-
Date June 28, 2011
EnviroPlanning AB Lilla Bommen 5 C, SE-411 04 Göteborg,
Sweden
Visitor address Lilla Bommen 5 C Telephone +46 31 771 87 40
Telefax +46 31 771 87 41
Web site www.enviroplanning.se e-mail [email protected]
Report
Worst ingredients in dishwasher detergents Italian and
Portuguese products
Deco Pro Teste
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
I (III)
U:\40
83-0
1\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
About the report
Title Worst ingredients in dishwasher detergents
Italian and Portuguese products
Version 001
Date June 28, 2011
Client Deco Pro Teste
Avenida Eng. Arantes e Oliveira, nº13, 1ºB
1900-221 Lisbon
Portugal
Project number 4083-01
Document number 4083-01\10\01\Report.doc
Report written by Helena Norin and Maria Sjö
Report reviewed by Jenny Robinson
Report verified by Helena Norin
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
II (III)
U:\40
83-0
1\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
Summary Deco Pro Teste is preparing a review of dishwasher
detergents available on the Italian and Portuguese market. One part
of this review is related to the ingredients in the chosen
products. EnviroPlanning has been hired to assess the environmental
and health properties of the ingredients in order to determine the
most hazardous ingredients in the dishwasher detergents chosen.
The substances are chosen because of bad environmental or health
properties. The concentration of the substances in the products has
not been taken into account, only the hazards of the ingredients.
The survey shows that it is possible to manufacture products
without these substances.
For dishwasher detergents almost all the products contained one
or more of the worst ingredients. The 11 worst ingredients were
found in 21 out of 24 products, and consequently only 3 products
contained none of the worst ingredients. The products with the
highest number of worst substances were, from Portugal,
Finish-Calgonit Quantum, Dia 5 em 1 and W5 All in 1 Detergente em
Pastilhas and, from Italy, Finish Powerball Quantum Tabs. These
products used all four of the worst ingredients.
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
III (III)
U:\40
83-0
1\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
Table of contents
1 Introduction
......................................................................
1
1.1 General information
........................................................... 1
2 Description of the survey
................................................... 1
2.1 Selection of products
......................................................... 1
2.2 Collection of ingredient lists on internet
............................. 2
2.3 Compilation of used ingredients
......................................... 3
2.4 Environmental and health hazards of selected
chemicals
..........................................................................
3
2.5 Sources of information
....................................................... 4
3 Ingredients in dishwasher detergents
................................ 5
4 Most hazardous substances in dishwasher detergents .........
7
5 Data gaps
........................................................................
10
6 Differences between Portugal, Italy and Belgium ..............
11
7 Conclusions
.....................................................................
11
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
1 (14) U
:\408
3-01
\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
1 Introduction
1.1 General information
Deco Pro Teste is preparing a review of dishwasher detergents on
the Italian and Portuguese market. One part of this review is
related to the ingredients in the chosen products. EnviroPlanning
has been hired to assess the environmental and health properties of
the ingredients in order to determine about ten of the most
un-wanted ingredients.
2 Description of the survey
2.1 Selection of products
A selection of representative brands was made by Deco Pro Teste
in Portugal with colleagues in Italy. For Italy 12 different
dishwasher detergents were chosen, see Table 1. For Portugal 12
different dishwasher detergents were chosen, see Table 2.
Table 1. Dishwasher detergents from Italy.
Brand Product EAN code
AUCHAN Tutto in uno - limone 8005476508847
CARREFOUR Tutto in 1 3560070319527
COOP Pastiglie lavastoviglie 3 in 1 8001120826046
ESSELUNGA Pastiglie Lavastoviglie 3:1 limone 8002330107147
FAIRY TUTTO IN 1 5413149852860
FINISH Powerball Classic 8002910022129
FINISH Powerball Quantum 8002910030438
FINISH Powerball Tutto in 1 8002910026424
PRIL 10 Ultra Brillante 8015100561971
PRIL 5 Ultra Brillante 8015100562008
PRIL Tabs Igiene con Bicarbonato 8015100562497
W5 All in 1 20174682
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
2 (14)
U:\40
83-0
1\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
Table 2. Dishwasher detergents from Portugal.
Brand Product EAN code
APTA Tout en 1 (Pastilhas Tudo em 1 para máquina de lavar
loiça)
3250391046843
AUCHAN Tudo em 1 8410104080808
FINISH-CALGONIT Quantum 5011417548110
FINISH-CALGONIT Tudo em 1 5201347155315
CONTINENTE Tudo em 1 5601312036296
DIA 5 em 1 8480017608864
FAIRY Platinum 5413149873957
FAIRY Ultra Caps 5413149661691
SUN All in 1 - Extra Power 8718114473987
SUN All in 1 8718114461243
ULTRA PRO 5 em 1 Ultra 4 + Protecção do Aço Inoxidável
5601009943470
W5 All in 1 Detergente em Pastilhas 20234614
2.2 Collection of ingredient lists on internet
The ingredients in dishwasher detergents must, according to the
European detergents legislation, be publicly accessible on internet
pages.1 The manufacturers should use specific INCI2 names for the
chemicals or names used in the European Pharmacopoeia3, if INCI
names don’t exist.
The address of the website must be written on the package of a
product. For Procter & Gamble brands, a production code is
needed as well, to have access to the list of ingredients. The
production code, also known as batch number, is printed on the
package. The ingredients should be given in descending order based
on the concentration in the product, but the concentrations of the
individual ingredients don’t need to be stated.
1 Regulation (EC) No 648/2004 on detergents 2 CosIng is the
European Commission database with information on cosmetic
ingredients http://ec.europa.eu/consumers/cosmetics/cosing/ INCI
stands for International Nomenclature Cosmetic Ingredient 3
http://www.edqm.eu/site/Background-amp-Legal-Framework-50.html
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
3 (14) U
:\408
3-01
\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
The ingredient lists were collected for the selected products.
All ingredient lists were collected and compiled by Deco Pro
Teste.
2.3 Compilation of used ingredients
The ingredients were compiled in a database in MS Excel by Deco
Pro Teste. If available, Deco Pro Teste also included CAS-numbers
to the database. When available, the correct INCI nomenclature as
well as the missing CAS-numbers were added and used. In total 182
ingredients were used in the examined dishwasher detergents. Some
ingredient names could be identified as the same as another one, so
that the actual number of different ingredients is 169. As some
ingredients were identified as neither INCI or European
Pharmacopoeia names, nor more general chemical names, the actual
number of ingredients may be lower, if the ingredients with unknown
names are identical with other known ingredients.
There was a wide range in how many ingredients the different
products contained, varying from 6 to 44.
2.4 Environmental and health hazards of selected chemicals
A screening of the properties of the substances used was made
using relevant sources of information (see “2.5 Sources of
information”). The results were compiled in the MS Excel file
mentioned above. This screening indicated which substances contain
the most hazardous properties to the environment and human
health.
The environmental properties used for determination of the worst
ingredients were:
Toxicity to aquatic organisms
Biodegradability
Bioaccumulation
Health aspects include CMR substances (carcinogenic, mutagenic
and toxic to reproduction) and allergy.
Eutrophication
No substances have been chosen only because of poor
biodegradability. For substances where data for different species
are available, the most sensitive species
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
4 (14)
U:\40
83-0
1\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
has been used for the evaluation. The toxicity to aquatic
organisms is an important property for dishwasher detergents, as
all of them end up in the waste water and may harm aquatic
organisms. Bioaccumulation, substances entering the food chain
without being excreted, is another property important for the
environment. Many substances may accumulate in fat tissue and,
especially if they are toxic, may cause harm. They may cause harm
even if they are not so toxic if they take the place of other
natural and important substances in the body.
The main human health effect found for the substances used in
the products are sensitizing substances that may cause allergic
reactions.
Eutrophication is chosen as phosphorous in detergents contribute
to eutrophication of European waters. In more and more European
countries phosphates are being phased out in washing powders and
some countries are also phasing them out or restricting the use in
dishwasher detergents. Italy accepts 6%, Phosphorous in a dish
washer detergent, while Norway restricts it to 3,8% and Sweden to
0,5%. This has led to products formulated without phosphates in
Norway and Sweden, but in Italy most products still contain
phosphates (as will be seen in Table 4).
Out of the chosen products does 17 products contain phosphate,
14 phosphonates and one phopsphoric acid.
2.5 Sources of information
To identify the properties of the ingredients, different sources
of information were used. The Nordic Swan and the European
eco-label (the EU Flower) have developed a Detergent Ingredient
Database4 of the ingredients in household chemical products which
was used to identify the properties of the ingredients. As this
database does not cover all ingredients used in products, but
focuses mostly on those that may be used in eco-labeled products,
other sources of information were used as well.
Toxicological and eco-toxicological information is the base for
classification and labeling of chemical products. The database for
classification from the former European Chemicals Bureau5 was also
used as a source for checking properties. It is however important
to know that all chemicals do not have an official classification,
but the classification is made by the manufacturers and it can not
be found in the
4
http://ec.europa.eu/environment/ecolabel/ecolabelled_products/categories/did_list_en.htm
5 http://tcsweb3.jrc.it/classification-labelling/clp/
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
5 (14) U
:\408
3-01
\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
official databases. The Swedish database Chemical Substances6
from Prevent was also used to collect information on properties as
well as the recently published OECD database e-chemportal7.
Official priority lists of chemicals with most hazardous
characteristics that ideally should be substituted are published in
Sweden8, Norway9 and Denmark10. These lists have their background
in official classification system. The SIN list 2.011, an NGO
initiative led by ChemSec, cover substances that fall within the
definition of “substances of very high concern” according to the
European chemicals legislation REACH. All these lists contain
substances with severe potential effects on environment and
health.
3 Ingredients in dishwasher detergents
The main purpose with dishwasher detergents is to clean the
dishes in an automated dishwasher. This is done by surfactants that
bind to fat and grease and make the lipids suspend in water. When
the lipids are suspended in water they are possible to rinse away.
Other important ingredients are builders and anti re-depositioning
agents. Builders react with calcium and magnesium ions in the water
to make the water softer. Soft water requires less amount of
surfactant to clean the dishes. Anti re-depositioning agents
prevent grease in the water from settling on the cleaned dishes.
Table 3 shows the most common ingredients in dishwasher
detergents.
Table 3. General dishwasher ingredients.
Function Used for Example
6 http://kemi.prevent.se/default_eng.asp 7
http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
8 PRIO – a tool for Risk Reduction of Chemicals
http://www.kemi.se/templates/PRIOEngframes____4144.aspx 9 List of
Priority Substances – State of the Environment Norway
http://www.miljostatus.no/en/Topics/Hazardous-chemicals/Hazardous-chemical-lists/List-of-Priority-Substances/
10 Listen over uønskede stoffer 2009(in Danish) Environmental
Protection Agency-Danish Ministry of the Environment
http://www2.mst.dk/udgiv/publikationer/2010/978-87-92617-15-6/pdf/978-87-92617-16-3.pdf
11 http://www.sinlist.org/
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
6 (14)
U:\40
83-0
1\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
Surfactants Suspends grease in the water which then can be
rinsed away.
Amino acids
Fatty alcohols
Builders React with ions like calcium and magnesium in hard
waterto make the surfactants work more effectively.
Phosphates
Zeolites
Polycarboxylic acid
Oxidizing agent Bleaching stains by oxidation. Sodium carbonate
peroxide
Enzymes Microbiological substances that react and dissolve
specific stains like blood, egg and fat.
Amylase
Protease
Anti re-depositioning agents
Prevents dirt in suspension from resettling on the clean
dishes.
Polyethylene glycol (PEG)
Color & fragrance Color and fragrance are used to make the
product appear more attractive to the consumer and to enhance the
difference between products.
Limonene
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
7 (14) U
:\408
3-01
\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
4 Most hazardous substances in dishwasher detergents
The criteria used to rank the different products in the survey
based on the ingredients environmental and health properties have
been any or more of the following:
Substances
not being readily biodegradable
more toxic than 1mg/l
with bioaccumulation factor above 100 or log Kow above 3
sensitizing in contact with the skin
endocrine disrupting
releasing phosphorous to the environment
The ranking resulted in a selection of eleven most hazardous
ingredients, based on the properties of the substances.
Several of the most hazardous ingredients are antimicrobials,
which often are hazardous to the environment as well as sensitizing
to humans. A wide use of antimicrobial substances may lead to
increased resistance among bacteria. This may result in the usage
of more powerful antibacterial substances needed to kill bacteria
in the few cases where the bacteria need to be killed. Dishwasher
detergents do not need antimicrobial substances to clean the dishes
and more than 50% of the products did not contain
antimicrobials.
A group of substances that is not biodegradable is colorants.
They are widely used in dishwasher detergents. They are used in low
amounts in the detergents and it was chosen not to include them in
the list of worst ingredients. However, their use does not
contribute to the function of the detergents.
Benzisothiazolinone
This substance is a preservative and an antimicrobial with a
toxicity to algae of 0,15 mg/l. It is inherently biodegradable in
an aerobic environment and not biodegradable in anaerobic
conditions. It is officially classified as harmful if swallowed,
irritating to skin, cause serious eye damage, may cause
sensitization by skin contact and is very toxic to aquatic
organisms. As the products assessed are solid, the use of
preservatives is deemed unnecessary as preservatives are used to
prevent mould in
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
8 (14)
U:\40
83-0
1\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
aqueous solutions during storage. Benzisothiazolinone is hence
chosen as one of the most hazardous substances. Benzisothiazolinone
is not a permitted preservative in cosmetics, according to the
Cosmetics Directive 76/768/EEC.
Zinc acetate and zinc sulphate
Zinc acetate and zinc sulphate are antimicrobial substances
which are very toxic to fish and algae. The use of antimicrobial
substances in dishwasher detergents is not necessary to clean the
dishes. Wide use of antimicrobial substances may lead to increased
resistance among bacteria. This may result in the usage of more
powerful antibacterial substances needed to kill bacteria in the
few cases where the bacteria need to be killed. Zinc sulphate has
toxicity to fresh water fish (LC50) as low as 0,084 mg/l. This
value is far below 1 mg/l, the limit for “very toxic to aquatic
organisms”.
Phosphates and Pentasodium triphosphate
Some of the studied dishwasher detergents used the substance
name pentasodium triphosphate and some did not give a specific
name, but only used the group name phosphates. Phosphates are used
as builders or complexing agents in dishwasher detergents. The
water is softened and less surfactant is needed to clean the goods.
Phosphates contribute to the eutrophication and in some European
countries such as Sweden, Norway and Italy, the presence of
phosphates in dishwasher detergents is forbidden or heavily
restricted. In Italy is maximum 6% phosphorus allowed, which
correspond to 24% phosphate. According to a Swedish report most of
the Italian dishwasher detergents uses phosphate at a level just
below the limit.12 For laundry detergents a recent proposal for an
EU wide ban has been presented.13 The environmental movement
regretted that the proposed ban did not cover dishwasher detergents
as well.14 Phosphates are considered as one of the most hazardous
ingredients, since there are other builders, as well as phosphate
free dishwasher detergents available on the market. Phosphates are
chosen as one of the worst substances due to their eutrophication
properties.
12
http://www.kemi.se/upload/Medier/Pressmeddelanden/2007/Fosfater_i_maskindiskmedel.pdf
13 Commission proposal COM (2010) 597 amending Regulation (EC) No
648/2004 as regards the use of phosphates and other phosphorous
compounds in household laundry detergents 14
http://wwf.panda.org/about_our_earth/about_freshwater/freshwater_news/?196405/Commissions-proposal-to-ban-phosphates-in-laundry-detergents
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
9 (14) U
:\408
3-01
\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
Phosphonates, Tetrasodium etidronate & Ethylenediamine-tetra
(methylene
phosphonic acid)-Ca-Na-salt
In this survey two different phosphonate substances were
identified, as well as the group name phosphonates. The specified
phosphonates are tetrasodium etidronate and ethylenediamine-tetra
(methylene phosphonic acid)-Ca-Na-salt. Phosphonates is a large
group of chemicals with many different substances. Little
information is available about the characteristics of different
phosphonates, but some sources indicate that the substances are not
biodegradable and have low toxicity. Tetrasodium etidronate have
been determined to to have similar properties as other phosphonates
since data for this substance was not available.
Ethylenediamine-tetra (methylene phosphonic acid)-Ca-Na-salt is
readily biodegradable, unlike most phosphonates.
Limonene
This substance is used as a perfume and deodorant and is among
the 26 most sensitizing substances in fragrances.15 Such substances
have to be declared in the list of ingredients. The use of
fragrances in dishwasher detergents can be questioned and
especially the substances with known sensitizing properties.
Limonene is readily biodegradable but it is also very toxic to
aquatic organisms and it bioaccumulates. It is officially
classified as flammable, irritating to skin, may cause sensitation
by skin contact, very toxic to aquatic organisms and may cause
long-term adverse effects in the aquatic environment.
Petroleum distillates
This is a petroleum based substance that is used as a solvent or
antifoaming. It may bioaccumulate and it is not readily
biodegradable. Different sources indicate that petroleum
distillates are toxic to aquatic organisms, but it varies from
moderate to very toxic. It is officially classified as potentially
carcinogenic. The classification is not valid if the substance
contains less than 0,1% by weight of 1,3-butadiene. The
manufacturer of the detergent is responsible to make sure that the
substance is pure enough to avoid the risk of cancer. There are
many solvents with better
15 Opinion SCCNFP/0017/98 and Regulation (EC) No 648/2004 on
detergents
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
10 (14)
U:\40
83-0
1\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
ecotoxicological properties and is why this substance is one of
the most hazardous solvents.
Sodium polynaphthalenesulfonate
This substance is persistent in the environment. It is a
polymerization product of naphthalene sulfonic acid and
formaldehyde it is one of the worst substances because formaldehyde
is carcinogenic.
5 Data gaps
For some of the ingredients there were no, or very few,
ecotoxicological data to be found. This could be because the name
of the ingredient is not specific enough, for example “metal
protection agents” or “oxygenated optical brightener”. It can also
be that the substance is poorly investigated. For 9% of the
substances surveyed, the information available was not enough to
make a proper conclusion. These data gaps can lead to the fact that
new substances might show up as unwanted substances in the future,
since there is not enough information available to evaluate their
properties. The same applies to many of the polymeric ingredients
being both difficult to identify and to find any information about.
Concerning optical brighteners, they do not have any cleaning
properties, but makes the cleaned object appear whiter and are
mostly used in laundry detergents. They are normally not used in
dish washer detergents, which is why it may be assumed that the
substance could be a bleaching agent, such as sodium
percarbonate.
Ethylene/propylene oxide copolymer
Ethylene/propylene oxide copolymer with the CAS number 9003-11-6
corresponds with 73 different INCI names, and the ecotoxicological
results also differ. The substance is persistent or only partially
biodegradable. Some sources indicate that the substance is toxic to
aquatic organisms, but there are others that show a low toxicity.
This substance is not present in eco-labeled products from the same
manufacturer of dishwasher detergents.
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
11 (14) U
:\408
3-01
\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
6 Differences between Portugal, Italy and Belgium
An earlier survey of 12 dishwasher detergents in Belgium showed
both similar and different results16. Five of the twelve dishwasher
detergents in the aforementioned survey were also included in this
survey for Portugal and Italy. Most of them had a similar recipe in
the different countries. About 80% of the ingredients were the same
in Finish, Sun and W5, but the products by Carrefour varied more.
In Belgium 50% of the studied dishwasher detergents were
phosphate-free but only about 40% in Portugal and 20% in Italy.
7 Conclusions
Of all the substances in this survey some remain unevaluated due
to the lack of available data and correct naming. As mentioned
earlier, the ingredient lists should use the CosIng nomenclature or
the European Pharmacopeia. This is not followed by all
manufacturers. Despite Deco Pro Teste’s efforts to make a list of
INCI names, not all ingredients were possible to identify, this
applies to about 6% of the ingredients.
In Tables 4 and 5 the most hazardous substances are presented
together with the products containing them. The substances were
chosen because of their effects on environment or human health. The
concentration of the substances in the products has not been taken
into account, only the hazards of the ingredients. The survey shows
that it is possible to manufacture products without these
substances.
For the dishwasher detergents 21 of 24 products contained one or
more of the most hazardous ingredients. In Italy, there was only
one product completely free of these substances, Coop Pastiglie
lavastoviglie 3 in 1, and in Portugal there were two, Fairy
Platinum and Fairy Ultra Caps. There were four products with four
of the most hazardous substances. From Portugal: Finish-Calgonit
Quantum, Dia 5 em 1 and W5 All in 1 Detergente em Pastilhas. From
Italy: Finish Powerball Quantum Tabs.
The use of phosphorous is questionable due to their
eutrophicating properties and the fact that all dishwasher
detergents end up in the waste water system. Out of 24 dishwasher
detergents 20 contained phosphate or phosphonate. Three of the four
phosphorous free products were also free of the other hazardous
ingredients. That
16 Détergents lave-vaisselle. Test-Achats 552 • avril 2011
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
12 (14)
U:\40
83-0
1\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
means that all but one phosphate/phosphonate using product also
contains one or more of the other hazardous ingredients.
Table 4. Worst substances in dishwasher detergents in Italy
Name Function
Au
chan
Tu
tto
in
un
o -
lim
on
e
Carr
efo
ur
Tu
tto
in
1
Esselu
ng
a P
asti
gli
e L
avasto
vig
lie
3:1
lim
on
e
Fair
y T
utt
o in
1 (
Ori
gin
al)
Fin
ish
Po
we
rba
ll C
lassic
Fin
ish
Po
we
rba
ll Q
uan
tum
Tab
s
Fin
ish
Po
we
rba
ll t
ab
s T
utt
o in
1
Pri
l 1
0 U
ltra
-Bri
llan
te (
tab
s)
Peil
5 U
ltra
-Bri
llan
te (
Ta
bs)
Pri
l U
ltra
-Bri
llan
te i
gie
ne c
on
bic
arb
on
ato
(ta
bs)
W5
All
in
1
Benzisothiazolinone Antimicrobial x
Ethylene diamine-tetra (methylene phosphonic acid)-Ca-Na-salt
Sequestrant x
Limonene Deodorant, Perfuming x x x x x
Pentasodium triphosphate Sequestrant x x x x x x x x x x
Petroleum distillates Solvent
Phosphates Sequestrant
Phosphonate okänd Sequestrant
Sodium polynaphtalenesulfonate Surfactant x
Tetrasodium etidronate Sequestrant x x x x
Zinc acetate Antimicrobial x
Zinc sulfate Antimicrobial x x x
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
13 (14) U
:\408
3-01
\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
Table 5. Worst substances in dishwasher detergents in
Portugal
Name Function
Ap
ta T
ou
t en
1 (
Pasti
lhas T
ud
o e
m 1
pa
ra
máq
uin
a d
e l
avar
loiç
a)
Au
chan
Tu
do
em
1
Fin
ish
-Calg
on
it Q
uan
tum
Fin
ish
-Calg
on
it T
ud
o e
m 1
Co
nti
nen
te T
ud
o e
m 1
Dia
5 e
m 1
Su
n A
ll in
1 -
Extr
a P
ow
er
Su
n A
ll in
1
Ult
ra P
ro 5
em
1
U
ltra
4 +
Pro
tecçã
o d
o A
ço I
no
xid
áve
l
W5
All
in
1 D
ete
rgen
te e
m P
asti
lhas
Benzisothiazolinone Antimicrobial x x
Ethylene diamine-tetra (methylene phosphonic acid)-Ca-Na-salt
Sequestrant
Limonene Deodorant, Perfuming x x
Pentasodium triphosphate Sequestrant x x x x x x
Petroleum distillates Solvent x
Phosphates Sequestrant x
Phosphonate okänd Sequestrant x x x x
Sodium polynaphtalenesulfonate Surfactant
Tetrasodium etidronate Sequestrant x x x x x x
Zinc acetate Antimicrobial x
Zinc sulfate Antimicrobial x x x x
-
Worst ingredients in WC cleaners Date June 28, 2011
Italian and Portuguese products Version Final
Doc.no 4083-01\10\01\Report.doc
14 (14)
U:\40
83-0
1\10-
udo\0
1-utr
\Rep
ort 4
083-
01.d
oc
References
See footnotes in the report.