vat lieu mao quan

7/17/2019 vat lieu mao quan

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n tt nghip Trng i hc M - a cht

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hn 250 nm k t khi pht hin ra zeolite u tin, lnh !" khoa h#" $t

liu n%& '(" pht trin )*i +n, nh-t l% t nh.n nm /0 "a th1 k 20, khi

zeolite tr3 th%nh "h-t 4" t" 6uan tr#n tron "*n nhip h7a 8u, t 7 h'9n

nhin ":u n%& "7 ):" h-p 8;n k< l= trn th1 i9i % 3 >it ?am, "hn ta "@n thamia tA"h "!" %o )! pht trin n%&B

Ceolite, m+t lo=i $t liu * " tinh th alumino)ili"at, 9i h thDn i mao 6uEn

pht trin "7 kA"h th'9" mao 6uEn FGHIJB Ku& "7 nhiLu :n 8Mn r+n ri nh'nzeolite "7 kA"h th'9" mao 6uEn hNp l%m h=n "h1 n k tAnh "h-t h-p phM, trao Oi

% o4i h7a khP "" phQn tP "7 kA"h th'9" l9nB

>$t liu mao 6uEn trun RSnh TUVKWX 9i kA"h th'9" Lu Yn t 20 J1n 500 J

ra Zi nh' U[UGFH, \W]GH5, \W]GH/,^ kh_" phM" nh.n h=n "h1 L kA"h th'9"

l` "a zeolite T H0JX "ho phbp khu1"h tn "" phQn tP l9n trn RL mYt $t liu thamia phEn :nB ?o%i ra, $t liu UVKW "7 th tA"h % RL mYt rin l9n, "-u tr" mao

6uEn 9i + tr$t t! "ao % kA"h th'9" mao 6uEn r-t cn Lu nn "7 tiLm nn l9n

tron :n 8Mn l%m "h-t 4" t", h-p phM, Y" Rit l% "" 6u trSnh "7 )! tham ia

"a "" phQn tP l9n d5,H0,50B fo "-u tr" mao 6uEn cn Lu Y" Rit nh' $& nn

$t liu n%& Rg h=n "h1 tron i" ti1p "$n "" g trA ho=t tAnh 8o tr3 n=i l`B

kh_" phM" nh'(" im n%&, $t liu phQn "-p a mao 6uEn % an '("

pht trin d5H, A 8M nh' U[UGFH\W]GH5 l% nh.n $t liu "7 "-u tr" phQn "-p

cm nhiLu h thDn l` "7 kA"h th'9" kh" nhau Tmi"rome)oma"roXB Q& l% m+t "on

'Zn tOn h(p $t liu a "-u tr" "7 8in tA"h RL mYt rin "ao, th tA"h l` l9n

% khE nn khu1"h tn phQn tP tDt 8o "hn "7 m=n l'9i l` cm nhiLu lo=i l` "7

kA"h th'9" kh" nhau tron "n m+t $t liuB Ku& $& thS khE nn :n 8Mn th!" t1

"a m+t )D $t liu lo=i n%& ;n "jn h=n "h1 8o "-u tr" th%nh mao 6uEn 8=n *

gnh hSnh nn "7 + RLn thu nhit kbmB

h'9n nhin ":u ti1n R+ hn, "" nh% khoa h#" nhin ":u tinh th h7a $t

liu trn " )3 4Q& 8!n "" "Mm nano TnanoclustersX t=o th%nh "" i tinh th trn

th%nh t'Zn "7 REn "h-t * gnh hSnhB U+t )D $t liu nh' C\UG5\W]GH5 TU]\GX,

K\GH\W]GH5 T UK\GX ^ l% nh.n $t liu m9i ra Zi 9i nh.n 'u im nOi R$t

nh' + RLn nhit, + RLn th& nhit, khE nn o4& h7a % + a4it "ao, "hu&n h7a

'(" phQn tP "7 kA"h th'9" nh % kA"h th'9" l9nB :n tr'9" nhu "u th!" tin hin

na& L -n L REo m*i tr'Zn, "h1 t=o nhin )inh h#" tha& th1 nhin liu h7a

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2/83


th="h )_p "=n kit,^ t=o nn nh.n "*n nh )="h "ho t'n lai thS "" $t liu trn

an '(" nhiLu nh% khoa h#" nhin ":u pht trin nhm p :n &u "u th!" tinB

Kron khi nh.n nhin ":u L zeolite ;n ti1p tM" thS 4u-t hin m+t h'9n

pht trin m9i "" $t liu mao 6uEn "7 RL mYt rin "!" l9n th1 h m9i ra ZiB ?1u

zeolite l% lo=i $t liu * " thS h'9n pht trin m9i nhm %o )! k1t h(p "a * "% h.u ", t:" l% i.a "" kim lo=i % "" phDi tP h.u " a "h:", #i "hun l%

Uq) TUetal ani" qramesorkXB

>$t liu "7 khun kim lo=i G h.u " TUq)X "7 "-u tr" m=n kh*n ian a

"hiLu '(" t=o nn t "" nt kim lo=i hoY" o4it kim lo=i % '(" k1t nDi Rn ""

phDi tP h.u " a "h:" TlinkerX th%nh khun m=n, t=o ra nh.n khoEn trDn l9n

Rn tron, '(" th*n ra no%i Rn nh.n "Pa )O "7 kA"h th'9" nano Lu YnB>$t

liu Uq) 9i 8in tA"h RL mYt r-t l9n T5000 G 000 m2X "7 tiLm nn :n 8Mn to

l9n tron nhiLu "" lnh !" nh'

'u tr. khA [2, l%m iEm khA Q& hiu :n nh% kAnh, REo m*i tr'ZnB 'u tr. khA v2, "h1 t=o nhin liu )="h tha& th1 4n 8uB [h1 t=o "" $t liu 4" t" o4i h7a, 4" t" o4i h7a khP, 4" t" Raz, 4" t" 6uan

h7a^B [h1 t=o "" "h-t man tron 8'(" h#" % & h#"B [h1 t=o "" 4" t" l$p th tron "" phEn :n h.u "^

Kron hn m+t th$p kw, $t liu "7 khun kim lo=i G h.u " '(" pht trin theo

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^B Kh%nh "*n u tin phEi k 1n l% $t liu UqG5, '(" tOn h(p R3i ahi

dF,5FB >i" )P 8Mn phDi tP h.u " imi8azole t=o ra $t liu "7 khun kim lo=i G

h.u " "7 "-u tr" t'n t! zeoliteB \! ra Zi "a h# $t liu Uy) UyG5I, UyG

/{, UilG{{, UyGH00, UyGH0H, UyGH02, UyGH25^ Y" Rit 9i nh.n th%nh 6uE

nhin ":u trn "-u tr" UyGH0H '(" "" nh% khoa h#" trn th1 i9i nh i

"ao nh-t tron hiu 6uE l'u tr. khA % "h1 t=o 4" t"B Krn " )3 $t liu Uq)

n'Zi ta Ri1n tAnh Rn ""h 'a "" tQm 4" t" nh' "" tQm o4i h7a khP hoY" tQma4it "h1 t=o "" 4" t" "ho h%n lo=t "" phEn :n kh" nhauB v'9n Ri1n tAnh

$t liu UyGH0H tr3 th%nh $t liu 6uan 4" t" "7 khE nn h-p thM nh )n nhSn

th-& 4P l| "" "h-t +" h=i tron m*i tr'Zn Tnh' FG nitrophenolX, 4" t" "ho 6u

trSnh o4i h7a "h#n l#" tron iLu "h1 tOn h(p h'n liu Tnh' o4i h7a }GpinenX,

8'(" liu T"h-t man 8'(" ph~m l% "-u tr" UyGH0HTqeXX % _n nh7m "h:" nn

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3/83


amino :n 8Mn tron phQn t"h khA, tha& th1 nt m=n ion kim lo=i "h:a tQm a4it

esi) Tnh' UyGH0HT]lX, UyGH0HTqeXX h:a hNn nhiLu :n 8Mn tron t'n laiB

vin na&, nh.n nhin ":u L Uq) 3 >it ?am "@n =t '(" m+t )D k1t

6uE, S $& trn " )3 k1 tha nh.n th%nh t!u khoa h#" $t liu trn th1 i9i nhm

mM" tiu 4Q& 8!n % pht trin " )3 khoa h#" tron lnh !" tOn h(p $t liu "7khun kim lo=i h.u " Uq), "hn t*i L ra mM" tiu % nhim M "a c n

n%& nh' )au

HB KOn h(p % Y" tr'n $t liu khun kim lo=i h.u " UyGH0H tron m*i tr'Zn

a4itB2B KOn h(p % Y" tr'n $t liu khun kim lo=i h.u " UyGH0H tinh th nano tron

m*i tr'Zn Raz 8un 8g"h Ketraprop&lammonium h&8ro4i8e TK]vXBIB KOn h(p % Y" tr'n $t liu khun kim lo=i h.u " "-u tr" a "-p mao 6uEn

Ue)o UyGH0H )P 8Mn )iu phQn tP [et&ltrimeth&lammonium Rromi8e T[K]WX l%mt" nhQn gnh h'9n "-u tr"B

FB KOn h(p % Y" tr'n $t liu khun kim lo=i h.u " "h:" nn h7a amino ?v2G

UyGH0HT]lX Rn ph'n php tOn h(p tr!" ti1p T8ire"tG)&nthe)i)XB5B KOn h(p % Y" tr'n $t liu khun kim lo=i h.u " "-u tr" Ue)o ?v 2GUyG

H0HT]lX )P 8Mn )iu phQn tP [et&ltrimeth&lammonium Rromi8e l%m t" nhQn gnh

h'9n "-u tr"B/B ?hin ":u nh i ho=t tAnh h-p phM thuD" nhu+m h.u " meth&lene Rlue trn $t

liu "-u tr" UyGH0H, Ue)o UyGH0H, Ue)o ?v2GUyGH0HT]lXB

[hn t*i h& #n nh.n k1t 6uE nhin ":u ) 7p phn 4Q& 8!n % pht trin """ )3 khoa h#" "ho i" tOn h(p $t liu "7 "-u tr" khun kim lo=i G h.u ", p :n

nh.n &u "u "-p thi1t tron khoa h#" " REn "@n nh' :n 8Mn "" $t liu tron lnh

!" h7a 8'(", nhin liu, nn l'(n % REo m*i tr'Zn^

Chng 1: TNG QUAN

1.1. Gii thiu chung v v!t "iu c# $hung $i% "&'i ( h)u c

Sinh vin: Ng Mnh Tng "#p: "c - $%a &'() *+,


4/83


Kron khi nh.n nhin ":u L zeolite T$t liu i mao 6uEnX "7 nhiLu khE nn

:n 8Mn phon ph %o nhiLu lnh !" ;n an '(" ti1p tM" th!" hin L nhiLu

ph'n 8in thS thZi ian n Q& 4u-t hin m+t h'9n pht trin "" $t liu i

mao 6uEnB Q& l% m+t h'9n m9i tron lnh !" 4" t" % khoa h#" $t liu, thu ht

)! 6uan tQm "a "" nh% khoa h#" nhiLu n'9" trn th1 i9i tron hn m+t th$p k6uaB

?1u zeolit l% lo=i $t liu * ", thS h'9n pht trin m9i n%& nhm %o )! k1t

h(p i.a * " % h.u ", t:" l% i.a "" ion kim lo=i % "" phDi tP h.u " a "h:",

t=o nn lo=i $t liu "@n "7 h thDn mao 6uEn 9i "" "Pa )O Lu Yn, 8in tA"h RL

mYt l=i r-t "ao T"7 th ln t9i 000m2XB >$t liu mao 6uEn phDi trA i.a kim lo=i G

h.u " hin an '(" pht trin nhin ":u tOn h(p theo hai 8jn $t liu "hAnh l%

Cyq) TZeolitic Imidazolate FrameworksX % Uq) TMetal Organic FrameworksX d/,

/{, /BWo "o L "" lo=i $t liu n%& '(" Ri1t 1n t nh.n nm H5, khi ino)hita

m* tE "-u tr" tinh th "a Ri)GTa8iponitriloX cnTyX nitrat dFHB ?m H/0, "" -n

L trn "@n '(" nh_" t9i tron "" Ro "o d52,5I tu& nhin "" L 4u-t kh*n

nh$n '(" nhiLu 6uan tQmB K9i nh.n nm H0 L t%i n%& '(" ti nhin ":u, u

tin phEi k 1n l% "" t" ph~m "a oR)on dF{ % )au 7 R3i ahi n'Zi Y" Rit

th%nh "*n nOi ti1n 9i UqG5 dF,5FB

Kron th$p k 6ua, $t liu phDi trA kim lo=i G h.u " Uq) TMetal Organic

Frameworks X '(" 6uan tQm Y" RitB 7 l% m+t h# $t liu khun lai hbp i.a *

" h.u " 9i tiLm nn :n 8Mn 6uan tr#n tron nhiLu lnh !" nh' h-p phM,

4" t", l'u tr. khA, phQn t"h khABBB nh-t l% tron i" nhin ":u pht trin nhin

liu )="h, "h1 t=o m%n l#", 4" t" "ho tOn h(p "" i "h-t, Y" Rit l% 8'(" ph~mBBB

?h.n khun lai Uq) n%& '(" 4em l% =i 8in "a "-u tr" mao 6uEn r+n tiu

Riu, 3 7 "" th%nh phn h.u " ho=t +n nh' nh.n "u nDi k1t nDi "" "Mm *

", t=o th%nh "" nh7m % "" l9p dHGIB

>$t liu lai kim lo=i G h.u " TUq)X "7 "-u tr" m=n kh*n ian a "hiLu,

'(" t=o nn t "" nt kim lo=i hoY" o4it kim lo=i % '(" k1t nDi Rn "" phDi tP

l% nh.n a4it h.u " a "h:" th%nh khun m=n, t=o ra nh.n khoEn trDn l9n Rn

tron, '(" th*n ra no%i Rn "Pa )O "7 kA"h th'9" nano Lu Ynx 9i 8in tA"h RL

mYt "7 th ln t9i 000m2B \o 9i "" $t liu r_n 4Dp kh" nh' zeolite ha& "" $t

liu rQ& phQn tP, thS + 8%& th%nh mao 6uEn "a h# $t liu Uq) l% kh nh nn

"hn "7 khE nn h-p phM Y" RitB [-u tr" On gnh, REn "h-t tinh th, + 4Dp "ao

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5/83


% 8in tA"h RL mYt rin l9n, h# $t liu Uq) hin an thu ht )! 6uan tQm "a

nhiLu in h%n lQm khoa h#" % "" in nhin ":u trn th1 i9i d/, 0B

$/nh !0! S1 i 2in t3ng 4(t cc h v5t 6i( r7n 8p: 96i;< r7n 8p c( tr=c

h>( c1? @( c1 -v c10

1.1.1. *nh ngh+, v $hung %'ng $i% "&'i ( h)u c

ol&me phDi trA TCoordination ol!mers" CsX l% lo=i $t liu r_n hSnh th%nh

R3i m+t m=n l'9i m3 r+n "a "" ion kim lo=i phDi trA 9i "" phQn tP h.u " d5FB

gnh nha n%& 8n "hw "" $t liu m% tron th%nh phn phQn tP "7 "h:a cn

thZi "E kim lo=i % "" phQn tP h.u "B vin na& "hn ta an nhin ":u % 4em

4bt rin m+t nh7m "" [) Y" Rit #i l% khun kim lo=i G h.u " TMetal

Organic Frameworks" MOFsX dFFB

Kheo gnh nha trn,Metal - Organic Frameworks #MOFs$l% m+t phQn nh7m

"a h# [)B Uq) "7 )! 4u-t hin cn thZi "a Ra Y" im 6uan tr#n tinh th,

tAnh "h-t l` % )! tcn t=i "a t'n t" kim lo=i phDi tP m=nhB [hAnh )! k1t h(p +"

o "a "" Y" tAnh h7a h#" n%& m% Uq) t=o nn m+t nh7m $t liu r-t Y" RitB

>$t liu lai kim lo=i h.u " TUq)X "7 th hiu m+t ""h n iEn, l% m+t

m=n kh*n ian a "hiLu, '(" t=o nn t "" nt kim lo=i hoY" o4it kim lo=i %

'(" k1t nDi 9i "" phDi tP l% nh.n a4it h.u " a "h:" t=o th%nh khun m=n,

l=i nh.n khoEn trDn l9n Rn tron, '(" th*n ra no%i Rn "Pa )O "7 kA"h th'9"

nano Lu YnB

1.1.-. ,nh /h0/

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?h.n nm 6ua, )! nhin ":u L Uq) '(" ti1n h%nh 9i 6u& m* r+n l9n

trn nhiLu 6uD" iaB \D l'(n "" "-u tr" m9i '(" pht hin m`i nm l% r-t l9n,

th'Zn tn theo "-p )D nhQnB [hAnh S th1 i" "hu~n h7a tn #i "a lo=i $t liu

n%& Yp nhiLu kh7 khnB vin na&, "7 r-t nhiLu ""h #i tn, theo nhiLu h'9n kh"

nhau nh'G >$t liu khun kim lo=i G h.u " '(" t=o ra R3i ahi #i "hun l% Uq)

TMetal Organic FrameworksX, A 8M UqGH, UqG2, UqG5,^

G >$t liu khun kim lo=i G h.u " '(" t=o ra "7 "-u tr" t'n t! zeolite 9i

phDi tP h.u " imi8azolate #i l% Cyq) TZeolitic Imidazolate FrameworksX, A 8M

CyqGH, CyqG2, CyqGF,^

G ["h Yt tn theo phjn thA nhim tOn h(p th%nh "*n nh' Uy) TMatriaux

de l'Institut LavoisierX, A 8M UyG5I, UyG/{, UyG{{, UyGH00, UyGH0H, UyG

H25^x v\KGnI/ # %&i (c )oa (c v* C+ng ng, ong-)ongX^G Kn #i )P 8Mn "" "*n th:" kinh nhim "a $t liu, t:" l% "*n th:" th

hin kim lo=i T)X, "" phDi tP T)X % 6uan h gnh l'(n tron )! lYp i lYp l=i n g,

A 8M dCnFTWf[XI TWf[ H,F Renzene8i"arRo4&lateX hoY" [uITWK[X2 TWK[ a4it

H,I,5GRenzentri"a"Ro4&lateXB

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tron "Gp"u hoY" R"uGkXB h'n php n%& "ho phbp m+t n'Zi m* tE % phQn lo=i

"" "-u tr", k "E nh.n "-u tr" tiLm nn m9i "a "-u tr" Uq)B Kron tr'Zn

h(p n%&, i" phQn lo=i h=n "h1 hn 8o thi1u th*n tin L REn "h-t ho h#" "a $t

liuB

1.1.. 2ng 34ng c5, v!t "iu M678

!0!00!0 EhF t v5t 6i( hp phG) 6( tr> HhI

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6u&n, Q& hiu :n nh% kAnh, l%m tn m!" n'9" Rin % tn + a4it 3 =i 8'nB

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Kron "*n nhip, i" thu i. khA [2th'Zn '(" th!" hin Rn 8un 8g"h

n'9" "a aminGal"ohol, )au 7 [2iEi thot Rn ""h nQn nhit +B vin na& "7 r-t

nhiLu Ro "o "ho th-& khE nn h-p phM tDt [2"a "" $t liu Uq) nh' aminoG

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n'Zi ta lo l_n i" l'u tr. h&8ro tron RSnh khA nbn ) "7 khE nn Q& "h& nO ha&

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ta '(" n`i lo trnB

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h7a "h#n l#", h-p phM, 6uan 4" t", phQn t"hBBB

!0!000 EhF t ;Ang 6cf!a trn khE nn h-p phM "h#n l#" kA"h th'9" phQn tP "a $t liu Uq), "7

th "h1 t=o m%n l#" "ho i" phQn t"h h`n h(p, p :n "" &u "u L tinh "h1 %

l%m )="hB ?hin ":u t=o m%n t"h t $t liu nano '(" lin k1t Rn porph&rin %

p&razinedF/, m%n '(" "h1 t=o Rn ""h 8t hu&Ln ph ln m%n pol&e)teB ?hZ

m& ]qU n'Zi ta nh$n th-&, phQn tP "7 'Zn kAnh HIJ"7 th th-m 6ua m%n "a

Sinh vin: Ng Mnh Tng K "#p: "c - $%a &'() *+,


8/83


$t liu lin k1t Rn porph&rin, "jn "" phQn tP nh hn "7 'Zn kAnh 5, J thS

th-m 6ua m%n p&razineB

1.1.9. C0c /hng /h0/ tng h;/ v!t "iu c# $hung $i% "&'i < h)u c

Uq) '(" tOn h(p theo nh.n ph'n php "hAnh 8'9i iLu kin th& nhit

T!drotermalX hoY" 8un nhit TsolvotermalXB \! a 8=n L "-u tr" phM thu+"%o ion trun tQm % "" phDi tP )P 8MnB fo 7, t nh.n "u nDi TlinkerX % "" ion

kim lo=i kh" nhau m% ta "h1 t=o ra nhiLu lo=i $t liu 9i nhiLu :n 8Mn kh" nhauB

vn th1 n.a, i" iLu "hwnh "" tham )D tron 6u trSnh tOn h(p Tnhit + phEn

:n, thZi ian phEn :n, 8=n muDi kim lo=i, 8un m*i hoY" pv "a 8un 8g"h phEn

:nX "@n "7 Enh h'3n )Qu )_" t9i )! hSnh th%nh hSnh thi "-u tr" tinh th % tAnh

"h-t "a $t liu dH{, 2/ T"hn h=n tr'Zn h(p iu khin tOn h(p "-u tr" UyG

5ITqeX khi tha& Oi t l ncn + % 8un m*i )P 8Mn l=i 8;n t9i )! hSnh th%nh "-u

tr" UyG{{TqeXXB vin na& "" nh% khoa h#" th1 i9i tOn h(p '(" khoEn hnH0B000 "-u tr" Uq)B

hDi tP h.u " l% nh.n tQm Raz, lin k1t 9i tQm a4it l% ion kim lo=i trun tQmB

[" kim lo=i l% wnh "a m+t a i" LuB [" "u nDi h.u " l% nh.n thanh "hDn

% =i 8in "ho khoEn ""h i.a "" wnh 4" gnh "hu i "a a i" T.n /01XB

$/nh !0,0 S1 t3ng hLp Hh(ng ;ng MBCD

U+t tron nh.n ph'n php 4" gnh khun kim lo=i G h.u " l% th*n 6ua

i" )P 8Mn m+t n g 4Q& 8!n th: "-p T2econdar! 3uilding 4nit" 234X dFB ["

n g 4Q& 8!n " REn phEi m=nh kh*n 4E& ra )! )_p 41p l=i tron 6u trSnh

hSnh th%nh m=n l'9i TA 8M nh' tha& S thZi ian th& nhit {GH0 iZ tron phEn :n

tOn h(p UyGH0HT[rX, thZi ian th& nhit kbo 8%i 2F iZ l=i 8;n t9i )! hSnh th%nh

"-u tr" UyG5IT[rXXB

Uq) th'Zn '(" tOn h(p Rn ""h k1t h(p phDi tP h.u " % muDi kim lo=i

tron "" phEn :n 8un nhit TsolvotermalX 3 nhit + t'n Di th-p T I00o[XB

[" Y" tAnh "a phDi tP h.u " T+ 8%i phDi tP, 7" lin k1tX 7n ai trj 6uan tr#n

tron i" hSnh th%nh "-u tr" khunB ?o%i ra, 4u h'9n t=o 8=n ph:" "a "" ion

kim lo=i "@n Enh h'3n t9i "-u tr" "a Uq)B



9/83


[" th*n )D 6uan tr#n nh-t "a 6u trSnh tOn h(p 8un nhit Uq) l% ncn

+ muDi kim lo=i % phDi tP, + tan "a "" "h-t phEn :n tron 8un m*i, pv 8un

8g"hB U+t tron nh.n ph'n php h:a hNn nh-t l% "hi1u 4= i )7n TmicrowareX

'(" )P 8Mn rt n_n thZi ian k1t tinh cn thZi kim )ot hSnh thi RL mYt %

kA"h th'9" h=tB

n Q&, "-u tr" hSnh h#" "a \W '(" "h:n minh l% "7 )! phM thu+"

kh*n "hw "a phDi tP % "" kim lo=i )P 8Mn, m% "jn l% t l kim lo=i, phDi tP, ""

8un m*i % nucn D" "a anion "Qn Rn h7a trg "a ion kim lo=i d2/B

[" l` 4Dp "a Uq) th'Zn Rg "hi1m R3i "" phQn tP 8un m*i nn tron 6u

trSnh tOn h(p phEi lo=i R h1t "" phQn tP 7B \! )Mp O Tkh*n t=o th%nhX "-u tr"

"7 th 4E& ra % n7i "hun "" l` 4Dp "7 kA"h th'9" "%n l9n "%n "7 khE nn )Mp

OBU+t tron nh.n $t liu Uq) '(" tOn h(p u tin '(" Ri1t l% UqG5

T.n /05XB >$t liu UqG5 '(" tOn h(p t muDi Cn2% a4it terephtali" dF/B

UqG5 "7 "*n th:" l% dCnFTWf[XI, tron 7 Wf[ RenzeneGH,FG8i"a"Ro4&late,

l% m+t pol&me phDi trA tinh th i mao 6uEnB [Mm Cn F l% trun tQm "a "-u tr"

T.n /06XB [" nu&n tP o4i '(" 4" gnh 3 tQm "a t: 8in % '(" phDi trA Rn

RDn nu&n tP km, "" nu&n tP km '(" Yt 3 RDn wnh t: 8inB [" "=nh "a t:

8in '(" R_" "u Rn )u nh7m "a"Ro4&late "a "h-t k1t nDi h.u " t=o th%nh m+t

nt Rt 8inB [" nt l=i lin k1t 9i nhau Rn "" nh7m H,FGphen&lene "a "h-t link1t Wf[ t=o th%nh m=n l'9i l$p ph'n Ra "hiLuB

] UqG5 W yUqG/ [ yUqG{



10/83


yUqGH UqGI2F Uq G I2/

$/nh !00 MOt D c( tr=c tinh thP MBCD

[" wnh "a hSnh l$p ph'n l=i '(" k1t nDi th%nh m=n l'9i Ra "hiLu, t=o nn $t

liu "7 h thDn l` 9i "Pa )O cn Lu % RL mYt rin pht trin T.n /06XB

$/nh !0.. E( tr=c tinh thP MBC-+ trng Hhng gian

Sinh vin: Ng Mnh Tng !Q "#p: "c - $%a &'() *+,


11/83


$/nh !0+0 T3ng 4(an cc ph1ng php t3ng hLp v5t 6i( MBCD R!Q

KOn h(p "" $t liu khun kim lo=i h.u " TUq)X n7i "hun 8 8%n hn

)o 9i tOn h(p zeoliteB [" ph'n php tOn h(p $t liu n%& "7 th "hia th%nh

nh.n h'9n )au Q&

!0!0.0!0 9h1ng php thU nhit

[" h(p phn tham ia phEn :n t=o th%nh m=n kh*n ian '(" tr+n tron

8un 8g"h n'9", 'a %o RSnh kAn, un n7n 1n "" nhit + thA"h h(p hSnh th%nh

$t liuB

>A 8M $t liu UqGI2 '(" tOn h(p t [8T? IX2BFv2 % phDi tP h.u " l%

a4it a8amantantetra"arRo4&li" TvF]K[X, tron 8un 8g"h n'9" "a ?avB v`n h(p

'(" un n7n tron RSnh kAn ln H{0 o[ tron /0 iZ, 9i tD" + nQn nhit +

5o[pht, )au 7 nu+i 4uDn nhit + phjn 9i tD" + h= nhit l% 2 o[phtB \En

ph~m l% tinh th Rt 8in kh*n m%u dHF, I0B

Sinh vin: Ng Mnh Tng !! "#p: "c - $%a &'() *+,


12/83


!0!0.0,0 9h1ng php 2(ng nhit

Kron tr'Zn h(p "" h(p phn tham ia phEn :n kh*n tan tron n'9", thS

tr+n muDi kim lo=i % phDi tP h.u " tron 8un m*i thA"h h(p, 'a %o RSnh kAn %

un n7n 1n nhit + thA"h h(pB >A 8M tOn h(p $t liu UqG5 '(" th!" hin

tron 8un m*i 8iet&lormamit TfqXB ?u&n liu l% CnT?IX2BFv2 % a4it H,FGRenzen8i"a"Ro4&li" Tv2Wf[XB v`n h(p hja tan tron 8un m*i '(" thOi khA tr %

"hu&n %o auto"lae, un n7n ln H05 o[ tron 2F iZ, thu '(" )En ph~m k1t tinh

CnFTWf[XIB

U9i Q& ph'n php 8un nhit '(" th!" hin na& 3 nhit + phjnB >A 8M

tOn h(p UqG5, a4it H,FGRenzen8i"a"Ro4&li" % trieth&lamine '(" hja tan tron

8un m*i ?,?G8imet&lormamit TfUqXB UuDi km a4etat "@n '(" hja tan tron

fUq, 'a 8un 8g"h muDi km %o 8un 8g"h "a a4it H,FGRenzen8i"a"Ro4&li",

khu-& tron H5 pht, k1t ta R_t u t=o th%nh, ti1p tM" khu-& tron 2,5 iZ, thu '("$t liu r_n k1t tinh l% UqG5 dFB

!0!0.00 9h1ng php Di( V;

h'n php )iu Qm d5/ l% m+t tron nh.n ph'n php ip rt n_n thZi

ian tOn h(p % =t '(" hiu )u-t "aoB Kron ph'n php n%&, 8un 8g"h phEn

:n '(" ti1n h%nh 8'9i t" 8Mn R:" 4= )iu Qm tron thi1t Rg pht )iu QmB

>A 8M, tOn h(p [uITWK[X '(" th!" hin nh' )au ]4it H,I,5Renzene

tri"a"Ro4&li" TvIWK[X '(" hja tan tron 8un m*i h`n h(p 8imet&lormalin %

ethanol )au 7 em tr+n 9i 8un 8g"h n'9" "a cn a4etat 8ih&8ratB hEn :n '("

ti1n h%nh 8'9i t" 8Mn R:" 4= )iu Qm tron thi1t Rg pht )iu Qm 9i tn )D F0 kvz,

"*n )u-t /0B >9i thZi ian phEn :n /0 pht, thu '(" )En ph~m r_n 9i hiu )u-t

{5,HB \En ph~m l% $t liu r_n k1t tinh [uITWK[X2 B

!0!0.0.0 9h1ng php vi D%ng

h'n php i )7n TmicrowaveX '(" pht hin % :n 8Mn r-t nhiLu

tron lnh !" tOn h(p $t liuB vin na& trn th1 i9i "7 r-t nhiLu nh.n

th%nh "*n t i" :n 8Mn ph'n php n%&, nh' "h1 t=o ra nh.n $t liu

zeolit K\GH, U[UGFH, \W]GH5, \W]GH/ % "" $t liu m9i UqG5, UyGH0HBBB

dHF, 2{, I0B

K nh.n Y" tr'n "a "" m;u $t liu tOn h(p '(", n'Zi ta nh$n th-&

nh.n 'u im m% ph'n php n%& man l=i l% r-t th!" tinB ?1u em )o )nh

i.a ph'n php n%& % ph'n php thu nhit th*n th'Zn "hn ta "7 th

th-& r '(" m+t )D nh.n 'u im nh'

Sinh vin: Ng Mnh Tng !, "#p: "c - $%a &'() *+,


13/83


G t n_n '(" thZi ian k1t tinh iEm i '(" H0 ln )o 9i 8n ph'n

php th& nhit th*n th'ZnB cn thZi l%m iEm nn l'(n nn ph'n php

n%& kinh t1 hn r-t nhiLuB

G fn ph'n php microwavet=o ra $t liu "7 tr$t t! "-u tr" cn Lu

hn ph'n php thu nhitB iLu n%& '(" iEi thA"h l% khi 8n ph'n phpmi"rosae thS khE nn "hi1u 4= l% cn Lu hn 8;n 1n )! t" 8Mn "a nhit

+ ln to%n R+ h`n h(p l% cn nh-t hnB

Uì ph'n php tOn h(p Lu "7 'u im % nh'(" imB vin na&, ;n "jn

r-t nhiLu n` l!" )n t=o ho%n thin iLu kin phEn :n theo mì ph'n php

=t '(" hiu 6uE mon muDnB

1.1.=. 0nh gi0 ti% n>ng c5, v!t "iu M678

Ku& "7 r-t nhiLu nh.n th%nh 6uE nhin ":u L Uq) '(" Ro "o nh'n

theo Ki1n ) ]B[oma dFI nh.n nhin ":u L Uq) m9i "hw l% tron tr:n n'9",nh.n :n 8Mn r+n ri "a Uq) "jn "h'a R_t uB [hn ta "7 th nhSn th-& tiLm

nn nhin ":u l| thu&1t L Uq) 3 )D l'(n "-u tr" Uq) tn ln mì nm,

tiLm nn :n 8Mn 4" t" Uq) tron -n L REo m*i tr'Zn, -n L nhin liu

)="h "n '(" nhin ":u )Qu )_" hn,^B[hAnh S $&, nhin ":u L $t liu Uq)

trn th1 i9i n7i "hun % 3 >it ?am n7i rin ;n "jn r-t m9i mB Kron n+i 8un

"a c n n%& "hn t*i ti1n h%nh nhin ":u tOn h(p $t liu UyGH0H, UyGH0H

tinh th nano, ?v2GUyGH0HT]lX, Ue)o UyGH0H "-u tr" a "-p mao 6uEnB

1.-. ?!t "iu MIL(1@1 NB-(MIL(1@1 v MD8& MIL(1@1 E, cF/ %,& uHn.

1.-.1 ?!t "iu MIL(1@1

UyGH0H l% k1t 6uE nhin ":u tOn h(p "a m+t nh% khoa h#" B qbre& n'Zi

hp TUy l% i1t t_t "aMatriaux de l'Institut LavoisierXB >%o thn nm 2005,

nh% nhin ":u khoa h#" "a Kr'Zn =i h#" >er)aille) ThpX phDi h(p "" 8jn tia

yf IH t=i " )3 R:" 4= \&n"hrotron "hQu u T\qX, Ro "o ti1n + "a h# tron

i" thi1t k1 % Y" tr'n $t liu kA"h th'9" mi"roB \! k1t h(p "a h7a h#" lo lu&n

% thi1t k1 tAnh ton tOn h(p nn m+t $t liu m9i, '(" Yt tn UyGH0H, 9i

kA"h th'9" mao 6uEn l9n thu+" h# $t liu mao 6uEn trun RSnh T I,F nmX % 8in

tA"h RL mYt "ao t F500 m2 G 5500 m2 d20, 22, I{B

\! k1t h(p "a h7a h#" tinh th % m* phn nhm mM" tiu tDi 'u h7a "-u tr"

tinh th tron Ro "o dH{R "a ran8e qere& % nh7m nhin ":u trSnh R%& m+t "-u



14/83


tr" khDi 9i kA"h th'9" m`i "hiLu { J '(" t=o nn t n g [romTyyyX

terephthalate TH,FGRenzen 8i"arRr4&late H,FGWf[XB i1n tr" i 4Dp kA"h th'9" mao

6uEn trun RSnh Rao cm I khDi lin k1t trun ian T mo7il tirt!-nine UK?X TvSnh

HB/ eX t=o ra m+t t1 R%o khOn lc Tth tA"h 02000 J IX 9i h thDn l` "7 'Zn kAnh

T2 G IF JX, th tA"h hai lo=i lcn kA"h th'9" trun RSnh ln l'(t l% H200 % 20/00JIX )3 h.u tiLm nn h-p thu tu&t Zi T\anmuir 500 I00 m2XB [-u tr" "a

UyGH0H '(" 4Q& 8!n t "" )iu t: 8in Tsu8ertetraedral \KXB U`i \K '(" t=o

nn t "" lin k1t "a khDi trime kim lo=i h7a trg TyyyX % "" anion H,FGWf[ TvSnh

HB/ a,RXB WDn wnh "a \K '(" "D gnh R3i "" trime tron khi "u nDi h.u "

Torganic linkerX '(" Yt t=i )u "=nh "a \K ThSnh HB/ "XB in k1t "a khDi )iu t:

8in T\KX t=o ra m+t m=n l'9i Ra "hiLu '(" hSnh th%nh R3i "" "-u tr" lin k1t

UK? ThSnh HB/ 8XB \K l% "-u tr" r`n 4Dp Tkh~u + {,/ JX tron khi k1t "-u khun

t=o R3i hai lo=i lcn kA"h th'9" trun RSnh hin 8in 9i t l 2H, '(" i9i h=n R3iln l'(t 20 % 2{ \K "7 'Zn kAnh lcn ln l'(t l% 2 % IF JB 7 l% ki1n tr" tDt

nh-t tn '(" t=o ra R3i nh7m nhin ":u, "ho th-& nh.n i trg "ao nh-t tn =t

'(" tron thi1t k1 tOn h(p khun kim lo=i G h.u " Uq) 9i lo=i lcn nh T"Pa

)O n@ i" "7 'Zn kAnh mao 6uEn H2,0 JX tron khi lcn l9n "7 "E "Pa )O n@

i" % lM" i" l9n hn "7 'Zn kAnh HF,5 % H/,0 JB

$/nh !0J0 E( tr=c tinh thP MW"-!Q!

Sinh vin: Ng Mnh Tng !. "#p: "c - $%a &'() *+,


15/83


$/nh !0K0 E( tr=c 6ng c1 XYn ca MW"-!Q!

$/nh !00 Znh nhi[( 8 in t\ ]


16/83


$/nh !0!Q0 Znh hiPn vi in t\ tr(Un 4(a O phVn giYi ca ]high r


17/83


vin na& "" nh% khoa h#" trn th1 i9i nhin ":u tOn h(p "" lo=i $t liu

UyGH0H kh" nhau nh' UyGH0H?f[x UyGH0H TqeX, UyGH0H T]lX^

!0,0!0,0 5t 6i( MW"-!Q! tinh thP nan t3ng hLp trng ;i trng Xa@1

>$t liu UyGH0H "7 + 4Dp r-t l9n, l% m+t tron nh.n nhin ":u r+n ri nh-t

L $t liu khun h.u " kim lo=i Uq), '(" tOn h(p tron ph=m i r+n "aiLu kin phEn :n nh' ncn + n'9", + pv m*i tr'Zn % ph'n php tOn h(p

kh" nhau Tia nhit th*n th'Zn, "hi1u 4= i )7n, )iu QmX "7 '(" kA"h th'9"

tinh th nanoB A"h th'9" tinh th iEm khi tn ncn + n'9" % pv 8un 8g"hB \!

iEm kA"h th'9" tinh th khi pha lon "" "h-t phEn :n "7 th '(" iEi thA"h R3i

tD" + tn tr'3n tinh th "h$m hn )o 9i tD" + t=o mm tron 8un 8g"h h`n h(p

phEn :nB vn n.a, pv 8un 8g"h "ao th" ~& )! phQn tn a4it terephtali" % "E

"ation [rI, t=o iLu kin thu$n l(i "ho 6u trSnh t=o mm UyGH0H tron thi1t Rg

phEn :nB Kron m+t iLu kin '(" l!a "h#n, UyGH0H "7 kA"h th'9" khoEn 50 nm"7 th '(" t=o ra % ti )En 4u-t 9i nn )u-t "ao, "7 th m3 r+n "" :n 8Mn "a

$t liu Uq "7 i trgB

Ki1n R+ n Q& n "h | trn "" $t liu 4Dp =t '(" R3i )! pht trin

"a $t liu Uq), $t liu lai h.u " G * " tinh th 4Dp d2B Km 6uan tr#n "a

Uq), lo=i $t liu "7 + 4Dp r-t l9n % 8 8%n iLu "hwnh kA"h th'9" l` mao 6uEn

% hSnh 8=n t h thDn mao 6uEn nh Tmicro8orousX t9i h thDn mao 6uEn trun

RSnh Tmeso8orousX % l9n Tmacro8orousX Rn ""h tha& Oi "" "u nDi "a "" "Mm

* " % REn "h-t "a "" lin k1t tron "Mm * " d2B

[ho 1n na&, tOn h(p Uq)x lo=i $t liu '(" nhin ":u r+n ri kh*n

"hw "ho i" tSm ki1m "" "-u tr" m9i m% "jn tSm ki1m "" ph'n php hiu

6uE nh' "hi1u 4= i )7n TMicrowave"M9X dI/ % )iu Qm T4ltrasonic 42X d5/B

Ku& nhin, i" kim )ot hSnh thi "a Uq), Y" Rit "7 '(" Uq) kA"h th'9"

nano kh*n '(" nhin ":u "hi ti1t mY" 8 n7 l% r-t 6uan tr#n R3i S "" Uq)

kA"h th'9" nano "7 nh.n :n 8Mn tiLm nn nh' "h-t man 8'(" ph~m d/H, /2 %

"h1 t=o Enh d/IB vn n.a, hSnh 8=n % kA"h th'9" "a m+t $t liu 4Dp l% r-t 6uan

tr#n "ho "" :n 8Mn nh' m%n 4" t" % phQn t"h d/F, /5B

vSnh 8=n % kA"h th'9" "a Uq) '(" kim )ot, Y" Rit l% "ho "" Uq)

nano, R3i m+t %i ph'n phpB >A 8M k thu$t )iu Qm tOn h(p Uq) tinh th

nano d//B KOn h(p UqG5 % UqGH dHH5 3 nhit + t'n Di "aox tu& nhin,

"hn "7 tinh th kh l9n mY" 8 kA"h th'9" nh hn )o 9i ph'n php tOn h(p

th*n th'Zn T[XB U+t h# Uq) '(" #i l% "" khun zeoliti" imi8azolate TCyqX

Sinh vin: Ng Mnh Tng !K "#p: "c - $%a &'() *+,


18/83


nh' CyqG dHH/ % CyqG{ dHH '(" tOn h(p tron iLu kin phEn :n )P 8Mn

l'(n 8' "u nDi imi8azole) t=o th%nh Cyq 9i kA"h th'9" nh hn 50 nmB iLu

kin phEn :n "@n '(" tha& Oi hoY" tDi 'u h7a tOn h(p Uq) 9i "" hSnh

thi kh" nhauB UqGH tinh th '(" tOn h(p 3 "" hSnh thi kh" nhau Rn

""h tha& Oi "" iLu kin phEn :nx tu& nhin, th'Zn thu '(" "" tinh th kA"hth'9" mi"romet dHH{B

h'n php "hi1u 4= i )7n TMicrowave" M9X "@n '(" )P 8Mn, % kA"h

th'9" thu '(" th'Zn nh hn )o 9i $t liu tOn h(p Rn ""h ia nhit th*n

th'Zn TConventional :lectrical" C:X dHHB [" nh% khoa h#" "hw ra rn kA"h

th'9" "a m+t "-u tr" Iron-7enzenedicar7ox!late TqeGWf[X "7 th tOn h(p 9i

kA"h th'9" iEm Rn U hoY" theo th: t! [ U \ '(" tOn h(p t ""

phEn :n iDn nhau 3 "n iLu kin nhit + phEn :n dH20x tu& nhin, "" tinh

th "7 kA"h th'9" kh l9n T 0,5 m na& "E Rn ph'n php )iu Qm T\XB UYtkh", trn " )3 k thu$t i nh@, "h-t :" "h1 '(" )P 8Mn "7 '(" kA"h th'9"

nano Uq) d/I % kA"h th'9" "h#n l#" UqG5 dH2HB Ku& nhin, "" ph'n n

tOn h(p "7 phn ph:" t=p % khE nn "" h7a "h-t phM tr( ;n "jn tron Uq) )au

tOn h(pB

>i" kim )ot hSnh thi h#" "a UyGH0H "@n '(" \un vsa hun %

cn nhip Ro "o 9i k thu$t U dH22B UyGH0H "7 kA"h th'9" nano T H00

nmX "7 th thu '(" t=i iai o=n u "a phEn :n, nh'n )En l'(n th-p % khE

nn ti )En 4u-t th-p dH25B ]minoGUyGH0H TUq 9i "-u tr" UyGH0H, '(" t=o

ra t aminoGK]X "7 kA"h th'9" H20 nm '(" )P 8Mn l%m "h-t man 8'(" ph~m

% "h1 t=o Enh, nh'n kh*n "7 ph'n php tOn h(p "M th '(" ti1t l+ d/HB

Kron 7 Ro "o i" pha lon h`n h(p phEn :n "7 li "ho tOn h(p "" Uq) "7

kA"h th'9" nh nh' UyGH0H dH2I % [uGWK[ dH2F, k1t 6uE thu '(" kA"h th'9"

"a UyGH0H l% khoEn H50 nm % [uGWK[ l% kh l9n )o 9i tinh th nanoB KOn

h(p UyGH0H 3 pv "ao T/G/,5X "@n '(" Ro "o nh'n kA"h th'9" khoEn 200

I00 nmB >S $&, r-t n 6uan tQm nhin ":u m+t ph'n php tOn h(p Uq

tinh th nano, Y" Rit l% UyGH0H Rn ""h tha& Oi iLu kin phEn :nB [uDi "n,

m+t ph'n php )En 4u-t UyGH0H nano "7 hiu )u-t "ao m% kh*n "n )P 8Mn

"h-t ho=t +n RL mYt, "h-t :" "h1 hoY" "h-t kSm hm )! tn tr'3n tinh th, l% m+t

mon muDn "ho "" :n 8Mn kh" nhau Rao cm "E "h-t man 8'(" ph~m % "h1

t=o EnhB h'n php n iEn tOn h(p nano UyGH0H Rn ""h tDi 'u h7a iLu

kin phEn :n nh' pv % ncn + n'9" )P 8Mn k thu$t "hi1u 4= i )7nB Kinh th



19/83


nano UyGH0H 9i kA"h th'9" khoEn 50 nm tOn h(p th%nh "*n 9i hiu )u-t I

Rn ""h "hi1u 4= i )7n tron H5 pht t 8un 8g"h h`n h(p " )3 pha lon

d{/B Q& l% k1t 6uE tDt nh-t tn '(" Ri1t, thu '(" Uq) nh nh-t 9i hiu )u-t

)En ph~m t'n t! ph'n php tOn h(p "a ran8e qere& dH{B Ku& nhin Y"

im h=n "h1 "a hu h1t "" ph'n php n%& l% hiu )u-t )En ph~m tOn h(p th-pT 50X % kh*n n iEn h7a '(" 6u& trSnh t"h l#" )En ph~m R3i )! ti k1t tinh

"a a4it terephtali" 8' tron h`n h(p )En ph~m )au tOn h(pB

\! ti k1t tinh "a tinh th a4it terephtali" 8in ra na& tron h`n h(p phEn :n

"hAnh l% nu&n nhQn l%m "ho hiu )u-t )En ph~m tOn h(p UyGH0H th-p T 50X

% i" t"h l#" a4it terephtali" ti k1t tinh tr3 nn ph:" t=pB "7 '(" nn )u-t

"ao, "" nh% nhin ":u "Ei thin "" ph'n php tOn h(p kim )ot iLu

kin +n h#" phEn :nB Ku& nhin, ph'n php n%& kh*n n iEn h7a '(" 6u&

trSnh t"h l#" dI, F0B [hn t*i 6uan tQm t9i i" iEm h%m l'(n ti k1t tinh a4itterephtali" Tv2Wf[X tron h`n h(p )En ph~m )au iLu "h1 % 8o 7 trnh "" ph'n

n ph:" t=p khi t"h l#" m;uB f!a trn )! hiu Ri1t rn v2Wf[ "7 th hja tan 8

8%n tron 8un 8g"h kiLm dF2, m+t m*i tr'Zn Raz '(" l!a "h#n tn )En

l'(n UyGH0H % trnh )! ti k1t tinh "a v 2Wf[B [hn t*i )P 8Mn 8un 8g"h

kiLm "7 tAnh "h-t gnh h'9n "-u tr" Ketraprop&lammonium h&8ro4i8e TK]vX

tron iLu kin tOn h(p 8un nhit 3 nhit + TH{0 o[X tron thZi ian T20 iZXB

viu )u-t )En ph~m thu '(" "ao hn hn )o 9i "" ph'n php tOn h(p tr'9"

Q& T{F X % n iEn h7a '(" 6u& trSnh t"h l#" )En ph~m )au tOn h(p, p :n

'(" &u "u "*n nh m3 r+n 6u& m* )En 4u-tB \En ph~m thu '(" l% "h-t R+t

r_n mgn 4anh "7 "-u tr" tinh th nano T 50 nmX Y" tr'n R3i "*n th:" phQn tP

CK6BKB-6-6K6-CCB9KC6-O.nB-6. Kron 7 n 25B

v'9n pht trin ti1p theo, "hn t*i nhin ":u +n h#" k1t tinh iLu khin

kA"h th'9" tinh th % tDi 'u h7a iLu kin k1t tinh tOn h(p "-u tr" tinh th nano

UyGH0H Rn ph'n php "hi1u 4= i )7n TMicrowaveXB

1.-.-. ?!t "iu MD8& MIL(1@1

!0,0,0!0 5t 6i( ;a 4(Yn tr(ng X/nh ]MdTe`

Y" im 6uan tr#n nh-t "a "" $t liu UVKW Tmeso8orous materialsX l%

"hn "7 kA"h th'9" mao 6uEn r+n, 8in tA"h RL mYt rin l9n, 8o 7 $t liu )

"h:a nhiLu tQm ho=t +n 3 trn RL mYt nn 8 8%n ti1p "$n 9i t" nhQn phEn :nB

Ku& nhin, $t liu UVKW kh*n phEi l% $t liu tinh thB bt L mDi 6uan h 4a thS



20/83


"" mYt m=n, )! )_p 41p "" mao 6uEn^ '(" phQn RD theo 6u& lu$t tun ho%n nh'

tron m=n tinh th, nh'n nhSn 3 7" + n thS "" phn tP Tion, nu&n tP, nh7m

nu&n tP,^X l=i lin k1t 9i nhau m+t ""h * gnh hSnhB ?h' $& "7 th 4em $t

liu UVKW l% iE tinh thB

U+t "Qu hi Yt ra l% t=i )ao "" $t liu UVKW '(" tOn h(p kh*n 3 8=n

tinh th [" nh% khoa h#" "ho rn + tinh th "a $t liu lu*n lu*n "7 mDi 6uan

h 9i m$t + m=n T)D nu&n tP tron m+t nmI Framework ;ensit!, qfXB ?m

H{, Wrunner % Ueier nh$n th-& rn "" "-u tr" tinh th "h:a nu&n tP K

Tnu&n tP tron "-u tr" t: 8inGtetraonalX Lu phEi tuQn theo m+t 6u& t_" nhim

nYt i.a qf % kA"h th'9" jn K Tjn X "!" tiu TUy? Minimum ringX dH0B

Kh!" $&, "" o4it tinh th 9i "-u tr" Uy? F % :n 9i khoEn trDn "!" =i

tron $t liu Tvoid


21/83


ncn + ion tron 8un 8g"hB ?7i ""h kh", [U[ tn khi tn Rn kAnh Di ion, pv

% nhit +B [hn h=n 3 25o[ [K]W "7 [U[ l% 0,{I mUx t [U[ 1n HH 4u-t

hin "" mi4en hSnh "ux t HH 20,5 hSnh th%nh "" mi4en hSnh 6ue linh +nx

pha tinh th ln lM" '(" hSnh th%nh 3 ncn + 2/ /5x n1u ti1p tM" tn ncn +

) 8;n 1n hSnh th%nh "" pha l$p ph'n, pha l9p mn % "uDi "n l% hSnh th%nh"" mi4en EoB 0 o[, thu '(" pha lM" ln khi ncn + =t 1n i trg /5B Krn

" )3 "a )! t$p h(p "" phn tP "h-t ho=t +n RL mYt 7, n'Zi ta )P 8Mn "hn

nh' t" nhQn gnh h'9n "-u tr" tron 6u trSnh tOn h(p $t liu UVKWB

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P h n t c h th o t n g b m t

C M C

P h a t in h th l n g

C h i u t n g n n g c h t h o t n g b m t

C c d n g m i x n

! n g c " u

P h a l # c l n g! n g $ u P h a l % & & h ' n g P h a l ( & m n g

$/nh !0!!0 Ec trng thi t5p hLp ca phVn t\ cht $eM

Kin phon tron lnh !" nhin ":u $t liu UFH\ dH2/ 8, "" nh% nhin ":u

"a UoRil )P 8Mn "h-t ho=t +n RL mYt l% "" alk&ltrimet&l ammonium

haloenua l%m "h-t t=o khu*n "-u tr"x )P 8Mn natri h&8ro4it T?avX hoY"

Ketraet&lammonium h&8ro4i8e TK]vX t=o m*i tr'Zn Raz "ho h`n h(p phEn

:nB [" nh% nhin ":u tSm ra m+t mDi t'n 6uan 7 l% ncn + t'n Di "a

"" "-u tP tron h`n h(p phEn :n Enh h'3n r-t l9n 1n "-u tr" l` "a $t liuB v#

"@n "hw ra rn 'Zn kAnh l` "a U[UGFH tn ln khi tn "hiLu 8%i m="h alk&l"a "h-t ho=t +n RL mYtB vn n.a, n1u thm me)it&len %o h phEn :n, "h-t n%&

) hja tan %o tron "" mi4en l%m "ho th tA"h "a mi4en tn ln hn n.a %

'Zn kAnh "a l` 4Dp $t liu *i khi "7 th =t t9i H20 J, 7 l% m+t )! R-t nZ R3i

kA"h th'9" l` "a U[UGFH th'Zn t H5 H00 JB

Sinh vin: Ng Mnh Tng ,! "#p: "c - $%a &'() *+,


22/83


Kron nh.n "*n trSnh )au 7, n'Zi ta L 4u-t nhiLu Ri1n th "a ph'n php

tOn h(p trn dH2 a, R, "B ?h.n "Ei ti1n "7 th Rao cm thm 8n a4it %o h phEn

:n tron )uDt 6u trSnh tOn h(p, tDi 'u h7a pv "a h`n h(p phEn :n dH2 8, thm

anion qG"7 t" 8Mn nh' m+t "h-t 4" t" dH2 e, thm "h-t cn ho=t +n RL mYt

% th& nhit )_p 41p l=i "-u tr" $t liuB ]n8er)on % "+n )! nhin ":u Enhh'3n "a i" thm cn 8un m*i %o h`n h(p phEn :n, h# thu '(" nh.n $t

liu kh*n "7 tAnh tr$t t! khi h%m l'(n cn 8un m*i tn lnB

Ku< thu+" %o in tA"h "a nh7m 'a n'9", vWU "7 th '(" "hia th%nh Ra

lo=i dH2

G C=t %3M lo&i anion nh7m 'a n'9" man in tA"h Qm nh' )unat [nv2nH\IG,

)unonat [H/vII\IG, phDtpht [HFv2Iv2, "" a4it "a"Ro4&li" B

G C=t %3M lo&i cation nh7m 'a n'9" man in tA"h 8'n nh' muDi "a

alk&trimet&lamonihaloennua 9i m="h ank&l t [{G[H{B

G C=t %3M lo&i k+ng ion nh7m 'a n'9" kh*n man in tA"h nh' "" amin

trun ho%, "" "opol&mer, pol& et&len o4it^

Ec HiP( t3ng t1ng tc ca cht ht Ong X ;t vA tin cht v c1

vuo % "+n )! L 4u-t RDn kiu t'n t" kh" nhau "7 th iEi thA"h Rn

nh.n " "h1 )au dH2{ a

G iu T\yGXB Kron tr'Zn h(p n%& "h-t ho=t +n RL mYt "ation T\X '(" )P 8Mn

t=o khu*n "ho "" lo=i anion * " Ty GXB Q& l% ph'n n tOn h(p lo=i $t liu

U[UGFHB

G iu T\GyXB >9i L 4u-t n%&, "h-t ho=t +n RL mYt anion T\GX t'n t" 9i lo=i

"ation * " TyGXB

G iu T\GyXB Q& "E "h-t ho=t +n RL mYt % phQn tP * " Lu l% "ation, 8o

7 phEi "7 m+t Di ion man in tA"h Qm l%m trun ian "ho t'n t" i.a "hn

TG [lGx WrG ^XB

G iu T\GUyGXB Kron tr'Zn h(p "uDi "n n%&, "E "h-t ho=t +n RL mYt % phn

tP * " Lu l% anion % phEi )P 8Mn Di ion man in tA"h 8'n TU

?a

x

^X l%m trun ian hSnh th%nh "-u tr"B

Sinh vin: Ng Mnh Tng ,, "#p: "c - $%a &'() *+,


23/83


$/nh !0!,0 S t1ng tc gi>a cht ht Ong X ;t vA cc cht v c1

\! t'n t" i.a "h-t vWU T\X % tiLn "h-t * " TyX l% &1u tD 6uan tr#n "ho

)! hSnh th%nh $t liu UVKWB K hSnh HBH2 ta th-& Di 9i "h-t vWU lo=i ion

Tanion, "ationX )! hSnh th%nh $t liu UVKW "h &1u 8o )! t'n t" tnh inB

Kr'Zn h(p n iEn nh-t, in tA"h nh7m 'a n'9" "a "h-t vWU % tiLn "h-t *

" l% Di nhau, khi 7 t'n t" ) l% \ yGhoY" \GyB vai t'n t" kh" 4E& ra khi

"h-t vWU % "h-t * " "n lo=i in tA"h 7 l% \Gy, \GUyGB K'n t" \Gy

4E& ra tron m*i tr'Zn a4it "7 mYt "a "" anion haloen GT[lG, WrGX, t'n t" \G

UyG4E& ra tron m*i tr'Zn kiLm 9i )! "7 mYt "a "ation kim lo=i kiLm U T?a,

XB Di 9i "h-t vWU lo=i kh*n ion, t'n t" i.a "h-t vWU % tiLn "h-t *

" l% t'n t" 6ua lin k1t h&8ro hoY" l'n "!" \oyo, \oTyoXB

ai tr ca cht nh h#ng c( tr=c:

G KO "h:" m=n l'9i th*n 6ua i" l-p & "" l` 4Dp, "Qn Rn in tA"h d{B

G K=o nn hSnh thi "-u tr" "ho "" knh mao 6uEn th*n 6ua hSnh 8=n, kA"h

th'9", tAnh "h-t "a "hnB

G %m iEm th1 h7a h#" "a m=n l'9i hSnh th%nh nhZ t=o nn "" t'n t" 9i

"" "h-t * " Tlin k1t h&8ro, t'n t" tnh in,BBXBG [h-t t=o "-u tr" "7 khE nn hja tan tDt tron 8un 8g"h, RLn 8'9i "" iLu kin

tOn h(p, "7 khE nn l%m RLn m=n l'9i mao 6uEn '(" hSnh th%nh, t"h khi

$t liu m% kh*n Rg ph h& khunB dHH

!0,0,00 5t 6i( M


24/83


>9i nh.n Y" tAnh nOi tr+i "a tinh th 4Dp "-u tr" khun h.u " G kim lo=i

Uq) nh' kA"h th'9" mao 6uEn l9n, 8in tA"h RL mYt "ao d5G{0B [" tAnh nn nOi

R$t "a $t liu thu ht )! 6uan tQm n k tron "" :n 8Mn tiLm nn l'u tr.

khA h&8ro d{H, 4" t" d{2, phQn t"h khA d{I, "Em Ri1n )inh h#" d{F % "h1 t=o

"h-t man 8'(" ph~m d{5B Ku& nhin, hu h1t "" tinh th $t liu Uq) th hinm+t )D h=n "h1 S "" l` mao 6uEn nh Tmicro8oreX "En tr3 )! 8i "hu&n "a ""

phQn tP l9n tron "" knh mao 6uEn, 8o 7 h=n "h1 "" :n 8Mn th!" t1 "a $t

liu tron 4" t" 8g th, h-p thM, phQn t"h khA "@n nh' "h1 t=o "Em Ri1nB kh_"

phM" tr3 n=i n%&, m+t "hi1n l'(" tOn h(p nhm ia tn "hiLu 8%i phDi tP h.u "

m3 r+n l` % tn + 4Dp "a Uq) '(" trin khai, nh'n tron nhiLu tr'Zn

h(p "" khun m=n "a $t liu %o thEi "" phQn tP l= n%&B U+t ph'n n tOn

h(p kh" l% nhm iEm kA"h th'9" "a tinh th Uq) t9i kA"h th'9" nano d{/ % 8o

7 l%m iEm "hiLu 8%i 'Zn i khu1"h tn "a "" phQn tP $t "h-tB h'n n n%&nQn "ao '(" hiu )u-t phEn :n, tu& nhin i" iLu khin kA"h th'9" tinh th l% r-t

kh7 khn tron iLu kin +n h#" tOn h(pB [hAnh S $& "hi1n l'(" tOn h(p $t

liu Uq) "-u tr" a "-p mao 6uEn 9i phQn RD l` trun RSnh % l9n T meso8ore

macro8oreX Rn ""h )P 8Mn t" nhQn gnh h'9n "-u tr" nh$n '(" nhiLu )!

6uan tQm n k 8o m:" + iLu "hwnh "-u tr" "ao % th hin nhiLu tAnh nn +"

o "a Uq) "-u tr" phQn "-p mao 6uEn trun RSnh T mesostructureX d{GHB Wn

tron $t liu "-u tr" a "-p mao 6uEn Ue)oGUq), "" 6u trSnh "hu&n Oi khDi

l'(n 8in ra m=nh m, tr3 th%nh $t liu 8u& nh-t "7 th "un "-p "" :n 8Mn

tiLm nn n k nh' l%m "h-t 4" t" 8g th, h-p thu, phQn t"h khA % "h1 t=o "Em

Ri1nB

KhZi ian n Q& an Chan % nh7m nhin ":u Ro "o ln u tin m+t

thi1t k1 h(p l| % tOn h(p th%nh "*n $t liu Uq) phQn "-p micro - meso8ore

v\KGH '(" iLu "hwnh + 4Dp Rn "" )P 8Mn )iu phQn tP "h-t ho=t +n RL

mYt l%m t" nhQn gnh h'9n "-u tr" d{{ Rn "=nh h thDn mi"ropore Dn "7 T

{,2 JX tron tinh th v\KGH, i" tOn h(p "-u tr" Ue)o v\KGH thu '(" h

thDn mao 6uEn trun RSnh 9i 'Zn kAnh t I,{ G IH,0 nm d{{ TRo "o tOn h(p

"-u tr" Ue)o v\KGHX, % "h:n minh 'u th1 $t liu "ho )! h-p thu h&8ro d{B

aliauine % cn nhip tOn h(p "-u tr" UyG5IT]lX Rn ""h )P 8Mn

polime H2I % qH2 l%m t" nhQn gnh h'9n "-u tr" d0 aB Wo "o "a ahi

tOn h(p th%nh "*n UqG5 "7 )! phQn "-p micro-meso-macro8ore, Rn ""h )P

8Mn m+t l'(n nh-t gnh "a TFGTfo8e"&lo4&XRenzoi" a"i8 fW]X dH tOn h(p

Sinh vin: Ng Mnh Tng ,. "#p: "c - $%a &'() *+,


25/83


"-u tr" phQn "-p )pnGUqG5 % pmGUqG5 9i t l fW]v 2Wf[ ln l'(t l%

5050 % I00 TvSnh HBHFXB Ku& nhin, 1n na& i" 4Q& 8!n Uq) "-u tr" phQn

"-p me)o h(p l| ;n "jn At '(" khm phB

$/nh !0!0 E1 chF h/nh thAnh c( tr=c tinh thP nan phVn cp ;a 4(YnMicr-;


26/83


[-u tr" a "-p mao 6uEn khun kim lo=i G h.u " Ue)o UyGH0H '(" tOn

h(p th%nh "*n tron iLu kin tOn h(p 8un nhit TsolvotermalX t'n t! nh'

tron 6u trSnh tOn h(p UyGH0H nh'n "7 )P 8Mn )iu phQn tP "h-t ho=t +n RL

mYt Cet!ltrimet!lammmonium 7romideT[K]WX l%m t" nhQn gnh h'9n "-u tr"B

>$t liu Uq) "-u tr" Ue)o UyGH0H '(" Y" tr'n nhiu 4= Ga&, hin i intP 6ubt \TUX, hin i in tP tru&Ln 6ua KTUX, n nhit h-p phM % iEi h-p

?it 3 B 1t 6uE "ho th-& "-u tr" Ue)o UyGH0H thu '(" l% r-t nhiLu tinh th

nano Uq)B hQn tA"h phQn RD l` "ho th-& $t liu UyGH0H "-u tr" me)o tcn t=i "E

h thDn meso8ore% macro8oreB n "h | "-u tr" me)o phQn "-p UyGH0H th

hin ho=t tAnh h-p phM r-t "ao lo=i R thuD" nhu+m )o 9i $t liu UyGH0H tinh

th tr'9" Q&, 7 l% 8o "-u tr" phQn "-p meso8oreG macro8ore'(" t=o th%nh tron

"h-t r_nB

[hn t*i "h#n UyGH0H l%m :n "P in R3i S "" tinh th UyGH0H l% $tliu 8u& nh-t "7 kA"h th'9" mao 6uEn nm tron khoEn 2GIF J, "-u tr" Ra "hiLu

8=n khDi Rt 8in, "7 8in tA"h RL mYt anmuir l9n, "@n nh' tAnh "h-t h7a h#"

tu&t Zi % khE nn On gnh nhit "ao dH{B UyGH0H 9i hSnh thi Uq) m9i %

"-u tr" me)o phQn "-p '(" tOn h(p th%nh "*nB vSnh thi "a $t liu '" tSm

th-& kh" nhiLu )o 9i "" tinh th mi"ro Tmicro8orousX Rt 8in phM thu+" %o t l

"a phQn tP [K]W gnh h'9n "-u tr" ion [rIB n "h |, "-u tr" me)o phQn "-p

UyGH0H '(" "h:n minh tn "'Zn n k khE nn h-p phM lo=i R thuD"

nhu+m khi )o )nh 9i )D l'(n l9n tinh th UyGH0HB W3i $& Ue)o UyGH0H l% )!

l!a "h#n l| t'3n "ho thi1t k1 "" lo=i $t liu 4Dp "-u tr" tinh th m9i "ho "" :n

8Mn l%m 4" t" 8g th, "Em Ri1n % phQn t"h khAB

1.-.. ?!t "iu chPc n>ng h#, ,%in& NB-(MIL(1@1KA"

Krn " )3 k1t h(p "" tiu phQn h.u " % * ", "" $t liu 4Dp "-u tr" tinh

th '(" nhin ":u tOn h(p ln 1n h%n n%n "-u tr" Uq) d2B =t '("

nhiLu ti1n R+ n k tron lnh !" 4" t", phQn t"hB Ku& nhin, m+t )D &1u tD

an "En tr3 )! pht trin "a "" :n 8Mn Uq) tron "" lnh !" nhin ":u

6uan tr#nB u tin, )! pht trin phi m "a "" nhin ":u Uq) th" ~& )! ra

Zi "a "" nu&n l| tOn h(p, 8;n t9i "" "*n trSnh nhin ":u kh*n & m%

hu nh' kh*n '(" pht trin ti1p )au 7B vn n.a, mY" 8 m+t )D $t liu Uq)

nh' UyGH0H dH{, UilG5I d2, CyqGH dI [G2 dF, 5 % yG// d/, "ho

th-& )! On inh nhit % tAnh "h-t h7a h#" kh" th'Zn nh'n i" )P 8Mn "" "-u

tr" Uq) tron "" :n 8Mn l%m 4" t", phQn t"h phn l9n ;n "jn h=n "h1 R3i

Sinh vin: Ng Mnh Tng ,J "#p: "c - $%a &'() *+,


27/83


thi1u "" nh7m "h:" nn % tAnh "h#n l#" tron hu h1t "" $t liu Uq)B ["

ph'n n th!" t1 t=o ra "" $t liu r_n "h:" nn Rao cm tOn h(p tr!" ti1p

Tdirect s!ntesisX hoY" _n nh7m "h:" nn T8ost-s!ntesis


28/83


$/nh !0!+0 1n v c( tr=c c1 XYn ca v5t 6i( N$,-MW"-!Q!]l6`

[-u t=o khDi "h-t r_n "h:a hai lo=i lcn 8=n "u kA"h th'9" trun RSnh

Tmeso8orousX '(" hSnh th%nh R3i H2 n@ i" % H/ mYt t'n :nB [" hD" nh "7

'Zn kAnh H,2 nm tron khi "" hD" l9n lM" i" l% H,/ nm ThSnhHBH/XB \! "7 mYt

"a "" g trA kim lo=i phDi trA kh*n no Tcoordinativel! unsaturated metal sites"

[\X t=o ra UyGH0H "7 tAnh a4it esi) dIH % 6uan tr#n hn, "ho phbp _n nh7m

"h:" nn "a n7 th*n 6ua 6u trSnh hbp nDi dHHFB ` mao 6uEn "7 hai kA"h th'9"

kh" nhau, + 4Dp "ao "n 9i )! On gnh nhit, On gnh h7a h#" l%m "ho n7 tr3th%nh m+t :n "P in tu&t Zi "ho :n 8Mn phQn t"h khA % 4" t" "a UyGH0HB

$/nh !0!J0 $/nh thi c( tr=c N$,-MW"-!Q!]l6`: E( tr=c MTN ca cc 6ng

;


29/83


hi 4bt 1n thi1t k1 m=n l'9i, "hw UyGH0HT[rX % ?v2GUyGH0HTqeX '(" Ri1t

1n "ho 1n na& dHH0, tron khi Uq) t=o ra R3i kim lo=i h7a trg TyyyX % "" "u

nDi terephthalate thS "-u tr" UyG5I "7 th%nh phn h7a h#" r+n l9n hn "E L kim

lo=i % "" mDi lin k1t "h:" nn '(" Ri1t 1nB iLu n%& kh*n n=" nhin khi

4em 4bt UyGH0H l% )En ph~m +n h#" % UyG5I l% "-u tr" nhit +n l!" h#"'(" 'u tin tn tr'3n khi R_t u t 6u trSnh "ompo)it h7a dHH0B KOn h(p

t'n t! )au n%& "@n nhm mM" A"h "h:" nn h7a amino trn "" Uq)G]l kh",

)En ph~m "h:" nn h7a trn UyGH0HTqeX '(" Ro "o % p 8Mn l%m "h-t

man 8'(" ph~m tron & t1 d{5 th hin )! On gnh nhit % h7a h#" t'n Di th-pB

Q& ore a)"on Ro "o tOn h(p m+t pha r_n tinh khi1t "a "-u tr" UyG

H0HT]lXB 1t 6uE "ho th-& m+t h(p "h-t h7a h#" "7 "-u tr" tinh th % )! On gnh

nhit "aoB [" Y" tAnh phQn t"h '(" nh i L m:" + "h#n l#" th%nh phn

h-p phM % phQn t"h h`n h(p, "h:n minh rn khun h.u " '(" _n nh7m "h:"nn amino l% m+t :n "P in tu&t Zi "ho i" phQn t"h "h#n l#" [2 t khA

Uetan % ?itB vn n.a, nhZ )! "7 mYt "a "" nh7m amino, ?v 2GUyGH0HT]lX th

hin tAnh "h-t 4" t" nOi R$t % l% m+t :n "P in ho%n hEo "ho i" tOn h(p $t

liu "h:" nn h7a lin k1t "+n h7a trgB

Krn " )3 $t liu "h:" nn h7a amino Tamino


30/83


Chng -

CC RBSNG RBR NGBIN C2U

-.1. Rhng /h0/ thVc nghi%

-.1.1. 4ng c4 v h#, chFt 8W 34ng

( fMn "M U& khu-& t G ia nhit WSnh n7n, "D" m ipet WSnh Kelon % ]uto"lae

G v7a "h-t )P 8Mn trSnh R%& 33@ng 10/WEn 2BHB [" h7a "h-t )P 8Mn tOn h(p Uq)

\KK Kn h7a "h-t )P 8Mn |

hiu

[*n th:" phQn tP Kinh

hi1t

TX

u-t

4:

H [horo8ium TyyyX nitrate [rT?IXB v2 [hina

2 H,FGWenzene8i"arRo4&li"a"i8

v2Wf[ [/vFT[vX2 B Uer"k

I 2GaminoGH,FG

Wenzene8i"arRo4&li" a"i8

2G?v2G

v2Wf[

[/vI?v2T[vX2 \ima

]l8ri"hF qluorh&8ri" a"i8 vq F0 [hina5 ?,?G8imet&l ormami8e fUq T[vIX2?[TXv B Uer"k/ ?'9" khP ion T"-t 2 lnX v2 B >it

?am Ketraprop&lammonium

h&8ro4i8e

K]v T[IvXFG? TvGX F0 \ima

]l8ri"h{ [et&ltrimeth&lammonium

Rromi8e[K]W vI[GT[v2XH5G?T[vIXI

TWrGX

Uer"k

]luminum "hlori8e

he4ah&8rate

]l[lIB/v2 [hina

H0 Uethanol [vIv B [hinaHH thanol [vI[v2v B [hinaH2 ]"etone [vI[[vI B [hinaHI v&8rate meth&lene Rlue UW [H/vH{?I\[lBIv2 [hina

-.1.-. Rhng /h0/ tng h;/ v!t "iu $hung $i% "&'i < h)u c

,0!0,0!0 T3ng hLp v5t 6i( MW"-!Q! trng ;i trng a8it

Sinh vin: Ng Mnh Tng Q "#p: "c - $%a &'() *+,


31/83

fun 8g"h[rT?IXIBv2

hu-& tr+n Hh,

thu h`n h(p ]

Kh& nhit

220o[, h thu h`n h(p W

#" rPa Rn n'9" trn i-& l#" )D 2,thu )ol lnG r_n [

#" ht "hQn kh*n Rn i-&

l#" )D 5, thu R+t mgn r_n f

\-& H00o[, Ih

fun nhit 9i ethanol n7nH00 o[, 2Fh

#" rPa Rn ethanol n7n,)-& 0 o[, FhMIL(1@1

fun 8g"hv2Wf[, vq


$/nh ,0!0 S1 t3ng hLp v5t 6i( Hh(ng Hi; 6i o h>( c1 MW"o!Q!v`n h(p W )au phEn :n tOn h(p thu '(" l% h`n h(p r_n "a tinh th $t liu

UyGH0H m%u 4anh l "Q& % tinh th a4it tereGphtali" ti k1t tinh 8=n hSnh kimB hEi

ti1n h%nh l#" hai iai o=n t"h tinh th hSnh kim "a a4it tereGphtali" ti k1t tinh

ra khi )En ph~m R+t mgn 4anh UyGH0HB\au tOn h(p hiu )u-t )En ph~m UyGH0H 8=n R+t mgn 4anh l "Q& thu '(" l%

I{B [ho th-& hiu )u-t tOn h(p tron m*i tr'Zn a4it 3 iLu kin th& nhit th-p,

"" iai o=n t"h l#" ph:" t=p l% "" &1u tD "n '(" nhin ":u kh_" phM"B f;n t9ih'9n nhin ":u tOn h(p tron m*i tr'Zn Raz '(" "hn t*i 4u-t nhm h=n

"h1 tDi thiu )! ti k1t tinh "a a4it terephtali" tron iLu kin tOn h(p % tn hiu

)u-t )En ph~mB

,0!0,0,0 T3ng hLp v5t 6i( MW"-!Q! tinh thP nan trng ;i trng Xa@1



32/83

fun 8g"h[rT?IXIBv2

hu-& tr+n Hh,thu h`n h(p ]

Kh& nhit H{0 o[, 20 hthu h`n h(p W

#" l& tQm, thu R+tmgn [

\-& H00o

[, Ih



fun 8g"hv2Wf[, K]v


$/nh ,0,0 S1 t3ng hLp v5t 6i( MW"o!Q! tinh thP nan trng ;i trng Xa@1

v`n h(p W )au phEn :n tOn h(p thu '(" )au tOn h(p thu R+t mgn r_n 4anh l

"Q& UyGH0HB v`n h(p thu '(" )au tOn h(p 3 8=n )ol r_n ln '(" phQn tn

tron n'9", un n7n t9i 0 o[FiZ rPa "" "h-t 8' )au tOn h(p, )au 7 l#" l&

tQm thu )En ph~mB

Vu& trSnh t"h l#" )En ph~m n iEn, "7 khE nn m3 r+n )En 4u-t trn 6u&

m* l9n 9i hiu )u-t )En ph~m "ao T{FXB [ho th-& ph'n n tOn h(p '(" "hn

t*i l!a "h#n iEi 6u&1t '(" I -n L h=n "h1 tron 6u& trSnh tOn h(p viu )u-t

th-p, kA"h th'9" tinh th l9n, t"h l#" )En ph~m ph:" t=pBKron h'9n nhin ":u ti1p theo "hn t*i L 4u-t ph'n n tOn h(p tinh th

nano UyGH0H tron m*i tr'Zn kiLm Rn ph'n php "hi1u 4= i )7n nhm tDi

'u h7a iLu kin k1t tinhB h'n n n%& h:a hNn :n 8Mn )En 4u-t $t liu UyG

H0H nano trn 6u& m* l9nB

,0!0,00 T3ng hLp v5t 6i( M


33/83

fun 8g"h [rT?IXIBv2,[K]W

hu-& tr+n Hh thuh`n h(p ]

Kh& nhit 220o[, hthu h`n h(p W

#" tr%o n'(" Rn n'9""-t thu )ol lnGr_n [

#" l& tQm thu R+tmgn f

\-& H00o[, Ih



fun 8g"hv2Wf[, vq


$/nh ,00 S1 t3ng hLp v5t 6i( M


34/83

fun 8g"h ]l[lIB/v2


fun nhit HI0 o[, 2 hthu h`n h(p W

#" ht"hQn kh*n,

thu R+t mgn [

Pa Rn]"etone

fun nhit 9i Uethanol n7nH00 o[, 2Fh

#" ht "hQn kh*n,)-& 0 o[, FhNB-(MIL(1@1KA"

fun 8g"h ]minoGv2Wf[fUq


,0!0,0.0 T3ng hLp v5t 6i( chmc nng h%a a;in N$,-MW"-!Q!]l6`?

M


35/83

fun 8g"h ]l[lIB/v2


fun nhit HI0 o[, 2 hthu h`n h(p W

#" ht"hQn kh*n,

thu R+t mgn [

HBPa Rn ]"etone F02B Pa Rn a"eton ,

fun nhit 9i Uethanol n7nH00 o[, 2Fh

#" ht "hQn kh*n,)-& 0 o[, FhNB-(MIL(1@1KA"

fun 8g"h[K]W ]minoG

v2Wf[fUq


$/nh ,0+0 S1 t3ng hLp v5t 6i( M


36/83


-.-. C0c /hng /h0/ EXc tng v!t "iu,0,0!0 9h1ng php ph3 hp thG hng ngi ]Wb`

Ng(Un t7c

h'n php phO y 8!a trn )! t'n t" "a "" tia in t miLn hcn no=i

TF00 G F000 "mGH

X 9i "" phQn tP "n nhin ":uB Vu trSnh t'n t" 7 "7 th 8;n1n )! h-p thM nn l'(n, "7 lin 6uan "hYt "h 1n "-u tr" "a "" phQn tP, 8o 7

phO y '(" 8n nhin ":u "-u tr" "" "h-tB

Thc nghi;

hO y "a "" m;u $t liu tOn h(p tron c n n%& '(" 4" gnh theo k

thu$t bp in 9i Wr theo t l Hm m;u H00m Wr trn m& ympa"t GFH0 T:"X,

>in vo v#" >in hoa h#" % "*n nh >it ?am, tron n F00 F000 "mGH

3 nhit + phjnB

,0,0,0 9h1ng php nhi[( 8 b1ngh


37/83


bt hai mYt phn )on )on y % yy "7 khoEn ""h 8B [hi1u "hm tia onhen

t=o 9i mYt phn trn m+t 7" B "" tia phEn 4= "7 th iao thoa thS hiu 6uan

trSnh hai tia HH % 22 phEi Rn )D nu&n ln R'9" )7n ]W ][ nB

UYt kh", "" nu&n tP, ion n%& '(" phQn RD trn "" mYt )on )on, 8o 7

hiu 6uan trSnh "a hai tia phEn 4= R-t k< trn hai mYt phn )on )on "=nh nhau

'(" tAnh nh' )au

2B8B)in T2B2XKron 7 G 8 l% khoEn ""h i.a hai mYt )on )onB

G l% 7" i.a "hm tia % mYt phn phEn 4=BG l% hiu 6uan trSnh "a hai tia phEn 4=B

Kheo iLu kin iao thoa, "" )7n phEn 4= trn hai mYt phn "n pha thS

hiu 6uan trSnh phEi Rn nu&n ln + 8%i )7n TXB

[ho nn 2B8B)in nB T2BIXQ& l% h th:" >ulGWra, l% ph'n trSnh " REn nhin ":u "-u tr" m=n

tinh thB [n ": %o "!" =i nhiu 4= trn iEn c Ti trg 2X, "7 th )u& ra 8 theo h

th:" T2BIXB \o )nh i trg 8 tSm '(" 9i 8 "hu~n ) 4" gnh '(" th%nh phn "-u

tr" m=n tinh th "a "h-t "n nhin ":uB [hAnh S $&, ph'n php n%& '(" )P

8Mn r+n ri tron nhin ":u "-u tr" tinh th "a $t "h-tB

Thc nghi;

[" iEn c nhiu 4= tia "a ""m;u nhin ":u '(" hi t=i hoa

v7aG Kr'Zn =i v#" hoa v#" K!

?hinG =i v#" VuD" ia v% ?+i trn

m& f{G ]8an"eG WrukerG erman&B

.n 10A"hMp Enh m& nhiu 4=

tia t=i hoa v7a h#" Kr'Zn =i

v#" hoa v#" K! ?hinG =i v#"

VuD" ia v% ?+iB

$/nh ,0K: MU nhi[( 8 tia q0

Sinh vin: Ng Mnh Tng K "#p: "c - $%a &'() *+,


38/83


,0,00 9h1ng php ng nhit hp phG - Hh\ hp phG Nit1 ]e_T`

E1 Ds 6f th(UFt

vin t'(n h-p phM trn RL mYt "h-t r_n \! tn ncn + "h-t khA ThoY" "h-t

tanX trn RL mYt phQn ""h i.a "" pha TkhA G r_n, ln G r_nX '(" "oi l% hin t'(n

h-p phMB hi l!" t'n t" i.a "" phQn tP l% l!" >an 8er all) thS )! h-p phM '("#i l% )! h-p phM $t l|B Kron tr'Zn h(p n%&, nn l'(n t'n t" oi.a "" "h-t

r_n T"h-t h-p phMX % phQn tP Rg h-p phM T"h-t Rg h-p phMX "hw "ao hn m+t At )o 9i

nn l'(n ho ln o"a "h-t khA 7B

'(n khA Rg h-p phM > '(" Riu 8in 8'9i 8=n th tA"h l% =i l'(n Y"

tr'n "ho )D phQn tP Rg h-p phM, n7 phM thu+" %o p )u-t "Qn Rn , nhit +, REn

"h-t "a khA % REn "h-t "a $t liu r_nB > l% m+t h%m cn Ri1n 9i p )u-t "Qn

RnB hi p )u-t tn 1n p )u-t hi Ro ho% "a "h-t khA Rg h-p phM t=i m+t nhit

+ "ho thS mDi 6uan h i.a > % '(" #i l% n nhit h-p phMB \au khi

=t 1n p )u-t hi Ro ho% o, n'Zi ta o "" i trg th tA"h khA h-p phM 3 "" p

)u-t t'n Di ToX iEm 8n % nh$n '(" 'Zn n nhit h-p phMB Kron

th!" t1 Di 9i $t liu UVKW 'Zn n nhit h-p phM khP h-p phM kh*n

trn nhau, '(" #i l% hin t'(n trB .n 10BRiu 8in "" 8=n 'Zn n

nhit h-p phMGkhP h-p phM theo phQn lo=i y][B

$/nh ,00 Ec 2ng ng ng nhit hp phG-giYi hp th


39/83


,0,0.0 $iPn vi in t\ 4(ut ]Scanning _6$t liu G >in hoa h#" % [*n nh

>it ?am % >in > \inh fg"h K KB

>c ngi,m"nh hin i in tP 6ubt \U

"a "" m;u $t liu '(" hi trn m& \UG

5I00 > "a hn eol T?h$t WEnX t=i >in

hoa v#" >$t iuG >in hoa v#" % [*n

?h >it ?am % m& ?yv \GF{00 t=i in

> \inh fg"h K Krun nB

$/nh ,00 MU hiPn vi in t\ 4(ut SM-+QQ

,0,0+0 9h1ng php ph3 hp thG t\ ngi vA HhY HiFn ]6tra i6


40/83


Kron phO >G>y\, R'9" )7n th'Zn '(" Riu 8in Rn n g + 8%i

nanomet TnmXB

hi R:" 4= t'n t" 9i $t "h-t, "" 6u trSnh 4~& ra Rao cm phEn 4=, tn 4=,

h-p thM, hu G >i) "7

nn l'(n Q& ra )! "hu&n 8g"h i.a "" m:" nn l'(n in tP kh" nhauB W'9"

)7n "a nh )n h-p thM l% R'9" )7n "7 nn l'(n ji hi t=o ra R'9"

nhE& "a m+t in tP t m:" nn l'(n th-p 1n m:" nn l'(n "ao hnB ["R'9" nhE& n%& t=o ra 8Ei h-p thM t=i "" R'9" )7n Y" tr'n 3 "" m:" nn l'(n

"a "" 8=n h-p thM d5B

Thc nghi;

Kron c n n%& "hn t*i th!" hin i" o phO h-p thM ele"tron >G>i) trn

m& W[ yn)trumentG2{{5 tron n t 200G00 nm t=i hjn v7a | WL UYt

>in v7a v#" >in hoa v#" % [*n ?h >it ?amB

,0,0J0 9h1ng php phVn tIch nhit ]Twl-&Tl`

hQn tA"h nhit l% nh7m "" ph'n php nhin ":u tAnh "h-t "a m;u o khi

t" +n nhit + ln m;u theo m+t "h'n trSnh ia nhit 9i m+t tD" + n%o 7 khi

m;u '(" Yt tron m*i tr'Zn nh-t gnhB hbp phQn tA"h nhit i )ai Rao cm nhiLu

ph'n php kh" nhauB Q& "hn t*i "hw )P 8Mn 2 ph'n php cm

h'n php fK] Tfierential Khermal ]nal&)i)X nhin ":u "" 6u trSnh

4E& ra Di 9i $t liu m% nh.n 6u trSnh 7 km theo hiu :n nhit Tthu hoY" ta

nhitX khi tn nhit + theo "h'n trSnh Tth'Zn l% tn tu&1n tAnhXB [" 6u trSnh

th'Zn Yp l% "hu&n pha, L h&8rat, khP h-p phM, h7a hi Tthu nhitXx tinh th h7a,o4i h7a, h-p phM, "h& Tta nhitXB Kron fK] n'Zi ta th'Zn 8n k thu$t )o )nhB

hbp o th!" hin cn thZi trn m;u khEo )t % m;u )o )nhB Kh*n tin nh$n '("

l% k1t 6uE )o )nh tAn hiu nh$n '(" t hai m;u trnB [" th*n )D "hAnh thu '(" t

iEn c fK] nhit + R_t u % k1t th" hiu :n nhitx nhit + :n 9i "!" trg

"a hiu :n nhit Twnh pi"XB

Sinh vin: Ng Mnh Tng .Q "#p: "c - $%a &'() *+,


41/83


h'n php K] TKhermoraimetri" ]nal&)i)X khEo )t )! tha& Oi tr#n

l'(n "a m;u khi th!" hin "h'n trSnh nhit +B [@n "7 th hiu n_n #n, K]

l% phbp "Qn m;u lin tM" khi nhit + tha& OiB

8 nh$n Ri1t m+t )D Y" tr'n "a iEn c K], n'Zi ta th'Zn nh$n iEn

c 8'9i 8=n i )ai TfK, fierential Khermal raimetr&X, Riu 8in tD" + tha&Oi khDi l'(n m;u theo thZi ianB iLu n%& thu$n l(i khi "n phQn tA"h "" 6u trSnh

cm nhiLu 6u trSnh "on "hcn "h$p ln nhauB [" th*n )D "hAnh thu '(" t iEn

c K] % fK nhit + R_t u, i.a % k1t th" "a 6u trSnh tha& Oi khDi

l'(n m;uB

Kron c n n%&, "hn t*i th!" hin "" phbp o K]GfK] trn m& fKG/0v

9i tD" + tn nhit + l% H0 +pht % khoEn nhit + o l% 0 o[ GH000o[ t=i

Kr'Zn =i h#" \' h=m v% ?+iB

,0,0K0 9h1ng php ph3 tn D7cnng 6Lngtia q

hO tn )_"nn l'(ntia , ha& hO tn )_" nn l'(n l% k thu$t phQn tA"h

th%nh phn h7a h#" "a $t r_n 8!a %o i" hi l=i phO tia pht ra t $t r_n 8o

t'n t" 9i ""R:" 4=Tm% "h &1u l% "hm in tP"7 nn l'(n "ao tron

""kAnh hin i in tPXB Kron "" t%i liu khoa h#", k thu$t n%& th'Zn '(" i1t

t_t l% f ha& f\ T ner&G8i)per)ie Gra& )pe"tro)"op&XB

Kia pht ra t $t r_n T8o t'n t" 9i "hm in tPX ) "7 nn l'(n Ri1n

thin tron 8Ei r+n, ) '(" 'a 1n h tn )_" % hi nh$n Tnn l'(nX nhZ

8ete"tor 8g"h "hu&n Tth'Zn l% \i, e, iBBBX '(" l%m l=nh Rn nit ln, l% m+t

"on "hip nh t=o ra in tP th: "-p 8o t'n t" 9i tia , rci '(" li %o

m+t anDtnhB ['Zn + tia tw l 9i tw phn nu&n tD "7 mYt tron m;uB + phQn

iEi "a phbp phQn tA"h phM thu+" %o kA"h " "hm in tP % + nh=& "a 8ete"tor

Tn ho=t +n tA"h "!" "a 8ete"torXB

+ "hAnh 4" "a f 3 "-p + m+t %i phn trm Tth*n th'Zn hi nh$n '("

)! "7 mYt "a "" nu&n tD "7 tw phn " IG5 tr3 lnXB Ku& nhin, f t ra kh*n

hiu 6uE 9i "" nu&n tD nhN TA 8M W, [BBBX % th'Zn 4u-t hin hiu :n trcn

"h$p "" wnh tia "a "" nu&n tD kh" nhau Tm+t nu&n tD th'Zn pht ra

nhiLu wnh Y" tr'n }, BBB, % "" wnh "a "" nu&n tD kh" nhau "7 th "hcn

"h$p ln nhau Q& kh7 khn "ho phQn tA"hXB

Sinh vin: Ng Mnh Tng .! "#p: "c - $%a &'() *+,
http://vi.wikipedia.org/w/index.php?title=T%C3%A1n_s%E1%BA%AFc&action=edit&redlink=1http://vi.wikipedia.org/wiki/N%C4%83ng_l%C6%B0%E1%BB%A3nghttp://vi.wikipedia.org/wiki/N%C4%83ng_l%C6%B0%E1%BB%A3nghttp://vi.wikipedia.org/wiki/Tia_Xhttp://vi.wikipedia.org/w/index.php?title=T%C3%A1n_s%E1%BA%AFc&action=edit&redlink=1http://vi.wikipedia.org/wiki/N%C4%83ng_l%C6%B0%E1%BB%A3nghttp://vi.wikipedia.org/wiki/Tia_Xhttp://vi.wikipedia.org/wiki/Tia_Xhttp://vi.wikipedia.org/wiki/Tia_Xhttp://vi.wikipedia.org/wiki/Tia_Xhttp://vi.wikipedia.org/wiki/B%E1%BB%A9c_x%E1%BA%A1http://vi.wikipedia.org/wiki/B%E1%BB%A9c_x%E1%BA%A1http://vi.wikipedia.org/wiki/B%E1%BB%A9c_x%E1%BA%A1http://vi.wikipedia.org/wiki/%C4%90i%E1%BB%87n_t%E1%BB%ADhttp://vi.wikipedia.org/wiki/K%C3%ADnh_hi%E1%BB%83n_vi_%C4%91i%E1%BB%87n_t%E1%BB%ADhttp://vi.wikipedia.org/wiki/K%C3%ADnh_hi%E1%BB%83n_vi_%C4%91i%E1%BB%87n_t%E1%BB%ADhttp://vi.wikipedia.org/wiki/Sihttp://vi.wikipedia.org/w/index.php?title=Ge&action=edit&redlink=1http://vi.wikipedia.org/wiki/Lihttp://vi.wikipedia.org/wiki/Nit%C6%A1_l%E1%BB%8Fnghttp://vi.wikipedia.org/w/index.php?title=An%E1%BB%91t&action=edit&redlink=1http://vi.wikipedia.org/wiki/Tia_Xhttp://vi.wikipedia.org/wiki/Bhttp://vi.wikipedia.org/wiki/Chttp://vi.wikipedia.org/wiki/Chttp://vi.wikipedia.org/wiki/N%C4%83ng_l%C6%B0%E1%BB%A3nghttp://vi.wikipedia.org/wiki/Tia_Xhttp://vi.wikipedia.org/w/index.php?title=T%C3%A1n_s%E1%BA%AFc&action=edit&redlink=1http://vi.wikipedia.org/wiki/N%C4%83ng_l%C6%B0%E1%BB%A3nghttp://vi.wikipedia.org/wiki/Tia_Xhttp://vi.wikipedia.org/wiki/Tia_Xhttp://vi.wikipedia.org/wiki/B%E1%BB%A9c_x%E1%BA%A1http://vi.wikipedia.org/wiki/%C4%90i%E1%BB%87n_t%E1%BB%ADhttp://vi.wikipedia.org/wiki/K%C3%ADnh_hi%E1%BB%83n_vi_%C4%91i%E1%BB%87n_t%E1%BB%ADhttp://vi.wikipedia.org/wiki/Sihttp://vi.wikipedia.org/w/index.php?title=Ge&action=edit&redlink=1http://vi.wikipedia.org/wiki/Lihttp://vi.wikipedia.org/wiki/Nit%C6%A1_l%E1%BB%8Fnghttp://vi.wikipedia.org/w/index.php?title=An%E1%BB%91t&action=edit&redlink=1http://vi.wikipedia.org/wiki/Tia_Xhttp://vi.wikipedia.org/wiki/Bhttp://vi.wikipedia.org/wiki/Chttp://vi.wikipedia.org/w/index.php?title=T%C3%A1n_s%E1%BA%AFc&action=edit&redlink=1


42/83


>c ngi,m Kron c n n%& "hn t*i th!" hin i" o phO tn 4= nn

l'(n tia TfX t=i >in hoa v#" >$t iuG >in hoa v#" % [*n ?h >it

?amB

-.. _hH& 80t h&'t t`nh hF/ /h4 chFt nhua% %Dthb"DnD "uD t\n c0c v!t"iu MIL(1@1d MD8& MIL(1@1d NB-(MIL(1@1KA"

M


43/83


$/nh ,0!!0 d(ang ph3 hp thG ;A( ca 2(ng 2ch Me

U%u 4anh Y" tr'n "a UW '(" )P 8un l%m "h-t "hw thg o4i h7a khP tron

h7a h#" phQn tA"hB fun 8g"h "a UW "7 m%u 4anh khi m*i tr'Zn o4i h7a, nh'n )

"hu&n )an kh*n m%u n1u ti1p 4" 9i "h-t khPB

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"a nhit +, ncn + hoY" p )u-t 6 TK,[X hoY" 6 TK, X, khi "D gnh nhit +

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nh.n tr'Zn h(p kh" nhau Tn l9p, a l9p, h-p phM $t l|, h7a h#", h-p phM trnRL mYt phQn ""h pha r_nGln, lnGkhA^X, nh'n Di 9i h-p phM trn RL mYt phQn

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ph'n trSnh h-p phM n nhit qreun8li"h % ph'n trSnh e8li"h eter)on,

ph'n trSnh iE R$" 2 T8seudo-second-orderX th hin tron REn 2BI dHIHB

WEn 2BI [" ph'n trSnh n nhit h-p phM

h'n php h'n trSnh n nhit h-p phM

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44/83


e8li"h eter)ong

e

ee

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nhu+m, "hn t*i ti1n h%nh khEo )t ho=t tAnh h-p phM "h-t nhu+m meth&lene Rlue

trn "" $t liu phQn "-p Ue)o Uq "h:n minh 'u th1 "a $t liu phQn "-p

mao 6uEn )o 9i "" $t liu i mao 6uEnB

,00!0 ThI nghi; HhY Dt ht tInh hp phG cht nh(O; Me

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TH00mlXB fun 8g"h '(" khu-& t 9i tD" + 500 TjnphtX t l" R_t u "ho R+t

$t liu %o 8un 8g"h UWB \au m`i khoEn thZi ian nh-t gnh TI0 phtX 8n

4&lanh trA"h l-& 5 ml 8un 8g"h em l& tQm thu l-& 8un 8g"h khEo )tB KhA nhim

'(" ti1n h%nh tron thZi ian 2H0 pht 9i ln trA"h m;uB [" m;u 8un 8g"h trA"h

ra TkhoEn 5 mlX )au khi l#" l& tQm '(" phQn tA"h ncn + Rn m& >Gi) pha

ln tron i9i h=n R'9" )7n t 200 00 nmB

KhP nhim '(" "hn t*i ti1n h%nh trn "" $t liu UyGH0H tOn h(p tron

m*i tr'Zn a4it, Ue)o UyGH0H, ?v2GUyGH0HT]lX % Ue)o ?v2GUyGH0HT]lXB

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2XT tet EEk

dt

dE=

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Sinh vin: Ng Mnh Tng .. "#p: "c - $%a &'() *+,


45/83


Kron 7 k l% h )D h-p phM TmBphtXx 6e l% l'(n "h-t Rg h-p phM khi "Qn

Rn TmXx 6t l% l'(n "h-t Rg h-p phM )au thZi ian t TmXB

'(n "h-t Rg h-p phM )au thZi ian t l%

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EtkE

tE

+

=

T2BHX

c thg khEo )t '(" th hin 8'9i 8=n

tEkEE

t

eet

BHH

2 +=

T2BH{X

'(n "h-t Rg h-p phM khi =t tr=n thi "Qn Rn h-p phMG iEi h-p '(" khEo

)t t ncn + 8un 8g"h meth&lenen Rlue T[eX )au phQn tA"h >Gi)

oee CCm

GE +=

T2BHX

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ti1p 4" TXx [e ncn + 8un 8g"h UW tron 8un 8i"h "Qn Rn TmlXx [o ncn

+ 8un 8g"h UW tron 8un 8g"h khEo )t Ran u TmlXB

Chng III

_fT QU ? TB6 LUN

.1. Rhjn t`ch EXc tng v!t "iu MIL


46/83


$/nh 0!0 9h3 Wb ;x( MW"-!Q! t3ng hLp trng ;i trng a8itK phO y m;u UyGH0H "hn t*i nh$n gnh nh' )au

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k1t [rGB

Sinh vin: Ng Mnh Tng .J "#p: "c - $%a &'() *+,


47/83


- fEi h-p thM 3 tn )D 50 "m GH % H02H "mGH Y" tr'n "ho 8ao +n "a jn

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nh7m pi" Y" tr'n "a $t liu Uy H0HB 7 l% "" pi" nhiu 4= t=i "" 7" H, ox

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th pha r_n "ao, Y" Rit l% "" pi" nhiu 4= "ao 3 "" 7" H, % 2,{ o"ho th-& $t

liu "7 phQn RD mao 6uEn kA"h th'9" trun RSnhB

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48/83


'Zn n nhit h-p phM % iEi h-p phM ?2"a UyGH0H "7 4u-t hin jn tr

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thi % 4" gnh kA"h th'9" tinh th UyGH0H, "hn t*i ti1n h%nh "hMp Enh \U RL



49/83


mYt $t liu, k1t 6uE th hin 3 .n 50? "ho th-& $t liu UyGH0H tOn h(p '(" "7

hai nh7m tinh th 0,5 H m % H HB5 mB ?h' $&, $t liu '(" tOn h(p Rn

ph'n php th& nhit r-t kh7 khn tron i" iLu khin kA"h th'9" tinh thB

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50/83


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h%nh nhin ":u tOn h(p $t liu UyGH0H tron m*i tr'Zn Raz nhm tOn h(p

tinh th nano % nQn "ao hiu )u-t )En ph~m T {0, Ri1n tAnh $t liu UyGH0H tr3

th%nh $t liu h-p phM % 4" t" Rn ""h "h:" nn h7a amin T?v 2X, tha& th1 nt

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51/83


$/nh 00 9h3 Wb ;x( MW"-!Q! t3ng hLp trng ;i trng Xa@1

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52/83


- fEi h-p thM 3 tn )D 50 "m GH % H0H{ "mGH Y" tr'n "ho 8ao +n "a jnRenzenB

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tr'n tron phQn tP "a UyGH0HB

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hin "" nh7m pi" Y" tr'n "a $t liu UyGH0H t=i "" 7" nhiu 4= H, ox 2,{o,

F,ox o"ho th-& pha r_n tinh th UyGH0H hSnh th%nh tron m*i tr'Zn RazB

Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Mau M!"!-#

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th hin 3 "'Zn + "" nh7m pi" Y" tr'n th-pB ?u&n nhQn l% 8o hSnh th%nh tinh

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53/83


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UyGH0H tron m*i tr'Zn kiLm 8un 8g"h ?av d{/B

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hQn tA"h 8. liu phO WK "a UyGH0H tinh th nano '(" trSnh R%& trn.n

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6uEn trun RSnhB

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liu "7 "-u tr" mao 6uEn a "-p 9i kA"h th'9" mao 6uEn trun RSnh 8 tR nm,

phQn "-p 'Zn kAnh mao 6uEn 8H I,2 nmx 82 /, nmx 8I HF nmB Kron 7 phQn

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RL mYt rin "ao, =t H{F2 m2B

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54/83


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"ao T{FX th%nh "*nB

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Sinh vin: Ng Mnh Tng +. "#p: "c - $%a &'() *+,


55/83


$/nh 0!0 9h3 tn 8 _&q ;x( MW"-!Q! nan t3ng hLp trng ;i trng Xa@1

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