ˆ - LeMondePrépa.Frlemondeprepa.fr/cours/MPSI-Physique-Chimie.pdf · ˘ˇˆ ˙ ˝˛˛˘˚˜ˆ [ mpsi – chimie ].....1

[ MPSI – CHIMIE ]...................................................................................................................................................1

CHIMIE DES SOLUTIONS.....................................................................................................................................2 1 – LOI DES EQUILIBRES CHIMIQUES ..........................................................................................................................2 2 – CONDUCTIVITE D'UNE SOLUTION AQUEUSE ..........................................................................................................2 3 – COUPLES ACIDE / BASE........................................................................................................................................4 4 – EQUILIBRES DE COMPLEXATION ..........................................................................................................................5 5 – REACTIONS DE PRECIPITATION ............................................................................................................................7 6 – OXYDOREDUCTION .............................................................................................................................................8 7 – POTENTIELS D'ELECTRODE ..................................................................................................................................9

STRUCTURE DE LA MATIERE .......................................................................................................................... 13 8 – STRUCTURE ATOMIQUE DE LA MATIERE ............................................................................................................. 13 9 – LES NOMBRES QUANTIQUES .............................................................................................................................. 13 10 – ORGANISATION ELECTRONIQUE DES ATOMES ................................................................................................... 14 11 – CLASSIFICATION PERIODIQUE DES ELEMENTS ................................................................................................... 15 12 – STRUCTURE ELECTRONIQUE DES MOLECULES................................................................................................... 16 13 – STRUCTURE CRISTALLINE................................................................................................................................ 18 14 – RESULTATS DE L'EQUATION DE SCHRÖDINGER POUR UN SYSTEME HYDROGENOÏDE............................................ 21 15 – L'ATOME POLYELECTRONIQUE ........................................................................................................................ 22

CINETIQUE CHIMIQUE...................................................................................................................................... 25 16 – LOIS EXPERIMENTALES DE LA CINETIQUE CHIMIQUE ......................................................................................... 25 17 – CINETIQUE FORMELLE..................................................................................................................................... 27 18 – MECANISMES REACTIONNELS .......................................................................................................................... 29

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