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Global Technical InstituteL-2/26 Shah Faisal Colony No-2 Karachi, Pakistan,
Contact: +92213-4941!, +92321-23"3#62
MCQ’sFi$% &%ar Pa'%rs
1( )h% 'roc%ss in *hich a soli ir%ctly chan%s to $a'ors *ithot .%ltin is call% (
0$a'oration, Con%nsation, Sli.ation
2( )h% oiation n.%r o5 P in P3-4 is (
03+, +, 3-
3( )h% '7 o5 "(""1 8 7Cl is (
02, 4, 3
4( K 0 rat% constant is %'%n%nt on (
0t%.'%ratr%, conc%ntration, $ol.%
( )h% ni$%rsal inicator in *at%r sho*s th% color (
0r%, r%%n, l%
6( )h% '7 o5 loo is (
0#(3, !(4, (6
#( )h% oiation 'ot%ntial o5 hyro%n %l%ctro% is (
0"(" $olt, +"(#6$olt, -"(36$olt
!( ant. n.%r %scri%s th% sha'% o5 a .ol%cl%(
0Prici'al, ;i.thal, S'in
9( n orital can ha$% th% .ai.. n.%r o5 t*o %l%ctrons t *ith o''osit% s'in, it is call% (
0Pali<s clsion Princi'l%, 7n<s =l%, 5a Princi'l%
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1"( >h%n a-'articl% is %.itt% 5ro. th% ncl%s o5 raioacti$% %l%.%nt, th% .ass n.%r o5 th%ato. (
0?ncr%as%s, @%cr%as%s, @o%s not chan%
11( @issociation o5 Kcl3 is a 'roc%ss(
0=%$%rsil%, ?rr%$%rsil%
12( )h% %/. ratio o5 catho% rays is th% *h%n 7yro%n is tak%n in th% ischar%t%(
0Lo*%st, 7ih%st
13( )h% n%ati$% ion t%ns to %'an *ith th% o5 n%ati$% chan% on it(
0@%cr%as%s, ?ncr%as%s
14( ?onic co.'ons ha$% .%ltin 'oints(
0Lo*, 7ih
1( )h% allotro'ic 5or.s o5 an %l%.%nt ar% call% (
0Poly.or'hs, ?so.or'hs
16( solt% A%ro is %al to (
02#3(16BC, -2#3(16BC
1#( )h% co.'ons ha$in hyro%n on %n%rally ha$% oilin 'oints(
07ih, Lo*
1!( Sr5ac% t%nsion *ith th% ris% o5 t%.'%ratr%(
0?ncr%as%s, @%cr%as%s
19( 8%rcry 5or.s .%niscs in a lass t%(
0conca$%, con$%
2"( )h% r%actions *ith th% hih $al% o5 %n%ry o5 acti$ation ar% (
0slo*, 5ast21( 2(""" has/ha$% sini5icant 5ir%0s(
01, 4
22( + P is call% (
0ntro'y, nthal'y
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23( )h% short%r th% on l%nth in a .ol%cl%, th% *ill % on %n%ry(
0L%ss%r, Dr%at%r
24( Positi$% rays ar% 'roc% 5ro. (
0ano%, Catho%, ?oni;ation o5 as in a ischar% t%2( o5 th% 5ollo*in contains th% 5%*%r n.%r o5 .ol%cl%s(
01 . o5 hyro%n, 4 . o5 oy%n, 2 . o5 nitro%n
26( th% tr% stat%.%nt aot th% a$%ra% s'%% o5 th% .ol%cl%s o5 hyro%n, oy%n annitro%n con5in% in a contain%r is (
07yro%n is ick%r, y%n is ick%r, )h% .ol%cl%s o5 all th% as%s ha$% th% sa.% a$%ra%s'%%
2#( )h% corr%ct stat%.%nt aot th% lass is (
0?t is crystallin% soli, ?ts ato.s ar% arran% in an or%rly 5ashion, ?t is a s'%r cool% lii
2!( >h%n a sstanc% that has asor% %n%ry %.its it in th% 5or. o5 raiation th% s'%ctr.otain% is (
0Continos S'%ctr., Lin% S'%ctr., .ission S'%ctr.
29( o5 th% o$%rla' 5or.s stron on(
0S-S, P-S, P-P
3"( co.'on has a r%at%r anl% %t*%%n a co$al%nt on(072, N73, C2
31( >h%n soi. chlori% is .i% in *at%r th%n (
0'7 is chan%, Na7 an 7Cl ar% 5or.%, Soi. an chlori% ions %co.% hyrat%
32( )h% oilin 'oint o5 a lii *ith an incr%as% in 'r%ssr%(
0@%cr%as%s, ?ncr%as%s, r%.ains constant
33( n ;i.thal Eant. N.%r %scri%s th% (
0si;% o5 an ato., sha'% o5 an orital, s'in o5 orital
34( )h% rat% o5 th% ack*ar r%action is ir%ctly 'ro'ortional to th% 'roct o5 th% .olarconc%ntration o5 (
0=%actants, Procts, Non% o5 th%.
Cha't%r 1
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?ntroction )o Fna.%ntal Conc%'ts
1( )h% 5or.la, *hich i$%s th% si.'l% ratio o5 %ach kin o5 ato.s 'r%s%nt in th%
.ol%cl% o5 co.'on, is call% (
08ol%clar For.la, .'irical For.la, Strctral For.la
2( )h% 5or.la, *hich %'r%ss%s th% actal n.%r o5 %ach kin o5 ato. 'r%s%nt in th%.ol%cl% o5 a co.'on, is call% (
0.'irical For.la, 8ol%clar For.la, Strctral For.la
3( 8ol% is a antity, *hich has 'articl%s o5 th% sstanc%(
0n% illion, 6("2 1"23, 1("13 1"
4( )h% si.'l%st 5or.la o5 a co.'on that contain !1(! caron an 1!(2hyro%n is (
0C73, C7, C276
( )h% %.'irical For.la o5 a co.'on (
0is al*ays th% sa.% as th% .ol%clar 5or.la, ?nicat%s th% %act co.'osition,?nicat%s th% si.'l%st ratio o5 th% ato.s
6( %ry s.all an $%ry lar% antiti%s ar% %'r%ss% in t%r.s o5 (
0sini5icant 5ir%s, 'on%ntial Notation, Loarith.
#( )*o .ol%s o5 *at%r contains .ol%cl%s(
06("2 1"23, 1(2"4 1"24, 3("1 1"23
!( n% .ol% o5 Cl- ions contains ions(
06("2 1"23, 1(2"4 1"24, 3("1 1"23
9( 22" .s o5 C2 contains .ol%s o5 C2(
0n%, Fi$%, )%n
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1"( ?n ronin o55 5ir% is ro''%(
0First, Last, No
11( Pr%cision is link% *ith (
0?ni$ial .%asr%.%nts, ctal r%slts, cc%'t% al%
12( ccracy r%5%rs to ho* clos%ly a .%asr% $al% ar%%s *ith (
0?ni$ial r%slt, ctal r%slt, $%ra% $al%
13( 66"" contains sini5icant 5ir%s(
02, 3, 4
14( 3(# 1"4 contains sini5icant 5ir%s(
02, 3,
1( 9(4" 1"-19 contains sini5icant 5ir%s(
02, 3,
16( )h% 5ir% 39(4 *ill % ron% o55 to (
039(4, 39(, 39
1#( .%ans that th% r%slt otain% in i55%r%nt %'%ri.%nts ar% $%ry clos%to th% acc%'t% $al%s(
0ccracy, Pr%cision, Sini5icant Fir%
1!( )h% a$%ra% *%iht o5 ato.s o5 an %l%.%nt as co.'ar% to th% *%iht o5 on% ato.o5 caron tak%n as is call% th% ato.ic *%iht(
012, 13, 14
19( !( is o5 NaCl(
0to.ic *%iht, For.la >%iht, 8ol%clar >%iht
2"( 1!(" a(.( is th% *%iht o5 *at%r(
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0to.ic, For.la, 8ol%clar
21( 2! .s o5 nitro%n *ill ha$% .ol%cl%s(
06("2 1"23, 12("4 1"23, 3("1 1"23
22( 22(4 .3 o5 C2 is 22(4 .3 o5 S2(
07%a$i%r than, Liht%r than, al to
23( 1"" .s o5 *at%r is %al to .ol%s(
0(6, 2#(#!, 6(2
24( )h% r%actions, *hich 'roc%% in oth th% ir%ctions ar% call%
r%actions(
0=%$%rsil%, ?rr%$%rsil%, N%trili;ation
2( )h% r%actions, *hich 'roc%% in 5or*ar ir%ction only ar% call% r%actions(
0=%$%rsil%, ?rr%$%rsil%, ?onic
26( 8ol%clar *%iht is s% 5or sstanc%s(
0?onic, Non ionic, N%tral
2#( For.la *%iht is s% 5or sstanc%s(
0?onic, Non ionic, N%tral
2!( )h% .o%rn syst%. o5 .%asr%.%nt is call% syst%.(
0S?, 8%tric, F(P(S
29( )h% S(? nit o5 .ass is (
0kilora., ra., 'on
3"( n% .ol% o5 lcos% contains .s(
01"", 1!", 342
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Cha't%r 2
)h% )hr%% Stat%s o5 8att%r
1( *as th% 5irst sci%ntist *ho %'r%ss% a r%lation %t*%%n 'r%ssr% an
th% $ol.% o5 a as(
0Charl%s, Goyl%, $oaro
2( ?5 th% 'r%ssr% 'on a as con5in% in a $%ss%l $ari%s, th% t%.'%ratr% r%.aininsa.%, th% $ol.% *ill (
0ary ir%ctly as th% 'r%ssr%, ary in$%rs%ly as th% t%.'%ratr%, ary in$%rs%ly as th% 'r%ssr%
3( )h% stat%.%nt conc%rnin th% r%lation o5 t%.'%ratr% to th% $ol.% o5 a as n%r5i% 'r%ssr% *as 5irst synth%si;% y (
0Goyl%, Charl%s, $oaro
4( solt% A%ro is (
02#3BC, -2#3BC, -2#3BK
( Das%s int%r.i to 5or. (
07o.o%HI os .itr%, 7%t%ro%nos .itr%, co.'on
6( >at%r can %ists in 'hysical stat%s at a c%rtain conition o5 t%.'%ratr% 'r%ssr%(
0n%, )*o, thr%%
#( )h% t%.'%ratr% at *hich th% $ol.% o5 a as th%or%tically %co.%s ;%ro is call% (
0)ransition t%.'%ratr%, Critical )%.'%ratr%, solt% A%ro
!( Das%s %$iat% 5ro. i%al %ha$ior at 'r%ssr% an t%.'%ratr%(
0Lo*, 7ih, Nor.al
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9( %ry lo* t%.'%ratr% can y 'roc% y th% o5 as%s(
0'ansionn, Contraction, Co.'r%ssion
1"( Goilin 'oint o5 a lii *ith incr%as% in 'r%ssr%(
0incr%as%s, %cr%as%s, r%.ains sa.%
11( 2#3BK I
01""BC, 2#3BC, "BC
12( -2#3BC is %al to (
0"BK, 2#3BK, 1""BK
13( $a'oration tak%s 'lac% at (
0ll t%.'%ratr%s, t constant t%.'%ratr%, at 1""BC
14( is th% t%.'%ratr% at *hich th% $a'or 'r%ssr% o5 a lii %co.%s%al to at.os'h%ric 'r%ssr%(
1( )h% 5r%%;in 'oint o5 *at%r in Fahr%nh%it scal% is (
0"BF, 32BF, 212BF
16( ll as%s chan% to soli %5or% r%achin to (
0-1""BC, "BC, -2#3BC
1#( Pr%ssr% o5 th% as is % o5 th% .ol%cl%s on th% *all o5 th% $%ss%l(
0Collisionns, ttraction, =%'lsion
1!( Goilin 'oint o5 *at%r in asolt% scal% is (
0212BK, 1""BK, 3#3BK
19( Goyl%<s La* r%lat%s (
0Pr%ssr% an $ol.%, )%.'%ratr% an $ol.%, Pr%ssr% an t%.'%ratr%
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2"( Charl%s La* %als *ith r%lationshi'(
0t%.'%ratr% an $ol.%, 'r%ssr% an $ol.%, t%.'%ratr% an 'r%ssr%
21( 55sion is th% %sca'% o5 as throh (
0 s.all 'in hol%, S%.i '%r.%al% .%.ran%, 'oros contain%r
22( )h% %'r%ssion P I P1 + P2 + P3 r%'r%s%nts .ath%.atically(
0Draha.<s La*, $oaro<s La*, @alton<s la* o5 'artial Pr%ssr%
23( ccorin to %al $ol.%s o5 all as%s at th% sa.% t%.'%ratr% an 'r%ssr% contain %al n.%r o5 .ol%cl%s(
0Draha.<s La*, $oaro<s La*, @alton<s La*
24( )h% oilin 'oint o5 'r% *at%r is (
032BC, 1""BF, 3#3BK
2( )h% int%rnal r%sistanc% o5 a lii to 5lo* is call% (
0Sr5ac% t%nsion, Ca'illary action, iscosity
26( )h% %ist%nc% o5 i55%r%nt crystals 5or.s o5 th% sa.% sstanc% is call% (
0?so.or'his., Poly.or'his., ?soto'%s
2#( =at% o5 $a'oration on incr%asin t%.'%ratr%(
0?ncr%as%s, @%cr%as%s, =%.ains sa.%
2!( )h% t%.'%ratr% at *hich .or% than on% crystallin% 5or.s o5 a sstanc% co%ist iscall% th% (
0Critical )%.'%ratr%, )ransition )%.'%ratr%, solt% )%.'%ratr%
29( )h% as%s *hich strictly o%y th% as la*s ar% call% (
0?%al as%s, P%r.an%nt as%s, solt% as%s
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3"( Liht%r as i55s% than th% h%a$i%r as%s(
08or% r%aily, L%ss r%aily, %ry slo*ly
Cha't%r 3
Strctr% o5 to.
1( )h% char% on an %l%ctron is (
0-2(46 1"4 colo.s, -1(6 1"-19 colo.s, 1(6 1"-9colo.s
2( )h% .ai.. n.%r o5 %l%ctrons that can acco..oat% y a '-orital is (
02, 6, 1"
3( 'roton is (
0a h%li. ion, a 'ositi$%ly char% 'articl% o5 .ass 1(6# 1"-2# k, a 'ositi$%lychar% 'articl% o5 .ass 1/1!3# that o5 7yro%n ato.
4( 8ost '%n%tratin raiation o5 a raioacti$% %l%.%nt is (
0a-rays, -rays, -rays
( )h% 5na.%ntal 'articl%s o5 an ato. ar% (
0l%ctrons an 'rotons, %l%ctrons an n%trons, l%ctrons, Protons, N%trons
6( )h% 5na.%ntal 'articl%s o5 an ato.s ar% (
0th% n.%r o5 'rotons, )h% n.%r o5 n%trons, )h% s. o5 'rotons an n%trons
#( JNo t*o %l%ctrons in th% sa.% ato.s can ha$% i%ntical s%t o5 5or ant.n.%rs( )his stat%.%nt is kno*n as (
0Pali<s clsion Princi'l%, 7n<s rl%, 5a =l%
!( has th% hih%st %l%ctron%ati$ity $al%(
0Florin%, Chlorin%, Gro.in%
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9( Princi'l% Eant. n.%r %scri%s (
0Sha'% o5 orital , si;% o5 th% orital, S'in o5 %l%ctron in th% orital
1"( Canal rays ar% 'roc% 5ro. (
0no%, Catho%, ?oni;ation o5 as in th% ischar% t%
11( l%ctro.an%tic raiation 'roc% 5ro. ncl%ar r%actions ar% kno*n as (
0a-rays, -rays, -rays
12( Catho% rays consist o5 (
0l%ctorns, Protons, Positrons
13( )h% 'ro'%rti%s o5 catho% rays 'on th% natr% o5 th% as insi% th%t%(
0%'%n, 'artially %'%n, o not %'%n
14( no% rays consists o5 'articl%s(
0N%ati$%, Positi$%, N%tral
1( to.ic .ass o5 an %l%.%nt is %al to th% s. o5 (
0%l%ctrons an 'rotons, 'rotons an n%trons, %l%ctrons an n%trons
16( N%trons *%r% isco$%r% y (
0Faraay, @alton, Cha*ick
1#( )h% $al% o5 Plank<s constant is (
06(626 1"-34, 6("23 1"24, 1(66# 1"-2!
1!( P-oritals ar% in sha'%(
0s'h%rical, iaonal, . %ll
19( )h% r%.o$al o5 an %l%ctron 5ro. an ato. in as%os stat% is call% (
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0?oni;ation %n%ry, l%ctron 55inity, l%ctron%ati$ity
2"( )h% %n%ry r%l%as% *h%n an %l%ctron is a% to an ato. in th% as%os stat% iscall% (
0?oni;ation Pot%ntial, %l%ctron 55inity, l%ctron%ati$ity
21( )h% 'o*%r o5 an ato. to attract a shar% 'air o5 %l%ctrons is call% (
0?oni;ation Pot%ntial, l%ctron 55inity, l%ctron%ati$ity
22( l%ctron%ati$ity o5 Florin% is aritrarily 5i% as (
02, 3, 4
23( )h% %n%ry i55%r%nc% %t*%%n th% sh%lls o on *h%n .o$% a*ay5ro. th% ncl%s(
0?ncr%asin, %cr%asin, %ali;in
24( isco$%r% that th% ncl%s o5 an ato. is 'ositi$%ly char%(
0>illia. Crook%<s, =th%r5or, @alton
2( ?soto'%s ar% ato.s ha$in sa.% t i55%r%nt (
0to.ic *%iht, to.ic n.%r, $oaro<s N.%r
26( consists o5 7%li. Ncl%i or 7%li. ion 07%++(
2#( )h% anlar .o.%nt. o5 an %l%ctron r%$ol$in aron th% ncl%s o5 ato. is (
0nh/2', n2h2/2', nh3/3'
2!( )h% *a$%l%nths o5 -rays ar% .ath%.atically r%lat% to th% o5
anticatho% %l%.%nt(
0ato.ic *%iht, ato.ic n.%r, $oaro<s n.%r
29( Ly.an S%ri%s o5 s'%ctral lin%s a''%ar in th% 'ortion o5 s'%ctr.(
0Mltra$iol%t, ?n5ra r%, isil%
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3"( ccorin to %l%ctrons ar% al*ays 5ill% in or%r o5 incr%asin %n%ry(
0Pali<s clsion Princi'l%, Mnc%rtainty Princi'l%, 5a Princi'l%
Cha't%r 4
Ch%.ical Gonin
1( )h% %n%ry r%ir% to r%ak a ch%.ical on to 5or. n%tral ato.s is call% (
0?oni;ation Pot%ntial, l%ctron 55inity, Gon n%ry
2( )h% ch%.ical on 'r%s%nt in 7-Cl is (
0Non Polar, Polar Co$al%nt, l%ctro$al%nt
3( 'olar co$al%nt on is 5or.% %t*%%n t*o ato.s *h%n th% i55%r%nc% %t*%%n th%ir (N$al%s is (
0al to 1(#, l%ss than 1(#, 8or% than 1(#
4( )h% .ost 'olar co$al%nt on ot o5 th% 5ollo*in is (
07-Cl, 7-F, 7-?
( on is on% in *hich an %l%ctron has %%n co.'l%t%ly trans5%rr% 5ro. on% ato.to anoth%r(
0?onic, Co$al%nt, co-orinat%
6( on is on% in *hich an %l%ctron 'air is shar% %ally %t*%%n th% t*o ato.s(
0?onic, Co$al%nt, Co-orinat%
#( Gon anl% in th% .ol%cl% o5 C74 is o5 (
012"B, 1"9(B, 1!"B
!( .ol%cl% o5 C2 has strctr%(
9( )h% si.a on is than 'i on(
0>%ak%r, Stron%r, Mnstal%
1"( )h% s'3 oritals ar% in sha'%(
0)%trah%ral, )rional, @iaonal
11( )h% sha'% o5 C74 .ol%cl% is (
0)%trah%ral, )rional, @iaonal
12( )h% on in Cl2 is (
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0Non 'olar, Polar, l%ctro$al%nt
13( >at%r is .ol%cl%(
0Non% 'olar, Polar, l%ctro$al%nt
14( Co$al%nt ons in *hich %l%ctron 'air ar% shar% %ally %t*%%n th% t*o ato.s is call% co$al%nt on(
0Non 'olar, Polar, Co-orinat%
1( ach caron ato. in C74 is hyrii;%(
0S'3, S'2, S'
16( ach caron ato. in C274 is hyrii;%(
0S'3, S'2, S'
1#( ach caron ato. in C272 is hyrii;%(
0S'3, S'2, S'
1!( y%n ato. in 72 has nshar% %l%ctron 'air(
0n%, t*o , thr%%
19( Nitro%n ato. in N73 has nshar% %l%ctron 'air(
0n%, t*o, thr%%
2"( )h% clo o5 char% that srrons t*o or .or% ncl%i is call% orital(
0to.ic, 8ol%clar, 7yri
21( sstanc%, *hich is hihly attract% y a .an%tic 5i%l, is call% (
0l%ctro.an%tic, Para.an%tic, @ia.an%tic
22( 7F %ists in lii % to (
0an%r >aal Forc%s, 7yro%n on, co$al%nt Gon
23( G%st hyro%n onin is 5on in
07F, 7Cl, 7?
24( Sha'% o5 CCl4 .ol%cl% is (
0t%trah%ral, )rional, @iaonal
2( on is 5or.% % to lin%ar o$%rla'(
0Si.a on, Pi on, 7yro%n on
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26( is %5in% as th% antity o5 %n%ry r%ir% to r%ak on% .ol% o5 co$al%nt inas%os stat%(
0Gon %n%ry, ?oni;ation %n%ry, n%ry o5 cti$ation
2#( =%'lsi$% 5orc% %t*%%n %l%ctron 'air in a .ol%cl% is .ai.. *h%n it has an anl% o5
(
012"B, 1"9(B, 1!"B
2!( =%'lsi$% 5orc% %t*%%n %l%ctron 'air in a .ol%cl% is .ai.. *h%n it has an anl% o5 (
012"B, 1"9(B, 1!"B
29( )h% s. o5 total n.%r o5 %l%ctrons 'airs 0onin an lon% 'airs is call% (
0to.ic N.%r, $oaro<s N.%r, St%ric N.%r
3"( Sha'% o5 .ol%cl% is t%trah%ral(
0GaCl2, GF3, N73
Cha't%r
n%r%tics o5 Ch%.ical =%action
1( )h% antity o5 h%at %$ol$% or asor% rin a ch%.ical r%action is call% (
07%at or =%action, 7%at o5 For.ation, 7%at o5 Co.ination
2( n %noth%r.ic r%action is on%, *hich occrs (0>ith %$oltion o5 h%at, >ith asor'tion o5 7%at, ?n 5or*ar @ir%ction
3( n %oth%r.ic r%action is on% rin *hich (
07%at is li%rat%, 7%at is asor%, no chan% o5 h%at occrs
4( )h% %ation C + 2 C2 @7 I -4"!KO r%'r%s%nts r%action(
0noth%r.ic, oth%r.ic, =%$%rsil%
( )h% %ation N2 + 2 2N @7 I 1!"KO r%'r%s%nts r%action(
0noth%r.ic, oth%r.ic, ?rr%$%rsil%
6( )h%r.o-ch%.istry %als *ith (
0)h%r.al Ch%.istry, 8%chanical n%ry, Pot%ntial n%ry
#( nthal'y is (
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07%at cont%nt, ?nt%rnal %n%ry, Pot%ntial n%ry
!( 7%ss<s La* is also kno*n as (
0La* o5 cons%r$ation o5 8ass, La* o5 cons%r$ation o5 n%ry, La* o5 8ass ction
9( ny thin n%r %a.ination in th% Laoratory is call% (0=%actant, Syst%., l%ctrolyt%
1"( )h% %n$iron.%nt in *hich th% syst%. is sti% in th% laoratory is call% (
0Conitions, Srronins, Stat%
11( >h%n th% ons %in rok%n ar% .or% than thos% %in 5or.% in a ch%.ical r%action, th%n@7 *ill % (
0Positi$%, N%ati$%, A%ro
12( >h%n th% on %in 5or.% ar% .or% than thos% %in rok%n in a ch%.ical r%action, th%nth% @7 *ill % (
0Positi$%, N%ati$%, A%ro
13( )h% %nthal'y chan% *h%n a r%action is co.'l%t% in sinl% st%' *ill % asco.'ar% to that *h%n it is co.'l%t% in .or% than on% st%'s(
0al to, Partially i55%r%nt 5ro., ntir%ly i55%r%nt 5ro.
14( )h% %nthal'y o5 a syst%. is r%'r%s%nt y (
07, @7, @1( )h% 5actor + P is kno*n as (
07%at cont%nt, Chan% in nthal'y, >ork on%
16( 7%at o5 5or.ation is r%'r%s%nt% y (
0@5, @75, 75
1#( )h% h%at asor% y th% syst%. at constant is co.'l%t%ly tili;% to incr%as% th%int%rnal %n%ry o5 th% syst%.(
0ol.%, Pr%ssr%, )%.'%ratr%1!( 7%at chan% at constant 5ro. initial to 5inal stat% is si.'ly %al to th% chan%in %nthal'y(
0ol.%, Pr%ssr%, )%.'%ratr%
19( syst%., *hich %chan% oth %n%ry an %n%ry *ith th% srronin, is syst%.(
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0'%n, Clos%, ?solat%
2"( syst%., *hich only %chan% %n%ry *ith th% srronin t not th% .att%r, is syst%.(
0'%n, Clos%, ?solat%
21( syst%., *hich n%ith%r %chan%s %n%ry nor .att%r *ith th% srronins is syst%.(
0'%n, Clos%, ?solat%
22( 'ro'%rty o5 a syst%. is in%'%n%nt o5 th% a.ont o5 .at%rial conc%rn%(
0?nt%nsi$%, t%nsi$%, Physical
23( 'ro'%rty o5 a syst%. %'%ns 'on th% a.ont o5 sstanc% 'r%s%nt in th%syst%.(
0?nt%nsi$%, t%nsi$%, Physical
24( @ I * r%'r%s%nts (
0First La* o5 )h%r.oyna.ics, 7%ss<s La*, nthal'y Chan%
2( is %5in% as th% chan% in %nthal'y *h%n on% ra. .ol% o5 a co.'on is 'roc% 5ro. its %l%.%nts(
07%at o5 =%action, h%at o5 For.ation, 7%at o5 N%trili;ation
Cha't%r 6
Ch%.ical iliri.
1( t %iliri. th% rat% o5 5or*ar r%action an th% rat% o5 r%$%rs% r%action ar% (
0al, Chanin, @i55%r%nt
2( Sch r%actions, *hich 'roc%% to 5or*ar ir%ction only an ar% co.'l%t% a5t%r so.%ti.% ar%call% r%action(
0?rr%$%rsil%, =%$%rsil%, 8ol%clar
3( Sch r%actions, *hich 'roc%% to oth th% ir%ction an ar% n%$%r co.'l%t%, ar% call%
r%action(
0?rr%$%rsil%, =%$%rsil%, 8ol%clar
4( )h% rat% o5 ch%.ical r%action is ir%ctly 'ro'ortional to th% 'roct o5 th% .olar conc%ntrationo5 (
0=%actants, Procts, Goth r%actants an 'rocts
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( J?5 a syst%. in %iliri. is sQ%ct% to a str%ss, th% %iliri. shi5ts in a ir%ction to.ini.i;% or no th% %55%ct o5 this str%ss( )his 'rinci'l% is kno*n as (
0L%-Chat%li%r<s Princi'l%, Day Lssac<s Princi'l%, $oaro<s Princi'l%
6( $%ry lar% $al% o5 Kc inicat%s that r%actants ar% (
0$%ry stal%, nstal%, .o%rat%ly stal%
#( $%ry lo* $al% o5 Kc inicat%s that r%actants ar% (
0$%ry stal%, $%ry nstal%, .o%rat%ly stal%
!( )h% %iliri. in *hich r%actants ar% 'rocts ar% in sinl% 'has% is call% (
07o.o%nos iliri., 7%t%ro%nos iliri., @yna.ic iliri.
9( )h% %iliri. in *hich r%actants an 'rocts ar% in .or% than on% 'has%s ar% call% (
07o.o%nios iliri., 7%t%ro%nios iliri., @yna.ic iliri.
1"( Ch%.ical iliri. is %iliri.(
[email protected] , Static, 7%t%ro%n%os
11( ?n %oth%r.ic r%action, lo*%rin o5 t%.'%ratr% *ill shi5t th% %iliri. to (
0riht, l%5t, %ally on oth th% ir%ction
12( ?n %noth%r.ic r%action, lo*%rin o5 t%.'%ratr% *ill shi5t th% %iliri. to (
0riht, l%5t, %ally on oth th% ir%ction
13( catalyst th% %n%ry o5 acti$ation(
0incr%as%s, %cr%as%s, has no %55%ct on
14( t %iliri. 'oint (
05or*ar r%action is incr%as%, ack*ar r%action is incr%as%, 5or*ar an ack*ar r%actions %co.% %al
1( N73 is 'r%'ar% y th% r%action N2 + 372 R 2N73 @7 I -21(9 Kcal( )h% .ai.. yi%l o5
N73 is otain% (0t lo* t%.'%ratr% an hih 'r%ssr%, at hih t%.'%ratr% an lo* 'r%ssr%, at hih t%.'%ratr%an hih 'r%ssr%
16( >h%n a hih 'r%ssr% is a''li% to th% 5ollo*in r%$%rsil% 'roc%ss: N2 + 2 R2N )h% %iliri. *ill
0shi5t to th% 5or*ar ir%ction, shi5t to th% ack*ar ir%ction, not chan%
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1#( )h% $al% o5 Kc 'on th% initial conc%ntration o5 th% r%action(
0%'%ns, 'artially %'%ns, o%s not %'%n
1!( >hil% *ritin th% Kc %'r%ssion, th% conc%ntration o5 ar% tak%n in th%n.%rator(
19( Solility 'roct constant is %not% y (
0Kc, Ks', Kr
2"( J)h% %r%% o5 ioni;ation o5 an %l%ctrolyt% is s''r%ss% y th% aition o5 anoth%r%l%ctrolyt% containin a co..on ion( )his 'h%no.%non is call% (
0Solility Proct, Co..on ?on 55%ct, L%-Chat%li%r<s Princi'l%
Cha't%r #
Soltions an l%ctrolyt%s
1( 8olarity is th% n.%r o5 .ol%s o5 a solt% issol$% '%r (
0.3 o5 a soltion, .3 o5 sol$%nt, K o5 sol$%nt
2( 8olality is %5in% as th% n.%r o5 .ol%s o5 solt% issol$% '%r (
0.3 o5 soltion, k o5 sol$%nt, k o5 solt%
3( )h% solility o5 a solt% *ith th% incr%as% o5 t%.'%ratr%(
0incr%as%s, %cr%as%s, o%s not alt%r
4( )h% loss o5 %l%ctron rin a ch%.ical r%action is kno*n as (
0iation, =%ction, N%trali;ation
( )h% ain o5 %l%ctron rin a ch%.ical r%action is kno*n as (
0iation, =%ction, N%trali;ation
6( )h% ions, *hich ar% attract% to*ars th% ano%, ar% kno*n as (
0nins, Cations, Positron(
#( )h% '7 o5 a n%tral soltion is (01(#, #, 14
!( crr%nt o5 on% a.'%r% 5lo*in 5or on% .int% is %al to (
0n% colo., 6" colo., on% Faraay
9( sstanc%, *hich o%s not allo* %l%ctricity to 'ass throh, is kno*n as (
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0?nslator, Conctor, l%ctrolyt%
1"( Sch sstanc%s, *hich allo* %l%ctricity to 'ass throh th%. an ar% ch%.ically%co.'os%, ar% call% (
0l%ctrolyt%s, ?nslators, 8%tallic conctors
11( is an %a.'l% o5 stron aci(
0c%tic ci, Caronic ci, 7yrochloric ci
12( is an %a.'l% o5 *%ak aci(
07yrochloric ci, c%tic ci, Sl'hric ci
13( >h%n N74Cl is hyroly;%, th% soltion *ill % (
0ciic, Gasic, N%tral
14( >h%n Na2C3 is hyroly;%, th% soltion *ill % (
0ciic, Gasic, N%tral
1( >h%n l% hyrat% co''%r sl'hat% is h%at% (
0?t chan%s into *hit%, it trns lack, it r%.ains l%
16( Sl'hr has th% hih%st oiation n.%r in (
0S2, 72S4, 72S3
1#( )h% r%action %t*%%n an aci an a as% to 5or. a salt an *at%r is call% (
07yration, 7yrolysis, N%trali;ation
1!( is o''osit% o5 N%trali;ation(
07yration, 7yrolysis, ?oni;ation
19( )h% sstanc% ha$in '7 $al% # is (
0Gasic, ciic, N%tral
2"( n a%os soltion *hos% '7 is ;%ro is (
0lkalin%, N%tral, Stronly ciic
21( Solility 'roct o5 slihtly soll% salt is %not% y (
0Kc, K', Ks'
22( )h% incr%as% o5 oiation n.%r is kno*n as (
0iation, =%ction, 7yrolysis
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23( )h% %cr%as% o5 iation n.%r is kno*n as (
0iation, =%ction, l%ctrolysis
24( n% .olar soltion o5 lcos% contains .s o5 lcos% '%r .3 o5 soltion(
• 1!", 1"", 3422( )h% n.%r o5 .ol%s o5 solt% 'r%s%nt '%r .3 o5 soltion is call% (
08olality, 8olarity, Nor.ality
26( T8< is th% sy.ol s% 5or r%'r%s%ntin (
08olality, 8olarity, Nor.ality
2#( 1 .ol% o5 72S4 is %al to (
09!.s, 49.s, 1!".s
2!( G55%r soltion t%ns to '7(
0Chan%, ?ncr%as%, .aintain
29( )h% loarith. o5 r%ci'rocal o5 hyroi% ion is r%'r%s%nt% as (
0'7, '7, P7
3"( ?n *at%r .ol%cl%s srron solt% 'articl%s(
07yration, 7yrolysis, N%trali;ation
Cha't%r !
?ntroction to Ch%.ical Kin%tics
1( )h% rat% o5 ch%.ical r%action *ith incr%as% in conc%ntration o5 th% r%actants(
0?ncr%as%s, @%cr%as%s, @o%s not alt%r
2( ?onic r%actions o5 inoranic co.'ons ar% (
0$%ry slo*, .o%rat%ly slo*, $%ry 5ast
3( )h% rat% o5 r%actions can % %t%r.in%(
0%ry Slo*, 8o%rat%ly Slo*, %ry 5ast
4( )h% s. o5 %'on%nts o5 th% conc%ntrations o5 r%actants is call% (
0r%r o5 r%action, 8ol%clarity, iliri. Constant
( )h% rat% o5 r%action %n%rally in th% 'r%s%nc% o5 a sital% catalyst(
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0?ncr%as%s, @%cr%as%s, r%.ains constant
6( )h% rat% o5 a r%action 'on th% t%.'%ratr%(
0%'%ns, slihtly %'%ns, o%s not %'%ns
#( )h% .ini.. %n%ry r%ir% to rin aot a ch%.ical r%action is call% (0Gon %n%ry, ?oni;ation %n%ry, n%ry o5 cti$ation
!( iation o5 S2 in th% 'r%s%nc% o5 2 in Sl'hric ci instry is an %a.'l% o5 (
07o.o%nos catalyst, 7%t%ro%n%os catalyst, N%ati$% catalyst
9( 7yrolys%s o5 %st%r in th% 'r%s%nc% o5 aci is an %a.'l% o5 (
07o.o%nos catalyst, 7%t%ro%n%os catalyst, N%ati$% catalyst
1"( Conc%ntration o5 th% r%actants *ith th% 'assa% o5 ti.% rin a ch%.icalr%action(
0?ncr%as%s, @%cr%as%s, @o%s not alt%r
11( Conc%ntration o5 th% 'rocts *ith th% 'assa% o5 ti.% rin a ch%.icalr%action(
0?ncr%as%s, @%cr%as%s, @o%s not alt%r
12( )h% rat% constant *ith t%.'%ratr% 5or a sinl% r%action(
0ari%s, Slihtly ari%s, @o%s not $ary13( )h% rat% o5 r%action at a 'articlar ti.% is call% (
0$%ra% =at% o5 r%action, solt% rat% o5 r%action, ?nstantan%os rat% o5 r%action
14( )h% s'%ci5ic rat% constant K has $al% 5or all conc%ntrations o5 th% r%actant(
0Fi%, arial%, n%liil% $al%
1( Gy incr%asin th% sr5ac% ar%a th% rat% o5 r%action can % (
0?ncr%as%, @%cr%as%, @ol%
16( 8n2 *h%n h%at% *ith KCl3 (
0Di$%s ' its o*n oy%n, Proc%s o;on% 3, cts as catalyst
1#( =%actions *ith hih %n%ry o5 acti$ation 'roc%% *ith (
07ih s'%%, 8o%rat%ly slo* s'%%, slo* s'%%
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1!( )h% .ini.. a.ont o5 %n%ry r%ir% to rin aot a ch%.ical r%action is call% (
0n%ry o5 ioni;ation, n%ry o5 cti$ation, n%ry o5 Collision
19( n inhiitor is a catalyst *hich rat% o5 r%action(
0?ncr%as%s, @%cr%as%s, @o%s not alt%r
2"( is th% chan% o5 th% conc%ntration o5 r%actant i$i% y th% ti.%(
0=at% o5 r%action, %locity Constant, 8ol%clarity
Pr%'ar% Gy: @anish nsaari 0+92333-3144#22