1 1 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH Austin, Texas • 28th of October 2019 Veronika Gronemann, Jason Holland • Global Syngas and Technology Conference THIS DOCUMENT IS PUBLIC Synergies in Air Liquide’s Syngas Technologies & Low Carbon Syngas Offer
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11 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH Austin, Texas • 28th of October 2019Veronika Gronemann, Jason Holland • Global Syngas and Technology Conference
THIS DOCUMENT IS PUBLIC
Synergies in Air Liquide’s Syngas Technologies & Low Carbon Syngas Offer
22 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Agenda
1. Air Liquide Overview2. Syngas Technology Overview3. Syngas utilization: HP ATR based methanol4. Syngas utilization: OTF Gas Supply5. Conclusion
33 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
1.Air Liquide Overview
44 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Air Liquide - One business, several activitiesThe Air Liquide business is founded on technical and scientific expertise in essential small molecules for life, matter and energy, as well as on recognized operational know-how. Today, around 67,000 employees are working toward the shared goal of the Group’s sustainable development, driven by a true entrepreneurial spirit and the unrelenting desire for innovation that better serves our customers.
Air Liquide’s value creation model works by integrating and sharing our industrial assets.
This efficient industrial system brings Air Liquide closer to its customers so that it can anticipate their needs and offer them innovative solutions. The Group currently serves more than 3 million customers and patients from a wide range of sectors.
Comparison of Combined Reforming and HP ATR based MegaMethanol Plant
1313 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
4.Syngas Utilization:OTF Gas Supply
1414 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Air Liquide Global Footprint
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● Global Owner Operator ○ Air Liquide Group operates more than 90 Hydrogen, Syngas and CO Production Plants
● Markets catered to include,○ Refineries, Chemicals (Isocyanates, acetic acid, oxo-alcohols, polycarbonate, nylons, H2O2, NH3 and
others), Metals, Electronics
Singapore
1515 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
What outsourcing means...
H2/CO/Syngas/Steam
Feedstock/Utilities Supplied by 3rd party or customers
Feedstock
Utilities
Electricity or O2 / N2
CUSTOMERAIR LIQUIDE
Air Liquide will ● build, own, operate and maintain the plants, and ● sign a long-term contract (15-20 yrs) to supply products to customer through pipelines
1616 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Avoided CO2 emissions A new driver for Syngas/H2 production costs? “ ”
Steam Reforming
Biogas
Water + Renewable Electricity
Electrolysis
COS*Fossil Feed
Air Liquide is committed to
produce at least 50% of its
Hydrogen for energy
markets without CO2
emissions by 2020. This is
the Group’s “Blue Hydrogen”
initiative.
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*CO Shift
1717 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Air Liquide Low Carbon Offering Cryocap (HYCO Only) Up to a 60% reduction in CO2 emissions
Absorption Systems (Amine)
Retrofit SMRs to SyngasUp to 60% emissions reduction
CO Coldbox (HYCO Only) ~40-90% footprint reduction
Power Purchase Agreement Menard County Wind Farm
1818 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
Carbon Capture on Syngas/H2 Production Unit
PSA
ShiftNatural Gas
H2/SYG/CO
Fuel Gas System ~60% of CO2
emissions
Solution 1: Amine Unit
(aMDEA)
Solution 2: Cryocap™
Solution 3: Amine Unit
(MEA)~100% of CO2 emissions
CO+ H2O-> CO2+H2
Steam Methane Reformer
Shift
~40% of CO2 emissions
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1919 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
5.Conclusion
2020 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH 20
Conclusion
Technology+
Operations
reliableefficient
cost-effective
Solutions
Customer
Low Carbon World
2121 October 2019 AIR LIQUIDE, A WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH