TETRA TECH - FINAL TRIP REPORT FOR FORMER H&R BLOCK … · The Former H&R Block UST Parcel is currently owned by Margo A. Weber Revocable Trust of Sierra Madre, California, is vacant,

Wes WilliamsProject Manager

Tetra Tech, Inc.6777 Engle Road, Suite L. Middleburg Heights, Ohio 44130

Tel 440-297-2178www.tetratech.com

October 16, 2015

Mr. James AugustynFederal On-Scene CoordinatorU.S. Environmental Protection Agency (EPA) Region 525063 Center Ridge RoadWestlake, Ohio 44145

Subject: Final Trip Report for Former H&R Block UST SiteEPA Contract No. EP-S3-13-01Technical Direction Document No. S05-0001-1508-211Document Tracking No. 0415

Dear Mr. Augustyn:

Tetra Tech, Inc. (Tetra Tech) is submitting the final trip report for the Former H&R BlockUST site. This report summarizes the waste oil assessment sampling event conducted onAugust 27, 2015, and addresses your comments on the draft report that Tetra Tech previouslysubmitted. If you have any questions regarding this report, please contact me at (216) 470-8109 or via electronic mail at [email protected].

Sincerely,

Wes Williams

Project Manager

Enclosure(s)cc: TDD File

Kevin Scott, Program Manager

FINAL TRIP REPORTFOR THE

FORMER H&R BLOCK UST SITEOBERLIN, LORAIN COUNTY, OHIO

Prepared for

U.S. Environmental Protection Agency Region 525063 Center Ridge Road

Westlake, Ohio 44145

Submitted by

Tetra Tech, Inc.6777 Engle Road, Suite L

Middleburg Heights, Ohio 44130

EPA Contract No. EP-S3-13-01

Technical Direction Document No. S05-0001-1508-211Document Tracking No. 0375

October 16, 2015

Prepared by Approved by

Wes Williams John DirgoGeologist Quality Control Reviewer

Former H&R Block UST Site Tetra Tech, Inc.Final Trip Report TDD No S05-0001-1508-211October 16, 2015 i

CONTENTSSection Page

1.0 INTRODUCTION ......................................................................................................................... 1

2.0 SITE BACKGROUND .................................................................................................................. 1

2.1 SITE LOCATION AND HISTOR7 .................................................................................... 1

3.0 SITE ACTIVITIES........................................................................................................................ 2

3.1 SAMPLING ACTIVITIES.................................................................................................. 23.2 SAMPLEE MANAGEMENT ............................................................................................. 3

4.0 ANALYTICAL RESULTS ........................................................................................................... 3

5.0 SUMMARY .................................................................................................................................... 3

6.0 REFERENCES............................................................................................................................... 4

Appendix

A FIGURESB ANALYTICAL RESULTS TABLEC LABORATORY ANALYTICAL RESULTS WITH DATA VALIDATION REPORT

Former H&R Block UST Site Tetra Tech, Inc.Final Trip Report TDD No S05-0001-1508-211October 16, 2015 1

1.0 INTRODUCTION

Under Superfund Technical Assessment and Response Team (START) Contract No. EP-S5-13-01,

Technical Direction Document (TDD) No. S05-0001-1508-211, the U.S. Environmental Protection

Agency (EPA) Region 5 tasked Tetra Tech Inc. (Tetra Tech) to assist the EPA On-Scene Coordinator

(OSC) James Augustyn with assessment and sampling activities at the Former H&R Block UST site in the

City of Oberlin, Lorain County, Ohio. The purpose of the assessment was to determine the contents of the

abandoned underground storage tank (UST) located at the site.

This trip report presents site background and history in Section 2.0, describes site activities in Section 3.0,

summarizes analytical results in Section 4.0, and provides a summary in Section 5.0. All references cited

in this report are listed after the text. Site figures can be found in Appendix A, the analytical results table

in Appendix B, and the laboratory analytical results with a data validation report are found in Appendix C.

2.0 SITE BACKGROUND

This section describes the site location and layout and summarizes the operational history and previous

investigations.

2.1 SITE LOCATION AND HISTORY

The Former H&R Block UST Parcel is currently owned by Margo A. Weber Revocable Trust of Sierra

Madre, California, is vacant, and is located in a mixed residential and commercial area. Prior to being

vacant, the property operated as an H&R Block office, and previously operated as a gasoline and service

station. The timeframe of the changes in ownership is unknown. The 1.45 acre parcel is bounded by

West College Street to the south and west, West Lorain Street to the north, and Dollar General to the east.

On August 19, 2013, Oberlin Assistant Fire Chief Susan Hiesser notified the Ohio State Fire Marshall of

product emanating from the UST fill port on the site. The Ohio State Fire Marshall’s Release Prevention

Activity Request stated that the site was not listed in the Ohio Tank Tracking and Environmental

Regulations (OTTER) system and the presence of an UST at the site would need to be verified.

On July 14, 2015 during a rain event, Oberlin Assistant Fire Chief Susan Hiesser contacted the Ohio EPA

Emergency Response Division (incident number 1507-47-1500) to notify the division of an overflowing


fill port. During the rain event, an oily substance was released which impacted the parking lot and

migrated off site into a storm drain.

The Oberlin Fire Department attempted to contain the release with absorbent pads and booms. Oberlin

Fire Department and Ohio’s Bureau of Underground Storage Tank Registration (BUSTR) attempted on

several occasions to contact the property owner unsuccessfully. BUSTR subsequently declared the site a

nuisance, which allowed the City of Oberlin to take action with an environmental contractor. The

material in the tank was sampled and the results indicated that the tank may exceed the characteristic

hazardous waste regulatory levels for barium (D005), lead (D008), and para-dichlorobenzene (D027).

Additionally, ortho-dichlorobenzene was detected in the material in the tank and polychlorinated

biphenyls were detected at concentrations greater than 50 parts per million (ppm). It was noted that the

UST and fill piping appear to be compromised due to water infiltration. Impacts to soil and groundwater

were unknown.

3.0 SITE ACTIVITIES

On August 27, 2015, the EPA OSC Augustyn, Tetra Tech START, and Oberlin Assistant Fire Chief

Hiesser mobilized to the site to complete reconnaissance and collect a sample from the waste oil UST.

Tetra Tech documented and photographed all work completed on the site in accordance with Tetra Tech

Standard Operating Procedure (SOP) No. 024, “Recording Notes in Field Logbooks” (Tetra Tech 2014b).

Sampling activities and sample management activities are summarized in Sections 3.1 and 3.2,

respectively.

3.1 SAMPLING ACTIVITIES

This section discusses the waste oil UST sampling activities conducted by Tetra Tech to assess the Former

H&R Block UST site. Appendix B presents the results in Table 1, while the sampling location is shown

in Figure 2, Site Layout and Sampling Results.

One waste oil UST sample was collected during the 1-day sampling event. The sample was collected

from aforementioned UST fill port located west of the Former H&R Block building (Figure 2).


3.2 SAMPLE MANAGEMENT

The sample collected during this sampling event was handled and packaged in accordance with Tetra

Tech SOP No. 019, “Packaging and Shipping Samples” (Tetra Tech 2014a) and with the Tetra Tech

“Quality Assurance Project Plan (QAPP) for START” (Tetra Tech 2015). The shipping container was

properly labeled with EPA chain-of-custody seals and was delivered with signed chain-of-custody forms

and appropriate hazard warnings for laboratory personnel. In addition, Tetra Tech photographed the site

and documented activities in a logbook in accordance with Tetra Tech SOP No. 024, “Recording Notes in

Field Logbooks” (Tetra Tech 2014b), and Tetra Tech’s QAPP for START (Tetra Tech 2015).

The sample was delivered to Test America Laboratories, 4101 Shuffel Street NW, North Canton, Ohio,

for analysis of toxicity characteristic leaching procedure (TCLP) volatile organic compounds, semivolatile

organic compounds, and metals; PCBs; flashpoint; and pH.

4.0 ANALYTICAL RESULTS

This section presents sampling results from the waste oil sampling event at the Former H&R Block UST site.

Results are summarized in the Analytical Results Table provided in Appendix B and are shown on Figure 2

in Appendix A.

Analytical results for the waste oil sample collected on site revealed that concentrations of several organic

compounds and metals exceeded TCLP regulatory limits in 40 CFR 261.24, indicating that the waste oil is a

hazardous waste. TCLP concentrations of the following compounds exceeded regulatory limits: benzene

(28 milligrams per liter [mg/L]), carbon tetrachloride (2.6 mg/L), trichloroethene (3.6 mg/L), barium (580

mg/L), and lead (2,800 mg/L). In addition, the waste oil is a considered a polychlorinated biphenyl (PCB)

liquid under 40 CFR 761.60 because the concentration of Arolcor-1242 (190,000 micrograms per kilogram

[ug/Kg]) is greater than 50 parts per million (or 50,000 ug/kg).

5.0 SUMMARY

The primary objective of this assessment at the Former H&R Block UST site was to determine the waste

profile of the contents in the UST. Based on analytical results, the content of the UST is both a hazardous

waste and a PCB waste, and the content should be removed and disposed of in accordance with regulatory

requirements.


6.0 REFERENCES

Tetra Tech. 2014a. “Packaging and Shipping Samples.” SOP No. 019. Revision No. 7. November.

Tetra Tech. 2014b. “Recording Notes in Field Logbooks.” SOP No. 024. Revision No. 2. November.

Tetra Tech. 2015. “Quality Assurance Project Plan [QAPP] for START (Revision 1).” July.

APPENDIX A

FIGURES

1 – SITE LOCATION MAP2 – SITE LAYOUT AND SAMPLING RESULTS

Oberlin UST EROberlin, Ohio

Figure 1Site Location

Prepared For: Jason Cashmere Prepared By: Dale Von BuschDate Saved: 9/23/2015

File P

ath: L

:\103

X902

6000

1S05

1\821

1_Ob

erlin_

UST_

ER\m

xd\si

te_loc

ation

.mxd

IN

PA

WVKY

MI

OHIO

EPA Contract No.: EP-S5-13-01TDD No.: S05-0001-1508-211

Sources:Lorain County Auditor, 2015.

USGS 7.5 Minute Topographic Quadrangle Maps:Kipton, OH 1969 & Oberlin, OH 1979.

±Legend

Approximate Property Boundary

1,000 0 1,000

Feet

LorainCounty

Oberlin UST ER544-550 West College StreetOberlin, Lorain County, OH

41.294072o N, 82.237511o W

FormerH&RBlock Dollar

General

Restaurant

Residential

Residential

W Lorain St

WCollege St

SP

yle-

Am

her

stR

d

550

Oberlin UST EROberlin, Ohio

Figure 2Site Layout and

Sampling Results

Prepared For: Jason Cashmere Prepared By: Dale Von Busch

Date Saved: 10/15/2015

File

Pa

th:

L:\1

03

X9

02

60

00

1S

05

1\8

211

_O

berl

in_

US

T_

ER

\mxd

\site

_la

you

t_re

sults

.mxd

EPA Contract No.: EP-S5-13-01

TDD No.: S05-0001-1508-211

Sources:Lorain County Auditor, 2015.ESRI Aerial Imagery, 2012.

±Legend

Approximate Location andSize of Former UST

Approximate PropertyBoundary

40 0 40

Feet

Benzene 28 mg/L

Carbon tetrachloride 2.6 mg/L

Trichloroethene 3.6 mg/L

Aroclor-1242 190,000 µg/kg

Barium 580 mg/L

Lead 2,800 mg/L

TCLP VOCs

TCLP PCBs

TCLP Metals

APPENDIX B

ANALYTICAL RESULTS TABLES

Table 1

Analytical Results

Sample ID Date Time Method Analyte Result Result Unit Result Qualifier Comparison Criteria1,2,3

WOT-1 8/27/2015 10:40:00 AM 1010 Flashpoint >200 Degrees F <140

WOT-1 8/27/2015 10:40:00 AM 9045D Corrosivity 5.2 SU <2 or >12.5

WOT-1 8/27/2015 10:40:00 AM 9045D pH 5.2 SU <2 or >12.5

WOT-1 8/27/2015 10:40:00 AM 8260B 1,1-Dichloroethene ND mg/L 0.70

WOT-1 8/27/2015 10:40:00 AM 8260B 1,2-Dichloroethane ND mg/L 0.50

WOT-1 8/27/2015 10:40:00 AM 8260B 2-Butanone (MEK) ND mg/L 200.00

WOT-1 8/27/2015 10:40:00 AM 8260B Benzene 28 mg/L 0.50

WOT-1 8/27/2015 10:40:00 AM 8260B Carbon tetrachloride 2.6 mg/L 0.50

WOT-1 8/27/2015 10:40:00 AM 8260B Chlorobenzene 0.34 mg/L J 100.00

WOT-1 8/27/2015 10:40:00 AM 8260B Chloroform 2.6 mg/L 6.00

WOT-1 8/27/2015 10:40:00 AM 8260B Tetrachloroethene ND mg/L 0.70

WOT-1 8/27/2015 10:40:00 AM 8260B Trichloroethene 3.6 mg/L 0.50

WOT-1 8/27/2015 10:40:00 AM 8260B Vinyl chloride ND mg/L 0.20

WOT-1 8/27/2015 10:40:00 AM 8270C 2,4,5-Trichlorophenol ND mg/L 400.00

WOT-1 8/27/2015 10:40:00 AM 8270C 2,4,6-Trichlorophenol ND mg/L 2.00

WOT-1 8/27/2015 10:40:00 AM 8270C Dinitrotoluene ND mg/L 0.13

WOT-1 8/27/2015 10:40:00 AM 8270C Methylphenol ND mg/L NA

WOT-1 8/27/2015 10:40:00 AM 8270C Hexachlorobenzene ND mg/L 0.13

WOT-1 8/27/2015 10:40:00 AM 8270C Hexachlorobutadiene ND mg/L 0.50

WOT-1 8/27/2015 10:40:00 AM 8270C Hexachloroethane ND mg/L 3.00

WOT-1 8/27/2015 10:40:00 AM 8270C Nitrobenzene ND mg/L 2.00

WOT-1 8/27/2015 10:40:00 AM 8270C Pentachlorophenol ND mg/L 100.00

WOT-1 8/27/2015 10:40:00 AM 8270C Pyridine ND mg/L 5.00

WOT-1 8/27/2015 10:40:00 AM 6010B Arsenic ND mg/L 5.00

WOT-1 8/27/2015 10:40:00 AM 6010B Barium 580 mg/L 100.00

WOT-1 8/27/2015 10:40:00 AM 6010B Cadmium 0.61 mg/L 1.00

WOT-1 8/27/2015 10:40:00 AM 6010B Chromium 3.5 mg/L J+ 5.00

WOT-1 8/27/2015 10:40:00 AM 6010B Mercury ND mg/L 0.20

WOT-1 8/27/2015 10:40:00 AM 6010B Selenium ND mg/L 1.00

WOT-1 8/27/2015 10:40:00 AM 6010B Silver ND mg/L 5.00

WOT-1 8/27/2015 10:40:00 AM 7470A Lead 2800 mg/L 5.00

WOT-1 8/27/2015 10:40:00 AM 8082 Aroclor-1016 ND ug/Kg 50000.00



WOT-1 8/27/2015 10:40:00 AM 8082 Aroclor-1242 190000 ug/Kg 50000.00



WOT-1 8/27/2015 10:40:00 AM 8082 Aroclor-1260 29000 ug/Kg J- 50000.00

Notes:1

2 TCLP regulatory levels for disposal 40 CFR 261.24

3 TSCA regulatory levels for PCBs 40 CFR 761.60

BOLD Exceeds comparison for waste charecterization

F

J The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample.

J+ The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample and may be biased high.

J- The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample and may be biased low.

mg/L

ND

SU

ug/Kg Micrograms per kilogram

RCRA criteria for ignitability and corrosivity

Degrees Farenheit

Milligrams per liter

Not detected above the laboratory detection limit

Standard unit

APPENDIX C

LABORATORY ANALYTICAL RESULTS WITH DATA VALIDATION REPORT

ANALYTICAL REPORTTestAmerica Laboratories, Inc.TestAmerica Canton4101 Shuffel Street NWNorth Canton, OH 44720Tel: (330)497-9396

TestAmerica Job ID: 240-54790-1Client Project/Site: Oberlin ER

For:Tetra Tech, Inc.6777 Engle RoadSuite LMiddleburg Heights, Ohio 44130

Attn: Mr. Brian Malone

Authorized for release by:9/4/2015 8:56:54 AM

Patrick O'Meara, Manager of Project Management(330)[email protected]

This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

1

2

3

4

5

6

7

8

9

10

11

12

13

14

https://secure.testamericainc.com/TotalAccess/login.aspx

http://www.testamericainc.com/AskTheExpert/Expert_index.htm

http://www.testamericainc.com

mailto:[email protected]

Table of Contents

Client: Tetra Tech, Inc.Project/Site: Oberlin ER

TestAmerica Job ID: 240-54790-1

Page 2 of 28TestAmerica Canton

9/4/2015

Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24

Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25

Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Definitions/GlossaryTestAmerica Job ID: 240-54790-1Client: Tetra Tech, Inc.

Project/Site: Oberlin ER

Qualifiers

GC/MS VOA

Qualifier Description

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

Qualifier

GC/MS Semi VOA


F1 MS and/or MSD Recovery is outside acceptance limits.

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

GC Semi VOA



Qualifier

p The %RPD between the primary and confirmation column/detector is >40%. The lower value has been reported.

X Surrogate is outside control limits

Metals


B Compound was found in the blank and sample.

Qualifier


4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not

applicable.J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TestAmerica Canton

Page 3 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Case NarrativeClient: Tetra Tech, Inc. TestAmerica Job ID: 240-54790-1Project/Site: Oberlin ER

Job ID: 240-54790-1

Laboratory: TestAmerica Canton

Narrative

CASE NARRATIVE

Client: Tetra Tech, Inc.

Project: Oberlin ER

Report Number: 240-54790-1

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples,

the reporting limits are adjusted relative to the dilution required.

TestAmerica Canton attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmerica’s operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data

have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the

individual sections below.

All solid sample results are reported on an "as received" basis unless otherwise indicated by the presence of a % solids value in the method header.

This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.

RECEIPT

The sample was received on 8/27/2015 1:45 PM; the sample arrived in good condition, properly preserved and, where required, on ice.

The temperature of the cooler at receipt was 4.8º C.

TCLP VOLATILE ORGANIC COMPOUNDS (GCMS)

Sample WOT-1 (240-54790-1) was analyzed for TCLP volatile organic compounds (GCMS) in accordance with EPA SW-846 Methods 1311/8260B. The sample was leached on 08/30/2015 and analyzed on 09/01/2015.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TCLP SEMIVOLATILE ORGANIC COMPOUNDS (GCMS)Sample WOT-1 (240-54790-1) was analyzed for TCLP semivolatile organic compounds (GCMS) in accordance with EPA SW-846 Methods

1311/8270C. The sample was leached on 08/31/2015, prepared on 08/31/2015 and analyzed on 09/01/2015.

Hexachloroethane, Nitrobenzene and Pyridine failed the recovery criteria high for the MS of sample WOT-1 (240-54790-1) in batch

240-195789.

The following samples were diluted due to the nature of the sample matrix: WOT-1 (240-54790-1) and (240-54790-C-1-J MS). Elevated reporting limits (RLs) are provided.

TestAmerica CantonPage 4 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14


Job ID: 240-54790-1 (Continued)

Laboratory: TestAmerica Canton (Continued)

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

POLYCHLORINATED BIPHENYLS (PCBS)

Sample WOT-1 (240-54790-1) was analyzed for polychlorinated biphenyls (PCBs) in accordance with EPA SW-846 Method 8082. The

sample was prepared on 08/28/2015 and analyzed on 09/01/2015.

Surrogates are added during the extraction process prior to dilution. When the sample dilution is 5X or greater, surrogate recoveries are diluted out and no corrective action is required. All of the samples in this data set analyzed for PCBs were subjected to the sulfuric acid

cleanup procedure before instrumental analysis, per EPA Method 3665A.

DCB Decachlorobiphenyl failed the surrogate recovery criteria low for WOT-1 (240-54790-1MS).

Aroclor-1260 failed the recovery criteria low for the MS of sample WOT-1 (240-54790-1) in batch 240-195666. Aroclor-1016 failed the

recovery criteria high. Aroclor-1016 failed the recovery criteria high for the MSD of sample WOT-1 (240-54790-1) in batch 240-195666.

Sample WOT-1 (240-54790-1)[20X] required dilution prior to analysis. The reporting limits have been adjusted accordingly.

The following sample appears to contain polychlorinated biphenyls (PCBs); however, due to weathering or other environmental processes, the PCBs in the sample do not closely match any of the laboratory's Aroclor standards used for instrument calibration: WOT-1 (240-54790-1). The sample has been quantified and reported as a mixture of Aroclors.


TCLP METALS (ICP)Sample WOT-1 (240-54790-1) was analyzed for TCLP metals (ICP) in accordance with EPA SW-846 Methods 1311/6010B. The sample was leached on 08/31/2015, prepared on 08/31/2015 and analyzed on 09/01/2015.

Barium, Chromium and Lead were detected in method blank LB 240-195548/1-B at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

Chromium and Lead were detected in method blank MB 240-195567/2-A at levels that were above the method detection limit but below

the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

Silver and Lead failed the recovery criteria low for the MS/MSD of sample WOT-1 (240-54790-1) in batch 240-195713.

Sample WOT-1 (240-54790-1)[5X] required dilution prior to analysis. The reporting limits have been adjusted accordingly.


TCLP MERCURYSample WOT-1 (240-54790-1) was analyzed for TCLP mercury in accordance with EPA SW-846 Methods 1311/7470A. The sample was

leached on 08/31/2015, prepared on 08/31/2015 and analyzed on 09/01/2015.


FLASHPOINT

Sample WOT-1 (240-54790-1) was analyzed for flashpoint in accordance with EPA SW-846 Method 1010. The sample was analyzed on

08/28/2015.


PH

Sample WOT-1 (240-54790-1) was analyzed for pH in accordance with EPA SW-846 Method 9045D. The sample was analyzed on


1

2

3

4

5

6

7

8

9

10

11

12

13

14


Job ID: 240-54790-1 (Continued)

Laboratory: TestAmerica Canton (Continued)

08/27/2015.



1

2

3

4

5

6

7

8

9

10

11

12

13

14

Method SummaryTestAmerica Job ID: 240-54790-1Client: Tetra Tech, Inc.


Method Method Description LaboratoryProtocol

SW8468260B Volatile Organic Compounds (GC/MS) TAL CAN

SW8468270C Semivolatile Organic Compounds (GC/MS) TAL CAN

SW8468082 Polychlorinated Biphenyls (PCBs) by Gas Chromatography TAL CAN

SW8466010B Metals (ICP) TAL CAN

SW8467470A Mercury (CVAA) TAL CAN

SW8461010 Ignitability, Pensky-Martens Closed-Cup Method TAL CAN

SW8469045D pH TAL CAN

Protocol References:

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL CAN = TestAmerica Canton, 4101 Shuffel Street NW, North Canton, OH 44720, TEL (330)497-9396

TestAmerica Canton

Page 7 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Sample SummaryTestAmerica Job ID: 240-54790-1Client: Tetra Tech, Inc.


Lab Sample ID Client Sample ID ReceivedCollectedMatrix

240-54790-1 WOT-1 Waste 08/27/15 10:40 08/27/15 13:45

TestAmerica Canton

Page 8 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Detection SummaryTestAmerica Job ID: 240-54790-1Client: Tetra Tech, Inc.


Client Sample ID: WOT-1 Lab Sample ID: 240-54790-1

Benzene

RL

0.50 mg/L

MDL

0.0026

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

TCLP128 8260B

Carbon tetrachloride 0.50 mg/L0.0026 TCLP12.6 8260B

Chlorobenzene 0.50 mg/L0.0030 TCLP10.34 J 8260B

Chloroform 0.50 mg/L0.0032 TCLP12.6 8260B

Trichloroethene 0.50 mg/L0.0034 TCLP13.6 8260B

1,4-Dichlorobenzene 10 mg/L8.5 TCLP2099 8270C

Aroclor-1242 9800 ug/Kg5700 Total/NA20190000 8082

Aroclor-1260 9800 ug/Kg2500 Total/NA2029000 F1 8082

Barium 10 mg/L0.41 TCLP1580 B 6010B

Cadmium 0.10 mg/L0.021 TCLP10.61 6010B

Chromium 0.50 mg/L0.075 TCLP13.5 B 6010B

Lead 2.5 mg/L0.11 TCLP52800 B 6010B

Flashpoint

RL

1.00 Degrees F

RL

1.00

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA1>200 1010

pH 0.100 SU0.100 Total/NA15.20 9045D

Corrosivity 0.100 SU0.100 Total/NA15.20 9045D

TestAmerica Canton

This Detection Summary does not include radiochemical test results.

Page 9 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Client Sample ResultsTestAmerica Job ID: 240-54790-1Client: Tetra Tech, Inc.


Lab Sample ID: 240-54790-1Client Sample ID: WOT-1Matrix: WasteDate Collected: 08/27/15 10:40

Date Received: 08/27/15 13:45

Method: 8260B - Volatile Organic Compounds (GC/MS) - TCLPRL MDL

1,1-Dichloroethene ND 0.50 0.0038 mg/L 08/31/15 14:50 09/01/15 22:26 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.50 0.0044 mg/L 08/31/15 14:50 09/01/15 22:26 11,2-Dichloroethane ND

5.0 0.012 mg/L 08/31/15 14:50 09/01/15 22:26 12-Butanone (MEK) ND

0.50 0.0026 mg/L 08/31/15 14:50 09/01/15 22:26 1Benzene 28

0.50 0.0026 mg/L 08/31/15 14:50 09/01/15 22:26 1Carbon tetrachloride 2.6

0.50 0.0030 mg/L 08/31/15 14:50 09/01/15 22:26 1Chlorobenzene 0.34 J

0.50 0.0032 mg/L 08/31/15 14:50 09/01/15 22:26 1Chloroform 2.6

0.50 0.0060 mg/L 08/31/15 14:50 09/01/15 22:26 1Tetrachloroethene ND

0.50 0.0034 mg/L 08/31/15 14:50 09/01/15 22:26 1Trichloroethene 3.6

0.50 0.0044 mg/L 08/31/15 14:50 09/01/15 22:26 1Vinyl chloride ND

1,2-Dichloroethane-d4 (Surr) 82 39 - 128 08/31/15 14:50 09/01/15 22:26 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

4-Bromofluorobenzene (Surr) 107 08/31/15 14:50 09/01/15 22:26 126 - 141

Toluene-d8 (Surr) 76 08/31/15 14:50 09/01/15 22:26 133 - 134

Dibromofluoromethane (Surr) 82 08/31/15 14:50 09/01/15 22:26 130 - 122

Method: 8270C - Semivolatile Organic Compounds (GC/MS) - TCLPRL MDL

1,4-Dichlorobenzene 99 10 8.5 mg/L 08/31/15 12:47 09/01/15 22:19 20


50 7.5 mg/L 08/31/15 12:47 09/01/15 22:19 202,4,5-Trichlorophenol ND

50 6.0 mg/L 08/31/15 12:47 09/01/15 22:19 202,4,6-Trichlorophenol ND

50 6.3 mg/L 08/31/15 12:47 09/01/15 22:19 202,4-Dinitrotoluene ND

50 2.1 mg/L 08/31/15 12:47 09/01/15 22:19 20Hexachlorobenzene ND

50 6.8 mg/L 08/31/15 12:47 09/01/15 22:19 20Hexachlorobutadiene ND

50 4.8 mg/L 08/31/15 12:47 09/01/15 22:19 20Hexachloroethane ND F1

100 20 mg/L 08/31/15 12:47 09/01/15 22:19 203 & 4 Methylphenol ND

25 4.3 mg/L 08/31/15 12:47 09/01/15 22:19 202-Methylphenol ND

10 1.0 mg/L 08/31/15 12:47 09/01/15 22:19 20Nitrobenzene ND F1

100 6.8 mg/L 08/31/15 12:47 09/01/15 22:19 20Pentachlorophenol ND

50 8.8 mg/L 08/31/15 12:47 09/01/15 22:19 20Pyridine ND F1

2-Fluorobiphenyl (Surr) 94 30 - 110 08/31/15 12:47 09/01/15 22:19 20


2-Fluorophenol (Surr) 102 08/31/15 12:47 09/01/15 22:19 2020 - 110

2,4,6-Tribromophenol (Surr) 82 08/31/15 12:47 09/01/15 22:19 2023 - 110

Nitrobenzene-d5 (Surr) 106 08/31/15 12:47 09/01/15 22:19 2028 - 110

Phenol-d5 (Surr) 93 08/31/15 12:47 09/01/15 22:19 2021 - 110

Terphenyl-d14 (Surr) 98 08/31/15 12:47 09/01/15 22:19 2048 - 110

Method: 8082 - Polychlorinated Biphenyls (PCBs) by Gas ChromatographyRL MDL

Aroclor-1016 ND F1 9800 3700 ug/Kg 08/28/15 13:42 09/01/15 11:48 20


9800 4300 ug/Kg 08/28/15 13:42 09/01/15 11:48 20Aroclor-1221 ND

9800 3300 ug/Kg 08/28/15 13:42 09/01/15 11:48 20Aroclor-1232 ND

9800 5700 ug/Kg 08/28/15 13:42 09/01/15 11:48 20Aroclor-1242 190000

9800 3900 ug/Kg 08/28/15 13:42 09/01/15 11:48 20Aroclor-1248 ND

9800 2400 ug/Kg 08/28/15 13:42 09/01/15 11:48 20Aroclor-1254 ND

9800 2500 ug/Kg 08/28/15 13:42 09/01/15 11:48 20Aroclor-1260 29000 F1

TestAmerica Canton

Page 10 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Client Sample ResultsTestAmerica Job ID: 240-54790-1Client: Tetra Tech, Inc.


Lab Sample ID: 240-54790-1Client Sample ID: WOT-1Matrix: WasteDate Collected: 08/27/15 10:40


Tetrachloro-m-xylene 153 p 40 - 184 08/28/15 13:42 09/01/15 11:48 20


DCB Decachlorobiphenyl 75 p 08/28/15 13:42 09/01/15 11:48 2030 - 174

Method: 6010B - Metals (ICP) - TCLPRL MDL

Arsenic ND 0.50 0.41 mg/L 08/31/15 10:24 09/01/15 11:39 1


10 0.41 mg/L 08/31/15 10:24 09/01/15 11:39 1Barium 580 B

0.10 0.021 mg/L 08/31/15 10:24 09/01/15 11:39 1Cadmium 0.61

0.50 0.075 mg/L 08/31/15 10:24 09/01/15 11:39 1Chromium 3.5 B

2.5 0.11 mg/L 08/31/15 10:24 09/01/15 13:28 5Lead 2800 B

0.50 0.34 mg/L 08/31/15 10:24 09/01/15 11:39 1Selenium ND

0.50 0.063 mg/L 08/31/15 10:24 09/01/15 11:39 1Silver ND F1

Method: 7470A - Mercury (CVAA) - TCLPRL MDL

Mercury ND 0.033 0.014 mg/L 08/31/15 15:20 09/01/15 11:38 1


General ChemistryRL RL

Flashpoint >200 1.00 1.00 Degrees F 08/28/15 11:48 1


0.100 0.100 SU 08/27/15 13:48 1pH 5.20

0.100 0.100 SU 08/27/15 13:48 1Corrosivity 5.20

TestAmerica Canton

Page 11 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Surrogate SummaryTestAmerica Job ID: 240-54790-1Client: Tetra Tech, Inc.


Method: 8260B - Volatile Organic Compounds (GC/MS)Prep Type: Total/NAMatrix: Waste

Lab Sample ID Client Sample ID (39-128) (26-141) (33-134) (30-122)

12DCE BFB TOL DBFM

102 97 98 96LCS 240-195639/2-A

Percent Surrogate Recovery (Acceptance Limits)

Lab Control Sample

96 95 92 89MB 240-195639/1-A Method Blank

Surrogate Legend

12DCE = 1,2-Dichloroethane-d4 (Surr)

BFB = 4-Bromofluorobenzene (Surr)

TOL = Toluene-d8 (Surr)

DBFM = Dibromofluoromethane (Surr)

Method: 8260B - Volatile Organic Compounds (GC/MS)Prep Type: TCLPMatrix: Waste

Lab Sample ID Client Sample ID (39-128) (26-141) (33-134) (30-122)

12DCE BFB TOL DBFM

82 107 76 82240-54790-1


WOT-1

Surrogate Legend

12DCE = 1,2-Dichloroethane-d4 (Surr)

BFB = 4-Bromofluorobenzene (Surr)

TOL = Toluene-d8 (Surr)

DBFM = Dibromofluoromethane (Surr)

Method: 8270C - Semivolatile Organic Compounds (GC/MS)Prep Type: Total/NAMatrix: Waste

Lab Sample ID Client Sample ID (30-110) (20-110) (23-110) (28-110) (21-110) (48-110)

FBP 2FP TBP NBZ PHL TPH

82 96 95 77 88 82LCS 240-195599/4-A


Lab Control Sample

84 93 91 8679 85MB 240-195599/3-A Method Blank

Surrogate Legend

FBP = 2-Fluorobiphenyl (Surr)

2FP = 2-Fluorophenol (Surr)

TBP = 2,4,6-Tribromophenol (Surr)

NBZ = Nitrobenzene-d5 (Surr)

PHL = Phenol-d5 (Surr)

TPH = Terphenyl-d14 (Surr)

Method: 8270C - Semivolatile Organic Compounds (GC/MS)Prep Type: TCLPMatrix: Waste

Lab Sample ID Client Sample ID (30-110) (20-110) (23-110) (28-110) (21-110) (48-110)

FBP 2FP TBP NBZ PHL TPH

94 102 82 106 93 98240-54790-1


WOT-1

94 105 81 10690 95240-54790-1 MS WOT-1

Surrogate Legend

FBP = 2-Fluorobiphenyl (Surr)

TestAmerica Canton

Page 12 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Surrogate SummaryTestAmerica Job ID: 240-54790-1Client: Tetra Tech, Inc.


2FP = 2-Fluorophenol (Surr)

TBP = 2,4,6-Tribromophenol (Surr)

NBZ = Nitrobenzene-d5 (Surr)

PHL = Phenol-d5 (Surr)

TPH = Terphenyl-d14 (Surr)

Method: 8082 - Polychlorinated Biphenyls (PCBs) by Gas ChromatographyPrep Type: Total/NAMatrix: Waste

Lab Sample ID Client Sample ID (40-184) (30-174)

TCX2 DCB2

153 p 75 p240-54790-1


WOT-1

112 p 24 p X240-54790-1 MS WOT-1

122 p 68 p240-54790-1 MSD WOT-1

128 129LCS 240-195369/5-A Lab Control Sample

100 87MB 240-195369/4-A Method Blank

Surrogate Legend

TCX = Tetrachloro-m-xylene

DCB = DCB Decachlorobiphenyl

TestAmerica Canton

Page 13 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

QC Sample ResultsTestAmerica Job ID: 240-54790-1Client: Tetra Tech, Inc.


Method: 8260B - Volatile Organic Compounds (GC/MS)

Client Sample ID: Method BlankLab Sample ID: MB 240-195639/1-AMatrix: Waste Prep Type: Total/NAAnalysis Batch: 195831 Prep Batch: 195639

RL MDL

1,1-Dichloroethene ND 0.50 0.0038 mg/L 08/31/15 14:50 09/01/15 19:48 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

ND 0.00440.50 mg/L 08/31/15 14:50 09/01/15 19:48 11,2-Dichloroethane

ND 0.0125.0 mg/L 08/31/15 14:50 09/01/15 19:48 12-Butanone (MEK)

ND 0.00260.50 mg/L 08/31/15 14:50 09/01/15 19:48 1Benzene

ND 0.00260.50 mg/L 08/31/15 14:50 09/01/15 19:48 1Carbon tetrachloride

ND 0.00300.50 mg/L 08/31/15 14:50 09/01/15 19:48 1Chlorobenzene

ND 0.00320.50 mg/L 08/31/15 14:50 09/01/15 19:48 1Chloroform

ND 0.00600.50 mg/L 08/31/15 14:50 09/01/15 19:48 1Tetrachloroethene

ND 0.00340.50 mg/L 08/31/15 14:50 09/01/15 19:48 1Trichloroethene

ND 0.00440.50 mg/L 08/31/15 14:50 09/01/15 19:48 1Vinyl chloride

1,2-Dichloroethane-d4 (Surr) 96 39 - 128 09/01/15 19:48 1

MB MB

Surrogate

08/31/15 14:50

Dil FacPrepared AnalyzedQualifier Limits%Recovery

95 08/31/15 14:50 09/01/15 19:48 14-Bromofluorobenzene (Surr) 26 - 141

92 08/31/15 14:50 09/01/15 19:48 1Toluene-d8 (Surr) 33 - 134

89 08/31/15 14:50 09/01/15 19:48 1Dibromofluoromethane (Surr) 30 - 122

Client Sample ID: Lab Control SampleLab Sample ID: LCS 240-195639/2-AMatrix: Waste Prep Type: Total/NAAnalysis Batch: 195831 Prep Batch: 195639

1,1-Dichloroethene 10.0 9.95 mg/L 100 44 - 143

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

1,2-Dichloroethane 10.0 10.5 mg/L 105 68 - 120

2-Butanone (MEK) 20.0 20.5 mg/L 102 10 - 199

Benzene 10.0 9.90 mg/L 99 70 - 120

Carbon tetrachloride 10.0 11.4 mg/L 114 29 - 120

Chlorobenzene 10.0 9.56 mg/L 96 71 - 120

Chloroform 10.0 9.71 mg/L 97 63 - 120

Tetrachloroethene 10.0 9.50 mg/L 95 58 - 131

Trichloroethene 10.0 10.4 mg/L 104 59 - 124

Vinyl chloride 10.0 9.64 mg/L 96 33 - 120

1,2-Dichloroethane-d4 (Surr) 39 - 128

Surrogate

102

LCS LCS

Qualifier Limits%Recovery

974-Bromofluorobenzene (Surr) 26 - 141

98Toluene-d8 (Surr) 33 - 134

96Dibromofluoromethane (Surr) 30 - 122

Method: 8270C - Semivolatile Organic Compounds (GC/MS)


RL MDL

1,4-Dichlorobenzene ND 0.50 0.43 mg/L 08/31/15 12:47 09/01/15 15:00 1

MB MB


TestAmerica Canton

Page 14 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14



Method: 8270C - Semivolatile Organic Compounds (GC/MS) (Continued)


RL MDL

2,4,5-Trichlorophenol ND 2.5 0.38 mg/L 08/31/15 12:47 09/01/15 15:00 1

MB MB


ND 0.302.5 mg/L 08/31/15 12:47 09/01/15 15:00 12,4,6-Trichlorophenol

ND 0.312.5 mg/L 08/31/15 12:47 09/01/15 15:00 12,4-Dinitrotoluene

ND 0.112.5 mg/L 08/31/15 12:47 09/01/15 15:00 1Hexachlorobenzene

ND 0.342.5 mg/L 08/31/15 12:47 09/01/15 15:00 1Hexachlorobutadiene

ND 0.242.5 mg/L 08/31/15 12:47 09/01/15 15:00 1Hexachloroethane

ND 1.05.0 mg/L 08/31/15 12:47 09/01/15 15:00 13 & 4 Methylphenol

ND 0.211.3 mg/L 08/31/15 12:47 09/01/15 15:00 12-Methylphenol

ND 0.0500.50 mg/L 08/31/15 12:47 09/01/15 15:00 1Nitrobenzene

ND 0.345.0 mg/L 08/31/15 12:47 09/01/15 15:00 1Pentachlorophenol

ND 0.442.5 mg/L 08/31/15 12:47 09/01/15 15:00 1Pyridine

2-Fluorobiphenyl (Surr) 84 30 - 110 09/01/15 15:00 1

MB MB

Surrogate

08/31/15 12:47


93 08/31/15 12:47 09/01/15 15:00 12-Fluorophenol (Surr) 20 - 110

91 08/31/15 12:47 09/01/15 15:00 12,4,6-Tribromophenol (Surr) 23 - 110

79 08/31/15 12:47 09/01/15 15:00 1Nitrobenzene-d5 (Surr) 28 - 110

86 08/31/15 12:47 09/01/15 15:00 1Phenol-d5 (Surr) 21 - 110

85 08/31/15 12:47 09/01/15 15:00 1Terphenyl-d14 (Surr) 48 - 110


1,4-Dichlorobenzene 50.0 44.8 mg/L 90 52 - 110

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

2,4,5-Trichlorophenol 50.0 38.5 mg/L 77 51 - 110

2,4,6-Trichlorophenol 50.0 42.1 mg/L 84 46 - 110

2,4-Dinitrotoluene 50.0 42.8 mg/L 86 54 - 110

Hexachlorobenzene 50.0 44.5 mg/L 89 50 - 110

Hexachlorobutadiene 50.0 43.2 mg/L 86 34 - 110

Hexachloroethane 50.0 46.4 mg/L 93 41 - 110

3 & 4 Methylphenol 50.0 40.9 mg/L 82 48 - 110

2-Methylphenol 50.0 43.3 mg/L 87 44 - 111

Nitrobenzene 50.0 42.0 mg/L 84 40 - 110

Pentachlorophenol 100 68.3 mg/L 68 12 - 110

Pyridine 50.0 50.6 mg/L 101 30 - 110

2-Fluorobiphenyl (Surr) 30 - 110

Surrogate

82

LCS LCS


962-Fluorophenol (Surr) 20 - 110

952,4,6-Tribromophenol (Surr) 23 - 110

77Nitrobenzene-d5 (Surr) 28 - 110

88Phenol-d5 (Surr) 21 - 110

82Terphenyl-d14 (Surr) 48 - 110

TestAmerica Canton

Page 15 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14



Method: 8270C - Semivolatile Organic Compounds (GC/MS) (Continued)

Client Sample ID: WOT-1Lab Sample ID: 240-54790-1 MSMatrix: Waste Prep Type: TCLPAnalysis Batch: 195789 Prep Batch: 195599

1,4-Dichlorobenzene 99 50.0 140 mg/L 82 31 - 110

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

2,4,5-Trichlorophenol ND 50.0 33.5 J mg/L 67 41 - 110

2,4,6-Trichlorophenol ND 50.0 41.4 J mg/L 83 35 - 110

2,4-Dinitrotoluene ND 50.0 38.2 J mg/L 76 42 - 110

Hexachlorobenzene ND 50.0 41.3 J mg/L 83 42 - 110

Hexachlorobutadiene ND 50.0 49.1 J mg/L 98 28 - 110

Hexachloroethane ND F1 50.0 420 F1 mg/L 840 26 - 110

3 & 4 Methylphenol ND 50.0 51.7 J mg/L 103 29 - 110

2-Methylphenol ND 50.0 49.8 mg/L 100 33 - 112

Nitrobenzene ND F1 50.0 67.3 F1 mg/L 135 32 - 110

Pentachlorophenol ND 100 29.1 J mg/L 29 10 - 124

Pyridine ND F1 50.0 60.3 F1 mg/L 121 21 - 110

2-Fluorobiphenyl (Surr) 30 - 110

Surrogate

94

MS MS


1052-Fluorophenol (Surr) 20 - 110

812,4,6-Tribromophenol (Surr) 23 - 110

90Nitrobenzene-d5 (Surr) 28 - 110

106Phenol-d5 (Surr) 21 - 110

95Terphenyl-d14 (Surr) 48 - 110

Method: 8082 - Polychlorinated Biphenyls (PCBs) by Gas Chromatography


RL MDL

Aroclor-1016 ND 500 190 ug/Kg 08/28/15 13:42 09/01/15 12:46 1

MB MB


ND 220500 ug/Kg 08/28/15 13:42 09/01/15 12:46 1Aroclor-1221

ND 170500 ug/Kg 08/28/15 13:42 09/01/15 12:46 1Aroclor-1232

ND 290500 ug/Kg 08/28/15 13:42 09/01/15 12:46 1Aroclor-1242

ND 200500 ug/Kg 08/28/15 13:42 09/01/15 12:46 1Aroclor-1248

ND 120500 ug/Kg 08/28/15 13:42 09/01/15 12:46 1Aroclor-1254

ND 130500 ug/Kg 08/28/15 13:42 09/01/15 12:46 1Aroclor-1260

Tetrachloro-m-xylene 100 40 - 184 09/01/15 12:46 1

MB MB

Surrogate

08/28/15 13:42


87 08/28/15 13:42 09/01/15 12:46 1DCB Decachlorobiphenyl 30 - 174


Aroclor-1016 10000 12800 ug/Kg 128 66 - 149

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Aroclor-1260 10000 12300 ug/Kg 123 50 - 155

TestAmerica Canton

Page 16 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14



Method: 8082 - Polychlorinated Biphenyls (PCBs) by Gas Chromatography (Continued)


Tetrachloro-m-xylene 40 - 184

Surrogate

128

LCS LCS


129DCB Decachlorobiphenyl 30 - 174

Client Sample ID: WOT-1Lab Sample ID: 240-54790-1 MSMatrix: Waste Prep Type: Total/NAAnalysis Batch: 195666 Prep Batch: 195369

Aroclor-1016 ND F1 9520 117000 F1 ug/Kg 1231 26 - 170

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Aroclor-1260 29000 F1 9520 26100 F1 ug/Kg -31 21 - 170

Tetrachloro-m-xylene p 40 - 184

Surrogate

112

MS MS


24 p XDCB Decachlorobiphenyl 30 - 174

Client Sample ID: WOT-1Lab Sample ID: 240-54790-1 MSDMatrix: Waste Prep Type: Total/NAAnalysis Batch: 195666 Prep Batch: 195369

Aroclor-1016 ND F1 9260 131000 F1 ug/Kg 1410 26 - 170 11 61

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Aroclor-1260 29000 F1 9260 33600 ug/Kg 48 21 - 170 25 75

Tetrachloro-m-xylene p 40 - 184

Surrogate

122

MSD MSD


68 pDCB Decachlorobiphenyl 30 - 174

Method: 6010B - Metals (ICP)


RL MDL

Arsenic ND 0.50 0.41 mg/L 08/31/15 10:24 09/01/15 13:24 1

MB MB


ND 0.4110 mg/L 08/31/15 10:24 09/01/15 13:24 1Barium

ND 0.0210.10 mg/L 08/31/15 10:24 09/01/15 13:24 1Cadmium

0.0750 J 0.0750.50 mg/L 08/31/15 10:24 09/01/15 13:24 1Chromium

0.177 J 0.0220.50 mg/L 08/31/15 10:24 09/01/15 13:24 1Lead

ND 0.340.50 mg/L 08/31/15 10:24 09/01/15 13:24 1Selenium

ND 0.0630.50 mg/L 08/31/15 10:24 09/01/15 13:24 1Silver

TestAmerica Canton

Page 17 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14



Method: 6010B - Metals (ICP) (Continued)


Arsenic 200 187 mg/L 93 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Barium 200 192 mg/L 96 80 - 120

Cadmium 5.00 4.98 mg/L 100 80 - 120

Chromium 20.0 20.3 mg/L 102 80 - 120

Lead 50.0 49.3 mg/L 99 80 - 120

Selenium 200 184 mg/L 92 80 - 120

Silver 5.00 4.87 mg/L 97 80 - 120

Client Sample ID: Method BlankLab Sample ID: LB 240-195548/1-BMatrix: Waste Prep Type: TCLPAnalysis Batch: 195713 Prep Batch: 195567

RL MDL

Arsenic ND 0.50 0.41 mg/L 08/31/15 10:24 09/01/15 11:27 1

LB LB


0.655 J 0.4110 mg/L 08/31/15 10:24 09/01/15 11:27 1Barium

ND 0.0210.10 mg/L 08/31/15 10:24 09/01/15 11:27 1Cadmium

0.0851 J 0.0750.50 mg/L 08/31/15 10:24 09/01/15 11:27 1Chromium

0.225 J 0.0220.50 mg/L 08/31/15 10:24 09/01/15 11:27 1Lead

ND 0.340.50 mg/L 08/31/15 10:24 09/01/15 11:27 1Selenium

ND 0.0630.50 mg/L 08/31/15 10:24 09/01/15 11:27 1Silver


Arsenic ND 500 475 mg/L 95 75 - 125

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Barium 580 B 5000 5110 mg/L 91 75 - 125

Cadmium 0.61 100 94.1 mg/L 93 75 - 125

Chromium 3.5 B 500 508 mg/L 101 75 - 125

Selenium ND 100 94.2 mg/L 94 75 - 125

Silver ND F1 100 53.2 F1 mg/L 53 75 - 125


Lead 2800 B 500 2490 4 mg/L -71 75 - 125

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: WOT-1Lab Sample ID: 240-54790-1 MSDMatrix: Waste Prep Type: TCLPAnalysis Batch: 195713 Prep Batch: 195567

Arsenic ND 500 466 mg/L 93 75 - 125 2 20

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Barium 580 B 5000 5050 mg/L 90 75 - 125 1 20

Cadmium 0.61 100 92.4 mg/L 92 75 - 125 2 20

Chromium 3.5 B 500 506 mg/L 100 75 - 125 0 20

TestAmerica Canton

Page 18 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14



Method: 6010B - Metals (ICP) (Continued)


Selenium ND 100 92.6 mg/L 93 75 - 125 2 20

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Silver ND F1 100 54.1 F1 mg/L 54 75 - 125 2 20


Lead 2800 B 500 2670 4 mg/L -36 75 - 125 7 20

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Method: 7470A - Mercury (CVAA)


RL MDL

Mercury ND 0.033 0.014 mg/L 08/31/15 15:20 09/01/15 11:34 1

MB MB



Mercury 0.833 0.873 mg/L 105 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Client Sample ID: Method BlankLab Sample ID: LB 240-195548/1-CMatrix: Waste Prep Type: TCLPAnalysis Batch: 195876 Prep Batch: 195570

RL MDL

Mercury ND 0.033 0.014 mg/L 08/31/15 15:20 09/01/15 11:32 1

LB LB



Mercury ND 0.833 0.747 mg/L 90 80 - 120

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits


Mercury ND 0.833 0.727 mg/L 87 80 - 120 3 20

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

TestAmerica Canton

Page 19 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14



Method: 1010 - Ignitability, Pensky-Martens Closed-Cup Method

Client Sample ID: Lab Control SampleLab Sample ID: LCS 240-195256/1Matrix: Waste Prep Type: Total/NAAnalysis Batch: 195256

Flashpoint 81.0 83.00 Degrees F 102 97 - 103

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Method: 9045D - pH

Client Sample ID: WOT-1Lab Sample ID: 240-54790-1 DUMatrix: Waste Prep Type: Total/NAAnalysis Batch: 195125

pH 5.20 5.260 SU 1 20

Analyte

DU DU

DUnitResult Qualifier

Sample

Result

Sample

Qualifier LimitRPD

RPD

Corrosivity 5.20 5.260 SU 1 20

TestAmerica Canton

Page 20 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

QC Association SummaryTestAmerica Job ID: 240-54790-1Client: Tetra Tech, Inc.


GC/MS VOA

Leach Batch: 195545

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Waste 1311240-54790-1 WOT-1 TCLP

Prep Batch: 195639


Waste 5030B 195545240-54790-1 WOT-1 TCLP

Waste 5030BLCS 240-195639/2-A Lab Control Sample Total/NA

Waste 5030BMB 240-195639/1-A Method Blank Total/NA

Analysis Batch: 195831


Waste 8260B 195639240-54790-1 WOT-1 TCLP

Waste 8260B 195639LCS 240-195639/2-A Lab Control Sample Total/NA

Waste 8260B 195639MB 240-195639/1-A Method Blank Total/NA

GC/MS Semi VOA

Leach Batch: 195548


Waste 1311240-54790-1 WOT-1 TCLP

Waste 1311240-54790-1 MS WOT-1 TCLP

Prep Batch: 195599


Waste 3580A 195548240-54790-1 WOT-1 TCLP

Waste 3580A 195548240-54790-1 MS WOT-1 TCLP

Waste 3580ALCS 240-195599/4-A Lab Control Sample Total/NA

Waste 3580AMB 240-195599/3-A Method Blank Total/NA



Waste 8270C 195599240-54790-1 WOT-1 TCLP

Waste 8270C 195599240-54790-1 MS WOT-1 TCLP

Waste 8270C 195599LCS 240-195599/4-A Lab Control Sample Total/NA

Waste 8270C 195599MB 240-195599/3-A Method Blank Total/NA

GC Semi VOA

Prep Batch: 195369


Waste 3580A240-54790-1 WOT-1 Total/NA

Waste 3580A240-54790-1 MS WOT-1 Total/NA

Waste 3580A240-54790-1 MSD WOT-1 Total/NA





Waste 8082 195369240-54790-1 WOT-1 Total/NA

Waste 8082 195369240-54790-1 MS WOT-1 Total/NA

Waste 8082 195369240-54790-1 MSD WOT-1 Total/NA

TestAmerica Canton

Page 21 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14



GC Semi VOA (Continued)

Analysis Batch: 195666 (Continued)


Waste 8082 195369LCS 240-195369/5-A Lab Control Sample Total/NA

Waste 8082 195369MB 240-195369/4-A Method Blank Total/NA

Metals

Leach Batch: 195548


Waste 1311240-54790-1 WOT-1 TCLP

Waste 1311240-54790-1 MS WOT-1 TCLP

Waste 1311240-54790-1 MSD WOT-1 TCLP

Waste 1311LB 240-195548/1-B Method Blank TCLP

Waste 1311LB 240-195548/1-C Method Blank TCLP

Prep Batch: 195567


Waste 3050B 195548240-54790-1 WOT-1 TCLP

Waste 3050B 195548240-54790-1 MS WOT-1 TCLP

Waste 3050B 195548240-54790-1 MSD WOT-1 TCLP

Waste 3050B 195548LB 240-195548/1-B Method Blank TCLP

Waste 3050BLCS 240-195567/3-A Lab Control Sample Total/NA

Waste 3050BMB 240-195567/2-A Method Blank Total/NA

Prep Batch: 195570


Waste 7470A 195548240-54790-1 WOT-1 TCLP


Waste 7470A 195548240-54790-1 MSD WOT-1 TCLP

Waste 7470A 195548LB 240-195548/1-C Method Blank TCLP





Waste 6010B 195567240-54790-1 WOT-1 TCLP

Waste 6010B 195567240-54790-1 WOT-1 TCLP





Waste 6010B 195567LB 240-195548/1-B Method Blank TCLP

Waste 6010B 195567LCS 240-195567/3-A Lab Control Sample Total/NA

Waste 6010B 195567MB 240-195567/2-A Method Blank Total/NA



Waste 7470A 195570240-54790-1 WOT-1 TCLP


Waste 7470A 195570240-54790-1 MSD WOT-1 TCLP

Waste 7470A 195570LB 240-195548/1-C Method Blank TCLP

Waste 7470A 195570LCS 240-195570/3-A Lab Control Sample Total/NA

TestAmerica Canton

Page 22 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14



Metals (Continued)

Analysis Batch: 195876 (Continued)


Waste 7470A 195570MB 240-195570/2-A Method Blank Total/NA

General Chemistry



Waste 9045D240-54790-1 WOT-1 Total/NA

Waste 9045D240-54790-1 DU WOT-1 Total/NA

Waste 9045DLCS 240-195125/2 Lab Control Sample Total/NA



Waste 1010240-54790-1 WOT-1 Total/NA

Waste 1010LCS 240-195256/1 Lab Control Sample Total/NA

TestAmerica Canton

Page 23 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Lab ChronicleClient: Tetra Tech, Inc. TestAmerica Job ID: 240-54790-1Project/Site: Oberlin ER

Client Sample ID: WOT-1 Lab Sample ID: 240-54790-1Matrix: WasteDate Collected: 08/27/15 10:40


Leach 1311 08/30/15 18:00 DRJ195545 TAL CAN

Type

Batch Batch

MethodPrep Type LabAnalystRun

Prepared

or Analyzed

Batch

Number

Dilution

Factor

TCLP

Prep 5030B 195639 08/31/15 14:50 LAM TAL CANTCLP

Analysis 8260B 1 195831 09/01/15 22:26 TJL1 TAL CANTCLP

Leach 1311 195548 08/31/15 10:00 DRJ TAL CANTCLP

Prep 3580A 195599 08/31/15 12:47 JDR TAL CANTCLP

Analysis 8270C 20 195789 09/01/15 22:19 MRU TAL CANTCLP

Prep 3580A 195369 08/28/15 13:42 NAK TAL CANTotal/NA

Analysis 8082 20 195666 09/01/15 11:48 SEM TAL CANTotal/NA


Prep 3050B 195567 08/31/15 10:24 DEE TAL CANTCLP

Analysis 6010B 1 195713 09/01/15 11:39 KLC TAL CANTCLP


Prep 3050B 195567 08/31/15 10:24 DEE TAL CANTCLP

Analysis 6010B 5 195713 09/01/15 13:28 KLC TAL CANTCLP


Prep 7470A 195570 08/31/15 15:20 DEE TAL CANTCLP

Analysis 7470A 1 195876 09/01/15 11:38 WAL TAL CANTCLP

Analysis 1010 1 195256 08/28/15 11:48 TPH TAL CANTotal/NA

Analysis 9045D 1 195125 08/27/15 13:48 BLW TAL CANTotal/NA

Laboratory References:

TAL CAN = TestAmerica Canton, 4101 Shuffel Street NW, North Canton, OH 44720, TEL (330)497-9396

TestAmerica Canton

Page 24 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Certification SummaryClient: Tetra Tech, Inc. TestAmerica Job ID: 240-54790-1Project/Site: Oberlin ER

Laboratory: TestAmerica CantonAll certifications held by this laboratory are listed. Not all certifications are applicable to this report.

Authority Program EPA Region Certification ID Expiration Date

California 01144CA9NELAP 06-30-14 *

California State Program 9 2927 04-30-17

Connecticut State Program 1 PH-0590 12-31-15

Illinois NELAP 5 200004 07-31-16

Kansas NELAP 7 E-10336 01-31-16 *

Kentucky (UST) State Program 4 58 02-26-16

Kentucky (WW) State Program 4 98016 12-31-15

L-A-B DoD ELAP L2315 07-18-16

Minnesota NELAP 5 039-999-348 12-31-15

Nevada State Program 9 OH-000482008A 07-31-16

New Jersey NELAP 2 OH001 09-30-15 *

New York NELAP 2 10975 03-31-16 *

Ohio VAP State Program 5 CL0024 10-31-15 *

Oregon NELAP 10 4062 02-23-16

Pennsylvania NELAP 3 68-00340 08-31-16

Texas NELAP 6 T104704517-15-5 08-31-16

USDA Federal P330-13-00319 11-26-16

Virginia NELAP 3 460175 09-14-15 *

Washington State Program 10 C971 01-12-16

West Virginia DEP State Program 3 210 12-31-15

Wisconsin State Program 5 999518190 08-31-15 *

TestAmerica Canton

* Certification renewal pending - certification considered valid.

Page 25 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Page 26 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

Page 27 of 28

9/4/2015

1234567891011121314

Page 28 of 28 9/4/2015

1

2

3

4

5

6

7

8

9

10

11

12

13

14

DATA VALIDATION CHECKLIST – STAGE 2AEPA REGION 5 START CONTRACT

Page 1 of 4

Site Name Oberlin ERTDD No. 0001/S05-0001-1508-211

Document Tracking No. 0368

Data Reviewer(signature and date) September 11, 2015

Technical Reviewer(signature and date) September 16, 2015

Laboratory Report No. 240-54790-1 Laboratory TestAmerica, North Canton, OH

Analyses

Toxicity Characteristic Leaching Procedure (TCLP) volatile organic compounds (VOC) by EPA methodsSW1311/SW8260, TCLP semivolatile organic compounds (SVOC) by EPA methods SW1311/SW8270,polychlorinated biphenyls (PCB) by EPA method SW8082, TCLP metals by EPA methodsSW1311/SW6010B/SW7470A, flashpoint by EPA method SW1010, and pH by EPA method SW9045D

Sample One (1) waste sample

Field Duplicate Pairs None

Field Blanks None

INTRODUCTION

This checklist summarizes the Stage 2A validation performed on the subject laboratory report, in accordance with the Environmental ProtectionAgency (EPA) Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund Use (January 2009). Analytical data wereevaluated in general accordance with the EPA’s Contract Laboratory Program (CLP) National Functional Guidelines (NFG) for Superfund OrganicMethods Data Review (August 2014) and CLP NFG for Inorganic Superfund Data Review (August 2014) data validation guidance documents, aswell as the above referenced methods.

OVERALL EVALUATION

The data are acceptable and usable as qualified.

Data completeness:

WithinCriteria

Exceedance/Notes

Y


Page 2 of 4

Sample preservation, receipt, and holding times:

WithinCriteria

Exceedance/Notes

Y

Method blanks:

WithinCriteria

Exceedance/Notes

N Barium, chromium, and lead were detected in the method blank below the RL. No qualifications of TCLP barium or TCLP leadresults were warranted because the associated field sample results are more than 10 times the amount in the method blank. TheTCLP chromium result for the associated sample was qualified as estimated and possibly biased high (J+).

Field blanks:

WithinCriteria

Exceedance/Notes

NA No field blanks are included in this SDG.

MS/MSD:

WithinCriteria

Exceedance/Notes

N Hexachloroethane, nitrobenzene, and pyridine failed recovery limits high from the MS of sample WOT-1. None of these analyteswere detected in the parent sample, however, so no data were qualified.

Silver and lead failed the recovery criteria low for the MS and MSD of sample WOT-1. The amount of lead in the parent sample isgreater than 4 times the amount spiked, so lead was not qualified. The non-detect silver result for parent sample WOT-1 wasqualified as estimated (UJ).

Aroclor 1260 failed recovery criteria low and Aroclor 1016 failed recovery criteria high from the MS/MSD. Aroclor 1260 in parentsample WOT-1 was qualified as estimated and possibly biased low (J-). Aroclor 1016 was not detected in parent sample WOT-1, sowas not qualified.


Page 3 of 4

Post digestion spikes:

WithinCriteria

Exceedance/Notes

NA No post digestion spikes were performed.

Serial dilutions:

WithinCriteria

Exceedance/Notes

NA No serial dilutions were performed.

Laboratory duplicates:

WithinCriteria

Exceedance/Notes

Y

Field duplicates:

WithinCriteria

Exceedance/Notes

NA No field duplicates are included in the SDG.

LCS/LCSD:

WithinCriteria

Exceedance/Notes

Y

Sample dilutions:

WithinCriteria

Exceedance/Notes

Y Sample WOT-1 required dilution due to the nature of the sample matrix for TCLP SVOC analysis (20x), PCB analysis (20x), TCLP leadanalysis (5x).


Page 4 of 4

Re-extraction and reanalysis:

WithinCriteria

Exceedance/Notes

Y

MDLs/RLs:

WithinCriteria

Exceedance/Notes

Y Detections below RLs were reported as estimated concentrations (flagged “J”).

Other [specify]:

WithinCriteria

Exceedance/Notes

NA

Overall Qualifications:

See results summary pages attached for changes to the laboratory qualifiers based upon this validation. The following is a list of qualifiers anddefinitions that may be used for the validation of this data package:

J The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample.

J+The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample and may bebiased high.

J-The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample and may bebiased low.

NJThe analysis indicates the presence of an analyte that has been “tentatively identified” and the associated value is the approximateconcentration of the analyte in the sample.

RThe sample result is rejected as unusable due to serious deficiencies in one or more quality control criteria. The analyte may or may notbe present in the sample.

U The analyte was analyzed for, but was not detected at or above the associated value (reporting limit).

UJThe analyte was analyzed for, but was not detected at or above the associated value (reporting limit), which is considered approximatedue to deficiencies in one or more quality control criteria.

TETRA TECH - FINAL TRIP REPORT FOR FORMER H&R BLOCK … · The Former H&R Block UST Parcel is currently owned by Margo A. Weber Revocable Trust of Sierra Madre, California, is vacant,

Documents