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ARUDRA ENGINEERS PVT LTD Project EMCO ENERGY THERMAL POWER
PROJECT LTD Title PROCEDURE FOR CHEMICAL CLEANING Rev 0 Page Page 1
of 10
TECHNICAL SPECIFICATION
PROJECT:
2 X 300 MW EMCO Energy Thermal Power Project at Warora
EPC CONTRACT:
ECPL / SHANGAI ELECTRI CORPORATION.
ARUDRA ENGINEERS PRIVATE LTD. Chennai.
THIS DOCUMENT IS THE PROPERTY OF AEPL AND HIS ONLY ALLOWED TO BE
USED BY EXPRESS PERMISSION FROM AEPL - CHENNAI.
TECHNICAL SPECIFICATION FOR PRE-
COMISSINING CHEMICAL CLEANING OF 2 x 300 MW BOILER AND PRE
BOILER
ARUDRA ENGINEERS PVT LTD No-79 Valmiki Street,
Thiruvanmiyur-Chennai-600041 Phone-044-2442 4755 /2490 1623 Fax
044-2442 4755
Email: [email protected]
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ARUDRA ENGINEERS PVT LTD Project EMCO ENERGY THERMAL POWER
PROJECT LTD Title PROCEDURE FOR CHEMICAL CLEANING Rev 0 Page Page 2
of 10
1. PLANT DETAILS
2. BOILER DETAILS
3. INTRODUCTION
4. PREPARATION
5. SEQUENCE OF PROCESS
6. PART- I HOT ALKALI FLUSHING OF BOILER FRONT SYSTEM
7. PART-II BOILER CHEMICAL CLEANING
8. INPUT REQUIREMENT FROM APL/SHUAN
9. SAFETY PRECAUTIONS
10. ANALYTICAL PROCEDURE
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ARUDRA ENGINEERS PVT LTD Project EMCO ENERGY THERMAL POWER
PROJECT LTD Title PROCEDURE FOR CHEMICAL CLEANING Rev 0 Page Page 3
of 10 1. PLANT DETAILS: GMR ENERGY LTD: 2 X 300 MW, project is
located at Warora,Maharastra. 2. BOILER DETAILS: SUPPLIER : SHANGAI
ELECTRICAL CORPORATION. MCR : 1025 TPH TYPE : Natural Circulation
Generation Capacity : 300 MW Each unit
3. INTRODUCTION: 1. The following will constitute brief
Technical specifications in connection with Pre
Commissioning chemical cleaning of 2 x 300 MW boiler and
pre-boiler system during Commissioning. Pre boiler system Feed
water system and Condensate System) must be cleaned (Hot Alkali
cleaning) before Starting the Boiler chemical cleaning.
2. The aim of Chemical Cleaning is to remove mill scale, oil,
paint, preservatives, rust, welding VODJV WKDW ZRXOG KDYH HQWHUHG
GXULQJ WKH DVVHPEO\ RI QHZ WXEHV $IWHU FDUU\LQJ RXW WKHprocess, the
internal surfaces of the tubes are passivated by means of
protective layer to prevent further rusting and corrosion.
3. The Main Boiler cleaning circuit consists of the following
equipments of the boiler.
Portion of Boiler Feed line Economizer Steam Drum Water Wall
Tube Down Comer and Bottom Header Super heater is not included in
the scope of chemical cleaning.
[Instead, it is flushed and filled up with Ammoniated Hydrazine]
4. The Pre Boiler system and Condensate system circuit consists the
following Equipments.
LP PIPING FROM CEP DISCHARGE LP HEATERS BFP SUCTION &
DISCHARGE HP HEATERS
4. SEQUENCE OF CIRCUITS: 4.1 ALKALI FLUSHING OF BOILER FRONT
SYSTEM: CC Tank CC Pump CEP discharge CPU (By Pass) GSC LPH and By
Pass FST Bypass BFP Suction BFP By pass BFP Discharge HPH and by
pass Feed Control Station
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ARUDRA ENGINEERS PVT LTD Project EMCO ENERGY THERMAL POWER
PROJECT LTD Title PROCEDURE FOR CHEMICAL CLEANING Rev 0 Page Page 4
of 10 4.2. ACID CLEANING OF MAIN BOILER: (i) Integral Circulation
Route: CC TANK CC PUMP ECONOMISER STEAM DRUM W/W TUBES DOWN COMER
BOTTOM HEADER CC TANK (ii) Circulation from left to right route: CC
TANK CC PUMP LEFT SIDE, LEFT-FRONT AND LEFT-REAR W/W LOWER HEADER
LEFT SIDE, LEFT-FRONT AND LEAF-REAR W/W DRUM RIGHT SIDE,
RIGHT-FRONT AND RIGHT-REAR W/W RIGHT SIDE, RIGHT FRONT AND
RIGHT-REAR W/W LOWER HEADER BACK TO MAIN PIPE CC TANK. (iii)
Circulation from right to left route: CC TANK CC PUMP RIGHT SIDE,
RIGHT FRONT AND RIGHT-REAR W/W LOWER HEADER RIGHT SIDE, RIGHT FRONT
AND RIGHT REAR W/W DRUM LEFT SIDE, LEFT-FRONT AND LEFT-REAR W/W
LEFT SIDE, LEFT FRONT AND LEFT-REAR W/W LOWER HEADER CC TANK 4.
PREPARATION:
1. Temporary chemical cleaning system will be made readily
available. 2. The whole process will be carried out using our
blending tank, circulating pumps, piping
and valves, which form a temporary circuit with the main boiler.
3. The common header of circulating pumps will be connected to the
Economizer inlet feed
at control station. Due care and precaution shall be taken to
prevent ingress of any acid in to the Boiler feed lines, if
necessary, using plugs.
4. All the drum internals will be removed before chemical
cleaning and reinstalled after
completion of First Stage Passivation by the customer. 5. Down
comers are suitably fitted with orifice plate to improve more flow
through water
wall steam generation tubes. 6. Bottom header end caps of the
lower ring header will be removed and necessary piping
of temporary circuit will be welded. After completion of the
cleaning process, piping will be cut and end caps are
reinstalled.
7. A separate line connecting all the drains from the dissolving
tank, main boiler and all
other pipelines will be laid and led to a separate
neutralization pit where neutralization of effluents after each
process will be carried.
8. Necessary safety precautions will be taken during cleaning
process to prevent any sort of
injury to the operating personnel.
9. All instrumentation lines will be either plugged or removed
temporarily during cleaning by the customer to prevent entry of
acid.
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ARUDRA ENGINEERS PVT LTD Project EMCO ENERGY THERMAL POWER
PROJECT LTD Title PROCEDURE FOR CHEMICAL CLEANING Rev 0 Page Page 5
of 10
10. Chemical analysis will be carried out during process for the
required test results.
11. Adequate DM water, steam and compressed air specified
chemicals will be made available at site.
12. Take trial run of individual circulation pump and check the
total System to the shut off
pressure of the pump for any leakages.
13. Chemical cleaning area shall be covered with safety
barricade tape.
14. Inhibitor evaluation test will be carried out prior to the
chemical cleaning.
15. 2 nos. of Sample tubes 200 mm each cut vertically and it
will be kept in steam drum and the mixing tank.
16. Express laboratory will be set up nearer to the chemical
cleaning area.
17. Ensure all Safety Equipment will be kept ready for emergency
use.
18. Ensure Lighting Facility in chemical cleaning area
19. Ensure availability of emergency power supply.
5. SEQUENCE OF PROCESS: 1. HOT ALKALI FLUSHING OF BOILER FRONT
SYSTEM:
Mass Flushing
Hot Alkali Flushing
DM Rinsing
2. CHEMICAL CLEANING OF MAIN BOILER:
Mass Flushing
Hot Alkali Flushing
DM rinsing
Inhibited acid cleaning
DM rinsing
Rinsing
Passivation
Boiler Restoration
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ARUDRA ENGINEERS PVT LTD Project EMCO ENERGY THERMAL POWER
PROJECT LTD Title PROCEDURE FOR CHEMICAL CLEANING Rev 0 Page Page 6
of 10 6. PART-I : HOT ALKALI FLUSHING OF BOILER FRONT SYSTEM 1.
Introduction:
1. It is important that the newly erected feed water and
condensate pipeline must be thoroughly cleaned to remove Dirt,
rust, oil and grease, welding debris etc. The complete removal of
the above things ensures clear condensate free from contaminants
required for trouble free operation during start up and loading
operation of the unit.
2. The procedure is essentially involves circulating the
alkaline solution which has been
found to be superior emulsifying agent with a high degree of
detergent properties enabling complete removal of debris from the
system. The added advantage of using alkaline solution is that it
can as well as be employed for flushing of both coil and shell side
of heater having copper alloys without any fear.
3. After installation of regenerative equipments and auxiliary
units, the temporary pipe work has to be completed as per
drawing.
4. Temporary pipe work has to be tested hydraulically. If any
leakage is observed it should be rectified. However, the following
points may be ensured before commencing the process.
2. Preparation:
Temporary piping to be done as per the scheme. All permanent
strainers to be removed before commencing the flushing activity.
Flow element to be replaced by spool pieces while making
temporary
connections. All valves on steam line to and from deaerator
should be closed. Ensure availability of chemicals, lab reagents
and apparatus for testing at site. All safety valves to be removed
from HP heater and LP heater. Suitable blanks
to be provided with valve for proper air venting. While carrying
out flushing of shell side of HP & LP Heaters, air vent should
be
properly operated. All instruments in the system to be isolated
before flushing. Ensure permanent supports are provided for all
valves and pipelines before
starting of process.
3. MASS FLUSHING: Mass Flushing is carried out initially with
cold filtered water / DM water. After filling the system, direct
flushing is continued till the effluent water is clear. 4. HOT
WATER FLUSHING:
The system is filled up and circulation is established. The
temperature of the water is raised by admitting steam to get around
70oC to 80oC. Circulation is continued for 6-8 hrs, check turbidity
and conductivity of water at inlet and outlet. When the values of
turbidity are less than 20 NTU and conductivity is less than 25
s/cm2 continue the next process without drain. 5. HOT ALKALI
FLUSHING / DEGREASING:
Chemicals must be mixed little by little observing the foaming
in the mixing tank.
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ARUDRA ENGINEERS PVT LTD Project EMCO ENERGY THERMAL POWER
PROJECT LTD Title PROCEDURE FOR CHEMICAL CLEANING Rev 0 Page Page 7
of 10 Chemicals: Trisodium Phosphate 0.4 0.45%
Di sodium Phosphate 0.10 0.20 % Non Ionic Wetting Agent -
0.05%
After adding the above chemicals, the temperature of the
solution to 70oC to 80oC, which is to be maintained throughout the
process. Keep the circulation 8 to 10 hrs. The samples are taken
out from inlet and outlet at regular intervals. The same samples
are analyzed for TSP, DSP, temperature and pH value. After getting
the steady values at inlet and outlet then drain the complete
system.
7. DM WATER RINSING: Fill up the system with DM water and rinse
the system by continuous filling and draining method circuit-wise
by running the pump at the maximum flow rate. The rinsing is
continued till a clear effluent is obtained indicating complete
cleaning of the system. The flushing is terminated once the water
is clear and free from alkaline solution for visual appearance.
Besides conductivity measurements at the inlet and outlet points
shall be taken as a guiding factor for termination within
reasonably acceptable limits of conductivity difference. 8.
RESTORATION: After completion of cleaning all temporary system will
be removed and restored the permanent system. 9. UTILITY
REQUIREMENTS:
S.No DESCRIPTION REMARKS
A Utility Requirements
1 DM water (for one unit cleaning) 770 M3/unit 2 Service
water(for one unit cleaning) 500 M3/unit 3 Electrical A.C. Power
supply (3 phase 415 V) 300 Kw 4 Emergency Power supply (3 phase 415
V) 200 Kw 5 Construction Power Supply (3 Phase 415 V) 125 Kw
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ARUDRA ENGINEERS PVT LTD Project EMCO ENERGY THERMAL POWER
PROJECT LTD Title PROCEDURE FOR CHEMICAL CLEANING Rev 0 Page Page 8
of 10 7. PART-II: CHEMICAL CLEANING OF MAIN BOILER: 1. SCOPE: The
cleaning process covers a portion of feed line, Economizer, Steam
drum, water walls, down comers, risers and bottom headers, etc. 2.
TECHNIQUE:
1. Chemical cleaning is to be done adopting circulation
technique. The water touched pressure parts are cleaned using
inhibited Hydrochloric acid and the solvent is circulated in the
water touched pressure parts by using chemical cleaning pump.
2. The cleaning operation comprises of the following major
steps. o SUPER HEATER BACK FILLING o COLD AND HOT WATER FLUSHING o
HOT ALKALINE CLEANING (DEGREASING) o INHIBITED ACID CLEANING o MILD
ACID RINSING o PASSIVATION
3. SUPER HEATER BACK FILLING: The Super Heater is back flushed
with DM Water using Super Heater Back filling line. It is further
filled up to overflow with DM water containing Hydrazine to the
concentration of 200 ppm and pH maintaining above 9.5 by the
addition of Ammonia. keep the water wall tube sample inside the
steam drum then the manhole is closed. 4. COLD AND HOT WATER
FLUSHING: The temporary circuit consisting of blending tank,
circulating pumps, valves and piping is fabricated and erected as
per the drawing. The complete circuits are tested and ensure no
leaks. DM Water is filled up and the system is flushed till the
water is clear by visual observation. Further to this flushing,
raise the temperature 700 C and flushing is continued. This
flushing is carried out for 6 - 8 hours to achieve stability of the
parameters. 5. HOT ALKALINE CLEANING (DEGREASING) Fill up the
system, establish circulation and raise the temperature of the
system to 60oC - 70oC. The process chemicals may be added in the
following concentration in the mixing tank. Chemicals:
Trisodium Phosphate - 0.3% 0.4 % Di-sodium phosphate - 0.1% -
0.2% Non Ionic Wetting Agent - 0.05%
Keep the circulation 8 10 hrs. The samples are taken out from
inlet and outlet at regular intervals. The same samples are
analyzed for alkalinity and pH value. After getting the steady
values at inlet and outlet, then drain the complete system.
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ARUDRA ENGINEERS PVT LTD Project EMCO ENERGY THERMAL POWER
PROJECT LTD Title PROCEDURE FOR CHEMICAL CLEANING Rev 0 Page Page 9
of 10 6. DM WATER RINSING: Fill up the system with DM water and
establish circulation. Rinse the system by continuous filling and
draining method. The rinsing is continued till the pH value is same
in I/L and O/L. The flushing is terminated once the water is clear
and free from alkaline solution. 7. INHIBITED ACID PICKLING After
DM water rinse, the DM water is circulated and its temperature
increased to 6050 C. Add the following chemicals one by one.
a. Inhibitor Coronil 213 SPL - 0.20 0.30% b. Hydrochloric Acid -
4.0 4.5 % c. Sodium Fluoride - 0.15 %
Circulation is continued for 4-6 hours, during the process total
iron and acid strength is checked in the inlet and outlet sampling
points at regular intervals. Circulation is continued until the
steady value is reached at a gap of 30 minutes. At this juncture
the whole solution is completely drained by displacement method
using DM water. The drained acid solution is neutralized using lime
and sodium hydroxide, and then discharged to the storm water drain.
8. DM WATER RINSE: The boiler is filled up with DM water and keeps
circulation for 1 hr then drain completely by displacement method
using DM water. Analyze the pH and Fe. The pH of the circulating
solution should not be allowed to go beyond 4.0 in order to prevent
the precipitation of Iron hydroxide, which may settle down on the
cleaned Boiler surfaces. 9. RINSE AND PASSIVATION: In this process,
0.15 % phosphoric acid and 0.20 % sodium poly phosphate is added in
the system through mixing tank. Raise the temperature to 45 5oC and
then re-circulate for 1 2 hours. Then adjust the pH valve to 9.5
10.0 by adding NH3 and then circulate for 4-6 hours. During this
process test for iron is carried out.
10. INSPECTION:
The drum man hole is opened, the exhaust fan / man cooler shall
be provided on one side of steam drum manhole door to avoid
sweating. The internal surfaces visually inspected for uniform
protective magnetite layer. All loose debris in the Steam Drum is
cleaned manually. Bottom header shall be flushed with water, to
make it free from loose mucks. Remove all the temporary piping and
restore the boiler for second stage passivation.
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ARUDRA ENGINEERS PVT LTD Project EMCO ENERGY THERMAL POWER
PROJECT LTD Title PROCEDURE FOR CHEMICAL CLEANING Rev 0 Page Page
10 of 10 11. UTILITY REQUIREMENTS:
S.No DESCRIPTION REMARKS
A Utility Requirements
1 DM water (for one unit cleaning) 5000 M3/unit 2 Service
water(for one unit cleaning) 1000 M3/unit 3 Electrical A.C. Power
supply (3 phase 415 V) 300 Kw 4 Emergency Power supply (3 phase 415
V) 200 Kw 5 Construction Power Supply (3 Phase 415 V) 125 Kw
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ARUDRA ENGINEERS PVT LTD PROJECT EMCO ENERGY THERMAL POWER
PROJECT LTD CLIENT EVERSENDAI CONSTRUCTION PVT LTD Rev o TITLE
SAFETY PROCEDURE FOR CHEMICAL
CLEANINGPage 1 of 3
SAFETY PROCEDURE
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ARUDRA ENGINEERS PVT LTD PROJECT EMCO ENERGY THERMAL POWER
PROJECT LTD CLIENT EVERSENDAI CONSTRUCTION PVT LTD Rev o TITLE
SAFETY PROCEDURE FOR CHEMICAL
CLEANINGPage 2 of 3
1. SAFETY PRECAUTIONS:
Alkaline /Acid solution may cause skin burning and its fumes are
injurious to eyes. All the safety precautions must be taken during
process.
All operators and workers must use rubber gloves, eyes
protecting glasses, apron, gumboots, masks etc.
Due precautions must be taken while tightening the flanges of
temporary piping joints of the loops during process.
Ensure the availability of first aid box in the site.
No drilling, welding and cutting operations are allowed during
the process.
Before the person enters the Steam Drum, its man- hole may be
kept opened before 2 hrs and air may be forced in side the Drum
during the period.
2. SAFETY EQUIPMENTS:
S.No Item
01 Gum boots (various sizes) 02 Rubber Gloves 03 Rubber or
Polythene Aprons 04 Helmets 05 Safety Goggles plain glass 06 Face
mask (Transparent, plastic)
First aid box
3. EMERGENCY PROVISIONS
Flushing and washing water supplies.
Ample supplies of tepid flushing and washing water supplies
shall be provided at all possible points of discharge, spillage or
escape of chemicals.
Adequate provisions shall be made for emergency treatment of the
eyes, comprising eye wash bottles, located conveniently to places
where discharge, spillage or escape of chemicals can occur
Safety shower shall be provided.
A suitable first aid treatment room with outside telephone
facilities shall be provided within a reasonable distance of the
place where chemicals are being used.
The protective clothing and apparatus required for emergency use
shall be made available near the acid cleaning area.
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ARUDRA ENGINEERS PVT LTD PROJECT EMCO ENERGY THERMAL POWER
PROJECT LTD CLIENT EVERSENDAI CONSTRUCTION PVT LTD Rev o TITLE
SAFETY PROCEDURE FOR CHEMICAL
CLEANINGPage 3 of 3
4. FIRST AID TREATMENT:
4.1 Splashes of the eye
Immediately flood the eye with to be effective the eyelids must
be opened. The eyelids should be pushed apart using the thumb and
index finger of the left hand. The casualty neither will probably
nor is able to open the eye himself because of painful spasms. If
an eye wash bottle is used the jet should not be directed at the
front of the eye. It should be directed in from the side, so that
flow is over the surface of the eye.
Irrigation should be continued for 5 10 minutes after which the
casualty should be taken to the first aid room.
Irrigation should be continued in the first aid room. Remember
vision is saved by thorough irrigation; no other treatment can
prevent damage if this is omitted.
After thorough irrigation the eye should be covered with a pad;
the patient should be referred for medical opinion.
4.2 Irritation of the skin
If signs of skin irritation occur the persons should be removed
from contact and referred for medical opinion. In the event of the
splashing of the skin with chemicals the effected area should be
washed thoroughly avoiding spreading contamination to the face and
eyes.
5. EMERGENCY PROCEDURES:
The testing team should be aware of the operating procedures of
fire extinguishers to be used for quenching minor or major
fires.
The testing team should be aware of the procedure to be followed
in case of accidents involving personnel injury.
In case of failure of running pump the stand by pump should be
started immediately without delay.
An operator posted at the pump, area should be instructed to
stop the pumps and properly isolate the system in the event of
emergency. All operators should be well conversant with the
emergency operating instructions
6. General Safety
Test area will be cordoned off and unauthorized persons entry
shall be prohibited. Suitable shall be displayed.
Whenever any inspection is made during the cleaning process, the
location should be adequately ventilated.
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ARUDRA ENGINEERS PVT LTD PROJECT EMCO ENERGY THERMAL POWER
PROJECT LTDCLIENT EVERSENDAI CONSTRUCTION PVT LTD Rev o TITLE
TESTING METHOD FOR CHEMICAL CLEANING Page 1 of 7
CHEMICAL TESTING PROCEDURE
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ARUDRA ENGINEERS PVT LTD PROJECT GMR ENERGY LTD
CLIENT UTILITY ENERGYTECH ENGINEERS PVT LTD Rev o
TITLE TESTING METHOD FOR CHEMICAL CLEANING Page 2 of 7
1. INHIBITOR EVALUATION
INHIBITOR:
An inhibitor is a chemical substance, when added in small
concentration effectively decreased the corrosion rate. Pickling
Inhibitors used for practical applications are usually mixtures of
various chemicals. Most of the pickling inhibitors function by
forming an absorbed layer on the metal surface. Probably, no more
than a mono layer in thickness which essentially blocks discharge
of HYDROGEN ION and dissolution of metal ions. It should be borne
in mind that an addition of an inhibitor to an acid, the corrosion
potential of steel is not altered although the corrosion rate may
be appreciably reduced.
Inhibitor is chosen for a particular solvent and application to
provide maximum protection and minimize substantially the rate of
corrosion of parent metal. Temperature of the bath and time of
contact of the metal with the solvent are decisive factors in the
function.
It is therefore essential to test the inhibitor for evaluation
prior to its usage specifically for two functions:
01. Percentage of protection offered 02. Corrosion rate
reduction obtained
PROCEDURE:
Prepare test coupons in duplicate of the material to be
chemically cleaned, for example carbon steel SA 213 T1 etc. The
surface area of each coupon in no case should be less than 25
sq.cm. It should be polished on all sides. Close to mirror surface
quality and free of sharp edges. There shall be no oxide scale left
on the surface.
The coupon should be degreased with Acetone initially. Prepare
in a container, 400 ml. of the acid bath mixed with inhibitor.
Measure accurately, the surface area of the coupon - A sq.cm.
Weight the acetone cleaned dry coupon - WI mgms. Prepare acid bath
in 400 ml. (Hot 65-70 deg.C.). DM water adding acid solvent
selected to attain required concentration of the acid and 0.3%
inhibitor.
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ARUDRA ENGINEERS PVT LTD PROJECT GMR ENERGY LTD
CLIENT UTILITY ENERGYTECH ENGINEERS PVT LTD Rev o
TITLE TESTING METHOD FOR CHEMICAL CLEANING Page 3 of 7
Hang the sample in the bath (nylon rope) well immersed without
touching the container walls. Note the time. Keep the container in
an oven and strictly maintain the temperature at 65 700
C.Remove the coupon exactly after 60 minutes. Do not touch by
hand. Wash it in hot DM water several times. Acetones dry
perfectly.
Cool in a dessicator. Desiccant should be only silica gel.
Weigh the coupon - W2 mgm.
Express corrosion rate mgm/sq.cm./hr.
W1 - W2 ----------- mg./sq.cm. A
Efficiency of the inhibitor is evaluated as follows:
Repeat the procedure with two weighed coupons under similar
conditions of acid strength, temperature and time.
One pre-weighed coupon should be immersed in uninhibited acid
for 60 minutes.
The other pre-weighed coupon should be immersed in inhibited
acid for 60 minutes.
Work out metal loss in both the cases.
Efficiency of the inhibitor:
X = Loss of Wt.in uninhibited acid
Y = Loss of Wt.in inhibited acid
Efficiency = X - Y ------ x 100% X
(Accepted weight loss of mild steel should be
0.1mgm./sq.cm./hr.)
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ARUDRA ENGINEERS PVT LTD PROJECT GMR ENERGY LTD
CLIENT UTILITY ENERGYTECH ENGINEERS PVT LTD Rev o
TITLE TESTING METHOD FOR CHEMICAL CLEANING Page 4 of 7
2. DETERMINATION OF TSP, DSP and Alkalinity;
Reagents required:
01. Hydrochloric Acid Standard (0.05N) 02. Mixed Indicator
Solution (0.5g of bromocresol green + 0.75 gm. Of methyl
red/1 ltr.of ethylalcohol. 03. Phenolphthalein Indicator
Solution (dissolve 1g. in 100 ml. Of
ethylalcohol).Procedure:
Pipette 10 ml. of filtered solution into a 150 ml beaker. Add 4
drops of phenolphthalein indicator, titrate against o.05N of HCL
solution until colourless, Record the volume as (PE). Add few drops
of mixed indicator to the same conical flask, titrate without
refilling the burette to a reddish-grey end point. Record the
volume as (ME).
Calculation:
The concentration of Na3Po4 and DSP solution as follows;
Na3Po4 (TSP) ppm: PE x 1900
Na2Hpo4.7H2o (DSP) ppm: ME - (2PE) x 1340
3. DETERMINATION OF HYDROCHLORIC ACID
Required reagents:1. 1N NaOH solution 2. Mixed Indicator (0.075
gm. Methyl Red and 0.05gm. Bromocresol Green
100ml. Ethanol). Procedure:
x Take 10ml. of sample in a clean conical flask. x Add 50 ml. of
DM water x Add 3-5 drops of Indicator x Titrate it against 1N NaOH
solution x The end point is red to green
Calculation: % of HCl = T.V. x 1N x 36.5 x 100
---------------------------- 10 x 1000
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ARUDRA ENGINEERS PVT LTD PROJECT GMR ENERGY LTD
CLIENT UTILITY ENERGYTECH ENGINEERS PVT LTD Rev o
TITLE TESTING METHOD FOR CHEMICAL CLEANING Page 5 of 7
= T.V. x 0.365
5. DETERMINATION OF IRON
Required reagents:1. 0.05 M EDTA 2. Chloroacetic acid 10% 3.
Sodium Acetate 10% 4. Sulphosalicyclic Acid 20% 5. Potassium
Per-sulphate
Procedure:x Take 10ml. of aliquot in a clean Erlenmeyer flask. x
Add 5 to 10 drops of 10% chloroacetic acid solution. x Add 5 to 10
drops of 10% sodium acetate solution. x Add 5 drops of 20%
sulphosalicyclic acid. x Add pinch of potasium persulphate x
Titrate against 0.05 M EDTA x End point is red to pale yellow
colour. x
Calculation:
Iron as Fe ppm = T.V. x 0.05 x 55.847 x 1000
--------------------------------- V
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ARUDRA ENGINEERS PVT LTD PROJECT GMR ENERGY LTD
CLIENT UTILITY ENERGYTECH ENGINEERS PVT LTD Rev o
TITLE TESTING METHOD FOR CHEMICAL CLEANING Page 6 of 7
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10.0 INPUTS REQUIREMENT FROM ECPL Sr.No DESCRIPTION REMARKS
A Utility Requirements
1 DM water (for one unit cleaning) 3500 M3/unit 2 Service
water(for one unit cleaning) 5000 M3/unit 3 Electrical A.C. Power
supply (3 phase 415 V) 300 Kw 4 Emergency Power supply (3 phase 415
V) 200 Kw 5 Construction Power Supply (3 Phase 415 V) 125 Kw *6
Auxiliary Steam supply 10-15 T/hr @ 15 Kg/Cm2 at 185 Deg C.(in
continuous
rating) Optional *7 Neutralization Pit f( for Holding 2 boiler
volume) B Area Requirements
1 Open Space requirement for installation of chemical
cleaning system and auxiliary boiler. 20 m X 15 m
2 Open Area requirement for site office/ material and chemical
storage.
12 m x 15 m
3 2SHQ6SDFHUHTXLUHPHQWROHYHOIRULQVWDOODWLRQRIpre-fabricated
neutralization tank on river bed
45 m x 15 m
C General Requirements
1 Hydra Crane facility for loading & unloading of materials
and equipments.
2 Necessary cutting and re-welding of permanent line if
required
3 Removal and refitting of drum internal 4 Round the clock gate
pass 5 Incoming power supply cable from your panel board up to
cleaning area.
6 Illumination facility at cleaning area 7 Fire tender/ambulance
facility during cleaning process for
emergency use
8 Necessary road crossing digging and refilling for laying
temporary drain pipe from chemical cleaning area up to
neutralization pit.
Note:
*6. Offer Enclosed *7. Offer Enclosed
-
11. LIST OF EOUIPMENTS.
Sr.No DESCRIPTION OF ITEM QTY 01 Chemical Mixing Tank (20 M3) 1
No 02 Motor Pump (2 Pump running, 2 Standby ) (Technical
Spec- 150 HP /2900 RPM/300 M3 /hr at 12 Kg/CM2 ) 4 Set
03 MCC Panel 150 HP 1 Set 04 C.S. Valves 150 Class With
Flange
8 Inch As required 6 Inch As required 4 Inch As required 3 Inch
As required 2 Inch As required 1 Inch As required 8 Inch NRV As
required 4 Inch NRV As required
05 M.S. ERW PIPES
8 Inch 800 M 6 Inch 150 M 4 Inch 475 M 3 Inch 100 M 2 Inch 200 M
1 Inch 50 M
06 Nitrogen Manifold with Regulator.
1 Set
07 Pressure Gauges 0-20 kg/cm2
6 Nos
08 Temperature Gauges 0- 100 0C
3 Nos
09 Compound gauges 1 214
1 Set
10 Pipe fittings Elbows/Reducers
As required
11 Tools Box with tools
As required
12 Express Laboratory
1 Set
13 Auxiliary Boiler 20 TPH @17.5 kg / cm2@ 205 DegC 1 sets
14 Neutralization tank 180 M3 each
3 tank