-
Angelika Kalt á Fernando Corfu á Jan R. Wijbrans
Time calibration of a P±T path from a Variscan
high-temperaturelow-pressure metamorphic complex (Bayerische Wald,
Germany),and the detection of inherited monazite
Abstract A temperature±time path was constructed
forhigh-temperature low-pressure (HT±LP) migmatites ofthe
Bayerische Wald, internal zone of the Variscan belt,Germany. The
migmatites are characterised by pro-grade biotite dehydration
melting, peak metamorphicconditions of approximately 850 °C and
0.5±0.7 GPaand retrograde melt crystallisation at 800 °C. The
time-calibration of the pressure±temperature path is basedon U±Pb
dating of single zircon and monazite grainsand titanite separates,
on 40Ar/39Ar ages obtained byincremental heating experiments on
hornblende sepa-rates, single grains of biotite and K-feldspar, and
on40Ar/39Ar spot fusion ages of biotite determined in situfrom
sample sections. Additionally, crude estimates ofthe duration of
peak metamorphism were derived fromgarnet zoning patterns,
suggesting that peak tempera-tures of 850 °C cannot have prevailed
much longerthan 2.5 Ma. The temperature±time paths obtained fortwo
areas approximately 30 km apart do not dierfrom each other
considerably. U±Pb zircon ages re¯ectcrystallisation from melt at
850±800 °C at 323 Ma(southeastern area) and 326 Ma (northwestern
area).The U±Pb ages of monazite mainly coincide with thosefrom
zircon but are complicated by variable degrees ofinheritance. The
preservation of inherited monazite and
the presence of excess 206Pb resulting from the incor-poration
of excess 230Th in monazite formed duringHT±LP metamorphism suggest
that monazite ages inthe migmatites of the Bayerische Wald re¯ect
crystal-lisation from melt at 850±800 °C and persistence ofolder
grains at these temperatures during a compara-tively short thermal
peak. The U±Pb ages of titanite(321 Ma) and 40Ar/39Ar ages of
hornblende (322±316 Ma) and biotite (313±309 Ma) re¯ect
coolingthrough the respective closure temperatures of
ap-proximately 700, 570±500 and 345±310 °C published inthe
literature. Most of the feldspars' ages (305±296 Ma)probably record
cooling below 150±300 °C, while twograins most likely have higher
closure temperatures.The temperature±time paths are characterised
by ashort thermal peak, by moderate average cooling ratesand by a
decrease in cooling rates from 100 °C/my attemperatures between
850±800 and 700 °C to 11±16 °C/my at temperatures down to 345±310
°C. Fur-ther cooling to feldspar closure for Ar was probablyeven
slower. The lack of decompressional features, themoderate average
cooling rates and the decline ofcooling rates with time are not
easily reconciled with amodel of asthenospheric heating, rapid
uplift and ex-tension due to lithospheric delamination as
proposedelsewhere. Instead, the high peak temperatures
atcomparatively shallow crustal levels along with theshort thermal
peak require external advective heatingby hot ma®c or ultrama®c
material.
Introduction
Granulite-facies metamorphism and migmatite forma-tion by
partial melting in mid to upper crustal levelspreviously thickened
by continental collision have beendescribed from quite a few
orogenic belts (e.g. De Yoreoet al. 1991 and references therein).
These ®ndings seemin apparent con¯ict with most commonly
acceptedthermal models for lithosphere thickened by collision.These
models predict high-temperature metamorphism
A. Kalt (&)Mineralogisches Institut, Im Neuenheimer Feld
236,D-69120 Heidelberg, Germanye-mail:
[email protected]: +49-6221-544805
F. Corfu1
Royal Ontario Museum, 100 Queen's Park, Toronto,Ontario, M5S
2C6, Canada
J. R. WijbransFaculty of Earth Sciences, Vrije Universiteit,De
Boelelaan 1085, 1081 HV Amsterdam, The Netherlands
Present address:1Mineralogical-Geological Museum,Sars gate 1,
N-0562 Oslo, NorwayEditorial responsibility: J. Hoefs
Published in Contributions to Mineralogy and Petrology 138,
issue 2, 143-163, 2000which should be used for any reference to
this work
1
-
and partial melting due to crustal stacking, increasedradiogenic
heat production and thermal relaxation onlyin lower crustal levels
(Thompson and Connolly 1995and references therein). Heating of the
mid and uppercrust to the temperatures observed in
high-temperaturelow-pressure (HT±LP) orogenic belts would take
sometens of millions of years. In collisional orogens wherethis
time span is not available, additional heat is re-quired to trigger
HT±LP metamorphism and melting(De Yoreo et al. 1991; Thompson and
Connolly 1995;Zen 1995). In most common models the asthenosphere
isinvoked as an additional heat source, brought up to thebase of
the crust either by convective removal of thelithospheric mantle
(e.g. England and Houseman 1989),delamination of the lithosphere
(Bird 1979) or by slabbreako (Davies and von Blanckenburg 1995).
Othermodels consider advective heating by rising magmas
orpre-collisional lithospheric extension (De Yoreo et al.1991 and
references therein).
Determining the pressure±temperature±time (P±T±t)paths of
metamorphic rocks in orogenic belts can be ofconsiderable help in
distinguishing the possible causes ofHT±LP metamorphism. Heating by
burial and subse-quent thermal relaxation and exhumation of the
crustresult in comparatively steep, sometimes counterclock-wise P±T
paths of time spans of tens of millions of years.On the other hand,
lithospheric or slab removal/detachment induces rapid uplift and
extension of thepreviously thickened crust as recognised from quite
afew mountain belts (e.g. Dewey 1988; Malavieille 1993;Ruppel
1995). In these cases, decompression (exhuma-tion) of metamorphic
rocks is accompanied by heating(Platt and England 1994). Heating
during decompres-sion and rapid exhumation of metamorphic rocks
withcooling rates of >100 to 500 °C/my have been describedfrom a
number of extensional settings (e.g. Kohn et al.1993; van der Wal
and Vissers 1993; GarcõÂ a-Casco 1996;Soto and Platt 1999; Zeck and
Whitehouse 1999). Animportant boundary condition for this mechanism
is aconsiderable time lapse (at least 10 my; Platt et al.
1998)between lithospheric thickening and the onset of exten-sion.
Heating by underplating or rise of magmas inducesP±T paths
comparable to those typical of contactmetamorphism, characterised
by an almost isobarictemperature increase and slow isobaric
cooling.
Within the Variscan belt of Europe, remnants of anHT metamorphic
belt can be traced from the BohemianMassif in the east via
Schwarzwald, Vosges, MassifCentral and the Armorican Massif to the
Iberian Massifin the southwest (e.g. Matte 1986). Most of the
beltrepresents fairly shallow crustal levels consisting ofgneisses,
migmatites and amphibolites. Granitoid plu-tons are abundant. The
P±T conditions recorded bythese rocks require an external heat
source for HT±LPmetamorphism (e.g. Le Me tour 1978; Latouche et
al.1992; Brown and Dallmeyer 1996; Kalt et al. 1999). Lateorogenic
extension has been recognised from large-scalestructures within the
Variscan belt (e.g. Me nard andMolnar 1988; Costa and Rey 1995).
However, within
some of the HT±LP metamorphic areas, compressionalstructures
often dominate (e.g. Tanner and Behrmann1995; Behrmann and Tanner
1997) and evidence forconsiderable decompression from phase
assemblagesand thermobarometry is often lacking (e.g. Latoucheet
al. 1992; Kalt et al. 1999). HT±LP metamorphism hasbeen dated at
approximately 330±310 Ma B.P., depend-ing on the location within
the elongate belt (e.g. Grauertet al. 1974; Pin and Peucat 1986;
Kalt et al. 1994a;Brown and Dallmeyer 1996). Eclogites contained in
theHT±LP rocks occur as isolated exotic bodies of variablesize. In
the Schwarzwald, they record a high-pressureevent at approximately
345±332 Ma (Kalt et al. 1994b;Kalt et al. 1997), suggesting that
the time lapse betweenlithospheric thickening and the onset of
heating may besmall. Hence, at least for some parts of the
VariscanHT±LP metamorphic belt, heating may have occurredduring
crustal thickening and may not have been ac-companied by
extension.
The Bayerische Wald in the Bohemian Massif (Fig. 1)forms part of
the Variscan HT±LP metamorphic belt.The P±T path of the migmatites
is characterised byprograde dehydration melting, by
granulite-facies peakmetamorphic conditions and by the absence of
signi®-cant decompression during heating (Kalt et al. 1999;Fig. 1).
The purpose of this investigation is to time-calibrate the P±T path
of the migmatites in order toconstrain boundary conditions for, and
to distinguishbetween, various causes for HT±LP metamorphism.Due to
the high peak temperatures, information on theprograde part of the
P±T path is not to be expected. In
Fig. 1a,b Variscan basement outcrops in central Europe,
simpli®edgeological map of the Bayerische Wald with sample
locations, andP±T path of the migmatites. a Simpli®ed geological
map of theBayerische Wald, modi®ed after Kalt et al. (1999).
Samplelocations of migmatites, gneisses and amphibolites are
indicatedby numbers from 1±7 (compare Table 1). The inset shows
Variscanbasement outcrops in central Europe. BM Bohemian Massif;
MOMoldanubian zone; ST Saxothuringian zone; RH Rhenohercynianzone.
The MO and ST de®ned by Kossmat (1927) represent theinternal part
of the Variscan belt, characterised by high-grademetamorphism and
plutonism. The black rectangle indicates thearea shown in the map.
b P±T path for the migmatites of theBayerische Wald, modi®ed after
Kalt et al. (1999). 1 Experimen-tally determined minimum
temperatures and pressures for dehy-dration melting of metapelites
in the absence of aqueous ¯uids bythe reaction biotite +
sillimanite + plagioclase + quartz gar-net + K-feldspar + melt (Le
Breton and Thompson 1988). 2aExperimentally determined minimum
temperatures and pressuresfor dehydration melting of metagreywackes
in the absence ofaqueous ¯uids by the reaction biotite +
plagioclase + quartz =garnet + orthopyroxene + K-feldspar + melt
(Vielzeuf andMontel 1994); 2b biotite-out curve at higher
temperatures in thesame experiments. 2a is a minimum temperature
for migmatites ofthe Bayerische Wald. The biotite-out curve marks
maximumtemperatures for the migmatites as textures and biotite
composi-tions indicate that biotite was not exhausted during
partial melting.A, B, C and D refer to metamorphic stages as
described in thesection on geological setting, petrological context
and geochrono-logical background and in Kalt et al. (1999). The
shaded areamarks the results of thermobarometry, indicating
equilibrationdown to stage D
2
-
order to constrain the cooling history of the migmatitesfrom
peak metamorphism to low temperatures, the fol-lowing dating
techniques were applied: U±Pb dating ofzircon, monazite and
titanite, 40Ar/39Ar dating ofhornblende, biotite and K-feldspar. In
order to obtain
high-precision data and to be able to link them to petro-logical
information, single grains were dated whereverpossible. In order to
test possible regional variations inthe cooling path, various
localities several kilometresapart were sampled.
Gro§er
Zwiesel
Viechtach
5 km
Gabbros,amphibolites
Cham
Sediments
Bodenmais
Tepl-Barrandian
Czech Rep
ublic
German
y
Arber
Regen
Granitoids
Bt-Fsp gneisses, locallymylonitic
Migmatites
Deformed granites
Mylonites
Diatexites includinggranitic diatexites
Bt-Pl gneisses
sample location
Mica schists
Bt-Sil gneisses
Moldanubian s.str.
Gneiss with Fsp megacrysts
Qtz-rich gneisses with local melts
7
6
52 3
1
4
4
0.8
0.6
0.4
0.2
0.0600 700 800 900 1000
T [°C]
ky
sil
and
sil
1.0
?
?
?
A
B
CD
1
P[GPa]
a
b
2a 2b
STRH
BM
Alps
MO
3
-
Geological setting, petrological contextand geochronological
background
Most of the Bohemian Massif forms part of theinternal Variscan
HT belt, the Moldanubian and Sax-othuringian zones according to the
subdivision byKossmat (1927; Fig. 1). Apart from the TeplaÂ
-Bar-randian unit, the Moldanubian zone is characterised
byhigh-grade metamorphism and widespread granitoidintrusions (Fig.
1). It has a complex structure withnappes of HT±HP granulites,
peridotites and eclogitesthrust over HT±LP gneisses and migmatites.
Thesegneisses and migmatites proper are devoid of MP orHP relics
and only contain very rare exotic lenses ofeclogite.
The Bayerische Wald (Fig. 1), located at the south-western
margin of the Bohemian Massif, comprises onlythe lower unit of
HT±LP migmatites and gneisses, in-truded by granitoid plutons of
variable size. Most mig-matites are of semipelitic to pelitic bulk
composition andare characterised by the assemblages biotite +
quartz +plagioclase + K-feldspar + cordierite + ilmenite.
Ad-ditional garnet, spinel, orthopyroxene and sillimaniteoccur
depending on bulk rock composition. The P±Tpathis most likely
clockwise (Fig. 1) and can be divided intofour stages. Apart from a
®rst stage A only preserved ingarnets of a few samples, the further
P±T path of allmigmatite samples is characterised by
melt-producingbiotite dehydration reactions in the absence of an
aqueous¯uid phase, peak conditions of approximately 850 °C/0.5±0.7
GPa and cooling (stage B) until the partial meltsformed at stage B
crystallised (stage C). Subsequent stageD, during which mineral
equilibria were frozen (770±846 °C/0.44±0.51 GPa), is characterised
by decompres-sion and cooling. The amphibolites are included as
bodiesof variable size in the migmatites and show relic
assem-blages of either plagioclase+ clinopyroxene+ titanite
orplagioclase + clinopyroxene+ orthopyroxene+ quartz+ ilmenite,
recording a granulite-facies stage with thesame peak temperatures
as those estimated for the mig-matites.
Previous geochronological studies have shown HT±LP metamorphism
to be of Carboniferous age. U±Pbages of monazite grain-size
fractions from migmatites ofthe Bayerische Wald range from 317 to
321 Ma (Grauertet al. 1974), similar to those obtained on
metamorphicrocks of the Moldanubian zone in the adjacent Ober-pfaÈ
lzer Wald (317 3±323 3 Ma; Teufel 1988). K±Ar ages of biotite
grain-size fractions from variousmetamorphic rocks of the
Bayerische Wald scatter be-tween 325 5 and 309 5 Ma (Kreuzer et al.
1989).For the granites intruding the migmatites, Rb±Sr min-eral
ages range from 302 7 to 322 5 Ma, and K±Ar mineral ages scatter
between 296 3 and320 8 Ma (compilation in Siebel 1998).
Sample selection
The aim of the study was to establish temperature±timepaths for
HT±LP migmatites and gneisses of the Bay-erische Wald by U±Pb
dating of zircon, monazite andtitanite and 40Ar/39Ar dating of
amphibole, biotite andK-feldspar. A temperature±time path ideally
requiresthat all chronometers used should be applied to oneoutcrop
or restricted area. This approach was limited inthe case of the
Bayerische Wald by the scarce occurrenceof amphibolites and
amphibole-bearing migmatites andby the fact that most of the latter
were found to behydrothermally overprinted. Therefore, amphibole
dat-ing could be performed only at a few outcrops (Table 1,Fig. 1).
However, a larger number of localities (Table 1,Fig. 1) had to be
selected for dating in order to detectpossible regional variations
in the cooling path. Thesampling sites can be roughly grouped into
a south-eastern area around Bodenmais (Fig. 1), comprisinglocations
1±5 and a northwestern area around Cham(Fig. 1), comprising
location 7 (and 6).
Two rock types were sampled for dating: (1) mig-matites and one
gneiss for U±Pb dating of zircon andmonazite and 40Ar/39Ar dating
of biotite and K-feld-spar, and (2) amphibolites for U±Pb dating of
titaniteand 40Ar/39Ar dating of amphibole and in one case
also40Ar/39Ar dating of biotite. Phase assemblages,
meltingreactions, melt fractions and microstructures of
themigmatites are described in detail in Kalt et al. (1999)and
Berger and Kalt (1999). The amphibolites are ®ne-to medium-grained
rocks with gneissose textures. Foli-ation is well pronounced and
de®ned by amphibole andbiotite (where present). Samples BW-112 and
BW-132contain quartz, clinopyroxene, orthopyroxene, biotiteand
accessory ilmenite and apatite in addition to am-phibole and
plagioclase. Pyroxene inclusions in someamphiboles indicate that
amphibole grew at the expenseof pyroxenes. However, the coexistence
of unreactedpyroxenes with amphibole, both displaying stable
grainboundaries, indicates equilibrium between the minerals.Sample
BW-134 shows compositional banding parallelto foliation. Amphibole-
and plagioclase-rich layers al-ternate with clinopyroxene- and
plagioclase-rich layers.Sample BW-118 contains amphibole,
plagioclase andquartz in textural equilibrium. Samples BW-134
andBW-118 contain accessory titanite.
Characteristics of the phases and sample preparation
The compositions of biotite, K-feldspar and amphibolefrom the
samples used here for dating are listed inTable 2 (for analytical
procedure see Kalt et al. 1999).
Zircon is present as accessory phase in the mig-matites. It
occurs interstitially in mesosomes and le-ucosomes and may also be
enclosed in garnet andbiotite. In thin section, zircons display
anhedral to eu-hedral shapes and in cases zoning under crossed
polars.
4
-
For the present study, only zircons formed during HT±LP
metamorphism were of interest. Hence, zircons wereonly selected
from leucosomes where the chance of beingnewly crystallised from
melt during HT±LP metamor-phism is high, whereas in mesosomes the
probability ofzircons containing inherited radiogenic lead or
olderzircon domains is much larger due to the restitic char-acter
of some mesosomes (Kalt et al. 1999). Under thebinocular
microscope, zircons partly showed core-rimstructures. In order to
avoid inheritance problems theanalyses were carried out only on rim
components(prisms and tips).
As is the case with zircon, monazite is an accessoryphase in
migmatites where it occurs interstitially andforms inclusions in
garnet and biotite. Monazites areanhedral to platy crystals that
partly display colourzoning under crossed polars. Though much less
oftenthan zircons, monazites may contain inherited radio-genic lead
(e.g. Copeland et al. 1988), possibly in theform of an inherited
monazite phase (Harrison et al.1995). The case was described by
Teufel (1988) forgneisses of the OberpfaÈ lzer Wald. Therefore, in
mig-matites with clear leucosome±mesosome boundaries(BW-70, BW-90,
Table 1), mesosomes and leucosomeswere carefully separated before
crushing. In one meso-some (BW-70M), monazite inclusions in garnet
could be
separated. Under the binocular microscope, monazitesdisplayed
clear core-rim structures only in one case(BW-90M) where fragments
were broken (Table 3).
Titanite is restricted to amphibolites. It displays ir-regular,
contorted shapes where grown interstitially(BW-118) or forms ¯at
sphenoidal crystals where in-cluded in amphibole and plagioclase
(BW-134). Nocolour zoning was detected under the polarising
micro-scope.
Amphibole in amphibolites grows mainly at the ex-pense of
granulite-stage pyroxenes, whereby it maycompletely replace
pyroxenes in distinct layers of therocks. XMg, Al2O3 and K2O
contents vary considerablyamong the samples, with K2O being
generally low (0.27±0.82 wt%, Table 2). The compositions correspond
tomagnesio-hornblende (BW-112), edenitic hornblende(BW-134) and
actinolitic hornblende (BW-118, BW-132)according to the
nomenclature of Leake (1978).
Biotite is one of the major phases in the migmatites. Itoccurs
mainly in mesosomes and melanosomes and onlyrarely in leucosomes.
Biotite is partly consumed by de-hydration melting reactions. Due
to the divariant char-acter of the latter reactions, a large
percentage of thebiotite remains stable during partial melting.
Duringsubsequent cooling, new biotite grows and all
biotitecompositions are re-equilibrated on the retrograde path
Table 1 Sample characteristics
Locationa Sample Lithology Phase assemblageb Dating
techniquec
1 BW-22 Migmatite crd + grt + bt + pl + qtz 40Ar/39Ar IH
biotiteBW-28 Migmatite crd + grt + bt + Kfs + pl +
qtz + sil + spl
40Ar/39Ar SF biotite
BW-70L Leucosome Kfs + pl + qtz + bt U-Pb zircon, U-Pb
monaziteBW-70M Mesosome crd + grt + bt + Kfs + pl +
qtz + sil + splU-Pb monazite
2 BW-30 Migmatite crd + grt + bt + pl + qtz 40Ar/39Ar IH
biotiteBW-32 Migmatite crd + grt + bt + Kfs + pl + qtz 40Ar/39Ar SF
biotiteBW-67 Migmatite crd + grt + bt + Kfs + pl +
qtz + sil + spl
40Ar/39Ar SF biotite, 40Ar/39Ar IHK-feldspar
3 BW-86246 Gneiss crd + grt + bt + pl + qtz + mt + spl 40Ar/39Ar
IH biotite
4 BW-132 Amphibolite hbl + cpx + opx + pl + qtz + bt + ilm
40Ar/39Ar IH hornblende, 40Ar/39Ar IHbiotite
BW-134 Amphibolite hbl + cpx + pl + ttn U-Pb titanite, 40Ar/39Ar
IH hornblende
5 BW-118 Amphibolite hbl + pl + qtz + ttn U-Pb titanite,
40Ar/39Ar IH hornblendeBW-120 Migmatite crd + bt + Kfs + pl + qtz
U-Pb monazite, 40Ar/39Ar IH
biotite, 40Ar/39Ar IH K-feldspar
6 BW-112 Amphibolite hbl + cpx + opx + pl + qtz +bt + ilm
40Ar/39Ar IH hornblende
BW-116 Migmatite crd + bt + Kfs + pl + qtz + sil U-Pb monazite,
40Ar/39Ar IHbiotite, 40Ar/39Ar IH K-feldspar
7 BW-44 Migmatite crd + grt + bt + Kfs + pl +qtz + sil
40Ar/39Ar IH biotite, 40Ar/39Ar SFbiotite, 40Ar/39Ar IH
K-feldspar
BW-46 Migmatite crd + grt + bt + Kfs + pl +qtz + spl + sil
40Ar/39Ar IH biotite, 40Ar/39Ar IHK-feldspar
BW-90L Leucosome Kfs + pl + qtz + bt U-Pb zircon, U-Pb
monaziteBW-90M Mesosome crd + grt + bt + Kfs + pl +
qtz + spl + silU-Pb monazite, 40Ar/39Ar SF biotite
a Location numbers correspond to those given in Fig. 1bMineral
abbreviations according to Kretz (1982)c IH incremental heating
experiments on single minerals or mineralseparates with a laser, SF
spot fusion experiments on minerals in
thin sections with a laser. In addition to the minerals
indicated,migmatites may contain accessory zircon, monazite,
apatite, ilme-nite, graphite, pyrrhotite and pyrite. Amphibolites
may bear ad-ditional zircon, ilmenite and apatite
5
-
Table
2Mineralcompositions.Mineralabbreviationsaccordingto
Kretz
(1982);n.d.notdetermined,n.c.notcalculated.Form
ula
calculations:bt,12O,2OH,Fe2
+/Fe tot=
0.85;
Kfs:8O,Fe3
+=Fe tot;hbl,22O,15cations±Na±K,2OH,Fe3
+per
chargebalance
Location1
Location2
Loca-
tion3
Location4
Location5
Location6
Location7
BW-22BW-28
BW-30
BW-32
BW-67
86246
BW-132
BW-132BW-134BW-118
BW-120BW-120BW-112
BW-116BW-116BW-44
BW-44
BW-46
BW-46
BW-90
bt
bt
bt
bt
Kfs
bt
hbl
bt
hbl
hbl
bt
Kfs
hbl
bt
Kfs
bt
Kfs
bt
Kfs
bt
SiO
234.96
34.96
34.22
34.02
65.57
34.88
51.09
38.19
43.77
50.49
34.74
64.47
48.07
33.80
64.50
34.42
65.21
34.45
64.75
34.53
TiO
24.41
4.28
4.08
3.95
0.00
0.04
0.52
2.68
1.87
0.78
3.82
0.00
1.51
3.82
0.00
5.12
0.00
4.15
0.00
4.96
Al 2O
318.26
18.38
18.69
18.73
19.18
19.91
5.86
15.00
10.77
5.56
18.49
18.28
7.02
18.28
19.16
17.88
19.32
17.85
19.54
17.74
Cr 2O
30.11
0.08
0.07
0.07
0.00
0.01
0.21
0.26
0.15
0.08
0.05
0.00
0.17
0.35
0.00
0.13
0.00
0.14
0.00
0.11
Fe 2O
33.33
3.37
3.85
3.91
0.02
3.87
0.13
2.21
0.04
0.26
3.59
0.00
0.00
4.04
0.04
3.48
0.01
3.69
0.05
3.47
FeO
16.99
17.18
19.63
19.96
0.00
19.74
10.89
11.29
14.82
12.56
18.30
0.00
15.00
20.62
0.00
17.74
0.00
18.83
0.00
17.68
MnO
0.09
0.09
0.08
0.08
0.00
0.00
0.36
0.15
0.26
0.40
0.17
0.00
0.23
0.09
0.00
0.07
0.00
0.13
0.00
0.08
MgO
8.45
8.18
6.00
5.91
0.00
7.59
16.22
15.25
11.44
14.84
7.01
0.00
12.79
5.33
0.00
7.71
0.00
7.38
0.00
7.63
CaO
0.07
0.00
0.00
0.00
0.23
0.02
11.55
0.00
12.09
11.78
0.01
0.04
10.95
0.00
0.08
0.00
0.12
0.00
0.12
0.02
Na2O
0.17
0.11
0.18
0.21
3.71
0.10
0.57
0.18
1.60
0.55
0.17
1.64
0.73
0.15
1.71
0.17
2.77
0.17
2.10
0.16
K2O
9.25
9.29
9.12
9.06
11.24
9.09
0.28
9.09
0.82
0.27
9.17
14.11
0.67
9.14
14.06
9.11
12.47
9.15
13.54
9.31
H2O
3.97
3.96
3.91
3.90
n.d.
3.90
2.09
4.03
2.01
2.07
3.92
n.d.
2.03
3.87
n.d.
3.94
n.d.
3.92
n.d.
3.93
Total100.06
99.89
99.82
99.78
99.95
99.15
99.76
98.33
99.64
99.63
99.43
98.54
99.17
99.47
99.55
99.77
99.90
99.84
100.10
99.61
Si
2.639
2.644
2.624
2.615
2.979
2.680
7.326
2.838
6.524
7.320
2.655
3.000
7.101
2.621
2.972
2.619
2.975
2.634
2.962
2.633
Ti
0.250
0.244
0.235
0.228
0.000
0.002
0.056
0.150
0.209
0.085
0.220
0.000
0.168
0.223
0.000
0.293
0.000
0.238
0.000
0.285
Al
1.624
1.638
1.589
1.696
1.027
1.803
0.990
1.314
1.893
0.951
1.666
1.003
1.223
1.670
1.041
1.603
1.039
1.608
1.053
1.594
Cr
0.006
0.004
0.004
0.004
0.000
0.001
0.023
0.015
0.018
0.009
0.003
0.000
0.020
0.022
0.000
0.008
0.000
0.008
0.000
0.007
Fe3
+0.189
0.192
0.222
0.226
0.001
0.224
0.014
0.124
0.004
0.028
0.206
0.000
0.000
0.236
0.002
0.199
0.000
0.212
0.002
0.199
Fe2
+1.073
1.087
1.259
1.283
0.000
1.269
1.306
0.702
1.847
1.523
1.169
0.000
1.853
1.337
0.000
1.129
0.000
1.204
0.000
1.127
Mn
0.006
0.006
0.005
0.005
0.000
0.000
0.044
0.009
0.033
0.050
0.011
0.000
0.028
0.006
0.000
0.004
0.000
0.008
0.000
0.005
Mg
0.950
0.923
0.686
0.677
0.000
0.870
3.468
1.690
2.542
3.206
0.799
0.000
2.817
0.616
0.000
0.874
0.000
0.841
0.000
0.867
Ca
0.006
0.000
0.000
0.000
0.011
0.001
1.774
0.000
1.930
1.829
0.001
0.002
1.733
0.000
0.004
0.000
0.006
0.000
0.006
0.001
Na
0.025
0.016
0.026
0.031
0.327
0.014
0.159
0.026
0.463
0.153
0.025
0.148
0.210
0.022
0.153
0.026
0.245
0.025
0.186
0.024
K0.890
0.896
0.892
0.888
0.651
0.891
0.051
0.826
0.156
0.050
0.894
0.838
0.127
0.904
0.826
0.884
0.726
0.892
0.790
0.906
OH
2.000
2.000
2.000
2.000
n.c.
2.000
2.000
2.000
2.000
2.000
2.000
n.c.
2.000
2.000
n.c.
2.000
n.c.
2.000
n.c.
2.000
Total
7.659
7.651
7.642
7.653
4.996
7.756
15.210
7.729
15.619
15.203
7.647
4.991
15.278
7.656
4.997
7.638
4.991
7.671
4.999
7.647
6
-
Table
3ResultsofU±Pbdating
Loca-
tion
Sample,analysisno.
and
mineralproperties
aWeight
[lg]b
U [ppm]b
Th/U
cPbcom
[pg]d
206Pb/
204Pbe
206Pb/238U
f,g
207Pb/235U
f,g
207Pb/206Pbf,g
206Pb/
238U
[Ma]f
+/)
[2r]g
207Pb/
235U
[Ma]f
+/)
[2r]g
207Pb/
206Pb[M
a]f
+/)
[2r]g
1BW-70M
1,m
euincl
ingrt
[1]
11918
16.00
12.0
701
0.06842
58
0.4867
60
0.05159
44
426.6
3.6
402.6
4.2
267
20
2,m
eu[1]
12053
13.84
1.2
5547
0.05162
25
0.3764
21
0.05288
11
324.5
1.6
324.4
1.6
323.6
4.9
3,m
eu[1]
1558
16.71
1.2
1529
0.05136
26
0.3745
31
0.05261
32
324.5
1.6
323.0
2.4
312
14
4,m
sb[1]
34932
9.19
8.7
5375
0.05143
28
0.3738
23
0.05271
10
323.3
1.8
322.4
1.6
316.3
4.3
5,m
euincl
A[1]
20
3079
17.43
76.9
2548
0.05045
25
0.3667
22
0.05271
12
317.3
1.6
317.2
1.6
316.3
5.2
BW-70L
6,m
eq[1]
35785
7.68
8.7
6458
0.05144
27
0.3740
22
0.05273
10
323.4
1.6
322.6
1.6
317.0
4.3
7,m
eu[1]
10
6278
7.64
5.6
35862
0.05148
33
0.3736
25
0.05263
08
323.6
2.0
322.3
1.8
312.7
3.3
8,m
eu[1]
47205
2.50
1.9
49912
0.05153
31
0.3731
24
0.05250
08
323.9
2.0
321.9
1.8
307.3
3.6
9,m
eu[1]
13095
5.85
1.3
7743
0.05128
24
0.3729
20
0.05274
10
322.4
1.4
321.8
1.4
317.6
4.3
10,m
sbA
[1]
17466
7.11
1.2
20059
0.05103
29
0.3710
23
0.05273
10
320.9
1.8
320.4
1.8
317.2
4.6
11,zeu
tipsA
[2]
2145
0.06
2.0
489
0.05145
26
0.3746
65
0.05281
82
323.4
1.6
323.1
4.8
321
35
4BW-134
31,tfr
lbrA
[>30]
333
21
1.47
405
73
0.05108
44
0.383
23
0.0543
32
321.2
2.6
329
17
384
129
32,teu-sbflbr[>
30]
170
16
1.79
178
68
0.05107
44
0.376
23
0.0534
33
321.1
2.8
324
17
347
136
5BW-118
33,tan-frlbrA
[>30]
173
110
0.64
132.2
477
0.05099
26
0.3729
36
0.05303
39
320.6
1.6
321.8
2.6
330.2
16.5
BW-120
23,m
eueq
[1]
21701
8.02
3.3
3332
0.05116
27
0.3723
23
0.05277
16
321.7
1.6
321.3
1.8
318.9
7.0
24,m
eueq
[1]
115364
5.63
3.2
15535
0.05122
26
0.3722
21
0.05270
08
322.0
1.6
321.3
1.6
315.9
3.6
25,m
eueq
[1]
22263
9.28
5.7
2590
0.05145
24
0.3737
21
0.05268
12
323.4
1.4
322.4
1.6
314.9
5.3
26,m
eueq
incl
[1]
26956
14.74
12.0
3836
0.05142
25
0.3740
21
0.05275
10
323.2
1.6
322.6
1.6
318.0
4.5
6BW-116
27,m
eu-sbeq
[1]
1519
10.95
2.6
697
0.05377
29
0.3936
44
0.05309
49
337.6
1.8
337.0
3.2
333
21
28,m
eu-sbtip[1]
31979
7.59
2.3
8527
0.05203
25
0.3828
22
0.05337
13
327.0
1.6
329.1
1.6
344.5
5.4
29,m
eueq
[1]
11780
8.31
6.7
883
0.05188
24
0.3789
27
0.05296
23
326.1
1.6
326.2
2.0
327
10
30,m
eueq
incl
[1]
34569
11.13
33
1360
0.05141
28
0.3744
25
0.05283
17
323.2
1.8
322.9
1.8
321.3
7.4
7BW-90M
12,m
eusp
[1]
2318
6.86
3.0
734
0.05421
27
0.3950
37
0.05285
39
340.3
1.6
338.0
2.8
322
17
13,m
sbA
[1]
18915
10.11
2.0
14368
0.05216
28
0.3809
23
0.05295
10
327.8
1.8
327.7
1.8
326.7
4.3
14,m
eu[1]
35287
6.75
4.1
12613
0.05200
30
0.3792
24
0.05289
08
326.8
1.8
326.4
1.8
323.9
3.6
15,m
ancore
[1]
11
933
7.57
2.4
13806
0.05168
25
0.3768
21
0.05288
09
324.8
1.6
324.7
1.6
323.6
3.7
16,m
anrim
[1]
27234
7.01
6.3
7408
0.05164
29
0.3764
23
0.05287
09
324.6
1.8
324.4
1.8
323.1
3.7
17,m
sbA
[1]
44030
7.18
2.2
23541
0.05156
26
0.3753
21
0.05280
08
324.1
1.6
323.1
1.6
320.0
3.5
BW-90L
18,m
eu[1]
112730
2.90
3.1
13420
0.05222
32
0.3805
25
0.05284
09
328.2
2.0
327.4
1.8
321.8
3.7
19,m
euA
[1]
21558
2.74
3.0
3415
0.05197
26
0.3797
22
0.05298
13
326.6
1.6
326.8
1.6
328.1
5.7
20,m
euA
[1]
410310
2.78
8.9
15019
0.05186
31
0.3780
25
0.05286
09
326.0
2.0
325.6
1.8
322.7
3.9
21,m
eu[1]
12632
7.03
0.9
9312
0.05173
24
0.3768
20
0.05283
11
325.2
1.4
324.7
1.4
321.4
47
22,zprism
[1]
1241
0.34
0.8
952
0.05186
26
0.3795
40
0.05307
46
325.9
1.6
326.7
3.0
332
20
am
Monazite,zzircon,ttitanite,
eueuhedral,sb
subhedral,ananhedral,eq
equant,f¯at,fr
fragments,incl
inclusion,lbrlight-brown,A
abraded,[1]number
ofgrainsanalysed
bWeightsknownto
betterthan10%
when
over
10
lg,andto
about50%
when
less
than2
lg;accuracy
ofU
andThconcentrationsisroughly
proportionalto
uncertainty
ofsampleweight
cModel
Th/U
ratioestimatedfrom
208Pb/206Pbratioandageofsample
dTotalcommonPbin
sample,includes
initialandblankPb
eMeasuredratio,correctedforfractionationandspikecontribution
fCorrectedforspike,
fractionation,blankandinitialcommonPb(StaceyandKramers1975)
g2runcertainty
calculatedbyerrorpropagationprocedure
thattakes
into
accountinternalmeasurementstatisticsandexternalreproducibilityaswellasuncertainties
intheblankandcommonPb
correction;errors
are
given
asthelast
decim
alplacesoftherespectivevalues
7
-
at very high temperatures (Kalt et al. 1999). Biotite
in-clusions in garnet may potentially record older stages
ofmetamorphism or earlier metamorphic events with the40Ar/39Ar
chronometer (Kelley et al. 1997) through be-ing armoured from Ar
diusion. Therefore, apart fromsingle grains very thin, polished
rock sections were pre-pared for dating biotite inclusions in
garnet and biotitegrains in the matrix. Biotites from migmatite
sampleshave rather uniform compositions characterised byfairly low
XMg values and K2O contents >9 wt%. Thelargest variation is
found in TiO2 (3.82±5.12 wt%,Table 2). Biotite in gneiss sample
BW-132 is in equilib-rium with amphibole, plagioclase and quartz.
It displayslower TiO2 contents and higher XMg values compared
tobiotite from migmatites (Table 2).
K-feldspar occurs in mesosomes and in leucosomesof the
migmatites. K-feldspars in leucosomes clearlycrystallised from a
melt during stage C. Conversely,their role in mesosomes is not
clear as in generalK-feldspar may be either consumed or formed
bydehydration melting reactions depending on the K2O/H2O ratio of
the melt (Carrington and Watt 1995).However, K-feldspars in all
samples are perthitic andthus record equilibration above
approximately 700 °C.Above this temperature and at the relevant
pressures,K-feldspar is generally homogeneous monoclinic,whereas
below approximately 700 °C, spinodal decom-position of domains to a
triclinic albite phase starts(Parsons and Brown 1991 and references
therein). Theexsolution lamellae observed in K-feldspars from
mig-matites of the Bayerische Wald have several scales. Witha
polarising microscope, parallel or subparallel lamellaeof 50±250 lm
widths can be observed. Back-scatteredelectron microprobe images
reveal further exsolutionlamellae of 1±5 lm widths. In thin
sections, beginningformation of braid perthite can be recognised,
resultingfrom rotation, broadening and coalescence of the
albitelamellae. These transformations occur at and below400 °C
(Parsons and Brown 1991 and references therein)and are generally
ascribed to slow cooling of the feld-spars. While K-feldspars of
samples BW-67, BW-120and BW-116 only have minor inclusions, those
in sam-ples BW-44 and BW-46 contain numerous inclusions
ofplagioclase. All K-feldspar grains selected for datingcome from
leucosomes.
U±Pb dating
Analytical techniques
The U±Pb isotopic measurements were conducted at theJack
Satterly Geochronological Laboratory, Depart-ment of Earth
Sciences, Royal Ontario Museum inToronto. Minerals were separated
by crushing with ajaw-crusher, pulverisation with a disk mill,
heavy min-eral enrichment on a Wil¯ey table, and subsequentmagnetic
separation on a Frantz isodynamic separatorand density separation
using heavy liquids. The minerals
to be analysed were separated under a binocular mi-croscope and
in part air-abraded (Table 3) following thetechnique of Krogh
(1982). Single grains or single frag-ments of grains were dated
except for zircon analysis ofsample BW-70L (two grain fragments,
Table 3) andtitanite analyses (>30 grains, Table 3).
After a ®nal selection, the minerals were washed inca. 4 N HNO3
on a hotplate and rinsed with H2O andacetone. A mixed 205Pb/235U
spike was used for U±Pbanalyses of zircon, titanite and monazite.
The spike wasadded to the sample after weighing and transfer to
thedissolution vessel. Zircon was dissolved in HF(+HNO3) in Te¯on
mini-bombs at ca. 190 °C, monazitewas dissolved in 6 N HCl in
Savillex vials on a hotplate,and titanite was dissolved in HF
(+HNO3) using Sa-villex vials on a hotplate. The solutions were
subse-quently evaporated, redissolved in 3.1 N HCl andpassed
through anion exchange resin in minicolumns inHCl medium to purify
U and Pb (zircon and monazite).For titanite, a more complex
HCl±HBr±HNO3 proce-dure was necessary to purify U and Pb. Blanks
were lessthan 2 pg Pb and 0.1 pg U for zircon and monazite and10 pg
Pb and 0.5 pg U for titanite.
Pb and U were collected together from the columns,loaded on
outgassed Re-®laments together with H3PO4and Si-gel, and run on a
VG354 mass spectrometer usinga Daly detector. Daly±Faraday
conversion was 0.04%/a.m.u. Fractionation factors for U and Pb
correspond to0.1%/a.m.u.
General features of the monazite and zircon data
The results for 28 monazite, 2 zircon and 3 titanite an-alyses
are given in Table 3 and presented in Concordiadiagrams (Figs.
2±4). The data patterns for the mona-zites reveal various degrees
of complexity and repeatedanalyses were carried out to verify the
reproducibility ofthe ages and explore possible causes for the
deviation ofsome of the samples.
All the monazite data plot on or slightly above theconcordia
curve, a common observation in monazite,re¯ecting on the one hand
the resistance of monazite tolead loss, and on the other hand the
presence of excess206Pb resulting from the incorporation of excess
230Th atthe time of formation (SchaÈ rer 1984; Parrish 1990).
Al-though excess 230Th mainly aects the U±Pb systematicsof very
young samples it may as well lead to severalpercent of excess 206Pb
in older samples provided thefractionation factor (f
(Th/U)mineral/(Th/U)reservoir) islarge enough (SchaÈ rer 1984). The
excess 206Pb results in206Pb/238U ages that are too high and
207Pb/206Pb ratiosthat are too low. A correction for the initial
disequilib-rium is generally possible but was not applied in this
caseas the Th/U ratio of the initial reservoir open to U, Thand Pb
exchange with monazite is not known. Withoutcorrection, the most
accurate estimate of the ages can beobtained from 207Pb/235U ratios
which are not aectedby the initial disequilibrium. Hence, all the
monazite
8
-
ages reported in Figs. 2±4 and referred to in the text arebased
on weighted averages of 207Pb/235U.
Zircon commonly incorporates very little Th at thetime of
formation and hence remains essentially unaf-fected by
disequilibrium. In order to date only zirconparts grown during
HT±LP metamorphism, very smallzircon fragments had to be used that
contained very littleU and Pb, aecting the precision of the
207Pb/235U and207Pb/206Pb ages through the common lead
correction.Therefore, the 206Pb/238U ages are reported for
zirconanalyses. Titanite also incorporates only very little Thand
is characterised by low U and Pb abundances.Therefore, 206Pb/238U
ages are also indicated for titanite.
Ages of monazite and zircon from migmatitesand gneisses
For sample BW-70, ®ve analyses of monazite from theleucosome
cluster tightly on or slightly above Con-cordia, yielding an
average 207Pb/235U age of
321.8 0.7 Ma (Fig. 2a). Analysis of two abradedzircon tips
yields a concordant data point and an over-lapping 206Pb/238U age
of 323.4 1.6 Ma (Fig. 2a).More complex relations are observed for
the mesosome(Fig. 2b). Three of the monazite analyses yield
over-lapping results at a mean 207Pb/235U age of323.3 1.0 Ma. One
analysis (no. 5, Table 3) yields ayounger age of 317.2 1.6 Ma (Fig.
2b). This graincontained several inclusions that probably
contributedto the elevated initial common Pb (Table 3), but
theireect on the age is not known. Another analysis (no. 1,Table 3)
provides a reversely discordant but much olderage (Fig. 2b). This
grain was enclosed in garnet.
For sample BW-90, analyses of four monazite grainsfrom the
leucosome yield a weighted average 207Pb/235Uage of 326.1 1.7 Ma
(Fig. 3a). The scatter of thedata, however, exceeds analytical
uncertainty. Analysisof a zircon prism from the leucosome yields a
concor-dant data point and a 206Pb/238U age of 325.9 1.6 Ma(Fig.
3a), identical to the monazite age. Five analyses ofmonazite from
the mesosome are clustered tightly on or
Fig. 2a, b U±Pb concordia diagram showing the results of
U±Pbdating of monazite and zircon from migmatite sample BW-70
oflocation 1. a Leucosome; bmesosome. Errors are given at the 2r
level.For further explanation see section on general features of
the zirconand monazite data and section on ages of monazite and
zircon frommigmatites and gneisses
Fig. 3a, b U±Pb concordia diagram showing the results of
U±Pbdating of monazite and zircon from migmatite sample BW-90
oflocation 7. a Leucosome; bmesosome. Errors are given at the 2r
level.For further explanation see section on general features of
the zirconand monazite data and section on ages of monazite and
zircon frommigmatites and gneisses
9
-
slightly above the Concordia curve (Fig. 3b). The aver-age
weighted 207Pb/235U age is 325.3 1.9 Ma, but thescatter of the data
is beyond analytical uncertainty. Asixth analysis (no. 12, Table 3)
of a simple prismaticcrystal gave a signi®cantly older age of 340
Ma. Some ofthe monazite grains of BW-90 mesosome showedapparent
cores and overgrowths. One of these grainswas broken into core and
rim fragments (nos 15±16,Table 3) to test for a possible inherited
origin of thecore. However, both parts of the grain yielded
identicalages (Table 3).
In migmatites BW-120 and BW-116, mesosome andleucosome could not
be separated. Four monazite grainsfrom sample BW-120 yield data
points that overlap onor slightly above the Concordia curve with a
mean207Pb/235U age of 321.9 0.8 Ma (Fig. 4a). The resultsfor four
monazite analyses of sample BW-116 are morecomplex (Fig. 4b). Three
of the analyses are concordantbut have 207Pb/235U ages ranging from
337 to 323 Ma.Another analysis (no. 28, Table 3) is slightly
discordant(Fig. 4b). There is no obvious morphological or
colourdierence between the four monazite grains. The
207Pb/235U age of the youngest monazite is322.9 1.8 Ma.
Ages of titanite from amphibolites
Two analyses were performed on titanite of sampleBW-134, one of
them using fragments that were abra-ded, the other using ¯at
spheroidal crystals. Both showlow U contents of 16±21 ppm and
provide identical206Pb/238U age values of 321.2 2.7 Ma. Although
thelow 206Pb/204Pb ratios of about 70 make the age cal-culation
quite sensitive to the choice of initial Pb, thevariation
introduced by this correction on the206Pb/238U age is minimal. For
example, the use ofStacey and Kramers (1975) model Pb
compositions,calculated for ages spanning almost the entire
Paleozoicand Mesozoic, yields a range of 206Pb/238U valuescovered
almost entirely by the quoted analytical un-certainty. The titanite
population of sample BW-118consists of anhedral grains with
irregular, contortedshapes. As the U content and the proportion of
ra-diogenic Pb are much higher than in sample BW-134(Table 3), the
206Pb/238U age of 320.6 1.6 Ma ismuch more precise, and much less
dependent on thechoice of initial Pb. In this case a
Paleozoic±Mesozoicrange of model corrections produces a variation
of lessthan half the analytical error.
40Ar/39Ar dating
Analytical techniques
The 40Ar/39Ar isotopic measurements were conductedusing the
VULKAAN argon laserprobe at the Facultyof Earth Sciences, Vrije
Universiteit Amsterdam. Forincremental heating experiments, mineral
separates wereobtained by carefully crushing ®nger- to
hand-sizedsamples, and sieving through 500 lm, 250 lm and125 lm
mesh fractions. The mineral separates werewashed with deionised
water, separated magneticallyand handpicked. For an incremental
heating experi-ment, 1±3 grains of biotite, 60 grains of hornblende
and1 grain of K-feldspar were used, respectively. The sep-arates
were put into Al tablets containing 20, 2-mmholes. On each tablet,
16 positions were loaded withsamples and 4 with a ¯ux monitor of
known age (stan-dard DRA-1, 24.99 Ma). For spot fusion experiments
onbiotite and K-feldspar, polished sample sections of2 ´ 2 cm, 90
lm thick, were prepared. Their corners andedges were then broken to
®t the sections onto an Altablet. Additional tablets containing
only the standardwere also prepared. All tablets were wrapped in Al
foiland loaded into cylindrical Al containers, with samplesections
and standard tablets alternating. The containerswere then
irradiated in the Triga Reactor at the OregonState University for
24 (®rst sample charge) and 18 h(second sample charge).
Fig. 4a±c U±Pb concordia diagrams showing the results of
U±Pbdating of monazite and titanite. a Monazite from migmatite
sampleBW-120 (location 5); b monazite from migmatite sample
BW-116(location 6); c titanite from amphibolite samples BW-134
(location 4)and BW-118 (location 5). Errors are given at the 2r
level. For furtherexplanation see section on general features of
the zircon and monazitedata and section on ages of monazite and
zircon from migmatites andgneisses
10
-
The VULKAAN argon laserprobe consists of a 24 Wargon ion laser
(visible light, 488±524 nm), beam optics,a low volume UHV gas inlet
system, and a MAP 215-50noble gas mass spectrometer. Full technical
and ana-lytical laserprobe dating procedures were described
byWijbrans et al. (1995). The isotopic composition of Arwas
measured in static mode. Intensities were recordedwith a secondary
electron multiplier detector usingswitchable pre-ampli®er resistor
settings (10, 100,1000 MW) and peak jumping at half mass intervals
frommass 40 down to mass 35.5. All measured values werecorrected
for mass discrimination, 37Ar and 39Ar decay,neutron-induced
interferences from Ca and K, andprocedural blanks. Correction
factors were as quoted inWijbrans et al. (1995). The J values
(irradiation pa-rameter) were calculated by measuring replicate
stan-dards from dierent locations within the tablets and
thecontainers and by ®tting a function through the datapoints,
respectively. Ages were calculated using thedecay constants
recommended by Steiger and JaÈ ger(1977). The quoted errors on the
ages (2r) includethe uncertainty on the irradiation parameter J,
theuncertainty on the mass spectrometric analyses of the
Arintensities, errors on the blanks and the mass interfer-ences of
radiogenic Ar with Ar derived from K, Ca andCl. The uncertainty of
a plateau age is calculated fromthe uncertainties of the individual
steps, using the in-verse variance of the 40Ar/39Ar ratios as a
weightingfactor.
Incremental heating experiments were performed byprogressively
degassing the sample grains using a defo-cused laser for 60 s at
successively greater laser powerincrements. System blanks were
measured before the®rst experiment and every ®fth analysis
thereafter.The blank correction applied to each sample usedthe
blank integrated over the time of sampleanalyses. Typical system
blanks were 3.92±6.63 ´ 10)17,5.18±8.91 ´ 10)19, 8.91±33.7 ´ 10)20,
2.61±3.23 ´ 10)18and 5.87±12.6 ´ 10)19 mol for masses 40, 39, 38,
37 and36, respectively. Spot fusion experiments on biotite
andK-feldspar in sample sections were performed using a2 W laser
beam focused at 20 lm for approximately 2 s in0.5 s pulses. System
blanks were measured before eachsample and every third analysis
thereafter. Typical systemblanks were 0.93±2.21 ´ 10)16, 1.03±1.60
´ 10)18, 7.59±8.02 ´ 10)19, 1.78±3.13 ´ 10)18 and 1.61±1.78 ´
10)18mol for masses 40, 39, 38, 37 and 36, respectively.
40Ar/39Ar ages
The results of incremental heating and spot fusion ex-periments
are given in Table 4. Representative agespectra obtained by
incremental heating on hornblende,biotite and K-feldspar are shown
in Figs 5, 6 and 7,respectively. Age plateaus are de®ned by at
least threeconsecutive steps that overlap at the 95% con®dencelevel
(exclusive of uncertainty in J) and together containat least 50% of
the 39ArK released by the sample. All
samples were additionally examined on inverse isochrondiagrams
(36Ar/40Ar vs 39Ar/40Ar), in which the age isgiven by the intercept
on the 39Ar/40Ar axis and thecomposition of any trapped
non-radiogenic argon by theintercept on the 36Ar/40Ar axis. In
principle, the inverseisochron approach allows to determine whether
thetrapped argon is air-derived and/or excess argon.However,
because the samples analysed here are fairlyold and potassium-rich
(except for hornblende), most ofthe data plot on or near the
39Ar/40Ar axis. Therefore,the 36Ar/40Ar intercepts have large
uncertainties andgive little information on initial ratios. The
ages given bythe 39Ar/40Ar intercepts generally coincide with
theplateau and total fusion ages (Table 4).
Hornblende from three dierent locations (Fig. 1,Table 4) was
analysed by incremental heating experi-ments. The separates yield
plateau ages between321.9 3.3 and 313.7 3.7 Ma (Table 4). Within
er-ror limits, there is good agreement between the plateauages and
the integrated total fusion ages (Table 4). Thedierent plateau ages
are not related to dierent samplelocations as almost the entire
range of ages is displayedby hornblende from location 4 (315.6 3.5
to321.9 3.3 Ma, Fig. 5). A common characteristic ofthe hornblende
age spectra is that the ®rst, usually verysmall, heating step
released argon with apparent agesthat are considerably higher or
lower than the plateauages. The contribution of air argon in these
®rst steps ofincremental heating is comparatively large and the
de-viation of the apparent ages is most likely induced bythe
release of argon trapped on cracks or cleavageplanes.
Biotite from all locations was analysed by incremen-tal heating
experiments on one or two grains, respec-tively. The obtained
plateau ages range between309.6 3.5 and 313.2 3.2 Ma (Fig. 6) and
coincidewith the integrated total fusion ages within error
limits.Most spectra are characterised by very even plateauswith
minor age deviations only in the ®rst heating steps.As for
hornblende, there are no signi®cant age dier-ences between the
locations as the values overlap withinerror limits. Additionally,
total fusion ages of singlebiotite grains from sample sections were
obtained forsome of the locations (Table 4). Garnet zoning
patternsrevealed that the inner cores of large garnets record
theoldest metamorphic stage (Kalt et al. 1999). Therefore,biotite
inclusions in garnet were analysed by spot fusionexperiments and
their mean ages were calculated sepa-rately from those obtained on
matrix biotites (Table 4).However, no signi®cant age dierence
between biotitefrom these two dierent textural positions is
recognis-able in any sample, and the mean spot fusion agescoincide
with those obtained by incremental heating inevery sample (Table
4). The spread in ages obtained byspot fusion experiments on single
grains from samplesections is inmost cases large, expressed by
large errors onthe mean ages (Table 4). This is probably because
biotitegrains were often rather small and some of the gas mayhave
come from adjacent minerals or grain boundaries.
11
-
Table
4Resultsof40Ar/39Ardating
Location
Sample
Mineralproperties
aIncrem
entalheating
Inverse
isochron
Spotfusion
J
nb
MSWD
39Ar
[%]c
PLdage
[Ma]
+/)
[2r]e
TFfage
[Ma]
+/)
[2r]e
nb
MSWD
40Ar/36Ar
intercept
+/)
[2r]e
Age
[Ma]
+/)
[2r]e
ng
Ageh
[Ma]
+/)
[2r]i
1BW-22
bt,250±500
lm[2]
10
1.8
100.0
311.7
3.2
311.0
5.4
10
0.7
170.7
48.9
313.0
3.0
0.006161
BW-28
bt,in
matrix
6306.2
6.1
0.005569
2BW-30
bt,250±500
lm[2]
11
2.4
96.8
311.6
3.5
310.3
5.7
11
2.4
173.0
174.5
312.4
5.5
0.006160
BW-32
bt,incl
ingrt
5313.6
1.8
0.005427
BW-32
bt,in
matrix
3314.8
4.8
0.005427
BW-67
bt,incl
ingrt
8312.2
7.9
0.005259
BW-67
bt,incl
ingrt
1311.4
1.6
0.005259
BW-67
Kfs,250±500
lm[1]
10
109.2
100.0
299.3
j2.9
292.2
2.9
10
109.2
)1099.5
1785.5
302.6
10.25
0.005259
BW-67
Kfs,250±500
lm[1]
10
203.2
299.9
300.0
j2.9
291.7
2.9
9271.6
949.4
*k
285.9
224.91
0.005259
386246
bt,250±500
lm[1]
50.5
99.7
312.0
3.1
312.1
3.9
50.4
330.0
145.6
311.9
3.2
0.006097
86246
bt,250±500
lm[2]
70.3
96.0
312.6
6.2
308.2
24.8
11
0.5
181.3
346.1
313.7
4.9
0.006160
4BW-132
bt,250±500
lm[3]
81.3
99.1
309.6
3.9
311.0
8.9
90.03
40771.1
*267.2
311.4
0.006161
BW-132
hbl,125±250
lm[60]
10
3.1
97.7
321.9
3.3
323.6
4.1
11
5.6
453.2
124.5
314.6
9.4
0.004425
BW-134
hbl,125±250
lm[60]
81.0
100.0
319.1
3.0
318.8
3.6
80.9
271.7
29.5
319.5
3.0
0.004425
BW-134
hbl,125±250
lm[60]
811.8
99.1
315.6
3.5
315.4
3.6
12
8.0
267.3
199.8
316.4
7.5
0.004425
5BW-118
hbl,125±250
lm[60]
91.8
98.4
313.7
3.7
316.3
7.2
10
3.3
358.6
75.9
308.8
9.6
0.004425
BW-120
bt,250±500
lm[2]
50.3
92.5
311.8
3.0
310.8
3.7
61.7
159.2
45.7
312.4
3.1
0.006097
BW-120
Kfs,250±500
lm[1]
945.8
82.8
296.4
3.0
296.3
3.2
10
14.5
878.3
1816.2
291.5
20.2
0.006136
6BW-112
hbl,125±250
lm[60]
95.4
98.8
320.3
3.2
318.9
3.5
10
18.2
119.3
190.4
322.6
8.3
0.004425
BW-116
bt,250±500
lm[3]
40.7
69.6
309.7
4.3
303.6
11.4
81.7
138.3
93.1
311.2
4.6
0.006161
BW-116
Kfs,250±500
lm[1]
720.3
87.7
305.3
3.8
306.9
3.3
82.2
2424.7
2390.5
296.9
13.0
0.006136
7BW-44
bt,in
matrix
8315.8
10.8
0.005364
BW-44
bt,incl.in
Kfs
2306.2
2.9
0.005364
BW-44
Kfs,250±500
lm[1]
11
24.1
84.3
305.1
3.6
307.2
3.2
12
14.0
518.8
358.9
302.8
11.2
0.005364
BW-46
bt,250±500
lm[2]
80.8
100.0
313.2
3.2
313.0
5.3
80.7
172.6
92.8
314.5
3.3
0.006097
BW-46
bt,250±500
lm[2]
12
1.7
100.0
311.5
3.7
312.1
8.7
12
1.6
108.2
119.7
314.4
3.5
0.006161
BW-46
Kfs,250±500
lm[1]
92.8
96.5
319.7
3.1
318.4
3.4
12
0.2
20010.0
*269.5
70.1
0.006136
BW-46
Kfs,250±500
lm[1]
32.3
84.0
317.8
3.1
318.0
3.3
95.7
3047.0
*297.6
39
0.006136
BW-90
bt,in
matrix
4316.6
2.8
0.005154
BW-90
bt,incl.in
grt
7302.0
13.9
0.005154
aMineralabbreviationsaccordingto
Kretz
(1982);incl.,inclusion;[1],number
ofgrains
bnnumber
ofheatingstepsincluded
intheplateauagecalculation
cPercentageof39Arincluded
intheplateauagecalculation
dPL
Plateau
eQuotederrors
includetheuncertainty
ontheirradiationparameter
J,theuncertainty
onthemass
spectrometricanalysesoftheArintensities
(includingerrors
ontheblanks),themass
interferencesofradiogenic
ArwithArderived
from
K,CaandClandtheerrorontheweightedmeanoftheindividualsteps(D
alrymple
andLanphere1971)
fTFTotalfusion
gnNumber
ofsingle
grainsanalysed
hMeanagecalculatedfrom
thetotalfusionages
ofsingle
grains
iStandard
deviationofthemeanage
jApparentageofthe®nalheatingstep
(noplateauagecould
becalculated)
kAsteriskindicateserrortoolargeto
beadequately
displayed
12
-
Spot fusion ages of K-feldspar from sample sectionscould not be
obtained. It was not possible to fuse thespots by hitting them with
the focused laser beam forseveral seconds. As longer laser
treatment would havethermally activated other parts of the section,
the spotfusion experiments on K-feldspar were not
continued.K-feldspar was broken from the sections and fragmentsof
grains were then analysed by incremental heatingexperiments.
Incremental heating experiments wereperformed on single K-feldspar
fragments from loca-tions 1, 5, 6 and 7 (Table 4). In general, the
age spectraobtained from K-feldspar are not as even as those
ofbiotite and hornblende (Fig. 7). Plateau ages that in-clude more
than 80% of the released Ar and that coin-cide with the integrated
total fusion ages could becalculated for samples BW-44, BW-46 and
BW-116. Fora K-feldspar of sample BW-120, a plateau age
includingonly 60% of the released Ar, but coinciding with
theintegrated total fusion age, could be calculated. The
twoK-feldspars of sample BW-67 are characterised by a
gentle staircase-like increase in apparent ages and by thelack
of plateaus. The integrated ages are in goodagreement with the
total fusion ages for each sample,whereas the apparent ages of the
®nal degassing step areslightly higher (Table 4). The K-feldspar
plateau ages(ages of the ®nal degassing step for sample BW-67)
formtwo distinct groups: K-feldspars from locations 2, 5 and6 have
ages of 299.3 2.9, 300.0 2.9, 296.4 3.0and 305.3 3.8 Ma, the latter
being identical to an ageof 305.1 3.6 Ma of one K-feldspar from
locality 7.Two other K-feldspars from location 7 have consider-ably
higher ages of 319.7 3.1 and 317.8 3.1 Ma.
Signi®cance of mineral ages and link to the P±T path
U±Pb zircon ages
Microstructural data and modes show the leucosomes ofmigmatites
from the Bayerische Wald to have either been
Fig. 5a±c Results of incremental heating experiments of
horn-blende separates from amphibolite samples BW-132 (a),
BW-134(b) and BW-112 (c). Errors are given at the 2r level. For
furtherexplanation see section on 40Ar/39Ar dating
Fig. 6a±c Results of incremental heating experiments of
biotitefrom migmatite samples BW-22 (a), BW-120 (b), and BW-46
(c).Errors are given at the 2r level. For further explanation see
sectionon 40Ar/39Ar dating
13
-
pure melt (Qtz±Kfs leucosomes) or melt and residualcrystals
(Plg±Qtz±Kfs leucosomes, Berger and Kalt1999). Therefore, the
analysed zircon tips from the leu-cosomes must have coexisted with
melt at some stage.The euhedral shapes of the zircons strongly
suggest thatthe tips grew during HT±LP metamorphism by
precipi-tation from a melt. This interpretation is supported bythe
fact that most crustal lithologies contain a sucientamount of
zirconium (Zr) and light rare earth elements(LREE) to saturate a
melt in these components and allowprecipitation of accessory phases
such as zircon andmonazite (see Watt and Harley 1993 for a
discussion).The case may be dierent in small-volume
disequilibriummelts (Sawyer 1991), but estimates of former melt
volumefractions in migmatites of the Bayerische Wald yieldvalues of
20±40% (Berger and Kalt 1999). The core-rimstructures of zircon
grains visible under the binocularmicroscope probably represent
residual zircons that wereentrained in the partial melt formed
during HT±LP
metamorphism, partly dissolved and later overgrownduring zircon
precipitation. Hence, the concordant U±Pbages of the zircon tips
must be crystallisation ages asopposed to resetting ages. The ages
do not record cool-ing. This interpretation is generally accepted
for zircons,based on low diusivities for U, Pb and Th (Cherniaket
al. 1997; Lee et al. 1997) and very high closure tem-peratures for
Pb in zircon (Lee et al. 1997), implying thatvolume diusion is not
the dominant process for Pb lossin zircon (Mezger and Krogstad
1997).
Zircon incorporates large amounts of incompatibleelements (Zr,
Hf, Y, U, LREE, e.g. Hanchar and Miller1993). In the metapelitic
migmatites of the BayerischeWald, these incompatible elements
became available assoon as in situ melting started during prograde
stage Bdehydration reactions through the dissolution of
existingzircon (Watson 1996). The numerical simulations ofWatson
(1996) show that diusion-controlled zircondissolution in melts of
granitic composition at increasingtemperatures is a continuous
process whereby dissolu-tion rates increase exponentially with
temperature in therange 650±850 °C. Diusion-controlled zircon
growth ingranitic melts is also favoured by increasing tempera-
Fig. 7a±f Results of incremental heating experiments of
K-feldsparfrom migmatite samples BW-67 (a), BW-120 (b), BW-116 (c),
BW-44(d) and BW-46 (e±f). Errors are given at the 2r level. For
furtherexplanation see section on 40Ar/39Ar dating
14
-
tures (Watson 1996). Therefore, the zircon tips used fordating
here should re¯ect growth beginning at peakmetamorphic conditions,
estimated to be about 850 °C(Kalt et al. 1999), down to
temperatures at which allmelt crystallised. This was at the end of
stage B andduring stage C (Fig. 1). Experiments in metapelitic
sys-tems indicate 800 °C as approximate minimum temper-ature for
biotite dehydration melting (e.g. Le Breton andThompson 1988;
Vielzeuf and Montel 1994) and ther-mobarometry on subsolidus stage
D phase assemblagesyields 770±846 °C as a minimum temperature for
meltcrystallisation in migmatites of the Bayerische Wald(Kalt et
al. 1999). Therefore, the U±Pb ages of zircontips date a minimum
temperature of approximately800 °C. This temperature is still below
common esti-mates of Pb closure temperature and thus supports
theinterpretation as crystallisation ages (Lee et al. 1997).
U±Pb monazite ages
In general, the interpretation of U±Pb ages is not
asstraightforward for monazites as it is for zircons
becausemonazite closure temperatures for U, Th and Pb are stilla
matter of debate. Comparatively high temperatures of³750 °C are
suggested by experimental diusion data(Smith and Giletti 1997) and
crystal-chemical consider-ations (Dahl 1997). Slightly lower
minimum estimates of680±720 °C emerge from the presence of
inherited mo-nazites in leucogranites (Copeland et al. 1988;
Kings-bury et al. 1993; Harrison et al. 1995), from
partialresetting of monazites at amphibolite-facies
conditions(Parrish et al. 1990) and from electron microprobe
ana-lyses of zoned monazites (Suzuki et al. 1994). However,slow
diusion velocities, the preservation of radiogeniclead in inherited
monazite grains from magmatic andmetamorphic rocks and postmagmatic
monazite re-crystallisation (Hawkins and Bowring 1997) argue
thatrecrystallisation rather than volume diusion controlsthe U±Pb
systematics of monazite. This view is alsosupported by the presence
of very sharp boundaries inline scans of Th, U and Pb across
granulite-facies mo-nazites (Zhu and O'Nions 1999). Peak
metamorphictemperatures in migmatites of the Bayerische Wald
areabove some of the assumed U±Pb closure temperaturesfor monazite.
However, a number of observations sug-gests that the obtained U±Pb
monazite ages re¯ectcrystallisation and inheritance rather than
monazite re-setting and/or cooling through a closure
temperature.
The euhedral shape of the monazites from leuco-somes suggest
that at least their rims record growth inthe presence of a melt and
not resetting of older crystals.The presence of excess 206Pb (see
section on U±Pb dat-ing) in monazites from leucosomes and mesosomes
is thestrongest argument for the monazite ages
re¯ectingcrystallisation. If resetting of older monazites by
diu-sion had occurred during HT±LP metamorphism, thisdisequilibrium
eect would not have been preserved.Both mesosome samples (BW-70 and
BW-90) contain
simple, euhedral to subhedral inherited monazite grainswith
distinctly higher ages (Figs 2b, 3b). In mesosomeBW-70, the
inherited monazite was included in earlygrown garnet that shielded
it from recrystallising ordissolving in a partial melt during HT±LP
metamor-phism. This eect was described by DeWolf et al. (1993)for
monazites from the high-grade core of the WindRiver Range, Wyoming.
In mesosome BW-90, the mo-nazite carrier phase is not known. The
rest of themonazites from the mesosome of sample BW-70 clusteron
concordia due to the absence of inherited monazitedomains, while
those from the mesosome of sampleBW-90 show a scatter that can be
best explained byinheritance of older concordant monazites.
The U±Pb systematics of monazites from migmatiteBW-116
(leucosome and mesosome could not be sepa-rated) most clearly
reveal the eects of inheritance(Fig. 4). Three concordant grains
with ages between 323and 337 Ma as well as one slightly discordant
graindemonstrate that monazite crystallised at 322.9 1.8 Ma during
HT±LP metamorphism may containvarying proportions of older monazite
with either undis-turbed or partially reset U±Pb systems. Monazites
ofsample BW-120 reveal a simpler picture (Fig. 4a) and arebest
interpreted as re¯ecting crystallisation withoutinheritance. Future
study on monazite composition mayhelp to distinguish inherited and
newly crystallised parts.
In summary, the monazite U±Pb data reveal crys-tallisation at
the same time as the precipitation of zirconfrom partial melts and
must hence record virtually thesame minimum temperature of
approximately 800 °C.Monazites in all samples except BW-120 show
inheri-tance of older monazite to varying degrees. The fact
thatthese older monazites survived metamorphic conditionsand
partial melting at temperatures of approximately850 °C places new
constraints on the U±Pb closuretemperature of monazite. There is a
slight trend towardshigher U±Pb ages of zircon and monazite from
thenorthwestern area around Cham. Considering the factthat the
monazites from all samples are eected byvariable degrees of
inheritance of older grains, it ispossible that the slightly higher
U±Pb monazite agesfrom the northwestern area re¯ect inheritance.
However,zircon tips that should be free of inherited componentsare
also older in the northwestern area, suggesting thatthe age
dierence is geologically meaningful. The veryyoung U±Pb age of 317
Ma for one monazite grain ofsample BW-70 cannot be reasonably
explained at themoment. Perhaps it is due to local late-stage
hydro-thermal features, although a U±Pb isotope study
onhydrothermally treated monazites suggests that mona-zite becomes
discordant due to lead loss under theseconditions (Teufel and
Heinrich 1997).
U±Pb titanite ages
Several U±Pb dating studies document that titanite mayremain
closed to Pb diusion at elevated temperatures,
15
-
may be reset during later metamorphism or may re-crystallise
even at low temperatures (Corfu and Grunsky1985; Corfu et al. 1994;
Corfu 1996). Other studiessuggest that while at temperatures above
700 °C titaniteis aected by Pb diusion, recrystallisation is the
dom-inant process below approximately 700 °C (Scott and St-Onge
1995; Verts et al. 1996). Calculations of U±Pbclosure temperatures
from magmatic titanite with in-herited Pb components yield minimum
estimates of712 °C (Zhang and SchaÈ rer 1996). These estimates
co-incide quite well with calculations from diusion ex-periments
(Cherniak 1993). As titanite in theamphibolites of the Bayerische
Wald is not only in-cluded in amphibole but also in plagioclase
that wasformed during earlier granulite-facies metamorphism, itmost
likely crystallised at temperatures (850 °C) con-siderably
exceeding any estimates of closure tempera-ture. Thus, the U±Pb
ages of titanites most likely do notrecord crystallisation but
cooling to temperatures ofapproximately 700 °C.
40Ar/39Ar ages
Diusion of Ar in amphibole, biotite and K-feldspar
iscomparatively fast, even at fairly low temperatures (e.g.Baldwin
et al. 1990; Lovera et al. 1991; Dahl 1996 andreferences therein).
As in many metamorphic terranesthe attained peak temperatures are
considerably higherthan the closure temperatures calculated from
the Ardiusion velocities, K-Ar and 40Ar/39Ar ages of am-phibole,
biotite and K-feldspar can be interpreted ascooling ages, provided
that thermally induced volumediusion according to Fick's Law is the
dominatingprocess and that the minerals did not form below
theirclosure temperatures. There are also other mechanismsof Ar
loss or exchange such as ¯uid- or deformation-assisted
recrystallisation (e.g. Wijbrans and McDougall1986; Villa 1998;
Parsons et al. 1999), but these mainlyapply to Ar-bearing minerals
that were substantiallyaected by hydrothermal overprint
(metamorphism)and/or deformation after their crystallisation.
Thesecomplex histories usually result in disturbed Ar spectra.In
the Bayerische Wald, migmatites and amphibolitesexperienced one
single HT-metamorphic event, peakmetamorphic temperatures
approximated 850 °C, theinvestigated rocks and minerals were not
subject to late-stage ¯uid- or deformation-assisted
recrystallisation (seesections on geological setting and on
characteristics ofthe phases), and apart from two feldspars, all
analysedAr-bearing minerals yielded good plateaus (Figs.
5±7).Therefore, it seems reasonable to interpret the 40Ar/39Arages
as recording cooling below closure temperatures.
For amphiboles it has been discussed whether the Arretentivity
and thus the closure temperatures depend oncomposition. Whereas
several geochronological studiesindicated the possibility of a
compositional dependence(e.g. O'Nions et al. 1969; Berry and
McDougall 1986;Onstott and Peacock 1987), experimental
determination
of Ar diusion velocities in metamorphic hornblendeshowed no
correlation between XMg and activation en-ergy (Baldwin et al.
1990). On the basis of the ionicporosity model of Fortier and
Giletti (1989), Dahl(1996) argued that there should be dierences in
closuretemperature due to compositional eects, but that
thesecompositional eects would probably become lostwithin
analytical uncertainty once the cooling rate ex-ceeded 10 °C/my.
The amphiboles examined here byincremental heating experiments are
magnesio-horn-blende (BW-112), edenitic hornblende (BW-134)
andactinolitic hornblende (BW-118, BW-132). The calcula-tions of
Dahl (1996) suggest that pure edenite shouldhave higher closure
temperatures (600±520 °C) thanpure ferro-actinolite (440±470 °C) at
cooling rates of10±100 °C/my, which are realistic for the
BayerischeWald (see section on cooling rates). This
compositionaleect cannot be seen in the 40Ar/39Ar hornblende
totalfusion ages obtained here (Tables 2 and 4), because
theinvestigated amphiboles have intermediate, but notendmember
compositions. Magnesio-hornblende andedenitic hornblende (320.3
3.2, 319.1 3.0,315.6 3.5 Ma) do not yield signi®cantly higher
agesthan actinolitic hornblende (321.9 3.3, 313.7 3.7 Ma).
Therefore, combining the hornblende compo-sitions of the samples
with the ionic porosity model ofDahl (1996), it can be assumed that
the hornblende agesobtained record cooling of the amphibolites
belowapproximately 500±570 °C.
As for amphibole, it has been discussed whether theclosure
temperatures of biotite may vary with compo-sition. Whereas
Harrison et al. (1985) found a negativecorrelation between XMg and
activation energy for thediusion of 40Ar* in their experiments,
hydrothermaldegassing experiments (Grove and Harrison 1996)yielded
nearly identical results for Fe-rich biotite(XMg 0.26) and biotite
of intermediate composition(XMg 0.47). Instead it was suggested
that high halogencontents may increase Ar retentivity. Applying
single-domain volume diusion models for argon transport inbiotite
of intermediate composition and assuming geo-logically reasonable
cooling rates yields closure tem-peratures between 310 and 345 °C
(Harrison et al. 1985;Grove and Harrison 1996 and references
therein).
The halogen contents of the biotite grains investi-gated in this
study are not known. The XMg values rangefrom 0.32 (BW-116) to 0.70
(BW-132). No systematicrelationship between XMg value and age can
be recog-nised (Tables 2 and 4). Moreover, all biotite ages
coin-cide within error limits. Therefore, the obtained Ar±Arages
are interpreted to record cooling of the samplesbelow approximately
310±345 °C.
The Ar diusion systematics of K-feldspar are gen-erally more
complicated than those of micas and horn-blende, and many 40Ar/39Ar
spectra obtained byincremental heating are rather complex. While
earlierstudies suggested that many K-feldspars may not bereliable
geochronometers due to the continuous loss of40Ar* at low
temperatures and the incorporation of
16
-
excess argon (e.g. Faure 1977), increasing knowledge onthe
transport behaviour of argon in feldspars has con-siderably
increased the ability to extract geologicallymeaningful ages (see
Harrison and McDougall 1982;Lovera et al. 1989; Foster et al. 1990
and referencestherein). Further studies indicated that the
apparentlyanomalous 40Ar/39Ar spectra of K-feldspar re¯ect
thepresence of diusion domains of variable length scales(e.g.
Zeitler 1987; Lovera et al. 1989; Foster et al. 1990;Fitz Gerald
and Harrison 1993; Lovera et al. 1993) andthat this behaviour can
be modelled by assuming a dis-crete distribution of non-interacting
domains of variablesize (Lovera et al. 1989). The resulting closure
temper-atures for K-feldspar span up a range between 150 and300 °C.
Recent studies of alkali feldspar microtextures(Parsons et al.
1999) provide a critical view of the mul-tiple diusion domain
theory. They suggest that deut-erically altered zones formed by
¯uid±feldspar reactionsat temperatures below 500 °C provide fast
pathways forAr that will be metastable in step-heating
experiments.However, the study being performed on very
slowlycooling, strongly zoned crystals that reacted with ¯uid,its
implications are not necessarily applicable to otherrocks.
Most of the above studies and considerations applyto 40Ar/39Ar
spectra of K-feldspar that do not showplateaus but saddle- or
U-shaped spectra, gradients orspectra with two plateau segments
(Foster et al. 1990).Most of the K-feldspars analysed in this study
showbroad plateaus with the exception of the ®rst few steps
ofincremental heating that mainly have lower, but some-times also
higher apparent ages (Fig. 7). The fact thatthe domains with
anomalous behaviour are degassedduring the low-temperature steps
suggests that thesedomains are either located near crystal
surfaces, cleav-age planes or cracks and may correspond to
alteredmaterial. Considering a closure temperature between150 and
300 °C for K-feldspar, the plateau ages of296.4 3.0 Ma (BW-120),
305.3 3.8 Ma (BW-116)and 305.1 3.6 Ma (BW-44) ®t very well to the
coolingages obtained from hornblende and biotite (see aboveand
Table 4). K-feldspars from sample BW-67 do notyield plateaus, but
show increasing apparent ages fromapproximately 280 to 300 Ma, the
®nal degassing stepsyielding ages (299.3 2.9, 300.0 2.9 Ma, Table
4) inagreement with the plateau ages of samples BW-116,BW-120 and
BW-44. The rimward decrease in age maybe explained by loss of 40Ar*
or by progressive closureof the Ar system down to very low
temperatures duringslow cooling.
In contrast, the two K-feldspar ages of 319.7 3.1and 317.8 3.1
Ma (BW-46) from location 7 are sig-ni®cantly higher than the
biotite ages from the samelocation. Moreover, another K-feldspar
grain from thesame location yields a plateau age of 305.1 3.6
Ma(BW-44). Therefore, the age dierence between thegrains cannot be
due to dierent cooling rates at thevarious locations but must
re¯ect either loss of 40Ar*from the apparently younger grains, or
incorporation of
excess argon by the apparently older grains, or dierentAr
retentivities of the K-feldspars. Loss of 40Ar* is notapparent from
the spectrum of the feldspar from BW-44and, moreover, its plateau
age agrees with those fromsamples BW-116 and BW-120 (see above).
All horn-blende and biotite data and the other K-feldspar
datarepresent an internally consistent set, suggesting
thatincorporation of excess argon is not a problem in
theserocks.
Dierent Ar retentivities are the best explanation forthe high
ages. They could result from dierent structuralstates of
K-feldspars. However, as all the K-feldspars arechemically and
structurally very similar, we expect thediusion parameters to be in
the same range. Therefore,it is suggested that the eective diusion
radii of thedominant subgrains in the two K-feldspars of
sampleBW-46 are substantially larger than those of the
otherK-feldspars. Another possible reason for the elevatedAr±Ar
ages of the two K-feldspars is that they containnumerous inclusions
of plagioclase. Whereas K-feldsparmost likely crystallised from
melt produced during de-hydration melting reactions, plagioclase
could partlyrepresent an older stage of metamorphism as indicatedby
residual plagioclase crystals in some leucosomes(Berger and Kalt
1999). This hypothesis is supported bypartly low K/Ca ratios (9±87)
obtained during the in-cremental heating experiments on feldspars
of sampleBW-46 compared to signi®cantly higher K/Ca ratios inall
other analysed K-feldspars.
In conclusion, most of the analysed K-feldspar grainsyield
plateau ages or apparent ages of the ®nal stepsbetween 296 and 305
Ma. These ages ®t well with thoseobtained from biotite and
hornblende at the same oradjacent localities and probably record
cooling below150±300 °C. Staircase patterns may record closure of
theAr system down to lower temperatures, and older pla-teau ages of
318±320 Ma most likely re¯ect diusiondomains with higher closure
temperatures.
Cooling rates, duration of metamorphismand possible heat
sources
As discussed in the previous sections, U±Pb zircon andmonazite
ages are interpreted to re¯ect crystallisationfrom a melt at
approximately 800 °C. For the north-western area, mean leucosome
and mesosome monaziteages of 325.3 and 326.1 Ma are considered to
date thistemperature, although uncertainty remains about
in-heritance problems. U±Pb titanite ages are interpreted ascooling
below 700 °C and 40Ar/39Ar ages of hornblendeand biotite are
considered to re¯ect cooling below 500±570 and 310±345 °C
respectively. Most K-feldsparsprobably record cooling below 150±300
°C. Two feld-spar grains from location 7 (BW-46) most likely
havehigher closure temperatures and are excluded in thefollowing.
Taking the mean ages for the minerals andaverage cooling ages,
cooling paths can be constructedfor the southeastern area around
Bodenmais (locations
17
-
1±5) and for the northeastern area around Cham (lo-cations 6±7;
Fig. 8).
The two cooling paths are quite similar, although theclosure
temperatures of the K-feldspars and hence thelow-temperature part
of the paths are not well-con-strained. Both paths are
characterised by rapid cooling inthe high-temperature range and a
non-linear decrease inthe cooling rate towards lower temperatures.
Consideringan age dierence of approximately 1 million years
be-tween zircon andmonazite ages and titanite ages from
thesoutheastern area, cooling rates must have been in theorder of
100 °C/my. Further cooling down to the horn-blende closure
temperature is characterised by a rate ofapproximately 58 °C/my.
For the northwestern area, notitanite ages are available. An
average cooling rate ofabout 46 °C/Ma can be calculated for the
temperaturespan between 800 °C and hornblende closure tempera-ture.
The samples further cooled down to the biotiteclosure temperature
at rates of approximately 16 °C/my(southeastern area) and 11 °C/my
(northwestern area).Considering the average K-feldspar age of 300
Ma(excluding sample BW-46) to be geologically meaningful,the
further cooling rate is 1±17 °C/my. In summary,cooling from 800 to
150±300 °C lasted approximately20±30 my, provided that exhumation
was a continuousprocess.
Ideally, in order to constrain possible external heatsources and
mechanisms of heat input, not only thecooling rates but also the
timing of the peak and pro-grade parts of the P±T path should be
known. The onlymineral that potentially records all three parts of
theP±T path is garnet. Biotite included in garnets does notyield
ages signi®cantly older than those of biotite in thematrix. The
monazite that is preserved in a garnet corerecords older ages than
those in the matrix. However,
this places no time constraints on prograde or peakmetamorphism
as the age is not known precisely enoughand as it may record either
metamorphism of the hostrock or detrital inheritance or a
combination of the two.More data are needed to test whether the
obtained age isrepresentative and reproducible.
The zoning patterns of some very large garnets(5 mm diameter),
particularly their bell-shaped Mnpro®les, and their inclusion
relations indicate thatgrowth of these garnets started at prograde
conditions(Kalt et al. 1999, their Fig. 6a). Chakraborty andGanguly
(1991) have examined the extent of relaxationof initial garnet
zoning patterns in relation to grain-size,time and diusion
coecients. Their model calculationsfor Mn (their Fig. 13) predict
that an initially growth-zoned garnet of 5 mm diameter would have
beenhomogenised with respect to Mn by diusion if tem-peratures of
850 °C (the estimated peak temperature formigmatites of the
Bayerische Wald) prevailed longerthan approximately 2.5 million
years. As there are manyuncertainties in this calculation (the
initial zoning pat-tern is not known, processes other than diusion
mayhave contributed to the zoning pattern, the ®xed edgecomposition
assumed in the calculations may not bevalid), the result may just
be taken to indicate the orderof magnitude for the maximum duration
of peak meta-morphic conditions. A short heating period ®ts well
withthe survival of older monazite grains and with thecore-rim
structures of zircon grains that also suggestinheritance. No time
information can be gained on theprograde part of the P±T path.
As reasoned above, the T±t path of the BayerischeWald is
characterised by a short thermal peak and ex-ponentially decreasing
cooling rates. As stated in