Supporting information: Porous Coordination Polymer s ... · Porous Coordination Polymer s Based on Azamacrocyclic Complex: Syntheses, Solvent-induced Reversible Crystal-to-Crystal
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Supporting information: Porous Coordination Polymers Based on Azamacrocyclic Complex: Syntheses,
Solvent-induced Reversible Crystal-to-Crystal Transformation and Gas Sorption Properties
Figure S1, Other used analogous tripodal carboxylate ligands in experiments.
Calculation of sorption heat for CO2 uptake using Virial 2 model
The above virial expression was used to fit the combined isotherm data for 3 at 273 and 293
K, where P is the pressure, N is the adsorbed amount, T is the temperature, ai and bi are virial coefficients, and m and N are the number of coefficients used to describe the isotherms. Qst is the coverage-dependent enthalpy of adsorption and R is the universal gas constant.