Guideline Document Number ESS-0038692 Date Apr 15, 2016 Revision 1 State Released Classification Page 1 (17) Chess Controlled Core Ed: 1.0 Template Active Date: 11 Mar 2014 ESS Guideline for Oxygen Deficiency Hazard (ODH) Name Owners B. Winér; Occupational Health & Safety Engineer, E S & H Division Reviewers D. Phan; Accelerator Safety Engineer Approvers P.Jacobsson; Head of E S & H Division
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TwofactorsmakeOxygenDeficiencyHazards (ODH)sodangerous.Thefirst is the largevolumeratiobetweenacryogenicliquidanditsgaseousstateatroomtemperatureandpressure.Asanexample1litreofliquidnitrogenwillresultin700litresofnitrogengasatroomtemperatureandpressure.Thus,ittakesasmallamountofcryogenicliquidventedinto a space to reduce the oxygen concentrations to dangerous levels. Second, in lowenough oxygen concentrations the first physiological symptoms of a problem can beunconsciousness,comaanddeath.Unconsciousnesscanoccurinlessthan30seconds.
NouseofasphyxiantcryogenicfluidsorcompressedgasesispermittedatESSwithoutaformal evaluation of the ODH Class which shall be conducted through a specific ODHprocessforallactivitieswhicharephysicallycapableofexposingindividualstoanoxygendeficiency.
The ODH process can be divided into three main steps as shown in the followingflowchart (Figure 1). Note that the process is built around quantitative assessmentfollowed by independent expert review that will provide final clearance of theactivity/area/equipmentbeforeoperation.
Step1:ODHassessment5.1.AnyareaatESSknowntohaveanoxygenconcentration<18%(duringnormaland/oroff-normal operation) is considered to be an oxygen deficient area. All areas intended forhumanoccupancyatESSshallhaveanenvironmentorenvironmentalcontrolsthatwillnormallyensurethattheconcentrationofoxygenremains≥18%.
If an area contains equipment or sources of inert gas that could lead to a significantdecrease inoxygenconcentration, additionalmeasures shallbe taken to reduce risk topersonnel.ThegoalsofanODHassessmentaretoevaluatetherisklevelinagivenarea,
Thepurposeof theCERN’sODHassessmentmethodology [4] is toprovide toanynon-cryogenic expert with a fast and simple steady-state calculation model aiming atassessingtheO2concentrationremainingintheatmosphereofaspecificareaincaseofacompletereleaseofasphyxiantfluidwithoutconsideringanyventilationrate,leakrateortimeparameter.
ODHAssessmentEquations5.1.1.1.
TheO2 concentrationestimation ina confinedvolume is calculatedusing the followingequation(Table1):
Table1-ODHAssessmentequation(CERN'smodel)
Formula Definitions
C=oxygenconcentrationaftertherelease[%]V=confinedvolume[m3]Vgas = volume of gas discharged at room’s temperatureandpressure[m3]
Remark:forlargeenclosurespacessuchasexperimentalhalls,ODHmightnotrepresenta direct threat for people safety considering an entire homogenousmixture.However,there could be some localized areas with oxygen depletion. Therefore, wheneverapplicableasmallerenclosurespacecouldbeconsideredfortheODHassessment.
ODHClass5.1.1.2.
The ODH assessment carried for every activity/area/installation involving the use ofasphyxiant fluids allows determining an ODH Class that is calculated based on theselectionofthe“mostcrediblescenario”definedwiththehelpoftherelevantexperts.
Thepurpose of the FERMILAB’sODHassessmentmethodology [4] is to provide to anynon-cryogenic expert with a dynamic calculation model aiming at assessing the O2concentration remaining in the atmosphere of a specific area during and after anaccidentalreleaseofasphyxiantfluidconsideringtheventilationrate,leakrateandtimeparameter.
2AccordingtotheODHprocess,dependingofthecomplexityofthecasetheCryogenicSafetyCommitteecanrequireafurtherODHanalysisandadditionalcontrolmeasuresevenifthesituationhasbeeninitiallyassessed as “ODH Class 0”, e.g whenever ventilation, leak rate, time parameter or confined volumeconfigurationhaveanimpactonthefinalODH
# Time Mixing Ventilation Type Diff.eq. Concentration
TheODHClassisbaseduponthemostsevererisk:thelikelihoodthatafatalitywilloccur.Sincethe levelof risk is tiedtotheareaandthenatureof theactivity, thefatalityrateshallbedeterminedonanactivity-by-activitybasis.Foragivenactivity/area/equipment,several events may cause an oxygen deficiency. Each event has an expected rate ofoccurrence and each occurrence has an expected probability of causing a fatality.However,forthesakeofsimplificationonlythe“mostcrediblescenario”isconsideredforthe ODH assessment of every activity/area/equipment involving the use of asphyxiantfluids.Theoxygendeficiencyhazardfatalityrateisdefinedasfollows:
Table4–ODHfatalityrate(FERMILAB'smodel)
Formula Definitions
𝜙=theODHfatalityrate(perhour)Pi = the expected failure rate of the “most crediblescenario”(perhour)Fi = the probability of a fatality due to “most crediblescenario”
When possible, the value of Pi shall be determined by operating experience at ESS;otherwise data from similar systems elsewhere or other relevant values shall be used.EstimatesofequipmentfailureratesaregiveninAppendix8.1.
The value of Fi is the probability that a personwill die if the “most credible scenario”occurs.Thevaluedependsontheoxygenconcentration.Forconvenienceofcalculation,an approximate relationship between the value of Fi and the lowest attainable oxygenconcentrationhasbeendeveloped(Figure2).
Itisassumedthatallexposuresto18%oxygenorlowerdocontributetofatalityandthevalue of Fi is designed to reflect this dependence. If the lowest attainable oxygenconcentrationis18%,thenthevalueofFiis10-7.Thisvaluewouldcause𝜙tobe10-7perhouriftheexpectedrateofoccurrenceoftheeventwere1perhour.
At decreasing concentrations, the value of Fi should increase until, at some point, theprobability of fatality becomes unity. That point was selected to be 8.8% oxygen, theconcentrationatwhichoneminuteofconsciousnessisexpected.
The risk assessment should also consider thebenefit of existing active control systemssuchasforcedventilationoranysupplyshut-offvalvesthatareautomaticallyactivatedby area monitor readings or system failure indicators. The control systems must bedesignedtobeactivatedbeforetheoxygenconcentrationintheareadropsbelow18%.
Step2:Definitionofcontrolmeasures5.2.Controlmeasures appropriate to theODHClass shall be implemented as stated in theODHassessmentandTechnicalAppendix.
Equipment at ESS shall be designed and installed to ensure that areas intended forhumanentryduringnormaloperationarenothigherthanODHClass2.Nohumanaccesswill be allowed in areaswith anODH Class higher than 2 unless controlmeasures areimplementedinordertoreducetheODHClasstoanacceptablelevel,i.e.ODHClass0,1or2.
Asfaraspossible,preventiveandprotectivemeasuresshallbeimplementedinafashionthatreducestheexcessriskoffatalityfromexposuretoanoxygendeficientatmosphereto no more than 10-7 per hour. In parallel of the ODH assessment, it is highlyrecommendedtocoverthefollowingtopicsinaworkinggroupinvolvingalltherelevantstakeholders:
TechnicalSafetymeasuresWarningsigns X X XVentilation * *Area(fixed)OxygenMonitoring * X X
OrganizationalSafetymeasuresMedicalapprovalasODHqualified * *ODHtraining(e-learning) X X XPersonaloxygenmonitor X XSelf-rescuemask * *Presenceofminimum2persons X
AdministrativeSafetymeasuresAccessrestrictedtoauthorizedpersonnelonly X XEmergencyprocedure X XOperatingprocedure X X X*TobeevaluatedcasebycasewiththehelpofES&H
Remark:Note that theabove-mentionedtable isnon-exhaustiveandadditionalcontrolmeasurescanberequiredbytheCryogenicSafetyCommitteeorES&Hforspecificcases.
ODHTraining5.2.2.
IndividualsengagedinODHclass0orgreateroperationsshallreceivetraininginoxygendeficiency hazards and associated safety measures. The following topics should becovered.
The following flow chart (Figure 3) shows the process for conducting emergencyevacuationand rescue.Underno circumstances shall staff enteror re-enter a space inwhich an ODH alarm is sounding. Entry under these conditions shall only be done byqualifiedrescuepersonnelsuchastheFireDepartment.
Step3:Reviewandapproval5.3.Every ODH assessment carried out at ESS; independently from its results, shall besubmittedtoaCryogenicSafetyCommitteeforreviewandapprovalinordertoaddressthefollowingaspects:
Activity leadersandequipment/area responsible: responsible for theODHassessmentandimplementationofcontrolmeasuresrelatedtotheiractivityandequipment/area.
Operators: provide relevant information and knowledge to the ODH assessmentregardingtheactivity/equipment/areatobeanalysed.
ES&HDivision: provides help and support on theODHprocess from the choice of therelevantmethodologytobecarriedoutfortheODHassessmenttotheimplementationofcontrolmeasuressuchastrainingandPersonalProtectiveEquipment.
CryogenicSafetyCommittee(CSC):reviewsandapproveseveryactivity/equipment/areainvolving the use of asphyxiant agents. The review and approval covers the ODHassessment, the selection of control measures as well as the content of the Safetydocumentation.
Safetydocumentation6.2.Everyactivity leaderandequipment/arearesponsibleshalldemonstratethecomplianceof their activity/equipment/area involving the use of asphyxiant agent with applicableregulationsandstandards.Forthispurpose,theyshallprepareandsubmitthefollowingsafetydocumentationtotheCryogenicSafetyCommitteeaswellastoES&Hforreviewandapproval:
1x10-3 Selection of a switch (or pair of switches) dissimilar in shape or location to the desiredswitch(orpairofswitches),assumingnodecisionerror.Forexample,operatoractuateslargehandledswitchratherthansmallswitch.
1x10-2 General human error of omissionwhere there is no display in the control room of thestatusof the itemomitted,e.g., failuretoreturnmanuallyoperatedtestvalvetoproperconfigurationaftermaintenance.
3x10-3 Errorsofomission,where the itemsbeingomittedareembedded in aprocedure ratherthanattheendasabove.
1/x Giventhatanoperatorisreachingforanincorrectswitch(orpairofswitches),heselectsaparticularsimilarappearingswitch(orpairofswitches),wherex=thenumberofincorrectswitches(orpairofswitches)adjacenttothedesiredswitch(orpairofswitches).The1/xapplies up to 5 or 6 items. After that point the error ratewould be lower because theoperatorwouldtakemoretimetosearch.Withupto5or6itemshedoesn'texpecttobewrongandthereforeismorelikelytodolessdeliberatesearching.
1x10-1 Monitor or inspector fails to recognize initial error by operator. Note: With continuingfeedbackoftheerrorontheannunciatorpanel,thehigherrorratewouldnotapply.
1x10-1 Personnelondifferentwork shift fail to check conditionofhardwareunless requiredbycheckorwrittendirective.
5x10-1 Monitor fails to detect undesired position of valves, etc., during general walk-aroundinspection,assumingnochecklistisused.
0.2-0.3 General error rate given veryhigh stress levelswheredangerousactivities areoccurringrapidly.
2(n-1)x Givenseveretimestress,as in trying tocompensate foranerrormade inanemergencysituation, the initial error rate, x, for an activity doubles for each attempt, n, after apreviousincorrectattempt,untilthelimitingconditionofanerrorrateof1.0isreachedoruntil time runs out. This limiting condition corresponds to an individual's becomingcompletelydisorganizedorineffective.