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Unit 9 Metallic Bonding Table of Contents Table of Contents 1 Essential Questions 3 Review 3 Lesson 9.1: Metallic Compounds 5 Objective 5 Warm-Up 5 Learn about It 6 Key Points 9 Web Links 10 Check Your Understanding 10 Challenge Yourself 12 Lesson 9.2: Properties of Metallic Compounds 13 Objectives 13 Warm-Up 13 Learn about It 14 Key Points 19 Web Links 19 Check Your Understanding 20 Challenge Yourself 21 Laboratory Activity 22 Performance Task 24 Self Check 26 Key Words 26 Wrap Up 28 References 28
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Unit 9 Metallic Bonding

Mar 27, 2022

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Review 3 
Lesson 9.1: Metallic Compounds 5  Objective 5  Warm-Up 5  Learn about It 6  Key Points 9  Web Links 10  Check Your Understanding 10  Challenge Yourself 12 
Lesson 9.2: Properties of Metallic Compounds 13  Objectives 13  Warm-Up 13  Learn about It 14  Key Points 19  Web Links 19  Check Your Understanding 20  Challenge Yourself 21 
Laboratory Activity 22 
Performance Task 24 
Self Check 26 
Key Words 26 
Wrap Up 28 
Unit 9  Metallic Bonding 
 
 
 
 
conductors of electricity and heat. Furthermore, their ability to be drawn into thin                          wires and to be hammered into thin sheets show that the bonds between two                            metallic atoms are strong yet flexible. Alloys used in airplane turbines and                        conductors in electrical cells are just few examples of fantastic materials we can                          derive from metals.    But why are metals capable of these things? Why can copper, for example, exhibit                            ductility and be drawn into thin wires? In this unit, you will learn about how metals                                are structured, and how do their structures explain their wonderful properties. This                        unit describes the another type of chemical bonding known as metallic bonding                        which is present between metals. Ultimately, this chapter will help you distinguish                        different types of compounds based on some properties that differentiate metallic,                      ionic and covalent compounds.    
  Essential Questions 
  At the end of this unit, you should be able to answer the following questions.   
 
  Review   
An element is composed of only one kind of atom. It can be classified as                              metals, nonmetals, and metalloids. Compounds are substances made up of                    at least two or more elements chemically combined. 
Valence electrons are the most important electrons of an element, mainly                      because they are directly involved in bonding. These are electrons found at                        the outermost shell of an atom which are lost, gained or shared to satisfy                            octet.  
 
 
 
 
o A cation is a positively-charged atom, as a result of losing at least one                            electron in its valence shell. 
o Anion – negatively-charged atom, as a result of gaining at least one                        electron in its valence shell. 
Covalent compounds are compounds that form as a result of covalent                      bonding, wherein two atoms share their valence electrons. 
 
describe the electron sea model of metals.   
Metals can be distinguished from nonmetals based on their properties. Metals are                        electrically and thermally conductive, and they are also malleable, ductile and                      lustrous, unlike nonmetals. These properties can be explained by the structure of                        metallic compounds. Metallic compounds, or simply metals, are held together by                      metallic bonds. How are metals bonded together?    
  Warm-Up    Metallic Bonding  Metallic bonding exists between two metals. Let us consider the case where the                          metals are identical. Let us look at an aluminum atom. Fill up the table below.   
Chemical element  Aluminum 
Valence electron configuration   
 
 
 
       
Lewis electron-dot formula       
  1. Based on your answers for the table above, what is the easiest way                         
aluminum could attain an octet?  ________________________________________________________________________________  ________________________________________________________________________________ 
       
3. Based from your answer on number 2, is it possible for two aluminum atoms  to form a covalent compound? Why or why not?  ________________________________________________________________________________  ________________________________________________________________________________ 
 
  Learn about It 
 
 
 
 
hand, sharing electrons is also not an option. Even if they share all electrons from                              both metals, they will still lack some electrons to complete the octet. Representative                          metals are known to obey octet rule, and this inconsistency suggests that covalent                          bonding is not also suitable to explain the interaction between them. This opens up                            the idea that most likely, a third type of bonding is involved.     The Electron Sea Model  The atoms in a metal, when they bond together, form a metallic bond. In a metallic                                bond, the valence shells of a component atom overlaps with another one, much like                            in a covalent bond. However, unlike a covalent compound which only involves a few                            atoms to form a bond, multiple metal atoms surround each other in order to share                              their valence electrons simultaneously. This happens when a metal atom starts                      freeing valence electron to move around and create a domino effect to its                          neighboring electrons. Although the metal which loses the electron becomes                    incompletely filled, the vacated spot will be completely filled by another moving                        electron. In this scenario, electrons are said to be delocalized, or free to move from                              one atom to another. This results to a picture of bonding, wherein metallic cations,                            are fixed and embedded in a lattice surrounded by a sea of valence electrons. This                              is depicted in the following illustration.   
Fig. 1. Metallic bonding. Metal cations embedded in a sea of valence electrons.  
  Metallic bonding is not limited to one type of metal. Alloys, or solid homogeneous                            mixtures of metals, are formed by mixing two different metals together. Alloys                        modify properties of the original metal, enhancing strength, conductivity, or any                      other way depending on the application.   
Copyright © 2018 Quipper Limited  6 
 
 
 
  Substitutional alloys, are alloys in which the atoms of one element substitute for                          the atoms of the other element in the alloy. This occurs when two metals of roughly                                the same atomic size are mixed together. Examples of this alloy are brass                          (combination of copper and zinc) and bronze (combination of copper and                      aluminum). 
  Fig 2. Substitutional alloy. 
  Interstitial alloys, on the other hand, are alloys in which the atoms of one element                              is placed in between the spaces of the atoms of the other element. This occurs                              when one metal’s atoms are smaller than the atoms of the other metal. An example                              of interstitial alloys is steel, which is a combination of iron and carbon.    
Fig 3. Interstitial alloy. 
  Examples of alloys and their uses are listed below.   
Table 9.1. Various types and uses of alloys.  Alloy  Combination of metal  Uses 
Bronze  Copper and aluminum  Used in sculptures,  musical instruments, and 
medals 
 
 
 
 
automobiles and  appliances 
Brass  Copper and zinc  Used in plumbing,  musical instruments, and 
home furnitures 
Amalgam  Mercury and silver  Used in electrolytic cells,  extraction of gold, and  dentistry (cavity filler) 
Pewter  Tin and antimony  Used in decoration,  jewelry, and tableware 
Solder  Tin and lead  Used in connecting  electronic parts and 
plumbing 
   
 
 
 
Metallic bonding is formed when metal atoms free their valence electrons,                      producing a sea of electrons which they can all share. 
Alloys are solid homogeneous mixtures of metals formed by mixing two                      different metals together. 
Substitutional alloys are alloys in which the atoms of one element                      substitute for the atoms of the other element in the alloy.  
 
 
 
 
 
  Check Your Understanding 
  A. Write true if the statement is true. Otherwise, write false. 
 
 
 
 
4. Metallic bonding between atoms occur because of valence shell overlap                    between multiple atoms. 
5. Metallic bonding allows inner core electrons, as well as valence electrons, to                        freely move about. 
  B. Assess whether the following sentences describe a substitutional or an                   
interstitial alloy. Write S if the sentence describes a substitutional alloy. Write I                          if the sentence describes an interstitial alloy. Write A if the sentence describes                          both alloy type. Write N if it doesn’t describe an alloy. 
1. A piece of solid is made up of positively-charged copper and negatively-  charged chlorine. 
2. Alloys modify properties of the original metal, enhancing both strength and                      conductivity, 
3. Brass is an example of this alloy.  4. This type of alloy is made up of atoms with relatively similar sizes.  5. These are solid, homogeneous mixtures of metals.  6. The positively-charged ion is surrounded by negatively-charged ions in                 
almost all directions.  7. The electrons are collectively shared between iron and carbon.  8. Multiple bonds are formed to satisfy the octet between two rhenium atoms.  9. The protons are moving from one position to another in this type of alloy.  10.Electrons are delocalized between two metal atoms. 
  C. For the next few questions, refer to the figure below. Answer the next few                           
questions.   
 
 
 
   
 
  Answer the following questions comprehensively. 
1. Steel is a compound of iron and carbon. Why do you think steel is considered                              an alloy, as opposed to an ionic or covalent compound? 
2. Graphene, a 2D sheet of carbon atoms bonded together in a lattice, is                          electrically conductive, harder than steel, and has a very high melting point.                        Despite carbon being a nonmetal, why do you think Graphene possesses                      these properties? 
  For the following combination of metals, identify what type of alloy will be formed.                            You can look and compare the sizes of the ions that can form from each metals to                                  identify the type of alloy. 
3. Cu and Al  4. Hg and Ag 
 
 
 
 
 
 
   
 
  Objectives  In this lesson, you should be able to: 
explain the properties of metals in terms of the electron sea  model; and 
 
 
 
Making a Sea of Electron    Materials: 
5 pieces each of red and blue balls, of different sizes  5 ft. wires   glue or adhesives 
 
 
 
 
  Learn about It 
  Conductivity  Conductivity is the ability of a material to allow heat or electric current to easily                              pass through. Electricity, on the other hand, is the flow of electric charge brought                            by the movement of electrons. Whenever electricity or heat passes through metals,                        it can freely flow without much obstruction from the positive nuclei of atoms.                          Hence, metals and alloys are electrically and thermally conductive.   
  Fig 4. Cooking pans are made up of metals which can transfer heat. 
 
 
 
 
transfer of electricity. Electrons also carry energy while travelling which allows the                        transfer of heat.    Density and Tensile Strength  Metals are very dense, as shown in the table below. They also have high tensile                              strength, hence they are used as construction materials. Their high densities and                        high tensile strength suggest that metallic bond is very strong. This allows the                          atoms inside metals to pack tightly, producing rigid structures.   
Table 9.2 Densities of some metals. The density of water is 1 g/cm3. 
Metal  Density (g/cm3) 
 
 
 
  Fig 6. High tension wires which hold the tension bridges are usually made up of 
 
 
 
 
 
 
 
 
 
 
 
Luster 
 
 
 
 
 
 
   
  Key Points 
  Metals are good conductors of heat and electricity. The delocalized electrons                     
allows transfer of electricity, and heat is carried by the electrons as it travels                            from one place to another. 
Metals are very dense and have high tensile strength, indicative of the                        immense strength of metallic bonds. 
Metals have high melting and boiling points. Since metal cations are                      attracted to a sea of electrons, greater energy is needed to melt and boil                            metals. 
Metals and alloys are malleable and ductile. When atoms are under stress,                        the delocalized electrons allow for the metal atoms to simply slide over one                          another without breaking the metallic bond. 
 
 
 
 
 
 
 
 
  Check Your Understanding 
  A. Write true if the statement is true. Write false otherwise. 
1. Metals are ductile and malleable because cations can move about without                      breaking bonds. 
2. Metals have high boiling points.  3. Metals can conduct electricity because electrons can freely move about the                     
bulk of the metal.  4. Metals do not allow electric current to flow unimpeded.  5. Metals have low melting points 
  B. Identify if the following physical properties describe a metal or not. Write M if it                             
pertains to a property of metal, and N if not.  1. Electrical wires are used to transfer electricity from a source to your                       
household devices.  2. Coal transfers heat to the grilled liempo.  3. Pencil lead are good conductors of electricity.  4. Metallic particles float in water.  5. Metal sheets are found in heating materials and containers.  6. Aluminum foil is used to grill bangus.  7. Diamond conducts electricity and heat.  8. Oven uses gaseous metal to transfer heat and bake cakes.  9. Tin cans can be reshaped by hammering.  10.Liquid mercury conducts electricity even in liquid form. 
 
 
 
 
Answer the following questions comprehensively.  1. Differentiate a metallic bond from a covalent bond.  2. Which of the three bond types do you think is the strongest? Why?  3. Metals form metallic bonds, nonmetals form covalent bonds, and metals and                     
nonmetals form ionic bonds. How do you think metalloids form their bonds?  4. The conductivity of metals at very low temperatures increases to a point, that                         
it achieves a state called superconductivity. Based on what you know about                        metallic bonding, why is this so? 
     
 
 
 
 
 
Properties of Metals   
Objective  At the end of this laboratory activity, the students should be able to: 
observe properties of household metallic compounds.    Materials and Equipment 
stainless steel  copper wire  aluminum foil  iron nail  mossy zinc  tin can  charcoal  hammer  ziplock bags  water  beaker or container  watch glass 
  Procedure  Observation of Physical Properties 
1. Observe the color of stainless steel, copper wire, aluminum foil, iron nail,                        mossy zinc, tin can and charcoal. Record your observations on the table                        below. 
2. Similarly, observe if these solids exhibit luster. Record your observations on                      the table below. Put a check mark if the solid exhibits luster, and cross mark                              if the solid does not.  
 
 
 
 
 
Test for Hardness and Malleability  1. Take a small amount of steel, copper wire, aluminum foil, iron nail, mossy                         
zinc, tin can and charcoal on separate ziplock bags.  2. Close the ziplock bags. Using a hammer, carefully pound the solids inside the                         
ziplock bags. Observe what happens to the solids. Continue pounding until                      no more changes occur.  
3. Record your observations on the table below.    Test for Conductivity 
1. Take a small amount of steel, copper wire, aluminum foil, iron nail, mossy                          zinc and charcoal. Place it in separate watch glasses. 
2. Using an improvised electrical conductivity set-up, test the conductivity of                    each solid. Touch the solids using the loose ends of the set-up. Observe if the                              flashlight or bulb lights up. 
 
Waste Disposal  Dispose solids in a regular trash bin.  Dispose all solutions in sink with excessive amount of running water. 
  Data and Results (or Observation)  Record your observations on the table below.    
Table 1. Properties of household metals. 
Household  material 
Exhibit  luster? 
 
 
 
  Guide Questions 
1. Which solids sink on water? What property is this associated with?  2. Which solids exhibit luster? Explain why these solids shine with light.  3. What can you say about the hardness of each solids? Compare it with 
charcoal.  4. Which solids are malleable? Explain how can they be able to resist physical 
stress.  5. Which solids are able to light up the bulb? Explain why they can light up the 
bulb even at the solid state.   
  Performance Task 
 
Knowing the Bond Type  Your school launched a weeklong celebration called The Mystery Week. It’s an event                          that fosters skills development, critical thinking and creativity. The Chemistry                    department hosted the main activity of the week, a brain tickling puzzle about the                            identities of three different solids.    You are part of a group of young science enthusiasts. Your group take the                            challenge. The Chemistry department wanted to test your chemistry skills and                      asked you to identify what types of bonds are present in each solids.    Goal 
Your task is to design a method in identifying the type of chemical bond                            present in each solid . 
   
 
 
 
Role  You are part of a group of young science enthusiasts. 
  Audience 
Your audience is the Chemistry department.    Situation 
You have three different solids, labelled A, B and C. A is a thin silver sheet,                                while B and C are white powdery solids. 
Each solids just weigh exactly 1 gram.    Product/Performance and Purpose: 
You will conduct a series of experiment to be able to find out what types of                                bonds are present in each solid. 
You will explain your methods and how did you arrive to the conclusion on                            what type of bond each solid contains. 
  Standards and Criteria for Success 
Your work must meet the standards found in the rubric below.    Rubrics for Assessment 
Criteria  Below  Expectations  0% to 49% 
Needs  Improvement  50% to 74% 
Successful  Performance  75 to 99% 
Exemplary  Performance  100% 
Comprehensiveness  Methods does  not justify the  objectives   
Shows some  comprehensive-  ness, but most  methods are not  in line with the  objectives 
Comprehensive,  some methods  meet the  objectives but  are not planned  well   
Very  comprehensive,  method carefully  planned out and  techniques meet  the objectives 
Reliability  Methods  produced no  data   
Shows some  reliability, data  can be gathered  but cannot be  analyzed further 
Reliable, data  gathering and  analysis offers  reliable results  but sometimes  show  inconsistencies 
 
 
 
 
Shows some  originality,  inadequate used  of resources 
Original ideas,  adequate use of  resources 
Very original,  shows imaginative  use of resources 
   
After studying the unit, can you now do the following?   
Check  I can… 
   Recognize and explain properties of metals and alloys 
   Explain why copper can be drawn in thin wires 
 
Reflect 
 
Metallic compounds  These are compounds made up of metals. 
 
 
 
 
Delocalized electrons  These are electrons which are free to move from one  atom to another. 
Alloys  These are solid homogeneous mixtures of metals formed  by mixing two different metals together. 
Substitutional alloys  These are substituted alloys in which the atoms of one  element substitute for the atoms of the other element in  the alloy. 
Interstitial alloys  These are substituted alloys in which the atoms of one  element is placed in between the spaces of the atoms of  the other element.  
Sea of Electron Model  This describes metals as metal cations suspended in a  sea of mobile electrons. The electrons are collectively  shared to satisfy octet.  
Malleability  It is the ability of a material to be formed into sheets  without breaking apart 
   
 
 
 
 
 
  Clackamas Community College. “Metallic Bonding”. Accessed 3 Jul 2017.  http://dl.clackamas.edu/ch104-07/metallic.htm    Chang, Raymond and Kenneth A. Goldsby. 2016. Chemistry. New York, NY:  McGraw-Hill Education.    Silberberg, Martin. 2009. Chemistry: The Molecular Nature of Matter and Change,  5th edition.     Department of Education, Republic of the Philippines. EASE II Module 14: The  Chemical Bonds. 2014. Republic of the Philippines.