Chemical Changes Chemical Changes
Jan 01, 2016
Chemical ChangesChemical Changes
Matter and Chemical ReactionsMatter and Chemical ReactionsMatter and Chemical ReactionsMatter and Chemical Reactions
• What is a chemical change? – New substance formed; different properties from the
reactants
• How do we know a chemical reaction has taken place?– (1). Formation of a gas– (2). Permanent color change– (3). Temperature change
• Exothermic and endothermic – (4). Precipitant formed
• What is a chemical change? – New substance formed; different properties from the
reactants
• How do we know a chemical reaction has taken place?– (1). Formation of a gas– (2). Permanent color change– (3). Temperature change
• Exothermic and endothermic – (4). Precipitant formed
Matter and Chemical ReactionsMatter and Chemical ReactionsMatter and Chemical ReactionsMatter and Chemical Reactions
• How do elements form compounds?– Atoms of the reactant(s) are rearranged and bond in
different combinations
– A + B ----------- C + D
– Phase Changes and Chemical changes Animation
• How do elements form compounds?– Atoms of the reactant(s) are rearranged and bond in
different combinations
– A + B ----------- C + D
– Phase Changes and Chemical changes Animation
Electron ShellsElectron Shells
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
Note that elements within the same group have the same electron-dot structure. Note that elements within the same group have the same electron-dot structure.
Electron ShellsElectron Shells
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
• Valence electrons: Electrons in the outermost shell of an atom. These are the ones that can participate in chemical bonding.
• Electron-dot structure: A notation showing the valence electrons surrounding the atomic symbol.
Chemical Bonds Chemical Bonds Chemical Bonds Chemical Bonds • (1). Ionic– Metals transfer electrons to nonmetals– Positive ions (cations) and Negative ions (anions) are
formed
• (2). Covalent– Sharing of electrons between nonmetal atoms – Equal sharing: nonpolar compound– Unequal sharing: polar compound
• (3). Metallic– Sea of electrons float between metal atoms
• (1). Ionic– Metals transfer electrons to nonmetals– Positive ions (cations) and Negative ions (anions) are
formed
• (2). Covalent– Sharing of electrons between nonmetal atoms – Equal sharing: nonpolar compound– Unequal sharing: polar compound
• (3). Metallic– Sea of electrons float between metal atoms
Ionic BondingIonic BondingIonic BondingIonic Bonding
• Characteristics– (1). Electrostatic Attraction between positive and
negative ions– (2). Formation of Crystal Structures– (3). Strong Bonds – High Melting Points – (4). Electrolytes
– Animation
• Characteristics– (1). Electrostatic Attraction between positive and
negative ions– (2). Formation of Crystal Structures– (3). Strong Bonds – High Melting Points – (4). Electrolytes
– Animation
Polar Bonds and Polar MoleculesPolar Bonds and Polar Molecules
• Electronegativity: The ability of a bonded atom to pull on shared electrons. Greater electronegativity means greater “pulling power.”
• Electronegativity: The ability of a bonded atom to pull on shared electrons. Greater electronegativity means greater “pulling power.”
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
High
Low
Covalent BondingCovalent BondingCovalent BondingCovalent Bonding
• Characteristics• (1). Sharing of electrons between atoms• (2). Electronegativity is similar • (3). Molecules formed • (4). Bonds not as strong as covalent • (5). May be equal or unequal sharing between
electrons• (6). Gases form covalent bonds
• Characteristics• (1). Sharing of electrons between atoms• (2). Electronegativity is similar • (3). Molecules formed • (4). Bonds not as strong as covalent • (5). May be equal or unequal sharing between
electrons• (6). Gases form covalent bonds
The Covalent BondThe Covalent BondThe Covalent BondThe Covalent Bond
• The type of electrical attraction in which atoms are held together by their mutual attraction for shared electrons.
• The type of electrical attraction in which atoms are held together by their mutual attraction for shared electrons.
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
The Covalent BondThe Covalent BondThe Covalent BondThe Covalent Bond
• The type of electrical attraction in which atoms are held together by their mutual attraction for shared electrons.
• There are two electrons within a single covalent bond.
• The covalent bond is represented using a straight line.
• The type of electrical attraction in which atoms are held together by their mutual attraction for shared electrons.
• There are two electrons within a single covalent bond.
• The covalent bond is represented using a straight line.
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
F — FF F
Polar Bonds and Polar MoleculesPolar Bonds and Polar MoleculesPolar Bonds and Polar MoleculesPolar Bonds and Polar Molecules
• Electrons within a covalent bond are shared evenly when the two atoms are the same.
• They may be shared unevenly, however, when the bonded atoms are different.
• Electrons within a covalent bond are shared evenly when the two atoms are the same.
• They may be shared unevenly, however, when the bonded atoms are different.
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
Polar Bonds and Polar MoleculesPolar Bonds and Polar MoleculesPolar Bonds and Polar MoleculesPolar Bonds and Polar Molecules
• But if polar bonds within a molecule are facing in equal and opposite directions…
…then the polarity may cancel itself out.
• But if polar bonds within a molecule are facing in equal and opposite directions…
…then the polarity may cancel itself out.
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
Polar Bonds and Polar MoleculesPolar Bonds and Polar MoleculesPolar Bonds and Polar MoleculesPolar Bonds and Polar Molecules
• But if polar bonds within a molecule are facing in equal and opposite directions…
…then the polarity may cancel itself out.
• But if polar bonds within a molecule are facing in equal and opposite directions…
…then the polarity may cancel itself out.
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
Copyright © 2007 Pearson Education, Inc., publishing as Pearson Addison Wesley
…or not!
More Chemical ReactionsMore Chemical ReactionsMore Chemical ReactionsMore Chemical Reactions
• Animation – Chemistry Comes Alive
• Dust Explosion Animation
• Animation – Chemistry Comes Alive
• Dust Explosion Animation
Metallic BondingMetallic BondingMetallic BondingMetallic Bonding• Characteristics • Electrons of metal atoms flow freely between
other metal atoms• The more mobile the electrons, the better the
electrical conductor• Higher the vibration of electrons more metal is
shiny. • Malleable characteristic due to electrons not
being fixed, but freely flowing • Alloy: White gold (molten gold and palladium are
blended)
• Characteristics • Electrons of metal atoms flow freely between
other metal atoms• The more mobile the electrons, the better the
electrical conductor• Higher the vibration of electrons more metal is
shiny. • Malleable characteristic due to electrons not
being fixed, but freely flowing • Alloy: White gold (molten gold and palladium are
blended)
Metals vs NonmetalsMetals vs NonmetalsMetals vs NonmetalsMetals vs Nonmetals
• High luster, shiny• Malleable • Ductile • High Melting Points • Good Conductors• Poor Insulators
• High luster, shiny• Malleable • Ductile • High Melting Points • Good Conductors• Poor Insulators
• Low luster and dull• Nonmalleable • Not Ductile • Low Melting Points• Poor Conductors • Good Insulators
• Low luster and dull• Nonmalleable • Not Ductile • Low Melting Points• Poor Conductors • Good Insulators
Periodic and Group Trends Periodic and Group Trends
Atomic Size/RadiusAtomic Size/RadiusAtomic Size/RadiusAtomic Size/Radius
Ionization Energy Ionization Energy Ionization Energy Ionization Energy