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ISOBUTYRALDEHYDE(1) - n-heptane(2)ISOTÉRMICO
45°C
Isobutyraldehyde(1) n-heptane(2)VP_A -7.53679 -7.67468VP_B 1.08548 1.37068VP_C -1.52929 -3.53616 T (K)=VP_D -8.48589 -2.70794 R=Pc 41.5 27.4Tc 513 540.3 Pvp1=x 0.379824561403509 0.4111604664 Pvp2=z= 10
Grupos funcionalesn-Heptane CH3(2) y CH2(5)
Isobutyraldehyde CH3(2) CH(1)
SUBGRUPO k Rk Qk vk1CH3 1 0.9011 0.848 2CH2 2 0.6744 0.54 5CH 3 0.4469 0.228 0CHO 4 0.998 0.948 0
PARAMETROS DE INTERACCION BINARIA ajkk
j (SUBGRUPO) CH3 (1) CH2 (1) CH (1) CHO (10)CH3 (1) 0 0 0 618.8CH2 (1) 0 0 0 618.8CH (1) 0 0 0 618.8CHO (10) 2261 2261 2261 0
x2 Φ1 Φ2 Ѳ10.001 0.999 0.0015925383 0.998407462 0.0015298290.05 0.95 0.0773780416 0.922621958 0.0745539650.1 0.9 0.1504210988 0.849578901 0.1453511440.15 0.85 0.2194835365 0.780516463 0.2126685160.2 0.8 0.2848821204 0.71511788 0.2767564850.25 0.75 0.3469008749 0.653099125 0.337841992
CH3(CH2)5CH3
(CH3)2CHCHO
x1
F29
Admin: CON LOS NUEVOS VALORES UNIFAC, QUE SE MUESTRAN EN LA TABALA ADJUNTA
E32
Admin: CON LOS NUEVOS VALORES UNIFAC, QUE SE MUESTRAN EN LA TABALA ADJUNTA
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0.3 0.7 0.4057952071 0.594204793 0.3961312030.35 0.65 0.461795422 0.538204578 0.4518118280.4 0.6 0.5151097328 0.484890267 0.5050551470.45 0.55 0.5659268477 0.434073152 0.5560177640.5 0.5 0.6144182015 0.385581799 0.6048431480.55 0.45 0.6607398877 0.339260112 0.6516629830.6 0.4 0.7050343374 0.294965663 0.6965983520.65 0.35 0.7474317818 0.252568218 0.7397607830.7 0.3 0.788051531 0.211948469 0.7812531740.75 0.25 0.8270030954 0.172996905 0.821170610.8 0.2 0.8643871717 0.135612828 0.8596010950.85 0.15 0.9002965118 0.099703488 0.8966261940.9 0.1 0.9348166914 0.065183309 0.9323216140.95 0.05 0.9680267909 0.031973209 0.966757720.999 0.001 0.9993722102 0.00062779 0.999346452
Datos ExperimentalesP, mmHg P,Bar x1 y1
114.33 0.1524521952 0 0149.37 0.1991759328 0.0348 0.255187.03 0.2493932832 0.0846 0.4292225.09 0.3001440096 0.1583 0.5523257.76 0.3437074944 0.242 0.6344285.02 0.3800570688 0.3312 0.6924303.06 0.4041123264 0.4073 0.7266310.53 0.4140731232 0.4373 0.7426315.63 0.4208736672 0.4669 0.7499328.98 0.4386750912 0.5319 0.7786336.25 0.4483692 0.5843 0.7938
345.1 0.460170144 0.6284 0.8116356.43 0.4752780192 0.7043 0.8404364.64 0.4862255616 0.7636 0.8626371.13 0.4948795872 0.8167 0.8842377.06 0.5027868864 0.8616 0.9074381.41 0.5085873504 0.902 0.9301386.36 0.5151878784 0.9562 0.9641388.68 0.5182814592 0.9833 0.9839389.97 0.5200015968 1 1
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ISOBUTYRALDEHYDE(1) - n-heptane(2) ALUMNO: SÁNCHEZ OCHOA JORGE LUISISOTÉRMICO
45°C
318.158.314
0.5185690940.153465581
Parámetros calculados
r1= 5.1742 L1=
CHO(1) r2= 3.2471 L2=q1= 4.396
vk2 q2= 2.87220 X11= 0.285714286 X12= 0.51 X21= 0.714285714 X22= 01 X31= 0 X32= 0.25
X41= 0 X42= 0.25
ᴪ11= 1 ᴪ12= 1ᴪ21= 1 ᴪ22= 1ᴪ31= 1 ᴪ32= 1ᴪ41= 0.000819586 ᴪ42= 0.000819586
lnᴦ11= 0 lnᴦ12= 0.245729981lnᴦ21= 0 lnᴦ22= 0.156478997lnᴦ31= 0 lnᴦ32= 0.06606891lnᴦ41= 2.791077818 lnᴦ42= 1.021678008
Ѳ2 lnϒC1 lnϒC2 X1 X2 X3 X40.998470171 -0.109232558 -1.476491E-07 0.499625281 0.001249063 0.249562828 0.2495628280.925446035 -0.095498857 -0.0003564243 0.481927711 0.060240964 0.228915663 0.2289156630.854648856 -0.082874349 -0.0013768281 0.465116279 0.11627907 0.209302326 0.2093023260.787331484 -0.07153147 -0.0029941025 0.449438202 0.168539326 0.191011236 0.1910112360.723243515 -0.061360291 -0.0051485396 0.434782609 0.217391304 0.173913043 0.1739130430.662158008 -0.052262126 -0.0077868899 0.421052632 0.263157895 0.157894737 0.157894737
J16
Admin: PARTE COMBINATORIAL
J17
Admin: PARTE COMBINATORIAL
J18
Admin: PARTE COMBINATORIAL
J19
Admin: PARTE COMBINATORIAL
J21
Admin: PARTE RESIDUAL
L21
Admin: PARTE RESIDUAL
J26
Admin: PARTE RESIDUAL
L26
Admin: PARTE RESIDUAL
J31
Admin: PARTE RESIDUAL
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0.603868797 -0.044148175 -0.0108615578 0.408163265 0.306122449 0.142857143 0.1428571430.548188172 -0.036938354 -0.014329911 0.396039604 0.346534653 0.128712871 0.1287128710.494944853 -0.030560281 -0.0181536868 0.384615385 0.384615385 0.115384615 0.1153846150.443982236 -0.024948401 -0.0222984788 0.373831776 0.420560748 0.102803738 0.1028037380.395156852 -0.020043227 -0.0267332928 0.363636364 0.454545455 0.090909091 0.0909090910.348337017 -0.015790678 -0.0314301608 0.353982301 0.486725664 0.079646018 0.0796460180.303401648 -0.012141498 -0.036363805 0.344827586 0.517241379 0.068965517 0.0689655170.260239217 -0.009050747 -0.0415113439 0.336134454 0.546218487 0.058823529 0.0588235290.218746826 -0.006477361 -0.0468520354 0.327868852 0.573770492 0.049180328 0.049180328
0.17882939 -0.004383755 -0.0523670507 0.32 0.6 0.04 0.040.140398905 -0.002735475 -0.058039276 0.3125 0.625 0.03125 0.031250.103373806 -0.001500896 -0.0638531369 0.305343511 0.648854962 0.022900763 0.0229007630.067678386 -0.000650947 -0.0697944436 0.298507463 0.671641791 0.014925373 0.014925373
0.03324228 -0.000158869 -0.0758502535 0.291970803 0.693430657 0.00729927 0.007299270.000653548 -6.20907E-08 -0.0818846447 0.285836787 0.713877376 0.000142918 0.000142918
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ALUMNO: SÁNCHEZ OCHOA JORGE LUIS
Parámetros calculados
-0.2832
-0.3716
Ɵ11= 0.385805278 Ɵ12= 0.590529248Ɵ21= 0.614194722 Ɵ22= 0Ɵ31= 0 Ɵ32= 0.079387187Ɵ41= 0 Ɵ42= 0.330083565
ᴪ13= 1 ᴪ14= 0.14298801ᴪ23= 1 ᴪ24= 0.14298801ᴪ33= 1 ᴪ34= 0.14298801ᴪ43= 0.000819586 ᴪ44= 1
Diagonalx y0 01 1
O1 O2 O3 O4 lnᴦ10.590216055 0.000939613 0.079265737819 0.329578594 0.245139335866 0.1561028789720.575266264 0.045790652 0.073468557086 0.305474527 0.21761272945 0.1385741437540.560772385 0.089273906 0.067848168232 0.282105542 0.192150781806 0.122360167660.546990905 0.13061988 0.062504031478 0.259885184 0.169039324689 0.1076429661930.533870562 0.169982372 0.057416267943 0.238730798 0.148026578805 0.0942622082010.521364894 0.207500769 0.052566861359 0.218567476 0.128903361476 0.082084687732
lnᴦ2
Q4
Admin: NUEVOS PARAMETROS UNIFAC
N21
Admin: PARTE RESIDUAL
P21
Admin: PARTE RESIDUAL
N26
Admin: PARTE RESIDUAL
P26
Admin: PARTE RESIDUAL
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0.509431695 0.243301694 0.047939444912 0.199327166 0.111495214066 0.0709993108440.498032537 0.27750044 0.043519116697 0.180947906 0.095656404743 0.0609132766050.487132353 0.310202206 0.039292279412 0.163373162 0.081265330019 0.0517491488330.476699084 0.341503176 0.035246500646 0.14655124 0.068220981168 0.0434426059320.466703357 0.371491469 0.031370390754 0.130434783 0.05644023958 0.0359407186010.457118215 0.400247965 0.027653495768 0.114980325 0.04585583416 0.0292006491110.447918868 0.427847031 0.024086203254 0.100147898 0.036414844106 0.0231886978980.439082483 0.454357169 0.020659659297 0.085900689 0.02807766838 0.0178796473180.430587996 0.479841576 0.017365695136 0.072204732 0.020817413466 0.013256371783
0.42241594 0.504358655 0.014196762142 0.059028643 0.014619677011 0.0093096999830.414548299 0.527962456 0.011145874071 0.046343371 0.009482729311 0.0060385304580.406968374 0.550703076 0.008206555646 0.034121995 0.005418119875 0.0034502178450.399660665 0.572627015 0.005372796682 0.022339523 0.002451765213 0.0015612655840.392610769 0.59377749 0.002639011065 0.01097273 0.000625609852 0.0003983836320.385939074 0.613793317 5.188331897E-05 0.000215725 2.559589292E-07 1.629927143E-07
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lnᴦ3 lnϒR1 lnϒR2 lnϒ1 lnϒ2 ϒ10.065910104455 1.023019635 1.270793067 1.53144E-06 1.161560509 1.383791E-06 3.1949150820.058509082918 1.089178263 1.128096178 0.0037059251 1.032597321 0.0033495008 2.8083505570.051663181901 1.157622093 0.996102402 0.0143799586 0.913228053 0.0130031306 2.4923550160.045449252393 1.22714924 0.87629348 0.0314702619 0.80476201 0.0284761594 2.2361642510.039799599018 1.297907951 0.767364199 0.0545538273 0.706003908 0.0494052877 2.0258794610.034657979265 1.370056616 0.668230162 0.0833144384 0.615968036 0.0755275485 1.851448001
lnᴦ4
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0.029977486801 1.443765624 0.577986982 0.1175266593 0.533838807 0.1066651016 1.7054667160.025718939011 1.51921947 0.495879193 0.1570443384 0.458940838 0.1427144274 1.5823970830.021849640618 1.596619187 0.421276404 0.2017926073 0.390716123 0.1836389205 1.4780388730.018342433616 1.676185175 0.353654992 0.2517626915 0.328706591 0.2294642128 1.3891702010.015174970076 1.758160522 0.292584072 0.3070090909 0.272540845 0.2802757981 1.3132970990.012329162958 1.842814914 0.237714914 0.3676488656 0.221924236 0.3362187048 1.2484767840.009790783557 1.930449319 0.188773178 0.4338629113 0.17663168 0.3974991063 1.1931915360.007549184423 2.021401589 0.145553573 0.5058992307 0.136502826 0.4643878868 1.1462581170.005597134753 2.11605325 0.107916686 0.5840783316 0.101439325 0.5372262962 1.1067627630.003930762215 2.214837778 0.075787854 0.6688010141 0.071404099 0.6164339634 1.0740151470.002549601749 2.318250779 0.049158111 0.7605589592 0.046422636 0.7025196832 1.0475170360.001456758646 2.426862606 0.028087329 0.8599487249 0.026586433 0.796095588 1.0269430050.000659201024 2.541334152 0.012709858 0.9676900031 0.012058911 0.8978955595 1.0121319130.000168206422 2.662436787 0.003243138 1.0846493328 0.003084269 1.0087990793 1.00308903
6.881914605E-08 2.788424477 1.326881E-06 1.2092181779 1.264791E-06 1.1273335332 1.000001265
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ϒ2 P,bar y1 y2 y1+y21.00000138 0.15496911 0.01069106 0.98930894 11.00335512 0.21909764 0.33234584 0.66765416 11.01308804 0.26917256 0.48015975 0.51984025 11.02888548 0.30815458 0.56445972 0.43554028 11.05064608 0.3391021 0.61961189 0.38038811 11.07845294 0.36415498 0.65913125 0.34086875 1
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1.1125616 0.38483864 0.68943363 0.31056637 11.15340038 0.4022585 0.71397815 0.28602185 11.20158188 0.41722699 0.7348185 0.2651815 11.25792585 0.43034791 0.75327735 0.24672265 11.32349478 0.44207309 0.77027453 0.22972547 1
1.3996451 0.45274062 0.7865029 0.2134971 11.48809846 0.46260011 0.80253191 0.19746809 11.59103999 0.47182858 0.81887605 0.18112395 11.71125376 0.48053864 0.83604739 0.16395261 11.85231084 0.48877979 0.85460428 0.14539572 12.01883312 0.49653225 0.87520593 0.12479407 12.21686844 0.50369172 0.89868416 0.10131584 12.45443247 0.51004139 0.92614895 0.07385105 12.74230574 0.5152049 0.95915707 0.04084293 13.08741303 0.51852499 0.99908623 0.00091377 1
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0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10
0.1
0.2
0.3
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0.5
0.6
0.7
0.8
0.9
1
Isobutyraldehyde(1)-n-Heptane(2) UNIFAC ( X vs Y )
X vs Y (CALCULADO) DIAGONAL X vs Y (EXP)
X
Y
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0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10
0.1
0.2
0.3
0.4
0.5
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0.8
0.9
1
Isobutyraldehyde(1)-n-Heptane(2) UNIFAC ( X vs Y )
X vs Y (CALCULADO) DIAGONAL X vs Y (EXP)
X
Y
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0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10
0.1
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0.3
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0.8
0.9
1
Isobutyraldehyde(1)-n-Heptane(2) UNIFAC ( X vs Y )
X vs Y (CALCULADO) DIAGONAL X vs Y (EXP)
X
Y
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DIAGONALX Y
0 0.152521951 0.5200016
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10
0.1
0.2
0.3
0.4
0.5
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Isobutyraldehyde(1)-n-Heptane(2) UNIFAC (X Y vs P)
X vs P (CALC) Y vs P (CALC) X vs P (EXP) Y vs P (EXP) DIAGONAL
X Y
P (B
ar)
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0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10
0.1
0.2
0.3
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Isobutyraldehyde(1)-n-Heptane(2) UNIFAC (X Y vs P)
X vs P (CALC) Y vs P (CALC) X vs P (EXP) Y vs P (EXP) DIAGONAL
X Y
P (B
ar)
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0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10
0.1
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Isobutyraldehyde(1)-n-Heptane(2) UNIFAC (X Y vs P)
X vs P (CALC) Y vs P (CALC) X vs P (EXP) Y vs P (EXP) DIAGONAL
X Y
P (B
ar)