Managing CBM Product Water A Learning Process With Outcomes James W. Bauder Krista E. Pearson Department of Land Resources & Environmental Sciences Montana.
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Managing CBM Product WaterA Learning Process With Outcomes
James W. Bauder
Krista E. Pearson
Department of Land Resources & Environmental Sciences
Montana State University - Bozeman
Background Information
• Extraction of CBM requires withdrawal of large amounts of saline-sodic water from coal seams containing methane.
• Projections call for disposal or management of one quarter million acre-feet of product water annually in the Powder River Basin.
Coal bed methane development is neither new nor confined to the Powder River Basin.
Photo courtesy of Dudley Rice, U.S. Geological Survey
Objectives
• CBM Product Water – What does it look like?
• What are the interactions between CBM product water and the landscape?
• Can we effectively manage CBM product water?
CBM Product Water – What does it look like?
• The common signature of coal bed methane product water is salinity x sodicity.
Wildcat Creek, Campbell County, WY – Tributary to Little Powder River
What is saline water and why is it considered saline?
• Saline water has a relatively high concentration of dissolved salts.
• Salinity of water is referred to in terms of total dissolved solids (TDS).– Salinity is estimated by measuring the electrical
conductivity (EC) of water.• The U.S. Department of Agriculture defines water
with an EC greater than 3.0 dS/m as saline.
What is sodic water and why is it considered sodic?
• The sodicity of water is expressed as the sodium adsorption ratio which is:
• Sodic water is any water with a SAR greater than 12. Sodic water is not necessarily saline.
SA R N a / (C a + M g ) / 2
Chemistry of CBM Product Water upon Surface Dispersal
Holly Sessoms
MSU Graduate Research
Objective: Determine the behavior of chemistry of CBM product water in stream channels.
CBM Product Water Chemistry
• CBM product water is bicarbonate rich and under pressure in coal seams.
• When product water is exposed to the atmosphere, discharged into surface water or applied to soil, sodium bicarbonate undergoes the following reaction:
NaHCO3 H+ + CO3-2 + Na+
CBM Product Water Chemistry
• Free carbonate (CO3-2) in solution is now
available to bind with calcium in the surface water or soil to form calcium carbonate, i.e., limestone or calcite.
Ca+2 + 2HCO3- CaCO3
- + H20 + CO2
CBM Product Water Chemistry
• The dissolution of sodium bicarbonate (NaHCO3
-) also causes pH to increase with the formation of sodium hydroxide (NaOH):
Na+ + H+ CO3 CO2 + Na+ +OH-
CBM Product Water Chemistry
• In summary, sodium bicarbonate-rich CBM product water will initiate the precipitation of calcium carbonate causing:• SAR will increase• EC values may decrease slightly • pH will increase
CBM Product Water Chemistry
• In a laboratory experiment at MSU, water qualities 6, 7, and 8 with shown initial pH, EC, and SAR values were exposed to the atmosphere for a 9 day period. Initial pH, EC, and SAR reflect changes in CBM product water below the outfall point.
Change in water chemistry for three water qualities over a 9 day time
period (subject to evapoconcentration).
Initial
pHFinal pH
Initial EC
Final EC
Initial SAR
Final SAR
% Change
EC
% Change
SAR
WQ6 7.4 8.1 3.07 3.75 3.7 4.4 22.15 18.92
WQ7 7.7 8.4 3.36 4.01 12.5 18 19.35 44.00
WQ8 7.5 9.1 5.42 6.71 20.7 33.8 23.80 63.29
Average %
Change 21.77 42.07
Soil Chemistry Responses to Saline-Sodic Water
Kimberly Robinson
MSU Graduate Research
Objective: Determine how soils which may be subjected to irrigation will react with repeated wetting with saline-sodic water.
Soil Chemistry Responses to Saline-Sodic Water
• More than 4 dozen soil materials were collected at sample sites within the Powder River Basin.
• The samples were leached with various water qualities and soil chemical changes were assessed.
Sampling locations within Powder River watershed, Prairie County Conservation District, and Buffalo Rapids Irrigation District.
Soil textural triangle, illustrating representation of individual soil materials treated with various water quality x wetting regimes.
Irrigation Simulation Conditions
• Water Quality– Powder River
• EC = 1.6 dS/m SAR = 4.5 pH = 8.0
– CBM Product Water• EC = 3.1 dS/m SAR = 13.0 pH = 8.0
• Irrigation Treatment– Powder River:
• 1x 5x 5x then distilled water
– CBM Product Water: • 1x 5x 5x then distilled
water
0
2
4
6
8
10
12
4 6 7 8 9 15 17 18 19 21 21 22 23 26 28 29 30 33 33 34 37 44 45 52 56
Ranked Clay %
EC
(d
S/m
) (S
atu
rate
d P
aste
Ext
ract
)
Baseline
1X Wet/Dry-P.R.
1X Wet/Dry-CBM
5X Wet/Dry-P.R.
5X Wet/Dry-P.R.+distilled
5X Wet/Dry-CBM
5X Wet/Dry-CBM + distilled
Copyright: K. M. Robinson, MSU-BozemanLand Resources Environmental Science-2002
Textural Class 1 Textural Class 2 Textural Class 3 Textural Class 4
P.R. Treatment EC
CBM Treatment EC
Soil solution saturated paste extract (ECsat) versus percent clay of soil material prior to
treatment (baseline) and following treatment with various water quality x wetting regimes
Soil solution SAR versus percent clay of soil material prior to treatment (baseline) and following treatment with various water quality x wetting
regimes
0
5
10
15
20
25
30
4 6 7 8 9 15 17 18 19 21 21 22 23 26 28 29 30 33 33 34 37 44 45 52 56
Ranked Clay %
SA
R (S
atu
rate
d P
aste
Ext
ract
)
Baseline
1X Wet/Dry-P.R.
1X Wet/Dry-CBM
5X Wet/Dry-P.R.
5X Wet/Dry-P.R.+distilled
5X Wet/Dry-CBM
5X Wet/Dry-CBM+distilled
Copyright: K. M. Robinson, MSU-BozemanLand Resources Environmental Science-2002
Textural Class 1 Textural Class 2 Textural Class 3 Textural Class 4
CBM Treatment SAR
P.R. Treatment SAR
What are the common difficulties with the use of sodic water for irrigation?
• Use of sodic water for irrigation can be risky business on soils having significant amounts of swelling clay. On such soils:– Sodium changes soil physical properties,
leading to poor drainage and crusting, which can affect crop growth and yield.
– Irrigation with sodic water on sandy soils does not cause crusting and poor drainage. However, if the water is saline-sodic, it may affect crop growth and yield.
Effect of EC and SAR of applied water on relative hydraulic conductivity (Source: Shainberg and Letey, 1984).
Suggested range in EC and SAR of irrigation water for various soil textures
Soil Texture EC range (mmhos/cm)
SAR upper limit
Flood Sprinkler Flood Sprinkler
Very Coarsesand, loamy sand
0-4 0-5 18 24
Coarsesandy loam
0-3 0-4.5 12 15
Mediumloam, silt loam
0.2-2.5 0-3 12 15
Medium fineclay loam, sandy clay loam
0.3-2.5 0.2-3 8 12
FineSilty clay loam, sandy clay, clay, silty clay
0.5-2 0.3-2.5 6 9
Source: Western Fertilizer Handbook
1. Thresholds for irrigation.
What are the common problems or difficulties with the use of saline water for irrigation?
• Crop production becomes a problem as salts accumulate in the root zone high enough to negatively affect plant growth.
• Excess soluble salts in the root zone restrict plant roots from withdrawing water from the surrounding soil.
0
5
10
15
20
25
30
0 2 4 6 8 10 12
EC (dS/m)
SA
R (
soil)
Baseline
1X Wet/Dry-P.R.
1X Wet/Dry-CBM
5X Wet/Dry-CBM
5X Wet/Dry-CBM + Distilled
5X Wet/Dry-P.R.
5X Wet/Dry-P.R. + Distilled
Copyright: K. M. Robinson, MSU-BozemanLand Resources Environmental Science-2002
SAR = 1.46 (EC) + 1.29R2 = .54
Soil solution saturated paste extract (ECsat) versus soil solution SAR of soil material prior to treatment (baseline) and following treatment with various water quality x wetting regimes. Solid diagonal lines represent dispersion risk and salinity thresholds previously reported by Ayers
and Westcot (1976), Tanji and Ayers (1981), Hansen et al. (1999), Miller and Donahue (1999) and others.
No Reduction in Infiltration
Slight to Moderate Reduction in Infiltration
Severe Reduction in Infiltration
SAR = 12
EC = 3
Tolerant
EC > 10
Semi-Tolerant
EC = 4-10
Sensitive
EC < 4
Crops Barley
Sugarbeet
Sunflower
Wheat
Oats
Corn
Safflower
Potato
Field Bean
Peas
Lentils
Forages Tall wheatgrass
Bearless wildrye
Altai wildrye
Slender wheatgrass
Western Wheatgrass
Russian wildrye
Barley
Sweetclover
Alfalfa
Tall Fescue
Wheat (hay)
Orchardgrass
Cicer milkvetch
White clover
Red clover
Ladino clover
Alsike clover
Meadow foxtail
Crop Tolerance to Saline Water
Salinity & Sodicity Tolerance of Selected Plant Species of the Northern Cheyenne Reservation
Nikos J. Warrance
MSU Graduate Research
Objective: Understand how native and culturally
significant plant species would respond to increases in salinity and sodicity.
Tolerance and/or sensitivity of selected plants on the Northern Cheyenne Reservation to
salinity, sodicity, and flooding
• Understand how native and culturally significant plants would respond to increases in salinity and sodicity.
• A list of native and culturally significant plant species was obtained from the Department of Environmental Protection, Northern Cheyenne Tribe.
• A thorough search of references dealing with salinity, and sodicity tolerances for the plants in question was then undertaken.
Examples of culturally significant plant species of the Northern Cheyenne
Reservation
• Sensitive (EC < 2 dS/m, SAR 1.6 - 8– June/Service Berry– Red Osier Dogwood– Red Shoot Goose Berry– Chokecherry– Wild Plum– Quaking Aspen– Leafy Aster– Red Raspberry
• Moderately Sensitive (EC 2-4 dS/m, SAR <8)– Common Spikerush– Field Horsetail– Horsemint– Sweet Medicine– Sandbar Willow– Snowberry– Cattail– Sweet Grass– Saw Beak Sedge– Stinging Nettle– Western Yarrow
Recommended Wetland Species and Aggressive Invaders
Dry/moist transition area species include:• Canada wildrye (Elymus canadenisis)• Slender wheatgrass (Elymus trachycaulus)• Western wheatgrass (Pascopyrum smithii)• Tall wheatgrass (Thinopyrum ponticum)
Native and survivors:• Inland saltgrass (Distichlis spicata)• Prarie and Alkali cordgrass (Spartina pectinata and gracilis)• Baltic rush (Juncus balticus)• Nuttalls alkaligrass (Pucinellia nuttalliana)• Foxtail Barley (Hordium jubatum)
Wet area and in channel survivors or invaders include:• American bulrush (Scirpus americanus)• Sea Coast bulrush (Scirpus maritimus)• Baltic Rush (Juncus balticus)
Screening for Salt Tolerant Forage Species
Allison Levy
MSU Undergraduate Research
Objective: To determine the survivability and early plant biomass production of sixteen different forage species irrigated with water qualities that have been chosen to represent conditions of water surface supplies that could result from coal bed methane development.
Common Name Scientific Name
Corn Zea mays
Altai Elymus angustus
Tall Wheatgrass Agropyron elongatum
Crested Wheatgrass Agropyron cristatum
Kochia Kochia scorparia
Sorghum Bicolor (L.) moench
Intermediate Wheatgrass Agropyron intermedium
Newhly Wheatgrass Elyrtigia repens x Pseudoroegneria spicata
Tall Fescue Festuca arundinacea
Paiute Orchardgrass Dactylis glomerata L.
Slender Wheatgrass Agropyron trachycaulum
Perennial Ryegrass Lolium perennal
Valier Hordeum valier
Sugarbeets Beta vulgaris L.
Hi Mag Tall Fescue Festuca arundinacea hi mag
2nd Gen. Alfalfa Medicago sativa
Species Used in Screening for Salt Tolerance
Common Name Scientific Name
Tall fescue Festuca arundinacea
Intermediate wheatgrass Agropyron intermedium
Slender wheatgrass Agropyron trachycaulum
Altai Elymus angustus
Sorghum Bicolor (L.) moench
Corn Zea maysValier hay barley Hordeum valier
The Short List
The short list consists of eight forage species that were chosen for a long-term experiment to assess forage biomass production in greenhouse conditions.
Summary: Lessons Learned
• Sustainable CBM product water management requires rigorous monitoring and coordinated management. The essential requirements include:– Soil, water, and plant baseline information.– Quantity and quality of CBM product water.– Rigorous monitoring at all points.– Coordinated water management with multiple
strategies.
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