SUBURBAN LABORATORIES INC - GAS ...30GU SUBURBAN LABORATORIES 4140 LITT ORIUE HILLSIDE, IL 60162-1183 TEL 312-544-3260 FAX 312 544-8587 GAS CHROMATOGRAPHY / MASS SPECTROMETRY TECHNICAL

30GUSUBURBAN LABORATORIES4140 LITT ORIUEHILLSIDE, IL 60162-1183

TEL 312-544-3260FAX 312 544-8587

GAS CHROMATOGRAPHY / MASS SPECTROMETRY TECHNICAL REPORT

FOR

ROY F. UESTQN, INC. SPER DIVISION

ill. NORTH CANAL STREET, SUITE *8(>5

CHICAGO, ILLINOIS 60606

ATTENTION: MS. MAUREEN 0'MARA

S/L REFERENCE * CLIENT SAMPLE REFERENCE ft DATE REPORTED

•1 " ; l'• 1 .. 2.• I

:|ill

8-12013

8-12014

8-12015

8-12016

564 Core 13 Top 12/5

565 Core 13 Bottom 12/5

566 Core 14 Top 12/5

567 Core 14 Bottom 12/5

12/14/88

12/14/38

12/14/88

12/14/88

CHAIN OF CUSTODY REQUIRED FOR ALL GC / MS ANALYSIS.

LaAssociate Dyfector

. „ »i « i.V;*i. — •-'—"7• jff^Si ??

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41-iC L i T T OPI ' jF . *H » i t c i r^c ' • t » k/H ^ » ' <t ri ^

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r,As ^ FuGftuPHY / ELECTRON CAFINAL REPORT

S/L FILE NUMBER. ..... .8-fl0013

GC/ECD SIGNAL FILE. . . . A:Q7903D84

FINAL REPCRT BV: SDB

PH- <2

DATE RECEIUEO: 17/07/99

CLIENT: ROY F. U-ESTQN

" So" 'lorq 13 Top 1

DATE EXTRACTED: 12/08/88

Mn t >• : Ijoo-i v i sua l rev>ii»>*J of the To 1 * I Inn C h r o m < s t o q r a m , u n i d ^ n t ipp.uks umre obrksrv-d ou t s i de o»-" those c a r a m e t e ' - - wh i ch are i i s t - d

. .1

»»/>»» PCL/CHLCa:MATED B I PHENOLS '. ~':s;S: rETHCO SCSO

COMPOUND MDLug/U q

CASNljnSER

PCL SAMPLE Cur: • ' . - • :

T

P'"R-LPp = - 'urr:_ -

•*" * fu i 6 . . . . . . . . .2^1TT1

^ . PPP._ i 9^19 . . . . . . .<r.

n .

P r~* Q 1

P r. R - 1r • i 1 1 1

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. < 1

. na.

. on.. V j Q .. 00.. 00.. 00.. no .

c;

2674-111104-29

? 44 9 -21. . . . . . . . . . 12A7-2-29. . . . . . . . . . 1

. . . . i

_ i_o

-1?.-9 .-f,

1097-69-1 .1 096-82-5.

. . . 1

. . . 1

. . . 1

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n .n0.c.

00. ..0-Q . . .

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. INTERNAL STANDARD

.METHOD DETECTION L1MIT_THE MINI nun CGNCHNTRor'lQN OF « SucSTHNCE TnAT CAK 5EMEASURED AND REPORTED UITH 99* CONFIDENCE THAT UALUEIS ABOVE ZERO.-CRef: SU-946 3rd. Ed.)

BOL .RELOU DETECTION LIMITDETECTION LIMITS LISTED H£«E1N wkAflD MAY NOT ALWAYS BE ACHIEVABLE.

PROVIDED FOR GUIDANCE,>

.._ . _ CL'ANTITATIQN LIMITTH£ LOWEST LEUEL THAT CAM BE RELIABLY ACHIEVED ul THINSPECIFIED LIMITS OF PRECISION AND ,ACCURACY O'JP'.NG RCUTIMELA20PATCRY OPERATING CONDITIONS.*1 ' THC PQL ' s LISTED HEPEINAPC pQCUIDED FOR GUIDANCE AMD rm/ryQ"' ALWAYS 8E ACHlE'.'AELPC1-1 a ARE HIGHLY MATRIX DEPENDENT:' ccT:f.RniNATiGN OF P C L - S

----- • <~ -rue- wni " ~ . .^.•»i-m nor1! •« MK— " I uni- ' ' • • • • • - - • - -" —— 3 r-r — _„„_,-,- tc TUC HPLFQR VARIOUS nA,«iC« IS T. HOL

U _!-'' ' i-— . -» '0 1 lATOFACTU^: oi-.uui-<i> UH.^. - x 1 2 J

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PPPAHETESS: SPB-408 JUfWJ^,'".i i n . ',

^Qm x 0 .25mm;HOLD 4 mm. AT

^-UP GAS; NITRCG;

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REU. 4/88

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SUBURBAN LABORATORIES, INC.4140 UTT DRIVE

HILLSIDE. ILLINOIS c0162

ANALYSIS OF ORGANIC CHEMICAL COMPOUNDS BYGAS CHfiOriATOliRAPHY / ELECTRON CAPTURE DETECTOR

FINAL REPORT

..... .6-12014

GC/ECD SIGNAL FILc....A:Q7902322

FlhWL REPORT SY: SDB

PH- a.5DATE RECEIVED: i?xn7xaa

CLIENT: ROY F. Ut-ISfUN

SAMPLE:" S6? Cor. 1?

DATE EXTRACTED: 12-'C8x93

Noes: Upon visual review of th« Total Ion Chroma t ogr-sm, un idenf i P i idpr»ol<5 iwer» observed cutaidrs of tho^o parameters which ara liatrd b^l

!•(•<»»»*•«' r »««« «*«»•*«

>»>»-.;>» POLfCHLORINATED (PCB'SJ M£THCC 8C30 ««««««

COMPOUND MDL C«S PQL SAMPLE COMCugXkg NLJMSER utj/Jcg

1 . »dlO- Anthracene...................... ....................... 185. QQ1. PCS- 10 16. ...... ......<1. 00........... 12674-11-1. .. .10.00. .. SOL2 . PC9-1221. ............ <1. 00. .......... 111C4-2R-2. .. .10.00. .. BDL7 . PCS- 12 32. ............<1.00........... 11141-16-5. .. .10.00. .. 8DL4. PCS- 1242. ....... . . . . . <1. 00. ......... .=3469-21-9. .. .10.00. .. 8CL5.. PCS- 1248. ...... .. ....<!. 00........... 12672-29-4. .. .10.00. .. BDL6. PCB-1254. ......... ...<1. 00.... ...... .11 097- 69-1.... 10. 00... BDL7 . PCS- 1 2oO .............< 1 . UU ........... 1 1096-82-5 ....10.00... BDL

*........! NTF.RMAI . STANDARD

MDL. .... .METHOD DETECTION LIMITTHE MINIMUM CONCENTRATION OF A SUBSTANCE THAT CAN BEMEASURED AND REPORTED UITH 99* CONFIDENCE THAT UALUEIS ABOVE ZERO. (Rafi SU-846 3rd. Ed.)

SOL...... OELOU DETECTION LIMITDETECTION LIT TS LISTED HEREIN ARE PROVIDED FOR GUIDANCE,ANO MAY NOT A. AYS QC ACHIEVABLE.

.. -JI

INF»ACT!C'->L QUANT I 7 AT I ON L I M I TTHE L3UK3T LEUEL THAT CAN BF. RELIABLY ACHIEVEDSPECIFIED LIMITS OF PRECISION AMD ACCURACY DUPLABORATORY OPERATING CONDITIONS. THF PGL ' 5. L I 3TE3 HEREAP£ PROVIDED FOR GUIDANCE AND HAY NOT ALWAYS £E ACH I EUAPCL'a APE HIGHLY MATRIX DEPENDENT. OE i'EP.M 1 NAT I CN CF PGFCR VARIOUS MATRICES IS TH£ hOL x FACTOR: GRCU^O UATERLCU-LEUEL SOIL x6?0; HIGH-LEUEL SGIL £ SLUDGES x 10,000:NQN-UATER MISCIBLE UASTE xlOO.OOQ. -(REF: SUJ-8-i6 3RD ED.)

x :

PAF.Al-,ETEP-S: SP8-609 FUSED SILICA CAPILLARY COLUMN 30m x O10 FILM THICKNESS: Q.25um; COL. TMP.: HCLD 4 mm. ATiSO'C, THEN TO 29Q'C AT 8'CXmio.; MAKE-'JP GAS: N i TROH.EN6 0m I /nun.; DET . : ECD ; SPLIT RATIO: 5:1

£U. 4/88

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S^N L~3CP^TCR!r 3. I "•ii-o LI n ?si'j£

HILLS1CF . ILLINOIS 00142

S OF CWHAM1CGAS CHKUnpTOGRAPHY / ELECTRON CAPV'_:Rr.

FINAL PEPljPT

S.'u FiLt NuntJd'K. ...... S-12 Gl-i w!JP. CLIENT: crrr ". '_'£S7CM

f-C-"cL"0 SIGNAL FH.E. . . . A: n7V2E44C SAMPLE:" 3^7 ."..err: 13 Bottom

F;N«I_ REPORT BY: FOR

PH- 6.5 " •

DwTE RECEivEO: l?/rs?,'39 C«TF EXTRACTED: 12/08/38

,-m •• n : Lloon v i 5 u 3 1 - i » v i i » u j ii t tne To t .^ 1 Ion Ch r o ma : 09 r J.TI , un i den t i f i rop «• A X a t / j « r , - cc^ri*vec) o u t a i d e o^ t 'hose p ^ r a m r ^ a r ^ un icn aro l i a t > s C t » e l .

»«*»-^^^^^^^4|**^*A^i#^-*<l0<#4k^****''*^***^**'**'*******^'* »«*»* *w ••%*

>-,>•.:-.>»>» FOLYCHLGR'. NAT£D SIPHEnVL'.i >'PC£'5: r.ETHCD 3380 «««<^<'

MDL CA3 .c'-'.- SAMPLE CCNC.uq/kq NUMBER ug/'-q

11 weigh t /

13?. GC:. ?rn-ici6 .........< i. oo .. 1267.4- 11-1.... in. oc ............ SOL2 . PCa-1221 .........< 1 . Oi) .. 11 lC^-2a-2 .... 10 . 00. ........... SOLJ . PCS-1232 ........ . •:! . OH . . 11141-16-'? .... i.0 . 00. ........... 3DL4. PC8-1262. ....... .<1.0Q. .55469-21-9. ... 10.00. ........... BOLK . PCR-12-V3. ........ <1. 00. . 12672-29-6. ... 10. 00. ........... BDL

7. PCS-1260. . . .. . . . .<1.00. .110*6-6^--7. . ..iu.uii......... ... 001.

+ ......-.. INTERNAL STANDARD

MOI.. .... .METHOD DETECTION LIMIT'THE MINIMUM CONCENTRATION OF A SU6Sf«MC£ ThrtT CAN 5£MEASURED AND REPORTED WITH 99S CONFIDENCE THAT YALUEIS A8QUE ZERO. (Ref: SW-846 3rd. Ed.) . • ,

BOL......BELOU DETECT I ON LIMITDETECTION LIMITS LISTED HEREIN ARE PROUIDED FOR GUIDANCE,AND MAY NOT ALWAYS BE ACHIEVABLE.

SliJiii^jfi^rj^

PRACTICAL CUANTITATIQN LlnlTTitE LOUEST LEUEL THAT CAN RE RELIABLY ACHiEUEO U I THINSPECIFIED LintTS OF PRECISION ANDLABORATORY OPERATING CiJNDiTICNS.ARt PRQOIOEO FOR GUIDANCE AMD n«YPQL'a APE HIGHLY nATRIX DEPENDENTFCR UAK1CUS MATRICES IS THE nOl. xLOU-LEUEL SOIL x670; HIGH-LEUfiL SOIL & SLUDGES xiO.OOO

HISCIBLE WASTE xlOO.QCQ. ( REF : 5^-9^6 3RD30m x 0.25mm:HOLD 4 min. AT-uP GAS: NITRC:

ACCURACY DURING ROUT 1 METHE PC'_ ' a LlSTFH Hr^ElNNOT AL'^YS Gf ACHIEVABLE

DETERn I NAT ION OF P'~L ' iFACTOR: GROUND UATER x 1

GC PARAMETERS: SP8-608 FUSED SILICA CAPILLARY CCLLID FILM THICKNESS: O^Sum; COL. Tr.?150'C, THEN TO 290'C AT S'C/mir..; r.60ml/min.; DET . : ECO J SPLIT RATIO:

REU.

•M ' 'I... i

I' .'_tL* *~ M

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'^'^^?3F$?3&B^^

LABORATORIES, INC.A 1*0 LITT C'SH;£

HILLSIDE, ILLINOIS 60162

CF ORGANIC CHEMICAL COMPOUNDS SYG-'»3 CHRCnATQGRr.PHY / ELECTRON CA

FINAL REPORT

S/L r i L t NUMd'cK . . . . . . . 6- 12 0 15

r>C 'FCO SIGNAL r ILE. . . . Ai

F i'-iAL ^EPQPT BY: SOB

PH- <2

C.-HTE RECEIVED: 12 ''07/03

CLIENT: RCV F. wF.oTCN

SAMPLE:" S66 Core 14 Top i

EXTRACTED: 12/QS/S6

!-ii:te': Uoon v i s u a l r«visw of the TO t -•» ', icr Ch r cm.o : c. ram , un i den r i f i * ,-pcaU» un r • cb.^orwi-cJ o u t s i d e of the as p.a :• i .e t 2 r$ i-r i :n ar« l i ^ r < » d hrl

V / /

o

T

•

« .6 .7.

A

MDL

; > > > >

FOB- i

FC3-1F C EJ - 1

PC-3-iPCE-l

5 > ; POL

CCMPljlJN

0 A. 6 . . .

I' 7° .°^? .

25/». . . .2* 0. . . .

. METHOD

YCnLCRINATID

0 MO

. . . . . . . . .< 1.

. . . . . . . .< 1 .

... . . . . . . < 1 .

. . . . . . . . < ; .. • i

. . . . . . . . .< ! .

. . . . . . . . : i.

<3L STANDARD

DETECTION L

6 IPhENYLii,

L

00. . . . . . . . .00. . . . . . . .0 0 . . . . . . . .G O . . . . . . . .n n . .CO . . . . . . . .0 0 . . . . . . . . .

IMIT

•: -° ,- ' b ) r,t~HOD 8080

Ci^S PuLNUMBER

' *-> / ~* ' •* 1 1 I (1

. . . 1110^-28-2. ... 10.

... 1 11^ 1-16 -5. ... 10.

. . .«37469-21-9 . . . .10.1 •?«.- '7_ '?Q-A. ... 1 0.

. . . i ibV^-bV-l . . . , "LU.

< < S V. <

3»=

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00. ..OU. . .on. . .ULi . . .f\ **

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** 3i r~- ^p>'PL_ •-ug •/'--. •:

1 R "> . •)pr i

301. 'SDLWl 11

BDLDULr^*^t

BDL

THE MINinun CONCENTRATION OF ft SUBSTANCE THAT CAN BEMEASURED AND REPORTED UITH 99* CONFIDENCE THAT VALUEIS ABQUE ZERO. (Reft SU-0-06 3rd. fd.)

BELGU LCTECTION LIMITDETECTION LIMITS LI^Tl£u HEREIN ARE PROVIDED FOR GUIDANCE,AND MAY NOT ALWAYS Bt ACHIEVABLE.

ob)

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LABORATORIES, INC.414Q LIT! 0*1',£

HILLSIDE, ILLINOIS 60lo2

ANALYSIS CF ORGANIC r.HEMlTAL COMPOUNDS 9YGAS CHRCnwTOGRAPHY / ELECTRON C PTlJP. DETECT

FINAL REPUWT

i••SK (Gil

•T 1

't H

3/L FILE HIJM8FR. ..... .8-12016 CLIENT: ROY F.

GC/ECO SIGUAL FILE.... 3.~.r.PL£:M S«7 Co--? 14 8o<tom 12/5 "

FINAL REPORT BY: S08

PH- 8.5

DATE RECEIVED: 12/07/fl8 O^TE EXr«ACTSD: 12>'C3/93

Notis: Upcn visCial review of the Tota l Ion Chroma tog ram., un iden t i f ind» uer-ds observed outside of thoa* parameter* uhich are l isted bclo'-j.

PGLYChLCRlMATED 91PHENYLS tPi:8'Si .METHOD 8D30

COMPOUND MDLug/U

CAS PQL SAMPLE CC

1.»dlO-Anthracene............................................. 135.COi. Pea-1016.............<i.oo...........r:o74-ii-i....10.00... SOL2. PC3-1721. ........... .'.1.00. ......... .11104-28-2. .. .10.00. .. 8DL?. PCS-1232.............<1.CC...........1UA1-16-5....10.00... 8DL4. PCS-1242.............<!.00... ........53A49-21-9....10.00... BOL5. PCB-12A8.............<1.00........... 12672-29-6....10.00. . . BOL6. PC8-1254.............<1.00.......... .11097-69-1....10.00... BDL7. fCO- 12*0,.,,,,.,.....'. 1.00........... 11096-82-9. . . . Lfl.QC. . . SDL

«

*........INTERNAL STANDARD«OL......METHOO DETECTION LIMIT

THE MINIMUM CONCEHTSAT;:::* CF n SUSSTANCC THAT CAN BE •MEASURED AND REPORTED WITH 99S CCNFIOEMCE THAT UALUEIS A8QUE ZERO. (Raf: SU-846 3rd. Ed.)

BDL......BELOU DETECTION LIHIT •DETECTION LinITS LISTED HEREIN ARE PROVIDED FOR GUIDANCE,AND MAY NOT ALWAYS BE ACHIEUA8LE.

TH;N. . . . . c°ACT:CAi_ CUANTITATICN u. I ni T

THE LCUE3T LEYEL THAT CAN BE RELIA3LY ACH;E'JE3 '>S~ EC l~l EC- LIMITS OF FPECI5IQN AND ACCURACY C'JP. I."LAECPATCP.V OPERATING CCMO!TICNS. TVE PQL' 5 LISTED HE = E_IM;-,pr poQiJlOEO FOP GL'!OAklCE AMQ MAY NOT ALWAYS SE -a-jH IE'J«?LE.P:;..'! ARE HIGHLY M A T P I X CEPENCEMT. CETERM:MAT;CN OF PQL'SFC° UAQiOijS MATRICES IS THE nDL x F^CTGP: GPCLJNC 'JATE* xlC;LOU-LEUEu SOIL x670; HIGH-LEUEL SOIL i SLUDGES x10,COO;NCN-UATER M1SCIBLE UASTE xlOO,000. (REF: SU-B~6 7PO ED.1)

PARAMETERS: SPB-609 FUSED SILICA CAPILLARY COLUMM JCm x 0.25mm;10 FILM THICKNESS: 0.25um; CCL. TMP.: i-C^D 4 mm. AT1?S'C, THEM T2 290 *C ftT 6 ' C^-n •. r>. : MAKE-L:P GAS: NiTSCGEN6OmIxmin.; DET.: ECO; SPLIT RATIO: ?:1

RE'J. <i/83

SUBURBAN LABORATORIES, INC.Al-iO LITT DRIVE

HiLLSIRE. ILLINOIS o!K6C

ANALYSIS OF ORGANIC CHEMICAL COMPOUNDS SYGAS CHRCr!ATQG»«PHY / ELECTSCN CftPTUP.F, OFTECTCR

FINAL REPORT

S''L FILE NUMBER....... BLANK S/F

GC/ECO SIGNAL FILE....A:079019EV

FINAL REPORT BY: SOB

PH-

OATE RECEIUEO: 12x*07,'89

CLIENT: ROY F. UIE3TUN

SAnPLe:

DATE EXTRACTED:

NO t f> : Llpon visual review of the Totji Ion Chroma t ogrgm , un jderit i F i edwere observed outride of those oarameters which ai"« listed be'.

••»»»> PCLYCHLOPt NATED SIPHENYLS ( PCB ' S i HETHCD 8030 «««««.

COMPOUND

9.e7.

d 10 -AnthracenePCS- 10 16. .....Pr.B-1221. .....PCS-12?2. .....PC8-1242PCE-1248

r.DLug'Uq

............< 1

............ <1

............ <l

............ <1

......... ...<ii°CB-i71*. ............ ,-i

OP, .On.Ou .00 .00.r.l.

CASHUMBEP

PQL SAMPLE CC:

PCS- 1260. ............< 1. 00

\t 6 7*- 11-1. ... 10.00. ..11104-29-2. .. .10.00. ..111^1-1^-5. . . .10.00. . .53469-21-9. .. .10.00. ..12672-29-6. .. .10.00. ..11097-69-1. .. .10.00. ..I tO»A-«3 -»,,,, 10, 00, , .

13"? . 08CLBDLSOLEOLBOLSOLBCL

*........ INTERNAL STANDARD

BOL

DETECTION LIMITTHE MINI MUM CONCENTRPMON OF A SUSSTa-lSE THAT CAN BEMEASURED. AND REPORTED UITH 99% CONFIDENCE THAT VALUEIS ABOUE'ZERO. (Ref: SU-846 3rd. Ed.)

BELOW DETECTION LIMITDETECTION LIMITS LISTED HEREIN ARE PROVIDED TOR GUIDANCE,AND MAY NOT ALUAYS BE ACHIEVABLE.

L CUAN v i TAT ;CN LIMITST LE^EL TH«T CAN BE RELIABLY ACHIEVED ^ I TH I N

~P£C;FiEO LinlTS GF PRECISION ANO ACCURACY CUP I NG ROULA3CS-7CPY OPERATING CONDITIONS. THE PGL ' a LISTED-~E PRCuiDcO POP GUIDANCE AND HAY NOT ALWAYS BE ACH ; tUA-',;>.' a A^E HIGHLY HATRIX OErENCENT. CETEP" I MAT I CM 0" PCL ' a--r,=? UARICUS HATRiCcS IS THE HCL x FACTOH: GSC^ND UnTER « L C ;LCU-LEWEL SOIL «6?c; HIGH-LEUEL SOIL L SLUDGES -« 10,000;

ER r.ISCiBLE UPiSTE x l O O , 0 0 0 . (REF: SU-l ^ 3RD E 0 . 3

SP3-609 FUSED SILICA CPh'lLLWKY COLUMN 3 Cm « C.29n.,n;ID FIL.1 THICKNESS: 0.25um; CCL . Tr.P.: HCLC -- rn i n . AT1^0 'C, TH£st TO'290'C AT 8'C/min.; HAKE-UP ^A-6: NITROGEN6Qml/min.; OET.: ECD; SPLIT RATIO: 5:1

REU. 4/88

SUGURSAN LABORATORIES, INC.

HILL3JCE, t..LI NO I 3 60loC

_rS:5 OF ORGANIC CHEMICAL COMPOUNDS BY»S OROttATDGRAPHY / ELECTRON CAPTURE DETECTOR

FINAL REPORT

1S/L F ILE NUMBER. ..... .BLANK SOX

i;;VEC& SIGNAL FILE. ...

F'.HAL REPORT 3Y! SDQ

PH*

GHTE RECEIUED: 12X07/88

CLIEN1 : ftOY F. UtSTON

DATE EXTRACTED:' 17/08/83

Ne,r«: Upon v i s u a l ra-^iaw of thu Total lan Ch roma t ogram , un id«n «: i »•' i edot»«rv«d oufsicS's of thoia par am« f«9r-j whinh *r* liatec! b-?'.r

»»••»**•*»*«••

•»>»»»»> PCLYCHLQR tNATED 81PHENVLS (PCB'5) r.ETHOO 8030 <«««'«

COMPOUND MOL

1.? .3u .K t6 .

PCB-1016. . . .Oi~S_ 1 ")~> 1

eca i ** ' *^PCS— 1 *> .i.Qprp.i ORu«^ V* •«.• Jt fc r "* • > • •

......... <1 . 00. ....

.........< i . o n .....

......... <1 . 00. ....

........ ,<1.00. ....* « • • * • • * • ^ i * » U U * » * * «

»CAS

NUMBER

...... 12674-11-1.*> i n A— *^ft—

... ...111*1-16-5.

..... .12672-29-6.

..... .11097-69-1.

»«*«»«•PQL

... 10 .

... 10.

. . .10.

...in.

... 10.

. . .10.

.. .10.

SAMPLE

00. . .00. . .00. . .00...00. . .00. ..no. . .

5~LSOLSCLBDL

BDL

STANDARD

SOL

METHOD DETECTION LII1ITTHE r.!!*!WJM COMCFNTBATION OF A SUBSTANCE THAT CAN BEMEASURED AND REPORTED WITH 99S CONFIDENCE THAT UALUEIS ABOUE ZERO. (Ref: SU-346 3rd. Ed.)

BELOW DETECTIi/N LlltlTDETECTION LIMITS LISTED HEREIN ARE PROUlDEO F0« GUIDANCE,AND MAY NOT ALUAYS BE ACHIEVABLE.

PGL..... PWACTICAL GUANTITATICN LIMITTHE LOWEST LEVEL THAT CAN BE RELIABLY ACHIEVED WITHINSPECIFIED LIMITS OF PRECISION AND ACCURACY DURING ROUTINELABORATORY OPERATING CONDITIONS. THE PGL's LISTED HEREINAP£ PROUIOEO FOR GUIDANCE AMD MAY NOT ALWAYS 3E ACKlcUASLEPQL'» ARS£ HIGHLY MATRIX DEPENDENT. OFTERdlNATION OF PQL * 3FOR VARIOUS MATRICES IS THE MOL « FACTOR: GROUND WATER »iLOW-LEVEL SOIL x670; HIGH-LEVEL SOIL t SLUDGES x!0,OnO;NCN-UATER niSCIBLE WASTE xlOO.OOO. (R£F: SW-846 3RD tU.>

GC PARAMETERS: SP8-60S FUSED SILIC« CAPILLARY COLUMN 3G« x 0.25mm;ID FILM THICKNESS: 0.25um; COL. TMP.: HOLD A min. AT150'C. THEN TO 290'C AT Q'CXmin.; MAKE-UP GAS: NtTRCG.:60mlXmin.; DET.: ECO; SPLIT RATIO: 5:1

. REV. 4/86

'*" 1 "

•H

SUBURBAN LABORATORIES, IN•il«Q LtTT CRIME

HILLSIDE. ILLINOIS 65 laS

•ANALYSIS OF OFGAM'.C CHEMICAL CCrx ELECTRON CAPTU

FINAL REPORT

Cu: «CS 5VE DETECTOR

••_ FILE NUni=£R. . . . . . .SPI*E PCS S/'r CLIENT: R'JY f. UESTON

: -c:CO SIGNPL Fti_£. . . . A:

•• IMAL REPORT SY: SOS

SAMPLE I"PCS 1221, 20ngXulfull extraction "

DATE EXTRACTED: 12X09/93

Upon visual raviau o? tHa Total Ion Chroma cogram, unidentifiedcutsida of those parameter-* which are listed boloui.

**««»•»«•••••*<

>• > ? > PGLVCHLORIMATED 6T.PHENYL5 (PCS' 5) ME THCO 80S. 3 <;«<««««

COP1PCUND nOL CrtS FGL EXPECTED TRUE HRE-uqxi<9 Nur.EER CONC. CONC. CQUERY

1 , *d 10-An thrscena . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 . PCS- 10 Id. . . . . . . . . < 1 . 0 C . . 1267^-11-1 . . . .10 .00 . . . . . . . . . . . . . . . . . . . .2. PCS- 1221. ...... ..-: 1.00. .1110A-23-2. .. .10-00. .. .250. .... ..175.. . 70*? . PCS- 1272. . . , . . . . .< ! . no. .11141-16-5. . . .10.00.. . . . . . . . . . . . . . . . . . .6. PCS- 12 42. .... . . . .<!. 00. .53469-21-9. . . .10.00. . . . . . . . . . . . . . . . . . . .r , PC8-124Q. . . . . . . . . < 1 . 0 0 . . 12672-29-6. . . . 10 .00 . . . . . . . . . . . . . . . . . . . .6 . PCB-12%*. . . . . . . . .« i .oy . .Hn»5» ' - -»»™t . . . . to . OD, , , , , , i ! i i ,,. • , , , , , ,7. PCS- 1260. ........<1.0Q.. 11U96-82-5. ...10.00....................

*........ INTERNAL STANDARDMOI....... METHOD DETECTION LIMIT

THE MINIMUM CONCENTRATION OF A SUSSTANCE THAT CflN BEMEASURED AND REPORTED UITH 99H CONFIDENCE THAT VALUEIS ABOVE ZERO. (Raft SU-846 3rd. Ed.)

80L:.....8ELOU DETECTION LIMIT .DETECTION LIMITS LISTED HEREIN ARE PROVIDED FOR GUIDANCE,

MAY NOT ALWAYS BE ACHIEVABLE. . '

oni^•1.- PRACTICAL QUANTITY! I ON LlrKTTHE LOWEST LEUEL THAT CAN BE RELIABLY ACHl£U£0 UI THINSPECIFIED LI HITS OF PRECISION *NC ACCURACY DURING R!3UTl?«ELABORATORY OPERATING CONDITIONS. THE PGL-S LIST-:DAPE PROVIDED FOP GUIDANCE ^MO MMV NO" eL'-»AYS 3E ACHPCL'9 APE HlSriLY MATRIX Ce?ENCEr4T. DSTERn.'MAT ION OF P'JL ' »FOR VARIOUS n«TRlCcS IS TM£ rtOL x FACTGR: GRCUNC UATER x ILCU-LEVEL SOIL x6?0; HIGH-LEUEL SOIL i SLUDGES x10,000;HON-UATER niSCIBLE UASTE xlOO.OOO. <R£F: SU-8A6 3RD- ED.i

GC PARAMETERS: SP8-603 FUSED SILICAID FILM THICKNESS: 0150'C, THEN TO 290'C

CAPILLARY COLUMN25um; COL. TMP. :AT 8'C/min.; MAK

30m x 0.25mm;HOLD 4 min. A-uf GAS: N,rT<.-'

D£T. : ECO; SPLIT RATIO: 5:1

REU. 4/SQ

SUBURBAN LABORATORIES, INC.-143 LI rr CPi'.-e

HILLS ICE, ILLINOIS -.1)167

ANALYSIS '".F f jP^AfJJCCHPQMATC'^APHV / ELECTRO! C

FlrUL PEPCP.T

8V

SAMPI.F.:"PC9 12C1 . 2F u l l extract ton "

SXL PILE NUMBER. ..... .SPIKE PC8 SU* CUEUT: ROY F. UiESTON

CC.-'£C2 S1SM-L FILE. . . .A:q

Flhwi. >?£PQRT BY: SOB

pw-

DATE RECEIVED: 12/0 /"38 DATE EXTRACTED: 12/08.'8S

'Jcon visua l r<svi-»ui nf ^he T o t a l Ion "H^A were observed oufa ide of ^r.-jma t era *ihic^. are 1 t.^fnd below

Can?OUMO nDl. CASf.UMSES

P:JI. EXPECTEDCONC.

TRUE XPE-CONC. CQUEft

l.»d\0-Anthracene.................................................i. PCS-1016.........<1.0C..12674-11-1....1C.CO....................7. PCa-1221......... a.CC..11104-29-2. ... 10.00....250.......217...3. PCS-1232..... ....<!. 00.. 111-41-1 A-1?. ...10.00....................«i. PCB-1242.........<1.00..53469*21*9....10.00....................9. PCB-1248.........<1.00..12672-29-6....10.00....................6. pea-is*-*......... * i. oa. ,tiq«j>^d«>t t,, ,10.nil..4.«»...............7. PCS-1260.........<!.00..11096-82-?....10.00....................

MM.

COL.

.INTERNAL STANDARD

.METHOD DETECTION LIMITTHE MINI nun CONCENTRATION OF A suasr ucE THAT CAN BEMEASURED AND REPORTED UlTH 99S CONFIDENCE THAT UALUEIS A80UE ZERO. '(Rsf: SU-846 3rd. Ed.)

.BELOW DETECTION LIMITDETECTION LIMITS LISTED HEREIN ARE PROVIDED FOR GUIDANCE,AND MAY NOT ALWAYS BE ACHIEVABLE. . .

T'JO a. L 1-iPIXE PCS 5CX

PRACTICALTHE LOWEST• : r£C:FIEO

PCX '

GUANTlTrtTION LIMITLEVEL THAT CAN B£ RELIABLY ACHIEUFO u i T H I N

L in ITS CF PRECISION AND ACCLJPACY DUP i '->G ROUTINECP£PATiNG CONDITIONS. THE PCL's LISTED HEREIN

Ff!P GLUDAHLE AMD f.A/ N'.TT ALUAYS 5£ f.:-* I E'-'^et.E.•% ARE HIGHLY nnTP.IX DEPENDENT. DETERH <A T [ 3N Or r'd'^'sVM.RIQL'S MATRICES IS TH£ PCL v FACTOR: IMPOUND u»TER xiO

SOIL x67n; HIGH-LEOEL SOIL & SLUDGES xlQ.GOO;niSCIBLE UASTE xlOO,000. tPEF: SU-R^6 3RD ED.)NCN--JHTER

SP8-60S FUSED SILICA CAPILLARY COLUMN >0m x10 FILM THICKNESS: 0.2 = um; COL. TflP.: HOLD •l^U'C, THEN TO 290'C AT 3 ' CXm i n . ; n^KE-LP G.6Uml/min. ; DET.: ECD; SPLIT RATIO: 5:1

G.25mm;min . AT

S: NITROGEN

P.EU. 4/93