Henrik Udesen ‐ Haldor Topsøe A/S 16th IMPCA 2013 Asian Methanol Conference TIGAS Topsøe’s Improved Gasoline Synthesis 30 October - 1 November 2013 Shangri-La Hotel, Singapore Henrik Udesen Topsøe s Improved Gasoline Synthesis Presentation outline Brief introduction to TIGAS history Techncial features Marked considerations Round off
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Henrik Udesen ‐ Haldor Topsøe A/S16th IMPCA 2013 Asian Methanol Conference
TIGASTopsøe’s Improved Gasoline Synthesis
30 October - 1 November 2013
Shangri-La Hotel, Singapore
Henrik Udesen
Topsøe s Improved Gasoline Synthesis
Presentation outlineBrief introduction to TIGAS history
Techncial features
Marked considerations
Round off
Henrik Udesen ‐ Haldor Topsøe A/S16th IMPCA 2013 Asian Methanol Conference
Topsøe’s process for production of gasoline
T GASIT GASINatural Gas, Coal, Biomass or Waste to
Clean Transportation Fuels
Topsøe is the world’s leading supplier of catalyst and catalytic based technologies
Supply of thousands of catalyst charges for more than 70 yearsExperience reliability and combination ofExperience – reliability and combination of catalyst & technology in both refinery and synthesis gas areas
Design and license of large plants:– >300 Ammonia plants and revamps
Henrik Udesen ‐ Haldor Topsøe A/S16th IMPCA 2013 Asian Methanol Conference
Demonstration plants2 atm (Air)
GasolineSynthesis
Gas Cleaning
MeOH/DMESynthesis
23 bbl/d
The choice of technologyFeed Front-end
TubularReformingNatural gas
ProductPolishing
Gasoline Synthesis
Crude gasoline
Regular gasoline
AutothermalReforming
Heat ExchangeReforming
Two-stepOxygen-fired
ReformingShale gas
Associated gas
Coal
Gasoline Synthesis(STG)
Methanol loop+
Gasoline Synthesis(MTG)
GasificationBio mass
Henrik Udesen ‐ Haldor Topsøe A/S16th IMPCA 2013 Asian Methanol Conference
Gasoline Synthesis (MTG)
Fractionation
Henrik Udesen ‐ Haldor Topsøe A/S16th IMPCA 2013 Asian Methanol Conference
GSK – 10 References
References G li S th i C t l t GSK 10Gasoline Synthesis Catalyst, GSK-10
Customer Capacity Start-up date China Qinghua I, Inner Mongolia 100,000 MTPY Febuary 2012 Qinghua II, Inner Mongolia 100,000 MTPY July 2013 Xinjiang, Zhongji 50,000 MTPY January 2013 Xinjiang Xinye Energy, Xinjiang 100,000 MTPY Exp. 2013 Hebei Kanglida Steel, Hebei 50,000 MTPY Exp. 2014
TIGAS process lay-out
Fuel gas
Gasolinereactors
LPG
Separator
Processcondensate
De-ethaniser LPG splitter
GUU Gasoline
Henrik Udesen ‐ Haldor Topsøe A/S16th IMPCA 2013 Asian Methanol Conference
GUU (Gasoline Upgrade Unit)
SPECIFICATIONS FOR GASOLINE (UNLEADED PETROL)
Property UnitsTopsoe TIGAS
range
European specifications EN 228:2008 (Euro 5)
European specifications
EN 228:2008 (Euro 5)
Research Octane Number, RON >93 Min 95Motor Octane Number, MON >83 Min 85Motor Octane Number, MON 83 Min 85Lead content mg/l nil Max 5Density at 15oC (equivalent to SG 60/60oF) kg/m3 730 720-775Sulfur content wt ppm nil Max 10Oxidation stability minutes Min 360Existent gum content (solvent washed) mg/100 ml Max 5Copper strip corrosion (3 h at 50 oC) rating class 1Hydrocrabon type content olefins vol% 5-15 Max 18 aromatics vol% 30-35 Max 35Benzene content vol% Max. 1 Max 1Oxygen content wt% nil Max 2.7Oxygenates content methanol vol% Max 3 ethanol vol% Max 5 isopropyl alcohol vol% Max 10 isobutyl alcohol vol% Max 10 tertbutyl alcohol vol% Max 7 ethers (5 or more C atoms) vol% Max 15 other oxygenates vol% Max 10Distillation Summer Winter% evaporated at 70oC (158oF) vol% 30-32 20-48 22-50% evaporated at 100oC (212oF) vol% 50-52 46-71% evaporated at 150oC (302oF) vol% >80 Min 75Final boiling point (FBP) oC, max 210 Max 210Distillation residue vol% <2 Max 2
Henrik Udesen ‐ Haldor Topsøe A/S16th IMPCA 2013 Asian Methanol Conference
Market considerations
30 October - 1 November 2013
Shangri-La Hotel, Singapore
Henrik Udesen
Market considerations
Price development 2005-2013
Henrik Udesen ‐ Haldor Topsøe A/S16th IMPCA 2013 Asian Methanol Conference
Gas monetizationIncentive for conversion of natural/associated gas to
chemicals and transportation fuels;– Ammonia
– Methanol
– Gasoline
– Diesel (via Fischer-Tropsch synthesis)
The market interest for gasoline and diesel covers both – Mega scale 15,000 – 150,000 barrels per day
– Small and large scale 1,000 – 15,000 barrels per day
Ammonia, Methanol & GasolineAmmonia:
~ 150 mill. MTPY
Methanol :~ 45 mill. MTPY
Gasoline:~ 900 mill. MTPY
G 1 2%Growth ~ 3% p.a.
80% used for fertilizers
Growth ~ 4-8% p.a.
Formaldehyde, MTBE, Acetic acid, MTO
Growth ~ 1-2% p.a.
Fuel
Henrik Udesen ‐ Haldor Topsøe A/S16th IMPCA 2013 Asian Methanol Conference
Common challenges
Logistics Economy of scale
Market accessCAPEX vs. OPEX
Market sensitivity of one new plant addition
Product
Annual production
World scale
Nameplate capacity in
Specific NG consumption pr. Product
Million MT nameplate capacity
% of annual
production
MT of product (normalised)
Gasoline 900
17,500 bbl/d (1,975 MTPD) + 445 MTPD LPG
0.07%
298
244 (gasoline only)
M th l 45 5000 3 7% 106Methanol 45 5000 MTPD
3.7% 106
Ammonia 150 2200 MTPD
0.5% 100
Henrik Udesen ‐ Haldor Topsøe A/S16th IMPCA 2013 Asian Methanol Conference
TIC (ISBL cost estimate) (US Gulf coast basis)
NG to gasoline (> 15,000 bbl/d)
45 - 55,000 USD/bbl
Gasoline part only! (add-on to existing methanol plant)
6 - 10,000 USD/bbl
Why choose Topsoe TIGAS process?Opportunity to produce fuel – huge market!
TIGAS is an attractive alternative to FT– Investment per barrel lower than FT alternatives
– Drop in fuel
Highly sucessful operation of gasoline catalyst GSK-10
New feature: GUU = High quality high octane number