S1 Supporting Information Gold-Induced Unfolding of Lysozyme: Towards the Formation of Luminescent Clusters Debasmita Ghosh, 1† Ananya Baksi, 1† Sathish Kumar Mudedla, 2 Abhijit Nag, 1 Mohd Azhardin Ganayee, 1 Venkatesan Subramanian 2 and Thalappil. Pradeep 1* 1 DST Unit of Nanoscience (DST UNS) & Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology Madras, Chennai-600036, India 2 Chemical Laboratory, CSIR-Central Leather Research Institute, Adyar, Chennai- 600020 Email: [email protected]Table of Contents Number Description Page Number S1 The structures of Lyz at pH 5.5 and 7 S3 S2 ESI MS/MS of Lyz and Au 2 -Lyz at different collision energy S4 S3 Infrared (IR) spectra Lyz and Au n -Lyz complexes at different Lyz:Au ratio S5 S4 Original IR spectra and second derivative spectra of Lyz and Au n -Lyz complexes at different Lyz:Au ratios S6 S5 Simulated structures of Lyz S7 S6 Simulated structures of Au 2 -Lyz S8 S7 Simulated structures of Au 4 -Lyz S9 S8 Simulated structures of Au 6 -Lyz S10 S9 Simulated structures of Au 8 -Lyz S11 S10 Residue-wise calculated secondary structure of Lyz at pH 5.5. S12 S11 Residue-wise calculated secondary structure of Au 2 -Lyz and Au 4 -Lyz S13 S12 Residue-wise calculated secondary structure of Au 6 -Lyz and Au 8 -Lyz S14 S13 Root mean square fluctuation of Lyz and Au 8 -Lyz S15
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Supporting Information Gold-Induced Unfolding of … Ghosh,1 † Ananya Baksi,1† Sathish Kumar Mudedla,2 Abhijit Nag,1 Mohd Azhardin Ganayee,1 Venkatesan Subramanian ...
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S1
Supporting Information
Gold-Induced Unfolding of Lysozyme: Towards the Formation of Luminescent
Clusters
Debasmita Ghosh,1†
Ananya Baksi,1†
Sathish Kumar Mudedla,2 Abhijit Nag,
1 Mohd Azhardin
Ganayee,1 Venkatesan Subramanian
2 and Thalappil. Pradeep
1*
1DST Unit of Nanoscience (DST UNS) & Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology Madras, Chennai-600036, India
2Chemical Laboratory, CSIR-Central Leather Research Institute, Adyar, Chennai- 600020