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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Date: January 19, 2015
Subject: Data Validation for Lab Report L14120172 Radford Army Ammunition Plant
From: Linda Thal Senior Data Validator, AQA
To: Mary Lou Rochotte Kemron Environmental Services, Inc.
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
OVERVIEW
Microbac Laboratories Inc., Marietta, Ohio, received 10 field samples associated with the project work described in the Radford Army Ammunition Plant Final SWMU 40 (RAAP-009) Landfill Nitro Area IMWP (August 2011) (project QAPP) on December 3, 2014. The field samples were assigned laboratory sample delivery group (SDG) number L14120172 and included four normal water samples, one field duplicate water sample, one matrix spike pair, one equipment blank, one field blank, and one trip blank. The samples were analyzed for volatile organic compounds (VOCs) by EPA method 8260B, perchlorates by EPA method 6850, and total metals by EPA methods 6010B and 6020 as detailed in Test Methods for Evaluating Solid Wastes, Physical/Chemical Methods (SW-846), Third Edition, Final Update III.
SUMMARY
The samples were analyzed according to the quality control (QC) criteria of the applicable analytical method. The data for these samples were found to be compliant with the requirements of the project QAPP and/or EPA Region III’s Innovative Approaches to Data Validation (June 1995) and EPA Region III Modifications to the National Functional Guidelines for Organic Data Review (September 1994) or EPA Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses (April 1993) (Region III NFG, collectively), as applicable, and the results for all target analytes are considered usable.
MAJOR PROBLEMS
(Refer to Appendix B – Data Qualifier Summary)
• There were no major problems associated with the samples in this data package.
MINOR PROBLEMS
(Refer to Appendix B – Data Qualifier Summary)
• 40MW7GW12214: Acetone (UJ) Manganese, total (0.00135 L) Selenium, total (UL) Lead, total (UL)
• 40EQR12214: Acetone (UJ) Manganese, total (UL) Selenium, total (UL) Lead, total (UL)
• 40FB12214: Acetone (UJ) Manganese, total (UL) Selenium, total (UL) Lead, total (UL)
• 40MW5GW12214: Acetone (UJ) Manganese, total (UL)
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Selenium, total (UL) Lead, total (UL)
• 40DUPGW12214: Acetone (UJ) Manganese, total (UL) Selenium, total (UL) Lead, total (UL)
• 40MW6GW12214: Acetone (UJ) Manganese, total (0.00265 L) Selenium, total (UL) Lead, total (UL)
• LFMW01GW12214: Acetone (UJ) Manganese, total (0.00368 L) Selenium, total (0.000738 L) Lead, total (UL)
• 40TB12214: Acetone (UJ) NOTES
(Refer to Appendix D – Support Documentation)
Sample Chain of Custody (COC) Records
• The samples were listed on COC #A6140. Data were reported for all required analytes.
Preservation and Holding Times
• The samples were correctly preserved and analyzed within the holding times specified in the project QAPP and the Region III NFG with the following exception.
- The samples were not preserved for VOC analysis. The samples were analyzed within the holding time for unpreserved samples and, therefore, no sample data were qualified.
Instrument Tune
• The instrument tunes for all applicable analyses were within the criteria specified in the project QAPP and the Region III NFG with the following exception.
- The perchlorate tune data were not included in the data package. The laboratory previously stated that the instrument was tuned after maintenance was performed and that the ion ratio was verified with every sample reported to demonstrate that the instrument was working properly. No sample data were qualified based on professional judgment.
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Initial Calibration (ICAL)
• The ICAL relative response factors (RRFs), percent relative standard deviations (%RSDs), and/or correlation coefficients, as applicable, for all analyses were within the criteria specified in the project QAPP and the Region III NFG with the following exceptions.
- The ICAL relative response factors (RRFs) were <0.05 for acetone. Because acetone is considered to be a poor responder and the RRFs were >0.01, the associated non-detect sample results were qualified UJ based on professional judgment.
Initial Calibration Verification (ICV)/Continuing Calibration Verification (CCV)
• The ICV and/or CCV RRFs, percent differences (%Ds), and/or recoveries, as applicable, for all analyses were within the criteria specified in the project QAPP and the Region III NFG with the following exceptions.
- The ICV/CCV RRFs were <0.05 for acetone. Because acetone is considered to be a poor responder and the RRFs were >0.01, the associated non-detect sample results were qualified UJ based on professional judgment.
Contract Required Detection Limit (CRDL)
• The perchlorate CRDL was analyzed at the reporting limit (RL) and not at 2X the RL. No sample data were qualified as a result.
• A CRDL standard was not analyzed for method 6010B. The laboratory calibration curve was linear with a standard at or near the reporting limit (RL) and, therefore, no sample results were qualified. The laboratory analyzed a low level ICV (LLICV) for the calcium dilutions. However the results were not reported in the data package and it was not possible to recalculate the results due to insufficient information available.
• A CRDL standard was not analyzed for method 6020. The laboratory analyzed an LLICV, and the recoveries were reported in the raw data. The LLICV recoveries were >50% but <89% for manganese, selenium and lead. The manganese results for samples 40MW7GW12214 and 40MW6GW12214 and the manganese and selenium results for sample LFMW01GW12214 were detects > the method detection limit (MDL) but <2X the RL and were qualified L. The remaining associated sample results were non-detects and were qualified UL.
Inductively Coupled Plasma (ICP) Interference Check Sample
• ICP/ICP-MS interference check sample recoveries were not applicable because the results for interferents aluminum, calcium, magnesium, and iron were < the ICS spike amounts for all samples.
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
• Perchlorate interference check samples were not analyzed or reported in the data package. The laboratory analyzed and reported an MCT sample that met criteria.
Field Blanks
• No target analytes were detected in the field blank, equipment blank, or trip blank.
Laboratory Method Blanks
• No target analytes were detected in the method blanks.
Laboratory Calibration Blanks
• Sodium was detected in a calibration blank. The associated sample results were either detects >5X the calibration blank concentration or non-detects and, therefore, were not qualified.
Laboratory Control Samples (LCSs)
• The LCS recoveries met project QAPP- and Region III-specified QC acceptance criteria.
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Samples
• One MS/MSD pair was analyzed on sample 40MW5GW12214 for all analyses and met project QAPP- and Region III-specified QC acceptance criteria with the following exceptions.
The MS/MSD recoveries were > the upper acceptance limit for calcium. The parent sample concentration was >4X the spike amount and, therefore, no sample results were qualified.
ICP Serial Dilution Analyses
• The serial dilution %Ds met project QAPP- and Region III-specified QC acceptance criteria. It should be noted that the method 6020 serial dilution was performed on the equipment blank.
Laboratory Sample Duplicate
• MSDs were analyzed as the laboratory duplicates for all analyses and met project QAPP- and Region III-specified QC acceptance criteria for precision.
Field Sample Duplicate
• Sample 40MW5GW12214 was collected and analyzed in duplicate (sample 40DUPGW12214) for all analyses. The relative percent differences (RPDs) between the sample and duplicate results were within the project QAPP-specified control limits.
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Analyte Result RL Result RL RPD >25%
Perchlorate 0.883 0.2 0.856 0.2 3.11Al, total 0.256 0.2 0.3 0.2 15.83Ca, total (10X) 41.4 5 40.63 5 1.88Fe, total 0.155 0.1 0.177 0.1 13.25Mg, total 13.2 0.5 12.4 0.5 6.25K, total 0.764 1 0.817 1 <RLNa, total 6.58 0.5 6.35 0.5 3.56Ba, total 0.024 0.003 0.0241 0.003 0.42
40DUPGW1221440MW5GW12214
NOTE: All results not listed in the table were non-detects.
Sample Surrogate Spikes
• Surrogate spikes added to all field samples analyzed for VOCs were within the project QAPP-specified control limits.
Sample Internal Standard Recoveries
• The internal standard recoveries for VOCs and perchlorates were within the project QAPP- and Region III-specified control limits.
• The internal standard recoveries for metals by method 6020 were within the 60-125% limits provided in the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic Data Review (NFG) (October 2004).
Sample Results
• The samples were analyzed for the methods requested on the COC. Method detection limits (MDLs) and RLs were reported for all analyses and met project-specified MDLs and RLs with the following exceptions.
- The MDLs and/or RLs for potassium, aluminum, calcium, and iron were > the MDLs/RLs specified in the project QAPP.
- The MDLs for arsenic, barium, cobalt, lead and manganese were > the MDLs specified in the project QAPP; however, their associated RLs were ≤ the RLs specified in the project QAPP.
Action Level Notification
• No results were above the action levels specified in the EPA Region III’s Innovative Approaches to Data Validation (June 1995).
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Usability Statement
• There were 146 field sample data points associated with the data package for SDG L14120172. Of these field sample data points, 109 (74.66% of the total) were assessed and left unqualified, 10 (6.85% of the total) were assessed and qualified UJ, 4 (2.74% of the total) were assessed and qualified L, and 23 (15.75% of the total) were assessed and qualified UL.
• The field sample data points that were qualified UJ can be categorized as definitive data with non-detectable analyte concentrations that are only estimates due to QC deficiencies.
• The field sample data points that were qualified UL can be categorized as definitive data with non-detectable analyte concentrations that are only estimates and possibly biased low due to QC deficiencies.
• The field sample data points that were qualified L can be categorized as definitive data with positively identified analyte concentrations that are only estimates and possibly biased low due to QC deficiencies.
• The unqualified field sample data points can be categorized as definitive data with no associated QC deficiencies. Based on the number of unqualified data points, the percent completeness is 74.66%.
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Report Content Statement
This report has been formatted for consistency with Appendix B, Region III Standard Operating Procedures for Data Validation Reports, contained in the guidance EPA Region III Modifications to the National Functional Guidelines for Organic Data Review (September 1994). The laboratory data were reviewed in accordance with the EPA Region III’s Innovative Approaches to Data Validation (June 1995) and EPA Region III Modifications to the National Functional Guidelines for Organic Data Review (September 1994) or EPA Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses (April 1993) (Region III NFG, collectively), as applicable; and the Radford Army Ammunition Plant Final SWMU 40 (RAAP-009) Landfill Nitro Area IMWP (August 2011) (project QAPP); and the applicable SW-846 methods. This report only addresses those problems and issues that may affect data usability.
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Attachments
Appendix A – Glossary of Data Qualifiers
Appendix B – Data Qualifier Summary
Appendix C – Laboratory Report Results/Data Summary
Appendix D – Support Documentation
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Appendix A – Glossary of Data Qualifiers
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A-1
Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Data Qualifier Codes
Codes Related to Identification
U Not detected. The associated number indicates the approximate sample concentration necessary to be detected.
B Not detected substantially above the level reported in laboratory or field blanks.
R Unusable result. Analyte may or may not be present in the sample.
Codes Related to Quantitation
J Analyte present. Reported value may or may not be accurate or precise.
K Analyte present. Reported value may be biased high. Actual value is expected to be lower.
L Analyte present. Reported value may be biased low. Actual value is expected to be higher.
UJ Not detected. Quantitation limit may be inaccurate or imprecise.
UL The analyte was not detected, and the reported quantitation limit is probably higher than reported.
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Appendix B – Data Qualifier Summary
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Data Qualifier Summary
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Note: The results listed in this table are detects and qualified non-detects only. Unqualified non-detects are not listed.
FIELD SAMPLE ID/ LAB SAMPLE ID
ANALYTE FINAL
VALIDATION QUALIFIER
INITIAL LAB QUALIFIER
REASON
40TB12214 L14120172-01
Acetone UJ U ICAL/ICV/CCV RRFs <0.05
40MW7GW12214 L14120172-02
Acetone Manganese, total Selenium, total Lead, total
UJ L
UL UL
U J U U
ICAL/ICV/CCV RRFs <0.05 LLICV recovery >50% but <89% LLICV recovery >50% but <89% LLICV recovery >50% but <89%
40EQR12214 L14120172-03
Acetone Manganese, total Selenium, total Lead, total
UJ UL UL UL
U U U U
ICAL/ICV/CCV RRFs <0.05 LLICV recovery >50% but <89% LLICV recovery >50% but <89% LLICV recovery >50% but <89%
40FB12214 L14120172-04
Acetone Manganese, total Selenium, total Lead, total
UJ UL UL UL
U U U U
ICAL/ICV/CCV RRFs <0.05 LLICV recovery >50% but <89% LLICV recovery >50% but <89% LLICV recovery >50% but <89%
40MW5GW12214 L14120172-05
Acetone Manganese, total Selenium, total Lead, total
UJ UL UL UL
U U U U
ICAL/ICV/CCV RRFs <0.05 LLICV recovery >50% but <89% LLICV recovery >50% but <89% LLICV recovery >50% but <89%
40DUPGW12214 L14120172-06
Acetone Manganese, total Selenium, total Lead, total
UJ UL UL UL
U U U U
ICAL/ICV/CCV RRFs <0.05 LLICV recovery >50% but <89% LLICV recovery >50% but <89% LLICV recovery >50% but <89%
40MW6GW12214 L14120172-09
Acetone Manganese, total Selenium, total Lead, total
UJ L
UL UL
U
U U
ICAL/ICV/CCV RRFs <0.05 LLICV recovery >50% but <89% LLICV recovery >50% but <89% LLICV recovery >50% but <89%
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Data Qualifier Summary (Cont.)
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
FIELD SAMPLE ID/ LAB SAMPLE ID
ANALYTE FINAL
VALIDATION QUALIFIER
INITIAL LAB QUALIFIER
REASON
LFMW01GW12214 L14120172-10
Acetone Manganese, total Selenium, total Lead, total
UJ L L
UL
U J U
ICAL/ICV/CCV RRFs <0.05 LLICV recovery >50% but <89% LLICV recovery >50% but <89% LLICV recovery >50% but <89%
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172
Appendix C – Laboratory Report Results/Data Summary
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L14120172 / Revision: 0 / 1302 total pages Generated: 12/17/2014 09:08Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-10
Page 43
;���&���0�&�������+����>������4�
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� ��#��� !���$�!%�� "�"�������!�"�!�������!� ������*
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Page 13
L14120172 / Revision: 0 / 1302 total pages Generated: 12/17/2014 09:08Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-11
Page 44
��������� �� *������&���� ����%�����%����)��������!�"�!�������!� ������*
���+����%�����%����)�����!�"������ ! ��� ���*#�����������$����+��&�!�!�# � *��!�"�� ��)�,��-�!������,��&-�#�������!������"��!�����.�#�$��*!���*
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Page 14
L14120172 / Revision: 0 / 1302 total pages Generated: 12/17/2014 09:08Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-12
Page 45
SURROGATES - Modified 03/06/2008
12/04/2014 14:57Report generated:3903590PDF File ID:
SURROGATE STANDARDSMicrobac Laboratories Inc.
L14120172-01 L14120172-02 L14120172-03 L14120172-04 L14120172-05 L14120172-06 L14120172-07 L14120172-08 L14120172-09 L14120172-10 WG503275-02 WG503275-03
010101010101010101010101
1 2 3 4Sample Number Dilution Tag1.001.001.001.001.001.001.001.001.001.001.001.00
1234
----
1,2-Dichloroethane-d4Dibromofluoromethane4-BromofluorobenzeneToluene-d8
8260Method:HPMS8Instrument Id:L14120172Login Number:
WaterMatrix:WG503275Workgroup (AAB#):
Underline = Result out of surrogate limits
93.1 96.2 89.9 88.491.0 95.9 89.4 89.191.2 94.9 90.8 91.190.9 95.4 90.9 90.691.9 95.3 90.9 90.191.2 95.4 90.0 89.391.9 96.1 84.3 88.890.8 96.3 85.8 87.993.6 96.8 89.2 89.590.3 95.2 89.8 89.591.5 93.9 92.1 89.892.3 96.3 84.0 88.7
70857585
----
120115120120
Surrogates Surrogate Limits
DL = surrogate diluted out
HPMS8CAL ID: -19-NOV-14
ND = surrogate not detected
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Page 46
12/04/2014 14:57Report generated3903663PDF File ID:
Microbac Laboratories Inc.
METHOD BLANK SUMMARY
Report Name: BLANK_SUMMARY
8M40150612/03/14 16:5612/03/14 16:56
WG503275WG503275-02HPMS8
Blank File ID:Prep Date:
Analyzed Date:
Work Group:Blank Sample ID:
Instrument ID:8260BMethod:
TMBAnalyst:
L14120172Login Number:
LCS 40MW5MSGW12214 40MW5MSDGW12214 40TB12214 40EQR12214 40FB12214 40MW5GW12214 40MW7GW12214 40DUPGW12214 40MW6GW12214 LFMW01GW12214
WG503275-03L14120172-07L14120172-08L14120172-01L14120172-03L14120172-04L14120172-05L14120172-02L14120172-06L14120172-09L14120172-10
8M4015078M4015088M4015098M4015108M4015118M4015128M4015138M4015148M4015158M4015168M401517
12/03/14 17:2612/03/14 17:5412/03/14 18:2312/03/14 18:5212/03/14 19:2112/03/14 19:5012/03/14 20:1912/03/14 20:4812/03/14 21:1612/03/14 21:4512/03/14 22:14
This Method Blank Applies To The Following Samples:
Client ID Lab Sample ID Lab File ID Time Analyzed TAG0101010101010101010101
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Page 47
Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLANK
PDF ID: 3903664
04-DEC-2014 14:57
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-d8
91.5
92.1
93.9
89.8
Surrogates % Recovery Surrogate Limits
70
75
85
85
-
-
-
-
120
120
115
120
Qualifier
PASS
PASS
PASS
PASS
Analytes Concentration Dilution Qualifier
2-Chloroethyl vinyl ether
Acetone
1
1
2.00
2.50
10.0
10.0
U
U
2.00
2.50
ND Analyte Not detected at or above reporting limit
* |Analyte concentration| > 1/2 RL
8M401506WG503275
Instrument ID:HPMS8File ID:
Prep Date:12/03/14 16:56Run Date:12/03/14 16:56Analyst:TMB
Workgroup (AAB#): ug/LUnits:8260BMethod:
WaterMatrix:
L14120172Login Number: WG503275-02Sample ID:
19-NOV-14Cal ID: HPMS8-Contract #:
5030B/5030C/503Prep Method:
LOD LOQ
LOD
LOQ
Method Detection Limit
Reporting/Practical Quantitation Limit
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Page 48
LCS - Modified 03/06/2008
12/04/2014 14:57Report generated:3903586PDF File ID:
LABORATORY CONTROL SAMPLE (LCS)Microbac Laboratories Inc.
8M401507WG503275
Instrument ID:HPMS8File ID:
Run Date:12/03/2014Run Time:17:26Analyst:TMB
Workgroup (AAB#): ug/LUnits:
5030B/5030C/503Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found LCS Limits Q% Rec
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-d8
92.3
84.0
96.3
88.7
Surrogates % Recovery Surrogate Limits
70
75
85
85
-
-
-
-
120
120
115
120
Qualifier
PASS
PASS
PASS
PASS
WG503275-03Sample ID:
19-NOV-14Cal ID: HPMS8-DOD4QC Key:
2-Chloroethyl vinyl ether
Acetone
45
40
20.0
20.0
23.5
20.4
117
102
-
-
160
140
8260BMethod:
* EXCEEDS %REC LIMIT
Lot#:STD67765
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Page 49
MS_MSD - Modified 03/06/2008
12/04/2014 14:57Report generated3903587PDF File ID:
Microbac Laboratories Inc.
MS/MSD REPORT
L14120172Loginnum:
WaterMatrix:
2-Chloroethyl vinyl ether
Acetone
AnalyteMS MSD
23.9 22.9
20.1 19.5
Found Found
U
U
20.0 20.0
20.0 20.0
120 114
100 97.4
4.37
3.03
MS MSDMS MSD
Spiked Spiked%Rec %Rec
58
40
-
-
160
140
20
30
%RPDParent%Rec
LimitsRPDLimit Q
Instrument ID:HPMS8Parent ID:L14120172-05Sample ID:Sample ID:
L14120172-07L14120172-08
MSMSD
Method:8260B
Units:ug/L
Contract #:Cal ID: HPMS8- 19-NOV-14 WG503275Worknum:
8M4015138M4015088M401509
File ID:File ID:
File ID:Dil:Dil:
11
Dil:1Prep Method:5030B/5030C/
5035A
* FAILS %REC LIMIT
# FAILS RPD LIMIT
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Page 50
ORGANIC INSTRUMENT CHECK
TUNE - Modified 03/06/2008
12/04/2014 14:57Report generated3903665PDF File ID:
Microbac Laboratories Inc.
HPMS8FJBWG501514
11/18/201418:538M401217
50.075.095.096.0173174175176177
95.095.095.095.017495.0174174176
15.030.01005.000
50.05.0095.05.00
40.060.01009.002.001009.001019.00
21.451.81006.450
72.87.5496.86.92
7468180353482622480
253681912245551698
PASSPASSPASSPASSPASSPASSPASSPASSPASS
TargetMass
Rel. toMass
LowerLimit%
UpperLimit%
Rel.Abn%
RawAbn
ResultPass/Fail
This check relates to the following samples:
WG501514-02WG501514-03WG501514-04WG501514-05WG501514-06WG501514-07WG501514-08WG501514-09WG501514-10WG501514-11WG501514-12
0101010101010101010101
STDSTDSTDSTDSTDSTDSTD-CCVSTDSTDSTDSSCV
Lab ID Client ID Tag
BFB
L14120172 Tune ID:Run Date:Run Time:File ID:
WG501514-01Login Number:Instrument:
Analyst:Workgroup:
19-NOV-14Cal ID: HPMS8-
11/18/2014 19:46
11/18/2014 20:15
11/18/2014 20:44
11/18/2014 21:13
11/18/2014 21:43
11/18/2014 22:13
11/18/2014 22:42
11/18/2014 23:11
11/18/2014 23:40
11/19/2014 00:08
11/19/2014 01:06
Q
T
Date Analyzed
* Sample past 12 hour tune limit
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Page 51
ORGANIC INSTRUMENT CHECK
TUNE - Modified 03/06/2008
12/04/2014 14:57Report generated3903665PDF File ID:
Microbac Laboratories Inc.
HPMS8TMBWG503066
12/03/201415:058M401502
50.075.095.096.0173174175176177
95.095.095.095.017495.0174174176
15.030.01005.000
50.05.0095.05.00
40.060.01009.002.001009.001019.00
21.053.61007.530
77.27.6497.36.77
6245159422974122400
229681755223441513
PASSPASSPASSPASSPASSPASSPASSPASSPASS
TargetMass
Rel. toMass
LowerLimit%
UpperLimit%
Rel.Abn%
RawAbn
ResultPass/Fail
This check relates to the following samples:
WG503066-02WG503275-02WG503275-03L14120172-07L14120172-08L14120172-01L14120172-03L14120172-04L14120172-05L14120172-02L14120172-06L14120172-09L14120172-10
01010101010101010101010101
CCVBLANKLCS40MW5MSGW1221440MW5MSDGW1221440TB1221440EQR1221440FB1221440MW5GW1221440MW7GW1221440DUPGW1221440MW6GW12214LFMW01GW12214
Lab ID Client ID Tag
BFB
L14120172 Tune ID:Run Date:Run Time:File ID:
WG503066-01Login Number:Instrument:
Analyst:Workgroup:
19-NOV-14Cal ID: HPMS8-
12/03/2014 15:58
12/03/2014 16:56
12/03/2014 17:26
12/03/2014 17:54
12/03/2014 18:23
12/03/2014 18:52
12/03/2014 19:21
12/03/2014 19:50
12/03/2014 20:19
12/03/2014 20:48
12/03/2014 21:16
12/03/2014 21:45
12/03/2014 22:14
Q
T
Date Analyzed
* Sample past 12 hour tune limit
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Page 52
Calibration Table ReportMethod: 8260WT.MTitle: Method 8260B/624 WTR-SOP:OVLMSV01 11-18-14 HPMS 8Last Calibration: Wed Nov 19 12:08:00 2014Curve: WG501514Calibration Files
0.3 0.4 1 2 5 20 50 100 200 3008M401219.D 8M401220.D 8M401221.D 8M401222.D 8M401223.D 8M401224.D 8M401225.D 8M401226.D 8M401227.D 8M401228.D
Compound Avg %RSD Linear Quad
I Fluorobenzene ISTDT Dichlorodifluoromethane 0.237 0.284 0.252 0.314 0.327 0.316 0.313 0.285 0.291 11.275P Chloromethane 0.392 0.370 0.311 0.334 0.347 0.336 0.329 0.300 0.340 8.811C Vinyl Chloride 0.297 0.261 0.283 0.244 0.268 0.276 0.260 0.253 0.229 0.263 7.824T 1,3-Butadiene 0.248 0.209 0.258 0.214 0.127 0.129 0.124 0.187 31.549 0.991
T Bromomethane 0.118 0.124 0.117 0.140 0.165 0.174 0.183 0.181 0.150 18.978 0.998
T Chloroethane 0.162 0.176 0.164 0.176 0.186 0.182 0.185 0.175 0.176 5.157T Trichlorofluoromethane 0.327 0.333 0.367 0.336 0.372 0.402 0.387 0.391 0.381 0.366 7.581T Diethyl ether 0.136 0.141 0.137 0.128 0.142 0.145 0.145 0.139 4.363T Isoprene 0.308 0.375 0.375 0.375 0.390 0.373 0.366 7.886T Acrolein 0.001 0.001 0.002 0.002 0.002 37.668T 1,1,2-Trichloro-1,2,2-Trifluoroethane 0.180 0.220 0.205 0.218 0.243 0.249 0.256 0.245 0.227 11.515T Acetone 0.034 0.033 0.037 0.037 0.038 0.037 0.036 5.884C 1,1-Dichloroethene 0.328 0.334 0.359 0.333 0.360 0.385 0.373 0.376 0.361 0.357 5.766T Tert-Butyl Alcohol 0.011 0.010 0.009 0.008 0.009 0.009 0.009 10.115T Dimethyl Sulfide 0.184 0.171 0.205 0.203 0.204 0.212 0.205 0.198 7.403T Iodomethane 0.048 0.120 0.153 0.155 0.167 0.154 0.133 33.528 0.998
T Methyl acetate 0.114 0.095 0.099 0.095 0.095 0.095 0.094 0.098 7.199T Methylene Chloride 0.229 0.241 0.218 0.223 0.241 0.237 0.236 0.225 0.231 3.798T Carbon Disulfide 0.706 0.765 0.696 0.846 0.839 0.795 0.782 0.700 0.766 7.896T Acrylonitrile 0.037 0.043 0.043 0.042 0.047 0.048 0.053 0.045 11.752T Methyl Tert Butyl Ether 0.499 0.506 0.431 0.442 0.477 0.479 0.487 0.461 0.473 5.605T trans-1,2-Dichloroethene 0.360 0.331 0.382 0.341 0.367 0.403 0.397 0.398 0.371 0.372 6.810T n-Hexane 0.366 0.437 0.421 0.402 0.400 0.382 0.401 6.428T Diisopropyl ether 0.851 0.854 0.830 0.761 0.813 0.782 0.724 0.802 6.066T Vinyl Acetate 0.312 0.340 0.344 0.345 0.333 0.325 0.333 3.850P 1,1-Dichloroethane 0.485 0.449 0.477 0.439 0.460 0.499 0.491 0.486 0.453 0.471 4.514T Ethyl-Tert-Butyl ether 0.719 0.725 0.697 0.639 0.685 0.665 0.624 0.679 5.666T 2-Butanone 0.051 0.054 0.056 0.055 0.057 0.054 0.055 3.407T Propionitrile 0.016 0.015 0.015 0.015 0.016 0.016 0.016 3.470T 2,2-Dichloropropane 0.423 0.415 0.418 0.379 0.393 0.422 0.421 0.416 0.386 0.408 4.187T cis-1,2-Dichloroethene 0.239 0.248 0.258 0.235 0.258 0.277 0.272 0.273 0.259 0.258 5.734C Chloroform 0.486 0.447 0.455 0.470 0.417 0.443 0.474 0.467 0.455 0.417 0.453 5.075T 1-Bromopropane 0.012 0.034 0.037 0.044 0.044 0.044 0.044 0.042 0.038 29.667 0.999
T Bromochloromethane 0.095 0.126 0.137 0.122 0.130 0.138 0.139 0.140 0.131 0.129 10.924T Tetrahydrofuran 0.039 0.038 0.034 0.031 0.033 0.033 0.034 0.035 8.416S Dibromofluoromethane 0.200 0.220 0.231 0.241 0.240 0.247 0.247 0.239 0.233 6.844T 1,1,1-Trichloroethane 0.446 0.390 0.428 0.383 0.404 0.437 0.431 0.429 0.397 0.416 5.471T Cyclohexane 0.448 0.502 0.454 0.532 0.524 0.505 0.513 0.481 0.495 6.276T 1,1-Dichloropropene 0.364 0.388 0.361 0.373 0.402 0.393 0.387 0.364 0.379 4.076T Tert-Amyl-Methyl ether 0.577 0.571 0.542 0.496 0.527 0.521 0.492 0.532 6.244T Carbon Tetrachloride 0.318 0.323 0.354 0.327 0.345 0.374 0.377 0.38 0.355 0.3505 6.80094S 1,2-Dichloroethane-d4 0.257 0.271 0.253 0.26 0.262 0.266 0.267 0.253 0.2613 2.62832T Heptane 0 0T 1,2-Dichloroethane 0.324 0.318 0.345 0.301 0.314 0.332 0.328 0.323 0.297 0.3205 4.645T Benzene 1.212 1.14 1.036 1.092 0.981 0.992 1.045 0.999 0.905 0.778 1.018 11.8999T Trichloroethene 0.222 0.234 0.25 0.23 0.24 0.258 0.255 0.258 0.246 0.2436 5.32919T Methylcyclohexane 0.414 0.494 0.48 0.46 0.46 0.434 0.4568 6.40441C 1,2-Dichloropropane 0.238 0.265 0.282 0.249 0.256 0.277 0.276 0.277 0.265 0.265 5.56586T Bromodichloromethane 0.324 0.322 0.332 0.295 0.321 0.349 0.347 0.345 0.323 0.3286 5.19377T 1,4-Dioxane 0.001 0.001 0.001 0.001 0.001 0.001 0.0009 15.6565 0.994
T Dibromomethane 0.089 0.114 0.122 0.106 0.114 0.123 0.123 0.125 0.118 0.1148 9.96736T 2-Chloroethyl Vinyl Ether 0.101 0.09 0.104 0.103 0.091 0.088 0.087 0.0949 7.94583T 4-Methyl-2-Pentanone 0.04 0.045 0.05 0.048 0.05 0.048 0.0468 8.52012T cis-1,3-Dichloropropene 0.381 0.38 0.4 0.346 0.373 0.401 0.394 0.388 0.36 0.3804 4.8369
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Page 53
T Dimethyl Disulfide 0.356 0.32 0.405 0.408 0.405 0.409 0.384 0.384 8.86103I Chlorobenzene-d5 ISTDS Toluene-d8 1.141 1.321 1.305 1.298 1.297 1.291 1.217 1.141 1.2514 5.97636C Toluene 1.684 1.514 1.606 1.463 1.493 1.572 1.448 1.262 1.047 1.4544 13.2692T Ethyl Methacrylate 0.311 0.314 0.284 0.336 0.329 0.325 0.317 0.3 0.3146 5.2992T Paraldehyde 0 0T trans-1,3-Dichloropropene 0.466 0.467 0.433 0.456 0.499 0.48 0.464 0.428 0.4615 5.00645T 1,1,2-Trichloroethane 0.172 0.217 0.245 0.206 0.215 0.234 0.222 0.221 0.21 0.2157 9.34583T 2-Hexanone 0.054 0.06 0.068 0.063 0.064 0.06 0.0613 7.25961T 1,3-Dichloropropane 0.411 0.416 0.457 0.405 0.403 0.431 0.414 0.403 0.377 0.413 5.29214T Tetrachloroethene 0.301 0.284 0.308 0.291 0.301 0.325 0.312 0.316 0.303 0.3045 4.0681T Dibromochloromethane 0.198 0.249 0.271 0.239 0.257 0.295 0.291 0.293 0.279 0.2636 11.9908T 1,2-Dibromoethane 0.218 0.205 0.227 0.209 0.214 0.235 0.226 0.224 0.213 0.2192 4.37399T 1-Chlorohexane 0.604 0.522 0.561 0.496 0.591 0.578 0.54 0.519 0.483 0.5439 7.81351P Chlorobenzene 1.04 0.951 1.017 0.926 0.957 1.021 0.974 0.899 0.773 0.9508 8.54628T 1,1,1,2-Tetrachloroethane 0.278 0.323 0.318 0.299 0.321 0.358 0.352 0.349 0.323 0.3246 7.92839C Ethylbenzene 0.555 0.528 0.593 0.537 0.55 0.6 0.591 0.581 0.525 0.5623 5.20373T m-,p-Xylene 0.693 0.644 0.686 0.624 0.648 0.698 0.661 0.581 0.479 0.6348 10.89T o-Xylene 0.621 0.65 0.596 0.63 0.684 0.664 0.646 0.594 0.6355 4.9616T Styrene 1.035 1.007 1.018 1.066 0.984 1.029 1.119 1.071 0.979 0.842 1.015 7.28557P Bromoform 0.111 0.131 0.125 0.139 0.167 0.168 0.172 0.168 0.1479 16.1456 0.999
T Isopropylbenzene 1.72 1.648 1.762 1.593 1.632 1.718 1.58 1.339 1.091 1.5648 13.8199I 1,4-Dichlorobenzene-d4 ISTDP 1,1,2,2-Tetrachloroethane 0.45 0.491 0.521 0.474 0.477 0.522 0.49 0.486 0.469 0.4868 4.78291S p-Bromofluorobenzene 1.091 1.077 1.132 1.089 1.054 1.051 1.028 1.01 1.0666 3.63654T 1,2,3-Trichloropropane 0.08 0.142 0.132 0.133 0.145 0.137 0.138 0.133 0.13 15.8307 0.999
T trans-1,4-Dichloro-2-Butene 0.111 0.133 0.133 0.179 0.152 0.157 0.155 0.169 0.1487 14.6669T n-Propylbenzene 4.701 4.133 4.525 4.171 4.275 4.299 3.819 3.05 4.1216 12.2903T Bromobenzene 0.786 0.755 0.756 0.846 0.755 0.771 0.81 0.78 0.773 0.744 0.7776 3.95372T 1,3,5-Trimethylbenzene 3.014 2.933 2.746 2.98 2.717 2.87 2.992 2.805 2.468 2.068 2.7592 10.6544T 2-Chlorotoluene 2.743 2.962 3.177 2.519 2.563 2.648 2.484 2.158 2.6568 11.7113T 4-Chlorotoluene 2.59 2.506 2.487 2.574 2.629 2.72 2.461 2.167 2.5167 6.53729T a-Methylstyrene 1.334 1.629 1.567 1.531 1.468 1.352 1.4803 7.99335T tert-Butylbenzene 0.517 0.601 0.546 0.581 0.612 0.611 0.621 0.605 0.5866 6.27242T 1,2,4-Trimethylbenzene 2.792 2.533 2.736 2.52 2.703 2.885 2.752 2.427 2.025 2.597 10.0178T sec-Butylbenzene 3.76 3.378 3.799 3.395 3.543 3.643 3.392 2.867 2.346 3.3472 13.9298T p-Isopropyltoluene 2.807 2.502 2.727 2.549 2.753 2.95 2.83 2.475 2.059 2.628 10.1658T 1,3-Dichlorobenzene 1.688 1.467 1.629 1.47 1.515 1.586 1.532 1.469 1.329 1.5206 6.937T 1,4-Dichlorobenzene 1.643 1.436 1.559 1.539 1.418 1.455 1.547 1.487 1.428 1.292 1.4805 6.57069T n-Butylbenzene 2.223 2.43 2.258 2.561 2.741 2.615 2.316 1.938 2.3853 10.7478T 1,2-Dichlorobenzene 1.329 1.321 1.314 1.375 1.245 1.281 1.355 1.305 1.267 1.169 1.2962 4.59392T 1,2-Dibromo-3-Chloropropane 0.071 0.078 0.08 0.091 0.086 0.089 0.085 0.0828 8.57009T 1,2,4-Trichlorobenzene 0.803 0.693 0.795 0.733 0.761 0.808 0.777 0.784 0.745 0.7667 4.89524T Hexachlorobutadiene 0.518 0.485 0.526 0.504 0.523 0.549 0.537 0.54 0.515 0.5218 3.73555T Naphthalene 1.33 1.241 1.301 1.106 1.044 1.031 0.951 0.924 1.1159 14.0454T 1,2,3-Trichlorobenzene 0.564 0.618 0.547 0.597 0.545 0.56 0.57 0.538 0.531 0.498 0.5572 6.08187
Wed Nov 19 12:17:29 2014
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Page 54
ALT - Modified 09/06/2007
12/04/2014 14:57Version 1.5Report generated
3903588PDF File ID:
ALTERNATE SOURCE CALIBRATION REPORTMicrobac Laboratories Inc.
CCC Calibration Check CompoundsSPCC System Performance Check Compounds
Chlorobenzene
Chloromethane
1,1,2,2-Tetrachloroethane
1,1-Dichloroethane
Bromoform
2-Chloroethyl Vinyl Ether
Acetone
SPCCSPCCSPCCSPCCSPCC
20.020.020.020.020.020.020.0
20.722.920.219.519.423.821.1
0.9840.3890.4920.4600.1590.1130.0380
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
3.5014.41.002.303.0019.25.70
Analyte Expected Found
* Exceeds
%D
Limit %D
RF
8M401230WG501514
Instrument ID:HPMS8File ID:
Run Date:11/19/2014Run Time:01:06Analyst:FJB
ICal Workgroup:
8260BMethod:L14120172Login Number: WG501514-12Sample ID:
19-NOV-14HPMS8 -Cal ID:
QUCL20
20
20
20
20
30
20
Units
QC Key:DOD4
Page 66
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Page 55
CCV - Modified 03/05/2008
12/04/2014 14:57Report generated3903589PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
CCC Calibration Check CompoundsSPCC System Performance Check Compounds
1,1-Dichloroethene
1,2-Dichloropropane
Chloroform
Ethylbenzene
Toluene
Vinyl Chloride
1,1,2,2-Tetrachloroethane
1,1-Dichloroethane
Bromoform
Chlorobenzene
Chloromethane
2-Chloroethyl Vinyl Ether
Acetone
CCCCCCCCCCCCCCCCCCSPCCSPCCSPCCSPCCSPCC
50.050.050.050.050.050.050.050.050.050.050.050.050.0
52.254.754.650.050.362.650.653.853.050.755.254.750.0
0.3720.2900.4950.5621.460.3300.4920.5070.1770.9640.3760.1040.0359
*
4.339.379.250.07220.53725.21.107.695.941.3410.59.470.0360
Analyte Expected Found Q
* Exceeds
%D
Criteria %D
RF
8M401504WG503275
Instrument ID:HPMS8File ID:
Run Date:12/03/2014Run Time:15:58Analyst:TMB
Workgroup (AAB#):
8260BMethod:L14120172Login Number: WG503066-02Sample ID:
19-NOV-14HPMS8 -Cal ID:
UNITS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
UCL20
20
20
20
20
20
20
20
20
20
20
40
20
DOD4QC Key:
WATERMatrix:
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Page 56
INTERNAL STANDARD AREA SUMMARY(COMPARED TO MIDPOINT OF ICAL)
INTERNAL_STD_ICAL - Modified 03/06/2008
12/04/2014 14:57Report generated3903666PDF File ID:
Microbac Laboratories Inc.
L14120172-01L14120172-02L14120172-03L14120172-04L14120172-05L14120172-06L14120172-07L14120172-08L14120172-09L14120172-10WG503275-02WG503275-03
010101010101010101010101
1 2 3
298530 639738 858256271161 586193 787841279523 603865 829586274052 596277 810763270192 589901 798744266906 579178 772738328850 655220 860783330184 663423 868814268890 580879 771173263789 570515 773416286593 624624 845713330257 660284 876342
193228 397868 585193WG501514-08386456 795736 117038696614 198934 292597
Upper LimitLower Limit
Sample Number Dilution Tag
1.001.001.001.001.001.001.001.001.001.001.001.00
NANANA
NANANA
123
---
1,4-Dichlorobenzene-d4Chlorobenzene-d5Fluorobenzene
WG501514-08ICAL CCV Number:HPMS8Instrument ID:L14120172Login Number:
WATERMatrix:WG503275Workgroup (AAB#):
Underline = Response outside limits
IS- IS- IS-
IS-IS-IS-
HPMS8CAL ID: -19-NOV-14
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Page 57
INTERNAL STANDARD RETENTION TIME SUMMARY(COMPARED TO MIDPOINT OF ICAL)
INTERNAL_STD_RT_ICAL - Modified 03/06/2008
12/04/2014 14:57Report generated:3903667PDF File ID:
Microbac Laboratories Inc.
L14120172-01L14120172-02L14120172-03L14120172-04L14120172-05L14120172-06L14120172-07L14120172-08L14120172-09L14120172-10WG503275-02WG503275-03
010101010101010101010101
1 2 3
17.73 14.7 10.8317.72 14.7 10.8417.73 14.7 10.8417.73 14.7 10.8417.73 14.7 10.8417.72 14.7 10.8417.73 14.7 10.8317.72 14.7 10.8417.73 14.7 10.8317.72 14.7 10.8417.73 14.7 10.8417.72 14.7 10.84
17.73 14.7 10.84WG501514-0818.23 15.2 11.3417.23 14.2 10.34
Upper LimitLower Limit
Sample Number Dilution Tag
1.001.001.001.001.001.001.001.001.001.001.001.00
NANANA
NANANA
123
---
1,4-Dichlorobenzene-d4Chlorobenzene-d5Fluorobenzene
WG501514-08ICAL CCV Number:HPMS8Instrument ID:L14120172Login Number:
WATERMatrix:WG503275Workgroup (AAB#):
Underline = Response outside limits
IS- IS- IS-
IS-IS-IS-
HPMS8CAL ID: -19-NOV-14
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Page 58
Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLANK
PDF ID: 3916581
12-DEC-2014 14:36
Analytes Concentration Dilution Qualifier
Perchlorate 10.100 0.200 U0.100
ND Analyte Not detected at or above reporting limit
* |Analyte concentration| > 1/2 RL
1LM.LM27905WG504286
Instrument ID:LCMS1File ID:
Prep Date:12/10/14 10:00Run Date:12/10/14 17:42Analyst:ADC
Workgroup (AAB#): ug/LUnits:6850Method:
WaterMatrix:
L14120172Login Number: WG504286-02Sample ID:
17-NOV-14Cal ID: LCMS1-Contract #:
6850Prep Method:
LOD LOQ
LOD
LOQ
Method Detection Limit
Reporting/Practical Quantitation Limit
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Page 59
LCS - Modified 03/06/2008
12/12/2014 14:36Report generated:3916582PDF File ID:
LABORATORY CONTROL SAMPLE (LCS)Microbac Laboratories Inc.
1LM.LM27906WG504286
Instrument ID:LCMS1File ID:
Run Date:12/10/2014Run Time:18:01Analyst:ADC
Workgroup (AAB#): ug/LUnits:
6850Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found LCS Limits Q% Rec
WG504286-03Sample ID:
17-NOV-14Cal ID: LCMS1-DOD4QC Key:
Perchlorate 800.200 0.215 108 - 120
6850Method:
Lot#:STD67080
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Page 60
MS_MSD - Modified 03/06/2008
12/12/2014 14:36Report generated3916583PDF File ID:
Microbac Laboratories Inc.
MS/MSD REPORT
L14120172Loginnum:
WaterMatrix:
Perchlorate
AnalyteMS MSD
1.05 1.09
Found Found
0.883 0.200 0.20083.5 104 3.74
MS MSDMS MSD
Spiked Spiked%Rec %Rec
80 - 120 15
%RPDParent%Rec
LimitsRPDLimit Q
Instrument ID:LCMS1Parent ID:L14120172-05Sample ID:Sample ID:
L14120172-07L14120172-08
MSMSD
Method:6850
Units:ug/L
Contract #:Cal ID: LCMS1- 17-NOV-14 WG504286Worknum:
1LM.LM279121LM.LM279171LM.LM27918
File ID:File ID:
File ID:Dil:Dil:
11
Dil:1Prep Method:6850
* FAILS %REC LIMIT
# FAILS RPD LIMIT
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INT_CAL - Modified 03/06/2008
12/12/2014 14:36Report generated3917574PDF File ID:
Microbac Laboratories Inc.
INITIAL CALIBRATION SUMMARY
Perchlorate
Analyte
10.9 1.00000
% RSD LINEAR (R) QUAD (R²)
1.387
AVG RF
6850Analytical Method:Instrument ID:LCMS1
Initial Calibration Date:17-NOV-14 14:53L14120172Login Number:
WG501146ICAL Workgroup: FColumn ID:
R = Correlation coefficient; 0.995 minimumR² = Coefficient of determination; 0.99 minimum
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INT_CAL - Modified 03/06/2008
12/12/2014 14:36Report generated3917574PDF File ID:
Microbac Laboratories Inc.
INITIAL CALIBRATION DATA
Perchlorate
AnalyteWG501146-02 WG501146-03 WG501146-04
0.100 0.200 0.500
CONC CONC CONC
11100.0000 17300.0000 44100.0000
RESP RESP RESP
6850Analytical Method:Instrument ID:LCMS1
Initial Calibration Date:17-NOV-14 14:53L14120172Login Number:
1.719 1.339 1.338
RF RF RF
FColumn ID:
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INT_CAL - Modified 03/06/2008
12/12/2014 14:36Report generated3917574PDF File ID:
Microbac Laboratories Inc.
INITIAL CALIBRATION DATA
Perchlorate
AnalyteWG501146-05 WG501146-06 WG501146-07
1.00 2.00 5.00
CONC CONC CONC
84400.0000 173000.000 420000.000
RESP RESP RESP
6850Analytical Method:Instrument ID:LCMS1
Initial Calibration Date:17-NOV-14 14:53L14120172Login Number:
1.290 1.337 1.337
RF RF RF
FColumn ID:
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INT_CAL - Modified 03/06/2008
12/12/2014 14:36Report generated3917574PDF File ID:
Microbac Laboratories Inc.
INITIAL CALIBRATION DATA
Perchlorate
AnalyteWG501146-08
10.0
CONC
841000.000
RESP
6850Analytical Method:Instrument ID:LCMS1
Initial Calibration Date:17-NOV-14 14:53L14120172Login Number:
1.347
RF
FColumn ID:
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Page 65
ALT - Modified 09/06/2007
12/12/2014 14:36Version 1.5Report generated
3916585PDF File ID:
ALTERNATE SOURCE CALIBRATION REPORTMicrobac Laboratories Inc.
Perchlorate 1.00 1.01 1.36ug/L 1.00Analyte Expected Found
* Exceeds
%D
Limit %D
RF
1LM.LM27611WG501146
Instrument ID:LCMS1File ID:
Run Date:11/17/2014Run Time:15:12Analyst:ADC
ICal Workgroup:
6850Method:L14120172Login Number: WG501146-09Sample ID:
17-NOV-14LCMS1 -Cal ID:
QUCL15
Units
QC Key:DOD4
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Page 66
CCB - Modified 03/05/2008
12/12/2014 14:36Report generated3916587PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Perchlorate 0.100 0.200 0.100
1LM.LM27901WG504286
Instrument ID:LCMS1File ID:
Run Date:12/10/2014Run Time:16:26Analyst:ADC
Workgroup (AAB#):ug/LUnits:6850Method:
L14120172Login Number: WG504287-01Sample ID:
U
U = Result is less than MDL.F = Result is between MDL and RL.
17-NOV-14LCMS1 -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
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CCB - Modified 03/05/2008
12/12/2014 14:36Report generated3916587PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Perchlorate 0.100 0.200 0.100
1LM.LM27916WG504286
Instrument ID:LCMS1File ID:
Run Date:12/10/2014Run Time:21:10Analyst:ADC
Workgroup (AAB#):ug/LUnits:6850Method:
L14120172Login Number: WG504287-04Sample ID:
U
U = Result is less than MDL.F = Result is between MDL and RL.
17-NOV-14LCMS1 -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
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Page 68
CCB - Modified 03/05/2008
12/12/2014 14:36Report generated3916587PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Perchlorate 0.100 0.200 0.100
1LM.LM27926WG504286
Instrument ID:LCMS1File ID:
Run Date:12/11/2014Run Time:00:20Analyst:ADC
Workgroup (AAB#):ug/LUnits:6850Method:
L14120172Login Number: WG504287-06Sample ID:
U
U = Result is less than MDL.F = Result is between MDL and RL.
17-NOV-14LCMS1 -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
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Page 69
CCB - Modified 03/05/2008
12/12/2014 14:36Report generated3916587PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Perchlorate 0.100 0.200 0.100
1LM.LM27933WG504286
Instrument ID:LCMS1File ID:
Run Date:12/11/2014Run Time:02:32Analyst:ADC
Workgroup (AAB#):ug/LUnits:6850Method:
L14120172Login Number: WG504287-08Sample ID:
U
U = Result is less than MDL.F = Result is between MDL and RL.
17-NOV-14LCMS1 -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
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Page 70
CCB - Modified 03/05/2008
12/12/2014 14:36Report generated3916587PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Perchlorate 0.100 0.200 0.100
1LM.LM27936WG504286
Instrument ID:LCMS1File ID:
Run Date:12/11/2014Run Time:09:48Analyst:ADC
Workgroup (AAB#):ug/LUnits:6850Method:
L14120172Login Number: WG504287-10Sample ID:
U
U = Result is less than MDL.F = Result is between MDL and RL.
17-NOV-14LCMS1 -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
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Page 71
CCB - Modified 03/05/2008
12/12/2014 14:36Report generated3916587PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Perchlorate 0.100 0.200 0.100
1LM.LM27942WG504286
Instrument ID:LCMS1File ID:
Run Date:12/11/2014Run Time:11:41Analyst:ADC
Workgroup (AAB#):ug/LUnits:6850Method:
L14120172Login Number: WG504287-12Sample ID:
U
U = Result is less than MDL.F = Result is between MDL and RL.
17-NOV-14LCMS1 -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
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Page 72
CCV - Modified 03/05/2008
12/12/2014 14:36Report generated3916586PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Perchlorate 1.00 1.05 1.42 5.00Analyte Expected Found Q
* Exceeds
%D
Criteria %D
RF
1LM.LM27902WG504286
Instrument ID:LCMS1File ID:
Run Date:12/10/2014Run Time:16:45Analyst:ADC
Workgroup (AAB#):
6850Method:L14120172Login Number: WG504287-02Sample ID:
17-NOV-14LCMS1 -Cal ID:
UNITS
ug/L
UCL15
DOD4QC Key:
WATERMatrix:
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Page 73
CCV - Modified 03/05/2008
12/12/2014 14:36Report generated3916586PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Perchlorate 1.00 1.02 1.38 2.00Analyte Expected Found Q
* Exceeds
%D
Criteria %D
RF
1LM.LM27914WG504286
Instrument ID:LCMS1File ID:
Run Date:12/10/2014Run Time:20:33Analyst:ADC
Workgroup (AAB#):
6850Method:L14120172Login Number: WG504287-03Sample ID:
17-NOV-14LCMS1 -Cal ID:
UNITS
ug/L
UCL15
DOD4QC Key:
WATERMatrix:
Page 206
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Page 74
CCV - Modified 03/05/2008
12/12/2014 14:36Report generated3916586PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Perchlorate 1.00 1.01 1.36 1.00Analyte Expected Found Q
* Exceeds
%D
Criteria %D
RF
1LM.LM27924WG504286
Instrument ID:LCMS1File ID:
Run Date:12/10/2014Run Time:23:42Analyst:ADC
Workgroup (AAB#):
6850Method:L14120172Login Number: WG504287-05Sample ID:
17-NOV-14LCMS1 -Cal ID:
UNITS
ug/L
UCL15
DOD4QC Key:
WATERMatrix:
Page 207
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Page 75
CCV - Modified 03/05/2008
12/12/2014 14:36Report generated3916586PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Perchlorate 1.00 1.02 1.38 2.00Analyte Expected Found Q
* Exceeds
%D
Criteria %D
RF
1LM.LM27931WG504286
Instrument ID:LCMS1File ID:
Run Date:12/11/2014Run Time:01:55Analyst:ADC
Workgroup (AAB#):
6850Method:L14120172Login Number: WG504287-07Sample ID:
17-NOV-14LCMS1 -Cal ID:
UNITS
ug/L
UCL15
DOD4QC Key:
WATERMatrix:
Page 208
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Page 76
CCV - Modified 03/05/2008
12/12/2014 14:36Report generated3916586PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Perchlorate 1.00 1.05 1.42 5.00Analyte Expected Found Q
* Exceeds
%D
Criteria %D
RF
1LM.LM27934WG504286
Instrument ID:LCMS1File ID:
Run Date:12/11/2014Run Time:09:10Analyst:ADC
Workgroup (AAB#):
6850Method:L14120172Login Number: WG504287-09Sample ID:
17-NOV-14LCMS1 -Cal ID:
UNITS
ug/L
UCL15
DOD4QC Key:
WATERMatrix:
Page 209
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Page 77
CCV - Modified 03/05/2008
12/12/2014 14:36Report generated3916586PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Perchlorate 1.00 1.00 1.36 0Analyte Expected Found Q
* Exceeds
%D
Criteria %D
RF
1LM.LM27940WG504286
Instrument ID:LCMS1File ID:
Run Date:12/11/2014Run Time:11:03Analyst:ADC
Workgroup (AAB#):
6850Method:L14120172Login Number: WG504287-11Sample ID:
17-NOV-14LCMS1 -Cal ID:
UNITS
ug/L
UCL15
DOD4QC Key:
WATERMatrix:
Page 210
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Page 78
QCMRL - Modified 03/06/2007
12/12/2014 14:36Report generated3916584PDF File ID:
Microbac Laboratories Inc.
QCMRL SAMPLE
1LM.LM27903WG504286
Instrument ID:LCMS1File ID:
Run Date:12/10/2014Run Time:17:04Analyst:ADC
Workgroup (AAB#): ug/LUnits:
6850Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found Limits Q% Rec
WG504286-07Sample ID:
17-NOV-14Cal ID: LCMS1-Contract #:
Perchlorate 700.200 0.210 105 - 130
6850Method:
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-46
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QCMRL - Modified 03/06/2007
12/12/2014 14:36Report generated3916584PDF File ID:
Microbac Laboratories Inc.
QCMRL SAMPLE
1LM.LM27915WG504286
Instrument ID:LCMS1File ID:
Run Date:12/10/2014Run Time:20:51Analyst:ADC
Workgroup (AAB#): ug/LUnits:
6850Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found Limits Q% Rec
WG504286-08Sample ID:
17-NOV-14Cal ID: LCMS1-Contract #:
Perchlorate 700.200 0.203 102 - 130
6850Method:
Page 212
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QCMRL - Modified 03/06/2007
12/12/2014 14:36Report generated3916584PDF File ID:
Microbac Laboratories Inc.
QCMRL SAMPLE
1LM.LM27925WG504286
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Run Date:12/11/2014Run Time:00:01Analyst:ADC
Workgroup (AAB#): ug/LUnits:
6850Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found Limits Q% Rec
WG504286-09Sample ID:
17-NOV-14Cal ID: LCMS1-Contract #:
Perchlorate 700.200 0.197 98.5 - 130
6850Method:
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QCMRL - Modified 03/06/2007
12/12/2014 14:36Report generated3916584PDF File ID:
Microbac Laboratories Inc.
QCMRL SAMPLE
1LM.LM27932WG504286
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Run Date:12/11/2014Run Time:02:13Analyst:ADC
Workgroup (AAB#): ug/LUnits:
6850Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found Limits Q% Rec
WG504286-10Sample ID:
17-NOV-14Cal ID: LCMS1-Contract #:
Perchlorate 700.200 0.191 95.5 - 130
6850Method:
Page 214
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QCMRL - Modified 03/06/2007
12/12/2014 14:36Report generated3916584PDF File ID:
Microbac Laboratories Inc.
QCMRL SAMPLE
1LM.LM27935WG504286
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Run Date:12/11/2014Run Time:09:29Analyst:ADC
Workgroup (AAB#): ug/LUnits:
6850Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found Limits Q% Rec
WG504286-11Sample ID:
17-NOV-14Cal ID: LCMS1-Contract #:
Perchlorate 700.200 0.193 96.5 - 130
6850Method:
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QCMRL - Modified 03/06/2007
12/12/2014 14:36Report generated3916584PDF File ID:
Microbac Laboratories Inc.
QCMRL SAMPLE
1LM.LM27941WG504286
Instrument ID:LCMS1File ID:
Run Date:12/11/2014Run Time:11:22Analyst:ADC
Workgroup (AAB#): ug/LUnits:
6850Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found Limits Q% Rec
WG504286-12Sample ID:
17-NOV-14Cal ID: LCMS1-Contract #:
Perchlorate 700.200 0.198 99.0 - 130
6850Method:
Page 216
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INTERNAL STANDARD AREA SUMMARY(COMPARED TO AVERAGE OF ICAL)
INTERNAL_STD_AVG_ICAL - Modified 03/10/2010
12/12/2014 14:36Report generated3916588PDF File ID:
Microbac Laboratories Inc.
L14120172-02L14120172-03L14120172-04L14120172-05L14120172-06L14120172-07L14120172-08L14120172-09L14120172-10WG504286-02WG504286-03
0101010101010101010101
1
317000356000358000353000358000364000349000349000355000347000346000
321000WG501146481500160500
Upper LimitLower Limit
Sample Number Dilution Tag
1.001.001.001.001.001.001.001.001.001.001.00
NANANA
NANANA
1 - O18LP
WG501146-05ICAL CCV Number:LCMS1Instrument ID:L14120172Login Number:
WATERMatrix:WG504286Workgroup (AAB#):
Underline = Response outside limits
IS-
IS-
LCMS1CAL ID: -17-NOV-14
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Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLANK
PDF ID: 3912480
11-DEC-2014 08:50
Analytes Concentration Dilution Qualifier
Aluminum, Total
Calcium, Total
Iron, Total
Magnesium, Total
Potassium, Total
Sodium, Total
Vanadium, Total
1
1
1
1
1
1
1
0.100
0.250
0.0500
0.250
0.500
0.250
0.00500
0.200
0.500
0.100
0.500
1.00
0.500
0.0100
U
U
U
U
U
U
U
0.100
0.250
0.0500
0.250
0.500
0.250
0.00500
ND Analyte Not detected at or above reporting limit
* |Analyte concentration| > 1/2 RL
P2.121014.142656WG504197
Instrument ID:PE-ICP2File ID:
Prep Date:12/10/14 09:19Run Date:12/10/14 14:26Analyst:KHR
Workgroup (AAB#): mg/LUnits:6010BMethod:
WaterMatrix:
L14120172Login Number: WG504169-02Sample ID:
10-DEC-14Cal ID:PE-ICP-Contract #:
3015Prep Method:
LOD LOQ
LOD
LOQ
Method Detection Limit
Reporting/Practical Quantitation Limit
Page 381
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Page 124
LCS - Modified 03/06/2008
12/11/2014 08:50Report generated:3912481PDF File ID:
LABORATORY CONTROL SAMPLE (LCS)Microbac Laboratories Inc.
P2.121014.143019WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:14:30Analyst:KHR
Workgroup (AAB#): mg/LUnits:
3015Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found LCS Limits Q% Rec
WG504169-03Sample ID:
10-DEC-14Cal ID:PE-ICP-DOD4QC Key:
Aluminum, Total
Calcium, Total
Iron, Total
Magnesium, Total
Potassium, Total
Sodium, Total
Vanadium, Total
80
80
80
80
80
80
80
6.25
6.25
2.50
6.25
31.3
31.3
0.625
6.17
6.26
2.56
6.38
29.5
29.5
0.637
98.7
100
103
102
94.3
94.3
102
-
-
-
-
-
-
-
120
120
120
120
120
120
120
6010BMethod:
Lot#:STD67718
Page 382
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Page 125
MS_MSD - Modified 03/06/2008
12/11/2014 12:43Report generated3912482PDF File ID:
Microbac Laboratories Inc.
MS/MSD REPORT
L14120172Loginnum:
WaterMatrix:
Aluminum, Total
Iron, Total
Magnesium, Total
Potassium, Total
Sodium, Total
Vanadium, Total
AnalyteMS MSD
6.17 6.26
2.57 2.60
19.1 19.4
30.0 30.8
35.6 36.6
0.626 0.631
Found Found
0.256
0.155
13.2
0.764
6.58
U
6.25 6.25
2.50 2.50
6.25 6.25
31.3 31.3
31.3 31.3
0.625 0.625
94.7 96.1
96.7 97.6
94.4 99.3
93.7 96.1
93 96.2
100 101
1.40
0.916
1.58
2.48
2.77
0.858
MS MSDMS MSD
Spiked Spiked%Rec %Rec
80
80
80
80
80
80
-
-
-
-
-
-
120
120
120
120
120
120
20
20
20
20
20
20
%RPDParent%Rec
LimitsRPDLimit Q
Instrument ID:PE-ICP2Parent ID:L14120172-05Sample ID:Sample ID:
L14120172-07L14120172-08
MSMSD
Method:6010B
Units:mg/L
Contract #:Cal ID: PE-ICP2- 10-DEC-14 WG504197Worknum:
P2.121014.144249P2.121014.150311P2.121014.150537
File ID:File ID:
File ID:Dil:Dil:
11
Dil:1Prep Method:3015
* FAILS %REC LIMIT
# FAILS RPD LIMIT
Page 383
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-93
Page 126
MS_MSD - Modified 03/06/2008
12/11/2014 12:43Report generated3912482PDF File ID:
Microbac Laboratories Inc.
MS/MSD REPORT
L14120172Loginnum:
WaterMatrix:
Calcium, Total
AnalyteMS MSD
50.0 51.3
Found Found
41.4 6.25 6.25138 159 2.54
MS MSDMS MSD
Spiked Spiked%Rec %Rec
80 - 120 20 *
%RPDParent%Rec
LimitsRPDLimit Q
Instrument ID:PE-ICP2Parent ID:L14120172-05Sample ID:Sample ID:
L14120172-07L14120172-08
MSMSD
Method:6010B
Units:mg/L
Contract #:Cal ID: PE-ICP2- 11-DEC-14 WG504197Worknum:
P2.121114.102740P2.121114.104008P2.121114.104330
File ID:File ID:
File ID:Dil:Dil:
1010
Dil:10Prep Method:3015
* FAILS %REC LIMIT
# FAILS RPD LIMIT
Page 384
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Page 127
Microbac Laboratories Inc.Serial Dilution Report
SERIAL_DIL - Modified 09/22/2008
PDF File ID:
12/11/2014 12:42
3912476
L14120172PE-ICP2WG504197-02 P2.121014.145157 5
WG5041976010Bmg/L
L14120172-06 P2.121014.144610 1
AluminumCalciumIronMagnesiumPotassiumSodiumVanadium
0.24032.80.1419.920.6545.08ND
X
XXFXU
ND32.9ND10.4ND5.55ND
0.32
4.85
9.18
Analyte Sample Qual Serial Dil % DiffU
U
UXU
Qual Q
U = Result is below MDL.F = Result is greater than or equal to MDL and less than the RL.X = Result is greater than or equal to RL and less thanE = %D exceeds control limit of 10% and initial sample result is greater
Login:Instrument:Serial Dil: File ID: Dil: Units:
Method:Worknum:
Sample: File ID: Dil:
than or equal to times the MDL.50
50 times the MDL.
Page 385
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-95
Page 128
Microbac Laboratories Inc.Serial Dilution Report
SERIAL_DIL - Modified 09/22/2008
PDF File ID:
12/11/2014 12:42
3912476
L14120172PE-ICP2WG504197-02 P2.121114.103647 50
WG5041976010Bmg/L
L14120172-06 P2.121114.103101 10
AluminumCalciumIronMagnesiumPotassiumSodiumVanadium
ND32.5ND10.5ND5.15ND
UXUXUXU
ND42.4ND10.4NDNDND
30.60
0.58
Analyte Sample Qual Serial Dil % DiffUXUFUUU
Qual Q
U = Result is below MDL.F = Result is greater than or equal to MDL and less than the RL.X = Result is greater than or equal to RL and less thanE = %D exceeds control limit of 10% and initial sample result is greater
Login:Instrument:Serial Dil: File ID: Dil: Units:
Method:Worknum:
Sample: File ID: Dil:
than or equal to times the MDL.50
50 times the MDL.
Page 386
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Page 129
POST SPIKE REPORT
POST_SPIKE - Modified 03/06/2008
12/11/2014 12:42Report generated:3912477PDF File ID:
Microbac Laboratories Inc.
L14120172Sample Login ID:Instrument ID:Post Spike ID:
PE-ICP2WG504197-01
Sample ID: L14120172-06P2.121014.144931P2.121014.144610
11
File ID:File ID:
Dil:Dil:
Worknum:Method:
WG5041976010B
Units: mg/LWaterMatrix:
N = % Recovery exceeds control limitsF = Result is between MDL and RLU = Sample result is below MDL. A value of zero is used in the calculation
0.24032.80.1419.920.6545.080
ALUMINUMCALCIUMIRONMAGNESIUMPOTASSIUMSODIUMVANADIUM
AnalyteSampleResult
F
U
C
5.1634.62.1613.924.128.00.500
Post SpikeResult C
55252525.5
SpikeAdded(SA)
98.9 100.8 101.7 99.8 94.1 93.8 100.0
% R
75 - 12575 - 12575 - 12575 - 12575 - 12575 - 12575 - 125
QControlLimit %R
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Page 130
POST SPIKE REPORT
POST_SPIKE - Modified 03/06/2008
12/11/2014 12:42Report generated:3912477PDF File ID:
Microbac Laboratories Inc.
L14120172Sample Login ID:Instrument ID:Post Spike ID:
PE-ICP2WG504197-01
Sample ID: L14120172-06P2.121114.103422P2.121114.103101
1010
File ID:File ID:
Dil:Dil:
Worknum:Method:
WG5041976010B
Units: mg/LWaterMatrix:
N = % Recovery exceeds control limitsF = Result is between MDL and RLU = Sample result is below MDL. A value of zero is used in the calculation
03.250
1.050
0.5150
ALUMINUMCALCIUMIRONMAGNESIUMPOTASSIUMSODIUMVANADIUM
AnalyteSampleResult
U
U
U
U
C
4.868.022.025.9624.524.50.476
Post SpikeResult C
55252525.5
SpikeAdded(SA)
97.3 95.4 101.2 98.3 97.9 95.8 95.3
% R
75 - 12575 - 12575 - 12575 - 12575 - 12575 - 12575 - 125
QControlLimit %R
Page 388
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Page 131
Initial Calibration Summary
INT_CAL_ICP - Modified 03/06/2008PDF File ID: 3912486
Report generated: 11-DEC-2014 12:43
Microbac Laboratories Inc.
WG504225
ALUMINUM
CALCIUM
IRON
MAGNESIUM
POTASSIUM
SODIUM
VANADIUM
WG504225-01 WG504225-02 WG504225-03 WG504225-04 WG504225-05
0 .1 .2 10 20
0 .2 10 20
0 .04 .08 4 8
0 .1 .2 10 20
0 .5 1 50 100
0 .5 1 50 100
0 .01 .02 1 2
Conc Conc Conc Conc Conc
132 334 478 32600 65200
24.3 12.3 1160 2350
6.15 67.0 136 8200 16600
13.4 102 197 11500 23500
475 742 1750 98800 192000
1410 4560 9770 569000 1080000
5270 1620 3420 207000 416000
INT INT INT INT INT
.999999
.999988
.999983
.999951
1
1
.999996
R
6010B
L14120172Login:
Analytical Method:
ICAL Worknum: 10-DEC-2014 08:18
PE-ICP2
WG504197Workgroup (AAB#):
Instrument ID:
Initial Calibration Date:
Q
INT = Instrument intensityR = Coefficient of correlationQ = Data Qualifier* = Out of Compliance; R < 0.995
NA NA
Page 389
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Page 132
Initial Calibration Summary
INT_CAL_ICP - Modified 03/06/2008PDF File ID: 3912486
Report generated: 11-DEC-2014 12:43
Microbac Laboratories Inc.
WG504449
ALUMINUM
CALCIUM
IRON
MAGNESIUM
POTASSIUM
SODIUM
VANADIUM
WG504449-01 WG504449-02 WG504449-03 WG504449-04 WG504449-05
0 .1 .2 10 20
0 .2 10 20
0 .04 .08 4 8
0 .1 .2 10 20
0 .5 1 50 100
0 .5 1 50 100
0 .01 .02 1 2
Conc Conc Conc Conc Conc
152 213 507 31000 61900
18.0 12.1 1090 2280
3.44 66.7 130 7870 15800
16.6 90.2 182 11100 22200
573 768 1610 94100 188000
1730 4570 9040 541000 1050000
5040 1450 3220 196000 397000
INT INT INT INT INT
1
.999782
.999996
.999999
1
1
.999988
R
6010B
L14120172Login:
Analytical Method:
ICAL Worknum: 11-DEC-2014 08:56
PE-ICP2
WG504197Workgroup (AAB#):
Instrument ID:
Initial Calibration Date:
Q
INT = Instrument intensityR = Coefficient of correlationQ = Data Qualifier* = Out of Compliance; R < 0.995
NA NA
Page 390
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Page 133
ICB - Modified 07/14/2009
12/11/2014 12:42Report generated3912488PDF File ID:
INITIAL CALIBRATION BLANK (ICB)Microbac Laboratories Inc.
P2.121014.082931WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:08:29Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504225-09Sample ID:
Cal ID: -
Analytes MDL RDL Concentration Qualifier
ALUMINUM
CALCIUM
IRON
MAGNESIUM
POTASSIUM
SODIUM
VANADIUM
.08
.2
.04
.2
.4
.2
.004
.16
.4
.08
.4
.8
.4
.008
.08
.2
.04
.2
.4
.2
.004
U
U
U
U
U
U
U
U = Result is less than 2 x MDL
F = Result is between MDL and 2 x MDL
* = Result is above 2 x MDL
PE-ICP2 10-DEC-14WATERMatrix:
Page 391
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Page 134
ICB - Modified 07/14/2009
12/11/2014 12:42Report generated3912488PDF File ID:
INITIAL CALIBRATION BLANK (ICB)Microbac Laboratories Inc.
P2.121114.090052WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/11/2014Run Time:09:00Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504449-07Sample ID:
Cal ID: -
Analytes MDL RDL Concentration Qualifier
ALUMINUM
CALCIUM
IRON
MAGNESIUM
POTASSIUM
SODIUM
VANADIUM
.08
.2
.04
.2
.4
.2
.004
.16
.4
.08
.4
.8
.4
.008
.08
.2
.04
.2
.4
.214
.004
U
U
U
U
U
F
U
U = Result is less than 2 x MDL
F = Result is between MDL and 2 x MDL
* = Result is above 2 x MDL
PE-ICP2 11-DEC-14WATERMatrix:
Page 392
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Page 135
CCB - Modified 03/05/2008
12/11/2014 12:42Report generated3912491PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
0.160
0.400
0.0800
0.400
0.800
0.400
0.00800
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
P2.121014.084003WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:08:40Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504225-13Sample ID:
U
U
U
U
U
U
U
U = Result is less than MDL.F = Result is between MDL and RL.
10-DEC-14PE-ICP -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 393
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Page 136
CCB - Modified 03/05/2008
12/11/2014 12:42Report generated3912491PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
0.160
0.400
0.0800
0.400
0.800
0.400
0.00800
0.0800
0.200
0.0400
0.200
0.400
0.217
0.00400
P2.121014.141536WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:14:15Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504225-33Sample ID:
U
U
U
U
U
F
U
U = Result is less than MDL.F = Result is between MDL and RL.
10-DEC-14PE-ICP -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 394
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Page 137
CCB - Modified 03/05/2008
12/11/2014 12:42Report generated3912491PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
0.160
0.400
0.0800
0.400
0.800
0.400
0.00800
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
P2.121014.145744WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:14:57Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504225-35Sample ID:
U
U
U
U
U
U
U
U = Result is less than MDL.F = Result is between MDL and RL.
10-DEC-14PE-ICP -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 395
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Page 138
CCB - Modified 03/05/2008
12/11/2014 12:42Report generated3912491PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
0.160
0.400
0.0800
0.400
0.800
0.400
0.00800
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
P2.121014.153830WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:15:38Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504225-37Sample ID:
U
U
U
U
U
U
U
U = Result is less than MDL.F = Result is between MDL and RL.
10-DEC-14PE-ICP -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 396
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Page 139
CCB - Modified 03/05/2008
12/11/2014 12:42Report generated3912491PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
0.160
0.400
0.0800
0.400
0.800
0.400
0.00800
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
P2.121014.231004WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:23:10Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504225-65Sample ID:
U
U
U
U
U
U
U
U = Result is less than MDL.F = Result is between MDL and RL.
10-DEC-14PE-ICP -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 397
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Page 140
CCB - Modified 03/05/2008
12/11/2014 12:42Report generated3912491PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
0.160
0.400
0.0800
0.400
0.800
0.400
0.00800
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
P2.121014.232927WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:23:29Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504225-68Sample ID:
U
U
U
U
U
U
U
U = Result is less than MDL.F = Result is between MDL and RL.
10-DEC-14PE-ICP -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 398
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Page 141
CCB - Modified 03/05/2008
12/11/2014 12:42Report generated3912491PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
0.160
0.400
0.0800
0.400
0.800
0.400
0.00800
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
P2.121114.091445WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/11/2014Run Time:09:14Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504449-12Sample ID:
U
U
U
U
U
U
U
U = Result is less than MDL.F = Result is between MDL and RL.
11-DEC-14PE-ICP -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 399
L14120172 / Revision: 0 / 1302 total pages Generated: 12/17/2014 09:08Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-109
Page 142
CCB - Modified 03/05/2008
12/11/2014 12:42Report generated3912491PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
0.160
0.400
0.0800
0.400
0.800
0.400
0.00800
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
P2.121114.095710WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/11/2014Run Time:09:57Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504449-14Sample ID:
U
U
U
U
U
U
U
U = Result is less than MDL.F = Result is between MDL and RL.
11-DEC-14PE-ICP -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 400
L14120172 / Revision: 0 / 1302 total pages Generated: 12/17/2014 09:08Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-110
Page 143
CCB - Modified 03/05/2008
12/11/2014 12:42Report generated3912491PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
0.160
0.400
0.0800
0.400
0.800
0.400
0.00800
0.0800
0.200
0.0400
0.200
0.400
0.200
0.00400
P2.121114.105601WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/11/2014Run Time:10:56Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504449-17Sample ID:
U
U
U
U
U
U
U
U = Result is less than MDL.F = Result is between MDL and RL.
11-DEC-14PE-ICP -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 401
L14120172 / Revision: 0 / 1302 total pages Generated: 12/17/2014 09:08Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-111
Page 144
ICV - Modified 03/06/2008
12/11/2014 12:43Report generated3912487PDF File ID:
INITIAL CALIBRATION VERIFICATION (ICV)(Alternate Source)
Microbac Laboratories Inc.
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
101041050501
10.210.24.099.9649.549.01.01
10210210299.699.198.1101
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Limit LIMITS
%REC
P2.121014.082706WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:08:27Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504225-08Sample ID:
10-DEC-14PE-ICP -Cal ID:DOD4QC Key:
Page 402
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Page 145
ICV - Modified 03/06/2008
12/11/2014 12:43Report generated3912487PDF File ID:
INITIAL CALIBRATION VERIFICATION (ICV)(Alternate Source)
Microbac Laboratories Inc.
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
101041050501
10.110.14.039.9150.950.51.01
10110110199.1102101101
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Limit LIMITS
%REC
P2.121114.085827WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/11/2014Run Time:08:58Analyst:KHR
Workgroup (AAB#):mg/LUnits:6010BMethod:
L14120172Login Number: WG504449-06Sample ID:
11-DEC-14PE-ICP -Cal ID:DOD4QC Key:
Page 403
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Page 146
CCV - Modified 03/05/2008
12/11/2014 12:43Report generated3912490PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
10.010.04.0010.050.050.01.00
10.110.14.0410.150.350.30.999
10110110110110110199.9
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
P2.121014.083736WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:08:37Analyst:KHR
Workgroup (AAB#):
6010BMethod:L14120172Login Number: WG504225-12Sample ID:
10-DEC-14PE-ICP -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
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Page 147
CCV - Modified 03/05/2008
12/11/2014 12:43Report generated3912490PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
10.010.04.0010.050.050.01.00
10.310.34.0710.251.551.61.01
103103102102103103101
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
P2.121014.141310WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:14:13Analyst:KHR
Workgroup (AAB#):
6010BMethod:L14120172Login Number: WG504225-32Sample ID:
10-DEC-14PE-ICP -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
Page 405
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Page 148
CCV - Modified 03/05/2008
12/11/2014 12:43Report generated3912490PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
10.010.04.0010.050.050.01.00
10.010.34.0310.149.249.11.01
10010310110198.498.2101
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
P2.121014.145518WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:14:55Analyst:KHR
Workgroup (AAB#):
6010BMethod:L14120172Login Number: WG504225-34Sample ID:
10-DEC-14PE-ICP -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
Page 406
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Page 149
CCV - Modified 03/05/2008
12/11/2014 12:43Report generated3912490PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
10.010.04.0010.050.050.01.00
10.210.34.0310.150.550.61.03
102103101101101101103
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
P2.121014.153604WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:15:36Analyst:KHR
Workgroup (AAB#):
6010BMethod:L14120172Login Number: WG504225-36Sample ID:
10-DEC-14PE-ICP -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
Page 407
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Page 150
CCV - Modified 03/05/2008
12/11/2014 12:43Report generated3912490PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
10.010.04.0010.050.050.01.00
10.010.24.1110.449.749.31.02
10010210310499.498.7102
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
P2.121014.230737WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:23:07Analyst:KHR
Workgroup (AAB#):
6010BMethod:L14120172Login Number: WG504225-64Sample ID:
10-DEC-14PE-ICP -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
Page 408
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Page 151
CCV - Modified 03/05/2008
12/11/2014 12:43Report generated3912490PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
10.010.04.0010.050.050.01.00
10.010.33.9710.050.550.31.00
10010399.3100101101100
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
P2.121014.232700WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/10/2014Run Time:23:27Analyst:KHR
Workgroup (AAB#):
6010BMethod:L14120172Login Number: WG504225-67Sample ID:
10-DEC-14PE-ICP -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
Page 409
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Page 152
CCV - Modified 03/05/2008
12/11/2014 12:43Report generated3912490PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
10.010.04.0010.050.050.01.00
10.29.874.0810.251.150.80.985
10298.710210210210298.5
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
P2.121114.091219WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/11/2014Run Time:09:12Analyst:KHR
Workgroup (AAB#):
6010BMethod:L14120172Login Number: WG504449-11Sample ID:
11-DEC-14PE-ICP -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
Page 410
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Page 153
CCV - Modified 03/05/2008
12/11/2014 12:43Report generated3912490PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
10.010.04.0010.050.050.01.00
10.410.44.1510.450.950.41.03
104104104104102101103
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
P2.121114.095444WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/11/2014Run Time:09:54Analyst:KHR
Workgroup (AAB#):
6010BMethod:L14120172Login Number: WG504449-13Sample ID:
11-DEC-14PE-ICP -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
Page 411
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Page 154
CCV - Modified 03/05/2008
12/11/2014 12:43Report generated3912490PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Aluminum
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
10.010.04.0010.050.050.01.00
10.210.34.0510.150.149.71.03
10210310110110099.5103
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
P2.121114.105335WG504197
Instrument ID:PE-ICP2File ID:
Run Date:12/11/2014Run Time:10:53Analyst:KHR
Workgroup (AAB#):
6010BMethod:L14120172Login Number: WG504449-16Sample ID:
11-DEC-14PE-ICP -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
Page 412
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Page 155
INTERFERENCE CHECK SAMPLES
ICS - Modified 03/06/2008
12/11/2014 12:42Report generated3912489PDF File ID:
Microbac Laboratories Inc.
Aluminum Calcium Iron Magnesium Potassium Sodium Vanadium
ANALYTE250 256287 28695.1 96.3246 248
0.0514 5.210.0481 5.06-0.00465 0.249
Found Found250 250250 250100 100250 250NS 5.00NS 5.00NS 0.250
True True Q%Recovery %Recovery100 102115 11495.1 96.398.4 99.2NS 104NS 101NS 99.6
L14120172Login number:Instrument ID:PE-ICP2 Method:6010B
WG504197Workgroup (AAB#):
WG504225-10WG504225-11
P2.121014.083251P2.121014.083513
File ID:File ID:
Units:mg/L
Sol. A Sol. AB
Sol. ASol. AB
::
NS = Not spiked * = Recovery of spiked element is outside acceptance limit of 80% - 120% of true value. # = Result for unspiked element is outside the acceptance limits of (+/-) the project reporting limit (RL). + = Result for unspiked element is outside the acceptance limits of (+/-) 2 times the project method detection limit (MDL). This criteria is only applicable to specific QAPPs.
Matrix:Water
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Page 156
INTERFERENCE CHECK SAMPLES
ICS - Modified 03/06/2008
12/11/2014 12:42Report generated3912489PDF File ID:
Microbac Laboratories Inc.
Aluminum Calcium Iron Magnesium Potassium Sodium Vanadium
ANALYTE243 250280 27395.8 95.3247 246
0.0271 5.100.0442 4.87-0.00229 0.246
Found Found250 250250 250100 100250 250NS 5.00NS 5.00NS 0.250
True True Q%Recovery %Recovery97.2 100112 10995.8 95.398.8 98.4NS 102NS 97.4NS 98.4
L14120172Login number:Instrument ID:PE-ICP2 Method:6010B
WG504197Workgroup (AAB#):
WG504449-09WG504449-10
P2.121114.090734P2.121114.090956
File ID:File ID:
Units:mg/L
Sol. A Sol. AB
Sol. ASol. AB
::
NS = Not spiked * = Recovery of spiked element is outside acceptance limit of 80% - 120% of true value. # = Result for unspiked element is outside the acceptance limits of (+/-) the project reporting limit (RL). + = Result for unspiked element is outside the acceptance limits of (+/-) 2 times the project method detection limit (MDL). This criteria is only applicable to specific QAPPs.
Matrix:Water
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Page 157
KEMRON FORMS - Modified 08/28/2006
12/11/2014 08:51Version 1.5Report generated
3912485PDF File ID:
LRC SAMPLE
Analytes Expected Found Limits Q% Rec
Calcium, Total
Magnesium, Total
90
90
900
900
*1020
919
113
102
-
-
110
110
WG504197
Instrument ID:PE-ICP2Run Date:12/10/2014Run Time:08:18Analyst:KHR
Workgroup (AAB#): mg/LUnits:
3015Prep Method:
WaterMatrix:
L14120172Login Number: WG504225Sample ID:
10-DEC-2014 08:18Cal ID: 10-DEC-14-
6010BMethod:
Page 415
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Page 158
CORR_FACTORS - Modified 03/05/2008
12/11/2014 12:42Report generated:3912484PDF File ID:
INTERELEMENT CORRECTION FACTORS (ANNUALLY)Microbac Laboratories Inc.
ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM BORON CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD LITHIUM MAGNESIUM MANGANESE MOLYBDENUM NICKEL POTASSIUM SELENIUM SILICON SILVER SODIUM STRONTIUM THALLIUM TIN TITANIUM VANADIUM ZINC
Analyte
396.15 206.84 188.98 233.53 234.86 249.68 228.80 227.55 267.72 228.62 327.39 239.56 220.35 670.78 279.08 257.61 202.03 231.60 766.49 196.03 251.61 328.07 589.59 407.77 190.80 189.93 334.94 290.88 206.20
WaveLength
0 0 0.206 0 00 0 -0.740 0 00 0.0753 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 5.00 0 00 -0.158 10.0 0 00 -0.0395 0 0 00 0 0 0 0.3370 0 0 0 00 0 0 0 00 -0.153 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 -0.00743 0 0 00 0 0 0 00 0 0 0 00 0 0 0 0
0.200 0 0 0 00 -0.0270 0 0 00 0 0 0 00 0 0 0 00 0 0.200 0 0.04000 0 0 0 0
AG AL AS B BA
Insturment ID:Date:
Method:PE-ICP201/02/20146010B
Login Number:L14120172
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Page 159
CORR_FACTORS - Modified 03/05/2008
12/11/2014 12:42Report generated:3912484PDF File ID:
INTERELEMENT CORRECTION FACTORS (ANNUALLY)Microbac Laboratories Inc.
ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM BORON CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD LITHIUM MAGNESIUM MANGANESE MOLYBDENUM NICKEL POTASSIUM SELENIUM SILICON SILVER SODIUM STRONTIUM THALLIUM TIN TITANIUM VANADIUM ZINC
Analyte
396.15 206.84 188.98 233.53 234.86 249.68 228.80 227.55 267.72 228.62 327.39 239.56 220.35 670.78 279.08 257.61 202.03 231.60 766.49 196.03 251.61 328.07 589.59 407.77 190.80 189.93 334.94 290.88 206.20
WaveLength
0 0 0 0 00 0 0 0.730 8.460 -0.0220 0 0 -0.4900 0 0 -0.192 00 0 0 0 -0.02200 0 24.1 5.90 1.500 0 0 -3.64 00 0 0 180 00 0 0 0 00 0 0 0 -0.2000 0 0 0.280 -0.04000 0 0 2.77 00 0 0 0.462 0.05500 0 0 0 00 0 0 0 00 0 0 0 -0.1100 0 0 0 00 0 0 1.05 00 0 0 0 00 0 0 -0.250 00 0 0 0 00 0 0 0 00 0 0 0 00 0.0319 0 0 00 0 0 1.00 00 0 0 0 00 -0.150 0 0 0.2970 0 0 0 00 0 0 0 -8.16
BE CA CD CO CR
Insturment ID:Date:
Method:PE-ICP201/02/20146010B
Login Number:L14120172
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Page 160
CORR_FACTORS - Modified 03/05/2008
12/11/2014 12:42Report generated:3912484PDF File ID:
INTERELEMENT CORRECTION FACTORS (ANNUALLY)Microbac Laboratories Inc.
ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM BORON CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD LITHIUM MAGNESIUM MANGANESE MOLYBDENUM NICKEL POTASSIUM SELENIUM SILICON SILVER SODIUM STRONTIUM THALLIUM TIN TITANIUM VANADIUM ZINC
Analyte
396.15 206.84 188.98 233.53 234.86 249.68 228.80 227.55 267.72 228.62 327.39 239.56 220.35 670.78 279.08 257.61 202.03 231.60 766.49 196.03 251.61 328.07 589.59 407.77 190.80 189.93 334.94 290.88 206.20
WaveLength
0 -0.119 0 0 00 -0.0367 0 0 00 -0.234 0 0 00 0.0503 0 0 00 0.250 0 0 00 0.430 0 0 00 0.00198 0 0 00 -24.0 0 0 0.1040 0.119 0 0 00 0.0262 0 0 00 -0.0650 0 0.154 00 0 0 0 0.02000 0.0327 0 0 00 0 0 0 00 0.540 0 0 00 -0.0564 0 0 00 -0.0156 0 0 00 0 0 0 00 0 0 0 00 -0.200 0 0 00 0 0 0 0
0.0710 -0.464 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0.0955 0 0 0.0260
-0.200 0.00500 0 0 0
CU FE K LI MG
Insturment ID:Date:
Method:PE-ICP201/02/20146010B
Login Number:L14120172
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Page 161
CORR_FACTORS - Modified 03/05/2008
12/11/2014 12:42Report generated:3912484PDF File ID:
INTERELEMENT CORRECTION FACTORS (ANNUALLY)Microbac Laboratories Inc.
ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM BORON CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD LITHIUM MAGNESIUM MANGANESE MOLYBDENUM NICKEL POTASSIUM SELENIUM SILICON SILVER SODIUM STRONTIUM THALLIUM TIN TITANIUM VANADIUM ZINC
Analyte
396.15 206.84 188.98 233.53 234.86 249.68 228.80 227.55 267.72 228.62 327.39 239.56 220.35 670.78 279.08 257.61 202.03 231.60 766.49 196.03 251.61 328.07 589.59 407.77 190.80 189.93 334.94 290.88 206.20
WaveLength
0 69.0 0 0 00 -1.46 0 -0.745 00 5.34 0 0 00 -0.750 0 0 0
-0.100 -0.376 0 -0.00970 00 -1.00 0 0 00 0.0420 0 -0.0400 00 10.6 0 -831 00 0.170 0 0 00 -1.80 0 0.129 00 -0.0774 0 0.151 00 0 0 0 0
0.600 -0.500 0 -0.190 00 0 0 0 00 -18.0 0 0 00 -0.197 0 0 0.600
-0.209 0 0 0 00 -1.80 0 0 00 0 1.00 0 0
0.300 0 0 -0.376 00 11.1 0 0 0
0.130 0 0 0 00 0 0 0 00 0 0 0 0
1.00 -0.120 0 0 00 0 0 0 00 0 0 0 00 0.178 0 0 00 0 0 -0.200 -0.100
MN MO NA NI PB
Insturment ID:Date:
Method:PE-ICP201/02/20146010B
Login Number:L14120172
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Page 162
CORR_FACTORS - Modified 03/05/2008
12/11/2014 12:42Report generated:3912484PDF File ID:
INTERELEMENT CORRECTION FACTORS (ANNUALLY)Microbac Laboratories Inc.
ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM BORON CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD LITHIUM MAGNESIUM MANGANESE MOLYBDENUM NICKEL POTASSIUM SELENIUM SILICON SILVER SODIUM STRONTIUM THALLIUM TIN TITANIUM VANADIUM ZINC
Analyte
396.15 206.84 188.98 233.53 234.86 249.68 228.80 227.55 267.72 228.62 327.39 239.56 220.35 670.78 279.08 257.61 202.03 231.60 766.49 196.03 251.61 328.07 589.59 407.77 190.80 189.93 334.94 290.88 206.20
WaveLength
0 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0.0700 0 0 00 0 0 0 0
-0.0100 0 0 0 00 0 0 0 00 0 0 0 00 0.300 0 0 00 0 0 0 0
-0.0500 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 0.2000 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 00 0 0 0 0
-0.300 0 0 0 0
SB SE SI SN SR
Insturment ID:Date:
Method:PE-ICP201/02/20146010B
Login Number:L14120172
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Page 163
CORR_FACTORS - Modified 03/05/2008
12/11/2014 12:42Report generated:3912484PDF File ID:
INTERELEMENT CORRECTION FACTORS (ANNUALLY)Microbac Laboratories Inc.
ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM BORON CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD LITHIUM MAGNESIUM MANGANESE MOLYBDENUM NICKEL POTASSIUM SELENIUM SILICON SILVER SODIUM STRONTIUM THALLIUM TIN TITANIUM VANADIUM ZINC
Analyte
396.15 206.84 188.98 233.53 234.86 249.68 228.80 227.55 267.72 228.62 327.39 239.56 220.35 670.78 279.08 257.61 202.03 231.60 766.49 196.03 251.61 328.07 589.59 407.77 190.80 189.93 334.94 290.88 206.20
WaveLength
0 0 0 00 0 -0.920 00 0 0.0990 00 0 0.360 00 0 0 00 0 0 00 0 0.0800 0
3.00 0 0 00 0 -0.567 -0.0400
2.21 0 0 0-1.05 0 -0.440 -0.0600
0 0 0 00 0 -0.224 00 0 0 00 0 0 00 0 -0.200 -0.05500 0 -0.480 00 0.400 0 00 0 0 0
-0.220 0 -0.100 00 0 0 00 0 -2.05 00 0 0 00 0 0 0
-12.0 0 -2.76 00 0 0 00 0 0 00 0 0 00 0 -0.100 0
TI TL V ZN
Insturment ID:Date:
Method:PE-ICP201/02/20146010B
Login Number:L14120172
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Page 164
LINEAR_RANGE - Modified 03/06/2008
12/11/2014 12:42Report generated:3912483PDF File ID:
LINEAR RANGE (QUARTERLY)Microbac Laboratories Inc.
Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Lithium Magnesium Manganese Molybdenum Nickel Phosphorus Potassium Selenium Silicon Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc
Analyte
10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00
Integration Time(Sec.)
630.0 45.0 90.0 72.0 4.5 45.0 4.5 810.0 45.0 45.0 90.0 900.0 162.0 0.9 810.0 18.0 45.0 90.0 72.0 90.0 45.0 22.5 4.5 180.0 4.5 9.0 45.0 18.0 90.0 45.0
Concentration
Insturment ID:Date:
Method:PE-ICP210/23/20146010B
Comments:All analytes passed acceptance criteria at the specified concentration.
(mg/L)
Login Number:L14120172
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Page 165
Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLANK
PDF ID: 3914979
15-DEC-2014 14:09
Analytes Concentration Dilution Qualifier
Arsenic, Total
Barium, Total
Cobalt, Total
Lead, Total
Manganese, Total
Selenium, Total
1
1
1
1
1
1
0.000500
0.00150
0.000500
0.000500
0.00100
0.000500
0.00100
0.00300
0.00100
0.00100
0.00200
0.00100
U
U
U
U
U
U
0.000500
0.00150
0.000500
0.000500
0.00100
0.000500
ND Analyte Not detected at or above reporting limit
* |Analyte concentration| > 1/2 RL
NI.121514.124417WG504176
Instrument ID:ICP-MS2File ID:
Prep Date:12/10/14 07:25Run Date:12/15/14 12:44Analyst:JYH
Workgroup (AAB#): mg/LUnits:6020Method:
WaterMatrix:
L14120172Login Number: WG504133-03Sample ID:
15-DEC-14Cal ID:ICP-MS-Contract #:
3015Prep Method:
LOD LOQ
LOD
LOQ
Method Detection Limit
Reporting/Practical Quantitation Limit
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Page 166
LCS - Modified 03/06/2008
12/15/2014 14:09Report generated:3914980PDF File ID:
LABORATORY CONTROL SAMPLE (LCS)Microbac Laboratories Inc.
NI.121514.124725WG504176
Instrument ID:ICP-MS2File ID:
Run Date:12/15/2014Run Time:12:47Analyst:JYH
Workgroup (AAB#): mg/LUnits:
3015Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found LCS Limits Q% Rec
WG504133-04Sample ID:
15-DEC-14Cal ID:ICP-MS-DOD4QC Key:
Arsenic, Total
Barium, Total
Cobalt, Total
Lead, Total
Manganese, Total
Selenium, Total
80
80
80
80
80
80
0.0625
0.0625
0.0625
0.0625
0.0625
0.0625
0.0680
0.0663
0.0673
0.0685
0.0682
0.0690
109
106
108
110
109
110
-
-
-
-
-
-
120
120
120
120
120
120
6020Method:
Lot#:STD65967
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Page 167
MS_MSD - Modified 03/06/2008
12/15/2014 14:09Report generated3915559PDF File ID:
Microbac Laboratories Inc.
MS/MSD REPORT
L14120172Loginnum:
WaterMatrix:
Arsenic, Total
Barium, Total
Cobalt, Total
Lead, Total
Manganese, Total
Selenium, Total
AnalyteMS MSD
0.0666 0.0669
0.0897 0.101
0.0646 0.0657
0.0662 0.0658
0.0650 0.0661
0.0675 0.0680
Found Found
U
0.0240
U
U
U
U
0.0625 0.0625
0.0625 0.0625
0.0625 0.0625
0.0625 0.0625
0.0625 0.0625
0.0625 0.0625
107 107
105 123
103 105
106 105
104 106
108 109
0.363
11.4
1.71
0.625
1.71
0.693
MS MSDMS MSD
Spiked Spiked%Rec %Rec
80
80
80
80
80
80
-
-
-
-
-
-
120
120
120
120
120
120
20
20
20
20
20
20
*
%RPDParent%Rec
LimitsRPDLimit Q
Instrument ID:ICP-MS2Parent ID:L14120172-05Sample ID:Sample ID:
L14120172-07L14120172-08
MSMSD
Method:6020
Units:mg/L
Contract #:Cal ID: ICP-MS2- 15-DEC-14 WG504176Worknum:
NI.121514.125033NI.121514.125341NI.121514.125649
File ID:File ID:
File ID:Dil:Dil:
11
Dil:1Prep Method:3015
* FAILS %REC LIMIT
# FAILS RPD LIMIT
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Page 168
Microbac Laboratories Inc.Serial Dilution Report
SERIAL_DIL - Modified 09/22/2008
PDF File ID:
12/15/2014 14:14
3914973
L14120172ICP-MS2WG504176-06 NI.121514.130921 5
WG5041766020ug/L
L14120172-03 NI.121514.130305 1
ArsenicBariumCobaltLeadManganeseSelenium
NDNDNDNDNDND
UUUUUU
NDNDNDNDNDND
Analyte Sample Qual Serial Dil % DiffUUUUUU
Qual Q
U = Result is below MDL.F = Result is greater than or equal to MDL and less than the RL.X = Result is greater than or equal to RL and less thanE = %D exceeds control limit of 10% and initial sample result is greater
Login:Instrument:Serial Dil: File ID: Dil: Units:
Method:Worknum:
Sample: File ID: Dil:
than or equal to times the MDL.100
100 times the MDL.
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Page 169
POST SPIKE REPORT
POST_SPIKE - Modified 03/06/2008
12/15/2014 14:14Report generated:3914974PDF File ID:
Microbac Laboratories Inc.
L14120172Sample Login ID:Instrument ID:Post Spike ID:
ICP-MS2WG504176-05
Sample ID: L14120172-03NI.121514.130613NI.121514.130305
11
File ID:File ID:
Dil:Dil:
Worknum:Method:
WG5041766020
Units: ug/LWaterMatrix:
N = % Recovery exceeds control limitsF = Result is between MDL and RLU = Sample result is below MDL. A value of zero is used in the calculation
000000
ARSENICBARIUMCOBALTLEADMANGANESESELENIUM
AnalyteSampleResult
UUUUUU
C
53.352.753.553.254.053.4
Post SpikeResult C
505050505050
SpikeAdded(SA)
106.6 105.4 107.1 106.4 107.9 106.9
% R
75 - 12575 - 12575 - 12575 - 12575 - 12575 - 125
QControlLimit %R
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Page 170
Initial Calibration Summary
INT_CAL_ICP - Modified 03/06/2008PDF File ID: 3914986
Report generated: 15-DEC-2014 14:09
Microbac Laboratories Inc.
WG504857
ARSENIC
BARIUM
COBALT
LEAD
MANGANESE
SELENIUM
WG504857-01 WG504857-02 WG504857-03 WG504857-04
0 .4 50 100
0 .4 50 100
0 .4 50 100
0 .4 50 100
0 .4 50 100
0 .4 50 100
Conc Conc Conc Conc
-136 -31.6 75200 147000
66.3 230 108000 210000
149 699 486000 941000
852 2670 639000 1240000
2590 6120 654000 1250000
27.8 47.9 7360 14300
INT INT INT INT
.999998
.999993
.999998
1
.999988
.999998
R
6020
L14120172Login:
Analytical Method:
ICAL Worknum: 15-DEC-2014 12:19
ICP-MS2
WG504176Workgroup (AAB#):
Instrument ID:
Initial Calibration Date:
Q
INT = Instrument intensityR = Coefficient of correlationQ = Data Qualifier* = Out of Compliance; R < 0.995
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Page 171
ICB - Modified 07/14/2009
12/15/2014 14:09Report generated3914988PDF File ID:
INITIAL CALIBRATION BLANK (ICB)Microbac Laboratories Inc.
NI.121514.122521WG504176
Instrument ID:ICP-MS2File ID:
Run Date:12/15/2014Run Time:12:25Analyst:JYH
Workgroup (AAB#):ug/LUnits:6020Method:
L14120172Login Number: WG504857-06Sample ID:
Cal ID: -
Analytes MDL RDL Concentration Qualifier
ARSENIC
BARIUM
COBALT
MANGANESE
LEAD
SELENIUM
.2
.6
.2
.4
.2
.2
.4
1.2
.4
.8
.4
.4
.2
.6
.2
.4
.2
.2
U
U
U
U
U
U
U = Result is less than 2 x MDL
F = Result is between MDL and 2 x MDL
* = Result is above 2 x MDL
ICP-MS2 15-DEC-14WATERMatrix:
Page 870
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Page 172
CCB - Modified 03/05/2008
12/15/2014 14:09Report generated3914991PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Arsenic
Barium
Cobalt
Lead
Manganese
Selenium
0.200
0.600
0.200
0.200
0.400
0.200
0.400
1.20
0.400
0.400
0.800
0.400
0.200
0.600
0.200
0.200
0.400
0.200
NI.121514.124106WG504176
Instrument ID:ICP-MS2File ID:
Run Date:12/15/2014Run Time:12:41Analyst:JYH
Workgroup (AAB#):ug/LUnits:6020Method:
L14120172Login Number: WG504857-11Sample ID:
U
U
U
U
U
U
U = Result is less than MDL.F = Result is between MDL and RL.
15-DEC-14ICP-MS -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 871
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Page 173
CCB - Modified 03/05/2008
12/15/2014 14:09Report generated3914991PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Arsenic
Barium
Cobalt
Lead
Manganese
Selenium
0.200
0.600
0.200
0.200
0.400
0.200
0.400
1.20
0.400
0.400
0.800
0.400
0.200
0.600
0.200
0.200
0.400
0.200
NI.121514.131848WG504176
Instrument ID:ICP-MS2File ID:
Run Date:12/15/2014Run Time:13:18Analyst:JYH
Workgroup (AAB#):ug/LUnits:6020Method:
L14120172Login Number: WG504857-13Sample ID:
U
U
U
U
U
U
U = Result is less than MDL.F = Result is between MDL and RL.
15-DEC-14ICP-MS -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 872
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Page 174
CCB - Modified 03/05/2008
12/15/2014 14:09Report generated3914991PDF File ID:
CONTINUING CALIBRATION BLANK (CCB)Microbac Laboratories Inc.
Analytes MDL RDL Concentration Qualifier
Arsenic
Barium
Cobalt
Lead
Manganese
Selenium
0.200
0.600
0.200
0.200
0.400
0.200
0.400
1.20
0.400
0.400
0.800
0.400
0.200
0.600
0.200
0.200
0.400
0.200
NI.121514.133740WG504176
Instrument ID:ICP-MS2File ID:
Run Date:12/15/2014Run Time:13:37Analyst:JYH
Workgroup (AAB#):ug/LUnits:6020Method:
L14120172Login Number: WG504857-15Sample ID:
U
U
U
U
U
U
U = Result is less than MDL.F = Result is between MDL and RL.
15-DEC-14ICP-MS -Cal ID:
* = Result is above RL.
WATERMatrix: QAPP:DOD4
Page 873
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Page 175
ICV - Modified 03/06/2008
12/15/2014 14:09Report generated3914987PDF File ID:
INITIAL CALIBRATION VERIFICATION (ICV)(Alternate Source)
Microbac Laboratories Inc.
Arsenic
Barium
Cobalt
Lead
Manganese
Selenium
505050505050
50.450.450.750.250.251.6
101101101100100103
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Limit LIMITS
%REC
NI.121514.122211WG504176
Instrument ID:ICP-MS2File ID:
Run Date:12/15/2014Run Time:12:22Analyst:JYH
Workgroup (AAB#):ug/LUnits:6020Method:
L14120172Login Number: WG504857-05Sample ID:
15-DEC-14ICP-MS -Cal ID:DOD4QC Key:
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Page 176
CCV - Modified 03/05/2008
12/15/2014 14:09Report generated3914990PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Arsenic
Barium
Cobalt
Lead
Manganese
Selenium
0.05000.05000.05000.05000.05000.0500
0.05010.04970.04910.05020.04920.0511
10099.498.110098.3102
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
NI.121514.123758WG504176
Instrument ID:ICP-MS2File ID:
Run Date:12/15/2014Run Time:12:37Analyst:JYH
Workgroup (AAB#):
6020Method:L14120172Login Number: WG504857-10Sample ID:
15-DEC-14ICP-MS -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
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Page 177
CCV - Modified 03/05/2008
12/15/2014 14:09Report generated3914990PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Arsenic
Barium
Cobalt
Lead
Manganese
Selenium
0.05000.05000.05000.05000.05000.0500
0.05050.04920.04990.04970.05000.0508
10198.499.899.3100102
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
NI.121514.131539WG504176
Instrument ID:ICP-MS2File ID:
Run Date:12/15/2014Run Time:13:15Analyst:JYH
Workgroup (AAB#):
6020Method:L14120172Login Number: WG504857-12Sample ID:
15-DEC-14ICP-MS -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
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Page 178
CCV - Modified 03/05/2008
12/15/2014 14:09Report generated3914990PDF File ID:
CONTINUING CALIBRATION VERIFICATION (CCV)Microbac Laboratories Inc.
Arsenic
Barium
Cobalt
Lead
Manganese
Selenium
0.05000.05000.05000.05000.05000.0500
0.05140.04980.05040.05080.05120.0514
10399.5101102102103
90 - 11090 - 11090 - 11090 - 11090 - 11090 - 110
Analyte Expected Found Q
* Exceeds
LIMITS
Criteria LIMITS
%REC
NI.121514.133433WG504176
Instrument ID:ICP-MS2File ID:
Run Date:12/15/2014Run Time:13:34Analyst:JYH
Workgroup (AAB#):
6020Method:L14120172Login Number: WG504857-14Sample ID:
15-DEC-14ICP-MS -Cal ID:
UNITS
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
DOD4QC Key:
WATERMatrix:
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Page 179
INTERFERENCE CHECK SAMPLES
ICS - Modified 03/06/2008
12/15/2014 14:09Report generated3914989PDF File ID:
Microbac Laboratories Inc.
Arsenic Barium Cobalt Lead Manganese Selenium
ANALYTE0.00230 95.80.0507 93.90.0169 94.1-0.0193 97.00.109 95.5-0.0708 95.8
Found FoundNS 100NS 100NS 100NS 100NS 100NS 100
True True Q%Recovery %RecoveryNS 95.8NS 93.9NS 94.1NS 97.0NS 95.5NS 95.8
L14120172Login number:Instrument ID:ICP-MS2 Method:6020
WG504176Workgroup (AAB#):
WG504857-08WG504857-09
NI.121514.123139NI.121514.123447
File ID:File ID:
Units:ug/L
Sol. A Sol. AB
Sol. ASol. AB
::
NS = Not spiked * = Recovery of spiked element is outside acceptance limit of 80% - 120% of true value. # = Result for unspiked element is outside the acceptance limits of (+/-) the project reporting limit (RL). + = Result for unspiked element is outside the acceptance limits of (+/-) 2 times the project method detection limit (MDL). This criteria is only applicable to specific QAPPs.
Matrix:Water
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Page 180
INTERNAL STANDARD REPORT
INT_STD_ICPMS - Modified 07/28/2010
12/15/2014 14:09Report generated:3914984PDF File ID:
Acceptance criteria: 30% - 120% Underlined recoveries are out of rangeAcceptance criteria for CCVs and CCBs for method SW846-6020: 80% - 120%
Microbac Laboratories Inc.
WG504176
L14120172-02
L14120172-03
L14120172-04
L14120172-05
L14120172-06
L14120172-07
L14120172-08
L14120172-09
L14120172-10
WG504133-03
WG504133-04
WG504176-05
WG504176-06
WG504857-05
WG504857-06
WG504857-07
WG504857-08
WG504857-09
WG504857-10
WG504857-11
WG504857-12
WG504857-13
WG504857-14
WG504857-15
Sample
SAMP
SAMP
SAMP
SAMP
SAMP
SAMP
SAMP
SAMP
SAMP
BLANK
LCS
PSPK
SERIAL
ICV
ICB
LLICV
ICS
ICS
CCV
CCB
CCV
CCB
CCV
CCB
Type
15-DEC-2014 12:59
15-DEC-2014 13:03
15-DEC-2014 13:21
15-DEC-2014 12:50
15-DEC-2014 13:25
15-DEC-2014 12:53
15-DEC-2014 12:56
15-DEC-2014 13:28
15-DEC-2014 13:31
15-DEC-2014 12:44
15-DEC-2014 12:47
15-DEC-2014 13:06
15-DEC-2014 13:09
15-DEC-2014 12:22
15-DEC-2014 12:25
15-DEC-2014 12:28
15-DEC-2014 12:31
15-DEC-2014 12:34
15-DEC-2014 12:37
15-DEC-2014 12:41
15-DEC-2014 13:15
15-DEC-2014 13:18
15-DEC-2014 13:34
15-DEC-2014 13:37
Run Date
BISMUTH GERMANIUM INDIUM
% Rec % Rec % Rec
96.864 99.281 98.102
98.921 100.055 97.966
97.318 97.863 96.581
97.395 97.53 96.579
95.42 97.531 96.558
97.099 99.289 97.318
98.811 101.212 98.54
97.556 99.122 97.914
95.357 97.801 96.683
98.48 98.784 97.669
98.252 99.263 98.156
98.724 100.492 99.545
92.959 88.774 88.958
97.2 97.986 97.171
98.091 98.014 97.948
96.48 96.077 96.473
90.576 87.581 88.227
95.415 97.86 96.255
96.888 96.609 94.944
96.464 95.161 93.705
97.345 99.621 97.748
99.057 100.142 97.733
94.792 96.141 94.787
97.039 99.829 97.06
Analytical Workgroup:
L14120172Login:
Matrix:1
6020Analytical Method:
ICP-MS2Instrument: Analyst:JYH
ICAL Date:15-DEC-2014 12:09
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Page 181
LINEAR_RANGE - Modified 03/06/2008
12/15/2014 14:09Report generated:3914983PDF File ID:
LINEAR RANGE (QUARTERLY)Microbac Laboratories Inc.
Antimony Arsenic Barium Cadmium Chromium Cobalt Copper Lead Manganese Nickel Selenium Silver Thallium Uranium Vanadium Zinc
Analyte
1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00
Integration Time(Sec.)
100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0
Concentration
Insturment ID:Date:
Method:ICP-MS210/07/20146020
Comments:All analytes passed acceptance criteria at the specified concentration.
(ug/L)
Login Number:L14120172
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Page 182
Kem
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Arm
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uniti
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Dat
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alid
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La
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: Rad
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A
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ctio
n D
ate
Prep
arat
ion
Dat
e A
naly
sis
Dat
e A
naly
sis
<2X
HT
Ana
lysi
s �2
X H
T
Non
e
Com
men
ts:
Col
lect
ed 1
2/02
/201
4
Rev
ised
12/
2010
Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-150
Page 183
Kem
ron–
Rad
ford
Arm
y A
mm
uniti
on P
lant
Org
anic
Wor
kshe
et (G
CM
S)
SDG
: L14
1201
72
Met
hod:
826
0 M
atrix
: Wat
er
Leve
l III
Lab
Sam
ple
IDs:
NA
Bat
ch #
s: W
G46
9134
Le
vel I
V L
ab S
ampl
e ID
s: L
1412
0172
-01
thru
-10
Tuni
ng:
Pas
s F
ail
TIC
s Req
uire
d?
Yes
No
(EPA
Reg
ion
III L
imits
1 )
Ana
lyte
(o
utlie
rs)
Cal
ibra
tion
Met
hod
Bla
nk
5X
(10X
) M
etho
dB
lank
LC
S %
R
MS
%R
(-
07)
MSD
%R
(-
08)
MS/
DR
PD
TB
(-
01)
FB
(-04
) E
QR
(-03
) FD
(-
06)
RF
�0.0
5
RSD
/r
�30%
�0
.995
ICV
%
D
±25%
CC
V
%D
±2
5%
Ace
tone
0.
036
��
��
NA
�
��
��
��
�
(Lim
its1 :
1,2-
DC
A-d4
76-
114%
) Su
rrog
ate
Rec
over
y O
utlie
rs(B
FB 8
6-11
5% T
ol-d
8 88
-110
% )
Sam
ple
ID
1,2-
DC
A-d
4 D
BFM
B
FB
Tol
-d8
Sam
ple
ID
1,2-
DC
A-d
4 D
BFM
B
FB
Tol
-d8
MS
��
84.3
* �
M
SD�
�85
.8*
�
LCS
��
84*
�
IS O
utlie
rs (
-50%
to +
100%
of C
CV)
Sam
ple
ID
Are
a R
T
Are
a R
T
Are
a R
T
Are
a R
T
Are
a R
T
Are
a R
T
Non
e
Com
men
ts:
Sam
ples
unp
rese
rved
; ana
lyze
d w
ithin
HT
for u
npre
serv
ed sa
mpl
es; O
K.
Ace
tone
and
2-C
EVE
only
. La
b us
ed m
idpo
int s
td fo
r IS
sum
mar
y; D
V u
ses C
CV
; bot
h O
K.
*Met
lab
limits
< Q
APP
lim
its –
not
ass
ocia
ted
with
targ
et a
naly
tes
1 Der
ived
labo
rato
ry li
mits
use
d fo
r com
poun
ds n
ot li
sted
. R
evis
ed 1
2/20
10
Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-151
Page 184
Kem
ron–
Rad
ford
Arm
y A
mm
uniti
on P
lant
Org
anic
Wor
kshe
et (G
CM
S)
SDG
M
etho
d: 8
270C
SIM
M
atrix
: Le
vel I
II L
ab S
ampl
e ID
s: N
A
Bat
ch #
s:
Leve
l IV
Lab
Sam
ple
IDs:
Tuni
ng:
Pas
s F
ail
TIC
s Req
uire
d?
Yes
No
(EPA
Reg
ion
III L
imits
1 )
Ana
lyte
(o
utlie
rs)
Cal
ibra
tion
Met
hod
Bla
nk
5X
(10X
) M
etho
dB
lank
LC
S/D
%
R
MS
%R
MSD
%R
MS/
DR
PD
FB
FB
X5
EQ
R E
QR
X
5 R
F �0
.05
RSD
/r
�30%
�0
.995
ICV
%
D
±25%
CC
V
%D
±2
5%
(Lim
its:
NB-
d5 3
5-11
4%)
Surr
ogat
e R
ecov
ery
Out
liers
(2-F
lbip
h 43
-116
% p
-Ter
ph-d
14 3
3-14
1%)
Sam
ple
ID
2-Fl
BP
NB
-d5
p-T
erp-
d14
IS O
utlie
rs (-
50%
to +
100%
)Sa
mpl
e ID
A
rea
RT
A
rea
RT
A
rea
RT
A
rea
RT
A
rea
RT
A
rea
RT
Non
e
Com
men
ts:
1 Der
ived
labo
rato
ry li
mits
use
d fo
r com
poun
ds n
ot li
sted
. R
evis
ed 1
2/20
10
Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-152
Page 185
Kem
ron–
Rad
ford
Arm
y A
mm
uniti
on P
lant
Org
anic
Wor
kshe
et (L
CM
S)
SDG
: L14
1201
72
Met
hod:
685
0 M
atrix
: Wat
er
Leve
l III
Lab
Sam
ple
IDs:
NA
Bat
ch #
s: W
G50
4286
Le
vel I
V L
ab S
ampl
e ID
s: L
1412
0172
-02
thru
-10
Tuni
ng:
Pas
s F
ail
Mas
s Cal
ib:
P
ass
Fai
l (7
5-12
5%)
(�30
%)
Ana
lyte
(o
utlie
rs)
Cal
ibra
tion
Met
hod
Bla
nk
5X
(10X
) M
etho
dB
lank
LC
S %
R
1 (80-
120%
)
MS
%R
(-
07)
MSD
%R
(-
8)
MS/
DR
PD
FB
(-04
) E
QR
(-03
) FD
(-06
)
RSD
/r
�20%
�0
.995
ICV
/ C
CV
%
R
±15%
2 CR
DL
%R
±3
0%
ICS
%R
±2
0%
Non
e
35
Cl/ 3
7Cl I
soto
pe R
atio
(The
oret
ical
ratio
~3.
06; w
indo
w: 2
.3-3
.8)
Sam
ple
ID
Rat
io
Non
e
(Are
a: ±
50%
of I
CAL
avg
) IS
Out
liers
(RR
T: 0
.98
- 1.0
2)Sa
mpl
e ID
A
rea
RT
A
rea
RT
A
rea
RT
A
rea
RT
A
rea
RT
A
rea
RT
Non
e
Com
men
ts: H
Ts O
K; T
une
not i
nclu
ded
in d
ata
pack
age
CC
Bs O
K
CR
Is a
ll at
the
RL
not 2
X th
e R
L; C
alcu
late
d C
RIs
> re
porte
d C
RIs
1 O
r met
hod-
spec
ified
lim
its, w
hich
ever
is m
ore
strin
gent
2 CR
A a
t CR
DL
at b
egin
ning
of r
un; C
RI 2
X C
RD
L ev
ery
10 sa
mpl
es
Rev
ised
01/
2015
Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-153
Page 186
Kem
ron–
Rad
ford
Arm
y A
mm
uniti
on P
lant
Inor
gani
c M
etal
s Wor
kshe
et
SDG
: L14
1201
72
Mat
rix:
Wat
er
Leve
l III
Lab
Sam
ple
IDs:
NA
Met
hod/
Bat
ch #
s: 6
010B
: WG
5041
69/W
G50
4197
60
20: W
G50
4133
/WG
5041
76
Leve
l IV
Lab
Sam
ple
IDs:
L14
1201
72-0
2 th
ru -1
0
ICPM
S M
ass C
al:
Pas
s F
ail
NA
IC
PMS
Res
olut
ion:
P
ass
Fai
l N
A
ICPM
S %
RSD
: P
ass
Fai
l N
A
Ana
lyte
(o
utlie
rs)
Cal
ibra
tion
ICP
CR
DL
±10%
Met
hod
Bla
nk
(<M
DL)
5X
MB
ICS
A
<ID
L IC
S A
B±2
0%
LC
S %
R
(80-
120%
)
MS
%R
(7
5-12
5%)
MSD
%R
(7
5-12
5%)
MS/
DR
PD(�
20%
)
Seri
al
Dil.
%
D
(±10
%)
PS
(75-
125%
)
FD
RPD
(�
20%
) r
�0.9
95IC
V
±10%
1 C
CV
±1
0%1
ICB
ug
/L
CC
B
(<ID
L)
5X C
B
WG
5041
97
Al F
e M
g K
Na
V C
a
-07
-08
-0
6 -0
6 C
a�
��
��
NA
�
�N
A
��
�13
8*
159*
�
�36
* �
Na
��
��
.217
Ja 1.
09
��
NA
�
��
��
��
��
WG
5041
76
As B
a C
o Pb
Mn
Se
-07
-08
-0
3 E
QR
-0
6 M
n�
��
��
NA
58
�
NA
�
��
��
��
��
Se�
��
��
NA
81
�
NA
�
��
��
��
��
Pb�
��
��
NA
61
�
NA
�
��
��
��
��
a 2 th
ru 6
N
D
Or >
5X
IS O
utlie
rs3 (6
0-12
0%)
IS O
utlie
rs3 (6
0-12
0%)
Sam
ple
ID
%R
ecov
ery
%R
ecov
ery
%R
ecov
ery
CC
V/C
CB
ID
%R
ecov
ery
%R
ecov
ery
%R
ecov
ery
Non
e
Non
e
Com
men
ts:
HTs
OK
.; LO
D a
nd/o
r LO
Q sl
ight
ly >
QA
PP fo
r Al,
Ca,
Fe,
K (6
010B
); A
s, B
a, C
o, P
b, M
n, (6
020)
all
LOQ
s OK
, LO
D 2
X>Q
APP
;*>4
X sp
ike
amou
nt
Ca
dilu
ted
10X
-02
, -05
, -06
, -10
,-07M
S,-0
8MSD
-0
3(EQ
R):
ND
but
no
resu
lt or
qua
lifie
r rep
orte
d fo
r Na
(cal
c fr
om ra
w d
ata)
-0
4(FB
): N
D b
ut n
o re
sult
or q
ualif
ier r
epor
ted
for N
a (c
alc
from
raw
dat
a)
Ca
and
Mg
calc
PS
do n
ot a
gree
with
lab
resu
lt. C
alcu
late
d re
sults
use
d fo
r DV
60
10: N
o C
RIs
but
low
stan
dard
at R
L; L
LICV
with
Ca
dilu
tions
no
resu
lts re
porte
d
6020
: SD
and
PS
on E
QR
IC
S no
t per
form
ed a
t end
of a
naly
sis;
NA
sinc
e re
sults
for A
l, C
a, M
g an
d Fe
are
< IC
S sp
iked
am
ount
s -0
6 m
issi
ng C
a re
sult
(cal
c fr
om ra
w d
ata)
1 20
% fo
r Hg
2 For s
ampl
e re
sults
<5X
RL,
±R
L; 3 St
anda
rd C
LP N
FG c
riter
ia u
sed;
no
crite
ria sp
ecifi
ed in
QA
PP o
r Reg
ion
III N
FG;
CR
I and
ICS
begi
nnin
g an
d en
d of
run
Rev
ised
12/
2010
Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-154
Page 187
VOC
Cal
ibra
tion
Verif
icat
ion
for S
DG
L14
1201
72
Ave
rage
RF
Int.
Std.
=
25
13
53
37
43
Ace
tone
2-C
EVE
Dib
rom
oflu
orom
etha
ne1,
2-D
CE-
d4
Con
c.In
tern
al A
rea
#1In
tern
al A
rea
#1In
tern
al A
rea
#1A
rea
RR
FR
RF
Are
aR
RF
Are
aR
RF
0.3
0.4 1
590621
590621
590621
2363
0.2
00
3031
0.2
57
2595588
595588
595588
4813
0.1
01
5249
0.2
20
6465
0.2
71
5593360
593360
593360
3981
0.0
34
10738
0.0
90
13714
0.2
31
15014
0.2
53
20
591637
591637
591637
15631
0.0
33
49354
0.1
04
56949
0.2
41
61595
0.2
60
50
585193
585193
585193
42974
0.0
37
120775
0.1
03
140183
0.2
40
153462
0.2
62
100
594161
594161
594161
88402
0.0
37
215207
0.0
91
293318
0.2
47
316482
0.2
66
200
587557
587557
587557
179909
0.0
38
412065
0.0
88
580668
0.2
47
628514
0.2
67
300
600387
600387
600387
263814
0.0
37
629490
0.0
87
862565
0.2
39
910420
0.2
53
Multi
plie
rA
veR
FR
SD
ICV
11/1
9/20
14C
CV
12/0
3/20
14A
ceto
ne2-
CEV
EA
ceto
ne2-
CEV
EIn
t. St
d. R
espo
nse
585224
585224
909351
909351
Ana
lyte
Res
pons
e17768
52962
65261
189011
Ana
lyte
Con
cent
ratio
n20
20
50
50
Int.
Std.
Con
cent
ratio
n25
25
25
25
CC
RF
0.0
38
0.1
13
0.0
36
0.1
04
Ave
RF
0.0
36
0.0
949
0.0
36
0.0
949
Cal
c'd
Con
cent
ratio
n21.1
23.8
50.0
54.7
CC
V %
D5.7
25
19.1
6-0
.04
9.4
7Lab d
oes
not in
dic
ate
bia
s on their s
um
mary
form
s
12/3
/201
4M
BLC
S-0
1-0
2-0
3-0
4-0
5-0
6-0
9-0
7-0
8-1
0D
ilutio
n/D
F1
11
11
11
11
11
1Fi
nal V
olum
e (m
L)5
55
55
55
55
55
5Sa
mpl
e A
liquo
t (m
L)5
55
55
55
55
55
5
IS R
espo
nse
845713
876342
858256
787841
829586
810763
798744
772738
771173
860783
868814
773416
Surr
Res
pons
e185049
211330
192402
187399
183492
192613
177423
184099
174091
206640
195039
182371
Surr
ogat
e #
12
12
12
12
12
12
Cal
ibra
tion
R.F
.0.2
33
0.2
61
0.2
33
0.2
61
0.2
33
0.2
61
0.2
33
0.2
61
0.2
33
0.2
61
0.2
33
0.2
61
Surr
spi
ke C
onc.
(ug/
L)25
25
25
25
25
25
25
25
25
25
25
25
Surr
spi
ke C
onc.
(ug/
L)25
25
25
25
25
25
25
25
25
25
25
25
Surr
Con
c. (u
g/L)
23.5
23.1
24.0
22.8
23.7
22.7
23.8
22.8
24.2
23.0
24.1
22.6
Surr
%R
EC94
92
96
91
95
91
95
91
97
92
96
90
TCA
ceto
neTC
TCTC
TCTC
TCTC
2-C
EVE
2-C
EVE
TCIS
Res
pons
e876342
860783
868814
TC R
espo
nse
25705
78171
75524
Cal
ibra
tion
R.F
.0.0
36
0.0
95
0.0
95
0.0
95
0.0
95
TC C
onc.
(ug/
L)20.4
28
23.9
14
22.8
91
Am
ount
Spi
ked
20
20
20
%R
102.1
4119.5
7114.4
6R
PD
0.0
36
0.0
949
4.3
7
10.2
33
0.2
61
5.8
84
7.9
458
6.8
44
2.6
2832
Cal
ibra
tion:
WG
5015
14 H
PMS8
11/
18/2
014
11
1
Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-155
Page 188
Reg
ress
ion
Cal
cula
tor f
or a
Lin
ear R
F C
urve
- C
onc.
Rat
io O
n X-
Axi
s W
G50
1146
Per
chlo
rate
for S
DG
L14
1201
72
6/8
/20
13
ICA
L1IC
AL2
ICA
L3IC
AL4
ICA
L5IC
AL6
ICA
L7IC
AL8
ICA
L9IC
AL1
0C
ount
s A
naly
te (35
Cl)
11
10
01
73
00
44
10
08
44
00
17
30
00
42
00
00
84
10
00
00
0C
ount
s IS
32
20
00
32
20
00
32
90
00
32
70
00
32
30
00
31
40
00
31
20
00
11
1C
onc
Ana
lyte
0.1
00
.20
0.5
01
.00
2.0
05
.00
10
.00
00
0C
onc
IS5
.00
5.0
05
.00
5.0
05
.00
5.0
05
.00
11
1R
F1
.72
41
.34
31
.34
01
.29
11
.33
91
.33
81
.34
8x-
axis
0.0
20
0.0
40
0.1
00
0.2
00
0.4
00
1.0
00
2.0
00
0.0
00
0.0
00
0.0
00
y-ax
is0
.03
44
70
.05
37
30
.13
40
40
.25
81
00
.53
56
01
.33
75
82
.69
55
10
.00
00
00
.00
00
00
.00
00
0
En
ter
0 f
or
Co
un
ts A
na
lyte
an
d C
on
c A
na
lyte
if a
sta
nd
ard
is n
ot
use
dE
nte
r 1
fo
r C
ou
nts
IS
an
d C
on
c IS
if a
sta
nd
ard
is n
ot
use
dU
nu
sed
sta
nd
ard
s m
ust
be
on
th
e f
ar
rig
ht
(no
ga
ps
in t
he
use
d s
tan
da
rds)
Ca
lcs
slig
htly
off
du
e t
o r
ou
nd
ing
.O
ffset
Slop
eM
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-156
Page 189
CA
LCU
LATI
ON
WO
RK
SHEE
T FO
R 6
010
MET
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WA
TER
RES
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S FO
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72
Wat
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MD
L(m
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CR
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(mg/
L) Fina
l Vol
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50
50
50
50
50
50
Sam
ple
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40
40
40
40
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ug/L
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DF
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40
40
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10
DF
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10
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10
Ca
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0.5
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Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-157
Page 190
CALCULATION WORKSHEET FOR METALS RESULTS FOR SDG L14120172
6010 Water:8.27 8.37 14.13 14.55 15.36
12/10/2014 ICV ICSA ICSAB CCV CCV CCV CCVAnalyte Al Ca Fe Mg K Na VTrue Conc 10.0 250.0 100.0 10.0 50.0 50.0 1.0Reported Conc 10.2 287 96 10.1 51.5 49.1 1.0%D 1.98 13.78 -3.77 1.00 2.96 -1.82 2.96%R 102.0 114.8 96.3 101.0 103.0 98.2 103.0
8.58 9.12 9.54 10.5312/11/2014 ICV LLICV ICSA ICSAB CCV CCV CCVAnalyte Ca Ca Ca Ca Ca Ca CaTrue Conc 10.0 250.0 250.0 10.0 10.0 10.0Reported Conc 10.1 0.0369 280 273.0 9.9 10.4 10.3%D 1.00 200.00 11.32 8.80 -1.31 3.92 2.96%R 101.0 #DIV/0! 112.0 109.2 98.7 104.0 103.0
LCS -07 MS -08 MSDAnalyte Al Fe FeTrue Conc 6.250 2.500 2.500Reported Conc 6.170 2.570 2.600Sample Conc 0.155 0.155%R 98.72 96.60 97.80RPD
Analyte MDL PS -06 Spike Added %RAl 0.100 5.16 0.24 5.000 98.9Ca 0.250 34.6 32.8 5.000 101.6Fe 0.050 2.16 0.141 2.000 101.7Mg 0.250 13.9 9.92 5.0 99.4K 0.500 24.1 0.654 25.000 94.0Na 0 250 28 5 08 25 000 93 7
1.16
Na 0.250 28 5.08 25.000 93.7V 0.005 0.5 0 0.500 100.0
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Al 0.24 0.0554 0.277 0.100 5.000 10Ca 32.8 6.59 32.95 0.250 12.500 Y 10 0.46Fe 0.141 0.0343 0.1715 0.050 2.500 10Mg 9.92 2.08 10.4 0.250 12.500 10K 0.654 0.166 0.83 0.500 25.000 10Na 5.08 1.11 5.55 0.250 12.500 10V 0 0.00043 0.00215 0.005 0.250 10
%D >Limit?Analyte Serial Dilution 5x > 50*IDL? RPD Limit
Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-158
Page 191
CA
LCU
LATI
ON
WO
RK
SHEE
T FO
R 6
020
MET
ALS
WA
TER
RES
ULT
S FO
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Wat
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ampl
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alcu
latio
ns:
MD
L(m
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2-0
3 Fi
nal V
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l)1
00
10
01
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40
40
ug/L
mg/
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/Lm
g/L
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mg/
Lug
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g/L
ug/L
mg/
LD
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0.0
00
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27
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01
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10
01
00
10
01
00
Sam
ple
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40
40
40
40
40
40
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0.0
01
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03
09
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0.0
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09
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13
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40
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21
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0.0
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0.0
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62
6.2
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50
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0.0
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Pb (2
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0.0
00
50
0.0
01
0-0
.03
36
U-0
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79
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6.4
67
10
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26
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22
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80
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27
0.0
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02
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40
30
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1.0
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90
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05
00
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10
0.1
10
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0.1
08
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27
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41
0.0
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52
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90
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0.0
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Low
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me
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0.4
00
00
As
0.4
20
90
.40
00
10
5.2
25
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0.7
00
20
.75
00
93
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(111
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00
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r (52
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00
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69
0.4
00
09
9.2
25
Cu
0.8
00
00
Pb (2
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0.1
22
20
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00
61
.1M
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0.5
00
05
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00
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0.3
23
40
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00
80
.85
Ag
0.4
00
00
Tl (2
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0.0
80
00
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MB
LCS
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05-0
6-0
7 M
S-0
8 M
SD-0
9
Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-159
Page 192
CALCULATION WORKSHEET FOR METALS RESULTS FOR SDG L14120172
6020 Water:
12.37 13.15 13.3412/15/2014 ICV ICSAB ICSAB CCV CCV CCVAnalyte As Ba Co Pb Mn SeTrue Conc 50.0 100.0 100.0 50.0 50.0 50.0Reported Conc 50.38 93.88 94.06 50.16 49.98 51.41%D 0.75 -6.31 -6.13 0.32 -0.04 2.78%R 100.8 93.9 94.1 100.3 100.0 102.8
LCS -07 MS -08 MSDAnalyte Pb Ba BaTrue Conc 0.0625 0.0625 0.0625Reported Conc 0.0685 0.0897 0.1010Sample Conc 0.0240 0.0240%R 109.60 105.12 123.20RPD
Analyte MDL -03 PS -03 Spike Added %RAs 0.00050 53.32 0 50.000 106.6Ba 0.00150 52.68 0 50.000 105.4Co 0.00050 53.54 0 50.000 107.1Pb (208) 0.00050 53.22 0 50.000 106.4Mn 0.00100 53.97 0 50.000 107.9Se (82) 0.00050 53.43 0 50.000 106.9
-3 IDL 50 * IDL SD performed on EQRug/L ug/L ug/L mg/L mg/L
As 0 0.00050 0.025 10Ba 0 0.00150 0.075 10Co 0 0.00050 0.025 10Pb (208) 0 0.00050 0.025 10Mn 0 0.00100 0.050 10Se (82) 0 0.00050 0.025 10
%D >Limit?
11.85
Analyte Serial Dilution 5x > 50*IDL? RPD Limit
Radford Army Ammunition Plant: Data Validation for Lab Report L14120172 D-160
Page 193
Laboratory Report Number: L14120172 (Revised)
Revised to include a missing calcium result for the duplicate sample
Mary Lou RochetteKemron Environmental Services2343-A State Rt 821Marietta, OH 45750
Please find enclosed the analytical results for the samples you submitted to Microbac Laboratories. Review and compilation of your report was completed by Microbac’s Ohio Valley Division (OVD). If you have any questions, comments, or require further assistance regarding this report, please contact your service representative listed below.
Laboratory Contact:Stephanie Mossburg – Team Chemist/Data Specialist(740) [email protected]
I certify that all test results meet all of the requirements of the DoD QSM and other applicable contract terms and conditions. Any exceptions are attached to this cover page or addressed in the method narratives presented in the report. All results for soil samples are reported on a 'dry-weight' basis unless specified otherwise. Analytical results for water and wastes are reported on a 'as received' basis unless specified otherwise. A statement of uncertainty for each analysis is available upon request. This laboratory report shall not be reproduced, except in full, without the written approval of Microbac Laboratories, DoD ELAP certification number 2936.01. The reported results are related only to the samples analyzed as received.
This report was certified on January 22 2015
David Vandenberg – Managing Director State of Origin: VAAccrediting Authority: Common Wealth of Virginia ID:460187QAPP: DOD Ver 4.1
Microbac Laboratories * Ohio Valley Division158 Starlite Drive, Marietta, OH 45750 * T: (740) 373-4071 F: (740) 373-4835 * www.microbac.com
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Record of Sample Receipt and InspectionComments/DiscrepanciesThis is the record of the shipment conditions and the inspection records for the samples received and reported as a sample delivery group (SDG). All of the samples were inspected and observed to conform to our receipt policies, except as noted below.
There were no discrepancies.Discrepancy Resolution
CoolersCooler # Temperature
GunTemperature COC # Airbill # Temp Required?
0019428 H 1.0 X
Inspection Checklist
# Question Result
1 Were shipping coolers sealed? NA
2 Were custody seals intact? NA
3 Were cooler temperatures in range of 0-6? Yes
4 Was ice present? Yes
5 Were COC's received/information complete/signed and dated? Yes
6 Were sample containers intact and match COC? Yes
7 Were sample labels intact and match COC? Yes
8 Were the correct containers and volumes received? Yes
9 Were samples received within EPA hold times? Yes
10 Were correct preservatives used? (water only) Yes
11 Were pH ranges acceptable? (voa's excluded) Yes
12 Were VOA samples free of headspace (less than 6mm)? Yes
Microbac Laboratories ● Ohio Valley Division158 Starlite Drive, Marietta, OH 45750 ● T: (740)373-4071 F: (740)373-4835
www.microbac.com
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Samples ReceivedClient ID Laboratory ID Date Collected Date Received
40TB12214 L14120172-01 12/02/2014 00:01 12/03/2014 13:00
40MW7GW12214 L14120172-02 12/02/2014 09:17 12/03/2014 13:00
40EQR12214 L14120172-03 12/02/2014 10:50 12/03/2014 13:00
40FB12214 L14120172-04 12/02/2014 11:05 12/03/2014 13:00
40MW5GW12214 L14120172-05 12/02/2014 11:58 12/03/2014 13:00
40DUPGW12214 L14120172-06 12/02/2014 11:58 12/03/2014 13:00
40MW5MSGW12214 L14120172-07 12/02/2014 11:58 12/03/2014 13:00
40MW5MSDGW12214 L14120172-08 12/02/2014 11:58 12/03/2014 13:00
40MW6GW12214 L14120172-09 12/02/2014 14:06 12/03/2014 13:00
LFMW01GW12214 L14120172-10 12/02/2014 15:45 12/03/2014 13:00
Microbac Laboratories ● Ohio Valley Division158 Starlite Drive, Marietta, OH 45750 ● T: (740)373-4071 F: (740)373-4835
www.microbac.com
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Microbac LaboratoriesCase Narrative
Login Number: L14120172Department: VolatilesAnalyst: Tiffany Bailey
METHOD
Preparation SW-846 5030C/5035A
Analysis SW-846 8260B
HOLDING TIMES
Sample Preparation: All holding times were met.
Sample Analysis: All holding times were met.
PREPARATION
Sample preparation proceeded normally.
CALIBRATION
Initial Calibration: For all compounds that yielded a %RSD greater than 15%, linear or higher order equations were applied. All acceptance criteria were met.
Alternate Source Standards: All acceptance criteria were met.
Continuing Calibration and Tune: Non-target calibration check compound (CCC) vinyl chloride exceeded the upper control limit, however, the target analytes met CCC acceptance criteria.
BATCH QA/QC
Method Blank: All acceptance criteria were met.
Laboratory Control Sample: All acceptance criteria were met.
Matrix Spikes: All acceptance criteria were met.
SAMPLES
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Internal Standards: All acceptance criteria were met.
Surrogates: All acceptance criteria were met.
Other: None.
Manual Integration Reason Codes
Reason #1: Data System Fails to Select Correct Peak. In some cases the chromatography system selects and integrates the 'wrong peak'. In this case the analyst must correct the selection and force the system to integrate the proper peak. Other times the system may miss the peak completely.
Reason #2: Data System Splits the Peak Incorrectly or Integrates a False Peak as a Rider Peak. This phenomena is common at low concentrations where the signal:noise ratio is low. A single compound (peak) is incorrectly split into multiple peaks or integrated as a main peak with one or more rider peaks resulting in low area counts for the target compound.
Reason #3: Improperly Integrated Isomers and/or coeluting compounds. This system often fails to distinguish coeluting compounds and or isomers. The integration areas and concentrations are wrong, and they must be corrected by manual integration. Prime examples are benzo(k)fluoranthene and benzo(b)fluoranthene which are often unresolved and integrated improperly when both are present at low concentrations in standards or samples.
Reason #4: System Establishes Incorrect Baseline. There are numerous situations in chromatography where the system establishes the baseline incorrectly. Some baseline errors will be obvious to the analyst and should be corrected via manual procedures.
Reason #5: Miscellaneous. Other situations involving integration errors may require in-depth review and technical judgment. These cases should be brought to the attention of the laboratory management. If the form of manual integration is not clearly covered by these four cases, then review and approval by the Managing Director or the QAO will be required.
I certify that this data package is in compliance with the terms and conditions agreed to by the client and Microbac Laboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or designated person, as verified by the following signature.
Narrative ID: 92859Approved By: Michael Albertson
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Microbac LaboratoriesCase Narrative
Login Number: L14120172Department: General ChromatographyAnalyst: Anthony Canter
METHOD
Analysis SW-846 6850
HOLDING TIMES
Sample Preparation: All holding times were met.
Sample Analysis: All holding times were met.
PREPARATION
Sample preparation proceeded normally.
CALIBRATION
Initial Calibration: For all compounds that yielded a %RSD greater than 15%, linear or higher order equations were applied. All acceptance criteria were met.
Alternate Source Standards: All acceptance criteria were met.
Continuing Calibration and Tune: All acceptance criteria were met.
BATCH QA/QC
Method Blank: All acceptance criteria were met.
Laboratory Control Sample: All acceptance criteria were met.
Matrix Spikes: All acceptance criteria were met.
SAMPLES
Samples: All acceptance criteria were met.
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Internal Standards: All acceptance criteria were met.
Manual Integration Reason Codes
Reason #1: Data System Fails to Select Correct Peak In some cases the chromatography system selects and integrates the 'wrong peak'. In this case the analyst must correct the selection and force the system to integrate the proper peak. Other times the system may miss the peak completely.
Reason #2: Data System Splits the Peak Incorrectly or Integrates a False Peak as a Rider Peak This phenomena is common at low concentrations where the signal:noise ratio is low. A single compound (peak) is incorrectly split into multiple peaks or integrated as a main peak with one or more rider peaks resulting in low area counts for the target compound.
Reason #3: Improperly Integrated Isomers and/or coeluting compounds. This system often fails to distinguish coeluting compounds and or isomers. The integration areas and concentrations are wrong, and they must be corrected by manual integration. Prime examples are benzo(k)fluoranthene and benzo(b)fluoranthene which are often unresolved and integrated improperly when both are present at low concentrations in standards or samples.
Reason #4: System Establishes Incorrect Baseline There are numerous situations in chromatography where the system establishes the baseline incorrectly. Some baseline errors will be obvious to the analyst and should be corrected via manual procedures.
Reason #5: Miscellaneous Other situations involving integration errors may require in-depth review and technical judgment. These cases should be brought to the attention of the laboratory management. If the form of manual integration is not clearly covered by these four cases, then review and approval by the Laboratory Director or the QA/QC Supervisor will be required.
I certify that this data package is in compliance with the terms and conditions agreed to by the client and Microbac Laboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or designated person, as verified by the following signature.
Narrative ID: 93199Approved By: Leslie Bucina
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Microbac LaboratoriesCase Narrative
Login Number: L14120172Department: MetalsAnalyst: Kim Rhodes
METHOD
Preparation: SW-846 3015
Analysis: SW-846 6010
HOLDING TIMES
Sample Preparation: All holding times were met.
Sample Analysis: All holding times were met.
PREPARATION
Sample preparation proceeded normally.
CALIBRATION
Initial Calibration: All acceptance criteria were met.
Alternate Source Standards: All acceptance criteria were met.
Interference Check Standards: All acceptance criteria were met.
Continuing Calibration Verification: All acceptance criteria were met.
Continuing Calibration Blank: WG504197 - The continuing calibration blank analyzed on 10-DEC-2014 at 14:15 yielded a result for sodium of 0.217mg/L which exceeded the LOD. However, the reported sample results exceeded that of the CCB by greater than a factor of ten with the exception of fractions 03 and 04. Fractions 03 and 04 yielded results that were below the LOD, therefore, no further action was taken. The sodium results were reported with a 'B' qualifier to indicate the association with a noncompliant CCB.
BATCH QA/QC
Method Blank: All acceptance criteria were met.
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Laboratory Control Sample: All acceptance criteria were met.
Serial Dilution/Post Digestion Spikes: WG504197 - All acceptance criteria were met.
Matrix Spikes: WG504197 - Sample 05 was chosen by the client for MS/MSD analysis. Samples 07(MS) and 08(MSD) yielded noncompliant recoveries for calcium.
SAMPLES
Samples: WG504197 - Client samples 02, 05, 06, 07MS, 08MSD and 10 as well as the batch post digestion spike required dilution analyses in order to obtain results for calcium within the calibration range.
Narrative ID: 93050Approved By: Sheri Pfalzgraf
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Microbac LaboratoriesCase Narrative
Login Number: L14120172Department: MetalsAnalyst: Ji HuAnalyst #2: Pierce Morris
METHOD
Preparation: SW-846 3015
Analysis: SW-846 6020
HOLDING TIMES
Sample Preparation: All holding times were met.
Sample Analysis: All holding times were met.
PREPARATION
Sample preparation proceeded normally.
CALIBRATION
Initial Calibration: All acceptance criteria were met.
Alternate Source Standards: All acceptance criteria were met.
Interference Check Standards: All acceptance criteria were met.
Continuing Calibration: All acceptance criteria were met.
Continuing Calibration Blank: All acceptance criteria were met.
Low Level Check: All acceptance criteria were met.
BATCH QA/QC
Method Blank: All acceptance criteria were met.
Laboratory Control Sample: All acceptance criteria were met.
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Serial Dilution/Post Digestion Spikes: WG504176 - All acceptance criteria were met.
Matrix Spikes: WG504176 - Sample 05 was chosen by the client for MS/MSD analysis. Samples 07 (MS) and 08 (MSD) yielded a noncompliant recovery for barium.
SAMPLES
Samples: All acceptance criteria were met.
Narrative ID: 93175Approved By: Maren Beery
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisSample #: L14120172-01 PrePrep Method: N/A Instrument: HPMS8
Client ID: 40TB12214 Prep Method: 5030B/5030C/5035A Prep Date: N/A
Matrix: Water Analytical Method: 8260B Cal Date: 11/19/2014 00:08
Workgroup #: WG503275 Analyst: TMB Run Date: 12/03/2014 18:52
Collect Date: 12/02/2014 00:01 Dilution: 1 File ID: 8M401510
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
2-Chloroethyl vinyl ether 110-75-8 U 10.0 2.00
Acetone 67-64-1 U 10.0 2.50
Surrogate Recovery Lower Limit Upper Limit Q
1,2-Dichloroethane-d4 93.1 70 120
4-Bromofluorobenzene 89.9 75 120
Dibromofluoromethane 96.2 85 115
Toluene-d8 88.4 85 120
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-02 PrePrep Method: N/A Instrument: HPMS8
Client ID: 40MW7GW12214 Prep Method: 5030B/5030C/5035A Prep Date: N/A
Matrix: Water Analytical Method: 8260B Cal Date: 11/19/2014 00:08
Workgroup #: WG503275 Analyst: TMB Run Date: 12/03/2014 20:48
Collect Date: 12/02/2014 09:17 Dilution: 1 File ID: 8M401514
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
2-Chloroethyl vinyl ether 110-75-8 U 10.0 2.00
Acetone 67-64-1 U 10.0 2.50
Surrogate Recovery Lower Limit Upper Limit Q
1,2-Dichloroethane-d4 91.0 70 120
4-Bromofluorobenzene 89.4 75 120
Dibromofluoromethane 95.9 85 115
Toluene-d8 89.1 85 120
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-02 PrePrep Method: N/A Instrument: LCMS1
Client ID: 40MW7GW12214 Prep Method: 6850 Prep Date: 12/10/2014 10:00
Matrix: Water Analytical Method: 6850 Cal Date: 11/17/2014 14:53
Workgroup #: WG504286 Analyst: ADC Run Date: 12/11/2014 10:45
Collect Date: 12/02/2014 09:17 Dilution: 1 File ID: 1LM.LM27939
Sample Tag: 01 Units: ug/L
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisAnalyte CAS # Result Qual LOQ LOD
Perchlorate 14797-73-0 3.14 0.200 0.100
Sample #: L14120172-02 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40MW7GW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/10/2014 08:18
Workgroup #: WG504197 Analyst: KHR Run Date: 12/10/2014 14:32
Collect Date: 12/02/2014 09:17 Dilution: 1 File ID: P2.121014.143245
Sample Tag: 01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Aluminum, Total 7429-90-5 U 0.200 0.100
Iron, Total 7439-89-6 0.198 0.100 0.0500
Magnesium, Total 7439-95-4 29.7 0.500 0.250
Potassium, Total 7440-09-7 1.55 1.00 0.500
Sodium, Total 7440-23-5 3.81 B 0.500 0.250
Vanadium, Total 7440-62-2 U 0.0100 0.00500
B The reported result is associated with a contaminated method blank.
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-02 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40MW7GW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/11/2014 08:56
Workgroup #: WG504197 Analyst: KHR Run Date: 12/11/2014 10:24
Collect Date: 12/02/2014 09:17 Dilution: 10 File ID: P2.121114.102418
Sample Tag: DL01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Calcium, Total 7440-70-2 77.0 5.00 2.50
Sample #: L14120172-02 PrePrep Method: N/A Instrument: ICP-MS2
Client ID: 40MW7GW12214 Prep Method: 3015 Prep Date: 12/10/2014 07:25
Matrix: Water Analytical Method: 6020 Cal Date: 12/15/2014 12:19
Workgroup #: WG504176 Analyst: JYH Run Date: 12/15/2014 12:59
Collect Date: 12/02/2014 09:17 Dilution: 1 File ID: NI.121514.125957
Sample Tag: 03 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Arsenic, Total 7440-38-2 U 0.00100 0.000500
Barium, Total 7440-39-3 0.114 0.00300 0.00150
Cobalt, Total 7440-48-4 U 0.00100 0.000500
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisAnalyte CAS # Result Qual LOQ LOD
Lead, Total 7439-92-1 U 0.00100 0.000500
Manganese, Total 7439-96-5 0.00135 J 0.00200 0.00100
Selenium, Total 7782-49-2 U 0.00100 0.000500
J Estimated value ; the analyte concentration was less than the LOQ.
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-03 PrePrep Method: N/A Instrument: HPMS8
Client ID: 40EQR12214 Prep Method: 5030B/5030C/5035A Prep Date: N/A
Matrix: Water Analytical Method: 8260B Cal Date: 11/19/2014 00:08
Workgroup #: WG503275 Analyst: TMB Run Date: 12/03/2014 19:21
Collect Date: 12/02/2014 10:50 Dilution: 1 File ID: 8M401511
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
2-Chloroethyl vinyl ether 110-75-8 U 10.0 2.00
Acetone 67-64-1 U 10.0 2.50
Surrogate Recovery Lower Limit Upper Limit Q
1,2-Dichloroethane-d4 91.2 70 120
4-Bromofluorobenzene 90.8 75 120
Dibromofluoromethane 94.9 85 115
Toluene-d8 91.1 85 120
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-03 PrePrep Method: N/A Instrument: LCMS1
Client ID: 40EQR12214 Prep Method: 6850 Prep Date: 12/10/2014 10:00
Matrix: Water Analytical Method: 6850 Cal Date: 11/17/2014 14:53
Workgroup #: WG504286 Analyst: ADC Run Date: 12/10/2014 19:17
Collect Date: 12/02/2014 10:50 Dilution: 1 File ID: 1LM.LM27910
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
Perchlorate 14797-73-0 U 0.200 0.100
U Analyte was not detected. The concentration is below the reported LOD.
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisSample #: L14120172-03 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40EQR12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/10/2014 08:18
Workgroup #: WG504197 Analyst: KHR Run Date: 12/10/2014 14:36
Collect Date: 12/02/2014 10:50 Dilution: 1 File ID: P2.121014.143607
Sample Tag: 01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Aluminum, Total 7429-90-5 U 0.200 0.100
Calcium, Total 7440-70-2 U 0.500 0.250
Iron, Total 7439-89-6 U 0.100 0.0500
Magnesium, Total 7439-95-4 U 0.500 0.250
Potassium, Total 7440-09-7 U 1.00 0.500
Sodium, Total 7440-23-5 0.500 0.250
Vanadium, Total 7440-62-2 U 0.0100 0.00500
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-03 PrePrep Method: N/A Instrument: ICP-MS2
Client ID: 40EQR12214 Prep Method: 3015 Prep Date: 12/10/2014 07:25
Matrix: Water Analytical Method: 6020 Cal Date: 12/15/2014 12:19
Workgroup #: WG504176 Analyst: JYH Run Date: 12/15/2014 13:03
Collect Date: 12/02/2014 10:50 Dilution: 1 File ID: NI.121514.130305
Sample Tag: 03 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Arsenic, Total 7440-38-2 U 0.00100 0.000500
Barium, Total 7440-39-3 U 0.00300 0.00150
Cobalt, Total 7440-48-4 U 0.00100 0.000500
Lead, Total 7439-92-1 U 0.00100 0.000500
Manganese, Total 7439-96-5 U 0.00200 0.00100
Selenium, Total 7782-49-2 U 0.00100 0.000500
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-04 PrePrep Method: N/A Instrument: HPMS8
Client ID: 40FB12214 Prep Method: 5030B/5030C/5035A Prep Date: N/A
Matrix: Water Analytical Method: 8260B Cal Date: 11/19/2014 00:08
Workgroup #: WG503275 Analyst: TMB Run Date: 12/03/2014 19:50
Collect Date: 12/02/2014 11:05 Dilution: 1 File ID: 8M401512
Sample Tag: 01 Units: ug/L
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisAnalyte CAS # Result Qual LOQ LOD
2-Chloroethyl vinyl ether 110-75-8 U 10.0 2.00
Acetone 67-64-1 U 10.0 2.50
Surrogate Recovery Lower Limit Upper Limit Q
1,2-Dichloroethane-d4 90.9 70 120
4-Bromofluorobenzene 90.9 75 120
Dibromofluoromethane 95.4 85 115
Toluene-d8 90.6 85 120
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-04 PrePrep Method: N/A Instrument: LCMS1
Client ID: 40FB12214 Prep Method: 6850 Prep Date: 12/10/2014 10:00
Matrix: Water Analytical Method: 6850 Cal Date: 11/17/2014 14:53
Workgroup #: WG504286 Analyst: ADC Run Date: 12/10/2014 19:36
Collect Date: 12/02/2014 11:05 Dilution: 1 File ID: 1LM.LM27911
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
Perchlorate 14797-73-0 U 0.200 0.100
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-04 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40FB12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/10/2014 08:18
Workgroup #: WG504197 Analyst: KHR Run Date: 12/10/2014 14:39
Collect Date: 12/02/2014 11:05 Dilution: 1 File ID: P2.121014.143928
Sample Tag: 01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Aluminum, Total 7429-90-5 U 0.200 0.100
Calcium, Total 7440-70-2 U 0.500 0.250
Iron, Total 7439-89-6 U 0.100 0.0500
Magnesium, Total 7439-95-4 U 0.500 0.250
Potassium, Total 7440-09-7 U 1.00 0.500
Sodium, Total 7440-23-5 0.500 0.250
Vanadium, Total 7440-62-2 U 0.0100 0.00500
U Analyte was not detected. The concentration is below the reported LOD.
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisSample #: L14120172-04 PrePrep Method: N/A Instrument: ICP-MS2
Client ID: 40FB12214 Prep Method: 3015 Prep Date: 12/10/2014 07:25
Matrix: Water Analytical Method: 6020 Cal Date: 12/15/2014 12:19
Workgroup #: WG504176 Analyst: JYH Run Date: 12/15/2014 13:21
Collect Date: 12/02/2014 11:05 Dilution: 1 File ID: NI.121514.132157
Sample Tag: 03 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Arsenic, Total 7440-38-2 U 0.00100 0.000500
Barium, Total 7440-39-3 U 0.00300 0.00150
Cobalt, Total 7440-48-4 U 0.00100 0.000500
Lead, Total 7439-92-1 U 0.00100 0.000500
Manganese, Total 7439-96-5 U 0.00200 0.00100
Selenium, Total 7782-49-2 U 0.00100 0.000500
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-05 PrePrep Method: N/A Instrument: HPMS8
Client ID: 40MW5GW12214 Prep Method: 5030B/5030C/5035A Prep Date: N/A
Matrix: Water Analytical Method: 8260B Cal Date: 11/19/2014 00:08
Workgroup #: WG503275 Analyst: TMB Run Date: 12/03/2014 20:19
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: 8M401513
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
2-Chloroethyl vinyl ether 110-75-8 U 10.0 2.00
Acetone 67-64-1 U 10.0 2.50
Surrogate Recovery Lower Limit Upper Limit Q
1,2-Dichloroethane-d4 91.9 70 120
4-Bromofluorobenzene 90.9 75 120
Dibromofluoromethane 95.3 85 115
Toluene-d8 90.1 85 120
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-05 PrePrep Method: N/A Instrument: LCMS1
Client ID: 40MW5GW12214 Prep Method: 6850 Prep Date: 12/10/2014 10:00
Matrix: Water Analytical Method: 6850 Cal Date: 11/17/2014 14:53
Workgroup #: WG504286 Analyst: ADC Run Date: 12/10/2014 19:55
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: 1LM.LM27912
Sample Tag: 01 Units: ug/L
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisAnalyte CAS # Result Qual LOQ LOD
Perchlorate 14797-73-0 0.883 0.200 0.100
Sample #: L14120172-05 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40MW5GW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/10/2014 08:18
Workgroup #: WG504197 Analyst: KHR Run Date: 12/10/2014 14:42
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: P2.121014.144249
Sample Tag: 01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Aluminum, Total 7429-90-5 0.256 0.200 0.100
Iron, Total 7439-89-6 0.155 0.100 0.0500
Magnesium, Total 7439-95-4 13.2 0.500 0.250
Potassium, Total 7440-09-7 0.764 J 1.00 0.500
Sodium, Total 7440-23-5 6.58 B 0.500 0.250
Vanadium, Total 7440-62-2 U 0.0100 0.00500
B The reported result is associated with a contaminated method blank.
J Estimated value ; the analyte concentration was less than the LOQ.
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-05 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40MW5GW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/11/2014 08:56
Workgroup #: WG504197 Analyst: KHR Run Date: 12/11/2014 10:27
Collect Date: 12/02/2014 11:58 Dilution: 10 File ID: P2.121114.102740
Sample Tag: DL01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Calcium, Total 7440-70-2 41.4 5.00 2.50
Sample #: L14120172-05 PrePrep Method: N/A Instrument: ICP-MS2
Client ID: 40MW5GW12214 Prep Method: 3015 Prep Date: 12/10/2014 07:25
Matrix: Water Analytical Method: 6020 Cal Date: 12/15/2014 12:19
Workgroup #: WG504176 Analyst: JYH Run Date: 12/15/2014 12:50
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: NI.121514.125033
Sample Tag: 03 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Arsenic, Total 7440-38-2 U 0.00100 0.000500
Barium, Total 7440-39-3 0.0240 0.00300 0.00150
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisAnalyte CAS # Result Qual LOQ LOD
Cobalt, Total 7440-48-4 U 0.00100 0.000500
Lead, Total 7439-92-1 U 0.00100 0.000500
Manganese, Total 7439-96-5 U 0.00200 0.00100
Selenium, Total 7782-49-2 U 0.00100 0.000500
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-06 PrePrep Method: N/A Instrument: HPMS8
Client ID: 40DUPGW12214 Prep Method: 5030B/5030C/5035A Prep Date: N/A
Matrix: Water Analytical Method: 8260B Cal Date: 11/19/2014 00:08
Workgroup #: WG503275 Analyst: TMB Run Date: 12/03/2014 21:16
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: 8M401515
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
2-Chloroethyl vinyl ether 110-75-8 U 10.0 2.00
Acetone 67-64-1 U 10.0 2.50
Surrogate Recovery Lower Limit Upper Limit Q
1,2-Dichloroethane-d4 91.2 70 120
4-Bromofluorobenzene 90.0 75 120
Dibromofluoromethane 95.4 85 115
Toluene-d8 89.3 85 120
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-06 PrePrep Method: N/A Instrument: LCMS1
Client ID: 40DUPGW12214 Prep Method: 6850 Prep Date: 12/10/2014 10:00
Matrix: Water Analytical Method: 6850 Cal Date: 11/17/2014 14:53
Workgroup #: WG504286 Analyst: ADC Run Date: 12/10/2014 20:14
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: 1LM.LM27913
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
Perchlorate 14797-73-0 0.856 0.200 0.100
Sample #: L14120172-06 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40DUPGW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/10/2014 08:18
Workgroup #: WG504197 Analyst: KHR Run Date: 12/10/2014 14:46
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: P2.121014.144610
Sample Tag: 01 Units: mg/L
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisAnalyte CAS # Result Qual LOQ LOD
Aluminum, Total 7429-90-5 0.300 0.200 0.100
Calcium, Total 7440-70-2 41.0 0.500 0.250
Iron, Total 7439-89-6 0.177 0.100 0.0500
Magnesium, Total 7439-95-4 12.4 0.500 0.250
Potassium, Total 7440-09-7 0.817 J 1.00 0.500
Sodium, Total 7440-23-5 6.35 B 0.500 0.250
Vanadium, Total 7440-62-2 U 0.0100 0.00500
B The reported result is associated with a contaminated method blank.
J Estimated value ; the analyte concentration was less than the LOQ.
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-06 PrePrep Method: N/A Instrument: ICP-MS2
Client ID: 40DUPGW12214 Prep Method: 3015 Prep Date: 12/10/2014 07:25
Matrix: Water Analytical Method: 6020 Cal Date: 12/15/2014 12:19
Workgroup #: WG504176 Analyst: JYH Run Date: 12/15/2014 13:25
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: NI.121514.132506
Sample Tag: 02 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Arsenic, Total 7440-38-2 U 0.00100 0.000500
Barium, Total 7440-39-3 0.0241 0.00300 0.00150
Cobalt, Total 7440-48-4 U 0.00100 0.000500
Lead, Total 7439-92-1 U 0.00100 0.000500
Manganese, Total 7439-96-5 U 0.00200 0.00100
Selenium, Total 7782-49-2 U 0.00100 0.000500
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-07 PrePrep Method: N/A Instrument: HPMS8
Client ID: 40MW5MSGW12214 Prep Method: 5030B/5030C/5035A Prep Date: N/A
Matrix: Water Analytical Method: 8260B Cal Date: 11/19/2014 00:08
Workgroup #: WG503275 Analyst: TMB Run Date: 12/03/2014 17:54
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: 8M401508
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
2-Chloroethyl vinyl ether 110-75-8 23.9 10.0 2.00
Acetone 67-64-1 20.1 10.0 2.50
Surrogate Recovery Lower Limit Upper Limit Q
1,2-Dichloroethane-d4 91.9 70 120
4-Bromofluorobenzene 84.3 75 120
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisDibromofluoromethane 96.1 85 115
Toluene-d8 88.8 85 120
Sample #: L14120172-07 PrePrep Method: N/A Instrument: LCMS1
Client ID: 40MW5MSGW12214 Prep Method: 6850 Prep Date: 12/10/2014 10:00
Matrix: Water Analytical Method: 6850 Cal Date: 11/17/2014 14:53
Workgroup #: WG504286 Analyst: ADC Run Date: 12/10/2014 21:29
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: 1LM.LM27917
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
Perchlorate 14797-73-0 1.05 0.200 0.100
Sample #: L14120172-07 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40MW5MSGW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/10/2014 08:18
Workgroup #: WG504197 Analyst: KHR Run Date: 12/10/2014 15:03
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: P2.121014.150311
Sample Tag: 01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Aluminum, Total 7429-90-5 6.17 0.200 0.100
Iron, Total 7439-89-6 2.57 0.100 0.0500
Magnesium, Total 7439-95-4 19.1 0.500 0.250
Potassium, Total 7440-09-7 30.0 1.00 0.500
Sodium, Total 7440-23-5 35.6 B 0.500 0.250
Vanadium, Total 7440-62-2 0.626 0.0100 0.00500
B The reported result is associated with a contaminated method blank.
Sample #: L14120172-07 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40MW5MSGW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/11/2014 08:56
Workgroup #: WG504197 Analyst: KHR Run Date: 12/11/2014 10:40
Collect Date: 12/02/2014 11:58 Dilution: 10 File ID: P2.121114.104008
Sample Tag: DL01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Calcium, Total 7440-70-2 50.0 5.00 2.50
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisSample #: L14120172-07 PrePrep Method: N/A Instrument: ICP-MS2
Client ID: 40MW5MSGW12214 Prep Method: 3015 Prep Date: 12/10/2014 07:24
Matrix: Water Analytical Method: 6020 Cal Date: 12/15/2014 12:19
Workgroup #: WG504176 Analyst: JYH Run Date: 12/15/2014 12:53
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: NI.121514.125341
Sample Tag: 03 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Arsenic, Total 7440-38-2 0.0666 0.00100 0.000500
Barium, Total 7440-39-3 0.0897 0.00300 0.00150
Cobalt, Total 7440-48-4 0.0646 0.00100 0.000500
Lead, Total 7439-92-1 0.0662 0.00100 0.000500
Manganese, Total 7439-96-5 0.0650 0.00200 0.00100
Selenium, Total 7782-49-2 0.0675 0.00100 0.000500
Sample #: L14120172-08 PrePrep Method: N/A Instrument: HPMS8
Client ID: 40MW5MSDGW12214 Prep Method: 5030B/5030C/5035A Prep Date: N/A
Matrix: Water Analytical Method: 8260B Cal Date: 11/19/2014 00:08
Workgroup #: WG503275 Analyst: TMB Run Date: 12/03/2014 18:23
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: 8M401509
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
2-Chloroethyl vinyl ether 110-75-8 22.9 10.0 2.00
Acetone 67-64-1 19.5 10.0 2.50
Surrogate Recovery Lower Limit Upper Limit Q
1,2-Dichloroethane-d4 90.8 70 120
4-Bromofluorobenzene 85.8 75 120
Dibromofluoromethane 96.3 85 115
Toluene-d8 87.9 85 120
Sample #: L14120172-08 PrePrep Method: N/A Instrument: LCMS1
Client ID: 40MW5MSDGW12214 Prep Method: 6850 Prep Date: 12/10/2014 10:00
Matrix: Water Analytical Method: 6850 Cal Date: 11/17/2014 14:53
Workgroup #: WG504286 Analyst: ADC Run Date: 12/10/2014 21:48
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: 1LM.LM27918
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
Perchlorate 14797-73-0 1.09 0.200 0.100
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Page 215
Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisSample #: L14120172-08 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40MW5MSDGW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/10/2014 08:18
Workgroup #: WG504197 Analyst: KHR Run Date: 12/10/2014 15:05
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: P2.121014.150537
Sample Tag: 01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Aluminum, Total 7429-90-5 6.26 0.200 0.100
Iron, Total 7439-89-6 2.60 0.100 0.0500
Magnesium, Total 7439-95-4 19.4 0.500 0.250
Potassium, Total 7440-09-7 30.8 1.00 0.500
Sodium, Total 7440-23-5 36.6 B 0.500 0.250
Vanadium, Total 7440-62-2 0.631 0.0100 0.00500
B The reported result is associated with a contaminated method blank.
Sample #: L14120172-08 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40MW5MSDGW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/11/2014 08:56
Workgroup #: WG504197 Analyst: KHR Run Date: 12/11/2014 10:43
Collect Date: 12/02/2014 11:58 Dilution: 10 File ID: P2.121114.104330
Sample Tag: DL01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Calcium, Total 7440-70-2 51.3 5.00 2.50
Sample #: L14120172-08 PrePrep Method: N/A Instrument: ICP-MS2
Client ID: 40MW5MSDGW12214 Prep Method: 3015 Prep Date: 12/10/2014 07:25
Matrix: Water Analytical Method: 6020 Cal Date: 12/15/2014 12:19
Workgroup #: WG504176 Analyst: JYH Run Date: 12/15/2014 12:56
Collect Date: 12/02/2014 11:58 Dilution: 1 File ID: NI.121514.125649
Sample Tag: 03 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Arsenic, Total 7440-38-2 0.0669 0.00100 0.000500
Barium, Total 7440-39-3 0.101 0.00300 0.00150
Cobalt, Total 7440-48-4 0.0657 0.00100 0.000500
Lead, Total 7439-92-1 0.0658 0.00100 0.000500
Manganese, Total 7439-96-5 0.0661 0.00200 0.00100
Selenium, Total 7782-49-2 0.0680 0.00100 0.000500
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Page 216
Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisSample #: L14120172-09 PrePrep Method: N/A Instrument: HPMS8
Client ID: 40MW6GW12214 Prep Method: 5030B/5030C/5035A Prep Date: N/A
Matrix: Water Analytical Method: 8260B Cal Date: 11/19/2014 00:08
Workgroup #: WG503275 Analyst: TMB Run Date: 12/03/2014 21:45
Collect Date: 12/02/2014 14:06 Dilution: 1 File ID: 8M401516
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
2-Chloroethyl vinyl ether 110-75-8 U 10.0 2.00
Acetone 67-64-1 U 10.0 2.50
Surrogate Recovery Lower Limit Upper Limit Q
1,2-Dichloroethane-d4 93.6 70 120
4-Bromofluorobenzene 89.2 75 120
Dibromofluoromethane 96.8 85 115
Toluene-d8 89.5 85 120
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-09 PrePrep Method: N/A Instrument: LCMS1
Client ID: 40MW6GW12214 Prep Method: 6850 Prep Date: 12/10/2014 10:00
Matrix: Water Analytical Method: 6850 Cal Date: 11/17/2014 14:53
Workgroup #: WG504286 Analyst: ADC Run Date: 12/10/2014 22:07
Collect Date: 12/02/2014 14:06 Dilution: 1 File ID: 1LM.LM27919
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
Perchlorate 14797-73-0 1.03 0.200 0.100
Sample #: L14120172-09 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: 40MW6GW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/10/2014 08:18
Workgroup #: WG504197 Analyst: KHR Run Date: 12/10/2014 15:08
Collect Date: 12/02/2014 14:06 Dilution: 1 File ID: P2.121014.150803
Sample Tag: 01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Aluminum, Total 7429-90-5 0.466 0.200 0.100
Calcium, Total 7440-70-2 22.2 0.500 0.250
Iron, Total 7439-89-6 0.451 0.100 0.0500
Magnesium, Total 7439-95-4 6.79 0.500 0.250
Potassium, Total 7440-09-7 1.12 1.00 0.500
Sodium, Total 7440-23-5 7.98 B 0.500 0.250
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisAnalyte CAS # Result Qual LOQ LOD
Vanadium, Total 7440-62-2 U 0.0100 0.00500
B The reported result is associated with a contaminated method blank.
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-09 PrePrep Method: N/A Instrument: ICP-MS2
Client ID: 40MW6GW12214 Prep Method: 3015 Prep Date: 12/10/2014 07:25
Matrix: Water Analytical Method: 6020 Cal Date: 12/15/2014 12:19
Workgroup #: WG504176 Analyst: JYH Run Date: 12/15/2014 13:28
Collect Date: 12/02/2014 14:06 Dilution: 1 File ID: NI.121514.132814
Sample Tag: 03 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Arsenic, Total 7440-38-2 U 0.00100 0.000500
Barium, Total 7440-39-3 0.0122 0.00300 0.00150
Cobalt, Total 7440-48-4 U 0.00100 0.000500
Lead, Total 7439-92-1 U 0.00100 0.000500
Manganese, Total 7439-96-5 0.00265 0.00200 0.00100
Selenium, Total 7782-49-2 U 0.00100 0.000500
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-10 PrePrep Method: N/A Instrument: HPMS8
Client ID: LFMW01GW12214 Prep Method: 5030B/5030C/5035A Prep Date: N/A
Matrix: Water Analytical Method: 8260B Cal Date: 11/19/2014 00:08
Workgroup #: WG503275 Analyst: TMB Run Date: 12/03/2014 22:14
Collect Date: 12/02/2014 15:45 Dilution: 1 File ID: 8M401517
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
2-Chloroethyl vinyl ether 110-75-8 U 10.0 2.00
Acetone 67-64-1 U 10.0 2.50
Surrogate Recovery Lower Limit Upper Limit Q
1,2-Dichloroethane-d4 90.3 70 120
4-Bromofluorobenzene 89.8 75 120
Dibromofluoromethane 95.2 85 115
Toluene-d8 89.5 85 120
U Analyte was not detected. The concentration is below the reported LOD.
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Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisSample #: L14120172-10 PrePrep Method: N/A Instrument: LCMS1
Client ID: LFMW01GW12214 Prep Method: 6850 Prep Date: 12/10/2014 10:00
Matrix: Water Analytical Method: 6850 Cal Date: 11/17/2014 14:53
Workgroup #: WG504286 Analyst: ADC Run Date: 12/10/2014 22:26
Collect Date: 12/02/2014 15:45 Dilution: 1 File ID: 1LM.LM27920
Sample Tag: 01 Units: ug/L
Analyte CAS # Result Qual LOQ LOD
Perchlorate 14797-73-0 3.04 0.200 0.100
Sample #: L14120172-10 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: LFMW01GW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/10/2014 08:18
Workgroup #: WG504197 Analyst: KHR Run Date: 12/10/2014 15:15
Collect Date: 12/02/2014 15:45 Dilution: 1 File ID: P2.121014.151536
Sample Tag: 01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Aluminum, Total 7429-90-5 0.526 0.200 0.100
Iron, Total 7439-89-6 0.527 0.100 0.0500
Magnesium, Total 7439-95-4 22.3 0.500 0.250
Potassium, Total 7440-09-7 1.29 1.00 0.500
Sodium, Total 7440-23-5 6.08 B 0.500 0.250
Vanadium, Total 7440-62-2 U 0.0100 0.00500
B The reported result is associated with a contaminated method blank.
U Analyte was not detected. The concentration is below the reported LOD.
Sample #: L14120172-10 PrePrep Method: N/A Instrument: PE-ICP2
Client ID: LFMW01GW12214 Prep Method: 3015 Prep Date: 12/10/2014 09:19
Matrix: Water Analytical Method: 6010B Cal Date: 12/11/2014 08:56
Workgroup #: WG504197 Analyst: KHR Run Date: 12/11/2014 10:46
Collect Date: 12/02/2014 15:45 Dilution: 10 File ID: P2.121114.104651
Sample Tag: DL01 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Calcium, Total 7440-70-2 63.9 5.00 2.50
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Page 219
Lab Report #: L14120172
Lab Project #: 2820.216
Project Name: Radford AAP
Lab Contact: Stephanie Mossburg
Certificate of AnalysisSample #: L14120172-10 PrePrep Method: N/A Instrument: ICP-MS2
Client ID: LFMW01GW12214 Prep Method: 3015 Prep Date: 12/10/2014 07:25
Matrix: Water Analytical Method: 6020 Cal Date: 12/15/2014 12:19
Workgroup #: WG504176 Analyst: JYH Run Date: 12/15/2014 13:31
Collect Date: 12/02/2014 15:45 Dilution: 1 File ID: NI.121514.133122
Sample Tag: 03 Units: mg/L
Analyte CAS # Result Qual LOQ LOD
Arsenic, Total 7440-38-2 U 0.00100 0.000500
Barium, Total 7440-39-3 0.0494 0.00300 0.00150
Cobalt, Total 7440-48-4 U 0.00100 0.000500
Lead, Total 7439-92-1 U 0.00100 0.000500
Manganese, Total 7439-96-5 0.00368 0.00200 0.00100
Selenium, Total 7782-49-2 0.000738 J 0.00100 0.000500
J Estimated value ; the analyte concentration was less than the LOQ.
U Analyte was not detected. The concentration is below the reported LOD.
Page 16 of 16 Generated at Jan 22, 2015 10:02
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Page 220
12/04/2014 14:57Report generated3903663PDF File ID:
Microbac Laboratories Inc.
METHOD BLANK SUMMARY
Report Name: BLANK_SUMMARY
8M401506
12/03/14 16:56
12/03/14 16:56
WG503275
WG503275-02
HPMS8
Blank File ID:
Prep Date:
Analyzed Date:
Work Group:
Blank Sample ID:
Instrument ID:
8260BMethod:
TMBAnalyst:
L14120172Login Number:
LCS
40MW5MSGW12214
40MW5MSDGW12214
40TB12214
40EQR12214
40FB12214
40MW5GW12214
40MW7GW12214
40DUPGW12214
40MW6GW12214
LFMW01GW12214
WG503275-03
L14120172-07
L14120172-08
L14120172-01
L14120172-03
L14120172-04
L14120172-05
L14120172-02
L14120172-06
L14120172-09
L14120172-10
8M401507
8M401508
8M401509
8M401510
8M401511
8M401512
8M401513
8M401514
8M401515
8M401516
8M401517
12/03/14 17:26
12/03/14 17:54
12/03/14 18:23
12/03/14 18:52
12/03/14 19:21
12/03/14 19:50
12/03/14 20:19
12/03/14 20:48
12/03/14 21:16
12/03/14 21:45
12/03/14 22:14
This Method Blank Applies To The Following Samples:
Client ID Lab Sample ID Lab File ID Time Analyzed TAG
01
01
01
01
01
01
01
01
01
01
01
Page 28
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Page 221
Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLANK
PDF ID: 3903664
04-DEC-2014 14:57
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-d8
91.5
92.1
93.9
89.8
Surrogates % Recovery Surrogate Limits
70
75
85
85
-
-
-
-
120
120
115
120
Qualifier
PASS
PASS
PASS
PASS
Analytes Concentration Dilution Qualifier
2-Chloroethyl vinyl ether
Acetone
1
1
2.00
2.50
10.0
10.0
U
U
2.00
2.50
ND Analyte Not detected at or above reporting limit
* |Analyte concentration| > 1/2 RL
8M401506
WG503275
Instrument ID:HPMS8
File ID:
Prep Date:12/03/14 16:56
Run Date:12/03/14 16:56
Analyst:TMB
Workgroup (AAB#): ug/LUnits:
8260BMethod:
WaterMatrix:
L14120172Login Number: WG503275-02Sample ID:
19-NOV-14Cal ID: HPMS8-Contract #:
5030B/5030C/503Prep Method:
LOD LOQ
LOD
LOQ
Method Detection Limit
Reporting/Practical Quantitation Limit
Page 29
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Page 222
LCS - Modified 03/06/2008
12/04/2014 14:57Report generated:3903586PDF File ID:
LABORATORY CONTROL SAMPLE (LCS)
Microbac Laboratories Inc.
8M401507
WG503275
Instrument ID:HPMS8
File ID:
Run Date:12/03/2014
Run Time:17:26
Analyst:TMB
Workgroup (AAB#): ug/LUnits:
5030B/5030C/503Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found LCS Limits Q% Rec
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-d8
92.3
84.0
96.3
88.7
Surrogates % Recovery Surrogate Limits
70
75
85
85
-
-
-
-
120
120
115
120
Qualifier
PASS
PASS
PASS
PASS
WG503275-03Sample ID:
19-NOV-14Cal ID: HPMS8-DOD4QC Key:
2-Chloroethyl vinyl ether
Acetone
45
40
20.0
20.0
23.5
20.4
117
102
-
-
160
140
8260BMethod:
* EXCEEDS %REC LIMIT
Lot#:STD67765
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Page 223
MS_MSD - Modified 03/06/2008
12/04/2014 14:57Report generated3903587PDF File ID:
Microbac Laboratories Inc.
MS/MSD REPORT
L14120172Loginnum:
WaterMatrix:
2-Chloroethyl vinyl ether
Acetone
AnalyteMS MSD
23.9 22.9
20.1 19.5
Found Found
U
U
20.0 20.0
20.0 20.0
120 114
100 97.4
4.37
3.03
MS MSDMS MSD
Spiked Spiked%Rec %Rec
58
40
-
-
160
140
20
30
%RPDParent%RecLimits
RPDLimit Q
Instrument ID:HPMS8
Parent ID:L14120172-05
Sample ID:
Sample ID:
L14120172-07
L14120172-08
MS
MSD
Method:8260B
Units:ug/L
Contract #:
Cal ID: HPMS8- 19-NOV-14 WG503275Worknum:
8M401513
8M401508
8M401509
File ID:
File ID:
File ID:
Dil:
Dil:
1
1
Dil:1
Prep Method:5030B/5030C/5035A
* FAILS %REC LIMIT
# FAILS RPD LIMIT
Page 31
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Page 224
12/12/2014 14:36Report generated3916580PDF File ID:
Microbac Laboratories Inc.
METHOD BLANK SUMMARY
Report Name: BLANK_SUMMARY
1LM.LM27905
12/10/14 10:00
12/10/14 17:42
WG504286
WG504286-02
LCMS1
Blank File ID:
Prep Date:
Analyzed Date:
Work Group:
Blank Sample ID:
Instrument ID:
6850Method:
ADCAnalyst:
L14120172Login Number:
QCMRL
MCT
LCS
40EQR12214
40FB12214
40MW5GW12214
40DUPGW12214
QCMRL
40MW5MSGW12214
40MW5MSDGW12214
40MW6GW12214
LFMW01GW12214
QCMRL
QCMRL
QCMRL
40MW7GW12214
QCMRL
WG504286-07
WG504286-01
WG504286-03
L14120172-03
L14120172-04
L14120172-05
L14120172-06
WG504286-08
L14120172-07
L14120172-08
L14120172-09
L14120172-10
WG504286-09
WG504286-10
WG504286-11
L14120172-02
WG504286-12
1LM.LM27903
1LM.LM27904
1LM.LM27906
1LM.LM27910
1LM.LM27911
1LM.LM27912
1LM.LM27913
1LM.LM27915
1LM.LM27917
1LM.LM27918
1LM.LM27919
1LM.LM27920
1LM.LM27925
1LM.LM27932
1LM.LM27935
1LM.LM27939
1LM.LM27941
12/10/14 17:04
12/10/14 17:23
12/10/14 18:01
12/10/14 19:17
12/10/14 19:36
12/10/14 19:55
12/10/14 20:14
12/10/14 20:51
12/10/14 21:29
12/10/14 21:48
12/10/14 22:07
12/10/14 22:26
12/11/14 00:01
12/11/14 02:13
12/11/14 09:29
12/11/14 10:45
12/11/14 11:22
This Method Blank Applies To The Following Samples:
Client ID Lab Sample ID Lab File ID Time Analyzed TAG
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
01
Page 32
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Page 225
Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLANK
PDF ID: 3916581
12-DEC-2014 14:36
Analytes Concentration Dilution Qualifier
Perchlorate 10.100 0.200 U0.100
ND Analyte Not detected at or above reporting limit
* |Analyte concentration| > 1/2 RL
1LM.LM27905
WG504286
Instrument ID:LCMS1
File ID:
Prep Date:12/10/14 10:00
Run Date:12/10/14 17:42
Analyst:ADC
Workgroup (AAB#): ug/LUnits:
6850Method:
WaterMatrix:
L14120172Login Number: WG504286-02Sample ID:
17-NOV-14Cal ID: LCMS1-Contract #:
6850Prep Method:
LOD LOQ
LOD
LOQ
Method Detection Limit
Reporting/Practical Quantitation Limit
Page 33
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Page 226
LCS - Modified 03/06/2008
12/12/2014 14:36Report generated:3916582PDF File ID:
LABORATORY CONTROL SAMPLE (LCS)
Microbac Laboratories Inc.
1LM.LM27906
WG504286
Instrument ID:LCMS1
File ID:
Run Date:12/10/2014
Run Time:18:01
Analyst:ADC
Workgroup (AAB#): ug/LUnits:
6850Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found LCS Limits Q% Rec
WG504286-03Sample ID:
17-NOV-14Cal ID: LCMS1-DOD4QC Key:
Perchlorate 800.200 0.215 108 - 120
6850Method:
Lot#:STD67080
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Page 227
MS_MSD - Modified 03/06/2008
12/12/2014 14:36Report generated3916583PDF File ID:
Microbac Laboratories Inc.
MS/MSD REPORT
L14120172Loginnum:
WaterMatrix:
Perchlorate
AnalyteMS MSD
1.05 1.09
Found Found
0.883 0.200 0.20083.5 104 3.74
MS MSDMS MSD
Spiked Spiked%Rec %Rec
80 - 120 15
%RPDParent%RecLimits
RPDLimit Q
Instrument ID:LCMS1
Parent ID:L14120172-05
Sample ID:
Sample ID:
L14120172-07
L14120172-08
MS
MSD
Method:6850
Units:ug/L
Contract #:
Cal ID: LCMS1- 17-NOV-14 WG504286Worknum:
1LM.LM27912
1LM.LM27917
1LM.LM27918
File ID:
File ID:
File ID:
Dil:
Dil:
1
1
Dil:1
Prep Method:6850
* FAILS %REC LIMIT
# FAILS RPD LIMIT
Page 35
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Page 228
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: L14120172-02
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27939
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 10:45 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 267000 88100 3.03 2.3 3.8
Page 1 of 38 Generated at Jan 22, 2015 10:04
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Page 229
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: L14120172-03
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27910
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 19:17 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 527 223 2.36 2.3 3.8
Page 2 of 38 Generated at Jan 22, 2015 10:04
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Page 230
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: L14120172-04
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27911
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 19:36 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 722 332 2.17 2.3 3.8 *
Page 3 of 38 Generated at Jan 22, 2015 10:04
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Page 231
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: L14120172-05
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27912
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 19:55 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 84500 28500 2.96 2.3 3.8
Page 4 of 38 Generated at Jan 22, 2015 10:04
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Page 232
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: L14120172-06
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27913
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 20:14 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 83300 29400 2.83 2.3 3.8
Page 5 of 38 Generated at Jan 22, 2015 10:04
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Page 233
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: L14120172-07
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27917
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 21:29 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 104000 33800 3.08 2.3 3.8
Page 6 of 38 Generated at Jan 22, 2015 10:04
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Page 234
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: L14120172-08
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27918
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 21:48 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 103000 34600 2.98 2.3 3.8
Page 7 of 38 Generated at Jan 22, 2015 10:04
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Page 235
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: L14120172-09
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27919
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 22:07 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 97400 32600 2.99 2.3 3.8
Page 8 of 38 Generated at Jan 22, 2015 10:04
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Page 236
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: L14120172-10
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27920
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 22:26 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 290000 98600 2.94 2.3 3.8
Page 9 of 38 Generated at Jan 22, 2015 10:04
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Page 237
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG501146-02
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27604
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 11/17/2014 13:00 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 11100 3370 3.29 2.3 3.8
Page 10 of 38 Generated at Jan 22, 2015 10:04
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Page 238
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG501146-03
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27605
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 11/17/2014 13:19 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 17300 5740 3.01 2.3 3.8
Page 11 of 38 Generated at Jan 22, 2015 10:04
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Page 239
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG501146-04
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27606
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 11/17/2014 13:38 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 44100 14600 3.02 2.3 3.8
Page 12 of 38 Generated at Jan 22, 2015 10:04
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Page 240
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG501146-05
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27607
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 11/17/2014 13:56 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 84400 29400 2.87 2.3 3.8
Page 13 of 38 Generated at Jan 22, 2015 10:04
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Page 241
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG501146-06
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27608
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 11/17/2014 14:15 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 173000 54700 3.16 2.3 3.8
Page 14 of 38 Generated at Jan 22, 2015 10:04
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Page 242
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG501146-07
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27609
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 11/17/2014 14:34 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 420000 140000 3.00 2.3 3.8
Page 15 of 38 Generated at Jan 22, 2015 10:04
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Page 243
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG501146-08
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27610
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 11/17/2014 14:53 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 841000 276000 3.05 2.3 3.8
Page 16 of 38 Generated at Jan 22, 2015 10:04
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Page 244
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG501146-09
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27611
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 11/17/2014 15:12 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 88800 29400 3.02 2.3 3.8
Page 17 of 38 Generated at Jan 22, 2015 10:04
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Page 245
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: WG504286-01
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27904
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 17:23 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 20600 7320 2.81 2.3 3.8
Page 18 of 38 Generated at Jan 22, 2015 10:04
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Page 246
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: WG504286-02
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27905
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 17:42 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 0.000 0.000 0.000 2.3 3.8 *
Page 19 of 38 Generated at Jan 22, 2015 10:04
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Page 247
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: WG504286-03
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27906
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 18:01 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 21200 7360 2.88 2.3 3.8
Page 20 of 38 Generated at Jan 22, 2015 10:04
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Page 248
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: WG504286-07
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27903
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 17:04 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 19500 6490 3.00 2.3 3.8
Page 21 of 38 Generated at Jan 22, 2015 10:04
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Page 249
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: WG504286-08
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27915
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 20:51 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 21200 6500 3.26 2.3 3.8
Page 22 of 38 Generated at Jan 22, 2015 10:04
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Page 250
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: WG504286-09
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27925
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 00:01 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 20100 6670 3.01 2.3 3.8
Page 23 of 38 Generated at Jan 22, 2015 10:04
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Page 251
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: WG504286-10
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27932
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 02:13 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 19900 6850 2.91 2.3 3.8
Page 24 of 38 Generated at Jan 22, 2015 10:04
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L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 252
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: WG504286-11
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27935
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 09:29 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 19400 6380 3.04 2.3 3.8
Page 25 of 38 Generated at Jan 22, 2015 10:04
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L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 253
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: 6850 Samplenum: WG504286-12
Instrument: LCMS1 Prep Date: 12/10/2014 10:00 File ID: 1LM.LM27941
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 11:22 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 19500 6330 3.08 2.3 3.8
Page 26 of 38 Generated at Jan 22, 2015 10:04
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Page 254
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-01
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27901
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 16:26 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 0.000 0.000 0.000 2.3 3.8 *
Page 27 of 38 Generated at Jan 22, 2015 10:04
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Page 255
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-02
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27902
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 16:45 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 102000 33100 3.08 2.3 3.8
Page 28 of 38 Generated at Jan 22, 2015 10:04
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L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 256
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-03
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27914
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 20:33 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 106000 34000 3.12 2.3 3.8
Page 29 of 38 Generated at Jan 22, 2015 10:04
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Page 257
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-04
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27916
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 21:10 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 0.000 0.000 0.000 2.3 3.8 *
Page 30 of 38 Generated at Jan 22, 2015 10:04
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Page 258
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-05
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27924
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/10/2014 23:42 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 105000 35600 2.95 2.3 3.8
Page 31 of 38 Generated at Jan 22, 2015 10:04
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Page 259
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-06
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27926
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 00:20 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 0.000 0.000 0.000 2.3 3.8 *
Page 32 of 38 Generated at Jan 22, 2015 10:04
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Page 260
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-07
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27931
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 01:55 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 103000 33200 3.10 2.3 3.8
Page 33 of 38 Generated at Jan 22, 2015 10:04
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Page 261
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-08
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27933
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 02:32 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 0.000 0.000 0.000 2.3 3.8 *
Page 34 of 38 Generated at Jan 22, 2015 10:04
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L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 262
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-09
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27934
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 09:10 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 101000 33700 3.00 2.3 3.8
Page 35 of 38 Generated at Jan 22, 2015 10:04
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Page 263
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-10
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27936
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 09:48 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 0.000 171 0.000 2.3 3.8 *
Page 36 of 38 Generated at Jan 22, 2015 10:04
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Page 264
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-11
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27940
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 11:03 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 101000 33500 3.01 2.3 3.8
Page 37 of 38 Generated at Jan 22, 2015 10:04
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Page 265
Perchlorate Ion RatiosMicrobac Laboratories Inc.
Login #: L14120172 Prep Method: Samplenum: WG504287-12
Instrument: LCMS1 Prep Date: File ID: 1LM.LM27942
Analyst: ADC Anal Method: 6850 Matrix: Water
Worknum: WG504286 Analysis Date: 12/11/2014 11:41 Units: ug/L
Analyte Res #1 Res #2 Ratio Lower Upper Q
PERCHLORATE 0.000 218 0.000 2.3 3.8 *
Page 38 of 38 Generated at Jan 22, 2015 10:04
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L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 266
12/11/2014 12:43Report generated3912479PDF File ID:
Microbac Laboratories Inc.
METHOD BLANK SUMMARY
Report Name: BLANK_SUMMARY
P2.121014.142656
12/10/14 09:19
12/10/14 14:26
WG504197
WG504169-02
PE-ICP2
Blank File ID:
Prep Date:
Analyzed Date:
Work Group:
Blank Sample ID:
Instrument ID:
6010BMethod:
KHRAnalyst:
L14120172Login Number:
LCS
40MW7GW12214
40EQR12214
40FB12214
40MW5GW12214
40DUPGW12214
40MW5MSGW12214
40MW5MSDGW12214
40MW6GW12214
LFMW01GW12214
40MW7GW12214
40MW5GW12214
40DUPGW12214
40MW5MSGW12214
40MW5MSDGW12214
LFMW01GW12214
WG504169-03
L14120172-02
L14120172-03
L14120172-04
L14120172-05
L14120172-06
L14120172-07
L14120172-08
L14120172-09
L14120172-10
L14120172-02
L14120172-05
L14120172-06
L14120172-07
L14120172-08
L14120172-10
P2.121014.143019
P2.121014.143245
P2.121014.143607
P2.121014.143928
P2.121014.144249
P2.121014.144610
P2.121014.150311
P2.121014.150537
P2.121014.150803
P2.121014.151536
P2.121114.102418
P2.121114.102740
P2.121114.103101
P2.121114.104008
P2.121114.104330
P2.121114.104651
12/10/14 14:30
12/10/14 14:32
12/10/14 14:36
12/10/14 14:39
12/10/14 14:42
12/10/14 14:46
12/10/14 15:03
12/10/14 15:05
12/10/14 15:08
12/10/14 15:15
12/11/14 10:24
12/11/14 10:27
12/11/14 10:31
12/11/14 10:40
12/11/14 10:43
12/11/14 10:46
This Method Blank Applies To The Following Samples:
Client ID Lab Sample ID Lab File ID Time Analyzed TAG
01
01
01
01
01
01
01
01
01
01
DL01
DL01
DL01
DL01
DL01
DL01
Page 74
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 267
Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLANK
PDF ID: 3912480
11-DEC-2014 08:50
Analytes Concentration Dilution Qualifier
Aluminum, Total
Calcium, Total
Iron, Total
Magnesium, Total
Potassium, Total
Sodium, Total
Vanadium, Total
1
1
1
1
1
1
1
0.100
0.250
0.0500
0.250
0.500
0.250
0.00500
0.200
0.500
0.100
0.500
1.00
0.500
0.0100
U
U
U
U
U
U
U
0.100
0.250
0.0500
0.250
0.500
0.250
0.00500
ND Analyte Not detected at or above reporting limit
* |Analyte concentration| > 1/2 RL
P2.121014.142656
WG504197
Instrument ID:PE-ICP2
File ID:
Prep Date:12/10/14 09:19
Run Date:12/10/14 14:26
Analyst:KHR
Workgroup (AAB#): mg/LUnits:
6010BMethod:
WaterMatrix:
L14120172Login Number: WG504169-02Sample ID:
10-DEC-14Cal ID:PE-ICP-Contract #:
3015Prep Method:
LOD LOQ
LOD
LOQ
Method Detection Limit
Reporting/Practical Quantitation Limit
Page 75
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Page 268
LCS - Modified 03/06/2008
12/11/2014 08:50Report generated:3912481PDF File ID:
LABORATORY CONTROL SAMPLE (LCS)
Microbac Laboratories Inc.
P2.121014.143019
WG504197
Instrument ID:PE-ICP2
File ID:
Run Date:12/10/2014
Run Time:14:30
Analyst:KHR
Workgroup (AAB#): mg/LUnits:
3015Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found LCS Limits Q% Rec
WG504169-03Sample ID:
10-DEC-14Cal ID:PE-ICP-DOD4QC Key:
Aluminum, Total
Calcium, Total
Iron, Total
Magnesium, Total
Potassium, Total
Sodium, Total
Vanadium, Total
80
80
80
80
80
80
80
6.25
6.25
2.50
6.25
31.3
31.3
0.625
6.17
6.26
2.56
6.38
29.5
29.5
0.637
98.7
100
103
102
94.3
94.3
102
-
-
-
-
-
-
-
120
120
120
120
120
120
120
6010BMethod:
Lot#:STD67718
Page 76
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Page 269
MS_MSD - Modified 03/06/2008
12/11/2014 12:43Report generated3912482PDF File ID:
Microbac Laboratories Inc.
MS/MSD REPORT
L14120172Loginnum:
WaterMatrix:
Aluminum, Total
Iron, Total
Magnesium, Total
Potassium, Total
Sodium, Total
Vanadium, Total
AnalyteMS MSD
6.17 6.26
2.57 2.60
19.1 19.4
30.0 30.8
35.6 36.6
0.626 0.631
Found Found
0.256
0.155
13.2
0.764
6.58
U
6.25 6.25
2.50 2.50
6.25 6.25
31.3 31.3
31.3 31.3
0.625 0.625
94.7 96.1
96.7 97.6
94.4 99.3
93.7 96.1
93 96.2
100 101
1.40
0.916
1.58
2.48
2.77
0.858
MS MSDMS MSD
Spiked Spiked%Rec %Rec
80
80
80
80
80
80
-
-
-
-
-
-
120
120
120
120
120
120
20
20
20
20
20
20
%RPDParent%RecLimits
RPDLimit Q
Instrument ID:PE-ICP2
Parent ID:L14120172-05
Sample ID:
Sample ID:
L14120172-07
L14120172-08
MS
MSD
Method:6010B
Units:mg/L
Contract #:
Cal ID: PE-ICP2- 10-DEC-14 WG504197Worknum:
P2.121014.144249
P2.121014.150311
P2.121014.150537
File ID:
File ID:
File ID:
Dil:
Dil:
1
1
Dil:1
Prep Method:3015
* FAILS %REC LIMIT
# FAILS RPD LIMIT
Page 77
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Page 270
MS_MSD - Modified 03/06/2008
12/11/2014 12:43Report generated3912482PDF File ID:
Microbac Laboratories Inc.
MS/MSD REPORT
L14120172Loginnum:
WaterMatrix:
Calcium, Total
AnalyteMS MSD
50.0 51.3
Found Found
41.4 6.25 6.25138 159 2.54
MS MSDMS MSD
Spiked Spiked%Rec %Rec
80 - 120 20 *
%RPDParent%RecLimits
RPDLimit Q
Instrument ID:PE-ICP2
Parent ID:L14120172-05
Sample ID:
Sample ID:
L14120172-07
L14120172-08
MS
MSD
Method:6010B
Units:mg/L
Contract #:
Cal ID: PE-ICP2- 11-DEC-14 WG504197Worknum:
P2.121114.102740
P2.121114.104008
P2.121114.104330
File ID:
File ID:
File ID:
Dil:
Dil:
10
10
Dil:10
Prep Method:3015
* FAILS %REC LIMIT
# FAILS RPD LIMIT
Page 78
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 271
12/15/2014 14:09Report generated3914978PDF File ID:
Microbac Laboratories Inc.
METHOD BLANK SUMMARY
Report Name: BLANK_SUMMARY
NI.121514.124417
12/10/14 07:25
12/15/14 12:44
WG504176
WG504133-03
ICP-MS2
Blank File ID:
Prep Date:
Analyzed Date:
Work Group:
Blank Sample ID:
Instrument ID:
6020Method:
JYHAnalyst:
L14120172Login Number:
LCS
DUP
LCS
LCS
40MW5GW12214
40MW5MSGW12214
40MW5MSDGW12214
40MW7GW12214
40EQR12214
40FB12214
40DUPGW12214
40MW6GW12214
LFMW01GW12214
WG504133-04
WG504133-07
WG504133-04
WG504133-04
L14120172-05
L14120172-07
L14120172-08
L14120172-02
L14120172-03
L14120172-04
L14120172-06
L14120172-09
L14120172-10
NI.121114.130334
NI.121114.140005
NI.121214.121018
NI.121514.124725
NI.121514.125033
NI.121514.125341
NI.121514.125649
NI.121514.125957
NI.121514.130305
NI.121514.132157
NI.121514.132506
NI.121514.132814
NI.121514.133122
12/11/14 13:03
12/11/14 14:00
12/12/14 12:10
12/15/14 12:47
12/15/14 12:50
12/15/14 12:53
12/15/14 12:56
12/15/14 12:59
12/15/14 13:03
12/15/14 13:21
12/15/14 13:25
12/15/14 13:28
12/15/14 13:31
This Method Blank Applies To The Following Samples:
Client ID Lab Sample ID Lab File ID Time Analyzed TAG
01
01
02
03
03
03
03
03
03
03
02
03
03
Page 79
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Page 272
Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLANK
PDF ID: 3914979
15-DEC-2014 14:09
Analytes Concentration Dilution Qualifier
Arsenic, Total
Barium, Total
Cobalt, Total
Lead, Total
Manganese, Total
Selenium, Total
1
1
1
1
1
1
0.000500
0.00150
0.000500
0.000500
0.00100
0.000500
0.00100
0.00300
0.00100
0.00100
0.00200
0.00100
U
U
U
U
U
U
0.000500
0.00150
0.000500
0.000500
0.00100
0.000500
ND Analyte Not detected at or above reporting limit
* |Analyte concentration| > 1/2 RL
NI.121514.124417
WG504176
Instrument ID:ICP-MS2
File ID:
Prep Date:12/10/14 07:25
Run Date:12/15/14 12:44
Analyst:JYH
Workgroup (AAB#): mg/LUnits:
6020Method:
WaterMatrix:
L14120172Login Number: WG504133-03Sample ID:
15-DEC-14Cal ID:ICP-MS-Contract #:
3015Prep Method:
LOD LOQ
LOD
LOQ
Method Detection Limit
Reporting/Practical Quantitation Limit
Page 80
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 273
LCS - Modified 03/06/2008
12/15/2014 14:09Report generated:3914980PDF File ID:
LABORATORY CONTROL SAMPLE (LCS)
Microbac Laboratories Inc.
NI.121514.124725
WG504176
Instrument ID:ICP-MS2
File ID:
Run Date:12/15/2014
Run Time:12:47
Analyst:JYH
Workgroup (AAB#): mg/LUnits:
3015Prep Method:
WaterMatrix:
L14120172Login Number:
Analytes Expected Found LCS Limits Q% Rec
WG504133-04Sample ID:
15-DEC-14Cal ID:ICP-MS-DOD4QC Key:
Arsenic, Total
Barium, Total
Cobalt, Total
Lead, Total
Manganese, Total
Selenium, Total
80
80
80
80
80
80
0.0625
0.0625
0.0625
0.0625
0.0625
0.0625
0.0680
0.0663
0.0673
0.0685
0.0682
0.0690
109
106
108
110
109
110
-
-
-
-
-
-
120
120
120
120
120
120
6020Method:
Lot#:STD65967
Page 81
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Page 274
MS_MSD - Modified 03/06/2008
12/15/2014 14:09Report generated3915559PDF File ID:
Microbac Laboratories Inc.
MS/MSD REPORT
L14120172Loginnum:
WaterMatrix:
Arsenic, Total
Barium, Total
Cobalt, Total
Lead, Total
Manganese, Total
Selenium, Total
AnalyteMS MSD
0.0666 0.0669
0.0897 0.101
0.0646 0.0657
0.0662 0.0658
0.0650 0.0661
0.0675 0.0680
Found Found
U
0.0240
U
U
U
U
0.0625 0.0625
0.0625 0.0625
0.0625 0.0625
0.0625 0.0625
0.0625 0.0625
0.0625 0.0625
107 107
105 123
103 105
106 105
104 106
108 109
0.363
11.4
1.71
0.625
1.71
0.693
MS MSDMS MSD
Spiked Spiked%Rec %Rec
80
80
80
80
80
80
-
-
-
-
-
-
120
120
120
120
120
120
20
20
20
20
20
20
*
%RPDParent%RecLimits
RPDLimit Q
Instrument ID:ICP-MS2
Parent ID:L14120172-05
Sample ID:
Sample ID:
L14120172-07
L14120172-08
MS
MSD
Method:6020
Units:mg/L
Contract #:
Cal ID: ICP-MS2- 15-DEC-14 WG504176Worknum:
NI.121514.125033
NI.121514.125341
NI.121514.125649
File ID:
File ID:
File ID:
Dil:
Dil:
1
1
Dil:1
Prep Method:3015
* FAILS %REC LIMIT
# FAILS RPD LIMIT
Page 82
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 275
Microbac Laboratories Inc.Ohio Valley Division Analyst List
January 22, 2015
001 - BIO-CHEM TESTING WVDEP 220 002 - REIC Consultants, Inc. WVDEP 060003 - Sturm Environmental 004 - MICROBAC PITTSBURGH005 - ES LABORATORIES 006 - ALCOSAN LABORATORIES007 - ALS LABORATORIES 008 - BENCHMARK LABORATORIES010 - MICROBAC CHICAGOLAND ADC - ANTHONY D. CANTERADG - APRIL D. GREENE AED - ALLEN E. DAVISALS - ADRIANE L. STEED AWE - ANDREW W. ESSIGAZH - AFTER HOURS BJO - BRIAN J. OGDENBKT - BRENDAN TORRENCE BLG - BRENDA L. GREENWALTBRG - BRENDA R. GREGORY CAA - CASSIE A. AUGENSTEINCAF - CHERYL A. FLOWERS CEB - CHAD E. BARNESCJR - COURTNEY J. REXROAD CLC - CHRYS L. CRAWFORDCLS - CARA L. STRICKLER CLW - CHARISSA L. WINTERSCPD - CHAD P. DAVIS CSH - CHRIS S. HILLDAK - DEAN A. KETELSEN DCM - DAVID C. MERCKLEDEV - DAVID E. VANDENBERG DIH - DEANNA I. HESSONDLB - DAVID L. BUMGARNER DLP - DOROTHY L. PAYNEDSM - DAVID S. MOSSOR ECL - ERIC C. LAWSONENY - EMILY N. YOAK EPT - ETHAN P. TIDDERP - ERIN R. PORTER FJB - FRANCES J. BOLDENJBK - JEREMY B. KINNEY JDH - JUSTIN D. HESSONJDS - JARED D. SMITH JJS - JOHN J. STE MARIEJKP - JACQUELINE K. PARSONS JLL - JOHN L. LENTJMW - JEANA M. WHITE JTP - JOSHUA T. PEMBERTONJWR - JOHN W. RICHARDS JWS - JACK W. SHEAVESJYH - JI Y. HU KAJ - KELLIE A. JOHNSONKAT - KATHY A. TUCKER KDW - KATHRYN D. WELCHKEB - KATIE E. BARNES KHR - KIM H. RHODESKRA - KATHY R. ALBERTSON KRB - KAELY R. BECKERKRP - KATHY R. PARSONS LEC - LAURA E. CARPENTERLKN - LINDA K. NEDEFF LLS - LARRY L. STEPHENSLSB - LESLIE S. BUCINA MBK - MORGAN B. KNOWLTONMDA - MIKE D. ALBERTSON MDC - MIKE D. COCHRANMES - MARY E. SCHILLING MLB - MEGAN L. BACHEMMB - MAREN M. BEERY MRT - MICHELLE R. TAYLORMSW - MATT S. WILSON PDM - PIERCE D. MORRISPIT - MICROBAC WARRENDALE PRL - PAIGE R. LAMBPSW - PEGGY S. WEBB QX - QIN XURAH - ROY A. HALSTEAD REK - BOB E. KYERRLB - BOB BUCHANAN RM - RAYMOND MALEKERNP - RICK N. PETTY SAV - SARAH A. VANDENBERGSDC - SHALYN D. CONLEY SLM - STEPHANIE L. MOSSBURGSLP - SHERI L. PFALZGRAF TB - TODD BOYLETMB - TIFFANY M. BAILEY TMM - TAMMY M. MORRISVC - VICKI COLLIER WJB - WILL J. BEASLEYWRR - WESLEY R. RICHARDS WTD - WADE T. DELONGXXX - UNAVAILABLE OR SUBCONTRACT
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L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 276
List of Valid QualifiersJanuary 22, 2015
Qualkey: DOD
Microbac Laboratories Inc.
Qualifier Description
*+<>AB
B1B3B4C
CGCT1DLE
EDLEMPCF, S
F,CT1FLH1
H1,CT1IJJJJ
J,BJ,CT1J,CT1J,H1J,H1J,PJ,SJBJQLL1L2MN
NAND
ND, BND, CT1
ND, LND, SND,H1
ND,H1,CT1NFNFLNINRNSPQ
Q,H1QNSRARES
SMISPTIC
TNTCTNTC, B
TNTC,CT1TNTC,H1
Surrogate or spike compound out of rangeCorrelation coefficient for the MSA is less than 0.995Result is less than the associated numerical value.Greater thanSee the report narrativeThe reported result is associated with a contaminated method blank.Target analyte detected in method blank at or above the method reporting limitTarget analyte detected in calibration blank at or above the method reporting limitThe BOD unseeded dilution water blank exceeded 0.2 mg/LConfirmed by GC/MSConfluent growthThe cooler temperature at receipt exceeded regulatory guidelines for requested testing.Surrogate or spike compound was diluted outEstimated concentration due to sample matrix interferenceElevated sample reporting limits, presence of non-target analytesEstimated Maximum Possible ConcentrationEstimated result below quantitation limit; method of standard additions(MSA)Estimated value; the analyte concentration was less than the RL/LOQ. The cooler temperature at receipt exceeded regulaFree LiquidSample analysis performed past holding time.Sample analysis performed past holding time. The cooler temperature at receipt exceeded regulatory guidelines for requeSemiquantitative result (out of instrument calibration range)Estimated concentration; sample matrix interference.Estimated value ; the analyte concentration was greater than the highest standardEstimated value ; the analyte concentration was less than the LOQ.The reported result is an estimated value.Analyte detected in both the method blank and sample above the MDL.Estimated value; the analyte concentration was less than the RL/LOQ.Estimated value; the analyte concentration was less than the RL/LOQ. The cooler temperature at receipt exceeded regulaEstimated value ; the analyte concentration was less than the LOQ. Sample analysis performed past holding time.The reported result is an estimated value. Sample was analyzed past holding time.Estimate; columns don't agree to within 40%Estimated concentration; analyzed by method of standard addition (MSA)The reported result is an estimated value. The reported result is also associated with a contaminated method blank.The reported result is an estimated value and one or more quality control criteria failed. See narrative.Sample reporting limits elevated due to matrix interferenceThe associated blank spike (LCS) recovery was above the laboratory acceptance limits.The associated blank spike (LCS) recovery was below the laboratory acceptance limits.Matrix effect; the concentration is an estimate due to matrix effect.Nontarget analyte; the analyte is a tentativlely identified compound (TIC) by GC/MSNot applicableNot detected at or above the reporting limit (RL/MDL).Not detected at or above the reporting limit (RL). Analyte present in method blank.Analyte was not detected. The concentration is below the reported LOD. The cooler temperature at receipt exceeded regNot detected; sample reporting limit (RL) elevated due to interferenceNot detected; analyzed by method of standard addition (MSA)Not detected; Sample analysis performed past holding time.Not detected; Sample analysis performed past holding time. The cooler temperature at receipt exceeded regulatory guideNot found by library searchNo free liquidNon-ignitableAnalyte is not required to be analyzedNot spikedConcentrations >40% difference between the two GC columnsOne or more quality control criteria failed. See narrative.One or more quality control criteria failed. Sample analyzed past holding time. See narrative.Quantity of sample not sufficient to perform analysisReanalysis confirms reported resultsReanalysis confirms sample matrix interferenceAnalyzed by method of standard addition (MSA)Sample matrix interference on surrogateReported results are for spike compounds onlyLibrary Search CompoundToo numerous to countToo numerous to count. Analyte present in method blank.Too numerous to count. The cooler temperature at receipt exceeded regulatory guidelines for requested testing.Too numerous to count. Sample analysis performed past holding time.
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L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 277
List of Valid QualifiersJanuary 22, 2015
Qualkey: DOD
Microbac Laboratories Inc.
UU,H1UJUQWX
X, SZ
Analyte was not detected. The concentration is below the reported LOD.Not detected; Sample analysis performed past holding time.Undetected; the MDL and RL are estimated due to quality control discrepancies.Undetected; the analyte was analyzed for, but not detected.Post-digestion spike for furnace AA out of control limitsExceeds regulatory limitExceeds regulatory limit; method of standard additions (MSA)Cannot be resolved from isomer - see below
Page 85
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Page 278
Page 86
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 279
Internal Chain of Custody Report
Login:
Account:
Project:
Samples:
Due Date:
L14120172
2820
2820.216
10
12-DEC-2014
A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login
Microbac Laboratories Inc.
L14120172-01
L14120172-02
L14120172-02
484964
484965
484966
Samplenum
Samplenum
Samplenum
Container ID
Container ID
Container ID
1
2
1
2
3
1
Bottle:
Bottle:
Bottle:
Bottle:
Bottle:
Bottle:
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
W1
SEM
V1
ORG4
A2
V1
ORG4
A2
V1
ORG4
A2
V1
ORG4
A2
V1
ORG4
A2
W1
SEM
A2
03-DEC-2014 14:32
03-DEC-2014 15:31
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:31
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:31
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:31
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:31
18-DEC-2014 08:24
03-DEC-2014 14:32
10-DEC-2014 11:34
12-DEC-2014 11:39
CLS
TMB
CLS
CLS
TMB
CLS
CLS
TMB
CLS
CLS
TMB
CLS
CLS
TMB
CLS
CLS
ADC
CLS
CLS
AWE
CLS
AWE
CLS
AWE
CLS
AWE
CLS
AWE
CLS
ADC
Seq.
Seq.
Seq.
Seq.
Seq.
Seq.
Purpose
Purpose
Purpose
Purpose
Purpose
Purpose
From
From
From
From
From
From
To
To
To
To
To
To
Date/Time
Date/Time
Date/Time
Date/Time
Date/Time
Date/Time
Accept
Accept
Accept
Accept
Accept
Accept
Relinquish
Relinquish
Relinquish
Relinquish
Relinquish
Relinquish
Products
Products
Products
826-SPE
826-SPE
6850
NA
NA
NA
NA
NA
pH
pH
pH
pH
pH
pH
Page 87
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 280
Internal Chain of Custody Report
Login:
Account:
Project:
Samples:
Due Date:
L14120172
2820
2820.216
10
12-DEC-2014
A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login
Microbac Laboratories Inc.
L14120172-02
L14120172-03
484967
484968
Samplenum
Samplenum
Container ID
Container ID
1
1
2
3
Bottle:
Bottle:
Bottle:
Bottle:
1
2
3
4
1
5
6
1
2
3
1
2
3
LOGIN
PREP
ANALYZ*
STORE
LOGIN
STORE
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
COOLER
W1
DIG
DIG
COOLER
A1
A1
COOLER
V1
ORG4
COOLER
V1
ORG4
W1
DIG
METALS
A2
BUILDIN
BUILDIN
V1
ORG4
A2
V1
ORG4
A2
03-DEC-2014 14:32
05-DEC-2014 09:57
10-DEC-2014 09:35
10-DEC-2014 15:28
03-DEC-2014 14:32
08-MAR-2010 13:13
08-MAR-2010 13:13
03-DEC-2014 14:32
03-DEC-2014 15:31
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:31
18-DEC-2014 08:24
CLS
VC
PDM
CLS
CLS
RB
RB
CLS
TMB
CLS
CLS
TMB
CLS
BRG
VC
ERP
RB
RB
CLS
AWE
CLS
AWE
Seq.
Seq.
Seq.
Seq.
Purpose
Purpose
Purpose
Purpose
From
From
From
From
To
To
To
To
Date/Time
Date/Time
Date/Time
Date/Time
Accept
Accept
Accept
Accept
Relinquish
Relinquish
Relinquish
Relinquish
Products
Products
CA CO-MS FE K MG MN-MS NA PB-MS SE-MS V AL AS-
826-SPE
AUTO-ICOC
AUTO-ICOC
Comments:
Comments:
Sample number changed:
Sample number changed:
L08070621-17
L08070621-17
*Sample extract/digestate/leachate
NA
NA
NA
pH
pH
pH
pH
Page 88
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 281
Internal Chain of Custody Report
Login:
Account:
Project:
Samples:
Due Date:
L14120172
2820
2820.216
10
12-DEC-2014
A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login
Microbac Laboratories Inc.
L14120172-03
L14120172-03
484969
484970
Samplenum
Samplenum
Container ID
Container ID
1
1
Bottle:
Bottle:
1
5
6
1
5
6
LOGIN
STORE
STORE
LOGIN
STORE
STORE
COOLER
A1
A1
COOLER
A1
A1
W1
BUILDIN
BUILDIN
W1
BUILDIN
BUILDIN
03-DEC-2014 14:32
08-MAR-2010 13:13
08-MAR-2010 13:13
03-DEC-2014 14:32
08-MAR-2010 13:13
08-MAR-2010 13:13
CLS
RB
RB
CLS
RB
RB
RB
RB
RB
RB
Seq.
Seq.
Purpose
Purpose
From
From
To
To
Date/Time
Date/Time
Accept
Accept
Relinquish
Relinquish
Products
Products
6850
AL AS-MS BA-MS CA CO-MS FE K MG MN-MS NA PB-MS
AUTO-ICOC
AUTO-ICOC
AUTO-ICOC
AUTO-ICOC
Comments:
Comments:
Comments:
Comments:
Sample number changed:
Sample number changed:
Sample number changed:
Sample number changed:
L08070621-18
L08070621-18
L08070621-19
L08070621-19
pH
pH
Page 89
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 282
Internal Chain of Custody Report
Login:
Account:
Project:
Samples:
Due Date:
L14120172
2820
2820.216
10
12-DEC-2014
A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login
Microbac Laboratories Inc.
L14120172-04
L14120172-04
L14120172-04
484971
484972
484973
Samplenum
Samplenum
Samplenum
Container ID
Container ID
Container ID
1
2
3
1
1
Bottle:
Bottle:
Bottle:
Bottle:
Bottle:
1
5
6
1
2
3
1
2
3
1
2
3
1
2
3
4
LOGIN
STORE
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
PREP
ANALYZ*
STORE
COOLER
A1
A1
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
W1
SEM
COOLER
W1
DIG
DIG
BUILDIN
BUILDIN
V1
ORG4
A2
V1
ORG4
A2
W1
SEM
A2
W1
DIG
METALS
A2
03-DEC-2014 14:32
08-MAR-2010 13:13
08-MAR-2010 13:13
03-DEC-2014 14:32
03-DEC-2014 15:31
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:31
18-DEC-2014 08:24
03-DEC-2014 14:32
10-DEC-2014 11:34
12-DEC-2014 11:39
03-DEC-2014 14:32
05-DEC-2014 09:57
10-DEC-2014 09:35
10-DEC-2014 15:28
CLS
RB
RB
CLS
TMB
CLS
CLS
TMB
CLS
CLS
ADC
CLS
CLS
VC
PDM
CLS
RB
RB
CLS
AWE
CLS
AWE
CLS
ADC
BRG
VC
ERP
Seq.
Seq.
Seq.
Seq.
Seq.
Purpose
Purpose
Purpose
Purpose
Purpose
From
From
From
From
From
To
To
To
To
To
Date/Time
Date/Time
Date/Time
Date/Time
Date/Time
Accept
Accept
Accept
Accept
Accept
Relinquish
Relinquish
Relinquish
Relinquish
Relinquish
Products
Products
Products
826-SPE
6850
AL AS-MS BA-MS CA CO-MS FE K MG MN-MS NA PB-MS
AUTO-ICOC
AUTO-ICOC
Comments:
Comments:
Sample number changed:
Sample number changed:
L08070621-20
L08070621-20
*Sample extract/digestate/leachate
NA
NA
NA
pH
pH
pH
pH
pH
Page 90
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 283
Internal Chain of Custody Report
Login:
Account:
Project:
Samples:
Due Date:
L14120172
2820
2820.216
10
12-DEC-2014
A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login
Microbac Laboratories Inc.
L14120172-05
L14120172-05
L14120172-05
484974
484975
484976
Samplenum
Samplenum
Samplenum
Container ID
Container ID
Container ID
1
2
3
1
1
Bottle:
Bottle:
Bottle:
Bottle:
Bottle:
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
4
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
PREP
ANALYZ*
STORE
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
W1
SEM
COOLER
W1
DIG
DIG
V1
ORG4
A2
V1
ORG4
A2
V1
ORG4
A2
W1
SEM
A2
W1
DIG
METALS
A2
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
10-DEC-2014 11:34
12-DEC-2014 11:39
03-DEC-2014 14:32
05-DEC-2014 09:57
10-DEC-2014 09:35
10-DEC-2014 15:28
CLS
TMB
CLS
CLS
TMB
CLS
CLS
TMB
CLS
CLS
ADC
CLS
CLS
VC
PDM
CLS
CLS
AWE
CLS
AWE
CLS
AWE
CLS
ADC
BRG
VC
ERP
Seq.
Seq.
Seq.
Seq.
Seq.
Purpose
Purpose
Purpose
Purpose
Purpose
From
From
From
From
From
To
To
To
To
To
Date/Time
Date/Time
Date/Time
Date/Time
Date/Time
Accept
Accept
Accept
Accept
Accept
Relinquish
Relinquish
Relinquish
Relinquish
Relinquish
Products
Products
Products
826-SPE
6850
AL AS-MS BA-MS CA CO-MS FE K MG MN-MS NA PB-MS
*Sample extract/digestate/leachate
NA
NA
NA
pH
pH
pH
pH
pH
Page 91
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 284
Internal Chain of Custody Report
Login:
Account:
Project:
Samples:
Due Date:
L14120172
2820
2820.216
10
12-DEC-2014
A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login
Microbac Laboratories Inc.
L14120172-06
L14120172-06
484977
484978
Samplenum
Samplenum
Container ID
Container ID
1
2
3
1
Bottle:
Bottle:
Bottle:
Bottle:
1
2
3
1
2
3
1
2
3
1
5
6
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
STORE
STORE
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
A1
A1
V1
ORG4
A2
V1
ORG4
A2
V1
ORG4
A2
W1
BUILDIN
BUILDIN
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
08-MAR-2010 13:13
08-MAR-2010 13:13
CLS
TMB
CLS
CLS
TMB
CLS
CLS
TMB
CLS
CLS
RB
RB
CLS
AWE
CLS
AWE
CLS
AWE
RB
RB
Seq.
Seq.
Seq.
Seq.
Purpose
Purpose
Purpose
Purpose
From
From
From
From
To
To
To
To
Date/Time
Date/Time
Date/Time
Date/Time
Accept
Accept
Accept
Accept
Relinquish
Relinquish
Relinquish
Relinquish
Products
Products
826-SPE
6850
AUTO-ICOC
AUTO-ICOC
Comments:
Comments:
Sample number changed:
Sample number changed:
L08070621-27
L08070621-27
NA
NA
NA
pH
pH
pH
pH
Page 92
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 285
Internal Chain of Custody Report
Login:
Account:
Project:
Samples:
Due Date:
L14120172
2820
2820.216
10
12-DEC-2014
A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login
Microbac Laboratories Inc.
L14120172-06
L14120172-07
484979
484980
Samplenum
Samplenum
Container ID
Container ID
1
1
2
3
Bottle:
Bottle:
Bottle:
Bottle:
1
5
6
1
5
6
1
2
3
1
2
3
LOGIN
STORE
STORE
LOGIN
STORE
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
COOLER
A1
A1
COOLER
A1
A1
COOLER
V1
ORG4
COOLER
V1
ORG4
W1
BUILDIN
BUILDIN
BUILDIN
BUILDIN
V1
ORG4
A2
V1
ORG4
A2
03-DEC-2014 14:32
08-MAR-2010 13:13
08-MAR-2010 13:13
03-DEC-2014 14:32
08-MAR-2010 13:13
08-MAR-2010 13:13
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
CLS
RB
RB
CLS
RB
RB
CLS
TMB
CLS
CLS
TMB
CLS
RB
RB
RB
RB
CLS
AWE
CLS
AWE
Seq.
Seq.
Seq.
Seq.
Purpose
Purpose
Purpose
Purpose
From
From
From
From
To
To
To
To
Date/Time
Date/Time
Date/Time
Date/Time
Accept
Accept
Accept
Accept
Relinquish
Relinquish
Relinquish
Relinquish
Products
Products
AL AS-MS BA-MS CA CO-MS FE K MG MN-MS NA PB-MS
826-SPE
AUTO-ICOC
AUTO-ICOC
AUTO-ICOC
AUTO-ICOC
Comments:
Comments:
Comments:
Comments:
Sample number changed:
Sample number changed:
Sample number changed:
Sample number changed:
L08070621-28
L08070621-28
L08070621-29
L08070621-29
NA
NA
NA
pH
pH
pH
pH
Page 93
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 286
Internal Chain of Custody Report
Login:
Account:
Project:
Samples:
Due Date:
L14120172
2820
2820.216
10
12-DEC-2014
A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login
Microbac Laboratories Inc.
L14120172-07
L14120172-07
L14120172-08
484981
484982
484983
Samplenum
Samplenum
Samplenum
Container ID
Container ID
Container ID
1
1
1
2
3
Bottle:
Bottle:
Bottle:
Bottle:
Bottle:
1
5
6
1
1
2
3
1
2
3
1
2
3
LOGIN
STORE
STORE
LOGIN
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
COOLER
A1
A1
COOLER
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
V1
ORG4
W1
BUILDIN
BUILDIN
W1
V1
ORG4
A2
V1
ORG4
A2
V1
ORG4
A2
03-DEC-2014 14:32
08-MAR-2010 13:13
08-MAR-2010 13:13
03-DEC-2014 14:32
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
CLS
RB
RB
CLS
CLS
TMB
CLS
CLS
TMB
CLS
CLS
TMB
CLS
RB
RB
CLS
AWE
CLS
AWE
CLS
AWE
Seq.
Seq.
Seq.
Seq.
Seq.
Purpose
Purpose
Purpose
Purpose
Purpose
From
From
From
From
From
To
To
To
To
To
Date/Time
Date/Time
Date/Time
Date/Time
Date/Time
Accept
Accept
Accept
Accept
Accept
Relinquish
Relinquish
Relinquish
Relinquish
Relinquish
Products
Products
Products
6850
AL AS-MS BA-MS CA CO-MS FE K MG MN-MS NA PB-MS
826-SPE
AUTO-ICOC
AUTO-ICOC
Comments:
Comments:
Sample number changed:
Sample number changed:
L08070621-30
L08070621-30
NA
NA
NA
pH
pH
pH
pH
pH
Page 94
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 287
Internal Chain of Custody Report
Login:
Account:
Project:
Samples:
Due Date:
L14120172
2820
2820.216
10
12-DEC-2014
A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login
Microbac Laboratories Inc.
L14120172-08
L14120172-08
L14120172-09
484984
484985
484986
Samplenum
Samplenum
Samplenum
Container ID
Container ID
Container ID
1
1
1
2
3
Bottle:
Bottle:
Bottle:
Bottle:
Bottle:
1
2
3
1
2
3
4
1
2
3
1
2
3
1
2
3
LOGIN
ANALYZ
STORE
LOGIN
PREP
ANALYZ*
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
COOLER
W1
SEM
COOLER
W1
DIG
DIG
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
V1
ORG4
W1
SEM
A2
W1
DIG
METALS
A2
V1
ORG4
A2
V1
ORG4
A2
V1
ORG4
A2
03-DEC-2014 14:32
10-DEC-2014 11:34
12-DEC-2014 11:39
03-DEC-2014 14:32
05-DEC-2014 09:57
10-DEC-2014 09:35
10-DEC-2014 15:28
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
CLS
ADC
CLS
CLS
VC
PDM
CLS
CLS
TMB
CLS
CLS
TMB
CLS
CLS
TMB
CLS
CLS
ADC
BRG
VC
ERP
CLS
AWE
CLS
AWE
CLS
AWE
Seq.
Seq.
Seq.
Seq.
Seq.
Purpose
Purpose
Purpose
Purpose
Purpose
From
From
From
From
From
To
To
To
To
To
Date/Time
Date/Time
Date/Time
Date/Time
Date/Time
Accept
Accept
Accept
Accept
Accept
Relinquish
Relinquish
Relinquish
Relinquish
Relinquish
Products
Products
Products
6850
AL AS-MS BA-MS CA CO-MS FE K MG MN-MS NA PB-MS
826-SPE
*Sample extract/digestate/leachate
NA
NA
NA
pH
pH
pH
pH
pH
Page 95
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 288
Internal Chain of Custody Report
Login:
Account:
Project:
Samples:
Due Date:
L14120172
2820
2820.216
10
12-DEC-2014
A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login
Microbac Laboratories Inc.
L14120172-09
L14120172-09
484987
484988
Samplenum
Samplenum
Container ID
Container ID
1
1
Bottle:
Bottle:
1
2
3
1
5
6
LOGIN
ANALYZ
STORE
LOGIN
STORE
STORE
COOLER
W1
SEM
COOLER
A1
A1
W1
SEM
A2
W1
BUILDIN
BUILDIN
03-DEC-2014 14:32
10-DEC-2014 11:33
12-DEC-2014 11:39
03-DEC-2014 14:32
08-MAR-2010 13:13
08-MAR-2010 13:13
CLS
ADC
CLS
CLS
RB
RB
CLS
ADC
RB
RB
Seq.
Seq.
Purpose
Purpose
From
From
To
To
Date/Time
Date/Time
Accept
Accept
Relinquish
Relinquish
Products
Products
6850
AL AS-MS BA-MS CA CO-MS FE K MG MN-MS NA PB-MS
AUTO-ICOC
AUTO-ICOC
Comments:
Comments:
Sample number changed:
Sample number changed:
L08070621-37
L08070621-37
pH
pH
Page 96
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 289
Internal Chain of Custody Report
Login:
Account:
Project:
Samples:
Due Date:
L14120172
2820
2820.216
10
12-DEC-2014
A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login
Microbac Laboratories Inc.
L14120172-10
L14120172-10
L14120172-10
484989
484990
484991
Samplenum
Samplenum
Samplenum
Container ID
Container ID
Container ID
1
2
3
1
1
Bottle:
Bottle:
Bottle:
Bottle:
Bottle:
1
5
6
1
2
3
1
2
3
1
2
3
1
2
3
4
LOGIN
STORE
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
ANALYZ
STORE
LOGIN
PREP
ANALYZ*
STORE
COOLER
A1
A1
COOLER
V1
ORG4
COOLER
V1
ORG4
COOLER
W1
SEM
COOLER
W1
DIG
DIG
BUILDIN
BUILDIN
V1
ORG4
A2
V1
ORG4
A2
W1
SEM
A2
W1
DIG
METALS
A2
03-DEC-2014 14:32
08-MAR-2010 13:13
08-MAR-2010 13:13
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
03-DEC-2014 15:32
18-DEC-2014 08:24
03-DEC-2014 14:32
10-DEC-2014 11:34
12-DEC-2014 11:39
03-DEC-2014 14:32
05-DEC-2014 09:57
10-DEC-2014 09:35
10-DEC-2014 15:28
CLS
RB
RB
CLS
TMB
CLS
CLS
TMB
CLS
CLS
ADC
CLS
CLS
VC
PDM
CLS
RB
RB
CLS
AWE
CLS
AWE
CLS
ADC
BRG
VC
ERP
Seq.
Seq.
Seq.
Seq.
Seq.
Purpose
Purpose
Purpose
Purpose
Purpose
From
From
From
From
From
To
To
To
To
To
Date/Time
Date/Time
Date/Time
Date/Time
Date/Time
Accept
Accept
Accept
Accept
Accept
Relinquish
Relinquish
Relinquish
Relinquish
Relinquish
Products
Products
Products
826-SPE
6850
AL AS-MS BA-MS CA CO-MS FE K MG MN-MS NA PB-MS
AUTO-ICOC
AUTO-ICOC
Comments:
Comments:
Sample number changed:
Sample number changed:
L08070621-38
L08070621-38
*Sample extract/digestate/leachate
NA
NA
NA
pH
pH
pH
pH
pH
Page 97
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 290
NELAP Addendum - May 22, 2014 Non-NELAP LIMS Product and Description The following is a list of those tests that are not included in the Microbac – OVL NELAP Scope of Accreditation: Heat of Combustion (BTU) Total Halide by Bomb Combustion (TX) Particle Sizing - 200 Mesh (PS200) Specific Gravity/Density (SPGRAV) Total Residual Chlorine (CL-TRL) Total Volatile Solids (all forms) (TVS) Total Coliform Bacteria (all methods) Fecal Coliform Bacteria (all methods) Sulfite (SO3) Thiodiglycol (TDG-LCMS) Acetate (HPLC-UV) Formate (HPLC-UV) Acetaldehyde (HPLC-UV) Propionaldehyde (HPLC-UV) Fluoroborate (ISE) SOLID AND HAZARDOUS CHEMICALS Nitrogen, Ammonia by Method 350.1 Chromium, Hexavalent, Leachable by SM3500 Cr-B 2009 Phenolics, Total by Method 420.1 NELAP Accreditation by Laboratory SOP NONPOTABLE WATER OVL HPLC02/HPLC-UV Nitroglycerin Acetic acid Butyric acid Lactic acid Propionic acid Pyruvic acid OVL MSS01/GC-MS 1,4-Phenylenediamine 1-Methylnaphthalene 1,4-Dioxane Atrazine Benzaldehyde Biphenyl Caprolactam
Page 98
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 291
Hexamethylphosphoramide (HMPA) Pentachlorobenzene Pentachloroethane NELAP Accreditation by Laboratory SOP NONPOTABLE WATER OVL MSV0I/GC-MS 1, 1, 2-Trichloro-1,2,2-trifluoroethane 1,3-Butadiene Cyclohexane Cyclohexanone Dimethyl disulfide Dimethylsulfide Ethyl-t-butylether (ETBE) lsoprene Methylacetate Methylcyclohexane T-amylmethylether (TAME) Tetrahydrofuran (THF) OVL RSKOl/GC-FID lsobutane n-Butane Propane Propylene Propyne OVL HPLC07/HPLC-MS-MS Hexamethylphosphoramide (XMPA-LCMS) SOLID AND HAZARDOUS CHEMICALS OVL MSS0I/GC-MS 1-Methylnaphthalene Benzaldehyde Biphenyl Caprolactam Pentachloroethane NELAP Accreditation by Laboratory SOP
Page 99
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57
Page 292
SOLID AND HAZARDOUS CHEMICALS OVL MSV0I/GC-MS 1.3-Butadiene Cyclohexane Cyclohexanone Dimethyl disulfide Dimethylsulfide Ethyl-t-butylether (ETBE) lsoprene Methylacetate Methylcyclohexane n-Hexane T-amylmethylether (TAME)
Page 100
L14120172 / Revision: 1 / 100 total pages Generated: 01/22/2015 09:57