APPLICATIONS Energy, electronics, sensors, bio- medical , composites and many more. THE GRAPHENE & 2D MATERIALS GLOBAL OPPORTUNITY REPORT Forecast from 2010 to 2025 Production volumes, prices, future projections and end user markets. COMPANIES All graphene companies profiled. MARKETS Market opportunities. TECH Current and future products. EDITION 1 JUNE 2016 £1000 FUTURE MARKETS www.futuremarketsinc.com
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THE GRAPHENE & 2D MATERIALS GLOBAL OPPORTUNITY REPORT€¦ · THE GRAPHENE & 2D MATERIALS GLOBAL OPPORTUNITY REPORT Forecast from 2010 to 2025 Production volumes, prices, future projections
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APPLICATIONSEnergy, electronics, sensors, bio-medical , composites and many
more.
THE GRAPHENE & 2D MATERIALS GLOBAL OPPORTUNITY REPORTForecast from 2010 to 2025Production volumes, prices, future projections and end user markets.
Two-dimensional (2D) materials are currently one of the most active areas of nanomaterials research, and offer a huge opportunity for both fundamental studies and practical applications, including superfast, low-power, flexible and wearable electronics, sensors, photonics and electrochemical energy storage devices that will have an immense impact on our society.
Graphene is a ground-breaking 2D material that possesses extraordinary electrical and mechanical properties that promise a new generation of innovative devices. New methods of scalable synthesis of high-quality graphene, clean delamination transfer and device integration have resulted in the commercialization of state-of-the-art electronics such as graphene touchscreens in smartphones and flexible RF devices on plastics.
Beyond graphene, emerging elementary 2D materials such as transition metal dichalcogenides, group V systems including phosphorene, and related isoelectronic structures will potentially allow for flexible electronics and field-effect transistors that exhibit ambipolar transport behaviour with either a direct band-gap or greater gate modulation.
Graphene exhibits a unique combination of mechanical, thermal, electronic and optical properties that provide opportunities for new innovation in:
Electronics & photonics
• Conductive electrode films for flexible displays. • 2D printable and transparent ultrathin electronic devices. • 2D transistors and circuits. • RFID tags. • 2D magnetic semiconductors. • Conductive inks for wearable electronics. • 2d MOSFETs. • Inkjet-printed electronics. • Flexible Graphene FETs. • Flexible TMD FETs for digital logic and RF.
• Comprehensive quantitative data and forecasts for the global graphene and 2D materials market to 2025 including key market opportunities.
• Qualitative insight and perspective on the current market and future trends in end user markets based on interviews with key executives.
• End user market analysis and technology timelines. • Financial estimates for the markets graphene and 2D materials will impact,
including addressable market size, applications and key opportunities. • Patent analysis. • Competitive analysis of carbon nanotubes versus graphene. • Comparative analysis of graphene and other 2D Materials. • Tables and figures illustrating graphene market size. • Full company profiles of graphene producers and application developers
including technology descriptions and end user markets targeted • Profiles of prominent research centres. • Industry activity and breakthroughs by market 2013-2016.
Table 2: Graphene target markets-Applications, stage of commercialization and potential addressable market size...................................................................................................... 50
Table 3: Graphene producers annual production capacities...................... 53
Table 4: Global production of graphene, 2010-2025 in tons/year. Base year for projections is 2014. 55
Table 5: Graphene types and cost per kg....................................................... 58
Table 6: Categorization of nanomaterials........................................................ 69
Table 7: Properties of graphene........................................................................ 75
Table 8: Comparative properties of carbon materials.................................... 82
Table 9: Comparative properties of graphene with nanoclays and carbon nanotubes. 85
Table 10: Competitive analysis of Carbon nanotubes and graphene by application area and potential impact by 2025............................................................................. 87
Table 11: Electronic and mechanical properties of monolyaer phosphorene, graphene and MoS2. 92
Table 12: Recent phosphorene research news................................................ 94
Table 13: Recent silicene research news........................................................ 101
Table 14: Recent Molybdenum disulfide research news.............................. 107
Table 15: Recent hexagonal boron nitride research news........................... 112
Table 16: Recent germanane research news................................................ 115
Table 17: Recent stanene/tinene research news.......................................... 123
Table 18: Recent tungsten diselenide research news................................... 125
Table 19: Comparative analysis of graphene and other 2-D nanomaterials. 132
Table 20: Large area graphene films-Markets, applications and current global market. 134
Table 21: Graphene oxide flakes/graphene nanoplatelets-Markets, applications and current global market........................................................................................................... 135
Table 22: Main production methods for graphene....................................... 137
Table 23: Graphene synthesis methods, by company................................. 164
Table 25: Published patent publications for graphene, 2004-2014............. 178
Table 26: Leading graphene patentees........................................................ 180
Table 27: Industrial graphene patents in 2014............................................... 181
Table 28: Market penetration and volume estimates (tons) for graphene in key applications. 238
Table 29: Global production of graphene, 2010-2025 in tons/year. Base year for projections is 2014. 239
Table 30: Graphene producers and production capacity (Current and projected), prices and target markets.......................................................................................................... 242
Table 31: Graphene in the electronics and photonics market-applications, stage of commercialization and addressable market size...................................................................... 250
Table 32: Comparison of ITO replacements................................................... 254
Table 33: Graphene product and application developers in transparent conductive films. 267
Table 34: Comparative properties of conductive inks.................................. 270
Table 35: Opportunities for graphene and 2D materials in printed electronics. 272
Table 36: Graphene product and application developers in conductive inks. 276
Table 37: Graphene product and application developers in transistors and integrated circuits. 286
Table 38: Graphene product and application developers in memory devices. 295
Table 39: Graphene properties relevant to application in optical modulators. 297
Table 40: Dispersion of graphene in polymers................................................ 305
Table 41: Graphene in the polymer composites market-applications, stage of commercialization and addressable market size.............................................................................. 307
Table 43: Graphene properties relevant to application in polymer composites. 309
Table 44: Graphene product and application developers in the composites industry. 313
Table 45: Graphene in the aerospace market-applications, stage of commercialization and addressable market size.............................................................................. 319
Table 46: Graphene product and application developers in the aerospace industry. 322
Table 47: Graphene in the automotive market-applications, stage of commercialization and addressable market size.............................................................................. 327
Table 48: Graphene product and application developers in the automotive industry. 330
Table 49: Graphene in the biomedical and healthcare markets-applications, stage of commercialization and addressable market size..................................... 336
Table 50: Graphene properties relevant to application in biomedicine and healthcare. 338
Table 51: Graphene product and application developers in the biomedical and healthcare industry........................................................................................................................ 347
Table 52: Graphene in the coatings market-applications, stage of commercialization and addressable market size.................................................................................................... 355
Table 53: Graphene properties relevant to application in coatings........... 358
Table 54: Graphene product and application developers in the coatings industry. 372
Table 55: Graphene product and application developers in the filtration industry. 380
Table 56: Graphene in the energy market-Applications, stage of commercialization and addressable market size.................................................................................................... 383
Table 57: Comparative properties of graphene supercapacitors and lithium-ion batteries. 394
Table 58: Graphene product and application developers in the energy industry. 407
Table 59: Graphene in the sensors market-applications, stage of commercialization and addressable market size.................................................................................................... 414
Table 60: Graphene properties relevant to application in sensors.............. 419
Table 61: Comparison of ELISA (enzyme-linked immunosorbent assay) and graphene biosensor. 426
Table 62: Graphene product and application developers in the sensors industry. 429
Table 63: Graphene properties relevant to application in 3D printing....... 433
Table 64: Graphene product and application developers in the 3D printing industry. 435
Table 65: Graphene properties relevant to application in adhesives........ 438
Table 66: Graphene product and application developers in the adhesives industry. 439
Table 67: Applications of carbon nanomaterials in lubricants.................... 441
Table 68: Graphene product and application developers in the lubricants industry. 443
Table 69: Desirable functional properties for the textiles industry afforded by the use of nanomaterials........................................................................................................................ 445
Table 70: Graphene producers and types produced.................................. 449
Table 71: Graphene industrial collaborations and target markets.............. 452
FIGURES
Figure 1: Global government funding for graphene....................................... 49
Figure 2: Global market for graphene 2010-2025 in tons/year....................... 56
Figure 7: Graphene can be rolled up into a carbon nanotube, wrapped into a fullerene, and stacked into graphite................................................................................................... 81
Figure 12: Structure of 2D molybdenum disulfide.......................................... 102
Figure 13: Atomic force microscopy image of a representative MoS2 thin-film transistor. 105
Figure 14: Schematic of the molybdenum disulfide (MoS2) thin-film sensor with the deposited molecules that create additional charge................................................................... 106
Figure 15: Structure of hexagonal boron nitride............................................ 110
Figure 16: Schematic of germanene............................................................... 113
Figure 25: TEM micrographs of: A) HR-CNFs; B) GANF® HR-CNF, it can be observed its high graphitic structure; C) Unraveled ribbon from the HR-CNF; D) Detail of the ribbon; E) Scheme of the structure of the HR-CNFs; F) Large single graphene oxide sheets derived from GANF. 141
Figure 26: Graphene nanoribbons grown on germanium............................ 145
Figure 27: Roll-to-roll graphene production process...................................... 157
Figure 28: Schematic of roll-to-roll manufacturing process........................... 158
Figure 29: Microwave irradiation of graphite to produce single-layer graphene. 163
Figure 30: Schematic of typical commercialization route for graphene producer. 167
Figure 31: Published patent publications for graphene, 2004-2014............ 179
Figure 32: Technology Readiness Level (TRL) for graphene........................... 183
Figure 33: Global market for graphene 2010-2025 in tons/year................... 241
Figure 35: A large transparent conductive graphene film (about 20 × 20 cm2) manufactured by 2D Carbon Tech. Figure 24a (right): Prototype of a mobile phone
produced by 2D Carbon Tech using a graphene touch panel............................................................................... 259
Figure 36: Graphene electrochromic devices. Top left: Exploded-view illustration of the graphene electrochromic device. The device is formed by attaching two graphene-coated PVC substrates face-to-face and filling the gap with a liquid ionic electrolyte............. 261
Figure 38: The transmittance of glass/ITO, glass/ITO/four organic layers, and glass/ITO/four organic layers/4-layer graphene.............................................................................. 266
Figure 42: Schematic cross-section of a graphene based transistor (GBT, left) and a graphene field-effect transistor (GFET, right)........................................................................ 280
Figure 43: Graphene IC in wafer tester........................................................... 283
Figure 44: Graphene oxide-based RRAm device on a flexible substrate.... 290
Figure 45: Layered structure of tantalum oxide, multilayer graphene and platinum used for resistive random access memory (RRAM)................................................................ 293
Figure 46: A schematic diagram for the mechanism of the resistive switching in metal/GO/Pt. 294
Figure 51: Graphene Frontiers’ Six™ chemical sensors consists of a field effect transistor (FET) with a graphene channel. Receptor molecules, such as DNA, are attached directly to the graphene channel........................................................................................................ 343
Figure 52: Graphene-Oxide based chip prototypes for biopsy-free early cancer diagnosis. 344
Figure 53: Global Paints and Coatings Market, share by end user market. 355
Figure 54: Heat transfer coating developed at MIT....................................... 357
Figure 55: Water permeation through a brick without (left) and with (right) “graphene paint” coating........................................................................................................................ 366
Figure 56: Four layers of graphene oxide coatings on polycarbonate....... 371
Figure 57: Degradation of organic dye molecules by graphene hybrid composite photocatalysts. 379