Synthesis of Propionic acid from Syngas Date:05 April 2011 Team Echo: Sabah Basrawi Alex Guerrero Mrunal Patel Kevin Thompson Client Mentor: Shannon Brown
Feb 23, 2016
Synthesis of Propionic acid from Syngas
Date:05 April 2011Team Echo:
Sabah BasrawiAlex Guerrero
Mrunal PatelKevin Thompson
Client Mentor: Shannon Brown
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Presentation Layout
Design Basis Motivation Process Flow Diagram Plant Layout Economics
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Design Basis Production of:
Propionic Acid 33,000 ton/year Using syngas
Synthesized from Syngas (1:1 ratio of CO & H2) Ethylene Oxygen
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Chemical Information Analysis Reaction Mechanism
Syngas feed with Ethylene PropionaldehydeCatalyst: Rhodium(1) CO + H2 +C2H4 CH3CH2CHO
Aldehyde oxidation Propionic AcidCatalyst: Cobalt Ion(2) CH3CH2CHO + ½ O2 CH3CH2COOH
In = Out (per year) 6.64E7 lb (CO+H2+C2H4+O2)= 6.64E7 lb Product
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Motivation Increasing demand Increasing price (price already high) Easy to synthesize Wide variety of uses
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Uses of Propionic Acid• Mold inhibitor for various animal feed • Preservative in cheeses and baked goods to prevent
mold• Precursor in many industrial processes
• Pharmaceuticals• Plastics • Plasticizers• Textile and rubber auxiliaries
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Block Flow Diagram
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Process Flow Diagram
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Process Flow Diagram
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Plant Layout
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Plant Layout
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Process Floor Plan
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Process Floor Plan
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3-D Please enjoy this three dimensional
representation of our process
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Economics NPV: -$20 Million IRR: 4% Capital Cost: $57.8 million Total Yearly Cost: $28.6 Million Total Yearly Profit: $28.8 Million Break-Even Point: ~18.5 Years
Competing Processes Industry standard:
Hydrocarboxylation of ethylene using nickel carbonyl or ruthenium as catalyst:
H2C=CH2 + H2O + CO → CH3CH2COOH
Our process : Hydroformylation involves the addition of a
formyl group (CHO) and a hydrogen atom to a carbon-carbon double bond.
Promotes chain extension
Competing Processes Pt. 2
Choice of Syngas:The feed for the process since it’s thermodynamically efficient
Wacker process: Similar to Hydroformylation uses a Tetrachloropalladate catalyst.
Carbonylation Process: Produces Propionaldehyde, then oxidizes it in the
presence of cobalt ions to produce Propionic Acid. Typically requires a carbonyl catalyst like Nickel
Carbonyl
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Reccomendations Move the project forward if
Increase syngas H2 Ratio Find alternate H2 Increase Propionaldehyde selectivity
Otherwise, do not proceed
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References "Acetic Acid Production." Acetic Acid Production. 2009. Web. 22 Jan. 2011.
<http://www.starcontrols.com/Application/Application_min_e.asp?MinID=34>.
Boyaval, P., and C. Corre. Production of Propionic Acid. 1995. Print. Perlack, Robert D., Lynn L. Wright, Robin L. Graham, Bryce J. Stokes, and
Donald C. Erbach. Biomass as a Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply . Print.
"Propanoic Acid." Wikipedia, the Free Encyclopedia. Web. 22 Jan. 2011. <http://en.wikipedia.org/wiki/Propanoic_acid>.
Registration Review Document for Propionic Acid and Salts. Mar. 2008. Print.
Spivey, James J., Makarand R. Gogate, Ben W. Jang, Eric D. Middlemas, Joseph R. Zoeller, Gerald N. Choi, and Samuel S. Tam. Synthesis of Acrylates and Methacrylates from Coal-Derived Syngas. 1997. Print.
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References Pt. 2 http://www.engineeringtoolbox.com/air-co
mpressor-types-d_441.html
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QUESTIONS
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Flowsheeting
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Flowsheet (Left Side)
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Flowsheet (Center)
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Flowsheet (Right Side)
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Energy Sinks/Sources
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In=OutIN Mass/ Year Out Mass/year
CO 2.5E7 lb Propionic Acid 6.64E7 lb
H2 1.9 E6 lb Ethane
C2H4 2.5 E7 lb
O2 7.2E6 lb