Systems for safe and efficient hydrogen storage and ...donar.messe.de/exhibitor/hannovermesse/2017/K... · Systems for safe and efficient hydrogen storage and logistics via LOHC.

HYDROGENIOUS TECHNOLOGIES GmbH

Weidenweg 13

91058 Erlangen

Erlangen, March 2016

Systems for safe and efficient hydrogen storage and logistics via LOHC

1

Hydrogenious Technologies

Products and Projects

LOHC Technology

Applications

Hydrogenious Technologies GmbH – a pioneer in chemical hydrogen storage

Spin-off FAU Erlangen – Nürnberg

Global technology leader for Liquid Organic Hydrogen Carrier - LOHC

Specialized on the development and construction of containerized hydrogen storage & release systems

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January 2013Founding of HT by Dr. Teichmann, Prof. Arlt, Prof. Wasserscheid & Prof. Schlücker

May 2014Friedrich-Alexander University

becomes a shareholder

July 2014Strategic investment

by Anglo Platinum

September 2014HQ at Weidenweg in Erlangen opens

May 2015Commissioning of

hydrogenation unit

December 2015Delivery of first components

and lab systems

January 2016Ceremony for the commissioning of 1st

commercial system

Hydrogenious Technologies’ leadership team combines over 50 years of scientific and business experience

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Dr. Daniel TeichmannCEO & Founder

Dr. Berthold MelcherCTO

Dr. Martin SchneiderHead of Project Development

Cornelius von der HeydtHead of Business Development

Man

agem

ent

Team

Ad

viso

ry B

oar

d &

C

o-F

ou

nd

ers

• Dr.-Ing. University of Erlangen-Nuremberg• Conceptual father of the LOHC based energy

storage and logistics model • Industry experience with BMW, Leoni

(China) and McKinsey

• Dr.-Ing. University of Erlangen-Nuremberg• 5+ years industry experience with Siemens

Energy (thermal plant engineering and CCS) & Celanese

• Dr.-Ing. University of Erlangen-Nuremberg• Post-doc at University of St. Andrews• Industry experience with AREVA

• Alumnus of University of Munich and Constance (Economics)

• 4+ year experience in consulting and finance (BCG, Roland Berger, Deutsche Bank)

• Co-Founder of a bio-methane company

• Chair for chemical reaction engineering in Erlangen

• Head of Helmholtz-Institute Erlangen HI ERN

• Leibniz Prize winner 2006Prof. Peter Wasserscheid

• Chair for chemical process technology in Erlangen

• Head of Bavarian Hydrogen Center

• >10 years industry experienceProf.Eberhard Schlücker

• Chair for thermal process engineering in Erlangen

• Head of EnergiecampusNuremberg

• >10 years industry experienceProf.Wolfgang Arlt

Total team: 21 employees and growing

Hydrogenious Technologies offers innovative LOHC1

systems for hydrogen distribution and energy storage

41. Liquid Organic Hydrogen Carrier – here: Dibenzyltoluene

Innovative hydrogen logistics with:Industrial hydrogenation units up to 1,500 Nm3/h H2

Easy transport by truck, train or ship – up to 1,800 kg H2/ 40t-truckSafe supply of hydrogen filling stationsUtilization of existing infrastructure

F U E L S

LOHC – Energy storage systems:Turnkey plug & play systems and tailored solutions30 – 1,000 kW input powerStorage capacity of 10 – 1,000 MWhOptimized for local energy storage

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LOHC Technology

Applications

LOHC enables safe and efficient storage of hydrogen through molecular binding

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We build systems to chemically bind hydrogen to a carrier liquid

9 H2

9 H2

Our LOHC systems – containerized and easy to install on-site

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3kg Hydrogen Storage - Less Weight, Less Volume

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Compressed hydrogen storage (300bar)Total weight: 250 kgTotal volume: > 150 l

LOHC storage (ambient conditions)Total weight: 50 kgTotal volume: 50 l

Our LOHC technology has significant advantages in performance and handling compared to competing technologies

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Hydrogen logistics performance Energy storage performance

Efficient630 Nm3 H2 / m3 LOHC 6.23-wt%1.9 MWh / m³ LOHC

SafeNon-explosiveNon-toxic

Easy to handleDiesel-like liquidAmbient conditions

Low priced~4 €/lReusable

Our LOHC is…

LOHC

1,800.0

CGH2 (250 bar)

350.0

kg H2 / 40-to truck

20090

1

LOHCLi-Ion battery

1,900

CGH2

(70bar)

Pumped

hydro

kWh / m³5x

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LOHC Technology

Applications

Chemicals& Fertilizer

Mobility

On-grid

Off-grid

ProcessingIndustry

Specialapplications

The flexibility of hydrogen makes it a key resource in numerous applications and industries…

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Existing markets Developing markets

Industrial hydrogen

H2

… which can easily, safely and efficiently be connected by our LOHC technology

Hydro-genation

H2

Electrolysis

Mobility

Electricity

H2

De-Hydro-genation

Stationary2

H2

Industry

H2

Distribution1

De-Hydro-

genation

RenewableEnergies

Wind / PV EnergyBiomassHydropower

L HC+

L HC-

L HC+

L HC-

Steam Methane ReformingCoal gasificationBy-product hydrogen Hydrogen-rich gases

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LOHC enables safe and efficient hydrogen transport

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H2 per truck

Capex for trailer

Maintenance intensity

Handling HazardousNet energy required1

(excl. transport)Boil-off

LOHC (Perhydro-

Dibenzyltoluene)

up to 1.800kg

~60.000€ low + no 5-30%2 (th.) 0%

CGH2 (@ 250bar)

up to 350kg

>250.000€ very high - yes 5-6% (el.)

(eq. to ~ 18% th.)0%

CGH2 (@ 500bar)

up to 1.100kg

>800.000€ very high - yes 12-14% (el.)

(eq. to ~ 40% th.)0%

LH2 (@ -253°C)

up to 3.300kg

>1.000.000€ high - yes 30% (el.)

(eq. to ~ 90% th.)1-3% / day

1. In % of lower heating value of stored hydrogen 2. Actual value depends on utilization of exothermic heat from hydrogenation

Hydrogen logistics

LOHC – hydrogen storage offers significant advantages compared to competing long term energy storage technologies

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Lon

g te

rm s

tora

ge

1. Average parameters for electro-chemical batteries 2. Hydrogen storage in underground caverns

Applicability of energy storage technologies

Comparison of long term

energy storage technologies

Pumped hydro

Batteries1

Hydrogen(gaseous

@ 70bar)2

Hydrogen(LOHC)

Storage density (kWh/m³)

0,7 200 90 1.900

Self-discharge(% per month)

<0,3% 1-20% 1-5% 0

Marginal cost of storage capacity

lowhigh

(>200 €/kWh)medium

low(<2.5 €/kWh)

Hazard potential low medium high low

Geographical roll-out potential

small large small large

Power–to-power efficiency

< 85% <80% <40% <45%

Transportable No No No Yes

Energy storage

The stationary LOHC energy storage system offers the ideal solution for long-term storage of large amounts of energy

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Grid support – Grid stabilization and balancing of supply / demand peaks

Energy production buffering – Maximizing usable energy output of wind and PV parks

Energy self-supply and autarky – Independence from increasing electricity prices

Off-Grid and back-up – Installation at remote locations and as back-up supply

Long term storage – Seasonal storage of large amounts of energy

Possible applications

Energy storage

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LOHC Technology

Applications

Our end-to-end demonstration system will be deployedin Q2 2016

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98kWp PV@ Hydrogenious HQ

Hydrogenious HQ (Erlangen) Fraunhofer IAO (Stuttgart)

50kW SiemensPEM Electrolyzer

30kW Hydrogenation system

Transport of loaded LOHC

100kW Dehydrogenation system

PEM Fuel Cell

electric car filling station

System completed

Q2 2016

Excess heat10kW

The StorageBOX

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Hydrogenation unit

LOHC peripheryProcess-Cooling

LOHC storage tanks

H2 Inlet

H2 inlet pressure 30 - 50 bar

Electr. Connection 400V

Cooling 10 kWh / kg H2

Series 10 Series 50 Series 100

H2 storage 10 Nm³ / h

LOHC production 16 l / h

Housing 10‘ container







Hydrogenious Technologies‘ StorageBOX series binds hydrogen to a carrier liquid – enabling safe and continuous high density storage

Hydrogenious’ product portfolio: The StorageBOX Series

Intersections

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The ReleaseBOX

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Dehydrogenation unit

LOHC peripheryLOHC storage

tanks

H2 ZufuhrH2 outlet and purification

Heat exchanger

H2 purity 5.0

H2 outlet pressure up to 3 bar

Electr. connection 400V

Heating 10kWh / kg H2

(Natural gas or electricity)

Series 5 Series 33 Series 100

H2 outlet 5 Nm³ / h

LOHC throughput 8 l / h




Housing 20‘ Container



Housing 20‘ Container

Hydrogenious’ Produktportfolio: Die ReleaseBOX Serie

Hydrogenious Technologies‘ ReleaseBOX series delivers on-demand hydrogen from loaded LOHC – enabling continuous and safe hydrogen supply

Intersections

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Thank you for your interest!

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Managing Director

Dr. Daniel TeichmannTel: + 49 (0)9131-12640-0Mobil: +49 (0)160-4548292Mail: [email protected]

Head of Business Development & Sales

Cornelius von der HeydtTel: +49 (0)9131-12640-220Mobil: +49 (0)151-70800575Mail: [email protected]

HYDROGENIOUS TECHNOLOGIES GmbH • Weidenweg 13 • 91058 ErlangenTel: +49 (0)9131-12640-10 • Fax: +49 (0)9131-12640-29 • [email protected]

Sitz Erlangen • HRB 13922 Amtsgericht Fürth • USt.-IdNr.: DE288532636

mailto:[email protected]

mailto:[email protected]

Systems for safe and efficient hydrogen storage and ...donar.messe.de/exhibitor/hannovermesse/2017/K... · Systems for safe and efficient hydrogen storage and logistics via LOHC.

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