School of Engineering Thermodynamics Chapter 2: The World Energy System Dr. Jorge Francisco Estela Uribe
May 11, 2015
School of EngineeringThermodynamics
Chapter 2: The World Energy System
Dr. Jorge Francisco Estela Uribe
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ThermodynamicsDr. Jorge Francisco Estela
The World Energy System
Primary energy:
Primary energy is the total energy contents of a natural resource. It is the
energy in raw form without any transformation. It is the total energy that is
available for transformation and end use.
Energy carriers:
These are forms of energy between primary energy sources, from which
they are transformed, and the end use forms, to which they are converted.
Energy consumption:
As energy is always conserved, the concept of consumption only means
the transformation of energy to the forms of end use, i.e. energy services.
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Energy flows:
Primary energy
Transformation
Final use
Energy carrier
Reserves Exports Imports
Exports Imports
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Sources of primary energy:
HydroelectricityWindOcean (waves, currents, thermal gradient)Bioenergy
Indirect
ThermalPhotovoltaic
Direct
GeothermalTidal
Uranium (nuclear energy)
Crude oil
Coal
Natural gas
Non-solar
Mineral fuels
SolarFossil fuels
Renewable sourcesNon-renewable sources
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Primary energy, energy carriers and energy systems* :
Uranium
Natural gas
Coal
Crude oil
Nuclear power plantElectricity
Fossil fuel power station
Enthalpy, mechanical work, electricity
Oil refineryLiquid fuelsNon-renewable sources
Energy systems (conversion processes)
Energy carriers
Primary energy sources
* www.wikipedia.org
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Primary energy, energy carriers and energy systems* :
Biomass power stationEnthalpy, electricityBiomass sources
Geothermal power stationEnthalpy, electricityGeothermal energy
Hydropower plant, wave farm, tidal power station
Mechanical work, electricity
Flowing water, tidal energy
Wind farmMechanical work, electricity
Wind energy
Photovoltaic power plantElectricity
Solar energy Solar power tower, solar furnace
EnthalpyRenewable sources
Energy systems (conversion processes)
Energy carriers
Primary energy sources
* www.wikipedia.org
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The World Energy System
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Who uses energy:
ThermodynamicsDr. Jorge Francisco Estela
The World Energy System
�Those who drink potable water and eat non-raw food.
�Those who need to preserve food and other materials.
�Those who need heating, air conditioning or ventilation.
�Those who need artificial illumination.
�Those who need to travel through long distances.
�Those who need mechanical for their work.
�And those who do not wish or can not put aside all the technological
amenities, gadgets and services of modern society.
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Historical uses of energy per capita*:
* E. Cook, The Flow of Energy in an Industrial Society, Scientific American, September 1971
92025236426440Technological
308569612828Industrial
1044284824Advanced agriculture
48161616Primitive agriculture
20812Stone age
88Primitive
TotalTransportIndustry & agriculture
Home & commerce
Food
Daily per capita consumption, MJPeriod
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The World Energy System
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International Energy Agency, Key Energy Statistics 2011
0 1 2 3 4 5 6 7 8 9
Energy supply per capita (toe/capita)
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00
Hum
an D
evel
opm
ent I
ndex
Quality of Life and Energy Supply
Norway
NetherlandsNew Zeland
Mexico
Portugal
RussiaSaudi Arabia
South Africa
Spain
SwedenSwitzerland
United Kingdom
United States
Argentina
Australia
Austria
Brazil
Canada
Chile
Colombia
Denmark
Egypt
Ethiopia
FinlandFrance
Germany
JapanGreece
China
IndiaPakistan
Haiti
Mozambique
Sudan
Venezuela
Uruguay
Morocco
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The World Energy System
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International Energy Agency, Key Energy Statistics 2011
ThermodynamicsDr. Jorge Francisco Estela
The World Energy System
0 1 2 3 4 5 6
Energy Supply per capita (toe/capita)
0
10
20
30G
DP
per
cap
ita (
US
D/c
apita
)x10
00
Energy Supply and GDP 2009
OECD
Middle East
Non-OECD Europe & AsiaChina
Latin America
AsiaAfrica
World Average
Wor
ld A
vera
ge
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International Energy Agency, Key Energy Statistics 2011
ThermodynamicsDr. Jorge Francisco Estela
The World Energy System
0 1 2 3 4 5 6
Energy Efficiency (USD/toe)x1000
0
10
20
30
GD
P p
er c
apita
(U
SD
/cap
ita)x
1000
Energy Effciency and GDP 2009
World Average
Wor
ld A
vera
ge
OECD
Middle East
Non-OECD Eurasia ChinaAsia
Latin America
Africa
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Is this really necessary? Is it an excess…?
ThermodynamicsDr. Jorge Francisco Estela
The World Energy System
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Are these really necessary or are they excessive wa ste of energy?
ThermodynamicsDr. Jorge Francisco Estela
The World Energy System
Sustainable energy: why is it so important?
�The supply of energy is essential for the well-being of society.
�The current energy systems have been built around the multiple advantages of the fossil fuels.
�The duration of the fossil fuels reserves is a highly disputed issue, but those are essentially finite and will run out completely.
�The reserves of fossil fuels are concentrated on a relatively few countries, which leads to instability, crises and conflicts.
�The exploitation of fossil fuels entails significant threats to human health due to their extraction, distribution and final use.
�The combustion of fossil fuels produces enormous amounts of greenhouse gases.
Sustainability 14/84
G. Boyle, B. Everett, J. Ramage, Energy Systems and Sustainability: Power for a Sustainable Future, Oxford University Press, 2003.
ThermodynamicsDr. Jorge Francisco Estela
Sustainable energy: why is it so important?
�There is a sound scientific consensus about the connections between the anthropogenic emissions of greenhouse gases and the unprecedentedincrease in ambient temperatures since the last ice age.
�The increase in global temperatures will severely disrupt agriculture, all ecosystems and the economic system in a generalised scale.
�Nuclear energy does not emit greenhouse gases but its development has been limited by high operating costs and the public concern about the release of radioactive materials, catastrophic accidents, the disposal of radioactive wastes and the proliferation of materials for nuclear weapons.
�The efficiency of the conversion of energy from resources down to the energy services is very low and the cost of those services is very low.
Sustainability 15/84
G. Boyle, B. Everett, J. Ramage, Energy Systems and Sustainability: Power for a Sustainable Future, Oxford University Press, 2003.
ThermodynamicsDr. Jorge Francisco Estela
Sustainable energy: why is it so important?
�The above two circumstances make the environmental and social effects
of the energy systems larger than what those should really be.
�The renewable energy sources are based on energy flows, not on energy
stocks, and are expected to play a much larger role in the future.
�The environmental and social impacts of the renewable energy sources
are, in general, smaller than those from the conventional sources.
�However, there are other constraints for their widespread use such as
their intermittence and limited availability, the lack of a global infrastructure
for their distribution and use and the high costs for the end user.
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G. Boyle, B. Everett, J. Ramage, Energy Systems and Sustainability: Power for a Sustainable Future, Oxford University Press, 2003.
ThermodynamicsDr. Jorge Francisco Estela
2136
Transport: 2284
3 70 52 23 11 644 186 690 433 147 618 1000
Industry: 2282 Res., Comm., Agr.: 3040
Oil: 3987
Coal:3300
Natural Gas:2540
Nuclear:703
Hydraulic:280
Biofuels, Waste: 1238
Others:102
Liquid fuels: 3874
31 236 2139 1006 703 280 94
Consumption for electricity/heat: 4591
Conversion losses: 2641 1950
102
37
553
Non
-ene
rgy:
747
Total Primary Energy Supply and Consumption by Sect ors 2009TPES: 12150 Mtoe; TFC: 8353 Mtoe; Total Losses: 379 7 Mtoe
842441310
136
330
20
51
206
26964 237
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ThermodynamicsDr. Jorge Francisco Estela
Primary Energy Energy in Carriers Consumption by Sectors0
2000
4000
6000
8000
10000
12000
Mto
eTotal Primary Energy Supply and Total Final Consumption 2009
Oil
Coal
Natural Gas
Nuclear
Biofules/WasteH
ydra
ulic
Oth
ers
Liquid fuels
Electricity/Heat
Losses in
conversion and
transmission
Transport
Industry
Residential,Commercial,Agricultural
12150
8353
3797
Coal
Biofuels/Waste
Natural Gas
Non-energy
International Energy Agency, Key Energy Statistics 2011
The World Energy System 18/84
Petroleum:
1. www.wikipedia.org
2. G. Boyle, B.Everett, J. Ramage, Energy Systems and Sustainability, Power for a Sustainable Future, Oxford University Press, Oxford, 2003.
Petroleum is a naturally occurring complex flammable liquid mixture of hydrocarbons and other organic compounds [1].
Petroleum was formed by the decomposition, under high temperature and pressure in sedimentary rocks, of marine organisms, i.e. zooplankton and algae [2]. Thus, petroleum is currently found in sedimentary basins where marine sediments accumulated over time (the Middle East, the Gulf of Mexico or the North Sea).
Petroleum is converted into useful products by distillation (fractioning), i.e. separation by differences in boiling points of the liquid components. Those products are complex blends suited to particular commercial uses.
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ThermodynamicsDr. Jorge Francisco Estela
Broad composition by fractions and uses*:
* www.wikipedia.org
Waxes, asphalts26 – 35Asphaltenes
Fuel oil, lubricating oil, marine diesel
17 – 25Heavy distillate
Diesel fuel, kerosene, jet fuel
Nonane -Hexadecane
9 – 16Medium distillate
GasolinePentane - Octane5 – 8Light distillate
Gaseous fuels, petrochemicals
Methane - Butane1 – 4Petroleum gases
UsesHydrocarbonsCarbon atoms
Fractions
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ThermodynamicsDr. Jorge Francisco Estela
Conventional and non-conventional petroleum*:
* G. Boyle, B.Everett, J. Ramage, Energy Systems and Sustainability, Power for a Sustainable Future, Oxford
University Press, Oxford, 2003.
Petroleum that is obtained by the natural pressure of an underground reservoir is called conventional oil. Conventional oil is extracted by two methods and applies to roughly half of the petroleum reserves:
�Primary recovery: applies when the pressure of the reservoir is sufficient to drive the crude oil to the surface.
�Secondary recovery: the pressure of the reservoir has to be increased by the injection of natural gas or water.
Non-conventional petroleum applies to oil extracted by tertiary recovery (with high-pressure natural gas or CO2 to recover the remaining crude in the reservoirs) or from all other sources, i.e. shale oil, tar sands and heavy oil.
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Coal:
1. www.wikipedia.org
Coal is a combustible black or brownish-black sedimentary rock usually
occurring in layers called coal beds or coal seams [1]. Coal is composed
primarily of carbon, hydrogen, oxygen, nitrogen and sulphur.
Coal was formed by the decomposition, under high temperature and
pressure and in the absence of oxygen, of dead vegetation. This is why
coal deposits are widely spread in the world.
According to its heating value (heat released in combustion) and contents
of volatiles, coal is classified in ranks. In ascending order of heating value,
these are: peat, lignite, sub-bituminous, bituminous and anthracite.
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Natural Gas:
1. www.wikipedia.org
Natural gas is a naturally occurring hydrocarbon mixture, primarily
composed of methane, other hydrocarbons (ethane up to octane), nitrogen,
carbon dioxide and hydrogen sulphide [1].
Natural gas is found in deep underground formations or associated with
coal seams and petroleum deposits. Natural gas is created either by two
processes: a biogenic process (decomposition) of organic material in
shallow sediments, or by thermogenic process at great depths.
Before use, natural gas has to undergo extensive treatment to remove
undesirable components, such as nitrogen, carbon dioxide and hydrogen
sulphide.
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Nuclear energy:
1. www.wikipedia.org
Nuclear energy results from the sustained use of the energy released by
nuclear fission to generate electricity and heat [1].
In nuclear fission, the nuclei of heavy atoms (i.e. Uranium-235) split into
lighter nuclei and free neutrons. As the combined mass of the fission
products is slightly smaller than that of the original nucleus, the mass
defect is converted into energy in the form of photons (gamma radiation)
and kinetic energy of the products. The kinetic energy is transformed into
thermal energy, which is then used to generate electricity in a power cycle.
The released neutrons hit other nuclei causing their fission. Thus, a chain
reaction is established so that a sustained nuclear energy operation is
possible in practice.
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Nuclear energy:
1. www.wikipedia.org
Nuclear energy has always been a controversial issue. Its is an important
component of the world energy system for it produces about 7 per cent of
the world primary energy supply and about 14 per cent of the electricity [1].
The advocates of nuclear energy claim it is a sustainable form of energy for
it does no release greenhouse gases, but the processing of uranium
minerals do have important environmental impacts. The opponents sustain
that nuclear energy poses serious threats to human health and the
environment. Those threats come from the accidental release of
radioactive materials and from the very important issue of the disposal of
used nuclear fuels. There are also the security concerns as nuclear
reactors can be used to produce radioactive materials for weapons use.
ThermodynamicsDr. Jorge Francisco Estela
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Nuclear reactors:
1. www.wikipedia.org
About 80 per cent of reactors use light water as moderator. Three quarters
of those are pressurised water reactors [1].
Pressurised water reactors (PWRs): the reactor core is in a high-pressure
vessel is cooled by a primary circuit of pressurised water. The primary
water transfers heat to a secondary circuit in a steam generator. Then, the
secondary water drives the power cycle.
Boiling water reactors (BWRs): they are PWRs but water boils directly in
the pressure vessel. Therefore, these are simpler and safer than PWRs.
Other technologies include the pressurised heavy water reactor (PHWR),
the gas cooled reactors (GCR) and a number of experimental designs.
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Hydroelectricity:
1. www.wikipedia.org
Hydroelectricity is electricity generated by hydropower, i.e. from the potential energy of water falling through a difference of elevation. This is the second largest source of renewable energy, accounting for about a sixth of the world’s electricity generation [1].
The technologies are: the conventional dams; pumped storage (at times of low demand, water is pumped to higher elevations to be used at times of high demand) and run-of-the-river (it does not use a dam and the water is taken directly from the river to the generator).
Hydroelectricity is cheap and does not release carbon dioxide. But it has important environmental impacts because of the disruption of habitats (by the areas that have to be inundated) and the decay of vegetation under water releases methane (a more powerful greenhouse gas than carbon dioxide).
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Renewable energy:
1. www.wikipedia.org
Renewable energy rely on natural processes that are continuouslyreplenished [1]. Apart from the comparatively very small amount of geothermal and tidal energy, ultimately almost all renewable energy forms are transformations from solar energy.
Renewable energy accounts for around 16 per cent of the total primary energy supply and participates with about 19 per cent in the generation of electricity.
Climate change awareness, high oil prices and peak oil are driving a very rapid expansion in investment, development and commercialisation of renewable energy technologies. Those markets are growing at rates far exceeding 20 per cent per annum.
Renewable energy technologies are expected to play quite significant a role in power generation, space heating and transport fuels.
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Advantages of renewable energy sources:
1. www.wikipedia.org
�The very fact that they are continuously replenished by natural processes.
�The fact that they are fluxes and not stocks of energy.
�They are considerably more benign in environmental and health impacts
than fossil fuels and nuclear energy.
Disadvantages of renewable energy sources:
� They are intermittent, so that storage technologies are needed.
� Their distribution and availability is very limited because the infrastructure
for distribution and commercialisation is, so far, very limited.
� They remain to be expensive to the end user.
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ThermodynamicsDr. Jorge Francisco Estela
Oil and natural gas: why are they so special?
Oil and natural gas comprise half of the world primary energy supply and
consumption because of the following undisputable advantages:
�The are cheap and easily available.
�They are less contaminant than coal.
�They are convenient and easy to use.
�They are easy to distribute, store and transport.
�For many countries, the supply is ensured from domestic production.
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ThermodynamicsDr. Jorge Francisco Estela
British Petroleum, BP Statistical Review of World Energy, June 2011
Oil Natural Gas Coal0
10
20
30
40
50
60
70
80
90
100
Per
cent
age
Regional Distribution of Fossil Fuel Reserves
North America
S&C America
Europe/Eurasia
Middle East
Africa
Asia/Pacific
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North America
South & Central America
Europe & Eurasia
Middle East
Africa
Asia Pacific
World Average
0 50 100 150 200 250
Years
Reserves/Production Ratios of Fossil Fuels 2009
Oil Natural Gas Coal
Average Middle East and Africa
British Petroleum, BP Statistical Review of World Energy, June 2011
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ThermodynamicsDr. Jorge Francisco Estela
Environmental and social impacts associated with en ergy sources*:
Effects on landscape and biodiversity, ground water pollution due to fertilisers, use of scarce water, competition with food production.
Biomass
Radioactivity (routine release, risk of accidents, waste disposal), misuse of fissile and other radioactive materials, proliferation of nuclear weapons, land pollution by mining, health effects on uranium miners.
Nuclear power
Global climate change, acid rain, environmental spoliation by open-cast mining, land subsidence due to deep mining, ground water pollution, mining accidents, health effect on miners.
Coal
Global climate change, methane leakage from pipes, methane explosions, gas rig accidents.
Natural gas
Global climate change, air pollution by vehicles, acid rain, oil spills, oil rig accidents.
Oil
Potential impacts and concernsSource
* G. Boyle, B.Everett, J. Ramage, Energy Systems and Sustainability, Power for a Sustainable Future, Oxford University Press, Oxford, 2003.
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ThermodynamicsDr. Jorge Francisco Estela
Environmental and social impacts associated with en ergy sources*:
Sequestration of large land areas (centralised plants), use of toxic materials in manufacture of PV cells, visual intrusion.
Solar energy
Release of polluting gases (SO2, H2S, etc.), ground water pollution by chemicals including heavy metals, seismic effects.
Geothermal energy
Visual intrusion and destruction of wildlife habitat, reduced dispersal of effluents (apply only to tidal barrages).
Tidal power
Visual intrusion in sensitive landscapes, noise, bird strikes, interference with telecommunications.
Wind power
Displacement of communities, effects on rivers and ground water,dams (visual intrusion and risk of accidents), seismic effects, downstream effects on agriculture, methane emission from submerged biomass.
Hydroelectricity
Potential impacts and concernsSource
* G. Boyle, B.Everett, J. Ramage, Energy Systems and Sustainability, Power for a Sustainable Future, Oxford University Press, Oxford, 2003.
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International Energy Agency, Key Energy Statistics 2011
CO2 Emissions by Fuel 2009Oil 10643
36.7%
Coal 12470
43%Natural Gas 5771
19.9%
Renewables 116
0.4%
OECD 1204 43%
Middle East 1509 5%
Non-OECD Eurasia 2497 9%
China 6877 25%Asia 3153 11%
Latin America 975 3%Africa 928 3%
28999 x 10 6 ton
CO2 Emissions by Region
28999 x 106 ton
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ThermodynamicsDr. Jorge Francisco Estela
0 1 2 3 4 5 6
Energy Supply per capita (toe/capita)
0
5
10
15C
O2
Em
issi
ons
per
capi
ta (
ton/
capi
ta)
CO2 Emissions and Energy Supply 2009
OECD
Middle East
Non-OECD Eurasia
China
Latin AmericaAsia
Africa
World Average
Wor
ld A
vera
ge
International Energy Agency, Key Energy Statistics 2011
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ThermodynamicsDr. Jorge Francisco Estela
Emissions scenarios:
-0.51.5CO2/TPES
2.00.5TPES/cap
1.00.5Population
Growth scenarios28,99916,95412,045Emissions, Mton/year
12,1506,5825,238TPES, Mtoe
2.3872.532.300Intensity CO2, Mton/Mtoe
1.971.2494.276TPES/cap, toe/cap6,7615,5361,225Population, million
Base line 2009
TotalRest of the world
OECD
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ThermodynamicsDr. Jorge Francisco Estela
Emissions scenarios:
1,650,0231,204,731445,292Released CO2, Mton
3,771,541Accumulated CO2, Mton
482Concentration CO2, ppm
56,52946,7729,757Emissions, Mton/year
3,029,031Stock CO2, Mton
31,30223,4187,885TPES, Mtoe
1.8061.971.237Intensity CO2, Mton/Mtoe
3.852.8135.246TPES/cap, toe/cap9,8288,3251,503Population, million
Projections 2050
TotalRest of the world
OECD
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ThermodynamicsDr. Jorge Francisco Estela
Strategies for the control of atmospheric carbon di oxide*:
•Install CCS systems in 800 large power stations.
•Install CCS systems in carbon gasification plants.
•Install CCS systems in hydrogen production plants for 1500 million vehicles.
Capture and storage of CO 2 (CCS)
•Increase the thermal efficiency from 40 to 60 per cent in 1,600 large power stations (> 1 GW).
•Replace 1,400 large power stations with CCGT.
Power generation
•Increase the fuel economy of 2000 million automobiles from 48 km/gallon to 96 km/gallon.
•Reduce the use of 2000 million automobiles from 16,000 km/year to 8,000 km/year at and average 50 km/h.
•Reduce in 25 per cent the electricity consumption in residentialand commercial uses.
Efficiency of end uses and conservation
Technologies and patterns of useStrategies
*R.H. Sokolow, S.W. Pacala, A Plan to Keep Carbon in Check, Scientific American, September (2006, 28-35.
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ThermodynamicsDr. Jorge Francisco Estela
Strategies for the control of atmospheric carbon di oxide*:
•Stop all deforestation.
•Extend conventional agriculture practices to the whole cultivable land.
Agriculture and forestry management
•Double the generation of nuclear energy to displace carbon consumption.
•Multiply by 40 the generation of wind power to displace carbon consumption..
•Multiply by 700 the generation of solar energy to displace carbon consumption..
•Multiply by 80 the generation of wind power to produce hydrogen for automobiles.•Power 2000 million automobiles with ethanol produced from 1/6 ofthe total cultivable land and biomass with yield of 15 ton/ha.
Alternative energy sources
Technologies and patterns of useStrategies
*R.H. Sokolow, S.W. Pacala, A Plan to Keep Carbon in Check, Scientific American, September (2006, 28-35.
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ThermodynamicsDr. Jorge Francisco Estela
Renewables Share of World TPES 2009
CombustibleRenewables and waste:
10.6%
Hydroenergy:2.2%
Others: 0.5%
Geothermal:0.414%
Solar: 0.039%
Wind: 0.064%
Tide: 0.0004%
Oil
34.3%
Coal
25.1%
Natural Gas
20.9%
Nuclear
6.5%
Renewables
13.1%
International Energy Agency, Key Energy Statistics 2011
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ThermodynamicsDr. Jorge Francisco Estela
Potential resources of renewable energy*:
>2,800
TPES (2009): 500 x 1018 J. TPES (2100): 510 – 2700 x 10 18 J.
Total renewable sources:
>1,600Solar: 10 per cent efficiency of conversion solar radiation.
>20Geothermal: potential of the most promising locations.
>20Tidal: potential of the most promising locations.
>630Wind: 35 per cent of the potential in continental areas and coastal waters.
70Hydroelectricity: equivalent to half of the energy of all the rivers in the world.
>440Biomass: equivalent of 35 x 109 ton/year.
Potential, 10 18 J/yearSource
* Intergovernmental Panel on Climate Change, Third Assessment Report, 2001
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ThermodynamicsDr. Jorge Francisco Estela
Renewable energy scenarios:
As of 2009, all renewable sources (hydroelectricity, biofuels, waste and others) accounted for 13.3 per cent of the world TPES.
International Energy Agency: Scenarios to 2030
�Current Policy Scenario: All renewable sources would increase to 14.2 per cent.
�450 Policy Scenario: All renewable sources would increase to 22.1 per cent.
British Petroleum: Scenario to 2030
It foresees the doubling of the percentage of renewable energy in the TPES.
US Energy Information Administration: Scenario to 2035
It also foresees the doubling of the share of renewable energy in the TPES.
Royal Dutch Shell: Scenario to 2050
It foresees that renewable energy would account around 25 to 30 per cent of TPES.
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ThermodynamicsDr. Jorge Francisco Estela
The hydrogen economy:
It means the proposed extensive use of hydrogen as an energy carrier. Hydrogen does not occur freely in nature. Therefore, hydrogen is not a primary energy source, it is an energy carrier.
Hydrogen is produced basically by reforming of natural gas. It is also produced by electrolysis of water and by biotechnological processes involving algae and micro organisms.
Hydrogen is currently used for: petroleum refining (hydrocracking), the production of ammonia, methanol and hydrochloric acid, the hydrogenation of vegetable oils, the reduction of minerals, the treatment of metals, welding in reducing atmosphere, cooling of generators and for rocket fuels.
As the production of hydrogen is an energy expensive process, the feasibility of the hydrogen economy depends on coupling it with a zero- or low-emission energy source.
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ThermodynamicsDr. Jorge Francisco Estela
Technological challenges for the hydrogen economy:
Production:
If it is produced by reforming of hydrocarbons, it has to be coupled with CCS systems. If it is produced by electrolysis of water, the electricity must come from zero-emissions sources.
Storage in vehicles:
The mass energy density of hydrogen of 120 MJ/kg is much higher than that of gasoline (46 MJ/kg). But, due to its very low molar mass, the hydrogen volume energy density (10 MJ/m3) is much smaller than that of gasoline (35000 MJ/m3). Therefore, it has to be used either as compressed gas (∼70 MPa) or as cryogenic liquid (∼-253°C), but both processes would consume up to 30 per cent of the carried energy. The use as metallic hydrides, that solve the problem of volume storage, would otherwise impose heavy penalties in terms of weight and cost.
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ThermodynamicsDr. Jorge Francisco Estela
Hydrogen economy based on fossil fuels:
Fuel cells
Gas turbines
Liquefaction
Hydrogen from reforming ofnatural gas
CO2 capture
Geologic storage
Gas turbines
Homes,industry,transport
Gaseous hydrogen
Liquid hydrogen
Natural gas
CO2
Electricity
Reforming: CH4 + 2H2O → CO2 + 4H2
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Natural gas wells
ThermodynamicsDr. Jorge Francisco Estela
Solar and nuclear hydrogen economy:
Fuel cells
Gas turbines
Liquefaction
Homes,industry,transport
Gaseous hydrogen
Liquid hydrogen
Electricity
HydroelectricityWindPhotovoltaicWavesNuclear
Hydrogen from electrolysis
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ThermodynamicsDr. Jorge Francisco Estela
Energy sustainability: how to achieve it*:
To achieve a sustainable world energy system, the following is needed:
To develop much improved technologies for the exploitation and use of
fossil and nuclear fuels with much lower environmental and social impacts.
To significantly develop and implement renewable energy technologies in a
significantly greater scale.
To significantly improve the efficiency of the conversion, distribution and
end use of energy and change the patterns of use of energy.
* G. Boyle, B.Everett, J. Ramage, Energy Systems and Sustainability, Power for a Sustainable Future, Oxford University Press, Oxford, 2003.
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ThermodynamicsDr. Jorge Francisco Estela
More sustainable fossil fuels*:
Improve the efficiency of combustion:
�Highly efficient combined-cycle gas turbines (CCGT, IGCC).�Combined use of heat and power (co-generation).�Improved heating systems and appliances.�More efficient internal combustion engines.
Reduce the combustion emissions:�Removal of sulphur dioxide.�Smaller emissions of nitrogen oxides and particulates.�Capture and storage of carbon dioxide (CCS).
Non-combustion conversion of energy:�Fuel cells.
* G. Boyle, B.Everett, J. Ramage, Energy Systems and Sustainability, Power for a Sustainable Future, Oxford University Press, Oxford, 2003.
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ThermodynamicsDr. Jorge Francisco Estela
Technology perspectives for energy sustainability*:
Transforming the energy services:
�Improved energy efficiency in buildings, industry and vehicles.
Transforming the energy supply:
�Advanced combustion and CCS.
�Generation of electricity from natural gas and nuclear energy.
�Generation of electricity from renewable sources.
�Use of biofuels and hydrogen fuel cells in vehicles.
Transforming the electric system:
�Advanced storage technologies for intermittent renewable sources.
�Integration of power transmission and telecommunications.
* International Energy Agency, Energy Technologies Perspectives; Energy Technologies for a Sustainable Future, 2005 .
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ThermodynamicsDr. Jorge Francisco Estela
Conclusions:
�The world energy system is the largest and most complex industrial operation in the world. This is so because energy is essential for our civilisation.
�Although we cannot dispense with the energy supply, the world energy system has significant environmental impacts and threats to human health.
� Due to the undeniable conveniences of fossil fuels, about 80 per cent of the world energy system relies upon the use of these fuels. Climate change results from the carbon dioxide emitted by combustion of coal, oil and natural gas. The increase in temperatures, the raise of sea level and changes in rain patterns will affect all aspects of human life by the second half of the century.
�A shift to extensive use of low-emissions renewable energy sources is the only solution to mitigate in the medium term the effects of climate change. A number of promising technologies are well identified, but much more research and investment is needed to progress towards the extensive commercialisation of renewable energy.
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