 6 - 0 5 - 1 5 0 8 : 0 0

2 0 0 6 - 0 5 - 1 5 1 9 : 0 0

0 . 1

0 . 2

5

1 2 2 3 6

9

. 0

7 . 2

1

3 6 . 5

0 . 1

8

6 . 5

8

6 9

1 0 1 4 . 1

P F M 0 0 0

0 6 9

2 0 0 6 - 0 6 - 1 2 0 8 : 0 0

2 0 0 6 - 0 6 - 1 2 1 8 : 3 0

0 . 1

0 . 1

1 2 3 0 1

1 6

. 3

7 . 3

6

4 2 . 1

0 . 2

0

7 . 1

8

– 2 9

1 0 2 4 . 7

P F M 0 0 0

0 7 0

2 0 0 5 - 0 7 - 1 2 0 7 : 0 0

2 0 0 5 - 0 7 - 1 2 1 8 : 0 0

0 . 1

0 . 1

8 9 3 3

1 8

. 0

7 . 2

9

2 6 . 9

0 . 1

3

4 . 3

4

1 0 6

1 0 2 5 . 8





51

I d c o d e

S t a r t d a t e

S t o p d a t e

M e a s

d e p t h

( m )

W a t e r

d e p t h

( m )

S n o

t e m p .

( ° C

)

p H

E C ( m S /

m )

S a l i n i t y

( % )

T u r b *

( N T U )

L i g h t

( µ m o l / m 2 s )

O 2 d i s s .

( m g / L )


( µ g / L )

O R P

( m V )

A t m .

P r e s s u r e

( h P a )

P F M 0 0 0

0 8 2

2 0 0 6 - 0 1 - 2 3 0 8 : 0 0

2 0 0 6 - 0 1 - 2 3 1 9 : 0 0

3

6 . 4

– 0

. 3

7 . 8

7

9 5 8

5 . 2

1

– 1 . 2

2 . 1

1 4 . 1

2 . 2

1 2 2

1 0 1 9 . 9

P F M 0 0 0

0 8 2

2 0 0 6 - 0 1 - 2 3 0 8 : 0 0

2 0 0 6 - 0 1 - 2 3 1 9 : 0 0

4

6 . 4

– 0

. 3

7 . 8

8

9 6 0

5 . 2

3

– 1 . 3

1 . 4

1 4 . 0

1 . 4

1 2 0

1 0 2 0 . 4

P F M 0 0 0

0 8 2

2 0 0 6 - 0 1 - 2 3 0 8 : 0 0

2 0 0 6 - 0 1 - 2 3 1 9 : 0 0

5

6 . 4

– 0

. 4

7 . 8

8

9 6 2

5 . 2

3

– 1 . 2

0 . 5

1 4 . 0

1 . 5

1 1 9

1 0 2 1 . 0

P F M 0 0 0

0 8 2

2 0 0 6 - 0 1 - 2 3 0 8 : 0 0

2 0 0 6 - 0 1 - 2 3 1 9 : 0 0

6

6 . 4

1 2 0 3 0

– 0

. 3

7 . 8

8

9 6 3

5 . 2

4

– 1 . 2

– 0 . 4

1 3 . 9

1 . 7

1 1 7

1 0 2 1 . 5

P F M 0 0 0

0 8 2

2 0 0 6 - 0 2 - 2 0 0 8 : 0 0

2 0 0 6 - 0 2 - 2 0 1 8 : 3 0

0 . 5

6 . 6

1 2 0 8 4

– 0

. 3

7 . 8

7

9 2 9

5 . 0

4

– 0 . 8

2 9 . 6

1 6 . 0

1 . 9

2 2 1

1 0 1 3 . 6

P F M 0 0 0

0 8 2

2 0 0 6 - 0 2 - 2 0 0 8 : 0 0

2 0 0 6 - 0 2 - 2 0 1 8 : 3 0

1

6 . 6

– 0

. 3

7 . 9

1

9 3 0

5 . 0

5

– 0 . 9

1 7 . 2

1 6 . 1

2 . 3

2 1 6

1 0 1 4 . 4

P F M 0 0 0

0 8 2

2 0 0 6 - 0 2 - 2 0 0 8 : 0 0

2 0 0 6 - 0 2 - 2 0 1 8 : 3 0

2

6 . 6

– 0

. 3

7 . 9

3

9 3 0

5 . 0

5

– 0 . 9

7 . 1

1 6 . 1

2 . 0

2 1 1

1 0 1 4 . 8

P F M 0 0 0

0 8 2

2 0 0 6 - 0 2 - 2 0 0 8 : 0 0

2 0 0 6 - 0 2 - 2 0 1 8 : 3 0

3

6 . 6

– 0

. 3

7 . 9

5

9 2 9

5 . 0

5

– 0 . 7

3 . 3

1 5 . 9

2 . 7

2 0 8

1 0 1 5 . 1

P F M 0 0 0

0 8 2

2 0 0 6 - 0 2 - 2 0 0 8 : 0 0

2 0 0 6 - 0 2 - 2 0 1 8 : 3 0

4

6 . 6

– 0

. 3

7 . 9

6

9 2 9

5 . 0

5

– 0 . 9

1 . 5

1 6 . 1

2 . 4

2 0 4

1 0 1 4 . 6

P F M 0 0 0

0 8 2

2 0 0 6 - 0 2 - 2 0 0 8 : 0 0

2 0 0 6 - 0 2 - 2 0 1 8 : 3 0

5

6 . 6

– 0

. 2

7 . 9

6

9 2 8

5 . 0

4

– 0 . 9

0 . 4

1 6 . 0

2 . 3

2 0 3

1 0 1 4 . 8

P F M 0 0 0

0 8 2

2 0 0 6 - 0 2 - 2 0 0 8 : 0 0

2 0 0 6 - 0 2 - 2 0 1 8 : 3 0

6

6 . 6

1 2 0 8 5

– 0

. 1

7 . 9

5

9 2 7

5 . 0

4

– 0 . 9

– 0 . 3

1 5 . 8

2 . 7

2 0 2

1 0 1 5 . 1

P F M 0 0 0

0 8 2

2 0 0 6 - 0 3 - 2 0 0 8 : 0 0

2 0 0 6 - 0 3 - 2 0 1 9 : 3 0

0 . 5

6 . 3

1 2 0 9 7

1

. 1

7 . 8

3

9 1 4

5 . 0

0

– 1 . 2

1 1 1

1 4 . 5

0 . 9

3 5 4

1 0 0 3 . 4

P F M 0 0 0

0 8 2

2 0 0 6 - 0 3 - 2 0 0 8 : 0 0

2 0 0 6 - 0 3 - 2 0 1 9 : 3 0

1

6 . 3

1

. 1

7 . 8

8

9 1 5

5 . 0

1

– 1 . 2

9 1 . 2

1 4 . 5

1 . 7

3 4 5

1 0 0 4 . 4

S n o = C

o r r e s p o n d i n g w a t e r s a m p l e n o

E C = E l e c t r i c a l c o n d u c t i v i t y

N T U = N

e p h e l o m e t r i c T u r b i d i y U n i t

O R P = O

x i d i s i n g R e d u c i n g P o t e n t i a l

* M e a s u

r e m e n t s w i t h l o w r e l i a b i l i t y



53

Appendix 3

PAR-profile logs

PAR vs Depth: PFM 107, v28- 05

y = 1194.7e-0.7503x

R2

= 0.6729

0

500

1000

1500

2000

2500

0 0.5 1 1.5 2

Depth

P A R

Serie1

Expon. (Serie1)


y = 661.79e-0.9812x

R2

= 0.9214

0

100

200

300

400

500

600

700

800

0 0.5 1 1.5 2

Depth

P A R

Serie1

Expon. (Serie1)


y = 1417.2e-0.4812x

R2 = 0.8536

0

500

1000

1500

2000

2500

0 1 2 3 4

Depth

P A R Serie1

Expon. (Serie1)



54


y = 509.31e-0.8676x

R2

= 0.9941

0

100

200

300

400

500

600

0 0.5 1 1.5 2

Depth

P

A R Serie1

Expon. (Serie1)


y = 742.07e-1.4222x

R2

= 0,8992

0

100

200

300

400

500

600

0 0.5 1 1.5 2

Depth

P A R Serie1

Expon. (Serie1)


y = 1372.1e-0.5107x

R2

= 0.9477

0

200

400

600

800

1000

1200

1400

1600

1800

0 1 2 3 4

Depth

P A R Serie1

Expon. (Serie1)



55

PAR vs Depth: PFM 107, v36- 05y = 826.67e

-0.7112x

R2

= 0.8905

0

200

400

600

800

1000

0 0.5 1 1.5 2

Depth

P A R Serie1

Expon. (Serie1)


y = 426.14e-0.799x

R2

= 0.9662

0

100

200

300

400

500

0 0.5 1 1.5 2 2.5

Depth

P A R Serie1

Expon. (Serie1)


y = 617.55e-0.5258x

R2

= 0.997

0

100

200

300

400

500

600

700

0 1 2 3 4 5

Depth

P A R Serie1

Expon. (Serie1)



56

PAR vs Depth: PFM 107, v 40- 05y = 438.03e

-0.7034x

R2 = 0.576

0

100

200

300

400

500

600

700

0 0,5 1 1,5 2

Depth

P A R Serie1

Expon. (Serie1)


-0.7284x

R 2 = 0.869

0

100

200

300

400

500

600

0 0,5 1 1,5 2 2,5

Depth

P A R Serie1

Expon. (Serie1)

PAR vs Depth: PFM 62, v 40- 05

y = 266.96e-0.4605x

R2 = 0.9865

0

50

100

150

200

250

300

350

0 1 2 3 4 5

Depth

P A R Serie1

Expon. (Serie1)



57


y = 98.036e-0.8566x

R2 = 0.9845

0

20

40

60

80

100

0 0.5 1 1.5 2

Depth

P A R Serie1

Expon. (Serie1)


-0.7767x

R2

= 0.9562

0

50

100

150

200

0 0.5 1 1.5 2 2.5

Depth

P A R Serie1

Expon. (Serie1)


y = 156.31e-0.5968x

R2 = 0.9959

0

20

40

60

80

100

120

140

160

180

0 1 2 3 4

Depth

P A R Serie1

Expon. (Serie1)



58


y = 2.6169e-1.1852x

R2 = 0.5065

0

0.5

11,5

2

2.5

3

3.5

4

0 0.5 1 1.5 2

Depth

P A R Serie1

Expon. (Serie1)


y = 137.51e-0.7556x

R 2 = 0.9574

0

20

40

60

80

100

120

140

160

180

0 0.5 1 1.5 2 2.5

Depth

P A R Serie1

Expon. (Serie1)


y = 20.294e-0.7206x

R2 = 0.9802

0

5

10

15

20

25

0 1 2 3 4

Depth

P A R Serie1

Expon. (Serie1)



59


y = 12.086e-3.181x

R2

= 0.8399

0

2

4

6

8

10

12

0 0.5 1 1.5

Depth

P A R Serie1

Expon. (Serie1)


y = 25.927e-1.7788x

R2

= 0.9353

0

5

10

15

20

25

0 0.5 1 1.5 2 2.5

Depth

P A R Serie1

Expon. (Serie1)


y = 58.92e-0.6145x

R2

= 0.9906

0

10

20

30

40

50

60

70

80

0 1 2 3 4 5

Depth

P A R Serie1

Expon. (Serie1)



60


y = 21.703e-2.1693x

R2 = 0.8548

0

2

4

6

8

10

0 0.5 1 1.5 2

Depth

P A R Serie1

Expon. (Serie1)


y = 24.348e-1.8151x

R2 = 0.8739

0

2

4

6

8

10

12

14

16

18

0 0.5 1 1.5 2 2.5

Depth

P A R Serie1

Expon. (Serie1)


y = 60.86e-0.9315x

R2

= 0.9651

0

10

20

30

40

50

60

0 2 4 6 8

Depth

P A R

Serie1

Expon. (Serie1)



61


y = 32.436e-3.5942x

R2 = 0.9256

0

2

46

8

10

12

14

16

0 0.5 1 1.5 2

Depth

P A R Serie1

Expon. (Serie1)


y = 66.632e-1.8446x

R2 = 0.9705

0

10

20

30

40

50

0 0.5 1 1.5 2 2.5

Depth

P A R Serie1

Expon. (Serie1)


y = 80.963e-0.9265x

R2 = 0.9793

0

10

20

30

40

50

60

70

80

0 2 4 6 8

Depth

P A R

Serie1

Expon. (Serie1)



62


y = 76.776e-1.956x

R2

= 0.9662

0

10

20

30

40

50

60

0 0.5 1 1.5 2

Depth

P A R Serie1

Expon. (Serie1)


y = 166.78e-1.9207x

R2

= 0.9719

0

20

40

60

80

100

120

0 0.5 1 1.5 2 2.5

Depth

P A R Serie1

Expon. (Serie1)


y = 182.75e-0.4279x

R2

= 0.9791

0

50

100

150

200

250

0 2 4 6 8

Depth

P A R

Serie1

Expon. (Serie1)



63


y = 565.72e-0.3998x

R2

= 0.4657

0

200

400

600

800

1000

0 1 2 3 4 5

Depth

P A R

Serie1

Expon. (Serie1)



64


y = 293.71e-1.7866x

R2

= 0.9945

0

50

100

150

200

250

0 0.5 1 1.5 2

Depth

P A R

Serie1

Expon. (Serie1)


y = 1463.7e

-1.8357x

R2

= 0.8014

0

200

400

600

800

1000

1200

1400

1600

0 0.5 1 1.5 2 2.5

Depth

P A R Serie1

Expon. (Serie1)


y = 1124.5e-0.5918x

R2

= 0.8561

0

200

400

600

800

1000

1200

1400

1600

0 1 2 3 4

Depth

P A R

Serie1

Expon. (Serie1)



65


y = 725.44e-1.1418x

R2

= 0.7795

0

100

200

300

400

500

600

700

800

0 0.5 1 1.5 2

Depth

P A R Serie1

Expon. (Serie1)


y = 1337e -1.0388x

R2

= 0.8309

0

500

1000

1500

2000

2500

0 0.5 1 1.5 2 2.5

Depth

P A R Serie1

Expon. (Serie1)


y = 1337e-1.0388x

R2

= 0.8309

0

500

1000

1500

2000

2500

0 0.5 1 1.5 2 2.5

Depth

P A R Serie1

Expon. (Serie1)



67

Appendix 4

Water flow measurements

IDcode Start

date

Stop

date

Simple flow rate

(m3 /s)

Code

PFM000062 2005-07-11 08:00 2005-07-11 19:00 N

PFM000062 2005-08-01 08:00 2005-08-01 19:00 N

PFM000062 2005-09-05 08:00 2005-09-05 18:30 N

PFM000062 2005-10-03 08:00 2005-10-03 20:00 N

PFM000062 2005-10-31 08:00 2005-10-31 19:00 N

PFM000062 2005-11-28 08:00 2005-11-28 19:00 N

PFM000062 2005-12-19 08:00 2005-12-19 19:00 N

PFM000062 2006-04-18 08:00 2006-04-18 18:30 N

PFM000062 2006-05-15 08:00 2006-05-15 19:00 N

PFM000062 2006-06-12 08:00 2006-06-12 18:30 NPFM000066 2005-07-12 07:00 2005-07-12 18:00 F

PFM000066 2005-08-01 08:00 2005-08-01 19:00 F

PFM000066 2005-09-05 08:00 2005-09-05 18:30 F

PFM000066 2005-10-04 07:00 2005-10-04 17:00 G

PFM000066 2005-10-31 08:00 2005-10-31 19:00 F

PFM000066 2005-11-28 08:00 2005-11-28 19:00 2.30E–02 L

PFM000066 2005-12-19 08:00 2005-12-19 19:00 C

PFM000066 2006-01-23 08:00 2006-01-23 19:00 C

PFM000066 2006-02-20 08:00 2006-02-20 18:30 C

PFM000066 2006-03-20 08:00 2006-03-20 19:30 C

PFM000066 2006-04-18 08:00 2006-04-18 18:30 LPFM000066 2006-05-15 08:00 2006-05-15 19:00 3.60E–02 L

PFM000066 2006-06-13 07:00 2006-06-13 16:00 F

PFM000068 2005-07-12 07:00 2005-07-12 18:00 F

PFM000068 2005-08-01 08:00 2005-08-01 19:00 B

PFM000068 2005-09-05 08:00 2005-09-05 18:30 F

PFM000068 2005-10-03 08:00 2005-10-03 20:00 F

PFM000068 2005-10-31 08:00 2005-10-31 19:00 F

PFM000068 2005-11-28 08:00 2005-11-28 19:00 5.30E–02 L

PFM000068 2005-12-19 08:00 2005-12-19 19:00 C

PFM000068 2006-01-23 08:00 2006-01-23 19:00 C

PFM000068 2006-02-20 08:00 2006-02-20 18:30 CPFM000068 2006-03-20 08:00 2006-03-20 19:30 C

PFM000068 2006-04-19 07:00 2006-04-19 18:30 L

PFM000068 2006-05-15 08:00 2006-05-15 19:00 1.90E–01 L

PFM000068 2006-06-12 08:00 2006-06-12 18:30 F

PFM000069 2005-07-12 07:00 2005-07-12 18:00 8.00E–03 L

PFM000069 2005-08-01 08:00 2005-08-01 19:00 3.00E–03 L

PFM000069 2005-09-05 08:00 2005-09-05 18:30 5.00E–03 L

PFM000069 2005-10-03 08:00 2005-10-03 20:00 F

PFM000069 2005-10-31 08:00 2005-10-31 19:00 1.50E–02 L

PFM000069 2005-11-28 08:00 2005-11-28 19:00 2.90E–02 L

PFM000069 2005-12-19 08:00 2005-12-19 19:00 C

PFM000069 2006-01-23 08:00 2006-01-23 19:00 C



68

IDcode Start

date

Stop

date

Simple flow rate

(m3 /s)

Code

PFM000062 2005-07-11 08:00 2005-07-11 19:00 N

PFM000069 2006-02-20 08:00 2006-02-20 18:30 C

PFM000069 2006-03-20 08:00 2006-03-20 19:30 C

PFM000069 2006-04-19 07:00 2006-04-19 18:30 LPFM000069 2006-05-15 08:00 2006-05-15 19:00 7.00E–02 L

PFM000069 2006-06-12 08:00 2006-06-12 18:30 1.60E–02 L

PFM000070 2005-07-12 07:00 2005-07-12 18:00 B

PFM000070 2005-08-02 07:00 2005-08-02 17:00 B

PFM000070 2005-09-06 07:00 2005-09-06 16:00 F

PFM000070 2005-10-04 07:00 2005-10-04 17:00 F

PFM000070 2005-11-01 07:00 2005-11-01 16:00 F

PFM000070 2005-11-28 08:00 2005-11-28 19:00 1.60E–02 L

PFM000070 2005-12-20 07:00 2005-12-20 17:00 C

PFM000070 2006-01-24 07:00 2006-01-24 20:00 C

PFM000070 2006-02-21 07:00 2006-02-21 19:00 3.90E–02 L

PFM000070 2006-03-21 07:00 2006-03-21 17:30 C

PFM000070 2006-04-19 07:00 2006-04-19 18:30 L

PFM000070 2006-05-16 07:00 2006-05-16 16:00 1.80E–02 L

PFM000070 2006-06-12 08:00 2006-06-12 18:30 F

PFM000074 2005-07-11 08:00 2005-07-11 19:00 N

PFM000074 2005-08-01 08:00 2005-08-01 19:00 N

PFM000074 2005-09-05 08:00 2005-09-05 18:30 N

PFM000074 2005-10-03 08:00 2005-10-03 20:00 N

PFM000074 2005-10-31 08:00 2005-10-31 19:00 N

PFM000074 2005-11-29 07:00 2005-11-29 17:00 N

PFM000074 2005-12-20 07:00 2005-12-20 17:00 N

PFM000074 2006-01-24 07:00 2006-01-24 20:00 N

PFM000074 2006-02-21 07:00 2006-02-21 19:00 N

PFM000074 2006-03-20 08:00 2006-03-20 19:30 N

PFM000074 2006-04-18 08:00 2006-04-18 18:30 N

PFM000074 2006-05-15 08:00 2006-05-15 19:00 N

PFM000074 2006-06-13 07:00 2006-06-13 16:00 N

PFM000082 2006-01-23 08:00 2006-01-23 19:00 N

PFM000082 2006-02-20 08:00 2006-02-20 18:30 N

PFM000082 2006-03-20 08:00 2006-03-20 19:30 N

PFM000097 2005-07-12 07:00 2005-07-12 18:00 N

PFM000097 2005-08-02 07:00 2005-08-02 17:00 N

PFM000097 2005-09-06 07:00 2005-09-06 16:00 N

PFM000097 2005-10-04 07:00 2005-10-04 17:00 N

PFM000097 2005-11-01 07:00 2005-11-01 16:00 N

PFM000097 2005-11-29 07:00 2005-11-29 17:00 N

PFM000097 2005-12-20 07:00 2005-12-20 17:00 N

PFM000097 2006-01-24 07:00 2006-01-24 20:00 N

PFM000097 2006-02-21 07:00 2006-02-21 19:00 N

PFM000097 2006-03-21 07:00 2006-03-21 17:30 N

PFM000097 2006-04-19 07:00 2006-04-19 18:30 N

PFM000097 2006-05-16 07:00 2006-05-16 16:00 NPFM000097 2006-06-13 07:00 2006-06-13 16:00 N



69

IDcode Start

date

Stop

date

Simple flow rate

(m3 /s)

Code

PFM000062 2005-07-11 08:00 2005-07-11 19:00 N

PFM000107 2005-07-11 08:00 2005-07-11 19:00 N

PFM000107 2005-08-01 08:00 2005-08-01 19:00 N

PFM000107 2005-09-05 08:00 2005-09-05 18:30 NPFM000107 2005-10-03 08:00 2005-10-03 20:00 N

PFM000107 2005-10-31 08:00 2005-10-31 19:00 N

PFM000107 2005-11-28 08:00 2005-11-28 19:00 N

PFM000107 2005-12-19 08:00 2005-12-19 19:00 N

PFM000107 2006-01-23 08:00 2006-01-23 19:00 N

PFM000107 2006-02-20 08:00 2006-02-20 18:30 N

PFM000107 2006-03-20 08:00 2006-03-20 19:30 N

PFM000107 2006-05-15 08:00 2006-05-15 19:00 N

PFM000107 2006-06-12 08:00 2006-06-12 18:30 N

PFM000117 2005-07-11 08:00 2005-07-11 19:00 N

PFM000117 2005-08-02 07:00 2005-08-02 17:00 N

PFM000117 2005-09-06 07:00 2005-09-06 16:00 N

PFM000117 2005-10-04 07:00 2005-10-04 17:00 N

PFM000117 2005-11-01 07:00 2005-11-01 16:00 N

PFM000117 2005-11-29 07:00 2005-11-29 17:00 N

PFM000117 2005-12-20 07:00 2005-12-20 17:00 N

PFM000117 2006-01-24 07:00 2006-01-24 20:00 N

PFM000117 2006-02-21 07:00 2006-02-21 19:00 N

PFM000117 2006-03-21 07:00 2006-03-21 17:30 N

PFM000117 2006-04-19 07:00 2006-04-19 18:30 N

PFM000117 2006-05-16 07:00 2006-05-16 16:00 N

PFM000117 2006-06-12 08:00 2006-06-12 18:30 N

PFM102269 2005-07-12 07:00 2005-07-12 18:00 N

PFM102269 2006-01-24 07:00 2006-01-24 20:00 N

PFM102269 2006-02-21 07:00 2006-02-21 19:00 N

PFM102269 2006-03-21 07:00 2006-03-21 17:30 N

PFM102269 2006-04-19 07:00 2006-04-19 18:30 N

PFM102269 2006-05-15 08:00 2006-05-15 19:00 N

PFM102269 2006-06-12 08:00 2006-06-12 18:30 N

PFM102270 2006-04-18 08:00 2006-04-18 18:30 N

Simple flow rate = based on simple “floating bottle” method.

Code Code description

A Blocked flow; no measurementB Too much water vegetation, no measurementC Water compleately frosen, no measurementD Too much ice, no measurementE Flow rate too high, no measurementF Flow rate too low, no measurementG Dry conditions, no measurementsH Measurement not possible, estimated valueI Measurement not possible, see protocolK Comment missingL Flow rate value availableM Low water level

N Lake, Sea, no measurementO Too much wind, no measurementP Stationary water



71

A p p e n d i x 5

C o m p i l a t i o n o f h y d r o c h e m i c a l d a t a f r o m w a t e r a n a

l y s e s

T a b l e A

5 - 1 . W a t e r c o m p o s i t i o n .

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

R C B

%

N a m g / L

K m g / L

C a m g / L

M

g

m

g / L

H C O 3 –

m g / L

C l –

m g / L

S O 4

2 –

m g / L

S O 4 - S

m g / L

B r m g / L

F – m g / L

S i m g / l

F e m g / l

M n m g / L

L i m g / L

P F M 0 0 0

0 6 2

8 9 3 6

0 . 5

2 0 0 5 - 0 7 - 1 1

– 2 . 1

7

1 4 8 0

6 1 . 8

7 5 . 7

1

7 7

7 7 . 0

2 7 4 0

3 8 4

1 5 0

1 0 . 2

0 . 3

5

0 . 3

0

0 . 0 0 9

0 . 0

0 3 5

0 . 0

3 4

P F M 0 0 0

0 6 2

8 9 5 3

0 . 5

2 0 0 5 - 0 8 - 0 1

– 4 . 3

2

1 4 3 0

6 3 . 7

7 7 . 7

1

8 2

7 7 . 2

2 8 2 0

3 9 6

1 4 8

1 0 . 1

–

0 . 3

6

–

–

0 . 0

2 5

P F M 0 0 0

0 6 2

8 9 5 9

0 . 5

2 0 0 5 - 0 9 - 0 5

– 2 . 5

1

1 5 1 0

5 9 . 8

7 5 . 3

1

8 2

7 8 . 7

2 8 4 0

3 9 5

1 4 2

8 . 9

0

0 . 3

2

0 . 5

4

–

–

0 . 0

3 1

P F M 0 0 0

0 6 2

8 9 7 1

0 . 5

2 0 0 5 - 1 0 - 0 3

– 2 . 4

2

1 5 8 0

6 1 . 3

8 2 . 7

1

9 1

8 1 . 9

2 9 8 0

4 2 6

1 4 5

1 2 . 3

0 . 3

4

0 . 5

8

0 . 0 0 3

0 . 0

0 6 7

0 . 0

2 7

P F M 0 0 0

0 6 2

8 9 9 6

0 . 5

2 0 0 5 - 1 0 - 3 1

– 1 . 4

1

1 5 9 0

5 9 . 1

8 1 . 8

1

9 0

8 0 . 3

2 9 2 0

4 1 8

1 4 7

9 . 2

4

0 . 3

2

0 . 4

9

< 0 . 0 2

< 0 . 0

0 3

0 . 0

2 4

P F M 0 0 0

0 6 2

1 2 0 1 9

0 . 5

2 0 0 5 - 1 1 - 2 8

– 1 . 2

1

1 5 8 0

6 1 . 5

8 3 . 3

1

8 3

8 1 . 0

2 8 9 0

4 0 0

1 4 0

9 . 1

5

0 . 3

6

0 . 6

4

–

–

0 . 0

2 8

P F M 0 0 0

0 6 2

1 2 0 2 1

0 . 5

2 0 0 5 - 1 2 - 1 9

– 2 . 1

6

1 5 4 0

5 6 . 3

8 6 . 4

1

9 6

8 0 . 5

2 9 1 0

4 0 6

1 4 8

1 1 . 1

0 . 3

5

0 . 8

2

–

–

0 . 0

2 6

P F M 0 0 0

0 6 2

1 2 2 3 4

0 . 5

2 0 0 6 - 0 4 - 1 8

– 2 . 1

2

1 5 1 0

6 3 . 1

7 8 . 9

1

7 6

7 8 . 4

2 8 0 0

3 9 0

1 4 5

9 . 2

5

0 . 3

2

0 . 5

8

0 . 0 0 6

0 . 0

0 4 3

0 . 0

2 9

P F M 0 0 0

0 6 2

1 2 2 4 9

0 . 5

2 0 0 6 - 0 5 - 1 5

– 2 . 1

2

1 4 6 0

5 2 . 6

7 5 . 9

1

7 6

7 7 . 1

2 7 0 0

3 7 1

1 4 7

9 . 8

0

0 . 3

2

0 . 3

4

0 . 0 2 7

< 0 . 0

0 3

0 . 0

2 2

P F M 0 0 0

0 6 2

1 2 2 9 7

0 . 5

2 0 0 6 - 0 6 - 1 2

– 1 . 3

9

1 3 5 0

5 4 . 7

7 1 . 7

1

6 5

7 2 . 4

2 4 9 0

3 5 1

1 2 7

8 . 5

3

0 . 3

5

0 . 2

3

< 0 . 0 2

< 0 . 0

0 3

0 . 0

2 7

P F M 0 0 0

0 6 6

8 9 3 4

0 . 1

2 0 0 5 - 0 7 - 1 2

4 . 5

6

6 . 1

2 . 0

9

6 1 . 5

3 . 5

1 9 0

4 . 2

3 . 6

3

1 . 9

2

0 . 0

6 8

< 0 . 2

3 . 5

6

–

–

< 0 . 0

0 4

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

S r m g / L

I – m g / L

p H_

L

m g / L

p H_

F

m g / L

T

e m p_

F

°

C l

E C_

L

m S / m

P F M 0 0 0

0 6 2

8 9 3 6

0 . 5

2 0 0 5 - 0 7 - 1 1

1 . 2

1

0 . 0

1 7

8 . 0

2

7 . 9

4

1 6 . 8

8 7 7

P F M 0 0 0

0 6 2

8 9 5 3

0 . 5

2 0 0 5 - 0 8 - 0 1

1 . 2

3

0 . 0

1 7

8 . 1

9

8 . 2

0

1 8 . 4

9 0 1

P F M 0 0 0

0 6 2

8 9 5 9

0 . 5

2 0 0 5 - 0 9 - 0 5

1 . 2

9

0 . 0

1 5

7 . 8

2

7 . 8

2

1 4 . 4

9 1 5

P F M 0 0 0

0 6 2

8 9 7 1

0 . 5

2 0 0 5 - 1 0 - 0 3

1 . 2

3

0 . 0

3 0

7 . 6

8

7 . 5

0

8 . 2

9 5 9

P F M 0 0 0

0 6 2

8 9 9 6

0 . 5

2 0 0 5 - 1 0 - 3 1

1 . 1

7

0 . 0

1 1

7 . 8

4

7 . 5

2

7 . 1

9 2 8

P F M 0 0 0

0 6 2

1 2 0 1 9

0 . 5

2 0 0 5 - 1 1 - 2 8

1 . 2

7

0 . 0

1 4

7 . 8

0

7 . 7

2

4 . 5

9 2 3

P F M 0 0 0

0 6 2

1 2 0 2 1

0 . 5

2 0 0 5 - 1 2 - 1 9

1 . 1

3

< 0 . 0

5

7 . 7

5

7 . 7

9

2 . 2

9 2 9

P F M 0 0 0

0 6 2

1 2 2 3 4

0 . 5

2 0 0 6 - 0 4 - 1 8

1 . 1

5

0 . 0

1 0

7 . 8

2

8 . 0

4

1 . 2

9 0 4

P F M 0 0 0

0 6 2

1 2 2 4 9

0 . 5

2 0 0 6 - 0 5 - 1 5

1 . 0

8

0 . 0

1 0

8 . 2

9

8 . 4

4

9 . 5

8 7 3

P F M 0 0 0

0 6 2

1 2 2 9 7

0 . 5

2 0 0 6 - 0 6 - 1 2

0 . 9

5 6

< 0 . 0

1

7 . 9

9

8 . 1

4

1 4 . 2

8 0 1

P F M 0 0 0

0 6 6

8 9 3 4

0 . 1

2 0 0 5 - 0 7 - 1 2

0 . 0

7 2

0 . 0

0 8

7 . 4

6

7 . 3

0

1 8 . 6

3 2 . 4



72

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

R C B

%

N a m g / L

K m g / L

C a m g / L

M

g

m

g / L

H C O 3 –

m g / L

C l –

m g / L

S O 4

2 –

m g / L

S O 4 - S

m g / L

B r m g / L

F – m g / L

S i m g / l

F e m g / l

M n m g / L

L i m g / L

P F M 0 0 0

0 6 6

8 9 5 2

0 . 1

2 0 0 5 - 0 8 - 0 1

4 . 1

2

5 . 8

1 . 8

1

6 1 . 0

3 . 5

1 8 8

4 . 4

3 . 9

0

1 . 9

8

0 . 0

6 3

0 . 2

6

3 . 8

9

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 6

8 9 5 5

0 . 1

2 0 0 5 - 0 9 - 0 5

2 . 4

5

5 . 3

1 . 4

4

5 6 . 5

3 . 2

1 8 0

3 . 7

4 . 2

3

2 . 0

2

0 . 0

3 8

0 . 2

6

4 . 8

1

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 6

8 9 9 3

0 . 1

2 0 0 5 - 1 0 - 3 1

4 . 6

7

5 . 7

2 . 3

5

6 1 . 8

3 . 6

1 7 8

5 . 7

1 1 . 1

4 . 3

3

0 . 0

4 4

0 . 2

4

5 . 4

7

0 . 0 5 3

< 0 . 0

0 3

< 0 . 0

0 4

P F M 0 0 0

0 6 6

1 2 0 1 6

0 . 1

2 0 0 5 - 1 1 - 2 8

4 . 3

5

5 . 5

2 . 6

5

6 1 . 8

3 . 2

1 7 9

5 . 7

1 1 . 0

3 . 9

1

0 . 0

7 7

0 . 2

3

5 . 1

4

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 6

1 2 0 2 2

0 . 1

2 0 0 5 - 1 2 - 1 9

2 . 9

4

6 . 1

3 . 0

0

6 9 . 6

3 . 8

2 0 2

7 . 2

1 6 . 4

5 . 8

0

0 . 0

7 9

0 . 2

2

6 . 1

7

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 6

1 2 0 4 2

0 . 1

2 0 0 6 - 0 1 - 2 3

4 . 9

9

7 . 2

2 . 8

1

8 8 . 2

4 . 3

2 4 7

8 . 3

1 4 . 9

5 . 8

0

0 . 0

7 9

0 . 2

1

7 . 5

8

0 . 1 0 9

0 . 1

5 2 0

< 0 . 0

0 4

P F M 0 0 0

0 6 6

1 2 0 8 1

0 . 1

2 0 0 6 - 0 2 - 2 0

1 . 5

7

6 . 5

2 . 6

4

7 4 . 9

3 . 9

2 3 1

7 . 4

1 1 . 9

4 . 3

3

0 . 0

7 5

0 . 2

0

6 . 0

3

0 . 0 9 0

0 . 0

2 6 2

< 0 . 0

4

P F M 0 0 0

0 6 6

1 2 0 9 8

0 . 1

2 0 0 6 - 0 3 - 2 0

4 . 3

3

6 . 3

2 . 7

2

8 4 . 2

4 . 2

2 4 6

7 . 2

9 . 6

1

3 . 8

4

0 . 0

6

0 . 2

3

6 . 2

6

0 . 1 6 0

0 . 0

3 7 9

< 0 . 0

0 4

P F M 0 0 0

0 6 6

1 2 2 3 5

0 . 1

2 0 0 6 - 0 4 - 1 8

5 . 5

3

3 . 3

2 . 2

5

4 3 . 2

2 . 4

1 2 3

3 . 6

7 . 2

4

2 . 7

9

< 0 . 2

< 0 . 2

4 . 0

0

0 . 0 4 7

0 . 0

1 2 8

< 0 . 0

0 4

P F M 0 0 0

0 6 6

1 2 2 5 3

0 . 1

2 0 0 6 - 0 5 - 1 5

4 . 0

6

4 . 8

2 . 3

7

6 8 . 6

3 . 3

2 0 2

4 . 9

7 . 4

1

3 . 1

3

0 . 0

3 2

0 . 2

4

4 . 4

9

0 . 0 9 5

0 . 0

0 4 5

< 0 . 0

0 4

P F M 0 0 0

0 6 6

1 2 2 9 8

0 . 1

2 0 0 6 - 0 6 - 1 3

4 . 3

1

5 . 7

2 . 3

3

6 5 . 0

3 . 4

1 9 6

5 . 3

5 . 2

9

2 . 2

2

0 . 0

4 6

0 . 2

5

2 . 8

8

0 . 1 7 7

0 . 0

1 3 4

< 0 . 0

0 4

P F M 0 0 0

0 6 8

8 9 3 2

0 . 1

2 0 0 5 - 0 7 - 1 2

3 . 1

7

2 0 . 9

1 . 4

5

6 1 . 9

6 . 1

1 8 7

3 3 . 1

8 . 5

2

3 . 8

8

0 . 2

0 5

0 . 2

7

4 . 9

5

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 8

8 9 5 1

0 . 5

2 0 0 5 - 0 8 - 0 1

2 . 9

7

2 2 . 6

1 . 2

6

6 7 . 3

6 . 7

2 0 3

3 7 . 4

8 . 3

5

3 . 8

0

0 . 2

1

0 . 3

2

4 . 8

6

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 8

8 9 6 0

0 . 5

2 0 0 5 - 0 9 - 0 5

2 . 5

7

1 8 . 0

0 . 8

4

6 1 . 9

6 . 0

1 9 2

2 8 . 1

7 . 2

0

3 . 4

0

0 . 1

2

0 . 3

4

5 . 2

7

–

–

< 0 . 0

0 4

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

S r m g / L

I – m g / L

p H_

L

m g / L

p H_

F

m g / L

T

e m p_

F

°

C l

E C_

L

m S / m

P F M 0 0 0

0 6 6

8 9 5 2

0 . 1

2 0 0 5 - 0 8 - 0 1

0 . 0

7 1

0 . 0

0 6

7 . 6

0

7 . 5

6

1 6 . 3

3 2 . 3

P F M 0 0 0

0 6 6

8 9 5 5

0 . 1

2 0 0 5 - 0 9 - 0 5

0 . 0

7 2

0 . 0

1 0

7 . 5

6

7 . 7

2

1 2 . 8

3 2 . 6

P F M 0 0 0

0 6 6

8 9 9 3

0 . 1

2 0 0 5 - 1 0 - 3 1

0 . 0

6 2

0 . 0

0 4

7 . 4

4

7 . 3

9

7 . 2

3 2 . 2

P F M 0 0 0

0 6 6

1 2 0 1 6

0 . 1

2 0 0 5 - 1 1 - 2 8

0 . 0

6 5

0 . 0

0 9

7 . 4

4

7 . 4

7

0 . 6

3 3 . 3

P F M 0 0 0

0 6 6

1 2 0 2 2

0 . 1

2 0 0 5 - 1 2 - 1 9

0 . 0

7 3

0 . 0

0 9

7 . 0

7

7 . 2

6

– 0 . 1

3 7 . 5

P F M 0 0 0

0 6 6

1 2 0 4 2

0 . 1

2 0 0 6 - 0 1 - 2 3

0 . 0

8 4

0 . 0

0 8

7 . 0

2

7 . 0

9

– 0 . 1

4 4 . 0

P F M 0 0 0

0 6 6

1 2 0 8 1

0 . 1

2 0 0 6 - 0 2 - 2 0

0 . 0

7 5

0 . 0

0 7

7 . 0

7

7 . 1

8

– 0 . 1

4 0 . 7

P F M 0 0 0

0 6 6

1 2 0 9 8

0 . 1

2 0 0 6 - 0 3 - 2 0

0 . 0

8 3

0 . 0

0 5

7 . 0

0

7 . 0

8

– 0 . 1

4 2 . 7

P F M 0 0 0

0 6 6

1 2 2 3 5

0 . 1

2 0 0 6 - 0 4 - 1 8

0 . 0

4 2

0 . 0

0 8

7 . 0

4

7 . 1

2

3 . 8

2 3 . 2

P F M 0 0 0

0 6 6

1 2 2 5 3

0 . 1

2 0 0 6 - 0 5 - 1 5

0 . 0

6 5

0 . 0

0 5

7 . 4

6

7 . 4

8

1 1 . 5

3 5 . 2

P F M 0 0 0

0 6 6

1 2 2 9 8

0 . 1

2 0 0 6 - 0 6 - 1 3

0 . 0

7 1

0 . 0

0 5

7 . 4

5

7 . 4

6

1 7 . 8

3 3 . 1

P F M 0 0 0

0 6 8

8 9 3 2

0 . 1

2 0 0 5 - 0 7 - 1 2

0 . 1

0 3

0 . 0

0 9

7 . 4

3

7 . 3

8

1 6 . 7

4 2 . 5

P F M 0 0 0

0 6 8

8 9 5 1

0 . 5

2 0 0 5 - 0 8 - 0 1

0 . 1

1 6

0 . 0

0 9

7 . 4

9

7 . 5

7

1 5 . 5

4 6 . 2

P F M 0 0 0

0 6 8

8 9 6 0

0 . 5

2 0 0 5 - 0 9 - 0 5

0 . 1

1 4

0 . 0

0 9

7 . 5

2

7 . 6

7

1 2 . 5

4 1 . 8



73

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

R C B

%

N a m g / L

K m g / L

C a m g / L

M

g

m

g / L

H C O 3 –

m g / L

C l –

m g / L

S O 4

2 –

m g / L

S O 4 - S

m g / L

B r m g / L

F – m g / L

S i m g / l

F e m g / l

M n m g / L

L i m g / L

P F M 0 0 0

0 6 8

8 9 7 7

0 . 1

2 0 0 5 - 1 0 - 0 3

1 . 3

6

2 5 . 5

2 . 0

5

6 7 . 9

7 . 4

2 2 0

4 3 . 1

6 . 2

8

2 . 7

4

0 . 2

6 5

0 . 4

4

7 . 2

3

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 8

9 0 0 0

0 . 5

2 0 0 5 - 1 0 - 3 1

3 . 6

1

1 6 . 0

2 . 2

7

5 9 . 4

5 . 5

1 6 5

2 7 . 1

1 6 . 9

6 . 2

8

0 . 1

1 8

0 . 2

9

5 . 8

5

0 . 1 5 2

0 . 0

0 5 1

< 0 . 0

0 4

P F M 0 0 0

0 6 8

8 9 9 9

0 . 5

2 0 0 5 - 1 1 - 2 8

4 . 8

5

1 3 . 5

2 . 4

3

5 4 . 2

4 . 3

1 5 0

2 1 . 2

1 3 . 6

4 . 7

4

0 . 1

0 9

0 . 2

8

5 . 2

0

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 8

1 2 0 2 7

0 . 1

2 0 0 5 - 1 2 - 1 9

4 . 0

1

1 1 . 2

2 . 8

8

6 0 . 7

4 . 7

1 7 1

1 6 . 9

1 6 . 3

5 . 9

7

0 . 1

0

0 . 2

8

5 . 4

1

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 8

1 2 0 4 5

0 . 1

2 0 0 6 - 0 1 - 2 3

5 . 4

2

1 3 . 1

2 . 6

5

7 0 . 4

5 . 2

1 9 5

1 9 . 8

1 3 . 6

5 . 4

1

0 . 1

0 6

0 . 2

7

6 . 5

1

0 . 2 9 6

0 . 0

6 7 0

< 0 . 0

0 4

P F M 0 0 0

0 6 8

1 2 0 8 2

0 . 1

2 0 0 6 - 0 2 - 2 0

2 . 8

2

1 1 . 5

2 . 4

4

6 0 . 6

4 . 6

1 8 3

1 6 . 3

1 1 . 5

4 . 3

6

0 . 1

0

0 . 2

6

5 . 2

6

0 . 1 7 9

0 . 0

2 3 3

< 0 . 0

4

P F M 0 0 0

0 6 8

1 2 0 9 1

0 . 1

2 0 0 6 - 0 3 - 2 0

4 . 9

9

1 1 . 7

2 . 5

6

7 0 . 5

5 . 1

2 0 2

1 7 . 3

1 0 . 1

4 . 2

7

0 . 1

1 3

0 . 2

9

5 . 9

3

0 . 2 1 6

0 . 0

1 5 2

< 0 . 0

0 4

P F M 0 0 0

0 6 8

1 2 2 3 7

0 . 1

2 0 0 6 - 0 4 - 1 9

6 . 0

1

5 . 2

1 . 9

1

3 5 . 4

2 . 6

9 4 . 6

7 . 6

9 . 6

4

3 . 6

3

< 0 . 2

0 . 2

1

3 . 6

5

0 . 0 8 5

0 . 0

0 5 9

< 0 . 0

0 4

P F M 0 0 0

0 6 8

1 2 2 5 0

0 . 1

2 0 0 6 - 0 5 - 1 5

4 . 9

9

1 0 . 5

2 . 3

9

5 6 . 5

4 . 2

1 5 9

1 6 . 1

1 0 . 1

4 . 1

7

0 . 0

8 8

0 . 2

9

4 . 7

4

0 . 1 9 0

0 . 0

1 3 3

< 0 . 0

0 4

P F M 0 0 0

0 6 8

1 2 3 0 2

0 . 1

2 0 0 6 - 0 6 - 1 2

5 . 5

2

2 0 . 3

2 . 3

7

6 5 . 6

5 . 8

1 8 5

3 1 . 8

9 . 5

0

4 . 0

9

0 . 1

4 5

0 . 3

5

6 . 0

6

0 . 4 0 8

0 . 0

6 9 5

< 0 . 0

0 4

P F M 0 0 0

0 6 9

8 9 3 1

0 . 1

2 0 0 5 - 0 7 - 1 2

3 . 8

6

2 1 . 7

1 . 6

0

6 2 . 6

6 . 2

1 8 8

3 3 . 7

8 . 3

7

3 . 6

2

0 . 2

1 6

0 . 2

9

4 . 7

5

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 9

8 9 4 7

0 . 1

2 0 0 5 - 0 8 - 0 1

2 . 7

5

2 3 . 6

1 . 1

0

6 6 . 6

6 . 8

2 0 3

3 9 . 3

7 . 5

5

3 . 4

7

0 . 2

4 1

0 . 3

6

4 . 6

1

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 9

8 9 5 6

0 . 1

2 0 0 5 - 0 9 - 0 5

2 . 3

6

1 8 . 8

0 . 7

3

6 2 . 5

6 . 2

1 9 3

3 0 . 3

7 . 5

4

3 . 5

4

0 . 1

4

0 . 3

7

5 . 2

4

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 9

8 9 7 4

0 . 1

2 0 0 5 - 1 0 - 0 3

3 . 1

1

2 7 . 3

1 . 5

5

6 9 . 8

7 . 8

2 1 5

4 4 . 2

8 . 8

4

3 . 6

7

0 . 3

0

0 . 4

7

7 . 2

6

–

–

< 0 . 0

0 4

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

S r m g / L

I – m g / L

p H_

L

m g / L

p H_

F

m g / L

T

e m p_

F

°

C l

E C_

L

m S / m

P F M 0 0 0

0 6 8

8 9 7 7

0 . 1

2 0 0 5 - 1 0 - 0 3

0 . 1

1 4

0 . 0

1 1

7 . 3

2

7 . 3

4

1 0 . 2

4 9 . 3

P F M 0 0 0

0 6 8

9 0 0 0

0 . 5

2 0 0 5 - 1 0 - 3 1

0 . 0

8 6

0 . 0

0 6

7 . 3

2

7 . 3

4

7 . 3

3 9 . 5

P F M 0 0 0

0 6 8

8 9 9 9

0 . 5

2 0 0 5 - 1 1 - 2 8

0 . 0

8 1

0 . 0

0 7

7 . 3

1

7 . 5

2

1 . 1

3 4 . 4

P F M 0 0 0

0 6 8

1 2 0 2 7

0 . 1

2 0 0 5 - 1 2 - 1 9

0 . 0

8 6

0 . 0

0 3

6 . 9

3

7 . 2

8

– 0 . 1

3 6 . 8

P F M 0 0 0

0 6 8

1 2 0 4 5

0 . 1

2 0 0 6 - 0 1 - 2 3

0 . 0

9 3

0 . 0

0 7

6 . 9

6

7 . 0

1

– 0 . 1

4 1 . 3

P F M 0 0 0

0 6 8

1 2 0 8 2

0 . 1

2 0 0 6 - 0 2 - 2 0

0 . 0

8 3

0 . 0

0 7

6 . 9

9

7 . 1

1

– 0 . 1

3 7 . 2

P F M 0 0 0

0 6 8

1 2 0 9 1

0 . 1

2 0 0 6 - 0 3 - 2 0

0 . 0

9 4

0 . 0

0 9

7 . 0

2

7 . 1

4

– 0 . 1

3 9 . 8

P F M 0 0 0

0 6 8

1 2 2 3 7

0 . 1

2 0 0 6 - 0 4 - 1 9

0 . 0

4 5

0 . 0

0 7

7 . 0

5

7 . 1

3

2 . 2

2 1 . 8

P F M 0 0 0

0 6 8

1 2 2 5 0

0 . 1

2 0 0 6 - 0 5 - 1 5

0 . 0

7 4

0 . 0

0 6

7 . 3

2

7 . 3

2

9 . 3

3 3 . 2

P F M 0 0 0

0 6 8

1 2 3 0 2

0 . 1

2 0 0 6 - 0 6 - 1 2

0 . 1

0 2

0 . 0

0 6

7 . 4

5

7 . 4

3

1 6 . 8

4 2 . 1

P F M 0 0 0

0 6 9

8 9 3 1

0 . 1

2 0 0 5 - 0 7 - 1 2

0 . 1

0 4

0 . 0

0 9

7 . 6

1

7 . 5

7

1 6 . 6

4 2 . 7

P F M 0 0 0

0 6 9

8 9 4 7

0 . 1

2 0 0 5 - 0 8 - 0 1

0 . 1

1 3

0 . 0

1 0

7 . 7

1

7 . 6

7

1 5 . 7

4 8 . 3

P F M 0 0 0

0 6 9

8 9 5 6

0 . 1

2 0 0 5 - 0 9 - 0 5

0 . 1

1 6

0 . 0

0 9

7 . 5

5

7 . 8

0

1 2 . 6

4 2 . 2

P F M 0 0 0

0 6 9

8 9 7 4

0 . 1

2 0 0 5 - 1 0 - 0 3

0 . 1

1 9

0 . 0

1 3

7 . 6

1

7 . 6

6

1 0 . 1

4 9 . 8



74

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

R C B

%

N a m g / L

K m g / L

C a m g / L

M

g

m

g / L

H C O 3 –

m g / L

C l –

m g / L

S O 4

2 –

m g / L

S O 4 - S

m g / L

B r m g / L

F – m g / L

S i m g / l

F e m g / l

M n m g / L

L i m g / L

P F M 0 0 0

0 6 9

8 9 9 5

0 . 1

2 0 0 5 - 1 0 - 3 1

2 . 6

7

2 0 . 7

1 . 7

7

6 5 . 7

6 . 5

1 9 6

3 6 . 1

1 0 . 1

4 . 1

4

0 . 1

6

0 . 3

3

6 . 7

1

0 . 0 8 2

0 . 0

0 7 0

< 0 . 0

0 4

P F M 0 0 0

0 6 9

1 2 0 1 7

0 . 1

2 0 0 5 - 1 1 - 2 8

4 . 4

1

1 9 . 3

2 . 4

6

6 7 . 8

5 . 7

1 9 0

3 2 . 8

1 2 . 9

4 . 7

4

0 . 1

7 3

0 . 3

1

7 . 1

4

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 9

1 2 0 2 0

0 . 1

2 0 0 5 - 1 2 - 1 9

3 . 4

8

1 4 . 4

3 . 2

6

7 2 . 0

5 . 5

1 9 9

2 4 . 7

2 0 . 8

7 . 3

6

0 . 1

3 9

0 . 3

2

7 . 0

4

–

–

< 0 . 0

0 4

P F M 0 0 0

0 6 9

1 2 0 4 3

0 . 1

2 0 0 6 - 0 1 - 2 3

3 . 7

5

1 8 . 5

3 . 1

2

8 7 . 5

6 . 6

2 4 3

3 2 . 6

1 6 . 2

7 . 3

0

0 . 1

6

0 . 3

6

9 . 3

9

0 . 5 9 0

0 . 1

3 3 0

< 0 . 0

0 4

P F M 0 0 0

0 6 9

1 2 0 7 9

0 . 1

2 0 0 6 - 0 2 - 2 0

1 . 1

8

1 5 . 9

2 . 6

8

7 5 . 0

5 . 8

2 2 8

2 6 . 8

1 5 . 3

5 . 6

3

0 . 1

3 7

0 . 3

2

7 . 1

7

0 . 2 5 2

0 . 0

4 6 8

< 0 . 0

4

P F M 0 0 0

0 6 9

1 2 0 9 9

0 . 1

2 0 0 6 - 0 3 - 2 0

3 . 1

9

1 7 . 2

2 . 9

9

8 6 . 2

6 . 4

2 5 2

3 0 . 2

1 2 . 5

4 . 9

3

0 . 1

5 4

0 . 3

3

8 . 0

5

0 . 4 0 9

0 . 0

5 4 7

< 0 . 0

0 4

P F M 0 0 0

0 6 9

1 2 2 3 0

0 . 1

2 0 0 6 - 0 4 - 1 9

5 . 4

5

7 . 1

2 . 2

3

4 3 . 6

3 . 3

1 1 4

1 1 . 5

1 3 . 5

5 . 0

5

< 0 . 2

0 . 2

3

4 . 2

5

0 . 0 8 1

0 . 0

0 8 7

< 0 . 0

0 4

P F M 0 0 0

0 6 9

1 2 2 3 6

0 . 1

2 0 0 6 - 0 5 - 1 5

3 . 1

1 2 . 9

2 . 4

9

5 7 . 9

4 . 7

1 6 4

2 1 . 6

1 4 . 1

5 . 6

9

0 . 1

0 9

0 . 3

2

5 . 7

4

0 . 1 2 7

0 . 0

0 3 4

< 0 . 0

0 4

P F M 0 0 0

0 6 9

1 2 3 0 1

0 . 1

2 0 0 6 - 0 6 - 1 2

4 . 3

4

2 0 . 6

2 . 3

2

6 3 . 7

5 . 8

1 8 4

3 2 . 9

1 0 . 3

4 . 2

0

0 . 1

5

0 . 3

6

6 . 1

9

0 . 1 3 5

0 . 0

0 5 3

< 0 . 0

0 4

P F M 0 0 0

0 7 0

8 9 3 3

0 . 1

2 0 0 5 - 0 7 - 1 2

4 . 7

5

6 . 7

0 . 7

3

4 8 . 7

3 . 0

1 5 3

4 . 1

2 . 7

0

1 . 5

1

0 . 0

5 9

< 0 . 2

3 . 4

8

–

–

< 0 . 0

0 4

P F M 0 0 0

0 7 0

8 9 5 4

0 . 1

2 0 0 5 - 0 8 - 0 2

4 . 8

9

5 . 9

1 . 2

8

4 5 . 9

2 . 9

1 4 1

4 . 5

3 . 1

3

1 . 7

0

0 . 0

5 6

0 . 2

1

3 . 5

0

–

–

< 0 . 0

0 4

P F M 0 0 0

0 7 0

8 9 5 7

0 . 1

2 0 0 5 - 0 9 - 0 6

2 . 1

6

6 . 0

0 . 9

7

3 7 . 3

2 . 6

1 2 3

4 . 9

3 . 2

0

1 . 6

3

0 . 0

1 7

< 0 . 2

3 . 0

1

–

–

< 0 . 0

0 4

P F M 0 0 0

0 7 0

8 9 7 5

0 . 1

2 0 0 5 - 1 0 - 0 4

3 . 3

4

6 . 5

1 . 1

1

4 3 . 6

2 . 8

1 3 9

5 . 7

2 . 7

9

1 . 3

9

0 . 0

7 1

0 . 2

4

4 . 1

9

–

–

< 0 . 0

0 4

P F M 0 0 0

0 7 0

8 9 9 2

0 . 1

2 0 0 5 - 1 1 - 0 1

4 . 7

2

6 . 3

1 . 8

7

3 4 . 2

2 . 7

1 0 5

6 . 4

5 . 1

2

2 . 1

2

0 . 0

4 2

0 . 2

2

2 . 4

4

0 . 0 3 8

0 . 0

0 9 0

< 0 . 0

0 4

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

S r m g / L

I – m g / L

p H_

L

m g / L

p H_

F

m g / L

T

e m p_

F

°

C l

E C_

L

m S / m

P F M 0 0 0

0 6 9

8 9 9 5

0 . 1

2 0 0 5 - 1 0 - 3 1

0 . 0

9 6

0 . 0

0 8

7 . 3

8

7 . 3

7

7 . 3

4 5 . 0

P F M 0 0 0

0 6 9

1 2 0 1 7

0 . 1

2 0 0 5 - 1 1 - 2 8

0 . 1

0 5

0 . 0

0 7

7 . 2

8

7 . 4

9

1 . 3

4 4 . 0

P F M 0 0 0

0 6 9

1 2 0 2 0

0 . 1

2 0 0 5 - 1 2 - 1 9

0 . 1

0 4

0 . 0

1 0

6 . 9

1

7 . 3

2

– 0 . 1

4 4 . 0

P F M 0 0 0

0 6 9

1 2 0 4 3

0 . 1

2 0 0 6 - 0 1 - 2 3

0 . 1

1 7

0 . 0

0 9

6 . 8

3

6 . 9

2

– 0 . 1

5 1 . 6

P F M 0 0 0

0 6 9

1 2 0 7 9

0 . 1

2 0 0 6 - 0 2 - 2 0

0 . 1

0 3

0 . 0

0 9

6 . 8

9

7 . 0

2

– 0 . 1

4 7 . 4

P F M 0 0 0

0 6 9

1 2 0 9 9

0 . 1

2 0 0 6 - 0 3 - 2 0

0 . 1

1 7

0 . 0

0 7

6 . 8

6

6 . 9

9

– 0 . 1

5 1 . 5

P F M 0 0 0

0 6 9

1 2 2 3 0

0 . 1

2 0 0 6 - 0 4 - 1 9

0 . 0

5 5

0 . 0

1 2

6 . 9

7

7 . 0

6

1 . 9

2 6 . 4

P F M 0 0 0

0 6 9

1 2 2 3 6

0 . 1

2 0 0 6 - 0 5 - 1 5

0 . 0

7 8

0 . 0

0 6

7 . 2

6

7 . 2

1

9 . 0

3 6 . 7

P F M 0 0 0

0 6 9

1 2 3 0 1

0 . 1

2 0 0 6 - 0 6 - 1 2

0 . 1

0 0

0 . 0

0 8

7 . 3

9

7 . 3

6

1 6 . 3

4 2 . 4

P F M 0 0 0

0 7 0

8 9 3 3

0 . 1

2 0 0 5 - 0 7 - 1 2

0 . 0

5 6

0 . 0

1 3

7 . 0

6

7 . 2

9

1 8 . 0

2 6 . 5

P F M 0 0 0

0 7 0

8 9 5 4

0 . 1

2 0 0 5 - 0 8 - 0 2

0 . 0

5 1

0 . 0

1 0

7 . 2

2

7 . 3

6

1 5 . 9

2 5 . 5

P F M 0 0 0

0 7 0

8 9 5 7

0 . 1

2 0 0 5 - 0 9 - 0 6

0 . 0

4 7

< 0 . 0

0 1

7 . 1

4

7 . 4

4

1 4 . 0

2 2 . 6

P F M 0 0 0

0 7 0

8 9 7 5

0 . 1

2 0 0 5 - 1 0 - 0 4

0 . 0

4 5

0 . 0

1 1

7 . 1

3

7 . 4

6

9 . 2

2 4 . 9

P F M 0 0 0

0 7 0

8 9 9 2

0 . 1

2 0 0 5 - 1 1 - 0 1

0 . 0

3 6

0 . 0

0 5

7 . 1

8

7 . 3

8

6 . 4

2 0 . 7



75

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

R C B

%

N a m g / L

K m g / L

C a m g / L

M

g

m

g / L

H C O 3 –

m g / L

C l –

m g / L

S O 4

2 –

m g / L

S O 4 - S

m g / L

B r m g / L

F – m g / L

S i m g / l

F e m g / l

M n m g / L

L i m g / L

P F M 0 0 0

0 7 0

1 2 0 1 4

0 . 1

2 0 0 5 - 1 1 - 2 8

5 . 4

7

6 . 6

1 . 8

5

3 6 . 9

2 . 7

1 1 4

5 . 8

4 . 4

8

1 . 7

1

0 . 0

4 5

0 . 2

2

1 . 6

3

–

–

< 0 . 0

0 4

P F M 0 0 0

0 7 0

1 2 0 2 5

0 . 1

2 0 0 5 - 1 2 - 2 0

3 . 5

6

6 . 6

2 . 0

7

4 0 . 6

3 . 0

1 2 8

6 . 2

5 . 8

9

2 . 4

1

0 . 0

4 6

0 . 2

3

2 . 1

4

–

–

< 0 . 0

0 4

P F M 0 0 0

0 7 0

1 2 0 6 9

0 . 1

2 0 0 6 - 0 1 - 2 4

4 . 6

7 . 5

2 . 0

3

4 7 . 7

3 . 2

1 4 6

7 . 2

5 . 7

0

2 . 4

1

0 . 0

4 5

0 . 2

1

2 . 2

2

–

–

< 0 . 0

0 4

P F M 0 0 0

0 7 0

1 2 0 8 3

0 . 5

2 0 0 6 - 0 2 - 2 1

3 . 6

8

6 . 1

1 . 9

5

4 7 . 7

3 . 1

1 4 4

6 . 1

7 . 9

9

3 . 1

6

0 . 0

5 3

0 . 2

0

3 . 5

6

0 . 0 6 6

0 . 0

1 7 3

< 0 . 0

4

P F M 0 0 0

0 7 0

1 2 0 9 2

0 . 1

2 0 0 6 - 0 3 - 2 1

4 . 0

8

5 . 8

1 . 9

6

5 5 . 7

3 . 1

1 6 5

6 . 0

7 . 5

6

3 . 1

2

0 . 0

4 5

0 . 2

1

3 . 8

5

0 . 0 7 4

0 . 0

6 1 5

< 0 . 0

0 4

P F M 0 0 0

0 7 0

1 2 2 4 0

0 . 1

2 0 0 6 - 0 4 - 1 9

8 . 4

5

2 . 8

1 . 2

2

2 4 . 7

1 . 5

6 7 . 3

2 . 7

3 . 6

5

1 . 5

4

< 0 . 2

< 0 . 2

2 . 2

9

0 . 0 6 8

0 . 0

1 3 9

< 0 . 0

0 4

P F M 0 0 0

0 7 0

1 2 2 5 2

0 . 1

2 0 0 6 - 0 5 - 1 6

5 . 4

7

5 . 7

1 . 7

0

4 8 . 1

2 . 9

1 4 2

5 . 3

4 . 9

5

2 . 2

2

0 . 0

3 1

0 . 2

0

1 . 6

5

0 . 0 3 8

0 . 0

0 6 7

< 0 . 0

0 4

P F M 0 0 0

0 7 0

1 2 3 0 4

0 . 1

2 0 0 6 - 0 6 - 1 2

6 . 0

6

6 . 3

1 . 1

6

4 8 . 1

2 . 9

1 4 4

4 . 9

3 . 3

2

1 . 5

8

0 . 0

3 9

0 . 2

1

1 . 5

2

0 . 0 9 8

0 . 0

8 4 3

< 0 . 0

0 4

P F M 0 0 0

0 7 4

8 9 3 7

0 . 5

2 0 0 5 - 0 7 - 1 1

4 . 1

9

1 0 . 9

1 . 7

6

7 0 . 8

4 . 3

2 1 8

1 2 . 5

3 . 5

7

2 . 0

8

0 . 0

8

< 0 . 2

4 . 2

1

0 . 0 4 4

0 . 0

0 8 0

0 . 0

0 3

P F M 0 0 0

0 7 4

8 9 4 8

0 . 5

2 0 0 5 - 0 8 - 0 1

3 . 5

2

1 2 . 1

1 . 6

8

6 6 . 8

4 . 4

2 0 6

1 5 . 7

4 . 3

1

2 . 2

4

0 . 0

8 6

0 . 2

6

5 . 5

9

–

–

< 0 . 0

0 4

P F M 0 0 0

0 7 4

8 9 6 2

0 . 5

2 0 0 5 - 0 9 - 0 5

2 . 4

4

1 1 . 5

1 . 5

2

7 5 . 9

4 . 6

2 3 9

1 4 . 6

4 . 0

2

2 . 1

6

0 . 0

6 5

0 . 2

8

6 . 7

7

–

–

< 0 . 0

0 4

P F M 0 0 0

0 7 4

8 9 7 6

0 . 5

2 0 0 5 - 1 0 - 0 3

2 . 8

7

1 2 . 4

1 . 6

1

6 7 . 8

4 . 5

2 1 1

1 7 . 1

4 . 9

7

2 . 1

6

0 . 1

1 9

0 . 3

1

7 . 7

3

0 . 0 1 4

0 . 0

0 1 8

< 0 . 0

0 4

P F M 0 0 0

0 7 4

8 9 9 8

0 . 5

2 0 0 5 - 1 0 - 3 1

4 . 1

9

1 1 . 3

2 . 2

9

6 4 . 7

4 . 1

1 9 3

1 6 . 3

5 . 2

0

2 . 3

4

0 . 0

5 3

0 . 2

7

7 . 3

4

< 0 . 0 2

< 0 . 0

0 3

< 0 . 0

0 4

P F M 0 0 0

0 7 4

1 2 0 1 8

0 . 5

2 0 0 5 - 1 1 - 2 9

2 . 9

8

7 . 5

2 . 7

0

7 4 . 3

3 . 7

2 1 5

1 0 . 2

1 4 . 5

5 . 2

7

0 . 1

0 5

0 . 2

4

6 . 7

3

–

–

< 0 . 0

0 4

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

S r m g / L

I – m g / L

p H_

L

m g / L

p H_

F

m g / L

T

e m p_

F

°

C l

E C_

L

m S / m

P F M 0 0 0

0 7 0

1 2 0 1 4

0 . 1

2 0 0 5 - 1 1 - 2 8

0 . 0

4 6

0 . 0

0 6

7 . 7

6

7 . 8

6

1 . 0

2 2 . 0

P F M 0 0 0

0 7 0

1 2 0 2 5

0 . 1

2 0 0 5 - 1 2 - 2 0

0 . 0

5 2

0 . 0

0 2

7 . 6

4

7 . 7

8

0 . 2

2 4 . 1

P F M 0 0 0

0 7 0

1 2 0 6 9

0 . 1

2 0 0 6 - 0 1 - 2 4

0 . 0

5 5

0 . 0

0 5

7 . 6

8

7 . 7

5

– 0 . 1

2 7 . 5

P F M 0 0 0

0 7 0

1 2 0 8 3

0 . 5

2 0 0 6 - 0 2 - 2 1

0 . 0

5 2

0 . 0

0 7

7 . 2

8

7 . 4

5

0 . 3

2 7 . 1

P F M 0 0 0

0 7 0

1 2 0 9 2

0 . 1

2 0 0 6 - 0 3 - 2 1

0 . 0

5 7

0 . 0

0 6

7 . 2

4

7 . 3

2

0 . 2

2 9 . 7

P F M 0 0 0

0 7 0

1 2 2 4 0

0 . 1

2 0 0 6 - 0 4 - 1 9

0 . 0

2 5

0 . 0

0 6

7 . 0

6

7 . 3

7

4 . 7

1 3 . 5

P F M 0 0 0

0 7 0

1 2 2 5 2

0 . 1

2 0 0 6 - 0 5 - 1 6

0 . 0

4 8

0 . 0

0 5

7 . 5

0

7 . 5

0

1 1 . 5

2 5 . 8

P F M 0 0 0

0 7 0

1 2 3 0 4

0 . 1

2 0 0 6 - 0 6 - 1 2

0 . 0

5 3

0 . 0

0 7

7 . 0

9

7 . 1

4

1 9 . 6

2 5 . 3

P F M 0 0 0

0 7 4

8 9 3 7

0 . 5

2 0 0 5 - 0 7 - 1 1

0 . 0

9 0

0 . 0

1 1

7 . 5

6

7 . 2

5

2 0 . 6

3 9 . 4

P F M 0 0 0

0 7 4

8 9 4 8

0 . 5

2 0 0 5 - 0 8 - 0 1

0 . 0

8 8

0 . 0

0 9

7 . 5

7

7 . 5

1

1 9 . 4

3 8 . 8

P F M 0 0 0

0 7 4

8 9 6 2

0 . 5

2 0 0 5 - 0 9 - 0 5

0 . 1

0 3

0 . 0

1 0

7 . 7

3

8 . 1

7

1 5 . 4

4 2 . 4

P F M 0 0 0

0 7 4

8 9 7 6

0 . 5

2 0 0 5 - 1 0 - 0 3

0 . 0

8 4

0 . 0

1 3

8 . 1

2

8 . 1

5

1 2 . 1

3 9 . 4

P F M 0 0 0

0 7 4

8 9 9 8

0 . 5

2 0 0 5 - 1 0 - 3 1

0 . 0

7 0

0 . 0

0 4

8 . 0

0

8 . 0

7

7 . 3

3 6 . 8

P F M 0 0 0

0 7 4

1 2 0 1 8

0 . 5

2 0 0 5 - 1 1 - 2 9

0 . 0

8 0

0 . 0

1 3

6 . 9

2

7 . 5

9

3 . 7

4 0 . 1



76

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

R C B

%

N a m g / L

K m g / L

C a m g / L

M

g

m

g / L

H C O 3 –

m g / L

C l –

m g / L

S O 4

2 –

m g / L

S O 4 - S

m g / L

B r m g / L

F – m g / L

S i m g / l

F e m g / l

M n m g / L

L i m g / L

P F M 0 0 0

0 7 4

1 2 0 2 3

0 . 5

2 0 0 5 - 1 2 - 2 0

2 . 8

5

8 . 4

2 . 9

3

7 1 . 0

3 . 9

2 0 6

1 1 . 8

1 5 . 7

5 . 5

6

0 . 0

7 7

0 . 2

4

6 . 2

0

–

–

< 0 . 0

0 4

P F M 0 0 0

0 7 4

1 2 0 3 2

0 . 5

2 0 0 6 - 0 1 - 2 4

3 . 4

6

1 2 . 7

2 . 8

5

8 7 . 9

4 . 6

2 4 7

2 1 . 7

1 3 . 9

5 . 7

5

0 . 1

2 2

0 . 2

4

7 . 4

5

0 . 0 9 1

0 . 0

3 5 0

< 0 . 0

0 4

P F M 0 0 0

0 7 4

1 2 0 8 0

0 . 5

2 0 0 6 - 0 2 - 2 1

1 . 2

3

7 . 4

2 . 6

4

7 6 . 1

4 . 0

2 3 4

1 0 . 0

1 2 . 2

4 . 4

5

0 . 0

8 7

0 . 2

1

6 . 1

4

0 . 0 5 6

0 . 0

1 4 4

< 0 . 0

4

P F M 0 0 0

0 7 4

1 2 2 0 0

1 . 5

2 0 0 6 - 0 3 - 2 0

5 . 1

7

7 . 2

2 . 8

0

8 6 . 3

4 . 4

2 4 4

1 0 . 0

1 0 . 7

4 . 2

3

0 . 0

5 6

0 . 2

3

6 . 5

1

0 . 0 6 1

0 . 0

1 0 6

< 0 . 0

0 4

P F M 0 0 0

0 7 4

1 2 2 3 2

0 . 5

2 0 0 6 - 0 4 - 1 8

4 . 8

4

3 . 7

2 . 1

6

4 5 . 1

2 . 5

1 2 9

4 . 9

7 . 5

8

2 . 8

4

< 0 . 2

< 0 . 2

4 . 0

3

0 . 0 3 9

0 . 0

0 8 7

< 0 . 0

0 4

P F M 0 0 0

0 7 4

1 2 2 4 8

0 . 5

2 0 0 6 - 0 5 - 1 5

7

8 . 6

2 . 7

6

7 1 . 9

3 . 8

1 9 7

1 2 . 2

6 . 7

9

3 . 1

0

0 . 0

4 6

0 . 2

8

5 . 1

8

0 . 0 4 8

0 . 0

0 4 5

< 0 . 0

0 4

P F M 0 0 0

0 7 4

1 2 3 0 3

0 . 5

2 0 0 6 - 0 6 - 1 3

5 . 9

3

1 1 . 1

2 . 4

3

7 4 . 1

4 . 2

2 1 5

1 4 . 4

4 . 6

6

2 . 1

4

0 . 0

5 2

0 . 2

9

4 . 0

3

0 . 0 4 0

0 . 0

0 7 3

< 0 . 0

0 4

P F M 0 0 0

0 8 2

1 2 0 4 6

0 . 5

2 0 0 6 - 0 1 - 2 3

– 2 . 7

7

1 5 5 0

5 4 . 8

8 2 . 5

1

8 9

8 1 . 5

2 9 3 0

4 1 4

1 5 1

1 1 . 5

–

0 . 8

9

0 . 0 1 5

0 . 0

0 3 0

0 . 0

2 4

P F M 0 0 0

0 8 2

1 2 0 3 0

6

2 0 0 6 - 0 1 - 2 3

– 3 . 0

7

1 5 5 0

5 5 . 6

8 3 . 3

1

9 0

8 2 . 2

2 9 5 0

4 2 0

1 5 3

1 0 . 6

0 . 4

8

0 . 9

2

0 . 0 1 5

0 . 0

0 3 0

0 . 0

2 4

P F M 0 0 0

0 8 2

1 2 0 8 4

0 . 5

2 0 0 6 - 0 2 - 2 0

– 3 . 1

8

1 4 7 0

5 7 . 5

7 8 . 8

1

9 1

7 8 . 5

2 8 3 0

4 0 5

1 5 1

9 . 2

9

0 . 3

5

0 . 8

3

< 0 . 0 2

< 0 . 0

0 3

0 . 0

2 6

P F M 0 0 0

0 8 2

1 2 0 8 5

6

2 0 0 6 - 0 2 - 2 0

– 2 . 9

9

1 4 8 0

5 6 . 4

7 8 . 5

1

8 7

7 7 . 8

2 8 3 0

3 9 8

1 4 7

9 . 4

8

–

0 . 8

3

< 0 . 0 2

< 0 . 0

0 3

0 . 0

2 6

P F M 0 0 0

0 8 2

1 2 0 9 7

0 . 5

2 0 0 6 - 0 3 - 2 0

– 2 . 1

4

1 4 8 0

5 6 . 9

7 7 . 1

1

7 7

7 8 . 7

2 7 5 0

3 8 1

1 4 3

1 1 . 1

0 . 3

0

0 . 6

8

< 0 . 0 2

< 0 . 0

0 3

0 . 0

2 5

P F M 0 0 0

0 8 2

1 2 0 9 0

6

2 0 0 6 - 0 3 - 2 0

– 2 . 2

5

1 4 9 0

5 7 . 5

7 8 . 8

1

7 9

7 9 . 8

2 7 8 0

3 8 6

1 4 4

1 1 . 0

0 . 3

0

0 . 7

5

< 0 . 0 2

0 . 0

0 7 5

0 . 0

2 7

P F M 0 0 0

1 0 7

8 9 3 8

0 . 5

2 0 0 5 - 0 7 - 1 1

0 . 1

4

8 9 . 1

5 . 5

9

4 3 . 7

1 3 . 4

1 1 8

1 6 7

2 6 . 0

1 0 . 1

0 . 6

5 3

< 0 . 2

0 . 4

3

0 . 0 5 1

0 . 0

0 3 0

0 . 0

0 4

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

S r m g / L

I – m g / L

p H_

L

m g / L

p H_

F

m g / L

T

e m p_

F

°

C l

E C_

L

m S / m

P F M 0 0 0

0 7 4

1 2 0 2 3

0 . 5

2 0 0 5 - 1 2 - 2 0

0 . 0

7 7

0 . 0

0 6

7 . 0

7

7 . 2

5

0 . 9

3 9 . 4

P F M 0 0 0

0 7 4

1 2 0 3 2

0 . 5

2 0 0 6 - 0 1 - 2 4

0 . 0

9 0

0 . 0

1 1

7 . 0

0

7 . 0

4

0 . 7

4 8 . 6

P F M 0 0 0

0 7 4

1 2 0 8 0

0 . 5

2 0 0 6 - 0 2 - 2 1

0 . 0

7 8

0 . 0

0 7

7 . 0

6

7 . 2

3

0 . 2

4 1 . 9

P F M 0 0 0

0 7 4

1 2 2 0 0

1 . 5

2 0 0 6 - 0 3 - 2 0

0 . 0

8 7

0 . 0

0 6

7 . 0

1

7 . 1

3

0 . 1

4 3 . 9

P F M 0 0 0

0 7 4

1 2 2 3 2

0 . 5

2 0 0 6 - 0 4 - 1 8

0 . 0

4 5

0 . 0

1 0

7 . 1

9

7 . 3

4

1 . 2

2 4 . 5

P F M 0 0 0

0 7 4

1 2 2 4 8

0 . 5

2 0 0 6 - 0 5 - 1 5

0 . 0

7 4

0 . 0

0 5

7 . 4

0

7 . 4

4

1 2 . 0

3 7 . 2

P F M 0 0 0

0 7 4

1 2 3 0 3

0 . 5

2 0 0 6 - 0 6 - 1 3

0 . 0

8 7

0 . 0

0 7

7 . 4

0

7 . 2

7

1 8 . 6

3 9 . 2

P F M 0 0 0

0 8 2

1 2 0 4 6

0 . 5

2 0 0 6 - 0 1 - 2 3

1 . 1

4

0 . 0

1 2

7 . 7

1

7 . 8

5

– 0 . 3

9 3 0

P F M 0 0 0

0 8 2

1 2 0 3 0

6

2 0 0 6 - 0 1 - 2 3

1 . 1

6

0 . 0

1 3

7 . 7

1

7 . 8

8

– 0 . 3

9 3 8

P F M 0 0 0

0 8 2

1 2 0 8 4

0 . 5

2 0 0 6 - 0 2 - 2 0

1 . 1

5

0 . 0

0 7

7 . 7

3

7 . 8

7

– 0 . 3

8 9 3

P F M 0 0 0

0 8 2

1 2 0 8 5

6

2 0 0 6 - 0 2 - 2 0

1 . 1

3

0 . 0

0 7

7 . 7

2

7 . 9

5

– 0 . 1

8 9 3

P F M 0 0 0

0 8 2

1 2 0 9 7

0 . 5

2 0 0 6 - 0 3 - 2 0

1 . 1

1

< 0 . 0

1

7 . 7

4

7 . 8

3

1 . 1

8 9 4

P F M 0 0 0

0 8 2

1 2 0 9 0

6

2 0 0 6 - 0 3 - 2 0

1 . 1

4

< 0 . 0

1

7 . 7

6

7 . 9

4

1 . 2

8 9 9

P F M 0 0 0

1 0 7

8 9 3 8

0 . 5

2 0 0 5 - 0 7 - 1 1

0 . 1

1 9

0 . 0

0 9

8 . 5

6

8 . 5

6

2 5 . 3

7 9 . 5



77

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

R C B

%

N a m g / L

K m g / L

C a m g / L

M

g

m

g / L

H C O 3 –

m g / L

C l –

m g / L

S O 4

2 –

m g / L

S O 4 - S

m g / L

B r m g / L

F – m g / L

S i m g / l

F e m g / l

M n m g / L

L i m g / L

P F M 0 0 0

1 0 7

8 9 5 0

0 . 5

2 0 0 5 - 0 8 - 0 1

– 0 . 4

5

8 9 . 8

5 . 4

7

4 0 . 1

1 3 . 5

1 0 6

1 7 1

2 7 . 1

1 0 . 3

0 . 6

4 1

0 . 2

4

0 . 3

6

–

–

< 0 . 0

0 4

P F M 0 0 0

1 0 7

8 9 6 1

0 . 5

2 0 0 5 - 0 9 - 0 5

8 . 7

5

8 4 . 6

4 . 5

7

3 8 . 3

1 3 . 0

1 0 2

1 2 2

2 4 . 4

8 . 8

9

0 . 5

4

0 . 2

6

0 . 3

6

–

–

0 . 0

0 4

P F M 0 0 0

1 0 7

8 9 7 0

0 . 5

2 0 0 5 - 1 0 - 0 3

1 . 2

8

8 7 . 6

4 . 6

3

3 9 . 8

1 2 . 0

1 1 2

1 5 4

2 4 . 0

8 . 4

1

0 . 6

5 1

0 . 3

2

0 . 1

4

0 . 0 3 7

0 . 0

0 4 1

< 0 . 0

0 4

P F M 0 0 0

1 0 7

8 9 9 7

0 . 5

2 0 0 5 - 1 0 - 3 1

1 . 2

6

8 3 . 4

4 . 4

4

4 2 . 4

1 2 . 3

1 1 7

1 5 0

2 2 . 7

8 . 4

4

0 . 5

2 8

0 . 3

3

0 . 0

9

0 . 0 2 6

< 0 . 0

0 3

< 0 . 0

0 4

P F M 0 0 0

1 0 7

1 2 0 1 5

0 . 5

2 0 0 5 - 1 1 - 2 8

2 . 0

7

7 5 . 6

4 . 3

9

4 5 . 2

1 0 . 9

1 3 0

1 3 1

2 0 . 2

7 . 0

8

0 . 4

9 1

0 . 2

8

0 . 5

3

–

–

< 0 . 0

0 4

P F M 0 0 0

1 0 7

1 2 0 2 4

0 . 5

2 0 0 5 - 1 2 - 1 9

1 . 7

8

1 6 . 0

3 . 1

7

6 0 . 2

5 . 2

1 7 2

2 9 . 5

1 7 . 7

6 . 2

7

0 . 1

3 5

0 . 2

9

5 . 2

8

–

–

< 0 . 0

0 4

P F M 0 0 0

1 0 7

1 2 0 2 8

1

2 0 0 5 - 1 2 - 1 9

– 0 . 2

8

7 7 . 5

4 . 7

0

4 7 . 3

1 1 . 9

1 4 4

1 4 3

2 0 . 5

7 . 2

8

0 . 5

8

0 . 2

9

0 . 6

2

–

–

< 0 . 0

0 4

P F M 0 0 0

1 0 7

1 2 0 4 7

0 . 5

2 0 0 6 - 0 1 - 2 3

4 . 4

4 9 . 2

4 . 1

6

6 7 . 0

9 . 3

1 8 8

7 9 . 3

2 0 . 2

7 . 8

3

0 . 3

8 9

0 . 2

9

4 . 3

0

0 . 1 6 1

0 . 0

6 0 0

< 0 . 0

0 4

P F M 0 0 0

1 0 7

1 2 0 4 4

1

2 0 0 6 - 0 1 - 2 3

0 . 9

3

8 1 . 1

4 . 6

4

5 7 . 6

1 2 . 5

1 6 7

1 4 8

2 0 . 4

7 . 7

3

0 . 5

5 8

0 . 2

6

1 . 0

5

0 . 1 1 2

0 . 0

6 7 0

0 . 0

0 4

P F M 0 0 0

1 0 7

1 2 0 7 8

0 . 5

2 0 0 6 - 0 2 - 2 0

1 . 2

7

3 2 . 2

3 . 4

9

6 1 . 5

7 . 2

1 8 6

5 6 . 5

1 6 . 0

5 . 8

2

0 . 2

3 3

0 . 2

9

4 . 3

8

0 . 1 8 5

0 . 0

4 1 0

< 0 . 0

4

P F M 0 0 0

1 0 7

1 2 0 8 6

1

2 0 0 6 - 0 2 - 2 0

– 0 . 6

8

7 6 . 8

4 . 8

6

5 7 . 0

1 1 . 9

1 7 8

1 4 2

1 9 . 8

7 . 1

7

0 . 5

0 6

0 . 2

6

1 . 4

9

0 . 1 2 5

0 . 0

1 7 5

< 0 . 0

4

P F M 0 0 0

1 0 7

1 2 0 9 6

0 . 5

2 0 0 6 - 0 3 - 2 0

3 . 5

7

2 5 . 4

3 . 1

1

6 6 . 3

6 . 6

1 9 2

4 2 . 2

1 3 . 5

5 . 3

9

0 . 1

8 9

0 . 2

8

4 . 6

9

0 . 1 8 9

0 . 0

5 5 0

< 0 . 0

0 4

P F M 0 0 0

1 0 7

1 2 0 9 4

1

2 0 0 6 - 0 3 - 2 0

0 . 4

4

7 0 . 3

5 . 0

8

6 2 . 8

1 1 . 8

1 9 1

1 2 9

1 8 . 3

7 . 0

3

0 . 5

5 7

0 . 2

9

1 . 9

8

0 . 1 4 5

0 . 0

0 6 5

< 0 . 0

0 4

P F M 0 0 0

1 0 7

1 2 2 3 1

0 . 5

2 0 0 6 - 0 5 - 1 5

4 . 2

4

2 0 . 2

2 . 4

3

4 5 . 9

5 . 2

1 2 8

3 2 . 6

1 2 . 9

5 . 3

1

0 . 1

2 4

0 . 2

6

1 . 7

9

0 . 0 6 5

< 0 . 0

0 3

< 0 . 0

0 4

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

S r m g / L

I – m g / L

p H_

L

m g / L

p H_

F

m g / L

T

e m p_

F

°

C l

E C_

L

m S / m

P F M 0 0 0

1 0 7

8 9 5 0

0 . 5

2 0 0 5 - 0 8 - 0 1

0 . 1

1 5

0 . 0

0 8

8 . 7

7

8 . 7

8

2 1 . 8

7 8 . 9

P F M 0 0 0

1 0 7

8 9 6 1

0 . 5

2 0 0 5 - 0 9 - 0 5

0 . 1

2 3

0 . 0

0 8

8 . 7

8

8 . 8

3

1 6 . 4

7 3 . 8

P F M 0 0 0

1 0 7

8 9 7 0

0 . 5

2 0 0 5 - 1 0 - 0 3

0 . 1

1 0

0 . 0

1 1

8 . 2

7

8 . 4

1

1 1 . 7

7 5 . 7

P F M 0 0 0

1 0 7

8 9 9 7

0 . 5

2 0 0 5 - 1 0 - 3 1

0 . 1

0 1

0 . 0

0 6

8 . 0

9

8 . 2

5

6 . 2

7 3 . 9

P F M 0 0 0

1 0 7

1 2 0 1 5

0 . 5

2 0 0 5 - 1 1 - 2 8

0 . 1

1 2

0 . 0

0 5

7 . 8

9

8 . 2

5

1 . 2

7 1 . 8

P F M 0 0 0

1 0 7

1 2 0 2 4

0 . 5

2 0 0 5 - 1 2 - 1 9

0 . 0

9 1

0 . 0

0 3

7 . 3

1

7 . 8

6

1 . 8

4 0 . 9

P F M 0 0 0

1 0 7

1 2 0 2 8

1

2 0 0 5 - 1 2 - 1 9

0 . 1

2 1

< 0 . 0

0 2

7 . 5

8

7 . 8

3

2 . 4

7 5 . 3

P F M 0 0 0

1 0 7

1 2 0 4 7

0 . 5

2 0 0 6 - 0 1 - 2 3

0 . 1

2 0

0 . 0

0 8

7 . 1

3

7 . 3

1

1 . 7

6 3 . 4

P F M 0 0 0

1 0 7

1 2 0 4 4

1

2 0 0 6 - 0 1 - 2 3

0 . 1

3 0

0 . 0

0 7

7 . 3

8

7 . 4

1

3 . 2

7 9 . 4

P F M 0 0 0

1 0 7

1 2 0 7 8

0 . 5

2 0 0 6 - 0 2 - 2 0

0 . 1

0 1

0 . 0

0 8

7 . 0

8

7 . 2

5

1 . 1

5 2 . 1

P F M 0 0 0

1 0 7

1 2 0 8 6

1

2 0 0 6 - 0 2 - 2 0

0 . 1

2 8

0 . 0

0 7

7 . 3

1

7 . 3

1

2 . 7

7 8 . 6

P F M 0 0 0

1 0 7

1 2 0 9 6

0 . 5

2 0 0 6 - 0 3 - 2 0

0 . 1

0 1

0 . 0

0 5

7 . 0

2

7 . 2

1

1 . 2

4 7 . 8

P F M 0 0 0

1 0 7

1 2 0 9 4

1

2 0 0 6 - 0 3 - 2 0

0 . 1

3 6

0 . 0

0 7

7 . 2

6

7 . 2

9

3 . 5

7 8 . 2

P F M 0 0 0

1 0 7

1 2 2 3 1

0 . 5

2 0 0 6 - 0 5 - 1 5

0 . 0

7 2

0 . 0

0 5

8 . 1

4

8 . 3

1

1 3 . 7

3 5 . 1



78

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

R C B

%

N a m g / L

K m g / L

C a m g / L

M

g

m

g / L

H C O 3 –

m g / L

C l –

m g / L

S O 4

2 –

m g / L

S O 4 - S

m g / L

B r m g / L

F – m g / L

S i m g / l

F e m g / l

M n m g / L

L i m g / L

P F M 0 0 0

1 0 7

1 2 3 0 0

0 . 5

2 0 0 6 - 0 6 - 1 2

4 . 4

9

2 4 . 3

2 . 7

2

4 3 . 2

5 . 7

1 2 5

3 7 . 2

1 3 . 1

5 . 1

1

0 . 1

5 4

0 . 2

7

0 . 3

8

0 . 0 3 1

0 . 0

0 3 2

< 0 . 0

0 4

P F M 0 0 0

1 1 7

8 9 3 5

0 . 5

2 0 0 5 - 0 7 - 1 1

6 . 0

7

6 . 3

1 . 9

2

3 2 . 5

2 . 9

1 0 1

4 . 8

4 . 8

4

2 . 2

9

0 . 0

4 2

< 0 . 2

0 . 6

9

0 . 0 0 6

0 . 0

0 1 5

0 . 0

0 2

P F M 0 0 0

1 1 7

8 9 4 9

0 . 5

2 0 0 5 - 0 8 - 0 2

6 . 4

4

6 . 4

1 . 9

2

2 7 . 4

2 . 9

8 6 . 3

5 . 0

4 . 9

0

2 . 2

7

0 . 0

4 7

< 0 . 2

1 . 0

9

–

–

< 0 . 0

0 4

P F M 0 0 0

1 1 7

8 9 5 8

0 . 5

2 0 0 5 - 0 9 - 0 6

5 . 4

3

6 . 2

1 . 6

9

2 7 . 3

3 . 0

8 7 . 9

5 . 0

4 . 5

7

2 . 2

0

0 . 0

2

< 0 . 2

1 . 4

4

–

–

< 0 . 0

0 4

P F M 0 0 0

1 1 7

8 9 7 3

0 . 5

2 0 0 5 - 1 0 - 0 4

4 . 8

7

6 . 6

1 . 7

7

2 9 . 8

2 . 9

9 5 . 7

5 . 9

4 . 8

4

1 . 9

0

0 . 0

6

0 . 2

3

1 . 4

0

0 . 0 0 4

0 . 0

0 0 3

< 0 . 0

0 4

P F M 0 0 0

1 1 7

8 9 9 4

0 . 5

2 0 0 5 - 1 1 - 0 1

5 . 4

5

6 . 5

1 . 7

1

3 4 . 1

2 . 9

1 0 6

5 . 8

4 . 5

5

1 . 9

1

0 . 0

4 1

0 . 2

2

1 . 5

1

< 0 . 0 2

0 . 0

0 6 3

< 0 . 0

0 4

P F M 0 0 0

1 1 7

1 2 0 1 3

0 . 5

2 0 0 5 - 1 1 - 2 9

5 . 0

4

6 . 6

1 . 8

7

3 7 . 9

2 . 7

1 1 8

5 . 8

4 . 4

6

1 . 7

1

0 . 0

4

0 . 2

1

1 . 6

2

–

–

< 0 . 0

0 4

P F M 0 0 0

1 1 7

1 2 0 3 1

0 . 5

2 0 0 5 - 1 2 - 2 0

3 . 4

3

6 . 8

2 . 0

2

3 9 . 9

3 . 0

1 2 8

6 . 2

4 . 8

0

2 . 0

6

0 . 0

5 5

0 . 2

1

1 . 7

3

–

–

< 0 . 0

0 4

P F M 0 0 0

1 1 7

1 2 0 2 6

1 . 5

2 0 0 5 - 1 2 - 2 0

3 . 7

8

6 . 2

2 . 0

2

4 7 . 1

3 . 0

1 4 5

6 . 0

5 . 7

3

2 . 3

6

0 . 0

4 5

0 . 2

2

2 . 6

0

–

–

< 0 . 0

0 4

P F M 0 0 0

1 1 7

1 2 0 4 8

0 . 5

2 0 0 6 - 0 1 - 2 4

5 . 7

7

7 . 7

2 . 1

2

4 8 . 3

3 . 3

1 4 4

7 . 2

5 . 9

1

2 . 5

5

0 . 0

4 7

0 . 2

3

2 . 3

1

0 . 0 1 5

0 . 0

0 4

< 0 . 0

0 4

P F M 0 0 0

1 1 7

1 2 0 3 3

1 . 5

2 0 0 6 - 0 1 - 2 4

6 . 5

3

6 . 6

2 . 0

7

5 8 . 5

3 . 2

1 6 6

6 . 6

6 . 5

6

2 . 7

7

0 . 0

5 7

0 . 2

1

3 . 3

8

0 . 0 4 7

0 . 0

6 0

< 0 . 0

0 4

P F M 0 0 0

1 1 7

1 2 0 8 7

0 . 5

2 0 0 6 - 0 2 - 2 1

2 . 5

4

7 . 2

2 . 2

4

4 8 . 2

3 . 2

1 5 5

6 . 9

5 . 6

7

2 . 3

2

0 . 0

4 4

0 . 2

1

2 . 3

4

0 . 0 2 1

0 . 0

1 4 3

< 0 . 0

4

P F M 0 0 0

1 1 7

1 2 0 8 8

1 . 5

2 0 0 6 - 0 2 - 2 1

2 . 0

4

7 . 0

2 . 4

0

5 2 . 6

3 . 1

1 6 9

6 . 6

5 . 9

1

2 . 4

5

0 . 0

5 1

0 . 2

1

2 . 7

8

0 . 0 3 0

0 . 0

3 0 9

< 0 . 0

4

P F M 0 0 0

1 1 7

1 2 0 9 3

0 . 5

2 0 0 6 - 0 3 - 2 1

6 . 2

3

5 . 7

1 . 9

3

5 5 . 6

3 . 2

1 5 6

6 . 0

8 . 1

8

3 . 3

5

0 . 0

4 3

0 . 2

3

4 . 0

5

0 . 0 7 4

0 . 0

5 4 1

< 0 . 0

0 4

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

S r m g / L

I – m g / L

p H_

L

m g / L

p H_

F

m g / L

T

e m p_

F

°

C l

E C_

L

m S / m

P F M 0 0 0

1 0 7

1 2 3 0 0

0 . 5

2 0 0 6 - 0 6 - 1 2

0 . 0

8 0

0 . 0

0 5

8 . 6

6

8 . 8

1

2 3 . 2

3 5 . 2

P F M 0 0 0

1 1 7

8 9 3 5

0 . 5

2 0 0 5 - 0 7 - 1 1

0 . 0

4 6

0 . 0

0 7

8 . 7

7

8 . 7

7

2 6 . 2

1 9 . 3

P F M 0 0 0

1 1 7

8 9 4 9

0 . 5

2 0 0 5 - 0 8 - 0 2

0 . 0

4 3

0 . 0

0 7

8 . 9

8

8 . 9

5

2 1 . 2

2 0 . 2

P F M 0 0 0

1 1 7

8 9 5 8

0 . 5

2 0 0 5 - 0 9 - 0 6

0 . 0

4 7

0 . 0

0 4

8 . 7

6

8 . 8

4

1 6 . 2

1 7 . 8

P F M 0 0 0

1 1 7

8 9 7 3

0 . 5

2 0 0 5 - 1 0 - 0 4

0 . 0

4 3

0 . 0

1 0

7 . 2

1

8 . 5

9

1 1 . 6

1 9 . 1

P F M 0 0 0

1 1 7

8 9 9 4

0 . 5

2 0 0 5 - 1 1 - 0 1

0 . 0

4 1

0 . 0

0 6

8 . 1

5

8 . 2

4

5 . 5

2 0 . 3

P F M 0 0 0

1 1 7

1 2 0 1 3

0 . 5

2 0 0 5 - 1 1 - 2 9

0 . 0

4 7

0 . 0

0 5

8 . 0

1

8 . 2

5

0 . 9

2 2 . 3

P F M 0 0 0

1 1 7

1 2 0 3 1

0 . 5

2 0 0 5 - 1 2 - 2 0

0 . 0

5 2

< 0 . 0

0 2

7 . 9

6

8 . 0

4

1 . 3

2 3 . 9

P F M 0 0 0

1 1 7

1 2 0 2 6

1 . 5

2 0 0 5 - 1 2 - 2 0

0 . 0

5 4

< 0 . 0

0 2

7 . 5

4

7 . 8

5

3 . 4

2 6 . 8

P F M 0 0 0

1 1 7

1 2 0 4 8

0 . 5

2 0 0 6 - 0 1 - 2 4

0 . 0

6 0

0 . 0

0 5

7 . 6

9

7 . 7

4

1 . 5

2 7 . 0

P F M 0 0 0

1 1 7

1 2 0 3 3

1 . 5

2 0 0 6 - 0 1 - 2 4

0 . 0

6 0

0 . 0

0 8

7 . 4

4

7 . 4

8

4 . 0

3 0 . 7

P F M 0 0 0

1 1 7

1 2 0 8 7

0 . 5

2 0 0 6 - 0 2 - 2 1

0 . 0

5 6

0 . 0

0 5

7 . 4

8

7 . 6

7

1 . 1

2 8 . 6

P F M 0 0 0

1 1 7

1 2 0 8 8

1 . 5

2 0 0 6 - 0 2 - 2 1

0 . 0

5 7

0 . 0

0 7

7 . 4

1

7 . 5

1

3 . 7

3 0 . 6

P F M 0 0 0

1 1 7

1 2 0 9 3

0 . 5

2 0 0 6 - 0 3 - 2 1

0 . 0

5 9

0 . 0

0 5

7 . 1

6

7 . 3

9

1 . 0

2 9 . 3



79

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

R C B

%

N a m g / L

K m g / L

C a m g / L

M

g

m

g / L

H C O 3 –

m g / L

C l –

m g / L

S O 4

2 –

m g / L

S O 4 - S

m g / L

B r m g / L

F – m g / L

S i m g / l

F e m g / l

M n m g / L

L i m g / L

P F M 0 0 0

1 1 7

1 2 0 9 5

1 . 5

2 0 0 6 - 0 3 - 2 1

4 . 9

6

6 . 4

2 . 3

4

6 9 . 0

3 . 5

2 0 0

6 . 9

7 . 5

4

3 . 2

1

0 . 0

4 9

0 . 2

5

3 . 7

8

0 . 0 9 2

0 . 1

6 8

< 0 . 0

0 4

P F M 0 0 0

1 1 7

1 2 2 5 1

0 . 5

2 0 0 6 - 0 5 - 1 6

8 . 3

1

5 . 8

1 . 7

9

5 0 . 3

3 . 0

1 3 9

5 . 2

5 . 2

1

2 . 3

7

0 . 0

3 5

0 . 2

0

1 . 5

2

0 . 0 3 0

0 . 0

1 0 4

< 0 . 0

0 4

P F M 0 0 0

1 1 7

1 2 2 9 9

0 . 5

2 0 0 6 - 0 6 - 1 2

6 . 8

1

6 . 0

1 . 7

7

4 3 . 2

2 . 8

1 2 6

5 . 3

4 . 8

2

2 . 0

4

0 . 0

3 1

0 . 2

0

0 . 4

1

< 0 . 0 2

0 . 0

1 0 3

< 0 . 0

0 4

P F M 1 0 2

2 6 9

8 8 8 6

0 . 5

2 0 0 5 - 1 2 - 0 7

– 2 . 2

8

1 4 5 0

6 0 . 3

7 8 . 2

1

8 9

7 7 . 5

2 7 6 0

3 7 2

1 4 0

9 . 7

0

0 . 3

3

0 . 3

1

< 0 . 0 2

< 0 . 0

0 3

0 . 0

2 5

P F M 1 0 2

2 6 9

1 2 0 6 8

0 . 5

2 0 0 6 - 0 1 - 2 4

–

–

–

–

–

8 0 . 1

–

–

–

–

–

–

–

–

–

P F M 1 0 2

2 6 9

1 2 0 7 7

0 . 5

2 0 0 6 - 0 2 - 2 1

–

–

–

–

–

7 8 . 8

–

–

–

–

–

–

–

–

–

P F M 1 0 2

2 6 9

1 2 0 6 3

0 . 5

2 0 0 6 - 0 3 - 2 1

–

–

–

–

–

7 9 . 8

2 7 7 0

3 8 7

–

8 . 9

0

0 . 3

1

–

–

–

–

P F M 1 0 2

2 6 9

1 2 2 3 8

0 . 5

2 0 0 6 - 0 4 - 1 9

–

–

–

–

–

7 9 . 1

2 7 7 0

3 8 3

–

9 . 0

5

0 . 3

3

–

–

–

–

P F M 1 0 2

2 6 9

1 2 2 5 4

0 . 5

2 0 0 6 - 0 5 - 1 5

–

–

–

–

–

7 7 . 3

2 7 0 0

3 7 7

–

8 . 9

5

0 . 3

2

–

–

–

–

P F M 1 0 2

2 6 9

1 2 3 0 5

0 . 5

2 0 0 6 - 0 6 - 1 2

–

–

–

–

–

7 1 . 7

2 4 7 0

3 3 8

–

8 . 1

5

0 . 3

3

–

–

–

–

P F M 1 0 2

2 7 0

1 2 2 3 3

0 . 5

2 0 0 6 - 0 4 - 1 8

4 . 2

1

1 3 . 3

2 . 3

7

4 6 . 0

4 . 1

1 2 8

2 1 . 0

1 3 . 0

4 . 9

1

< 0 . 2

0 . 2

4

4 . 0

4

0 . 1 2 8

0 . 0

3 6 6

< 0 . 0

0 4

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

S r m g / L

I – m g / L

p H_

L

m g / L

p H_

F

m g / L

T

e m p_

F

°

C l

E C_

L

m S / m

P F M 0 0 0

1 1 7

1 2 0 9 5

1 . 5

2 0 0 6 - 0 3 - 2 1

0 . 0

6 5

0 . 0

0 6

7 . 3

0

7 . 4

1

3 . 9

3 6 . 3

P F M 0 0 0

1 1 7

1 2 2 5 1

0 . 5

2 0 0 6 - 0 5 - 1 6

0 . 0

4 9

0 . 0

0 5

8 . 3

2

8 . 4

2

1 3 . 5

2 5 . 4

P F M 0 0 0

1 1 7

1 2 2 9 9

0 . 5

2 0 0 6 - 0 6 - 1 2

0 . 0

4 6

0 . 0

0 5

8 . 5

4

8 . 6

8

2 2 . 4

2 2 . 9

P F M 1 0 2

2 6 9

8 8 8 6

0 . 5

2 0 0 5 - 1 2 - 0 7

1 . 0

7

0 . 0

1 5

8 . 1

6

8 . 0

6

3 0 . 0

8 8 1

P F M 1 0 2

2 6 9

1 2 0 6 8

0 . 5

2 0 0 6 - 0 1 - 2 4

–

–

7 . 7

0

7 . 8

6

1 1 . 5

9 2 2

P F M 1 0 2

2 6 9

1 2 0 7 7

0 . 5

2 0 0 6 - 0 2 - 2 1

–

–

7 . 7

2

7 . 9

5

1 1 . 5

8 8 8

P F M 1 0 2

2 6 9

1 2 0 6 3

0 . 5

2 0 0 6 - 0 3 - 2 1

–

–

7 . 7

9

7 . 9

7

1 1 . 8

1 0 6 0

P F M 1 0 2

2 6 9

1 2 2 3 8

0 . 5

2 0 0 6 - 0 4 - 1 9

–

–

7 . 8

5

8 . 0

9

1 2 . 4

8 9 3

P F M 1 0 2

2 6 9

1 2 2 5 4

0 . 5

2 0 0 6 - 0 5 - 1 5

–

–

8 . 2

9

8 . 3

9

2 0 . 5

8 7 0

P F M 1 0 2

2 6 9

1 2 3 0 5

0 . 5

2 0 0 6 - 0 6 - 1 2

–

–

7 . 9

4

8 . 0

5

2 5 . 2

8 0 3

P F M 1 0 2

2 7 0

1 2 2 3 3

0 . 5

2 0 0 6 - 0 4 - 1 8

0 . 0

6 8

0 . 0

0 8

7 . 1

2

7 . 7

1

3 . 7

3 1 . 7

R C B = R

e l a t i v e C h a r g e B a l a n c e e r r o r .

p H_

L = l a b . p H .

p H_

F =

f i e l d p H .

T e m p_ F

= w a t e r t e m p e r a t u r e i n t h e f i e l d .

E C = E l e c t r i c a l C o n d u c t i v i t y .

< ” v a l u e

” = b e l o w d e t e c t i o n l i m i t .



80

T a b l e A

5 - 2 . S u r f a c e w a t e r s u p p l i m e n t s .

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

N H 4_

N

m g / L

N O 2_

N

m g / L

N O 2_

N +

N O 3_ m g / L

N t o t

m g / L

P t o t

m g / L

P O 4_

P

m g / L

P O P m g / L

P O N

m g / L

S i O 4_

S i

m g / L

C h l . A

µ g / L

C h

l . C

µ g

/ L

P h e o p .

µ g / L

P F M 0 0 0

0 6 2

8 9 3 6

2 0 0 5 - 0 7 - 1 1

0

. 5

0 . 0

0 1 2

–

0 . 0

0 0 4

0 . 2

2

0 . 0

0 9 0

0 . 0

0 0 6

0 . 0 0

4 8

0 . 0

3 1 5

0 . 2

5 5

1 . 0

< 0 . 2

0 . 2

P F M 0 0 0

0 6 2

8 9 5 3

2 0 0 5 - 0 8 - 0 1

0

. 5

0 . 0

0 1 4

–

0 . 0

0 0 4

0 . 2

4

0 . 0

1 0 6

0 . 0

0 0 6

0 . 0 0

6 3

0 . 0

4 1 9

0 . 2

8 7

1 . 8

0 . 2

< 0 . 2

P F M 0 0 0

0 6 2

8 9 5 9

2 0 0 5 - 0 9 - 0 5

0

. 5

0 . 0

0 0 8

–

0 . 0

0 0 3

0 . 2

5

0 . 0

1 2 0

0 . 0

0 0 8

0 . 0 0

6 3

0 . 0

4 0 5

0 . 4

5 6

2 . 0

0 . 2

0 . 3

P F M 0 0 0

0 6 2

8 9 7 1

2 0 0 5 - 1 0 - 0 3

0

. 5

0 . 0

0 1 5

0 . 0

0 1 5

0 . 0

1 7 4

0 . 2

3

0 . 0

1 2 7

0 . 0

0 4 3

0 . 0 0

4 3

0 . 0

2 4 7

0 . 4

9 4

1 . 3

0 . 2

< 0 . 2

P F M 0 0 0

0 6 2

8 9 9 6

2 0 0 5 - 1 0 - 3 1

0

. 5

0 . 0

0 1 9

–

0 . 0

0 6 8

0 . 2

2

0 . 0

1 0 3

0 . 0

0 2 0

0 . 0 0

5 9

0 . 0

3 8 0

0 . 4

0 8

2 . 5

0 . 4

0 . 4

P F M 0 0 0

0 6 2

1 2 0 1 9

2 0 0 5 - 1 1 - 2 8

0

. 5

0 . 0

0 2 3

–

0 . 0

2 8 2

0 . 2

5

0 . 0

1 3 0

0 . 0

0 4 0

0 . 0 0

2 6

0 . 0

2 1 9

0 . 5

1 0

1 . 6

0 . 3

1 . 1

P F M 0 0 0

0 6 2

1 2 0 2 1

2 0 0 5 - 1 2 - 1 9

0

. 5

0 . 0

0 2 3

–

0 . 0

3 7 0

0 . 2

8

0 . 0

1 4 8

0 . 0

0 4 9

0 . 0 0

4 8

0 . 0

2 8 9

0 . 6

0 4

1 . 9

0 . 3

0 . 4

P F M 0 0 0

0 6 2

1 2 2 3 4

2 0 0 6 - 0 4 - 1 8

0

. 5

0 . 0

0 2 0

0 . 0

0 3 1

0 . 0

1 7 6

0 . 2

6

0 . 0

1 1 5

0 . 0

0 1 2

0 . 0 0

5 7

0 . 0

3 8 3

0 . 4

9 7

0 . 3

< 0 . 2

< 0 . 2

P F M 0 0 0

0 6 2

1 2 2 4 9

2 0 0 6 - 0 5 - 1 5

0

. 5

0 . 0

0 1 3

–

0 . 0

0 0 4

0 . 2

8

0 . 0

1 4 9

0 . 0

0 0 6

0 . 0 0

6 6

0 . 0

6 5 0

0 . 1

6 5

3 . 6

1 . 0

1 . 4

P F M 0 0 0

0 6 2

1 2 2 9 7

2 0 0 6 - 0 6 - 1 2

0

. 5

0 . 0

0 2 1

–

0 . 0

0 0 4

0 . 2

5

0 . 0

1 1 3

0 . 0

0 0 9

0 . 0 0

6 4

–

0 . 2

0 6

1 . 3

0 . 2

< 0 . 2

P F M 0 0 0

0 6 6

8 9 3 4

2 0 0 5 - 0 7 - 1 2

0

. 1

0 . 0

9 5 7

0 . 0

0 3 1

0 . 0

1 9 2

1 . 0

3

0 . 0

2 1 5

0 . 0

0 4 0

0 . 0 1

1 9

0 . 1

0 1 0

3 . 1

8

–

–

–

P F M 0 0 0

0 6 6

8 9 5 2

2 0 0 5 - 0 8 - 0 1

0

. 1

0 . 0

4 7 8

–

0 . 0

3 6 7

0 . 9

5

0 . 0

1 5 7

0 . 0

0 4 7

0 . 0 0

5 0

0 . 0

2 5 3

3 . 5

0

–

–

–

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

P O C

m g / L

T O C

m g / L

D O C

m g / L

D I C m g / L

O 2 m g / L

A b s . c o e f f .

m g / L

P F M 0 0 0

0 6 2

8 9 3 6

2 0 0 5 - 0 7 - 1 1

0

. 5

0 . 1

9

3 . 8

3 . 9

1 3 . 6

–

0 . 2

4

P F M 0 0 0

0 6 2

8 9 5 3

2 0 0 5 - 0 8 - 0 1

0

. 5

0 . 3

0

3 . 8

3 . 9

1 3 . 6

–

0 . 1

8

P F M 0 0 0

0 6 2

8 9 5 9

2 0 0 5 - 0 9 - 0 5

0

. 5

0 . 2

9

3 . 7

3 . 7

1 4 . 5

–

0 . 0

8

P F M 0 0 0

0 6 2

8 9 7 1

2 0 0 5 - 1 0 - 0 3

0

. 5

0 . 2

0

3 . 5

3 . 5

1 4 . 5

–

0 . 3

0

P F M 0 0 0

0 6 2

8 9 9 6

2 0 0 5 - 1 0 - 3 1

0

. 5

0 . 2

9

3 . 6

3 . 5

1 6 . 8

–

0 . 2

4

P F M 0 0 0

0 6 2

1 2 0 1 9

2 0 0 5 - 1 1 - 2 8

0

. 5

0 . 2

1

3 . 5

3 . 4

1 5 . 9

–

0 . 1

4

P F M 0 0 0

0 6 2

1 2 0 2 1

2 0 0 5 - 1 2 - 1 9

0

. 5

0 . 2

0

3 . 9

2 . 9

1 4 . 3

–

0 . 2

4

P F M 0 0 0

0 6 2

1 2 2 3 4

2 0 0 6 - 0 4 - 1 8

0

. 5

0 . 2

4

3 . 9

4 . 1

1 3 . 0

–

0 . 2

2

P F M 0 0 0

0 6 2

1 2 2 4 9

2 0 0 6 - 0 5 - 1 5

0

. 5

0 . 6

0

4 . 7

4 . 7

1 4 . 5

–

0 . 2

8

P F M 0 0 0

0 6 2

1 2 2 9 7

2 0 0 6 - 0 6 - 1 2

0

. 5

–

4 . 7

4 . 6

1 2 . 6

–

0 . 4

4

P F M 0 0 0

0 6 6

8 9 3 4

2 0 0 5 - 0 7 - 1 2

0

. 1

0 . 8

9

1 8 . 6

1 8 . 6

2 9 . 6

–

2 . 7

6

P F M 0 0 0

0 6 6

8 9 5 2

2 0 0 5 - 0 8 - 0 1

0

. 1

0 . 2

0

1 8 . 3

1 8 . 4

3 2 . 9

7 . 1

5

2 . 6

2



81

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

N H 4_

N

m g / L

N O 2_

N

m g / L

N O 2_

N +

N O 3_ m g / L

N t o t

m g / L

P t o t

m g / L

P O 4_

P

m g / L

P O P m g / L

P O N

m g / L

S i O 4_

S i

m g / L

C h l . A

µ g / L

C h

l . C

µ g

/ L

P h e o p .

µ g / L

P F M 0 0 0

0 6 6

8 9 5 5

2 0 0 5 - 0 9 - 0 5

0

. 1

0 . 0

3 7 0

–

0 . 0

7 3 2

0 . 9

8

0 . 0

1 4 7

0 . 0

0 3 0

0 . 0 0

4 7

0 . 0

3 0 9

4 . 3

5

–

–

–

P F M 0 0 0

0 6 6

8 9 9 3

2 0 0 5 - 1 0 - 3 1

0

. 1

0 . 0

0 1 6

–

0 . 0

0 3 4

0 . 8

0

0 . 0

1 0 2

0 . 0

0 0 8

0 . 0 0

4 4

0 . 0

3 7 1

4 . 8

0

–

–

–

P F M 0 0 0

0 6 6

1 2 0 1 6

2 0 0 5 - 1 1 - 2 8

0

. 1

0 . 0

1 0 8

–

0 . 0

2 5 3

0 . 7

3

0 . 0

0 7 5

0 . 0

0 0 8

0 . 0 0

2 9

0 . 0

2 4 8

4 . 4

6

–

–

–

P F M 0 0 0

0 6 6

1 2 0 2 2

2 0 0 5 - 1 2 - 1 9

0

. 1

0 . 0

0 6 2

–

0 . 2

5 3 0

0 . 8

0

0 . 0

0 6 9

0 . 0

0 1 0

0 . 0 0

2 4

0 . 0

1 5 8

5 . 4

8

< 0 . 0

2

< 0 . 2

< 0 . 2

P F M 0 0 0

0 6 6

1 2 0 4 2

2 0 0 6 - 0 1 - 2 3

0

. 1

0 . 0

0 6 7

0 . 0

0 0 3

0 . 0

0 1 6

0 . 7

8

0 . 0

0 6 7

0 . 0

0 0 6

0 . 0 0

1 9

0 . 0

1 4 9

6 . 3

1

–

–

–

P F M 0 0 0

0 6 6

1 2 0 8 1

2 0 0 6 - 0 2 - 2 0

0

. 1

0 . 0

0 4 7

–

0 . 0

0 2 1

0 . 6

5

0 . 0

0 5 7

0 . 0

0 0 7

0 . 0 0

1 4

0 . 0

1 2 2

5 . 6

2

–

–

–

P F M 0 0 0

0 6 6

1 2 0 9 8

2 0 0 6 - 0 3 - 2 0

0

. 1

0 . 0

1 0 9

–

0 . 0

0 1 8

0 . 6

6

0 . 0

0 6 2

0 . 0

0 0 7

0 . 0 0

2 1

0 . 0

1 9 0

5 . 7

5

–

–

–

P F M 0 0 0

0 6 6

1 2 2 3 5

2 0 0 6 - 0 4 - 1 8

0

. 1

0 . 0

0 9 4

0 . 0

0 1 9

0 . 0

9 2 1

0 . 7

5

0 . 0

1 6 0

0 . 0

0 1 5

0 . 0 0

8 2

0 . 0

5 9 2

3 . 6

5

–

–

–

P F M 0 0 0

0 6 6

1 2 2 5 3

2 0 0 6 - 0 5 - 1 5

0

. 1

0 . 0

1 5 3

–

0 . 0

0 3 1

0 . 7

6

0 . 0

0 8 8

0 . 0

0 1 4

0 . 0 0

2 5

0 . 0

2 2 4

4 . 0

1

–

–

–

P F M 0 0 0

0 6 6

1 2 2 9 8

2 0 0 6 - 0 6 - 1 3

0

. 1

0 . 0

8 7 0

–

0 . 0

1 4 0

1 . 0

2

0 . 0

1 6 3

0 . 0

0 2 8

–

–

2 . 6

1

–

–

–

P F M 0 0 0

0 6 8

8 9 3 2

2 0 0 5 - 0 7 - 1 2

0

. 1

0 . 1

1 0

0 . 0

0 5 5

0 . 0

2 6 2

1 . 0

1

0 . 0

2 5 2

0 . 0

1 0 4

0 . 0 0

6 8

0 . 0

4 3 6

4 . 4

4

–

–

–

P F M 0 0 0

0 6 8

8 9 5 1

2 0 0 5 - 0 8 - 0 1

0

. 5

0 . 0

6 0 1

–

0 . 0

4 6 2

1 . 0

3

0 . 0

2 9 1

0 . 0

1 3 3

0 . 0 0

7 4

0 . 0

3 5 0

4 . 3

4

–

–

–

P F M 0 0 0

0 6 8

8 9 6 0

2 0 0 5 - 0 9 - 0 5

0

. 5

0 . 0

2 1 2

–

0 . 0

2 3 1

0 . 9

9

0 . 0

1 6 6

0 . 0

0 3 0

0 . 0 0

6 1

0 . 0

2 8 2

4 . 5

9

–

–

–

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

P O C

m g / L

T O C

m g / L

D O C

m g / L

D I C m g / L

O 2 m g / L

A b s . c o e f f .

m g / L

P F M 0 0 0

0 6 6

8 9 5 5

2 0 0 5 - 0 9 - 0 5

0

. 1

0 . 2

5

1 7 . 3

1 6 . 7

3 2 . 9

5 . 8

0

2 . 2

6

P F M 0 0 0

0 6 6

8 9 9 3

2 0 0 5 - 1 0 - 3 1

0

. 1

0 . 2

4

1 7 . 0

1 7 . 0

2 8 . 6

–

2 . 1

2

P F M 0 0 0

0 6 6

1 2 0 1 6

2 0 0 5 - 1 1 - 2 8

0

. 1

0 . 1

8

1 5 . 3

1 5 . 2

2 9 . 5

–

1 . 9

0

P F M 0 0 0

0 6 6

1 2 0 2 2

2 0 0 5 - 1 2 - 1 9

0

. 1

0 . 0

9

1 7 . 5

1 9 . 1

3 7 . 7

–

2 . 5

6

P F M 0 0 0

0 6 6

1 2 0 4 2

2 0 0 6 - 0 1 - 2 3

0

. 1

0 . 1

2

1 9 . 4

1 9 . 2

4 5 . 6

0 . 7

0

2 . 5

4

P F M 0 0 0

0 6 6

1 2 0 8 1

2 0 0 6 - 0 2 - 2 0

0

. 1

0 . 0

9

1 6 . 3

1 5 . 8

4 1 . 9

–

2 . 1

2

P F M 0 0 0

0 6 6

1 2 0 9 8

2 0 0 6 - 0 3 - 2 0

0

. 1

0 . 1

1

1 6 . 5

1 6 . 3

4 7 . 7

1 . 6

0

2 . 2

0

P F M 0 0 0

0 6 6

1 2 2 3 5

2 0 0 6 - 0 4 - 1 8

0

. 1

0 . 3

7

1 4 . 5

1 4 . 4

2 4 . 4

–

2 . 4

8

P F M 0 0 0

0 6 6

1 2 2 5 3

2 0 0 6 - 0 5 - 1 5

0

. 1

0 . 1

6

1 8 . 2

1 8 . 6

3 8 . 1

–

2 . 6

8

P F M 0 0 0

0 6 6

1 2 2 9 8

2 0 0 6 - 0 6 - 1 3

0

. 1

–

1 8 . 3

1 7 . 8

3 1 . 4

–

2 . 9

4

P F M 0 0 0

0 6 8

8 9 3 2

2 0 0 5 - 0 7 - 1 2

0

. 1

0 . 4

2

1 9 . 5

1 9 . 6

3 0 . 2

3 . 7

0

3 . 9

2

P F M 0 0 0

0 6 8

8 9 5 1

2 0 0 5 - 0 8 - 0 1

0

. 5

0 . 2

8

2 0 . 9

2 0 . 1

3 7 . 5

–

4 . 0

6

P F M 0 0 0

0 6 8

8 9 6 0

2 0 0 5 - 0 9 - 0 5

0

. 5

0 . 2

6

1 9 . 5

1 5 . 2

3 2 . 4

–

3 . 4

2



82

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

N H 4_

N

m g / L

N O 2_

N

m g / L

N O 2_

N +

N O 3_ m g / L

N t o t

m g / L

P t o t

m g / L

P O 4_

P

m g / L

P O P m g / L

P O N

m g / L

S i O 4_

S i

m g / L

C h l . A

µ g / L

C h

l . C

µ g

/ L

P h e o p .

µ g / L

P F M 0 0 0

0 6 8

8 9 7 7

2 0 0 5 - 1 0 - 0 3

0

. 1

0 . 0

0 9 8

0 . 0

0 0 3

0 . 0

0 0 6

1 . 0

4

0 . 0

5 2 4

0 . 0

2 5 3

0 . 0 1

8 0

0 . 0

9 0 0

6 . 7

4

–

–

–

P F M 0 0 0

0 6 8

9 0 0 0

2 0 0 5 - 1 0 - 3 1

0

. 5

0 . 0

0 7 7

–

0 . 0

0 8 3

0 . 9

0

0 . 0

1 4 4

0 . 0

0 2 2

0 . 0 0

4 4

0 . 0

3 1 2

5 . 1

8

–

–

–

P F M 0 0 0

0 6 8

8 9 9 9

2 0 0 5 - 1 1 - 2 8

0

. 5

0 . 0

1 5 9

–

0 . 0

7 8 9

0 . 9

0

0 . 0

0 9 9

0 . 0

0 1 2

0 . 0 0

3 7

0 . 0

2 5 8

4 . 5

0

–

–

–

P F M 0 0 0

0 6 8

1 2 0 2 7

2 0 0 5 - 1 2 - 1 9

0

. 1

0 . 0

2 9 6

–

0 . 1

0 8

1 . 1

0

0 . 0

0 9 0

0 . 0

0 1 3

0 . 0 0

3 0

0 . 0

2 0 8

4 . 6

1

–

–

–

P F M 0 0 0

0 6 8

1 2 0 4 5

2 0 0 6 - 0 1 - 2 3

0

. 1

0 . 0

3 3 7

0 . 0

0 1 0

0 . 0

7 4 8

1 . 0

8

0 . 0

1 1 2

0 . 0

0 0 9

0 . 0 0

4 6

0 . 0

3 3 7

5 . 3

7

–

–

–

P F M 0 0 0

0 6 8

1 2 0 8 2

2 0 0 6 - 0 2 - 2 0

0

. 1

0 . 0

4 7 5

–

0 . 0

6 0 6

0 . 9

4

0 . 0

0 8 4

0 . 0

0 0 8

0 . 0 0

2 8

0 . 0

2 1 4

4 . 8

6

–

–

–

P F M 0 0 0

0 6 8

1 2 0 9 1

2 0 0 6 - 0 3 - 2 0

0

. 1

0 . 0

9 8 9

–

0 . 0

7 0 4

1 . 0

0

0 . 0

0 8 0

0 . 0

0 1 4

0 . 0 0

2 4

0 . 0

2 2 0

5 . 3

0

–

–

–

P F M 0 0 0

0 6 8

1 2 2 3 7

2 0 0 6 - 0 4 - 1 9

0

. 1

0 . 0

1 0 3

0 . 0

0 3 3

0 . 2

1 2

0 . 9

5

0 . 0

1 6 0

0 . 0

0 1 6

0 . 0 0

8 4

0 . 0

5 6 4

3 . 3

9

–

–

–

P F M 0 0 0

0 6 8

1 2 2 5 0

2 0 0 6 - 0 5 - 1 5

0

. 1

0 . 0

1 8 7

–

0 . 0

0 5 9

0 . 9

3

0 . 0

1 3 6

0 . 0

0 2 1

0 . 0 0

4 8

0 . 0

3 0 6

4 . 2

4

–

–

–

P F M 0 0 0

0 6 8

1 2 3 0 2

2 0 0 6 - 0 6 - 1 2

0

. 1

0 . 0

4 4 9

–

0 . 0

0 6 5

0 . 9

8

0 . 0

2 0 2

0 . 0

0 4 6

0 . 0 0

8 4

0 . 0

5 1 7

5 . 5

0

–

–

–

P F M 0 0 0

0 6 9

8 9 3 1

2 0 0 5 - 0 7 - 1 2

0

. 1

0 . 0

4 0 1

0 . 0

0 2 1

0 . 0

1 7 5

0 . 9

1

0 . 0

2 0 0

0 . 0

0 8 1

0 . 0 0

3 8

0 . 0

2 7 4

4 . 2

2

–

–

–

P F M 0 0 0

0 6 9

8 9 4 7

2 0 0 5 - 0 8 - 0 1

0

. 1

0 . 0

2 7 5

–

0 . 0

2 7 2

0 . 9

7

0 . 0

2 2 5

0 . 0

0 9 9

0 . 0 0

3 5

0 . 0

2 6 3

4 . 1

0

–

–

–

P F M 0 0 0

0 6 9

8 9 5 6

2 0 0 5 - 0 9 - 0 5

0

. 1

0 . 0

0 9 3

–

0 . 0

1 1 5

0 . 9

6

0 . 0

1 4 5

0 . 0

0 1 1

0 . 0 0

2 9

0 . 0

1 9 4

4 . 5

0

–

–

–

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

P O C

m g / L

T O C

m g / L

D O C

m g / L

D I C m g / L

O 2 m g / L

A b s . c o e f f .

m g / L

P F M 0 0 0

0 6 8

8 9 7 7

2 0 0 5 - 1 0 - 0 3

0

. 1

0 . 9

2

2 3 . 1

2 2 . 8

3 6 . 7

1 . 1

0

5 . 0

2

P F M 0 0 0

0 6 8

9 0 0 0

2 0 0 5 - 1 0 - 3 1

0

. 5

0 . 2

4

2 0 . 2

2 0 . 1

2 8 . 2

–

3 . 4

0

P F M 0 0 0

0 6 8

8 9 9 9

2 0 0 5 - 1 1 - 2 8

0

. 5

0 . 2

4

1 7 . 8

1 7 . 3

2 8 . 7

–

2 . 6

6

P F M 0 0 0

0 6 8

1 2 0 2 7

2 0 0 5 - 1 2 - 1 9

0

. 1

0 . 1

7

2 1 . 8

2 1 . 7

3 4 . 9

–

2 . 7

6

P F M 0 0 0

0 6 8

1 2 0 4 5

2 0 0 6 - 0 1 - 2 3

0

. 1

0 . 2

4

2 1 . 5

2 0 . 8

3 7 . 3

2 . 8

0

2 . 7

8

P F M 0 0 0

0 6 8

1 2 0 8 2

2 0 0 6 - 0 2 - 2 0

0

. 1

0 . 1

8

1 9 . 0

1 9 . 1

3 5 . 9

–

2 . 4

0

P F M 0 0 0

0 6 8

1 2 0 9 1

2 0 0 6 - 0 3 - 2 0

0

. 1

0 . 1

8

2 0 . 0

2 0 . 1

3 7 . 4

–

2 . 5

4

P F M 0 0 0

0 6 8

1 2 2 3 7

2 0 0 6 - 0 4 - 1 9

0

. 1

0 . 3

8

1 8 . 1

1 8 . 0

1 7 . 0

–

3 . 7

0

P F M 0 0 0

0 6 8

1 2 2 5 0

2 0 0 6 - 0 5 - 1 5

0

. 1

0 . 2

4

2 1 . 1

2 0 . 9

2 9 . 7

–

3 . 7

0

P F M 0 0 0

0 6 8

1 2 3 0 2

2 0 0 6 - 0 6 - 1 2

0

. 1

0 . 4

0

2 1 . 6

2 1 . 6

3 1 . 3

–

4 . 2

6

P F M 0 0 0

0 6 9

8 9 3 1

2 0 0 5 - 0 7 - 1 2

0

. 1

0 . 2

6

1 9 . 1

1 9 . 1

3 3 . 1

–

3 . 6

0

P F M 0 0 0

0 6 9

8 9 4 7

2 0 0 5 - 0 8 - 0 1

0

. 1

0 . 2

4

2 0 . 3

1 8 . 1

3 7 . 5

–

3 . 6

2

P F M 0 0 0

0 6 9

8 9 5 6

2 0 0 5 - 0 9 - 0 5

0

. 1

0 . 1

9

1 9 . 9

1 9 . 8

3 2 . 3

–

3 . 3

6



83

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

N H 4_

N

m g / L

N O 2_

N

m g / L

N O 2_

N +

N O 3_ m g / L

N t o t

m g / L

P t o t

m g / L

P O 4_

P

m g / L

P O P m g / L

P O N

m g / L

S i O 4_

S i

m g / L

C h l . A

µ g / L

C h

l . C

µ g

/ L

P h e o p .

µ g / L

P F M 0 0 0

0 6 9

8 9 7 4

2 0 0 5 - 1 0 - 0 3

0

. 1

0 . 0

2 9 5

0 . 0

0 4 4

0 . 0

5 5 0

1 . 0

7

0 . 0

2 0 9

0 . 0

0 4 5

0 . 0 0

5 0

0 . 0

4 3 1

6 . 5

2

–

–

–

P F M 0 0 0

0 6 9

8 9 9 5

2 0 0 5 - 1 0 - 3 1

0

. 1

0 . 0

1 4 1

–

0 . 0

0 7 6

0 . 9

0

0 . 0

1 4 9

0 . 0

0 1 6

0 . 0 0

4 5

0 . 0

2 9 9

5 . 9

9

–

–

–

P F M 0 0 0

0 6 9

1 2 0 1 7

2 0 0 5 - 1 1 - 2 8

0

. 1

0 . 0

1 3 5

–

0 . 0

2 4 3

0 . 8

2

0 . 0

1 2 3

0 . 0

0 2 1

0 . 0 0

3 6

0 . 0

1 9 8

6 . 1

4

–

–

–

P F M 0 0 0

0 6 9

1 2 0 2 0

2 0 0 5 - 1 2 - 1 9

0

. 1

0 . 0

0 7 2

–

0 . 1

2 1

0 . 0

1

0 . 0

0 9 8

0 . 0

0 1 4

0 . 0 0

2 8

0 . 0

1 7 5

6 . 2

2

–

–

–

P F M 0 0 0

0 6 9

1 2 0 4 3

2 0 0 6 - 0 1 - 2 3

0

. 1

0 . 0

0 6 7

0 . 0

0 0 5

0 . 0

0 1 4

0 . 9

3

0 . 0

1 8 3

0 . 0

0 1 2

0 . 0 0

8 9

0 . 0

5 5 7

7 . 8

2

–

–

–

P F M 0 0 0

0 6 9

1 2 0 7 9

2 0 0 6 - 0 2 - 2 0

0

. 1

0 . 0

0 4 2

–

0 . 0

0 3 5

0 . 7

2

0 . 0

1 0 6

0 . 0

0 1 3

0 . 0 0

4 1

0 . 0

2 7 3

6 . 7

9

–

–

–

P F M 0 0 0

0 6 9

1 2 0 9 9

2 0 0 6 - 0 3 - 2 0

0

. 1

0 . 0

1 5 0

–

0 . 0

0 3 3

0 . 7

6

0 . 0

1 1 2

0 . 0

0 1 0

0 . 0 0

4 6

0 . 0

3 2 1

7 . 3

9

–

–

–

P F M 0 0 0

0 6 9

1 2 2 3 0

2 0 0 6 - 0 4 - 1 9

0

. 1

0 . 0

0 6 1

0 . 0

0 5 2

0 . 3

5 6

1 . 0

8

0 . 0

1 7 6

0 . 0

0 1 3

0 . 0 0

9 5

0 . 0

6 4 4

3 . 8

7

–

–

–

P F M 0 0 0

0 6 9

1 2 2 3 6

2 0 0 6 - 0 5 - 1 5

0

. 1

0 . 0

0 6 9

–

0 . 0

0 1 4

0 . 8

7

0 . 0

1 1 8

0 . 0

0 1 7

0 . 0 0

2 7

0 . 0

2 2 8

5 . 3

2

–

–

–

P F M 0 0 0

0 6 9

1 2 3 0 1

2 0 0 6 - 0 6 - 1 2

0

. 1

0 . 0

1 8 5

–

0 . 0

0 2 9

0 . 9

4

0 . 0

1 5 0

0 . 0

0 3 4

0 . 0 0

5 7

0 . 0

2 7 2

5 . 6

4

–

–

–

P F M 0 0 0

0 7 0

8 9 3 3

2 0 0 5 - 0 7 - 1 2

0

. 1

0 . 1

9 8 0

0 . 0

0 0 6

0 . 0

0 4 2

1 . 0

9

0 . 0

1 4 2

0 . 0

0 2 1

0 . 0 0

6 5

0 . 0

6 2 9

3 . 1

3

–

–

–

P F M 0 0 0

0 7 0

8 9 5 4

2 0 0 5 - 0 8 - 0 2

0

. 1

0 . 0

7 3 7

–

0 . 0

0 7 8

0 . 9

8

0 . 0

0 9 5

0 . 0

0 1 1

0 . 0 0

4 6

0 . 0

3 7 8

3 . 1

6

–

–

–

P F M 0 0 0

0 7 0

8 9 5 7

2 0 0 5 - 0 9 - 0 6

0

. 1

0 . 1

3 3

–

0 . 0

1 3 2

1 . 0

0

0 . 0

1 1 0

0 . 0

0 1 7

0 . 0 0

5 2

0 . 0

4 4 9

2 . 7

8

–

–

–

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

P O C

m g / L

T O C

m g / L

D O C

m g / L

D I C m g / L

O 2 m g / L

A b s . c o e f f .

m g / L

P F M 0 0 0

0 6 9

8 9 7 4

2 0 0 5 - 1 0 - 0 3

0

. 1

0 . 4

2

2 0 . 6

2 0 . 2

3 2 . 6

–

3 . 7

2

P F M 0 0 0

0 6 9

8 9 9 5

2 0 0 5 - 1 0 - 3 1

0

. 1

0 . 2

1

1 9 . 2

1 8 . 5

3 1 . 6

–

3 . 1

8

P F M 0 0 0

0 6 9

1 2 0 1 7

2 0 0 5 - 1 1 - 2 8

0

. 1

0 . 1

8

1 7 . 9

1 7 . 7

3 5 . 7

–

2 . 8

6

P F M 0 0 0

0 6 9

1 2 0 2 0

2 0 0 5 - 1 2 - 1 9

0

. 1

0 . 1

1

2 1 . 9

2 0 . 8

3 7 . 3

2 . 7

0

3 . 3

0

P F M 0 0 0

0 6 9

1 2 0 4 3

2 0 0 6 - 0 1 - 2 3

0

. 1

0 . 3

4

2 3 . 2

2 2 . 9

5 0 . 1

< 0 . 2

3 . 9

6

P F M 0 0 0

0 6 9

1 2 0 7 9

2 0 0 6 - 0 2 - 2 0

0

. 1

0 . 1

7

1 8 . 8

1 8 . 5

4 3 . 9

1 . 2

0

2 . 8

2

P F M 0 0 0

0 6 9

1 2 0 9 9

2 0 0 6 - 0 3 - 2 0

0

. 1

0 . 2

2

1 9 . 7

1 9 . 5

4 6 . 5

1 . 1

0

3 . 3

0

P F M 0 0 0

0 6 9

1 2 2 3 0

2 0 0 6 - 0 4 - 1 9

0

. 1

0 . 4

0

1 6 . 5

1 6 . 5

2 5 . 4

–

3 . 0

8

P F M 0 0 0

0 6 9

1 2 2 3 6

2 0 0 6 - 0 5 - 1 5

0

. 1

0 . 1

6

2 2 . 3

2 1 . 6

3 2 . 5

–

3 . 9

8

P F M 0 0 0

0 6 9

1 2 3 0 1

2 0 0 6 - 0 6 - 1 2

0

. 1

0 . 2

4

2 1 . 2

2 1 . 1

3 0 . 1

–

4 . 1

6

P F M 0 0 0

0 7 0

8 9 3 3

2 0 0 5 - 0 7 - 1 2

0

. 1

0 . 5

6

1 8 . 2

1 8 . 3

2 7 . 6

–

2 . 3

2

P F M 0 0 0

0 7 0

8 9 5 4

2 0 0 5 - 0 8 - 0 2

0

. 1

0 . 3

2

1 9 . 3

1 9 . 5

2 7 . 4

–

2 . 7

2

P F M 0 0 0

0 7 0

8 9 5 7

2 0 0 5 - 0 9 - 0 6

0

. 1

0 . 4

6

1 6 . 7

1 6 . 5

2 2 . 8

–

1 . 9

0



84

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

N H 4_

N

m g / L

N O 2_

N

m g / L

N O 2_

N +

N O 3_ m g / L

N t o t

m g / L

P t o t

m g / L

P O 4_

P

m g / L

P O P m g / L

P O N

m g / L

S i O 4_

S i

m g / L

C h l . A

µ g / L

C h

l . C

µ g

/ L

P h e o p .

µ g / L

P F M 0 0 0

0 7 0

8 9 7 5

2 0 0 5 - 1 0 - 0 4

0

. 1

0 . 1

7 4

0 . 0

0 0 8

0 . 0

0 9 1

1 . 0

0

0 . 0

0 9 8

0 . 0

0 1 2

0 . 0 0

6 0

0 . 0

4 8 3

3 . 9

0

–

–

–

P F M 0 0 0

0 7 0

8 9 9 2

2 0 0 5 - 1 1 - 0 1

0

. 1

0 . 0

6 4 0

–

0 . 0

5 1 6

1 . 0

7

0 . 0

0 8 5

0 . 0

0 1 0

0 . 0 0

4 0

0 . 0

3 7 5

2 . 1

8

–

–

–

P F M 0 0 0

0 7 0

1 2 0 1 4

2 0 0 5 - 1 1 - 2 8

0

. 1

0 . 1

6 6

–

0 . 0

3 9 9

1 . 2

1

0 . 0

0 7 0

0 . 0

0 0 9

0 . 0 0

2 9

0 . 0

3 7 6

1 . 4

4

–

–

–

P F M 0 0 0

0 7 0

1 2 0 2 5

2 0 0 5 - 1 2 - 2 0

0

. 1

0 . 1

9 3

–

0 . 0

3 9 6

1 . 3

3

0 . 0

0 7 1

0 . 0

0 1 0

0 . 0 0

3 0

0 . 0

3 6 5

1 . 9

0

–

–

–

P F M 0 0 0

0 7 0

1 2 0 6 9

2 0 0 6 - 0 1 - 2 4

0

. 1

0 . 3

1 5

0 . 0

0 1 3

0 . 0

3 2 3

1 . 4

8

0 . 0

0 6 3

0 . 0

0 1 4

0 . 0 0

2 8

0 . 0

3 5 5

1 . 8

8

–

–

–

P F M 0 0 0

0 7 0

1 2 0 8 3

2 0 0 6 - 0 2 - 2 1

0

. 5

0 . 2

3 6

–

0 . 0

4 3 5

1 . 2

7

0 . 0

0 7 4

0 . 0

0 1 0

0 . 0 0

2 0

0 . 0

2 4 2

3 . 2

5

–

–

–

P F M 0 0 0

0 7 0

1 2 0 9 2

2 0 0 6 - 0 3 - 2 1

0

. 1

0 . 3

9 7

–

0 . 0

2 9 8

1 . 4

2

0 . 0

0 8 7

0 . 0

0 0 5

0 . 0 0

4 6

0 . 0

4 6 3

3 . 5

4

–

–

–

P F M 0 0 0

0 7 0

1 2 2 4 0

2 0 0 6 - 0 4 - 1 9

0

. 1

0 . 0

9 6 7

0 . 0

0 1 2

0 . 0

3 7 2

0 . 7

8

0 . 0

1 2 0

0 . 0

0 1 1

0 . 0 0

5 7

0 . 0

4 2 5

2 . 0

3

–

–

–

P F M 0 0 0

0 7 0

1 2 2 5 2

2 0 0 6 - 0 5 - 1 6

0

. 1

0 . 0

5 7 3

–

0 . 0

0 7 6

0 . 9

9

0 . 0

1 2 0

0 . 0

0 1 0

0 . 0 0

5 5

0 . 0

5 3 6

1 . 4

2

–

–

–

P F M 0 0 0

0 7 0

1 2 3 0 4

2 0 0 6 - 0 6 - 1 2

0

. 1

0 . 1

0 3

–

0 . 0

0 8 2

0 . 9

6

0 . 0

1 0 0

0 . 0

0 1 6

–

0 . 0

4 6 0

1 . 4

2

–

–

–

P F M 0 0 0

0 7 4

8 9 3 7

2 0 0 5 - 0 7 - 1 1

0

. 5

0 . 0

0 3

0 . 0

0 0 2

0 . 0

0 0 3

0 . 9

3

0 . 0

1 1 2

0 . 0

0 1 3

0 . 0 0

5 1

0 . 0

5 9 0

3 . 8

0

2 . 4

0 . 2

0 . 9

P F M 0 0 0

0 7 4

8 9 4 8

2 0 0 5 - 0 8 - 0 1

0

. 5

0 . 0

0 5 4

–

0 . 0

0 0 7

1 . 0

0

0 . 0

1 2 1

0 . 0

0 1 5

0 . 0 0

5 5

0 . 0

5 6 0

4 . 9

9

2 . 5

< 0 . 2

0 . 4

P F M 0 0 0

0 7 4

8 9 6 2

2 0 0 5 - 0 9 - 0 5

0

. 5

0 . 0

0 4 2

–

< 0 . 0

0 0 3

0 . 9

3

0 . 0

0 7 9

< 0 . 0

0 0 5

0 . 0 0

3 2

0 . 0

3 8 6

5 . 8

8

1 . 2

< 0 . 2

0 . 3

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

P O C

m g / L

T O C

m g / L

D O C

m g / L

D I C m g / L

O 2 m g / L

A b s . c o e f f .

m g / L

P F M 0 0 0

0 7 0

8 9 7 5

2 0 0 5 - 1 0 - 0 4

0

. 1

0 . 5

6

1 7 . 5

1 7 . 6

2 4 . 9

–

2 . 4

8

P F M 0 0 0

0 7 0

8 9 9 2

2 0 0 5 - 1 1 - 0 1

0

. 1

0 . 3

1

1 5 . 3

1 5 . 1

1 9 . 9

–

1 . 2

0

P F M 0 0 0

0 7 0

1 2 0 1 4

2 0 0 5 - 1 1 - 2 8

0

. 1

0 . 3

5

1 5 . 8

1 5 . 6

1 9 . 4

–

0 . 6

4

P F M 0 0 0

0 7 0

1 2 0 2 5

2 0 0 5 - 1 2 - 2 0

0

. 1

0 . 2

9

1 9 . 7

1 9 . 2

2 1 . 6

–

1 . 6

6

P F M 0 0 0

0 7 0

1 2 0 6 9

2 0 0 6 - 0 1 - 2 4

0

. 1

0 . 3

2

1 8 . 7

1 8 . 7

2 2 . 3

–

0 . 9

4

P F M 0 0 0

0 7 0

1 2 0 8 3

2 0 0 6 - 0 2 - 2 1

0

. 5

0 . 2

0

2 2 . 4

2 1 . 0

2 8 . 1

–

2 . 5

4

P F M 0 0 0

0 7 0

1 2 0 9 2

2 0 0 6 - 0 3 - 2 1

0

. 1

0 . 3

5

2 1 . 6

2 1 . 8

2 9 . 0

2 . 0

0

3 . 5

4

P F M 0 0 0

0 7 0

1 2 2 4 0

2 0 0 6 - 0 4 - 1 9

0

. 1

0 . 2

9

1 5 . 2

1 5 . 3

1 3 . 0

–

2 . 8

2

P F M 0 0 0

0 7 0

1 2 2 5 2

2 0 0 6 - 0 5 - 1 6

0

. 1

0 . 4

0

1 7 . 8

1 7 . 8

2 6 . 5

–

2 . 0

4

P F M 0 0 0

0 7 0

1 2 3 0 4

2 0 0 6 - 0 6 - 1 2

0

. 1

0 . 3

8

1 7 . 4

1 7 . 4

2 7 . 5

–

2 . 2

6

P F M 0 0 0

0 7 4

8 9 3 7

2 0 0 5 - 0 7 - 1 1

0

. 5

0 . 4

3

1 9 . 5

1 8 . 3

3 3 . 1

–

2 . 8

4

P F M 0 0 0

0 7 4

8 9 4 8

2 0 0 5 - 0 8 - 0 1

0

. 5

0 . 4

2

1 9 . 2

1 9 . 1

3 6 . 1

–

2 . 5

4

P F M 0 0 0

0 7 4

8 9 6 2

2 0 0 5 - 0 9 - 0 5

0

. 5

0 . 3

4

1 8 . 6

1 8 . 4

3 7 . 2

–

2 . 3

6



85

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

N H 4_

N

m g / L

N O 2_

N

m g / L

N O 2_

N +

N O 3_ m g / L

N t o t

m g / L

P t o t

m g / L

P O 4_

P

m g / L

P O P m g / L

P O N

m g / L

S i O 4_

S i

m g / L

C h l . A

µ g / L

C h

l . C

µ g

/ L

P h e o p .

µ g / L

P F M 0 0 0

0 7 4

8 9 7 6

2 0 0 5 - 1 0 - 0 3

0

. 5

0 . 0

0 5 8

< 0 . 0

0 0 3

< 0 . 0

0 0 3

0 . 8

9

0 . 0

0 7 0

0 . 0

0 0 8

0 . 0 0

2 9

0 . 0

3 8 1

7 . 1

6

1 . 5

< 0 . 2

0 . 2

P F M 0 0 0

0 7 4

8 9 9 8

2 0 0 5 - 1 0 - 3 1

0

. 5

0 . 0

0 3 7

–

0 . 0

0 1 1

0 . 7

8

0 . 0

0 6 0

0 . 0

0 0 4

0 . 0 0

2 4

0 . 0

3 2 1

6 . 4

6

1 . 2

0 . 2

0 . 2

P F M 0 0 0

0 7 4

1 2 0 1 8

2 0 0 5 - 1 1 - 2 9

0

. 5

0 . 0

1 5 0

–

0 . 0

1 0 6

0 . 7

4

0 . 0

0 7 0

0 . 0

0 1 0

0 . 0 0

2 3

0 . 0

1 7 2

5 . 9

1

0 . 5

0 . 2

0 . 2

P F M 0 0 0

0 7 4

1 2 0 2 3

2 0 0 5 - 1 2 - 2 0

0

. 5

0 . 0

0 5 7

–

0 . 0

4 5 9

0 . 7

8

0 . 0

0 6 2

0 . 0

0 0 7

0 . 0 0

1 6

0 . 0

0 8 9

5 . 5

4

0 . 3

< 0 . 2

0 . 4

P F M 0 0 0

0 7 4

1 2 0 3 2

2 0 0 6 - 0 1 - 2 4

0

. 5

0 . 0

2 5 9

0 . 0

0 1 0

0 . 0

1 2 6

0 . 7

7

0 . 0

0 6 2

0 . 0

0 0 6

0 . 0 0

1 6

0 . 0

1 2 1

6 . 3

8

0 . 5

0 . 2

0 . 3

P F M 0 0 0

0 7 4

1 2 0 8 0

2 0 0 6 - 0 2 - 2 1

0

. 5

0 . 0

0 5 5

–

0 . 0

1 5 4

0 . 6

4

0 . 0

0 4 6

0 . 0

0 0 6

0 . 0 0

0 7

0 . 0

0 8 1

5 . 7

1

< 0 . 2

< 0 . 2

< 0 . 2

P F M 0 0 0

0 7 4

1 2 2 0 0

2 0 0 6 - 0 3 - 2 0

1

. 5

0 . 0

1 4 9

–

0 . 0

2 3 3

0 . 6

6

0 . 0

0 5 0

0 . 0

0 0 5

0 . 0 0

1 3

0 . 0

1 3 0

5 . 9

4

–

–

–

P F M 0 0 0

0 7 4

1 2 2 3 2

2 0 0 6 - 0 4 - 1 8

0

. 5

0 . 0

0 5 5

0 . 0

0 1 1

0 . 0

8 6 5

0 . 6

7

0 . 0

1 2 8

0 . 0

0 1 0

0 . 0 0

6 4

0 . 0

4 6 9

3 . 6

7

0 . 3

< 0 . 2

< 0 . 2

P F M 0 0 0

0 7 4

1 2 2 4 8

2 0 0 6 - 0 5 - 1 5

0

. 5

0 . 0

0 3 3

–

0 . 0

0 0 5

0 . 7

7

0 . 0

0 9 0

0 . 0

0 1 1

0 . 0 0

3 0

0 . 0

3 0 0

4 . 3

1

1 . 0

< 0 . 2

0 . 2

P F M 0 0 0

0 7 4

1 2 3 0 3

2 0 0 6 - 0 6 - 1 3

0

. 5

0 . 0

0 6 9

–

0 . 0

0 0 4

0 . 9

4

0 . 0

1 3 7

0 . 0

0 1 5

0 . 0 0

7 4

0 . 0

3 9 5

3 . 5

9

2 . 4

0 . 2

0 . 9

P F M 0 0 0

0 8 2

1 2 0 3 0

2 0 0 6 - 0 1 - 2 3

0

. 5

0 . 0

0 4 8

0 . 0

0 1 5

0 . 0

6 4 8

0 . 2

8

0 . 0

1 4 3

0 . 0

0 7 5

0 . 0 0

1 9

–

0 . 7

3 3

1 . 1

0 . 3

0 . 2

P F M 0 0 0

0 8 2

1 2 0 4 6

2 0 0 6 - 0 1 - 2 3

6

0 . 0

0 3 2

0 . 0

0 1 8

0 . 0

6 2 9

0 . 2

8

0 . 0

1 4 9

0 . 0

0 7 0

0 . 0 0

2 8

0 . 0

1 4 8

0 . 7

1 6

1 . 4

0 . 3

0 . 2

P F M 0 0 0

0 8 2

1 2 0 8 4

2 0 0 6 - 0 2 - 2 0

0

. 5

0 . 0

0 2 2

–

0 . 0

5 2 9

0 . 2

6

0 . 0

1 3 0

0 . 0

0 5 6

0 . 0 0

3 3

0 . 0

2 0 2

0 . 6

4 6

1 . 8

0 . 2

< 0 . 2

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

P O C

m g / L

T O C

m g / L

D O C

m g / L

D I C m g / L

O 2 m g / L

A b s . c o e f f .

m g / L

P F M 0 0 0

0 7 4

8 9 7 6

2 0 0 5 - 1 0 - 0 3

0

. 5

0 . 2

9

1 8 . 5

1 8 . 0

2 9 . 1

–

2 . 0

6

P F M 0 0 0

0 7 4

8 9 9 8

2 0 0 5 - 1 0 - 3 1

0

. 5

0 . 2

3

1 6 . 2

1 5 . 8

3 0 . 3

–

1 . 9

0

P F M 0 0 0

0 7 4

1 2 0 1 8

2 0 0 5 - 1 1 - 2 9

0

. 5

0 . 1

2

1 6 . 6

1 6 . 3

4 1 . 9

3 . 3

0

2 . 0

0

P F M 0 0 0

0 7 4

1 2 0 2 3

2 0 0 5 - 1 2 - 2 0

0

. 5

0 . 0

5

1 8 . 5

1 8 . 4

3 8 . 2

3 . 0

0

2 . 3

8

P F M 0 0 0

0 7 4

1 2 0 3 2

2 0 0 6 - 0 1 - 2 4

0

. 5

0 . 0

8

1 9 . 2

1 8 . 8

4 9 . 2

0 . 4

0

2 . 2

8

P F M 0 0 0

0 7 4

1 2 0 8 0

2 0 0 6 - 0 2 - 2 1

0

. 5

0 . 0

6

1 5 . 6

1 5 . 5

4 5 . 4

2 . 8

0

1 . 9

2

P F M 0 0 0

0 7 4

1 2 2 0 0

2 0 0 6 - 0 3 - 2 0

1

. 5

0 . 0

8

1 6 . 2

1 6 . 1

4 6 . 8

2 . 6

0

1 . 9

4

P F M 0 0 0

0 7 4

1 2 2 3 2

2 0 0 6 - 0 4 - 1 8

0

. 5

0 . 2

8

1 3 . 5

1 3 . 5

2 6 . 0

–

2 . 2

4

P F M 0 0 0

0 7 4

1 2 2 4 8

2 0 0 6 - 0 5 - 1 5

0

. 5

0 . 1

9

1 8 . 5

1 7 . 9

3 8 . 7

–

2 . 8

8

P F M 0 0 0

0 7 4

1 2 3 0 3

2 0 0 6 - 0 6 - 1 3

0

. 5

0 . 2

8

1 8 . 8

1 8 . 1

3 6 . 3

–

2 . 7

8

P F M 0 0 0

0 8 2

1 2 0 3 0

2 0 0 6 - 0 1 - 2 3

0

. 5

–

3 . 7

3 . 7

1 3 . 9

–

0 . 2

4

P F M 0 0 0

0 8 2

1 2 0 4 6

2 0 0 6 - 0 1 - 2 3

6

0 . 1

2

3 . 8

3 . 8

1 4 . 2

–

0 . 2

6

P F M 0 0 0

0 8 2

1 2 0 8 4

2 0 0 6 - 0 2 - 2 0

0

. 5

0 . 1

7

3 . 7

3 . 7

1 0 . 1

–

0 . 2

4



86

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

N H 4_

N

m g / L

N O 2_

N

m g / L

N O 2_

N +

N O 3_ m g / L

N t o t

m g / L

P t o t

m g / L

P O 4_

P

m g / L

P O P m g / L

P O N

m g / L

S i O 4_

S i

m g / L

C h l . A

µ g / L

C h

l . C

µ g

/ L

P h e o p .

µ g / L

P F M 0 0 0

0 8 2

1 2 0 8 5

2 0 0 6 - 0 2 - 2 0

6

0 . 0

0 3 1

–

0 . 0

5 7 3

0 . 2

8

0 . 0

1 3 5

0 . 0

0 6 2

0 . 0 0

3 3

0 . 0

2 1 2

0 . 6

7 6

1 . 8

0 . 2

< 0 . 2

P F M 0 0 0

0 8 2

1 2 0 9 7

2 0 0 6 - 0 3 - 2 0

0

. 5

0 . 0

0 4 2

–

0 . 0

4 0 1

0 . 2

6

0 . 0

1 0 2

0 . 0

0 2 9

0 . 0 0

2 5

0 . 0

1 9 9

0 . 5

5 8

1 . 1

< 0 . 2

< 0 . 2

P F M 0 0 0

0 8 2

1 2 0 9 0

2 0 0 6 - 0 3 - 2 0

6

0 . 0

0 9 3

–

0 . 0

4 0 4

0 . 2

6

0 . 0

1 1 4

0 . 0

0 3 5

0 . 0 0

3 8

0 . 0

2 3 6

0 . 5

8 1

1 . 6

0 . 3

0 . 4

P F M 0 0 0

1 0 7

8 9 3 8

2 0 0 5 - 0 7 - 1 1

0

. 5

0 . 0

1 1 6

0 . 0

0 0 2

0 . 0

0 0 7

1 . 0

3

0 . 0

1 6 3

0 . 0

0 1 6

0 . 0 0

6 8

0 . 0

5 4 8

0 . 3

8 3

1 . 4

< 0 . 2

< 0 . 2

P F M 0 0 0

1 0 7

8 9 5 0

2 0 0 5 - 0 8 - 0 1

0

. 5

0 . 0

1 0 1

–

0 . 0

0 0 3

1 . 0

9

0 . 0

1 6 3

0 . 0

0 1 8

0 . 0 0

6 2

0 . 0

5 4 7

0 . 3

2 7

2 . 0

0 . 2

< 0 . 2

P F M 0 0 0

1 0 7

8 9 6 1

2 0 0 5 - 0 9 - 0 5

0

. 5

0 . 0

1 1 9

–

< 0 . 0

0 0 3

1 . 0

2

0 . 0

1 2 5

0 . 0

0 0 7

0 . 0 0

4 7

0 . 0

1 6 7

0 . 3

0 5

1 . 2

< 0 . 2

0 . 2

P F M 0 0 0

1 0 7

8 9 7 0

2 0 0 5 - 1 0 - 0 3

0

. 5

0 . 0

2 1 1

0 . 0

0 0 7

0 . 0

0 0 8

1 . 0

1

0 . 0

1 3 1

0 . 0

0 1 3

0 . 0 0

4 4

0 . 0

4 4 2

0 . 1

2 5

1 . 3

0 . 3

< 0 . 2

P F M 0 0 0

1 0 7

8 9 9 7

2 0 0 5 - 1 0 - 3 1

0

. 5

0 . 0

0 8 2

–

0 . 0

0 1 4

0 . 9

4

0 . 0

1 1 7

0 . 0

0 0 6

0 . 0 0

3 8

0 . 0

3 3 5

0 . 0

8 2

0 . 8

0 . 4

0 . 2

P F M 0 0 0

1 0 7

1 2 0 1 5

2 0 0 5 - 1 1 - 2 8

0

. 5

0 . 0

2 5 5

–

0 . 0

0 6 7

0 . 8

9

0 . 0

0 9 1

0 . 0

0 0 6

0 . 0 0

1 9

0 . 0

2 8 0

0 . 4

5 3

0 . 9

0 . 2

0 . 2

P F M 0 0 0

1 0 7

1 2 0 2 4

2 0 0 5 - 1 2 - 1 9

0

. 5

0 . 0

2 1 4

–

0 . 1

3 2

1 . 1

4

0 . 0

1 0 3

0 . 0

0 1 0

0 . 0 0

3 6

0 . 0

2 9 2

4 . 9

2

1 . 9

0 . 4

< 0 . 2

P F M 0 0 0

1 0 7

1 2 0 2 8

2 0 0 5 - 1 2 - 1 9

1

0 . 1

0 8

–

0 . 0

0 5 9

0 . 9

9

0 . 0

0 9 1

0 . 0

0 0 9

0 . 0 0

2 8

0 . 0

2 1 8

0 . 5

8 5

0 . 6

0 . 2

< 0 . 2

P F M 0 0 0

1 0 7

1 2 0 4 4

2 0 0 6 - 0 1 - 2 3

0

. 5

0 . 2

6 2

0 . 0

0 0 5

0 . 0

0 3 0

1 . 1

5

0 . 0

1 1 7

0 . 0

0 0 9

0 . 0 0

3 3

0 . 0

2 3 4

0 . 8

8 9

0 . 2

0 . 2

0 . 1

P F M 0 0 0

1 0 7

1 2 0 4 7

2 0 0 6 - 0 1 - 2 3

1

0 . 1

1 9

0 . 0

0 1 5

0 . 0

6 0 9

1 . 2

2

0 . 0

1 0 1

0 . 0

0 1 2

0 . 0 0

2 9

0 . 0

2 6 0

3 . 5

4

0 . 4

0 . 4

0 . 3

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

P O C

m g / L

T O C

m g / L

D O C

m g / L

D I C m g / L

O 2 m g / L

A b s . c o e f f .

m g / L

P F M 0 0 0

0 8 2

1 2 0 8 5

2 0 0 6 - 0 2 - 2 0

6

0 . 1

4

3 . 6

3 . 8

1 2 . 8

–

0 . 2

2

P F M 0 0 0

0 8 2

1 2 0 9 7

2 0 0 6 - 0 3 - 2 0

0

. 5

0 . 1

3

3 . 7

3 . 8

1 4 . 7

–

0 . 2

4

P F M 0 0 0

0 8 2

1 2 0 9 0

2 0 0 6 - 0 3 - 2 0

6

0 . 1

7

3 . 8

3 . 6

1 2 . 6

–

0 . 2

4

P F M 0 0 0

1 0 7

8 9 3 8

2 0 0 5 - 0 7 - 1 1

0

. 5

0 . 3

9

1 6 . 0

1 5 . 5

1 4 . 7

–

1 . 1

0

P F M 0 0 0

1 0 7

8 9 5 0

2 0 0 5 - 0 8 - 0 1

0

. 5

0 . 3

9

1 6 . 5

1 6 . 4

1 8 . 6

–

0 . 9

4

P F M 0 0 0

1 0 7

8 9 6 1

2 0 0 5 - 0 9 - 0 5

0

. 5

0 . 1

9

1 5 . 6

1 5 . 2

1 5 . 9

–

0 . 7

8

P F M 0 0 0

1 0 7

8 9 7 0

2 0 0 5 - 1 0 - 0 3

0

. 5

0 . 3

3

1 5 . 5

1 5 . 6

1 6 . 9

–

1 . 0

0

P F M 0 0 0

1 0 7

8 9 9 7

2 0 0 5 - 1 0 - 3 1

0

. 5

0 . 2

8

1 4 . 8

1 4 . 7

1 7 . 0

–

0 . 7

0

P F M 0 0 0

1 0 7

1 2 0 1 5

2 0 0 5 - 1 1 - 2 8

0

. 5

0 . 2

2

1 4 . 3

1 3 . 9

2 2 . 2

–

0 . 8

0

P F M 0 0 0

1 0 7

1 2 0 2 4

2 0 0 5 - 1 2 - 1 9

0

. 5

0 . 1

9

2 1 . 7

2 3 . 4

2 9 . 5

–

3 . 2

2

P F M 0 0 0

1 0 7

1 2 0 2 8

2 0 0 5 - 1 2 - 1 9

1

0 . 1

4

1 4 . 8

1 4 . 6

2 6 . 1

–

0 . 9

8

P F M 0 0 0

1 0 7

1 2 0 4 4

2 0 0 6 - 0 1 - 2 3

0

. 5

0 . 1

6

1 6 . 0

1 6 . 2

3 0 . 9

0 . 8

0

1 . 1

6

P F M 0 0 0

1 0 7

1 2 0 4 7

2 0 0 6 - 0 1 - 2 3

1

0 . 2

1

2 2 . 1

2 1 . 0

3 3 . 5

3 . 8

0

2 . 4

6



87

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

N H 4_

N

m g / L

N O 2_

N

m g / L

N O 2_

N +

N O 3_ m g / L

N t o t

m g / L

P t o t

m g / L

P O 4_

P

m g / L

P O P m g / L

P O N

m g / L

S i O 4_

S i

m g / L

C h l . A

µ g / L

C h

l . C

µ g

/ L

P h e o p .

µ g / L

P F M 0 0 0

1 0 7

1 2 0 7 8

2 0 0 6 - 0 2 - 2 0

0

. 5

0 . 0

9 5 9

–

0 . 0

4 3 6

1 . 0

7

0 . 0

1 2 0

0 . 0

0 0 9

0 . 0 0

3 6

0 . 0

2 6 8

3 . 9

8

0 . 2

< 0 . 2

< 0 . 2

P F M 0 0 0

1 0 7

1 2 0 8 6

2 0 0 6 - 0 2 - 2 0

1

0 . 2

7 8

–

0 . 0

0 0 7

1 . 1

8

0 . 0

1 2 0

0 . 0

0 0 6

0 . 0 0

5 0

0 . 0

3 6 6

1 . 3

7

< 0 . 2

< 0 . 2

< 0 . 2

P F M 0 0 0

1 0 7

1 2 0 9 6

2 0 0 6 - 0 3 - 2 0

0

. 5

0 . 0

9 5 6

–

0 . 0

3 0 6

0 . 9

6

0 . 0

0 8 7

0 . 0

0 0 5

0 . 0 0

2 7

0 . 0

3 2 4

4 . 3

6

0 . 1

< 0 . 2

< 0 . 2

P F M 0 0 0

1 0 7

1 2 0 9 4

2 0 0 6 - 0 3 - 2 0

1

0 . 2

7 2

–

0 . 0

0 0 7

1 . 1

8

0 . 0

1 2 5

0 . 0

0 0 6

0 . 0 0

6 2

0 . 0

5 1 8

1 . 8

3

0 . 5

< 0 . 2

0 . 3

P F M 0 0 0

1 0 7

1 2 2 3 1

2 0 0 6 - 0 5 - 1 5

0

. 5

0 . 0

1 0 4

–

0 . 0

0 1 0

0 . 8

4

0 . 0

1 4 2

0 . 0

0 1 9

0 . 0 0

5 1

0 . 0

5 9 1

1 . 5

6

2 . 0

0 . 4

0 . 7

P F M 0 0 0

1 0 7

1 2 3 0 0

2 0 0 6 - 0 6 - 1 2

0

. 5

0 . 0

0 6 7

–

0 . 0

0 0 6

0 . 9

4

0 . 0

1 5 8

0 . 0

0 2 2

0 . 0 0

8 7

0 . 0

8 4 7

0 . 3

6

4 . 1

0 . 6

0 . 3

P F M 0 0 0

1 1 7

8 9 3 5

2 0 0 5 - 0 7 - 1 1

0

. 5

0 . 0

1 1 9

< 0 . 0

0 0 2

0 . 0

0 1 2

1 . 1

2

0 . 0

0 9 0

0 . 0

0 1 0

0 . 0 0

3 8

0 . 0

7 6 5

0 . 6

3 3

2 . 2

< 0 . 2

< 0 . 2

P F M 0 0 0

1 1 7

8 9 4 9

2 0 0 5 - 0 8 - 0 2

0

. 5

0 . 0

0 9 6

–

0 . 0

0 0 8

1 . 1

6

0 . 0

0 8 0

0 . 0

0 0 9

0 . 0 0

3 3

0 . 0

5 7 5

0 . 9

9

1 . 9

0 . 2

< 0 . 2

P F M 0 0 0

1 1 7

8 9 5 8

2 0 0 5 - 0 9 - 0 6

0

. 5

0 . 0

1 0 1

–

0 . 0

0 0 3

1 . 1

4

0 . 0

0 6 9

0 . 0

0 0 9

0 . 0 0

3 7

0 . 0

5 8 9

1 . 2

5

1 . 2

< 0 . 2

< 0 . 2

P F M 0 0 0

1 1 7

8 9 7 3

2 0 0 5 - 1 0 - 0 4

0

. 5

0 . 0

2 1 2

0 . 0

0 0 2

0 . 0

0 1 4

1 . 1

2

0 . 0

0 6 5

0 . 0

0 1 1

0 . 0 0

2 6

0 . 0

4 2 5

1 . 2

7

1 . 3

< 0 . 2

< 0 . 2

P F M 0 0 0

1 1 7

8 9 9 4

2 0 0 5 - 1 1 - 0 1

0

. 5

0 . 0

7 6 1

–

0 . 0

0 6 4

1 . 1

4

0 . 0

0 5 9

0 . 0

0 0 9

0 . 0 0

2 4

0 . 0

4 1 6

1 . 3

2

1 . 0

< 0 . 2

1 . 2

P F M 0 0 0

1 1 7

1 2 0 1 3

2 0 0 5 - 1 1 - 2 9

0

. 5

0 . 1

8 9

–

0 . 0

1 2 4

1 . 2

3

0 . 0

0 5 6

0 . 0

0 0 8

0 . 0 0

2 4

0 . 0

3 1 8

1 . 4

1

1 . 8

0 . 2

< 0 . 2

P F M 0 0 0

1 1 7

1 2 0 2 6

2 0 0 5 - 1 2 - 2 0

0

. 5

0 . 4

6 1

–

0 . 0

1 7 9

1 . 5

6

0 . 0

0 8 1

0 . 0

0 0 7

0 . 0 0

3 2

0 . 0

3 7 9

2 . 3

0 . 8

0 . 2

0 . 3

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

P O C

m g / L

T O C

m g / L

D O C

m g / L

D I C m g / L

O 2 m g / L

A b s . c o e f f .

m g / L

P F M 0 0 0

1 0 7

1 2 0 7 8

2 0 0 6 - 0 2 - 2 0

0

. 5

0 . 2

0

2 0 . 2

1 9 . 7

3 4 . 8

1 . 4

0

2 . 4

0

P F M 0 0 0

1 0 7

1 2 0 8 6

2 0 0 6 - 0 2 - 2 0

1

0 . 2

8

1 6 . 9

1 6 . 9

3 3 . 6

< 0 . 2

1 . 2

8

P F M 0 0 0

1 0 7

1 2 0 9 6

2 0 0 6 - 0 3 - 2 0

0

. 5

0 . 2

7

1 8 . 8

1 8 . 2

3 3 . 1

1 . 5

0

2 . 4

0

P F M 0 0 0

1 0 7

1 2 0 9 4

2 0 0 6 - 0 3 - 2 0

1

0 . 4

4

1 7 . 4

1 6 . 7

3 1 . 9

< 0 . 2

1 . 6

4

P F M 0 0 0

1 0 7

1 2 2 3 1

2 0 0 6 - 0 5 - 1 5

0

. 5

0 . 3

7

1 7 . 6

1 7 . 2

2 3 . 2

–

2 . 6

0

P F M 0 0 0

1 0 7

1 2 3 0 0

2 0 0 6 - 0 6 - 1 2

0

. 5

0 . 5

6

1 8 . 2

1 8 . 2

1 7 . 2

–

2 . 0

0

P F M 0 0 0

1 1 7

8 9 3 5

2 0 0 5 - 0 7 - 1 1

0

. 5

0 . 6

0

1 7 . 5

1 7 . 7

1 4 . 4

–

0 . 9

8

P F M 0 0 0

1 1 7

8 9 4 9

2 0 0 5 - 0 8 - 0 2

0

. 5

0 . 5

2

1 8 . 2

1 8 . 3

1 5 . 4

–

0 . 8

2

P F M 0 0 0

1 1 7

8 9 5 8

2 0 0 5 - 0 9 - 0 6

0

. 5

0 . 5

5

1 7 . 4

1 6 . 9

1 4 . 1

–

0 . 6

8

P F M 0 0 0

1 1 7

8 9 7 3

2 0 0 5 - 1 0 - 0 4

0

. 5

0 . 4

1

1 6 . 9

1 6 . 8

1 4 . 9

–

0 . 7

0

P F M 0 0 0

1 1 7

8 9 9 4

2 0 0 5 - 1 1 - 0 1

0

. 5

0 . 3

7

1 6 . 2

1 6 . 0

1 4 . 8

–

0 . 6

8

P F M 0 0 0

1 1 7

1 2 0 1 3

2 0 0 5 - 1 1 - 2 9

0

. 5

0 . 2

9

1 5 . 7

1 5 . 9

2 0 . 5

–

0 . 7

6

P F M 0 0 0

1 1 7

1 2 0 2 6

2 0 0 5 - 1 2 - 2 0

0

. 5

0 . 3

0

1 9 . 5

1 9 . 3

2 4 . 4

–

1 . 7

4



88

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

N H 4_

N

m g / L

N O 2_

N

m g / L

N O 2_

N +

N O 3_ m g / L

N t o t

m g / L

P t o t

m g / L

P O 4_

P

m g / L

P O P m g / L

P O N

m g / L

S i O 4_

S i

m g / L

C h l . A

µ g / L

C h

l . C

µ g

/ L

P h e o p .

µ g / L

P F M 0 0 0

1 1 7

1 2 0 3 1

2 0 0 5 - 1 2 - 2 0

1

. 5

0 . 2

1 9

–

0 . 0

1 7 8

1 . 3

3

0 . 0

0 5 8

0 . 0

0 0 9

0 . 0 0

2 9

0 . 0

3 3 5

1 . 5

5

1 . 9

0 . 4

< 0 . 2

P F M 0 0 0

1 1 7

1 2 0 3 3

2 0 0 6 - 0 1 - 2 4

0

. 5

0 . 7

0 0

0 . 0

0 0 6

0 . 0

0 9 8

1 . 7

5

0 . 0

0 8 1

0 . 0

0 1 4

0 . 0 0

3 7

0 . 0

4 3 8

2 . 8

8

0 . 8

0 . 3

0 . 3

P F M 0 0 0

1 1 7

1 2 0 4 8

2 0 0 6 - 0 1 - 2 4

1

. 5

0 . 3

2 2

0 . 0

0 1 0

0 . 0

2 5 4

1 . 4

8

0 . 0

0 6 1

0 . 0

0 1 1

0 . 0 0

3 4

0 . 0

3 3 1

1 . 9

4

1 . 1

0 . 4

0 . 3

P F M 0 0 0

1 1 7

1 2 0 8 7

2 0 0 6 - 0 2 - 2 1

0

. 5

0 . 4

6 8

–

0 . 0

2 2 7

1 . 5

9

0 . 0

0 6 9

0 . 0

0 1 1

0 . 0 0

2 2

0 . 0

2 6 3

2 . 1

3

0 . 8

< 0 . 2

< 0 . 2

P F M 0 0 0

1 1 7

1 2 0 8 8

2 0 0 6 - 0 2 - 2 1

1

. 5

0 . 6

3 1

–

0 . 0

1 2 1

1 . 6

7

0 . 0

0 7 6

0 . 0

0 1 2

0 . 0 0

2 9

0 . 0

3 3 1

2 . 5

8

0 . 5

< 0 . 2

0 . 3

P F M 0 0 0

1 1 7

1 2 0 9 3

2 0 0 6 - 0 3 - 2 1

0

. 5

0 . 3

3 5

–

0 . 0

2 7 2

1 . 4

2

0 . 0

1 5 6

0 . 0

0 1 3

0 . 0 0

4 1

0 . 0

4 3 3

3 . 7

5

0 . 3

< 0 . 2

< 0 . 3

P F M 0 0 0

1 1 7

1 2 0 9 5

2 0 0 6 - 0 3 - 2 1

1

. 5

0 . 7

0 3

–

0 . 0

0 0 4

1 . 7

7

0 . 0

0 8 4

0 . 0

0 0 5

0 . 0 0

4 0

0 . 0

5 9 4

3 . 4

6

0 . 8

< 0 . 2

0 . 2

P F M 0 0 0

1 1 7

1 2 2 5 1

2 0 0 6 - 0 5 - 1 6

0

. 5

0 . 0

0 8 2

–

0 . 0

0 2 4

0 . 9

6

0 . 0

1 0 3

0 . 0

0 0 7

0 . 0 0

4 2

0 . 0

7 5 5

1 . 2

7

2 . 7

0 . 4

1 . 7

P F M 0 0 0

1 1 7

1 2 2 9 9

2 0 0 6 - 0 6 - 1 2

0

. 5

0 . 0

0 9 3

–

0 . 0

0 0 7

1 . 0

9

0 . 0

1 2 7

0 . 0

0 1 9

0 . 0 0

7 5

0 . 0

9 6 0

0 . 3

8 8

4 . 8

0 . 5

< 0 . 2

P F M 1 0 2

2 7 0

1 2 2 3 3

2 0 0 6 - 0 4 - 1 8

0

. 5

0 . 0

3 0 4

0 . 0

0 3 6

0 . 1

5 4

0 . 9

9

0 . 0

1 4 7

0 . 0

0 1 1

0 . 0 0

7 2

0 . 0

4 6 4

3 . 7

2

0 . 5

< 0 . 2

< 0 . 2

I d c o d e

S a m p l e

n o .

S a m p l i n g

d a t e

D

e p t h

m

P O C

m g / L

T O C

m g / L

D O C

m g / L

D I C m g / L

O 2 m g / L

A b s . c o e f f .

m g / L

P F M 0 0 0

1 1 7

1 2 0 3 1

2 0 0 5 - 1 2 - 2 0

1

. 5

0 . 2

7

1 7 . 2

1 7 . 0

2 2 . 7

–

0 . 8

4

P F M 0 0 0

1 1 7

1 2 0 3 3

2 0 0 6 - 0 1 - 2 4

0

. 5

0 . 3

6

1 9 . 3

1 8 . 8

2 6 . 8

1 . 8

0

2 . 6

8

P F M 0 0 0

1 1 7

1 2 0 4 8

2 0 0 6 - 0 1 - 2 4

1

. 5

0 . 2

9

1 9 . 2

1 9 . 1

2 3 . 0

–

1 . 3

8

P F M 0 0 0

1 1 7

1 2 0 8 7

2 0 0 6 - 0 2 - 2 1

0

. 5

0 . 2

6

1 8 . 5

1 8 . 5

2 7 . 3

–

1 . 0

8

P F M 0 0 0

1 1 7

1 2 0 8 8

2 0 0 6 - 0 2 - 2 1

1

. 5

0 . 2

8

1 8 . 4

1 7 . 0

3 0 . 0

2 . 0

0

2 . 1

0

P F M 0 0 0

1 1 7

1 2 0 9 3

2 0 0 6 - 0 3 - 2 1

0

. 5

0 . 2

8

2 3 . 3

2 2 . 6

2 9 . 5

0 . 5

0

2 . 9

4

P F M 0 0 0

1 1 7

1 2 0 9 5

2 0 0 6 - 0 3 - 2 1

1

. 5

0 . 4

6

2 0 . 1

2 0 . 6

3 2 . 6

< 0 . 2

2 . 5

6

P F M 0 0 0

1 1 7

1 2 2 5 1

2 0 0 6 - 0 5 - 1 6

0

. 5

0 . 5

3

1 7 . 9

1 8 . 2

2 4 . 6

–

1 . 9

2

P F M 0 0 0

1 1 7

1 2 2 9 9

2 0 0 6 - 0 6 - 1 2

0

. 5

0 . 6

7

1 7 . 8

1 7 . 7

1 8 . 9

–

1 . 8

0

P F M 1 0 2

2 7 0

1 2 2 3 3

2 0 0 6 - 0 4 - 1 8

0

. 5

0 . 2

9

1 8 . 9

1 8 . 3

2 5 . 1

–

3 . 4

0

C h l . A =

C h l o r o p h y l l a .

C h l . C =

C h l o r o p h y l l c .

P h e o p . = P h e o p i g m e n t .

A b s .

C o e f f . = A b s o r p t i o n C o e f f i c i e n t 4 3 6 n m ( c o

l o u r ) .



89

Table A5-3. Isotopes I (H-, B-, S- and C-isotopes).

Idcode Sample

no

Depth

m

Sampling

date

14C

pmC

δ13C

‰ PDB

δ34S

‰ CDT

δ37Cl

‰ SMOC

87Sr/86Sr

no unit

δ2H

‰ SMOW

3H

TU

δ18O

‰ SMOW

PFM000062 8936 0.5 2005-07-11 104.49 –2.23 19.5 –0.01 0.70947 –58.3 12.4 –8.2

PFM000062 8971 0.5 2005-10-03 – – – – – –65.9 13.1 –7.9

PFM000062 12234 0.5 2006-04-18 – – – – – –63.7 13.4 –8.2

PFM000066 8934 0.1 2005-07-12 – – – – – –66.9 12.5 –9.1

PFM000066 12042 0.1 2006-01-23 – – – – – –85.0 10.6 –12.2

PFM000066 12235 0.1 2006-04-18 – – – – – –90.8 10.7 –12.6

PFM000068 8932 0.1 2005-07-12 – – – – – –70.7 13.3 –10.3

PFM000068 8977 0.1 2005-10-03 – – – – – –77.1 13.4 –9.8

PFM000068 12045 0.1 2006-01-23 – – – – – –76.2 12.1 –10.3

PFM000068 12237 0.1 2006-04-19 – – – – – –89.8 12.4 –12.2

PFM000069 8931 0.1 2005-07-12 – – – – – –69.6 12.0 –10.3

PFM000069 8974 0.1 2005-10-03 – – – – – –77.5 12.9 –9.9

PFM000069 12043 0.1 2006-01-23 – – – – – –86.1 10.7 –12.3

PFM000069 12230 0.1 2006-04-19 – – – – – –92.2 12.1 –12.6

PFM000070 8933 0.1 2005-07-12 – – – – – –56.4 11.4 –7.2

PFM000070 8975 0.1 2005-10-04 – – – – – –64.9 11.9 –6.5

PFM000070 12069 0.1 2006-01-24 – – – – – –64.2 11.8 –7.6

PFM000070 12240 0.1 2006-04-19 – – – – – –85.2 11.1 –12.3

PFM000074 8937 0.5 2005-07-11 115.77 –7.23 3.9 0.3 0.72274 –68.2 12.3 –9.4

PFM000074 8976 0.5 2005-10-03 – – – – – –69.7 11.7 –8.3

PFM000074 12032 0.5 2006-01-24 – – – – – –86.6 10.3 –12.1

PFM000074 12232 0.5 2006-04-18 – – – – – –90.3 10.6 –12.5

PFM000082 12046 0.5 2006-01-23 – – – – – –61.3 11.7 –8.2

PFM000082 12030 6 2006-01-23 – – – – – –63.3 10.7 –8.2PFM000107 8938 0.5 2005-07-11 111.01 –5.52 13.3 –0.03 0.71808 –51.8 10.4 –6.1

PFM000107 8970 0.5 2005-10-03 – – – – – –56.7 11.7 –5.0

PFM000107 12047 0.5 2006-01-23 – – – – – –72.1 11.7 –9.5

PFM000107 12044 1 2006-01-23 – – – – – –59.4 13.2 –7.6

PFM000117 8935 0.5 2005-07-11 107.96 –9.64 3.8 0.42 0.72443 –53.8 10.8 –6.4

PFM000117 8973 0.5 2005-10-04 – – – – – –57.0 13.4 –5.4

PFM000117 12048 0.5 2006-01-24 – – – – – –59.3 12.6 –7.4

PFM000117 12033 1.5 2006-01-24 – – – – – –65.9 10.3 –8.1

PFM102269 8886 0.5 2005-07-12 – – – – – –59.8 120.7 –8.2

PFM102269 12068 0.5 2006-01-24 – – – – – – 12.7 –

PFM102269 12077 0.5 2006-02-21 – – – – – – 9.1 –

PFM102269 12063 0.5 2006-03-21 – – – – – – 12.9 –

PFM102269 12238 0.5 2006-04-19 – – – – – – 11.7 –

PFM102269 12254 0.5 2006-05-15 – – – – – – 12.2 –

PFM102269 12305 0.5 2006-06-12 – – – – – – 11.9 –

PFM102270 12233 0.5 2006-04-18 – – – – – –88.1 10.3 –12.0

The units are explained in Appendix 1.



90

T a b l e A 5

- 4 . T r a c e e l e m e n t s .

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

A l µ g / L

C d µ g / L

C r µ g / L

C u µ g / L

C o µ g / L

H g µ g / L

N i µ g / L

Z n µ g / L

P b µ g / L

V µ g / L

M o µ g / L

N b µ g / L

B a µ g / L

P F M 0 0 0 0 6 2

8 9 3 6

0 . 5

2 0 0 5 - 0 7 - 1 1

8 6

0 . 0

8 5 2

0 . 1

2 6

0 . 5 9

< 0 . 0

4

< 0 . 0

0 2

0 . 7

1 5

< 2

3 . 1

0

0 . 1

8

1 . 7

7

–

1 9 . 4

P F M 0 0 0 0 6 2

8 9 7 1

0 . 5

2 0 0 5 - 1 0 - 0 3

6 . 5

6

0 . 0

5 9 4

0 . 5

0 0

0 . 9 8

0 . 0

9 6

0 . 0

0 9 2

1 . 4

7

2 . 3

3

1 . 0

1

0 . 9

9

1 . 7

4

–

1 8 . 1

P F M 0 0 0 0 6 2

1 2 2 3 4

0 . 5

2 0 0 6 - 0 4 - 1 8

3 . 0

0

0 . 0

2 2 8

0 . 1

1 1

1 . 0 2

< 0 . 0

2

< 0 . 0

0 2

1 . 1

7

1 . 2

9

0 . 1

7 0

0 . 1

1

1 . 7

2

–

1 6 . 5

P F M 0 0 0 0 6 6

1 2 0 4 2

0 . 1

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

0 . 0

1 1

–

P F M 0 0 0 0 6 8

1 2 0 4 5

0 . 1

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

0 . 0

1 2

–

P F M 0 0 0 0 6 9

1 2 0 4 3

0 . 1

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

0 . 0

1 4

–

P F M 0 0 0 0 7 0

1 2 0 6 9

0 . 1

2 0 0 6 - 0 1 - 2 4

–

–

–

–

–

–

–

–

–

–

–

0 . 0

0 5

–

P F M 0 0 0 0 7 4

8 9 3 7

0 . 5

2 0 0 5 - 0 7 - 1 1

1 2 8

0 . 0

2 1 0

0 . 1

4 4

0 . 3 4

0 . 0

5 7

< 0 . 0

0 2

0 . 3

1 8

0 . 8

0 . 1

7 3

0 . 2

6

0 . 3

5

–

3 3 . 4

P F M 0 0 0 0 7 4

8 9 7 6

0 . 5

2 0 0 5 - 1 0 - 0 3

1 2 . 3

0 . 0

0 4 7

0 . 0

9 4

0 . 1 7

0 . 0

5 5

0 . 0

0 4 8

0 . 3

7 6

1 . 4

6

0 . 0

6 6

0 . 2

0

0 . 3

7 4

–

2 8 . 1

P F M 0 0 0 0 7 4

1 2 0 3 2

0 . 5

2 0 0 6 - 0 1 - 2 4

1 8 9

< 0 . 0

0 2

0 . 2

4 3

1 . 3 8

0 . 0

9 2

0 . 0

0 3 9

0 . 7

3 9

1 . 2

4

0 . 1

6 0

0 . 2

1

0 . 4

1 6

0 . 0

1 1

2 9 . 5

P F M 0 0 0 0 7 4

1 2 2 3 2

0 . 5

2 0 0 6 - 0 4 - 1 8

2 2 . 9

0 . 0

0 5 1

0 . 1

6 3

1 . 7 3

0 . 0

5 1

0 . 0

0 2 4

0 . 4

6 8

1 . 1

0

0 . 0

6 4

0 . 2

3

0 . 4

8

–

1 7 . 0

P F M 0 0 0 0 8 2

1 2 0 4 6

0 . 5

2 0 0 6 - 0 1 - 2 3

5 . 9

8

0 . 0

3 6 1

0 . 1

6 0

3 . 4 1

0 . 0

5 3

0 . 0

0 3 5

1 . 6

1

1 . 1

5

0 . 2

0 9

6 . 2

7

1 . 5

3

< 0 . 0

0 5

1 6 . 4

P F M 0 0 0 0 8 2

1 2 0 3 0

6

2 0 0 6 - 0 1 - 2 3

1 5 6

0 . 0

3 2 6

0 . 2

4 4

4 . 2 9

< 0 . 0

2

< 0 . 0

0 2

1 . 0

2

1 . 1

0

0 . 2

8 6

1 4 . 0

1 . 5

4

0 . 0

0 7

1 6 . 5

P F M 0 0 0 1 0 7

8 9 3 8

0 . 5

2 0 0 5 - 0 7 - 1 1

8 3 . 7

0 . 0

2 8 1

0 . 1

3 4

0 . 6 4

0 . 0

5 9

< 0 . 0

0 2

0 . 4

1 6

0 . 4

9

0 . 3

6 9

0 . 4

5

0 . 7

8 8

–

2 2 . 7

P F M 0 0 0 1 0 7

8 9 7 0

0 . 5

2 0 0 5 - 1 0 - 0 3

1 5 . 6

0 . 0

4 7 4

0 . 1

0 7

0 . 4 5

0 . 0

7 1

0 . 0

0 4 8

0 . 5

2 6

0 . 9

6

0 . 4

1 1

0 . 2

6

0 . 7

0 5

–

1 8 . 8

P F M 0 0 0 1 0 7

1 2 0 4 4

1

2 0 0 6 - 0 1 - 2 3

7 . 6

2

< 0 . 0

0 2

0 . 1

0 5

0 . 4 4

0 . 0

5 8

0 . 0

0 3 7

0 . 2

6 9

1 . 0

9

0 . 1

0 3

0 . 1

4

0 . 3

5 4

0 . 0

0 8

2 6 . 1

P F M 0 0 0 1 0 7

1 2 0 4 7

0 . 5

2 0 0 6 - 0 1 - 2 3

1 7 . 1

0 . 0

0 2 2

0 . 1

6 3

1 . 1 9

0 . 1

1 0

0 . 0

0 5 2

0 . 6

6 2

1 . 5

9

0 . 1

0 8

0 . 2

1

0 . 4

2 6

0 . 0

1 2

2 4 . 9

P F M 0 0 0 1 1 7

8 9 3 5

0 . 5

2 0 0 5 - 0 7 - 1 1

3 6 . 6

0 . 0

1 6 4

0 . 0

7 7

0 . 4 5

0 . 0

3 9

< 0 . 0

0 2

0 . 2

2 9

0 . 3

8

0 . 0

4 8

0 . 2

7

0 . 2

7 2

–

1 0 . 5

P F M 0 0 0 1 1 7

8 9 7 3

0 . 5

2 0 0 5 - 1 0 - 0 4

1 9 . 1

0 . 0

1 0 5

0 . 0

9 1

0 . 3 1

0 . 0

3 6

< 0 . 0

0 2

0 . 2

8 2

1 . 1

9

0 . 0

5 6

0 . 2

0

0 . 1

9 6

–

9 . 5

P F M 0 0 0 1 1 7

1 2 0 3 3

1 . 5

2 0 0 6 - 0 1 - 2 4

1 1 9

< 0 . 0

0 2

0 . 1

4 3

0 . 8 7

0 . 0

5 7

0 . 0

0 3 9

0 . 3

2 8

0 . 6

6

0 . 0

8 6

0 . 1

8

0 . 2

1 1

0 . 0

0 8

2 1 . 0

P F M 0 0 0 1 1 7

1 2 0 4 8

0 . 5

2 0 0 6 - 0 1 - 2 4

5 . 8

3

0 . 0

0 5 8

0 . 0

6 2

0 . 5

0 . 0

3 2

< 0 . 0

0 2

0 . 2

8 1

2 . 1

4

0 . 0

2 7

0 . 2

0

0 . 2

3 4

0 . 0

0 5

1 5 . 5

P F M 1 0 2 2 7 0

1 2 2 3 3

0 . 5

2 0 0 6 - 0 4 - 1 8

3 7 . 3

0 . 0

0 8 1

0 . 1

8 9

1 . 3 6

0 . 0

7 2

0 . 0

0 2 7

0 . 7

9 6

2 . 3

9

0 . 1

0 0

0 . 2

5

0 . 6

7 8

–

1 6 . 2



91

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

A s µ g / L

U µ g / L

T h µ g / L

S c µ g / L

R b µ g / L

Y µ g / L

Z r µ g / L

S b µ g / L

C s µ g / L

L a µ g / L

H f µ g / L

T l µ g / L

C e µ g / L

P F M 0 0 0 0

6 2

8 9 3 6

0 . 5

2 0 0 5 - 0 7 - 1 1

0 . 8

0

0 . 7

0 0

< 0 . 4

< 0 . 8

1 8 . 7

0 . 0

7 5

< 0 . 2

< 0 . 2

< 0 . 2

< 0 . 0

4

< 0 . 0

4

< 0 . 2

0 . 0

4 1

P F M 0 0 0 0

6 2

8 9 7 1

0 . 5

2 0 0 5 - 1 0 - 0 3

0 . 7

0

0 . 6

3 4

< 0 . 2

< 0 . 4

2 2 . 3

0 . 0

5 6

< 0 . 1

0 . 2

1

0 . 2

1

0 . 0

7 3 6

< 0 . 0

2

< 0 . 0

3

0 . 1

1 1

P F M 0 0 0 0

6 2

1 2 2 3 4

0 . 5

2 0 0 6 - 0 4 - 1 8

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0

6 6

1 2 0 4 2

0 . 1

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 6 8

1 2 0 4 5

0 . 1

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 6 9

1 2 0 4 3

0 . 1

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 7 0

1 2 0 6 9

0 . 1

2 0 0 6 - 0 1 - 2 4

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 7 4

8 9 3 7

0 . 5

2 0 0 5 - 0 7 - 1 1

0 . 3

5

1 . 4

1

< 0 . 0

2

< 0 . 0

5

1 . 8

6

0 . 1

1 2

0 . 0

7

0 . 0

6

< 0 . 0

3

0 . 0

5 0 1

0 . 0

0 6

< 0 . 0

3

0 . 0

7 2

P F M 0 0 0 0 7 4

8 9 7 6

0 . 5

2 0 0 5 - 1 0 - 0 3

0 . 3

0

1 . 5

8

< 0 . 0

2

< 0 . 0

5

1 . 8

1

0 . 0

4 8

0 . 0

9

0 . 0

4

< 0 . 0

3

0 . 0

1 9 0

< 0 . 0

0 5

0 . 0

1 2

0 . 0

2 6

P F M 0 0 0 0 7 4

1 2 0 3 2

0 . 5

2 0 0 6 - 0 1 - 2 4

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 7 4

1 2 2 3 2

0 . 5

2 0 0 6 - 0 4 - 1 8

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 8 2

1 2 0 4 6

0 . 5

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 8 2

1 2 0 3 0

6

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 1 0 7

8 9 3 8

0 . 5

2 0 0 5 - 0 7 - 1 1

0 . 5

3

2 . 1

7

< 0 . 0

2

< 0 . 0

5

4 . 0

0

0 . 0

7 7

0 . 0

5

0 . 1

2

< 0 . 0

3

0 . 0

6 1 9

< 0 . 0

0 5

< 0 . 0

3

0 . 0

8 7

P F M 0 0 0 1 0 7

8 9 7 0

0 . 5

2 0 0 5 - 1 0 - 0 3

0 . 5

0

1 . 6

3

< 0 . 0

2

< 0 . 0

5

4 . 1

4

0 . 0

9 1

0 . 1

4

0 . 1

2

< 0 . 0

3

0 . 1

3 6

< 0 . 0

0 5

0 . 0

1 6

0 . 1

9 2

P F M 0 0 0 1 0 7

1 2 0 4 4

1

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 1 0 7

1 2 0 4 7

0 . 5

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 1 1 7

8 9 3 5

0 . 5

2 0 0 5 - 0 7 - 1 1

0 . 3

1

1 . 2

3

< 0 . 0

2

< 0 . 0

5

2 . 0

5

0 . 0

3 6

0 . 0

5

0 . 0

9

< 0 . 0

3

0 . 0

1 1 9

< 0 . 0

0 5

< 0 . 0

3

0 . 0

1 6

P F M 0 0 0 1 1 7

8 9 7 3

0 . 5

2 0 0 5 - 1 0 - 0 4

0 . 3

0

0 . 9

4 7

< 0 . 0

2

< 0 . 0

5

2 . 0

5

0 . 0

2 7

0 . 0

9

0 . 0

8

< 0 . 0

3

0 . 0

1 9 6

< 0 . 0

0 5

0 . 0

1 2

0 . 0

3 0

P F M 0 0 0 1 1 7

1 2 0 3 3

1 . 5

2 0 0 6 - 0 1 - 2 4

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 1 1 7

1 2 0 4 8

0 . 5

2 0 0 6 - 0 1 - 2 4

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 1 0 2 2

7 0

1 2 2 3 3

0 . 5

2 0 0 6 - 0 4 - 1 8

–

–

–

–

–

–

–

–

–

–

–

–

–



92

I d c o d e

S a m p l e

n o .

D e p t h

m

S a m p l i n g

d a t e

P r µ g / L

N d µ g / L

S m µ g / L

E u µ g / L

G d µ g / L

T b µ g / L

D y µ g / L

H o µ g / L

E r µ g / L

T m µ g / L

Y b µ g / L

L u µ g / L

I n µ g / L

P F M 0 0 0 0 6 2

8 9 3 6

0 . 5

2 0 0 5 - 0 7 - 1 1

< 0 . 0

4

< 0 . 0

4

< 0 . 0

4

< 0 . 0

4

< 0 . 0

4

< 0 . 0

4

< 0 . 0

4

< 0 . 0

4

< 0 . 0

4

< 0 . 0

4

< 0

. 0 4

< 0 . 0

4

< 0 . 2

P F M 0 0 0 0 6 2

8 9 7 1

0 . 5

2 0 0 5 - 1 0 - 0 3

0 . 0

2 7 9

< 0 . 0

2

0 . 0

2 2 8

< 0 . 0

2

0 . 0

2 4

< 0 . 0

2

0 . 0

2 3 6

0 . 0

2 4 3

0 . 0

2 2

< 0 . 0

2

0

. 0 2 3 6

0 . 0

8 7 5

< 0 . 2

P F M 0 0 0 0 6 2

1 2 2 3 4

0 . 5

2 0 0 6 - 0 4 - 1 8

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 6 6

1 2 0 4 2

0 . 1

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 6 8

1 2 0 4 5

0 . 1

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 6 9

1 2 0 4 3

0 . 1

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 7 0

1 2 0 6 9

0 . 1

2 0 0 6 - 0 1 - 2 4

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 7 4

8 9 3 7

0 . 5

2 0 0 5 - 0 7 - 1 1

0 . 0

1 3 9

0 . 0

5 9

0 . 0

1 2 6

0 . 0

0 6 6

0 . 0

1 5

< 0 . 0

5

0 . 0

1 3 8

< 0 . 0

0 5

0 . 0

1

< 0 . 0

0 5

0

. 0 1 1 0

< 0 . 0

0 5

< 0 . 0

5

P F M 0 0 0 0 7 4

8 9 7 6

0 . 5

2 0 0 5 - 1 0 - 0 3

0 . 0

0 5 1

0 . 0

1 6

< 0 . 0

0 5

< 0 . 0

0 5

0 . 0

0 7

< 0 . 0

5

0 . 0

0 7 7

< 0 . 0

0 5

0 . 0

0 6

< 0 . 0

0 5

0

. 0 0 6 2

0 . 0

0 7 2

< 0 . 0

5

P F M 0 0 0 0 7 4

1 2 0 3 2

0 . 5

2 0 0 6 - 0 1 - 2 4

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 7 4

1 2 2 3 2

0 . 5

2 0 0 6 - 0 4 - 1 8

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 8 2

1 2 0 4 6

0 . 5

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 0 8 2

1 2 0 3 0

6

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 1 0 7

8 9 3 8

0 . 5

2 0 0 5 - 0 7 - 1 1

0 . 0

1 4 3

0 . 0

5 7

0 . 0

1 0 1

0 . 0

0 5 2

0 . 0

1 2

< 0 . 0

5

0 . 0

1 0 5

< 0 . 0

0 5

0 . 0

0 6 6

< 0 . 0

0 5

0

. 0 0 7 9

< 0 . 0

0 5

< 0 . 0

5

P F M 0 0 0 1 0 7

8 9 7 0

0 . 5

2 0 0 5 - 1 0 - 0 3

0 . 0

4 1 9

0 . 0

9 5

0 . 0

3 9 9

0 . 0

2 0 6

0 . 0

3 6

< 0 . 0

5

0 . 0

3 3 2

0 . 0

2 2 7

0 . 0

2 8 5

0 . 0

2 0 5

0

. 0 2 4 9

0 . 1

1 9

0 . 0

6 1

P F M 0 0 0 1 0 7

1 2 0 4 4

1

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 1 0 7

1 2 0 4 7

0 . 5

2 0 0 6 - 0 1 - 2 3

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 1 1 7

8 9 3 5

0 . 5

2 0 0 5 - 0 7 - 1 1

< 0 . 0

0 5

0 . 0

1 7

< 0 . 0

0 5

< 0 . 0

0 5

< 0 . 0

0 5

< 0 . 0

5

< 0 . 0

0 5

< 0 . 0

0 5

< 0 . 0

0 5

< 0 . 0

0 5

< 0

. 0 0 5

< 0 . 0

0 5

< 0 . 0

5

P F M 0 0 0 1 1 7

8 9 7 3

0 . 5

2 0 0 5 - 1 0 - 0 4

0 . 0

0 6 7

0 . 0

0 9

0 . 0

0 5 5

< 0 . 0

0 5

< 0 . 0

0 5

< 0 . 0

5

0 . 0

0 6 0

< 0 . 0

0 5

< 0 . 0

0 5

< 0 . 0

0 5

< 0

. 0 0 5

0 . 0

1 9 0

< 0 . 0

5

P F M 0 0 0 1 1 7

1 2 0 3 3

1 . 5

2 0 0 6 - 0 1 - 2 4

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 0 0 0 1 1 7

1 2 0 4 8

0 . 5

2 0 0 6 - 0 1 - 2 4

–

–

–

–

–

–

–

–

–

–

–

–

–

P F M 1 0 2 2 7 0

1 2 2 3 3

0 . 5

2 0 0 6 - 0 4 - 1 8

–

–

–

–

–

–

–

–

–

–

–

–

–

< “ v a l u e ” = b e l o w r e p o r t i n g l i m i t .

Y e l l o w m a

r k e d v a l u e s a r e p r o b a b l y a f f e c t e d b y c o

n t a m i n a t i o n .



Table A5-5. Isotopes II (U-, Th-, Ra- and Rn-isotopes).

Idcode Sample

no.

Depth

m

Sampling

date

238U

mBq/L

234U

mBq/L

230Th

mBq/L

226Ra

Bq/L

222Rn

Bq/L

PFM000062 8936 0.5 2005-07-11 7.4 9.4 1.5 0.031 0.009

PFM000074 8937 0.5 2005-07-11 14.9 15.7 0.3 0.038 0.010

PFM000107 8938 0.5 2005-07-11 25.3 27.4 0.1 < 0.03 –

PFM000117 8935 0.5 2005-07-11 15.3 17.5 < 0.35 < 0.025 –

HQ Nilsson Et Al (2007) Forsmark Site Investigation - Sampling and Analyses of Surface Waters

Documents