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THE USE OF WASTE COOKING OIL AS AN
ALTERNATIVE FUEL FOR THE DIESEL
ENGINE
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Abstract
This research project is directed toward those who are looking foran alternative source of fuel for the diesel engine. This report isan investigation on how a sole user can design and manufacturebiodiesel, how well the biodiesel compares with diesel in regardsto performance and also the economical benefits which can beachieved by using biodiesel blended fuels.This report firstly analyses what biodiesel is, and how it can be
made from waste cooking oil through both a chemical andphysical process.An economical analysis was then conducted for the fuel wherethe aim was to determine by how much the biodiesel producedfrom waste vegetable oil was an economical alternative to diesel.Assuming that the general maintenance (oil change etc) of usingbiodiesel remained the same as that of diesel, it was found thatusing B100 will provide the highest economical gains when used
and the initial cost of the biodiesel plant will be recovered thequickest.Based on these investigations it was concluded that biodiesel isindeed a feasible alternative to diesel that can save the user inexcess of 28% on their fuel costs, and that will yield similarperformance characteristics when used in a common IC engine.
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Table of Contents
Abstract .2
Glossary of Technical Terms .....6
Chapter 1
INTRODUCTION
1.1 Introduction 8
1.2 Project Outline.. 9
Chapter 2
LITERATURE REVIEW
2.1 Introduction....... 11
2.2 Literature Review: Transesterification... 12
2.3 Literature Review: Performance Characteristics.. 13
2.4 Literature Review: Economical Benefits... 14
2.5 Summary... 14
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Chapter 3
SYSTEM DESIGN & CONSTRUCTION
3.1 Introduction... 17
3.2 Design Requirements & Constraints... 17
3.3 System Processes....20
3.3.1 The Chemical Process..20
3.3.2 The Physical Process22
3.4 Conceptual Design Analysis.. 24
3.4.1 Titration24
3.4.2 Alcohol & Catalyst Mixing.27
3.4.3 Transesterification.....................................................................43
3.4.3.3 Glycerine removal.............................................................54
3.4.3.4 Waste Recovery System................................................. 58
3.4.4 Purification.... 69
Chapter 4
PRODUCTION AND TESTING OF WVO IN DCE LABORATORIES
4.1 Introduction......................................................................................80
4.2 Vegetable Oil to BioDiesel Via TransesterificationMethod..81
4.2.1. Procedure for Manufacturing of Biodiesel.84.
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4.3 PHYSICO-CHEMICAL PROPERTIES.86
4.4 Fuel Analysis...90
4.5 Conclusions.91
Chapter 5
ECONOMIC ANALYSIS
5.1 Introduction93
5.2 Economical Analysis.94
5.3 Costs Associated with Biodiesel Production.95
5.4 Conclusion100
Chapter 6
PROJECT CONCLUSION
6.1 Conclusion ..102
6.1.1 Implementation Plan103
6.1.2 Economic development progress and social progress..104
6.1.3 Environmental impact105
6.2 Future Work..106
REFERENCES...108
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Glossary of Technical Terms
ASTM-D6751: (American Society for Testing Materials) American
biodiesel fuel standard.
Biodiesel: A diesel equivalent fuel derived from vegetable oil.
Ethyl Ester: Biodiesel that has been created using ethanol as the source
of alcohol.
FFA: Free Fatty Acid: Contaminants that must be removed from
biodiesel.
Glycerine: The dark brown by-product which separates from the
biodiesel after transesterification (see transesterification) has
completed.
Methoxide: The name given to the methanol and sodium hydroxide
solution once it has been mixed.
Methyl Ester: Biodiesel that has been created using methanol as the
source of alcohol.
SVO: Straight Vegetable Oil.
Transesterification: The chemical process required to convert vegetable
oil into biodiesel.
Triglycerides: Vegetable oils are otherwise known as triglycerides.
WVO: Waste Vegetable Oil.
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Chapter 1INTRODUCTION
1.1 Introduction
As a result of technological evolution, it is becoming more andmore common to exchange money in place of a service orproduct. The dependence on ones personal ability to provide fortheir individual needs is diminishing. For example, why wouldsomeone cut their own fire wood if they can pay someone to do it
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for them, or even easier, buy it from a shop. But what happenswhen the price of fire wood goes up? The consumer pays more.
Generally speaking, the consumer wont cut their own wood, theywill continue to pay more and more and the consumer will feel asif they are forced to pay these prices because they have nochoice.Regardless of the reasons why these prices are higher and who isresponsible, there is little one can do about the situation ofoverpriced fuel but pay the price and complain to whoever iswilling to listen. But every now and then you hear about people
who are making their own diesel, or biodiesel as it is known, fromwaste cooking oil people who are no longer at the mercy of thecommercial fuel giants who extort your hard earned money for aproduct which is a necessity in todays society. But how do thesepeople make their own fuel, how does it compare to diesel and
just how much money (if any) do they save? This report willinvestigate these areas and first-hand information will be providedon how biodiesel can be made, how well it compares with dieseland the typical savings that can be achieved when using fuel
derived from waste cooking oil.
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1.2 Project Outline
This purpose of this research project was to investigate how aindividual user can design and fabricate a machine tomanufacture biodiesel, how well the biodiesel compares withdiesel in regards to performance, and also the economicalbenefits which can be achieved by using biodiesel blended fuels.
The objectives of this research project are to:1. Determine what biodiesel is.
2. Determine what chemical and physical processes are requiredto make biodiesel.
3. Design and construct a machine to make biodiesel that issuitable for the home user.
4. Conduct an economic analysis to determine the savings thatcan be achieved when biodiesel is used in place of diesel.
5. Conclude the report and summarise the findings.
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Chapter 2
LITERATURE REVIEW
Objectives
The objectives of this chapter are to analyse the literatureavailable on biodiesel and determine how biodiesel is made, how
it has performed in other studies, and typical cost benefits thatcan be achieved by using biodiesel blended fuels. Based on theinformation found from the literature review, a summary of keypoints will be made which will set the foundations of how thisresearch project will progress.
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1. Ethyl alcohol or Ethanol2. Methyl alcohol or Methanol
Ethanol is also a preferred alcohol in this process compared tomethanol because it is derived from agricultural products and isrenewable and biologically less objectionable in the environment.However, to an inexperienced manufacturer of biodiesel ethylesters are much more difficult to obtain than methyl esters.
When using ethanol in the transesterification process, potassium
hydroxide KOH appears to be the most effective catalyst to use.When using methanol in the transesterification processes, sodiumhydroxide (NaOH) has been found to be most effective catalyst.
There are also multiple washing techniques used to purify the rawesters produced from transesterification. Water washing has beenproven to be a quite inefficient, difficult and time consumingmethod of purifying the raw biodiesel or acidic esters . Waterlesswashing using synthetic magnesium-aluminium-silicate has
proven to be a much more effective means of purifying biodiesel.
2.3 Literature Review: Performance Characteristics
According to the University of Idaho, biodiesel blended fuelscompare quite well to diesel. It was found that biodiesel blendedfuels have lower power (4.9% loss) and torque (5% loss) outputswhen used in an in-line four cylinder John Deere 4239T
turbocharged, direct injected diesel engine.
A study conducted by Professor Barry Hertz of the University ofSaskatchewan (BioBus Project) has shown that biodiesel blendsas low as 5% can reduce engine wear by 7.8 23.4%. What thisindicates is that biodiesel can significantly increase
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the engine life in terms of frictional losses. What has also beenfound is that biodiesel is a very good cleaner and that it will
remove all of the deposits within the fuel system.However when the transition is made from diesel to biodiesl, thefuel filter must be changed several times so that the fuel filtrationsystem does not clog from the deposits that are being removed.While biodiesel in general may be a good cleaner of foreigndeposits, biodiesel that is of low quality and has a high FFA levelmay leave its own deposits in the fuel and combustion systemwhich may cause sticking valves, sticking piston rings and injector
coking. It is therefore very important that a high quality biodiesel isproduced.
In terms of emissions, it has been found by U.S E.P.A that theoverall emissions of biodiesel are lower than that of diesel withthe acception of NOx emissions. From this study it was found thatfor biodiesel blends of 20% biodiel and 80% diesel (B20),there was a 2% increase in NOx emissions, however particulatematter, hydrocarbons and carbon monoxide were down 10.1%,
21.1% and 21.1% respectively. A separate study conducted bythe society of automotive engineers concluded that the increasedlevels of NOx produced by using biodiesel can be reduced byretarding the injector timing 2 3 degrees and or fitting a catalyticconvertor.
2.4 Literature Review: Economical Benefits
The major influencing factors on the price of biodiesel are the costof the alcohol used for the transesterification and purificationprocess which is used to purify the raw biodiesel. Biodieselproduced using water purification is dependent on the cost ofalcohol only (provided that the water is free) and can bemanufactured for Rs12/litre (cost of materials only). Biodiesel that
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has been purified using synthetic magnesium silicate absorbentpowder can incur an additional cost of up to Rs 26/litre. Overall,
regardless of the purification, biodiesel can generally be producedat a lower can than what diesel can be purchased for atcommercial fuel distributors.
2.5 SummaryIt has been found that biodiesel is made from a process called
transesterification. The materials that can achievetransesterification involving the least complications aremethanol and sodium hydroxide in the presence of the wastecooking oil. It was also found that biodiesel purified usingsynthetic magnesium silicate produced superior quality biodieselthat is capable of meeting the ASTM fuel standards.
In terms of performance, Biodiesel should compare quite well to
diesel and should produce lower overall emissions with theexception of NOx. To reduce the NOx emissions the injectiontiming can be changed and or a catalytic converter can befitted to the exhaust system. It was also found that high qualitybiodiesel can have a positive impact on engine life andsubstantially reduce friction. However, low qualitybiodiesel can be detrimental to engine life and can cause injectorcoking as well as valves and rings sticking which ultimately canresult in engine failure. The emphasis of biodiesel productionmust therefore be on quality.
Finally it was found that biodiesel can generally be produced at alower cost than what diesel can be purchased for, where themajor influencing factors which affect the cost of biodiesel are thematerials used in the purification process and the alcohol used forthe transesterification reaction.
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Chapter 3SYSTEM DESIGN &
CONSTRUCTION
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ObjectiveThe objective if this chapter is to design and construct a prototypemachine that can make biodiesel from waste cooking oil that issuitable for the small-volume individual user.
3.1 Introduction
This chapter will firstly analyse the design requirements and
constraints that apply to the design and construction of thebiodiesel plant. The basic chemical and physical requirements toproduce biodiesel will then be analysed where a list of basicphysical requirements will be developed.
Finally, an appraisal on the entire design process will beperformed and any design changes and future work regarding thebiodiesel plant will be listed.
3.2 Design Requirements & Constraints
The design requirements of the system are guidelines whichdictate the direction of the overall design of the system.
The design requirements of the system are:
1. The system must produce biodiesel capable of meeting theASTM Standards.
It is the biodiesel that is the emphasis of this investigation. Thequality of the biodiesel will not only influence the performancecharacteristics of the fuel, but also the impact it has on the
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internal engine components. The use of poor quality biodiesel hasbeen can result in poor performance and can substantially reduce
the life of the engine . It is therefore imperative that the emphasison the biodiesel production be on quality. The American (ATSM-D6751) standards are currently being used by industry. Thereforethe fuel produced by the system must be capable of meetingthese standards so that a high quality of fuel is maintained.
2. The system must be designed to minimise operator interaction.
There are two basic factors that must be addressed in this area.That is the time spent to manufacture the biodiesel, and thephysical requirements needed by the operator to producebiodiesel. It is essentially the operator that will be in control ofproducing the biodiesel. As time is of value, the system must bedesigned so that the overall interaction of the operator is kept to aminimum.
3. The total storage area required by the system must be kept to aminimum.
By minimising the room that the unit occupies the emphasis of thedesign will be on asmarter, more efficient design as opposed to abulkier less efficient design.
4. Recover any materials that can be used.
Throughout the process of manufacturing biodiesel there arecertain products which can be reclaimed for use in the next batchof biodiesel. Therefore, a system must be designed to captureany products that can be reused whereby the aim is to minimizefuel production costs.
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The system constraints indicate the limitations of the design. Adesign which perfectly addresses the design requirements is not
necessarily the best design, as there may be conflict with theconstraints set forth on the design.
The design constraints are:
1. The prototype system must cost no more than Rs100000 tomanufacture (excluding labour).
This is the major factor which will stifle the best solution fromprevailing. However,it does constrain the project from becomingso expensive that biodiesel production is no longer an economicalalternative for the small-volume user. In this instance, thisparticular constraint may be beneficial.
2. The system must be designed to operate in accordance with
governments environmental regulations. To avoid any conflictwith the Environmental regulations and to also conserve theenvironment, the system must be designed so that the biodieselplant operates in compliance with the regulations set forth by thegovernment.
3.3 System Processes
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3.3.1 The Chemical Process
The process that occurs when vegetable oil is converted intobiodiesel isTransesterification. Transesterification occurs whenalcohol, an acid catalyst and vegetable oil are mixed together inthe correct proportions. The major products of the reaction areeither methyl esters (methanol as source of alcohol) or ethylesters (ethanol as the source of alcohol) where both esters arewhat is classified as biodiesel. The bi-product of the reactionwhich must be removed is glycerine.
Glycerine can be seen as the impurities and particulate matterthat is removed from the oil after transesterification.
The figure 3.1 shows the chemical process for methyl esterbiodiesel. The reaction between the oil and the alcohol is areversible reaction and so the alcohol must beadded in excess to drive the reaction towards the right and ensurecomplete conversion.
Vegetable oils are triglycerides, composed of three chains of fattyacids bound by a glycerine molecule. In the above figure the oilcomponent of reactants is theGlyceride or more accurately Tri-Glyceride, as there are three glycerides linkedtogether per molecule of vegetable oil. When the oil is mixed withthe alcohol and catalyst, esters and glycerine molecules are
formed. A successful trans-esterification reaction is signified bythe separation of the ester and glycerol layers after the reactiontime.
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Figure 3.1: Transesterification Process
Research has shown that the simplest way to achievetransesterification is through the use of methanol as the alcoholand sodium hydroxide as the catalyst. Othersubstances may be used such as ethanol and potassiumhydroxide, but the process is more complicated and thereforemore difficult to achieve a complete conversion for aninexperienced user.
As the aim of this investigation is to determine whether or not it isfeasible for an average individual to manufacture biodiesel forpersonal use, the easiest and most common form of trans-esterification will be used, whereby alleviating the host of
technical issues which can arise by using the more complicatedprocesses.
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Generalising the above process, the steps involved in makingbiodiesel can be broken down into the following subgroups:
1. Titration.
2. Alcohol and Catalyst mixing.
3. Transesterification.
4. Purification.
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3.4 Conceptual Design Analysis
3.4.1 Titration
As has been previously stated, vegetable oils are triglycerides,composed of three chains of fatty acids bound by a glycerinemolecule.
Free fatty acids (FFAs) are fatty acids that have becomeseparated from the triglycerides, leaving diglycerides,monoglycerides and free glycerine. This is causedby heat, water in the foods cooked in the oil, or oxidation. Thehotter the oil gets and the longer it's cooked, the more FFAs it willcontain.
There is a basic amount of sodium hydroxide (NaOH )required ascatalyst to transesterify fresh, uncooked oil and neutralise any
FFAs and that is 3.5 grams(NaOH)/litre. When transesterificationis performed on waste vegetable oil (WVO) however, anadditional amount of NaOH is needed to neutralise the additionalFFAs within the WVO, turning them to soaps. The majority of thesoaps sink to the bottom along with the glycerine product createdby the reaction, however some soap still remains within thebiodiesel. The remaining soap must be removed in thepurification process which will be addressed later in the paper.
If too much NaOH is used as a catalyst, the biodiesel ester bondswill break where some of the bonds will mate with the NaOHforming excess soap, and other with any water in the WVO whichwill form additional FFAs that dissolve back into thebiodiesel. Excess soap formation will form a very alkalinebiodiesel that's difficult to purify, with loss of production, or it can
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ruin the reaction when the ratio of soap to biodiesel reaches apoint where the whole batch turns into "glop soap".
While it is unavoidable that some FFAs are formed by biodieselester bonds being broken, excess NaOH increases theproportion.
So why it is that FFAs are so undesirable in biodiesel? Accordingto the Fuel Injection Equipment Manufacturers (Delphi,Stanadyne, Denso, Bosch), FFAs can corrode fuel injectionequipment, cause filter plugging and the build-up of sediments
on fuel injection parts.
The process used to determine how much additional sodiumhydroxide is needed for a specific batch of WVO is titration.Titration measures the pH of the oil, that is, the acid-alkaline level(pH7 is neutral, lower values are increasingly acidic, higher than 7is increasingly alkaline, or "base"). From this you can calculatehow much extra NaOH will be needed.
The manual titration process is as follows:
1. Measure out 1g of NaOH with 1liter of distilled water, andmix (test solution).
2. Add 10 ml of Methanol to a glass container.
3. Test the Ph of the methanol and add a few drops of the testsolution to neutralise the methanol if required.
4. Add 1 gram of oil to the methanol and stir.
5. Add a sufficient amount of test solution (drop by drop) untilthe Ph of theoil/methanol solution reaches 8.5 (within 4-8ml).
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6. Calculate the amount of NaOH required/litre to bring the
solution up to a PH of 8.5.
Example Calculation:
If titration showed 2 ml, that translates to 2 extra grams for eachliter of oil. Using 90 liters for example:
90 liters oil x (3.5 grams NaOH + 2)
Where the 3.5 grams is the amount of NaOH required as catalystto transesterify fresh, uncooked oil
The total amount of NaOH required is:
90 x 5.5 = 495 grams.
Mechanising the titration process will be quite difficult andexpensive to do. To do so would require the use of highlycalibrated ph measuring device, data acquisition andrecording device and a programmed CPU at the very least. Thisdevice in itself would be quite difficult, time consuming andexpensive to manufacture. An automatic titration device may bepurchased however, the cost of such a device amounts to
thousands of rupees.
For this particular application it is not justifiable to spend thisamount of time or money constructing or purchasing an automatictitration apparatus, where the titration procedure when performedmanually can be completed easily within 10 minutes. Therefore,the titration process will be performed manually by following thesame process listed above.
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3.4.2 Alcohol & Catalyst Mixing
The alcohol used within this process is methanol. Methanol is avery dangerous and volatile substance and must be treated withcaution. When mixed with an acid (NaOH in this case) the mixtureis even more dangerous. It is therefore necessary to minimisethe level of human interaction involved in all process where thesechemicals are present.
The functionalrequirementof this system is:
To mix the NaOH granules with the methanol until the NaOH iscompletely dissolved within the solution.
While this may seen like only a basic function, there are severalspecific design constraints which must be addressed in order todesign the best overall system.
The specific design requirementsare that:
The system can not have any device which has exposedelectrical components or generate enough heat so that a fire orexplosion will occur.
The proposed system must be sufficiently sealed so that harmfulgasses, vapours or emissions given off by the reaction generatedwithin the methoxide solution are not released into theatmosphere .
The proposed system must incorporate sufficient apparatus toensure the operator does not have to physically contact or inhaleany chemicals used throughout the process
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It is therefore important that any design proposal to mechanisethis process must be based on these design requirements and
limitations.
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3.4.2.1 Conceptual Design Proposal 1
Figure 3.2: Magnetic Stirring Bar Mixer
How the device works:
One sealed electric motor and another standard electric motoristaken. The armature of the standard electric motor is removedand the housing of the standard electric motor is fixed to theoutput shaft of the electric motor as shown above.
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The sealed electric motor is now coupled with the standardelectric housing beneath the sealed container. A mixing bar
magnet is placed inside the sealed container.
The sealed electric motor is powered on. The rotating magneticfield produced by the housing of the standard electric motor inrotation, will cause the mixing bar to rotate and stir the solutionwithin sealed vessel. The ball valve located on top of the tank canbe opened to add Methanol and NaOH and then closed off to sealthe system.
Advantagesof this design:
There are no input shafts or holes required to make this mixingapparatus work and therefore there is virtually no chance of thismixing device leaking.
As there is a low risk of this design leaking there is a low risk of
the methanol igniting from the electric engine.
Disadvantagesof this design:
The mixing bar may become stuck which will require humaninteraction to dislodge the bar reliability issues possible skincontamination.
Corrosion may take place between the mixing bar andmethoxide solution.
Mixing bars are not readily available, they are a specialty itemwhich may bedifficult to get.
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3.4.2.2 Critical Factor Analysis: Conceptual Design Proposal 1
Power: The power required to operate the system is consumedvia the electric motor at the base. The power consumed by thiselectric engine will only be marginal and will not be a problem.
Cost: The cost of this system would be quite cheap in terms ofeach component. The availability of the mixing bar however, maybe a problem. While mixing bars can be ordered, they are more ofa specialty item and are not readily available.
Reliability: The reliability of this unit is questionable. If the mixingbar were to become lodged in the alcohol/acid solution, themagnetic field generated by the rotating motor housing wouldmost likely not be enough to dislodge it. Therefore,some human interaction would be required to dislodge it. Thisparticular factor may have a significant impact on the ability of thisdesign to perform the specified task.
Safety: This is a very safe design as there is only a very smallchance of the mixing vessel leaking. As there are no shaftpenetrating the wall of the mixing vessel, the only way the vesselcould leak is that if there were a hole in the material in themissing vessel itself. Provided that the correct material wereselected, this is highly unlikely.
Functionality: The functionality of this unit may be compromised
by the reliability issues mentioned above. If it were guaranteedthat the mixing bar would never become stuck, this system wouldmost certainly be quite appropriate. However this is not the case,and therefore the functionality of this particular design is limited.
Maintainability: There are two areas which would requiremaintenance with this design; that is inside the tank where the
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mixing bar is, and the electric motor located on the outside of thetank. While only very little maintenance would be required on
the electric motor, constant and regular maintenance would needto be performed on the inside of the mixing vessel to remove anybuild up of gummy partially dissolved acid and alcohol. This wouldbe quite an annoying problem to address as it wouldoccur quite consistently. In terms of maintenance, this particulardesign has quite a high level of maintenance required and ratesquite poorly.
Manufacturability: This design would be relatively easy tomanufacture, however vibration issues may become evident if theempty housing of the electric motor were not mounted perfectly.Off course excessive vibration would ultimately cause the unit tofail which is obviously an undesirable quality. This is the only areathat would pose as a problem in terms of manufacturability.
3.4.2.3 Discussion: Conceptual Design Proposal 1
While the stirring bar mixer or design proposal 1 does have theadvantage of being unlikely to leak, it does have a majordisadvantage being unreliable as the stirring barmay get caught up and stop working properly. As the aciddissolves into the alcohol, some parts of the solution may becomequite thick and viscous. This may cause the magneticallyoperated stirring bar to become lodged in some of the partially
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dissolved acid, and stop working. This is a very real scenario andis characteristic of acid when it is dissolved into alcohol. As the
stirring bar rotates due to a rotating magnetic field, a very strongmagnetic field may be required to overcome the lodging that mayoccur. Relating this requirement of needing a large magnetic fieldback to the physical equipment which has a large magnetic field,it can be determined that the mixing device required tosuccessfully and reliably mix the methanol and alcohol solution, isnot feasible in terms of size and cost. The unit would simply betoo large and too expensive and may still prove unreliable.
3.4.2.4 Conceptual Design Proposal 2
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Figure 3.3: Stirring shaft mixer
How the device works:
A brushless sealed electric engine with a mixing propeller ismounted to the base of a sealed mixing vessel. On top of thevessel is a ball valve where the alcohol and acid can be added.Once added the brushless engine will be turned on and the
mixing propeller will stir the solution until the acid has dissolved.
Advantagesof this design:
High quality mixing possible, provided that rotation speed andmixingpropeller is appropriately matched to avoid cavitation fromvortex creation.
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Better mixing motion than mixing bar, less friction.
Simple and cheap to construct.
Disadvantagesof this design:
The system may leak though the seals surrounding the stirringshaft which may result in fire or area contamination.
Cavitation may occur if the pitch on the stirring propeller is toohigh or if rotation speed is too high
Quality of mixing may be compromised if the pitch on the stirringpropeller is too low or engine speed is too low.
3.4.2.5 Critical Factor Analysis: Conceptual Design Proposal 2
Power: The power required to operate this system is consumedthrough the electric engine which is attached to the stirring shaftand mixing propeller. The power required by this electric enginewill only be very small as the viscosity of the alcoholand acid solution is quite low. The power requirements of thismotor will not be a problem.
Cost: The cost of this system will be quite low, (including labour).The parts required by this system are quite readily available andeasy to make.
Reliability: The reliability of this system would be quite goodprovided that the correct materials were used throughout theconstruction. If and when the system fails, the problems it maycause could be fatal. If this particular system were to leak,
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alcohol and acid would be in direct contact with the electric enginemounted at the base of the mixing vessel. If for some reason a
spark were created (highly possible) the mixture would mostcertainly ignite and could explode. This is a highlyundesirable reliability issue to have.
Safety: The general safety of this system is compromised by thereliability issues mentioned above. Essentially this particulardesign is comparable to a time bomb, where eventually the sealsholding the alcohol and acid will fail, and the unit may
explode.
Functionality: The functionality of this system is quite good. Themixing properties achieved by the mixing propeller would be quitehigh and easily modifiable.
Maintainability: The only problem that there will be withmaintenance is the seal surrounding the input shaft protrudinginto the mixing tank. Provided that this seal is
maintained, there should not be a problem. Other than that, thisdesign will have very low, if any required maintenance.
Manufacturability: This system would be quite easy tomanufacture. The most difficult task would be getting the engineshaft to seal within the mixing vessel. The additional tasksrequired to manufacture this system would be quite easy toperform.
3.4.2.6 Discussion: Conceptual Design Proposal 2
By analysing this particular design it can be seen that the majorproblem is that, if the seal surround the shaft did leak, highly
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flammable methanol and corrosive acid may leak directly onto theelectric engine. This could most certainly cause a fire. To avoid
this situation, some form of pinion and crown wheel assemblymay be used whereby the electric engine could be located to theside of the mixing vessel, and the crown wheel and pinionarrangement could be placed directly beneath the point of entry. Ifthe system now leaked it would not leak directly onto the electricengine, however, this is now not a very practical system as it nowrequires a gear box and additional shafts. Another alternatepossibility is to locate the electric engine on the side of the
unit and have the mixing shaft protrude into the mixing vesselfrom the side. If the seal around the shaft leaked in thisconfiguration it would most likely not go into themotor, but it is still a possibility. Therefore, fire and sitecontamination is still a problem.There are many ways at which this mixing system can bechanged and altered, however the fact still remains that it isgenerally a clumsy system and perhaps not the best option.
3.4.2.7 Conceptual Design Proposal 3
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Figure 3.4: Pump Recirculation System
How the device works: A pump is externally mounted on themixing vessel whereby the inlet of the pump draws from the baseof the mixing vessel and the outlet of thepump connected towardthe top of the mixing vessel.Connecting a pump in this configuration will form a closed loopsystem whereby the acid and alcohol will bestirred via the impellor of the pump.
Advantagesof this design:
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Reliability: Provided that the correct pump was used within thissystem, the reliability of this system would be very high. If
however, a seal leaked within the pump and alcohol came incontact with the electric engine, a fire may occur. The systemsability to thoroughly mix the acid and alcohol together bothcompletely and reliability is quite high. There are no inherentproblems that this design will encounter whileperforming this task. Overall, this system is quite reliable.
Safety: The safety of this particular design may be compromised if
the pump were to leak. As has been described above, if the pumpwere to leak, a fire may occur which may cause an explosion.While the chance of this occurring is only very low, thepossibility is still there and it is debateable whether the risk isworth taking.
Functionality: The functionality of this system by far supersedesthe previous designs that have been discussed. This systemoffers superior mixing ability when compared
to that of the other systems and also, the path of the alcohol andacid solution can be diverted into the reactor while using the samemixing pump. As there are virtually noreliability issues which will affect the pumps ability to perform, theoverall functionality of this system is quite good.
Maintainability: Little if any maintenance is required to ensure thesystem keeps operating. If however, the seal within the mixingpump did fail there may be somemaintenance issues. This sealmay be difficult if not impossible to acquire. Thereforeit may be necessary to change the pump rather than replace theseal.
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Manufacturability: This system offers a few more challenges interms of manufacturability. The pluming required by this system
could be done a multitude of ways, however, there is obviouslybetter ways than others. This particular task however will not bedifficult. This system also requires the used of multipleconnections which could leak if not installed properly. This shouldnot be a problem, its just a matter of using the correct sealingcompound (e.g. thread tape or thread sealer).
3.4.2.9 Discussion: Conceptual Design Proposal 3
There are several advantagesthat this system has over the otherdesign proposal. The first is that this system will have a greaterability to mix the solution more consistently and thoroughly. Asolution which has dissolved the entire contents of the acid withinthe alcohol will react much better with the waste vegetable oil anda complete conversion is far more likely. A solution where the acidhas not completely dissolved into the alcohol will result in andinconsistent and incomplete reaction when added tothe waste vegetable oil. It is therefore quite favorable that thissystem utilizes a mixing process that will yield superior mixingresults when compared to that of the other systems.
The other useful advantage of this system is that the mixing pumpmay be used as a transfer pump to pump the contents out of themixing tank into a reaction tank. This is certainly a desirablequality to have as it eliminates any further chemical contact
required once the alcohol and acid have been mixed, thus makingthe system safer.
The disadvantages however are that the pump and associatedfittings may leak if the correct pump is not selected and the fittingsnot installed properly. The solution to this is to firstly select apump that will not react with the chemicals required to make
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biodiesel, and also ensure that the fittings are correctly installedand maintained.
3.4.2.10 Conceptual Design Selection: Alcohol & Catalyst Mixing
It can be determined that from the analysis of the above systemsthat design proposal 3 or the Pump Recirculation System, is thebest system to use. This particular system offers superior mixingability when compared to design proposal 1 & 2, and alsominimizes operator interaction both during and after the mixing
process. The pump recirculation system has the potential to bethe most reliable and economically feasible solution that requiresthe least amount of operator interaction. The recirculation pumpcan be employed for multiple uses. The first and primary functionis to stir and dissolve the acid into the alcohol. The secondfunction is that the recirculation pump can have the recirculationpath altered to pump out the contents of acid and alcohol into areaction vessel.
While there are some safety concerns, these can be minimized byutilizing a suitable pump and mixing vessel and also following thecorrect materials handling procedures..Concluding this investigation into the most appropriate concept tomix the acid and alcohol together, it has been decided that thePump Recirculation System will be used.
3.4.3 Transesterification
Transesterification is the chemical reaction that occurs whenalcohol, acid and waste vegetable oil are added together in thecorrect amounts. Once the reaction is complete and the solution
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has settled, two distinct layers will form. The upper layer isbiodiesel and the lower is glycerine. Once sufficient time has been
given for the solution to settle out completely, the glycerine mustthen be removed. The system that will be responsible forachieving transesterification will be the reactor.
The functional requirements of this system are:
To successfully contain the oil, alcohol and acid and mix
together until transesterification is complete.
To separate the glycerine from the biodiesel.
The reactor is basically a larger, slightly more complex methanoland acid mixing vessel with similar design requirements.
The specific designrequirements are that:
The proposed system can not have any device which hasexposed electrical components or generate enough heat so that afire or explosion will occur.
The proposed system must be sufficiently sealed so that harmfulgasses, vapors or emissions given off by the reaction generatedwithin the methoxide solution are not released into the
atmosphere.
3.4.3.1 Conceptual Design Proposal
Analysing both the functional and specific design requirements, itcan be seen that the reactor is basically a more complicatedalcohol and acid mixing vessel, only now oil has been added tothe solution. The method of mixing that will be adopted for this
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process will operate on the same principal as what has beendeveloped for the alcohol and acid mixer.
Figure 3.5: Basic Reactor Vessel
This principal alone however will not perform all the tasks requiredof the reactor. With this basic configuration the transesterificationprocess would take several days to complete. There is no glycerinremoval system and there is no system in place torecapture any materials that can be reused.
The following areas need to be addressed:
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1. Increasing the rate of reaction.
2. Glycerin Removal.
3. Waste recovery system.
3.4.3.2 Increasing the rate of reaction
There are a few techniques which can be introduced to thissystem to increase the rate of reaction. These techniques are:
i) Increasing the rate of reaction through better mixing.
ii) Heating.
3.4.3.2.1 i) Increasing the Rate of Reaction through better mixing
The first method which can be used to increase the rate ofreaction is to adopt a more effective method of mixing. A spoonfor example could be upgraded to a blender. Asthe basic designof the reactor incorporates a pump to do the stirring, it will be hardto achieve a mechanical device that can mix the solution better.The use of ultrasonic technology however, can substantiallyincrease the rate of reaction by effectively mixing the solutionmore thoroughly. To do this, the pump is still set up the same wayas a recirculation system, however, once the fluid exits the pumpit then passes through a small vessel that is saturated with
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ultrasonic waves. The fluid then exits the ultrasonic vessel andflows back into the tank. What the ultrasonic waves do is agitate
the acid, alcohol and oil solution on a molecular level. Thisagitation can substantially increase the level of molecularcollisions that occur within the solution which in turn,increases the rate of reaction which also results in a morethorough and complete reaction.
If ultrasonic mixing were used in conjunction with a heatingapparatus, reaction times could be cut back to less than 10minutes for a 100ltr batch. However, if ultrasonic technology wasused alone results are similar to that of heating.
Unfortunately incorporating ultrasonic technology into this systemwould be very expensive.
For large scale industrial biodiesel plants, ultrasonic technology
would prove invaluable. However, utilising this technology in theprototype model of this project is not economically feasible.
3.4.3.2.ii) Increasing the Rate of Reaction through Heating
The second method of increasing the rate of reaction is thoughheating the reactant. Heating the reactant acts as an additionalcatalyst to the reaction and can cut the reaction time down to less
than an hour. So simply by adding heat into the system therate of reaction can be increased dramatically. The amount ofheat however is what needs to be addressed. It has been foundthat temperatures between 48 - 54C have provided t he bestenvironment for an accelerated reaction. If the contents areheated any more than this, the risk of methanol evaporation isincreased which may result in a contaminated, semi converted
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biodiesel. It is therefore important to mention that if heat is usedwithin the reactor, the temperature must be closely monitored.
Another important factor which needs to be considered is that, ifheating is to be provided, what is the source of heat? Should it beelectrical, chemical, solar or some other form? As there iscertainly a risk that a fire could occur during biodieselproduction, it seems logical to steer away from heat sources thatutilise an open flame.
The other options available are solar and electrical.
Solar power is unreliable and is difficult to achieve a high amountof heating energy in a low cost unit. These simple points aloneare enough to eliminate the use of solarpower in this situation.
So it seems that all we are left with is electrical power. Electricalheating energy is easy to achieve in large amounts, can be
thermostatically controlled, however if not correctly set up, theelectrical heating system could ignite the fuel if the heatingelement reached the auto ignition temperature of the reactant.
Now, the next question is, what is the best method of electricalheating to use? There are many methods which can be usedhowever the most effective form of heating will be throughphysical conduction received though direct contact of a
heating element or a hotplate type of arrangement. Heat throughconvection or radiation is not an option as the heat energy used toheat the reactant needs to be utilised as efficiently as possible sothat costs are minimised.
So what are the best ways of applying heat to the reactantthrough conduction? There are two ways that will be analysed.The first is to have a hotplate mounted beneath the
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reactor.
Figure 3.6: Basic Reactor Vessel with Hotplate
Without much investigation it can be seen that this may create
several problems. Such problems include:
The base of the reactor must be the same shape as the surfaceof the hotplate,otherwise heat localising will occur (hot spots).
The hotplate may get in the way of the pluming of the reactor.
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If any reactant were to fall on the exposed hotplate, a fire mayoccur.
These factors are only some of the problems which can occur if ahot plate were used to heat the reactant. Based on these factors,it is safe to say that using a hot plate is not a good idea and nofurther investigation into this method of heating will be conducted.Another way of heating the reactant is through incorporating oneor several heating elements within the reactor similar to that of ahot water system or a kettle.
Figure 3.7: Basic Reactor Vessel with twin heating elementsThe method of using heating elements to heat the reactant hasbeen done successfully in many biodiesel plants. In most cases
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the heating elements used are out of electric hot water systemswhich have provided many years of service without any problems.
The advantage a heating element system has over a hot platesystem is that heat is conducted directly out of the element andinto the reactant, therefore making the heat transfer moreefficient. Heating elements can also be positioned anywherebeneath the fill line in the reactor making the elements versatile tomount.
The main problem with heating the reactant using this method isthat, if the heating elements were ever exposed there may be therisk of them getting too hot and igniting any flammable gassesthat are present. While this is a potential safety issue, the riskcan be easily avoided by mounting the heating elements belowthe fill line and also through the use of a thermostat and commonsense. Another way to avoid auto ignition though excessive heatis to use multiple, low wattage elements.
If for example the system required a 3.6kW heating element,instead of using 1 x 3.6kW element that can heat up very quickly,use 2 x 1.8 kW heating elements which will not heat up so quickly.
3.4.3.2.3 Critical Factor Analysis: Heating elements
Power: The power consumed by the heating elements will be
between 1.8 and 3.6kW depending on the size of the reactor. Thisheating capacity has been proven to be effective on units up to125ltr.
Cost: The cost of the heating system will be very low as theheating elements for the prototype model can be used from oldleaking hot water systems.
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Reliability: Provided that the heating elements are in good
condition, this method of heating has proven to be very reliable.
Safety: Provided that the heating elements are alwayssubmerged, the heating elements do not create any problems. Ifhowever a heating element became exposed, it could create anexplosion. Again, this is an easy problem to avoid so it is left up tothe common sense of the operator.
Functionality: The heating elements are certainly a very efficientmethod of heating the reactant and will be able to do so quitequickly.
Maintainability: The heating elements will require virtually nomaintenance provided that the heating element is still working andthe outer seal is not leaking. If the element is not working or theseal is leaking, these components can be easily andcheaply replaced.
Manufacturability: Incorporating several heating elements into thereactor system is quite easy. Fitment and wiring will not be aproblem however a heavy duty switch would be required to turnthe heating elements on and off.
3.4.3.2.4 Conceptual Design Selection: Increasing the rate of reaction
Analysing the techniques that are available to increase the rate ofreaction of the reactant, it can be determined that an electricalheating system utilising multiple heating elements is a feasiblesolution, and will be incorporated into the reactor design. As thismethod has been used within many biodiesel plants throughoutthe world, it is a proven and tested method of heating that is safeand that works and that is simple and cost effective.
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Figure 3.8: Basic Reactor Vessel with twin heating elements
The above design displays the simple concept that will beadopted to increase the rate of reaction of the reactant.
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3.4.3.3 Glycerine removal
When the oil, alcohol and acid have been mixed together for a setperiod of time the transesterification process will be complete.Once the reaction is complete the mixing pump will need to beturned off and the product will need to settle. Once completethere will be two distinct layers that form, biodiesel and glycerine.The biodiesel will remain on the top layer and the glycerine will fallto the lower layer. A picture of the separation can be seen below.
Figure 3.9: Biodiesel and Glycerine Separation
The above figure represents the separation that occurs after theoil, alcohol and acid have completed the transesterificationprocess and formed biodiesel and glycerine.
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There are two basic ways that the glycerine by-product can beremoved.
1. Remove the biodiesel from the glycerine.
2. Remove the glycerine from the biodiesel.
3.4.3.1 Removing the biodiesel from the glycerine
The problem with removing the biodiesel and leaving the
glycerine remain is firstly that the biodiesel needs to betransferred to another holding tank, even if only for theshort term. This will require a larger overall system and could bequite messy. The second problem with removing the biodieselfrom the glycerine, is how?
A siphon could be used but that is a technique that the operatorwould need to perform. Anyone that has ever used a siphon on
petrol for example will know that manually siphoning fuel is notthe most enjoyable past time.
A pump could be used to pump the biodiesel away from theglycerine but at what height should the inlet of the pump bemounted? The amount of glycerine produced inmaking biodiesel is certainly not consistent and therefore someform of adjustable pump inlet would need to be designed to
accommodate for the variable glycerine heights.
3.4.3.3.2 Removing the glycerin from the biodiesel
The other method of separation is by removing the glycerin fromthe biodiesel. The most practical way of doing this would be to
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Figure 3.10: Reactor with heating elements & glycerin removal system
The way this process works is that, after the glycerin has settledto the bottom of the reactor, the glycerin will be removed byopening via the lower ball valve which will be directed into aglycerin storage container. Once biodiesel starts coming out ofthe outlet of the ball valve, the ball valve is switched off and theglycerin removal process is complete.
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3.4.3.4 Waste Recovery System
The material that can be recaptured within the- process of makingbiodiesel is the alcohol. As the transesterification process isreversible, additional amounts of alcohol are required to drive thechemical reaction to produce biodiesel and glycerine. Once thetransesterification process is complete and all the alcohol that canbe used has been used, there will be a certain amount of alcoholleft within the solution of biodiesel and glycerine. The alcoholremaining in the biodiesel and glycerine can be either evaporatedout or recaptured and used within the next batch of biodiesel. Asthe alcohol used within this project is methanol and costsaround Rs60/litre, it makes economical sense to recapture asmuch of this valuable resource as possible to minimise the costsinvolved in making biodiesel.
Therefore, it is required that some form of waste recovery systembe incorporated into the design of the biodiesel plant to recapture
any methanol that would otherwise go to waste.
3.4.3.4.1 Methods of Recapturing Alcohol
There is a particular characteristic of alcohol that makes it quiteeasy to recapture, and that is its boiling temperature. The alcoholthat will be used in this project (methanol) has a boiling point of64.7C under atmospheric conditions. Therefore, if the raw
biodiesel and glycerine solution were exposed to temperaturesthat were above the boiling point, the methanol would evaporatefrom the solution where it could then be condensed and stored.There are two ways to expose the biodiesel and glycerine to asituation where the alcohol is above its boiling temperature.
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These are by:
i) Pressure reduction.
ii) The addition of heat.
3.4.3.4.2 (i) Pressure Reduction
The first method is to decrease the pressure of the solutionwhereby the boiling point is reduced. This could be done byplacing the solution into a vacuum vessel where a vacuum pumpwould be employed to lower the pressure within the vessel untilthe alcohol starts to boil out. The advantageof this method is thatit can be performed using less energy than the second method.However, the actual device that recaptures and condenses thealcohol can become quite complicated and expensive tomanufacture. This particular method will also require the use of apotentially expensive vacuum pump and vessel.
3.4.3.4.3 Critical Factor Analysis: Pressure Reduction
Power: The power used in this method is generally less than thatused within the second method as the power consumed within theprocess is via the vacuum pump.
Cost: The cost of this system could be quite high for this project.The main cost involved is the pressures vessel, the vacuum pump
and the associated parts and fittings to manufacture thecondensation system.
Reliability: The reliability of this system is basically dependentupon cost. The main components that may have reliability issuesare the vacuum pump and the vacuum vessel. However, providedthat the correct vacuum pump and vessel have been
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suitably selected and constructed for the task it would not be alarge concern. If the unit were made properly and without the
compromise of quality components, the system would be veryreliable.
Safety: This system is much safer than the second alternative asit does not require a great deal (if any) of heat to be introducedinto the system. The outlet of the vacuum pump also needs to bechanneled off to a well ventilated sink to prevent the build upof methanol vapour.
Provided that the vacuum pump were the correct unit for the taskand that the outlet ofthe vacuum pump were vented to anappropriate sink, the risk of fire and sitecontamination is very low.
Functionality: This method of removing a particular product(alcohol in this case) from a solution has been used quitefrequently in the petrochemical industry and is very effectiveprovided that it is set up properly. In most cases the product thatis being removed can be done so more thoroughly using this
technique as opposed to the other. In terms of the functionality,this system will be able to extract more alcohol from the solutionquicker and with less energy when compared to the other method.
Maintainability: Provided that the system were designed so thateach component could be accessed quite easily, the system willbe easy to maintain. While the pump and vacuum vessel arespecialty items, there should not be a problems replacing or
repairing these items.
Manufacturability: This system would be quite difficult tomanufacture on a budget. It is hard to build a system like thiswhen the most desirable parts can not be used dueto cost restrictions. Construction quality also needs to be closelymonitored as this vessel needs to be completely air tight and beable to hold a vacuum for it to work.
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3.4.3.4.4 ii) Addition of Heat
The second and most obvious method of recapturing the alcoholis quite straight forward. The solution is heated in some way untilit reaches a temperature above the boiling point of the alcoholwhere the alcohol would then evaporate out. The advantage ofthis system is that it requires no special vacuum vessel or pumpand the systems used to capture the evaporated methanol arequite cheap and simple to manufacture.
3.4.3.4.5 Critical Factor Analysis: Addition of HeatPower : The power used by this system could be quite high,especially in larger applications. While the specific heat ofvegetable oil is quite low, in larger volumes of biodieselproduction, the energy required to heat the solution up to over64.7C may be quite high. For this situation howeve r, the powerwould not be excessive.
Cost: The low setup cost is the major advantage of this system.For small volume applications of say
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to be very reliable so there should be no significant reliabilityissues within this design.
Safety : The safety of this system may be compromised if theheating elements heat up to a temperature above the auto ignitiontemperature of the mixture. There may also be an ignitionproblem if the heating elements became exposed while methanolis being boiled out of the solution. Both of these problems can berectified by ensuring the heating elements are always submergedin the solution and that a sufficient stirring action is provided
within the system to eliminate any stagnation that may occur.
Functionality : This method of separating the methanol from thesolution is, and has been proven to be quite effective. Providedthat a sufficient condensing system is in place to capture themethanol vapour, heating a solution to remove alcohol is quiteeffective. An advantage of this system is that, the same heatingelements used to heat the solution to increase the rate of reactioncould be used to further heat the solution to remove the methanol
from the system. So essentially he heating system would havemultiple requirements.
Maintainability: As the heating system used to remove the alcoholfrom the system would be the same heating system that was usedto increase the rate of reaction, it has already been determinedthat the heating system alone will not cause any significantreliability problems.
Manufacturability: As the heating elements would already be inplace as they will be used to increase the rate of reaction, noadditional heating elements will be required. However, some formof condenser would need to be incorporated in the system sothat the methanol vapour were captured, condensed and reused.
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3.4.3.4.6 Which method to use?
Both systems have very good qualities in terms of functionality,however, as always, the distinguishing factors which will dictatethe solution that is used is based around cost. While it is possibleto develop a superior methanol removal system using thepressure reduction technique, this system would be quite costlyfor it to be as reliable as the heating system. As there is a certaincost constraint placed on the construction materials used withinthe prototype, using the pressure reduction technique toremove methanol from the system is not economically feasible inthis instance. All is not lost however, the second system whichutilises to vaporise the methanol from the solution can be easilyand cheaply incorporated into the reactor design. As the reactoralready has its own heating system to increase the rate ofreaction, this heating system can be put to further use by alsobeing utilised to heat the solution further to vaporize the methanol.Therefore, no additional heating system is required and it can beconcluded that heat will be used as the primary technique to
remove methanol from the system.
3.4.3.4.7 Methanol Condensation
From the previous section it has been determined that heat will beused to vaporise the alcohol out of the solution. It was alsodetermined that no additional heating system would need to beincorporated within the reactor as there is already a heating
system available to increase the rate of reaction. What is requiredhowever is a system that catches and condenses the methanolvapour for reuse in the next batch. So, what happens with themethanol once it starts to vaporise from the solution? Themethanol will rise, and will continue to rise until it has eithercondensed on a surface, or dissipated in the atmosphere. Ofcourse the latter of the possibilities should be avoided as valuablemethanol will be lost.
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So it can be stated that the first requirements of the design
(provided that it does not operate on vacuum) is to incorporate asurface for the methanol vapor to condense on. Simple, put a roofon the reactor and keep it sealed.
Figure 3.11: Reactor with heating elements vaporising methanol
But where will the methanol go? It will simply condense on theroof an fall back into the solution from which the methanol is beingremoved from. So some how, the system that condenses themethanol needs to channel off the methanol to some
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external reservoir. If the lid of the reactor were tapered toward thecentre like an upside down witches hat, the methanol vapour
would condense on the roof of the reactor and fall to thecentre of the tapered lid. If a tundish arrangement where thenfitted underneath the lid, the condensed methanol could fall intothe tundish and be channelled out of the reactor via a pipe whichled to the outside. The methanol would then be in a condensedand ready to be reused for the next batch of biodiesel.
Figure 3.12: Reactor with heating elements and condenser
The figure 3.12 displays the reactor fitted with a condensingdevice to capture the methanol being evaporated out of the rawbiodiesel. The way this technique works is that the raw biodieselis heated to a temperature above the boiling point of the
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methanol whereby the methanol starts to boil. Once the methanolstarts to boil, methanol vapour will rise out of the raw biodiesel
toward the tapered roof of the reactor. The vapour will thencondense on the roof and fall toward the small protrusion in thecentre of the taper. The small protrusion will act as a region wherethe methanol can form small droplets which will fall and becaptured by the tundish.
The pipe mounted to the tundish will then channel the condensedmethanol to the outside of the tank. It should be noted that for the
methanol to proceed to the outside of the tank, the pipechannelling the condensed methanol out of the tank should havea slight fall. For example, where the pipe is attached to thetundish should be at a higher position than where the pipe isducted to the outside. This will ensure that the methanol will bechannelled toward the outside of the tank due to gravity, wherethe methanol can then be stored.
3.4.3.4.8 Critical Factor Analysis: Condenser
Power: The condenser itself will not use any power.
Cost: The cost of the condenser will be very low as there are veryfew parts involved.It would require several hours to construct however, as areasonable degree of accuracy will need to be achieved for this
technique to be successful.
Reliability : There should be no reliability issues associated withthis design provided that the correct materials were used and thatconstruction was completed properly.
Safety: The major safety concern with the condenser is related towhat happens with the methanol after it has condensed. Provided
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that the methanol is channelled off to a safe containing vesselwith no leaks along the way, there should be no safety issues
with the condenser.
Functionality : Provided that this technique was set up correctly,this method of condensing methanol would work very well. Similarmethods have been tested andproven in stills and other devices to make alcoholic beverages(This was found out after this design had been devised).
Maintainability : This method would be relatively maintenancefree. The only problem which may occur is that some soap scummay build up in the catchment area of the condenser however,this is highly unlikely. If this did occur it could be easily removedby compressed air, water or some other method.
Manufacturability : The condenser would require some skill tomanufacture however, this should not be that difficult, but moretime consuming. The parts required by the system would be easy
to acquire and would be available locally. Overall, this condensersystem should not be a problem to manufacture.
3.4.3.4.9 Conceptual Design Proposal: Waste Recovery System
The above condenser design is quite a feasible method ofcondensing the methanol which could be easily incorporatedwithin the system. This method is a cheap, reliable and functional
solution that would be easy to manufacture and would requireonly very little operator interaction when in use. It can beconcluded that it is not necessary to analyse any other designs atthis stage, as this technique already satisfies all therequirements of a feasible solution.
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Therefore, the proposed methanol removal system will be basedon heating and condensing techniques whereby, the conceptual
design can be seen below.
Figure 3.13Reactor with glycerine removal system, heating elements and acondenser.
3.4.4 Purification
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The purification process is one of the crucial processes that willdetermine the quality of the finished product. This process is
commenced after the methanol has been removed from the rawbiodiesel. So essentially, all that is remaining are some tracesof glycerine, soap and acid and hopefully, if the transesterificationprocess has completed properly, a very low free fatty acid level.It is the purification process that is responsible for removing thesecontaminants, and it is therefore the functional requirementofthe system to:
Remove the impurities that remain in the raw biodiesel.
Once the impurities have been removed the fuel is ready to go.However, it is not that simple to remove these impurities bothcheaply and effectively.
The specific design requirementof the system is:
The proposed system must not increase the cost of the biodiesel
beyond the point at which it is not longer economically feasible(costs more produce than diesel does to buy).
The proposed purification system must be capable of producinga fuel that can meet the ASTM standards.
There are only a limited amount of techniques that can be used topurify biodiesel and unfortunately most of them are limited to large
volume plants in order to maintain economic feasibility. The onlypurification techniques that remain feasible for low productionunits are:
1. Purification through Water.
2. Purification through Absorbent Powder.
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3.4.4.1 Purification through Water
Purification through the use of water has been very popular forsmaller producers of biodiesel as it is cheap and reasonablyeffective method of biodiesel purification,provided that it is done correctly. The way that the water purifiesthe biodiesel is through physically mixing water with the rawbiodiesel. It sounds like quite a primitive method, and it is, but it
works. Below is an illustration of how the system works
Figure 3.14: Typical Water Purification Process
Figure 3.14 displays a typal water purification process. The firststep to the process is to add clean water up to a ratio of 1:1 to theraw biodiesel. The water is then gently mixed through the rawbiodiesel and absorbs any water soluble impuritiesout of the raw biodiesel. As the water is being mixed through it willquickly turn a milky white colour indicating the presence of soap.
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The water and raw biodiesel is then allowed to settle and thewater is removed as waste. The process is repeated several
times until the water remains clear which will indicate thebiodiesel is reasonably clean.
Now, anyone who has had anything to do with water coming intocontact with oil will know that it is a bad idea. The first majordownfall of this process is, if the water is mixed too excessivelywith the oil, it will create a mayonnaise like emulsion. If thishappens it will takes quite some time to settle out, several days,maybe even weeks and this problem is characteristic of thisprocess. Also, water can be quite a rare commodity in someplaces. To be wasting such a valuable resource (up to 4 times theamount of fuel produced by volume) on biodiesel, a fuel intendedto be more environmentally friendly, does not make sense. On topof the large amount of water required, the waste water can bepotentially damaging to the environment and can bedifficult do dispose of.
There is a another major down fall, and that is caused bybiodiesels affinity to water. Although water is generally notsoluble in biodiesel, biodiesel still has some affinityto water and a small amount will remain in the fuel unless it isremoved. Obviously water within the fuel system of a vehicle ishighly undesirable so any excess water needs to be removed ifthis process is used.
And the final major down fall, which is the most disappointing ofall is that, when the fuel has been purified and the final washwater is clear and any remaining water in thebiodiesel has been removed, the biodiesel will still not be safe touse. The water used to wash the biodiesel will only absorb thewater soluble impurities out of the biodiesel. What remains are theoil soluble impurities such as any remaining free fatty acids,glycerine and vegetable gums. So even after the water
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purification process is complete the final product can stillpotentially harm the fuel system of the engine it is
being used in.
So the question is now, why would anyone use water washing?The answer is simple, it is a cheap and relatively effective methodof removing the water soluble impurities from raw biodiesel. Thefuel can still be used offcourse, and in many cases the fuelwill not cause a problem with the fuel system, however, in manycases it will.
In modern fuel delivery systems however, diesel injector pumpsare generally less robust, deliver higher pressure (increasedstress) and also have much finer injector orifices. If a fuel that isless than satisfactory is used in such a system, there will mostcertainly be some problems. One of many problems caused by apoor quality biodiesel is fuel injector coking. It is not surprisingthat users of water purified biodiesel are those which experiencethis problem the most.
Summarising the advantages and disadvantages of using water topurify biodiesel we find:
Advantages: Very cheap, water is free (in most places).
Disadvantages:
Uses excessive amounts of water (up to 4 times the amount ofbiodiesel produced).
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The waste water can be harmful to the environment.
Does not purify the biodiesel to a satisfactory level.
Takes a long time to complete (several days).
Risk of mayonnaise like emulsion.
And the list goes on. Without further investigation into the criticalfactors, it can already be determined that using water to purify the
biodiesel will not be a feasible option.
3.4.4.2 Purification through Absorbent Powder
Another method of purifying biodiesel which is starting to becomemore commonly used, is through the use of an impurity absorbing
powder. The powder that is used for this process is call SyntheticMagnesium Aluminium Silicate, or in simpler terms, a synthetictalcum powder. The way this method of purification works is bysimply adding the powder to the raw biodiesel, mixing it throughfor approx 20 minutes, and filtering the powder out . A system thatcould be incorporated into the reactor is illustrated below :
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Figure 3.15: Reactor with glycerine removal system,heating elements, condenser and powder purification system.
The first step with this system is to firstly ensure all glycerine
has been removed and the methanol has been evaporated offand condensed. Once these steps have been completed theabsorbent powder can be added to the system through thePowder Inlet where the recirculation pump will be turned on tomix the powder through. This would be done for several minutesto allow the powder to absorb all of the impurities from thebiodiesel.
After several minutes have passed, the recirculation pump canthen be turned off and the small pump turned on to pump thebiodiesel through the fine filter. The filter then removes thepowder resulting in a very clear, low impurity biodiesel.
The advantagesof purifying biodiesel with this powder are that:
The powder absorbs both water soluble and oil solubleimpurities resulting in a very high quality biodiesel.
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Power : The power consumed in this process is through therecirculation pump and the small pump. Neither pump will
consume an excessive amount of electricity.
Cost: The additional cost incurred by purifying biodiesel with thismethod is the major downfall. At $12-$14 per kg this can increasebiodiesel production costs by 12-23c/litre. While this may seemlike a lot, the biodiesel will generally remain cheaper to producethan diesel. Obviously these costs could also be reduced if thefuel was being produced in larger volumes as both the methanol
and the absorbent powder will be cheaper in bulk.
Reliability : Provided that a reliable filter and housing is used toremove the powder from the fuel, there should be no problemsthere. While it is unlikely, there may be a problem with theabsorbent powder increasing the rate of wear on the recirculationpump. The absorbent powder is quite fine and abrasive so careshould be taken to select a durable recirculation pump. Also, areliable measuring device needs to be obtained so that the correct
amount of absorbent powder can be added to the systemwith a reasonable level of consistency and accuracy.
Safety : This method of purification is very safe as all that isrequired is to simply add some powder to the system, mix it withthe recirculation pump, and filter the powder. The only operatorinteraction in this instance would be measuring the powder andadding it into the tank.
While the absorbent powder relatively harmless, the operator stillneeds to take care not to inhale excessive amounts of the powderwhile it is being measured. Also care should be taken not toexpose the vapours within the tank to an ignition source whenthe powder is added to the tank. Other than these minor points,this system is safe and should not cause any problems.
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Functionality : This method is very good at removing theimpurities from raw biodiesel and results have shown that if the
process has been completed correctly, the quality of biodieselproduced meets and exceeds the ASTM standards.This technique is also very easy and quick to perform, especiallycompared to that of water purification. While water purificationmay be cheap, it takes time to produce.
As time is money, it is debatable as to whether water purificationis cheaper than absorbent powder purification at all. Overall, this
technique is a very functional and user friendly method to purifybiodiesel.
Maintainability: The majority of the maintenance with this systemwill be with the filtration system. Depending on the volume ofbiodiesel that is being produced, the filter cartridge will need to bereplaced accordingly. There should not be any other maintenanceissues.
Manufacturability : This system would be very easy tomanufacture as there are only a few components required toinstall this system. The majority of the work involved would bewith the plumbing, which would not be difficult. Overall, thissystem would be quite easy to incorporate.
3.4.4.4 Which method to use?
It is not difficult to see that biodiesel purification through theaddition of absorbent powder is certainly the best method to usewhen compared to that of water purification. This method hasbeen proven by many successful biodiesel manufacturesand is currently used in both low and high production plants with ahigh success rate.
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PRODUCTION AND TESTING
OF WVO IN DCE
LABORATORIES
ObjectivesThe objectives of this chapter are to produce the biodiesel andtest for its various physical and chemical properties.Based on the results obtained in this chapter, an evaluation will
be made as to how well biodiesel compares to diesel in terms ofperformance.
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4.1 IntroductionThis chapter will firstly discuss the laboratory scale manufacturing
of biodiesel and then discuss how the physical and chemicalproperties compare with that to diesel. The results willthen be analysed. Finally a summary of important results will betabulated and a conclusion will be drawn.
4.2 Vegetable Oil to BioDiesel Via Transesterification
Method
A one liter batch of waste vegetable oil is taken and biodiesel is
being manufactured from it. The process involves a trans-esterificaiton, or converting one ester to another.
In this case we take the triglyceride molecule, and split off theglycerol (a three carbon alcohol) and replace it with a methanolmolecule (a single carbon alcohol) with the use of a caustic basecatalyst (sodium hydroxide). We are using NaOH (sodiumhydroxide). KOH (potassium hydroxide) may also be used.
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The glycerol layer will settle out as a bottom layer due to its higher
specific gravity. The biodiesel, or methyl ester, will float abovesince it is lighter. The glycerol can then be carefully drained offleaving a crude biodiesel product.
The interesting part is that all of the materials and ingredients maybe obtained from our home itself or from local departmental store.The result will be a diesel fuel substitute that will run any dieselengine without modification. The washing, drying, and filtering
steps that would complete biodiesel operation have also beendone in the laboratory itself and they can be done even at homewith minimum cost and great ease.
Raw Materials required:
One liter of waste vegetable oil. One 2 liter (thoroughly clean) bottle, rinsed and totally dry.
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4.2.1. Procedure for Manufacturing of Biodiesel
DAY 1
1 Measure 200 mL of methanol directly into the conical flaskpresent with a lid.
2. Measure in 5 g of NaOH, sodium hydroxide on the digital scaleand pour it into the flask.
3. Screw on the lid very tightly and carefully. It will generate someheat, but