RESEARCH GROUP ON ELECTROSPINNING CIRI MAM Nanofibers by Electrospinning Process Nanofibers by Electrospinning Process the ES group at Alma Mater ‐ Bologna University RESEARCH GROUP ON ELECTROSPINNING CIRI MAM Electrospinning of polymeric fibers Electrospinning of polymeric fibers From macromolecules Polymeric solution From macromolecules … Entanglements Disordered … to sub‐micrometric fibers Microfiber Disordered macromolecules Partially of fully orientation of macromolecules macromolecules Nanofiber
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RES EARCH GROUP ON
E L EC TROSP INN ING
CIRI MAM
Nanofibers by Electrospinning ProcessNanofibers by Electrospinning Processthe ES group at
Alma Mater ‐ Bologna University
RESEARCH GROUP ON
E L EC TROSP INN ING
CIRI MAM
Electrospinning of polymeric fibersElectrospinning of polymeric fibers
From macromolecules
Polymeric solution
From macromolecules …
Entanglements
Disordered
… to sub‐micrometric fibers
MicrofiberDisordered macromolecules Partially of fully
orientation of macromoleculesmacromolecules
Nanofiber
RES EARCH GROUP ON
E L EC TROSP INN ING
CIRI MAM
Electrospinning of polymeric fibersElectrospinning of polymeric fibers
Taylor cone
Stretching
RES EARCH GROUP ON
E L EC TROSP INN ING
CIRI MAM
Electrospinning of polymeric fibersElectrospinning of polymeric fibers
Non‐woven mat made of polymeric nanofibersof polymeric nanofibers
RES EARCH GROUP ON
E L EC TROSP INN ING
CIRI MAM
In 2006, in Bologna University the first Italian multidisciplinary research
group focused on the manufacturing of small scale fibers (nanometric
fibers) by means of electrospinning technology was establishedfibers) by means of electrospinning technology was established.
Polymer chemestryMembers of the R h G
Electrical EngineeringResearch Group on Electrospinning
(RGE)
Mechanical Engineering
( )are from
RESEARCH GROUP ON
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CIRI MAM
CHEMISTRY DEPARTMENTCHEMISTRY DEPARTMENTCHEMISTRY DEPARTMENTCHEMISTRY DEPARTMENTProf. Prof. M.L.M.L. FocareteFocarete, Dr. C. , Dr. C. GualandiGualandi
DEPARTMENT OF INDUSTRIAL ENGINEERINGDEPARTMENT OF INDUSTRIAL ENGINEERINGDEPARTMENT OF ELECTRICAL, ELECTRONIC AND INFORMATION ENGINEERING DEPARTMENT OF ELECTRICAL, ELECTRONIC AND INFORMATION ENGINEERING
ProfProf A A ZucchelliZucchelli Prof D Fabiani Prof D FabianiProfProf. A. . A. ZucchelliZucchelli, Prof. D. Fabiani, Prof. D. Fabiani,,
RES EARCH GROUP ON
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CIRI MAM
Th RGE i i i
Polymer characterization and functionalization Advanced Materials for Energy Distributions
The RGE activities
Polymer characterization and functionalization Biomedical applications Water treatment
Advanced Materials for Energy Distributions Electrical studies on High Voltage Fields
Energy Harvesting Sensors
Chemistry UnitElectric
Engineering Unit
Leaded by Prof. M. L. Focarete
Leaded by Prof. D. Fabiani
Mechanical and Mechatronic Unit
Leaded by Prof. A. Zucchelli
Mechatronic solutions for electrospinning Composites and Smart Materials
Packaging materials
RESEARCH GROUP ON
E L EC TROSP INN ING
CIRI MAMNanofibers and nanofibrous membrane by electrospinning
Fiber morphology Graphenep gy
Porous fibersSolid fibers Composite fibers
Core‐shell fibers Pearly fibersHollow fibers
RES EARCH GROUP ON
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CIRI MAMNanofibers and nanofibrous membrane
2D assembling
by electrospinning
Random Aligned Layered – cross aligned
RadialStar shaped
RESEARCH GROUP ON
E L EC TROSP INN ING
CIRI MAMNanofibers and nanofibrous membrane
3D assembling
by electrospinning
Yarn3D assembling
Bundle
H llHollow yarn
Pictures C and D kindly provided by Prof. RamakrishnaPictures C and D kindly provided by Prof. Ramakrishna
RES EARCH GROUP ON
E L EC TROSP INN ING
CIRI MAMNanofibers and nanofibrous membrane
Scaffolds with tunable porosity
by electrospinning
Scaffolds with tunable porosity
RESEARCH GROUP ON
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CIRI MAM
Wh fib ?
Nanofibers are characterized by:
Why nanofibers?
Nanofibers are characterized by:
1. Bio‐mimetism
Dorsal root ganglia (DRG) morphology on
biomimetic materials presenting replicated
Schwann cell (SC) topography.
Phase contrast (a, c) and fluorescent
micrographs (b, d ) of dissociated DRG
lt d f 5 d l di th l ilcultured for 5 days on polydimethylsiloxane
(PDMS) (a, b) or replicas (c, d ) and stained
with neurofilament immunocytochemistry
(b, d ). [1]( , ) [ ]
[1] Diane Hoffman‐Kim,1 Jennifer A. Mitchel, Ravi V. Bellamkonda, Topography, Cell Response, and Nerve Regeneration, Annu. Rev. Biomed. Eng. 2010. 12:203–31
RES EARCH GROUP ON
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CIRI MAM
Wh fib ?
Nanofibers are characterized by:
Why nanofibers?
Nanofibers are characterized by:
2. High surface/volume ratio
nanofiber
microfiber
RES EARCH GROUP ON
E L EC TROSP INN ING
CIRI MAMNowadays applications of y ppelectrospun nanofibers
Huang ZM, Zhang YZ, Kotaki M, Ramakrishna S. 2003. A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos. Sci. Technol. 63:2223–53
RES EARCH GROUP ON
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CIRI MAM
With UNIBO’ i t diff t tWith UNIBO’s equipment different types of Nanofibrous Membrane can be produced