Aromatic Yield Increases with Heating Rate
Reaction Conditions: Temperature 600oC; ZSM-5; Feed: Glucose;
Catalyst to Feed Ratio 19C6O6H12 → 12/22 C7H8 (63 % Yield) + 48/22
CO (36 % Yield) + 84/22 H2O
0
5
10
15
20
25
30
35
40
45
1 10 100 1000Nominal heating rate (°C s-1)
Carb
on y
ield
(%)
Aromatics Carbon monoxideCarbon dioxide coke
Carlson, T.R.; Vispute, T.P.; and Huber, G.W.; Green Gasoline by
Catalytic Fast Pyrolysis of Solid Biomass-derived Compounds,
ChemSusChem, 1, 397-400 (2008).
Selectivities (2)
BenzeneBenzeneBenzeneBenzene
TolueneTolueneTolueneToluene
Xylenes, ethyl-benzeneXylenes, ethyl-benzeneXylenes,
ethyl-benzeneXylenes, ethyl-benzene
Methyl-ethyl-benzene, trimethyl-benzeneMethyl-ethyl-benzene,
trimethyl-benzeneMethyl-ethyl-benzene,
trimethyl-benzeneMethyl-ethyl-benzene, trimethyl-benzene
IndanesIndanesIndanesIndanes
NapthalenesNapthalenesNapthalenesNapthalenes
CokeCokeCokeCoke
Glucose
Cellobiose
Cellulose
Xylitol
Selectivity (%)
12.9792209643
12.9238172581
11.0495115501
11.5419684189
21.5656347771
22.0954515898
20.3152491336
19.733840689
14.2728383261
14.471321865
15.8625765825
16.9804699675
3.2459675372
3.2872082023
4.0669216011
4.7095296295
4.2802810346
4.8589898264
5.5333155842
6.9736185411
43.6560573608
42.3632112584
43.1724255484
40.060572754
37.4990650292
36.8036772439
34.2557261186
35.7290723283
coke runs
sample numberconditionpercent CC per mginitial carbonyield
31000/400/2401.510.01510.020800646772.5938968248
81000/500/2400.930.00930.020800646744.7101483755
11000/600/2400.690.00690.020800646733.1720455689
71000/700/2400.570.00570.020800646727.4029941656
21000/800/2400.530.00530.020800646725.4799770312
41/600/2400.810.00810.020800646738.9410969722
55/600/2400.740.00740.020800646735.575816987
650/600/2400.710.00710.020800646734.1335541362
91000/600/240 cb0.630.00630.020973733130.0375711129
101000/600/240 ce0.60.0060.020973733128.6072105837
111000/600/240 xy0.790.00790.021066558637.5001923564
zsm1010%1.30.0130.040232029832.3125630904
zsm1120%3.450.03450.079195899243.5628616367
zsm1230%50.050.119959014141.6809027509
zsm1340%7.010.07010.159824578943.8605879409
nap expw+cw+c+smassmass naparea outmass napyeildarea/mass in
trc02p430.00E+000.000.50
trc03p43400108.48122.041.36E+010.13900163037895868750.070.505680414488.880.11
trc04p43800108.46122.791.43E+010.14689479087037492260.060.424790838547.10
trc05p43800.00108.40125.121.67E+010.15265656128880826870.080.515817520584.34
trc06p43400.00106.82124.481.77E+010.161238927710054117370.090.556235539714.900.520.0345821407
0.470.0639582945
0643520969
0631511537
0510842863
0486061264
0547373330
GlucoseCellobioseCelluloseFurfural
0000
0000
0000
1001001000
calibrations
CO, CO2 calnew runs
sample nameml dil CO (2%)mass COarea ion 28aveml dil CO (2%)mass
CO (mg)sample namearea ion 28average
0.50.012537279057370295260.50.01145trc20p131.94E+0719111082
0.50.0125367799950.50.01145trc21p131.88E+07
10.0254229618343232201.510.0229trc22p133.14E+0731386458
10.0254416822010.0229trc23p133.14E+07
2.50.0625185883937214797326.6666672.50.05725trc24p135.86E+0758254240
2.50.06252225244392.50.05725trc25p135.79E+07
2.50.06252359836041.50.03435trc26p134.29E+074.29E+07
ml dil CO2mass CO2area ion 44ml dil CO2mass CO2sample namearea
ion 44
0.250.0198192783916144506394.66666710.0792272.15E+082.13E+08
0.250.019812487524210.0792282.11E+08
0.250.01981158600260.250.0198297.52E+077.41E+07
0.50.0396299717644280786629.50.250.0198307.31E+07
0.50.03962618556150.50.0396311.49E+081.49E+08
10.0792328988971336992908.3333330.50.039632
10.079236435107620.1584332.70E+082.75E+08
10.079231763867820.1584342.80E+08
2.50.19835302206699294033471
2.50.19836285860243
0.29740391560263391560263
0.29741402403957
ml dil CO (30%)
0.250.085875trc01p15162725660167207264.5
0.250.085875trc02p15171688869
0.50.17175trc03p15257766352258659856
0.50.17175trc14p15259553360
10.3435trc04p15362769741357051579.5
10.3435trc05p15351333418
weight loss from the
catalyst1.50.51525trc06p15457922351457922351
1.50.51525trc07p15
sample namecap+woolcap+wool+sampmass cat (mg)area of water (ion
18)20.687trc08p15516580296516580296
trc01p10115.94127.2911.3522577183420.687trc09p15
trc02p10113.03119.146.112151471972.50.85875trc10p15672955337
trc03p10112.4116.754.352004747042.50.85875trc11p15672955337
trc04p10114.71123.328.614048076170.10.03435trc12p158835577986344533
trc05p10113.28126.1212.846122000890.10.03435trc13p1584333287
trc06p10110.22116.436.213068243590.050.017175trc15p154686024544484281.5
0.050.017175trc16p1542108318
BTEXN calibration
sample nameamount injectedarea benzavearea tolarea xylenearea
napmass compound (mg)area/mass
trc18p111ml758828916.43E+07632871695451977659937805570585216.02E+07552468490.002299689025000.99530327181.05092147391.2600810071
trc19p111ml6430769252864152587994525.49E+070.002293997260001.07085174480.96275845241.1711674487
trc20p111ml5264877847408007524383065.06E+070.002262191530001.03610794780.93671624021.0402665816
trc21p112ml899543948.97E+07746847257221070575916934747661316.68E+07696558440.004189792335001.13609504771.11765507041.3461652909
trc22p112ml8938962469736685736153287.25E+070.004184038320001.01553802820.96203137991.2331475654
trc23p113ml1069412029.38E+078224462479928143.66666678609993383649081.66666677.69E+0775762728.66666670.00614349988833.33331.11916312271.06905019571.3900666981
trc24p113ml8855088081070238832426667.68E+070.00613873777666.66671.08439070741.05609078811.1535400777
trc25p113ml8604373076469569816046467.36E+070.00613600774333.33331.10888982511.03911151081.169210595
trc26p115ml1219467841.24E+0810102264698884715.66666671070889351017699539.87E+0797766242.66666670.01107088935001.08487211481.02341714021.2353906167
trc27p115ml10477015592162751982753129.72E+070.0198275312001.01129768480.94839665041.0781325751
trc28p115ml146753075103468750999456129.74E+070.0199945612001.02602838791.0621964551.5065475907
1.0625943531.02075866881.234883277
nap cal
sample namewt%/100 napmass injectedareaave area
trc01p130.000140180.00011060221625232259571168533.3505748940.0745864372
trc03p130.000140180.0001106022302001
trc04p130.000140180.0001106022314189
trc05p130.000851630.00067193611225104312395637
trc06p130.000851630.000671936112540231
trc07p130.0016860.0013302542158171421933061
trc08p130.0016860.00133025422284408
trc09p130.0040240.0031749364429838844784706.5
trc10p130.0040240.00317493645271025
trc11p130.0064320.0050748487262862471814150.5
trc12p130.0064320.00507484870999677
trc13p130.0146020.011520978139097037136441921
trc14p130.0146020.011520978133786805
trc15p130.0183510.014478939151977601167098089.33333328773638.8627270.1721960974
trc16p130.0183510.014478939180617251
trc17p130.0183510.014478939168699416
trc18p130.0114780.009056142124649524121465509
trc19p130.0114780.009056142118281494
trc37p130.03550.0280095296386556293080559.50.0319051192
trc38p130.03550.0280095289774563
trc39p130.026890.021216212490559482490559489350770.17491597
0
furfural calibrationmass injectedareaarea ion 96
trc12p430.00748502150.00590568194264560644336637.584889888598994.5
trc13p430.00748502150.0059056819460276698709001
trc14p430.0154291680.012173613686031887809099201865053417631800
trc15p430.0154291680.01217361367578795316613066
0
0
calibration
0.789 mg injected
cal numbermass benzarea benzarea/massmass tolarea
tolarea/massmass naparea naparea/mass
cal
10.020277324271624311969850177.29180.0091445113039141214258982930.74210.003597847591029521098852366.9757
cal
20.003305915051965415281618071.87730.021460822053547910276200281.44340.010651512219676211472258555.1331
cal 310778306404607802702198297390
cal 1
(2)0.020277324508826512086829360.9110.0091445113352899714602094262.02170.003597846077729016892716185.2667
cal 2
(2)0.003305913821150811558544545.97980.02146082077425189680091981.659580.010651512153861011410468948.0355
cal 3 (2)10515788004042927802101963340
aromatic cal plot
225957144336637.58598994.5
123956378090992017631800
21933061
44784706.5
71814150.5
136441921
167098089.333333
121465509
293080559.5
249055948
napthalene
furfural
ion 96
area
mass (mg)
calibration for aromatics
0.000110602
0.0059056819
0.0059056819
0.0006719361
0.0121736136
0.0121736136
0.001330254
0.003174936
0.005074848
0.011520978
0.014478939
0.009056142
0.0280095
0.02121621
water calibration plot
13.3612.879.048.31
11.417.5610.7713.18
6.736.694.84
22-Sep
mass of catalyst (mg)
area of water peak
adsorbed water calibration
442535602
667226283
529216956
234618817
408440047
325455039
530515479
230456933
317698851
398861672
272114287
gas cal plot
167207264.5212704994
25865985674149032
357051579.5148774726
86344533275404142.5
44484281.5294033471
391560263
CO
CO2
area
mass (mg)
0.085875
0.0792
0.17175
0.0198
0.3435
0.0396
0.03435
0.1584
0.017175
0.198
0.297
main
sample namecapillary + wool (mg)capillary + wool + sample
(mg)total sample mass catalyst and reactat (mg)mass of reactant
(mg)mass of carbonmass of catalyst (mg)loss from cat
(mg)comments
trc06p07115.48124.128.641.73641900120.693962311120%physical
mix
trc07p07113.71123.039.323.75119129081.499168907940%mass glucose
(july 10)mass catfraction glucose
trc08p07114.63122.577.940.39519584510.15794057875%
trc09p07108.97117.418.440.83895487850.335289504510%glucose/zsm
5%0.06901.31730.0498
trc10p07115.01123.178.162.42984063170.971089247130%glucose/zsm
10%0.10310.93410.0994
trc11p07111.21121.8710.662.14238733250.856208129320%glucose/zsm
20%0.13200.52480.2010
trc12p07113.32121.468.140.40515040030.16191893085%glucose/zsm
30%0.20740.48910.2978
trc13p07111.67119.798.120.40415494480.16152109565%glucose/zsm
40%0.25880.38420.4025
trc01p09113.58122.528.940.88865599690.3551526268mass glucose
(july 25)
trc02p09112.79121.99.110.90555437720.36190608835%0.05471.01280.0512
trc03p09115.51124.028.510.84591303510.338070341610%0.09890.86320.1028
trc04p09112.12121.869.740.96817778630.3869336224aug 10
glucose
trc05p09110.14120.2410.11.00396259160.40123507055%0.0000
trc06p09113.93122.898.960.89064404170.355947151610%0.09180.81990.1007
trc02p17106.36116.8710.514.23015241061.69058639729/18/07
trc03p17106.21114.748.530.43708758780.1746826735%
trc04p17104.37115.0510.680.54725620610.218711717234.83597.520.0551
trc05p17106.94116.639.690.49652740050.19843787839/22/07
trc06p17107.31118.5911.281.15953850950.463411206329.61558.140.0504
trc07p170009/23/2007 G1
trc08p1700046.71880.410.0504
trc09p17108.54117.949.40.48166744730.1924990779/23/2007
G20.0000
trc10p17107.72120.2212.50.64051522250.255982815153.52991.750.0512
trc11p17108.78119.8911.110.56928992970.22751752619/24/2007 G3
p350.0000
trc12p17108.47118.29.730.97972359330.391547920539.98758.360.0501
trc13p17109.58119.8210.241.03107601180.41207098739/27/2007 G4
p35
trc15p17109.22119.6310.411.04819348470.418912009539.7721.960.0521
trc16p17106.84116.399.550.96159921030.38430448529/29/2007 G5
p350.0000
trc01p19107.39118.6311.241.13176702860.452312294668.861264.480.0516
trc02p19104.31116.1411.831.19117472850.4760546669/30/2007 G6
p350.0000
trc03p19106.82118.1311.311.13881539980.455129186136.38630.050.0546
trc04p19109.56121.9712.411.24957551830.49939462429/30/2007 G7
p350.0000
trc05p19108.7119.4110.711.07840078970.430984401772.47646.240.1008
trc06p19107.8120.112.31.23849950640.49496808049/30/2007 G1
p390.0000
000156.46589.880.2096
NEW RUNS (9-18-2007)0009/30/2007 G2 p390.0000
trc01p33106.27117.0110.740.59156195150.236418571163.58388.90.2961
trc02p33106.29117.2810.990.60533201550.24192179669/30/2007 G3
p390.0000
trc03p33108.4121.1912.790.70447647660.2815450208202.06301.610.4012
trc04p33106.89119.3212.430.68464758440.27362037610/01/2007 xy1
p390.0000
trc05p33108.13119.5211.390.6273641180.2507269576area
water42.72797.760.0508
trc06p33105.69119.0513.360.73587222270.2940923752442535602water
cal 110/01/2007 c1 p390.0000
trc07p33108.91120.3211.410.62846572310.2511672156408440047water
cal 29/18/0738.79720.440.0511
trc08p33105.35112.086.730.37069012410.1481468327317698851water
cal 310/01/2007 g4 p390.0000
trc09p33106.83119.712.870.70888289710.283306053667226283water
cal 1 fresh vacuum 9-1930.11546.80.0522
trc10p33106.79114.357.560.41640673680.166417541632545503910/01/2007
g5 p390.0000
trc11p33105.46112.156.690.36848691390.147266316639886167249.5907.680.0517
trc12p33107.48116.529.040.49792551590.198996637152921695610/01/2007
cb1 p390.0000
trc13p33108.96119.7310.770.59321435910.237078958153051547943.62769.420.0537
trc14p33108.46113.34.840.26658843990.106542447327211428710/08/2007
p39n10.0000
trc15p33107.11115.428.310.45771692890.1829272184234618817water
cal 19/22/0743.21312.660.0319
trc16p33107.63116.568.930.49186668780.1965752178water cal
210/08/2007 p39f10.0000
trc17p33105.04118.2213.180.72595777650.2901300527230456933water
cal 381.391294.780.0591
trc18p33104.56113.418.850.44585027650.178184693910/08/2007
p39n20.0000
trc19p33104.21117.6813.470.67859923440.271203144330.881239.160.0243
trc20p33106.26117.5911.330.5707891110.22811667610/10/2007
p39g70.0000
trc01p35107.81116.078.260.41615389590.16631649349/23/0755.711033.770.0511
trc02p35104.44113.789.340.47056626970.188062475610/12/2007
p39g80.0000
trc03p35107.95116.138.180.41212334970.164705679944.9862.70.0495
trc04p35106.73117.8411.110.55974210460.2237017242silicalite0.0000
trc05p35106.89118.3411.450.5768719260.230547681615.8233.060.0635
trc06p35106.62118.6111.990.61391296030.2453511834sio2al2o30.0000
trc07p35105.74117.5611.820.60520860640.24187247656.911059.170.0510
trc08p35106.85116.239.380.47258154280.188867882441688491water
cal 14444402.02558635beta0.0000
trc09p35106.92112.785.860.29523750970.117992088640690220water
cal 26943723.5494880645.52844.530.0511
trc10p35105.14113.948.80.44336008280.177189484583209323water cal
39/24/079455604.886363640.0000
trc11p35105.45115.8410.390.52346718870.209204402875201029water
cal 4(sealed after calcination 0n
9-23-07)7237827.622714150.0000
trc13p35106.92119.4812.560.63279575460.252897718898102403water
cal 17810700.875796180.0000
trc12p35105.7117.411.70.59906435660.2394169179g20.0000
trc14p35107.9119.1511.250.56338777960.2251587234g30.0000
trc15p35107.72119.5811.860.5939359170.2373673298g30.0000
trc16p35107.77117.9410.170.50930255280.2035434860.0000
trc17p35106.11116.099.980.49978755920.19974080530.0000
trc18p35106.21115.839.620.50142320720.2003944944g49/27/070.0000
trc19p35104.54113.098.550.44565160310.1781052938g40.0000
trc20p35103.99113.619.620.50142320720.2003944944g4
trc21p35106.17115.128.950.46650080090.1864377052g4
trc22p35106.75117.210.450.54468529270.217684248water cal 1
trc23p35105.41116.410.990.57283170970.2289330034g49/29/07
trc24p35107.27118.5411.270.58203623980.2326116069g5
trc25p35105.45113.958.50.43898030510.1754391002g5
trc26p35105.83115.59.670.4994046530.1995877763g5
000
000
000
trc27p35106.54115.749.20.47513162430.1898870261g5
trc28p35106.9116.379.470.48907570460.1954597975g5
trc29p35106.47115.418.940.46170399150.1845206536g5
trc30p35105.93115.199.260.47823030880.1911254197g5
trc01p37105.27113.137.860.40592767040.1622295679g5
trc02p37106.84114.797.950.41057569710.1640871584g5
trc03p37100.91111.3710.460.5402039990.2158932927g5
trc04p37104.43115.6311.20.57842110790.2311668143water cal 1
trc05p37106.96116.549.580.5229662530.2090042031water cal
19/30/07
trc06p37106.91117.1210.210.55735756190.2227487384g6
trc07p37106.89116.9810.090.55080683640.2201307317g6
trc08p37105.83115.149.310.50822712060.203113688g6
trc09p37106115.789.790.53443002270.2135857149g6
trc10p37106.64116.569.920.5415266420.2164218888water cal 2
trc11p37105.27112.26.930.69877572320.2792667066g7
trc12p37106.39111.575.181.08591633840.4339880014g1
trc13p37106.21112.025.811.72024290470.6874975113g2
trc14p37105.74110.815.072.03395913990.8128746486g3
trc15p37105.84117.4311.590.58909765850.2323092968xy1
trc16p37105.8114.78.90.45237007420.1783910907xy1
trc17p37103.55114.7411.190.56876641920.2242917197xy1
trc18p37106.14117.4911.350.57988554190.2439483437c1
trc19p37106.74117.6810.940.55893813470.2351361128c1
trc20p37104.37116.9712.60.6576173060.262817687p39g4
trc21p37106.58117.611.020.57515418350.2298611834p39g4
trc22p37107.83119.6411.810.61638574470.2463394352p39g4
trc23p37106.09116.8410.750.55592991910.2221781789g5
trc24p37105.53115.8110.280.53162414590.2124643423g5
trc25p37107.17118.1210.950.56627280140.2263117264g5
trc26p37104.85116.4711.620.60092145680.2401591106g5
trc27p37105.59118.2312.640.65367015610.2612402029g5
trc28p37106.56118.6912.130.62729580640.2506996568
trc29p37105.63116.0210.390.53731273110.2147377934
trc30p37108.82121.1212.300.63608725630.2542131721
trc31p37104.35116.4712.120.62677866230.2504929794
trc32p37104.52116.0111.490.59419858330.2374723047
trc01p41105.6116.5810.980.56782423370.2269317586
trc02p41109.09120.6611.570.62073624910.2611335667
trc03p41104.9116.8511.950.6411234380.2697101229
trc05p41105.58114.018.430.26859410260.2514729837n1
trc06p41104.26112.978.710.27751537770.2598255857n1
trc07p41105.25113.868.610.2743292080.2568425136n1
trc08p41106.83117.1110.280.60798389730.3796735412f1
trc09p41105.68115.9710.290.60857532140.3800428735f1
trc10p41106.68113.77.020.17068564770.159805553
trc11p41106.83115.478.640.21007464330.1966837575
trc13p41105.85115.8510.000.51134486180.2043596976g7
trc14p41106.26117.3411.080.56657010680.226430545g7
trc15p41105.96115.569.600.49089106730.1961853097g7
trc18p41104.41114.7710.360.52975327680.2117166468
trc19p41107.65117.359.700.49600451590.1982289067
trc20p41105.47116.410.930.54071947990.2160993054
trc21p41106.78117.210.420.51548920230.2060159892
trc22p41108.27118.269.990.49421661520.1975143697
trc07p43106.99117.7310.740.68187736080.2725132522
trc08p43107.91120.0712.160.77203246810.3085438684
trc09p43105.49118.5613.070.66645195680.2663484677area of ion 28
(carbon monoxide)mass of CO (mg)percent yeild (mass CO/mass
xylitol)mass carboncarbon yeild %selectivityarea of aromatics all
peaks after 4 min except 7.56 (furfural)mass of aromatics (mg)mass
carbon (mg)carbon yield %selectivitytotal carbon
percentcomments
trc10p43108.68123.0414.360.73223030610.292636878
trc11p43110.01121110.56410943210.2254471328
xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1xsa1
xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10xsa10
xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100xsa100
xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000xsa1000
Reaction time plot (600)
111
333
555
101010
303030
606060
120120120
240240240
Aromatics
Carbon Monoxide
Carbon Dioxide
t / s
Carbon yield (%)
2.8869243581
7.8953494628
6.7925233424
12.6063503672
9.803141366
8.4280412004
17.1044315609
11.1373168179
9.682680622
21.3255676372
10.8356007564
8.919867692
25.7107152741
13.3695544625
10.8280696993
27.7596010456
14.1364086955
11.6572795157
28.9295287882
14.6218210685
11.6833173964
31.3826941419
15.2908075456
12.6218920059
Percentage plot
55555
1010101010
2020202020
3030303030
4040404040
Aromatics
Carbon Monoxide
Carbon Dioxide
Oxygenates
coke
Glucose (%)
Carbon Yield (%)
31.3826941419
15.2908075456
12.6218920059
0
33.1720455689
27.1751449508
13.5553158551
11.0338284337
1.1730979757
32.3125630904
22.8546203764
11.4133152209
9.3425622504
3.4674435619
43.5628616367
16.5454626954
8.7303691642
7.2795637247
8.6050250628
41.6809027509
13.2399004427
7.0533624196
6.2552176745
10.257665918
43.8605879409
Percentage plot (2)
555555
101010101010
202020202020
303030303030
404040404040
Aromatics
Carbon Monoxide
Carbon Dioxide
C3 Oxygenates
coke
C5 oxygenates
Glucose (%)
Carbon Yield (%)
31.3826941419
15.2908075456
12.6218920059
0
33.1720455689
0
27.1751449508
13.5553158551
11.0338284337
1.1730979757
32.3125630904
0
22.8546203764
11.4133152209
9.3425622504
2.4247550677
43.5628616367
1.0426884942
16.5454626954
8.7303691642
7.2795637247
2.2698588765
41.6809027509
6.3351661863
13.2399004427
7.0533624196
6.2552176745
2.1332549078
43.8605879409
8.1244110102
Selectivities
Benzene12.923817258111.049511550111.5419684189
Toluene22.095451589820.315249133619.733840689
Xylenes, ethyl-benzene14.47132186515.862576582516.9804699675
Methyl-ethyl-benzene,
trimethyl-benzene3.28720820234.06692160114.7095296295
Indanes4.85898982645.53331558426.9736185411
Napthalenes42.363211258443.172425548440.060572754
b)
Glucose
Cellobiose
Cellulose
Xylitol
Selectivity (%)
11.2849327983
18.2680737143
12.485200852
3.3831827197
8.320080819
46.2585290967
feed comparison
XylitolXylitolXylitolXylitol
GlucoseGlucoseGlucoseGlucose
CellobioseCellobioseCellobioseCellobiose
CelluloseCelluloseCelluloseCellulose
a)
Aromatics
CO2
CO
coke
Carbon yield (%)
47.4867980788
7.2005721062
12.7695211799
37.5001923564
31.3826941419
12.6218920059
15.2908075456
35.575816987
28.1808120589
10.3637902859
13.0335056327
30.0375711129
31.0902547732
8.6010430382
15.2122322168
28.6072105837
Temperature plot
400400400400
500500500500
600600600600
700700700700
800800800800
Aromatics
Carbon monoxide
Carbon dioxide
coke
T/°C
Carbon yield (%)
8.1963868745
7.4015742412
6.7388391689
72.5938968248
19.190131076
10.1574227985
9.1069020058
44.7101483755
31.3826941419
15.2908075456
12.6218920059
33.1720455689
26.1277666136
10.3620419643
7.7983033485
27.4029941656
26.0483230109
11.760267854
8.4313490384
25.4799770312
heating rate
1111
5555
50505050
1000100010001000
Aromatics
Carbon monoxide
Carbon dioxide
coke
Nominal heating rate (°C s-1)
Carbon yield (%)
14.8556099406
8.9710840324
6.611488372
38.9410969722
23.6266449035
10.4602482553
8.5466103949
35.575816987
29.3530728097
13.3430477586
11.9569584425
34.1335541362
31.3826941419
15.2908075456
12.6218920059
33.1720455689
catalyst comparison
ZSM-5ZSM-5ZSM-5ZSM-5
SilicaliteSilicaliteSilicaliteSilicalite
Amorphous silica-aluminaAmorphous silica-aluminaAmorphous
silica-aluminaAmorphous silica-alumina
β-zeoliteβ-zeoliteβ-zeoliteβ-zeolite
Aromatics
CO2
CO
dehydration porducts
Carbon yield (%)
31.3826941419
12.6218920059
15.2908075456
0
6.5193290323
5.6326912099
6.1468432975
12.3029162134
0.5562347567
4.5340802887
4.2824652518
1.4797633829
4.2679122229
10.5422704206
7.7609171797
1.1018939417
aromatic breakdown
Reaction time (10% Glucose on ZSM-5)
old cal
sample nameReaction time (600C)initial mass of carbonarea
benzenemass carboncarbon yieldselectivity (just aro)area
toluenemass carboncarbon yieldselectivityarea xylenes,
ethylbenzmass carboncarbon yieldselecarea methy-ethyl-benz,
trimeth-benzmass carboncarbon yieldselecarea indanesmass
carboncarbon yieldselecarea napthalenesmass carboncarbon
yieldsecltotal areatotal aromatic yieldtotal carbon yieldarea ion
44 (CO2)mass Carboncarbon yieldarea ion 28 (CO)mass carboncarbon
yieldarea ion 18coke
trc01p090.50.3551526268000000000000000000004.9612472703-2.98E-03-0.8390758720.02065.8003231423Benzene
trc02p0910.36190608838.92E+060.00067075120.185338478524.3079750934.70E+060.00034943610.09655437112.66354004524.54E+060.00033503060.092573900712.14148346723.23E+060.00023822850.06582604538.63338192755.50E+060.00041038850.113396417114.87245014489.89E+060.00075555260.208770341527.3811693222367802380.762459554112.46836291657.35E+071.21E-023.3548842578.31E+070.03022284668.3510191054417724088TolueneXylitolGlucoseCellobioseCelluloseFurfural35.575816987sample
numberconditionpercent CC per mginitial carbonyield
trc03p0930.33807034163.17E+070.00238549240.705620135312.429379076.01E+070.00446740671.321442953323.27699361955.79E+070.00427457741.264404729322.27227497281.97E+070.00145410410.43011879837.57646972153.18E+070.00237128140.701416572512.35533402495.55E+070.00423950791.254031289722.08954859132567180105.677034478427.55323648041.07E+082.56E-027.56778191921.22E+080.048372524614.3084200828449697493Xylenes,
ethyl-benzeneAromatics47.486798078831.382694141928.180812058931.090254773222.034971911630.037571112931000/400/2401.510.01510.020800646772.5938968248
trc04p0950.38693362246.99E+070.00525937811.359245563911.24259665911.31E+080.00973405282.515690611820.80778898121.18E+080.00869408742.246919587218.58472914333.34E+070.00246128770.63610074455.26131870146.52E+070.00486196711.256537777410.3930796562.06E+080.01577003984.075644720733.710486858962364236812.090139005641.30273025141.36E+084.06E-0210.50037987311.58E+080.072403837318.7122113727528616008Methyl-ethyl-benzene,
trimethyl-benzeneCO27.200572106212.621892005910.36379028598.60104303824.848441137328.607210583781000/500/2400.930.00930.020800646744.7101483755
trc05p09100.40123507051.01E+080.00758254111.889800188811.3883651331.75E+080.01300092163.240225629119.5263355331.39E+080.01024804562.554125084215.39173782833.69E+070.00272462980.67906073994.09217424127.77E+070.00579286911.44375940858.70042208963.57E+080.02723246466.787159597340.90096517588563624716.594130647846.14018957961.37E+084.09E-0210.18463951991.64E+080.077684804819.3614194119484902074IndanesCO12.769521179915.290807545613.033505632715.212232216810.73631952437.500192356411000/600/2400.690.00690.020800646733.1720455689
trc06p09300.35594715161.17E+080.00882135252.478275894811.8789929121.91E+080.01422315143.9958604319.15315313551.38E+080.01014623422.850488945313.66310266233.46E+070.00255504280.71781522263.44066694088.05E+070.00600037481.68574878098.0802132894.26E+080.03251394819.134487496943.783871060398679176920.862676770450.3311843061.26E+083.49E-029.80200859621.55E+080.070002342819.6664989393456334000Napthalenescoke37.500192356435.57581698730.037571112928.607210583771000/700/2400.570.00570.020800646727.4029941656
trc09p07600.33528950451.43E+080.01078291533.216001434712.2362058512.29E+080.01702272865.077024003719.31700345331.55E+080.01140172893.400562414112.93842137623.87E+070.00285516710.85155278473.23997839519.41E+070.00702156022.09417834567.96790606145.11E+080.039038929311.643349630744.300484863117071457626.282668613558.92227638941.31E+083.75E-0211.19475335241.57E+080.071902346121.4448544235190010453CokeOther32.543108635140.704606306748.421892022545.096469971762.380267427121000/800/2400.530.00530.020800646725.4799770312
trc13p17900.41207098731.84E+080.01387273573.366588795212.60337621412.78E+080.02065500955.012488165518.76506991541.92E+080.01418499453.442366712412.88706325064.96E+070.00365595030.88721371233.32142975521.26E+080.00939558822.28008970828.53588903866.32E+080.048307304711.72305407843.8871718261146238261226.711801171766.40702265641.60E+085.53E-0213.4139256421.98E+080.108297595226.2812958427sum104.957083721394.871210680381.615679090483.510740611941/600/2400.810.00810.020800646738.9410969722
trc12p171200.39154792051.86E+080.01398174293.570889318112.44016873942.83E+080.02101831515.368005795618.70091507792.03E+080.01496637733.822361593413.31624112885.13E+070.00378303390.96617391733.36593086241.19E+080.00888540422.26930185067.90573311766.51E+080.049757033612.707776225444.2710110738149316925028.704508700471.61171251021.63E+085.74E-0214.65891848392.00E+080.110605573828.2482853259CO255/600/2400.740.00740.020800646735.575816987
trc15p171800.41891200951.74E+080.01305822553.117176221512.03171359472.69E+080.01998151334.769859273318.4107591571.95E+080.01442174973.442667992813.28805057775.15E+070.00380241630.90768854093.50350695051.11E+080.00829131241.97924916037.63952928456.41E+080.048976501411.691357675645.1264404356144164838725.907998864464.50081396731.59E+085.46E-0213.03703054951.97E+080.107056250625.5557845534selec35.729072328337.499065029236.803677243934.2557261186650/600/2400.710.00710.020800646734.1335541362
trc16p171800.38430448521.54E+080.01160956713.020929386612.11399701022.40E+080.01786360244.648294020318.63976699161.76E+080.01298061923.377691319613.5446206484.91E+070.00362213840.94251786083.77951851441.01E+080.00753957841.96187625627.86716935785.53E+080.042220469210.986202566544.054927478127340500624.9375114158.43753081291.42E+084.38E-0211.38976894131.73E+080.084970684222.110250461591000/600/240
cb0.630.00630.020973733130.0375711129
reaction time
(400C)00000000000000-2.98E-0300.02060101000/600/240
ce0.60.0060.020973733128.6072105837
trc03p1950.45512918618.05E+050.00006053390.01330037198.16E+050.00006071970.01334119375.86E+050.00004327010.00950721223.52E+050.00002597060.00570619490.00E+00000.00E+00000.041854972613.5694912219.72E+072.12E-024.66135561791.07E+080.04035303098.8662806304111000/600/240
xy0.790.00790.021066558637.5001923564
trc01p19100.45231229461.66E+070.0012470680.27570951776.66E+060.00049519160.10948001175.66E+060.00041791920.09239616131.81E+060.00013372690.02956517041.03E+060.00007698880.01702116040.00E+00000.524172021421.24382187271.27E+083.53E-027.8144844191.38E+080.058371649912.9051654324
trc02p19300.4760546663.45E+070.00259275760.54463442184.51E+070.00335477290.70470328284.30E+070.00317213920.66633926311.22E+070.00090150040.18936910091.14E+070.00084844720.17822474610.00E+00002.283270814634.72266955931.70E+086.23E-0213.07767803241.81E+080.092172374919.3617207123zsm100.11.30.0130.040232029832.3125630904
trc06p19600.49496808041.38E+080.01035541142.09213720721.07E+080.00795184671.60653727688.37E+070.00617590411.24773786252.48E+070.00182890190.36949896542.84E+070.00211970030.4282498933.80E+070.00290067450.58603262826.330193833150.84155513362.08E+089.09E-0218.37205767622.18E+080.129381209426.1393036242zsm200.23.450.03450.079195899243.5628616367
trc04p19900.49939462421.22E+080.00921288661.84481092871.54E+080.01147505572.29779320571.23E+080.00904456841.81110648113.03E+070.00223535370.44761269773.39E+070.00253182080.50697799227.83E+070.00598005911.19746165238.105762957649.33982204872.09E+089.15E-0218.32036338462.04E+080.114429764622.9136957064zsm300.350.050.119959014141.6809027509
trc05p191800.43098440178.55E+070.00643123281.49221938571.25E+080.00932445182.16352420471307458190.00964678222.238313525648530230.00478503241.1102565239273614370.00204068160.4734931545979368760.00748018351.73560423789.213411031545.67060694081720086576.34E-0214.70512257191828344160.093748043121.7520733374zsm400.47.010.07010.159824578943.8605879409
-2.98E-030.0206
percentage glucose000000-2.98E-030.0206total
trc12p075000000-2.98E-030.0206
trc13p075000000-2.98E-030.0206
trc08p0750.15794057877.46E+070.0056143433.554718510711.83671042781.27E+080.00944631755.980931288719.91565620138.35E+070.00615959123.899942120812.98625627581.90E+070.0014047040.88938763462.96153516985.01E+070.0037373092.36627536017.87936264032.76E+080.02106935113.34004924244.420479284963012650030.031304156960.33687803247.68E+071.33E-028.3906336189.45E+070.034612583521.91494025751825071511957699638.11E-0234.28496522472502044390.168741707671.3741339455643520969Compositionheating
ratereaction temperaturereaction timearomatic yieldoxygenate
yieldCO2 yieldCO yieldcoke yieldtotal carbonunidentified
trc09p07100.33528950451.27E+080.01028231273.066696845611.28493279832.07E+080.01664503014.964375511618.26807371431.43E+080.01137594183.392871428912.4852008523.87E+070.00308260080.9193848083.38318271979.41E+070.00758087572.26099402268.3200808195.11E+080.042148647912.570822334146.2585290967112066012927.175144950859.81475272671.31E+083.75E-0211.19475335241.57E+080.071902346121.44485442351900104531813201547.01E-0228.95920859572469513450.164526042668.00794509546315115375%
glucose100060024031.4