Steven L. Masia Sappi Fine Paper › content › events › 08nano › papers › 08nan53.pdf · Sappi: Nanotechnology and Sustainable Development “Development which meets the needs

Nanotechnologyand Forest products

Opportunity RoadmapSteven L. Masia

Sappi Fine Paper

Resources End Results: Sustainable Forest Products Productivity

ForestsForests

LigninLignin

HemicelluloseHemicellulose

CelluloseCellulose

FibreFibre

Other FibersOther FibersMaterialsMaterials

DissolvingDissolvingPulpPulp

SubstrateSubstrateSurfaceSurface

ModifiedModifiedSurfaceSurface

Paper Board

Printing

Coating

LandLandTreesTrees

Composites

POSITIVELY IMPACTING THE ENVIRONMENT

ForestsForests

LandLandTreesTrees

Time

LigninModification

CelluloseModification

Genetic and Mendel manipulation

Extraction of resins;oils; perfumes- Biomedicine

Markers

Cellulose andbiomass

SUSTAINABLE FOREST PRODUCTIVITY

Genetic Modification of trees

LigninLignin

HemicelluloseHemicellulose

Xylose from cellulose

Methane from cellulose

Hydrogen

Furfuralfrom cellulose

Fermentation & Distillation

Bioethanol

Electricity/energy

Steam

HydrolysisGlucose from cellulose

Sorbitol

Mannitol

Lactic Acid

Ammonia

Extraction

Nano Biological devices

ADVANCING THE FOREST BIOREFINERY

LigninLignin Adhesives with, or from cellulose

ThermochemicalPlatform

Syngas (H2 and CO)

Electricity/energy

Steam

GasificationFi

sche

r Tr

opsc

h

WaxesDieselsOlefins

Gasoline

MethanolOlefins

Gasoline

AceticAcid

MTBEFormaldehyde

EthanolDMEM100

M85DMFC

MixedAlcohols

i-C4

Aldehydes Alcohols

Pyrolysis Oil

Carbon nanotubes

ADVANCING THE FOREST BIOREFINERY

ForestsForests

CelluloseCellulose

DissolvingDissolvingPulpPulp

Bacterial Cellulose

Enzymes Fractionation,

Catalysts

IonicLiquids

Lignosulphonates

CarbonNanotubes

RayonsNanoComposites

ADVANCING THE WOOD PRODUCTS REVOLUTION: Forest Nanomaterials

Wood and microcelluloseNanocomposites

http://www.cermav.cnrs.fr/glyco3d/lessons/modeling/index.html

Cellulose Nanowire

Cellulose Chiral strand Double helix winding Multiple helix branching

http://www.cermav.cnrs.fr/glyco3d/lessons/modeling/index.html

HemicelluloseHemicelluloseCelluloseCellulose FibreFibre Double

Cellulose nanocrystals

Carbon nanotubes

Piezoelectric

Nanowires and nano ribbons-self assembly

Amorphous cellulose

Treatments;reactions

Refining

Preservation of cellulose

NEXT GENERATION FIBER RECOVERY & UTILIZATION

Water interaction

Nanocellulose wire filmLangmuir, 23 (15), 7901 -7906, 2007.10.1021/la700772a S0743-7463(70)00772-2 http://pubs.acs.org/cgi-bin/abstract.cgi/langd5/2007/23/i15/abs/la700772a.html

Nanotitania on cellulose

http://www.rsc.org/ejga/GC/2007/b609887h-ga.gif

http://pubs.acs.org/cgi-bin/abstract.cgi/langd5/2007/23/i15/abs/la700772a.htmlhttp://pubs.acs.org/cgi-bin/abstract.cgi/langd5/2007/23/i15/abs/la700772a.htmlhttp://pubs.acs.org/cgi-bin/abstract.cgi/langd5/2007/23/i15/abs/la700772a.htmlhttp://www.rsc.org/ejga/GC/2007/b609887h-ga.gifhttp://www.rsc.org/ejga/GC/2007/b609887h-ga.gif

Preparation Of Nanocomposite Cellulose Fibres

Silvo Hribernik 1, M. Sfiligoj Smole 1, K. Stana Kleinschek 1, S. Strnad 1, M. Bele

2, V. Ribitsch 31University of Maribor, Laboratory for

Characterisation and Processing of Polymers2National Institute of Chemistry, Ljubljana3University of Graz, Institute of Chemistry,

Rheology and Colloid Science, Graz

http://complex.ijs.si/slonano2005/abstract_web.htm

Paper + Nanotubes = Reeeally Thin Batteries

Emily GertzAugust 17, 2007

http://www.worldchanging.com/archives/007130.html

http://complex.ijs.si/slonano2005/abstract_web.htmhttp://complex.ijs.si/slonano2005/abstract_web.htmhttp://www.worldchanging.com/emily_bio.htmlhttp://www.worldchanging.com/archives/007130.htmlhttp://www.worldchanging.com/archives/007130.html

New metal crystals, formed on a cotton assembly line

Configurations of metal crystals that show promise as components in Biosensors;

http://www.physorg.com/news94131885.html

The Influence of Nano-Confinement and Hydrogen

Bonding on the Transition State of Model Lignin CompoundsBobby G. Sumpter, Phillip F.

Britt, A.C. Buchanan IIIhttp://www.csm.ornl.gov/ccsg/html

/downloads/phenoxyhightxt.pdf

(WO/2005/023708) LASER PYROLYSIS METHOD FOR PRODUCING CARBON NANO-SPHERES

http://nanotechnologytoday.blogspot.com/2007/03/new-metal-crystals-formed-on-cotton.htmlhttp://nanotechnologytoday.blogspot.com/2007/03/new-metal-crystals-formed-on-cotton.htmlhttp://www.physorg.com/news94131885.htmlhttp://www.physorg.com/news94131885.htmlhttp://www.csm.ornl.gov/ccsg/html/downloads/phenoxyhightxt.pdfhttp://www.csm.ornl.gov/ccsg/html/downloads/phenoxyhightxt.pdfhttp://bp0.blogger.com/_TZ4zYEBSw1I/Rg6heMqEdfI/AAAAAAAAAqo/v2ygHz3ye60/s1600-h/nano_crystals.jpg

Double

Double Sided Double Sided Substrate SurfaceSubstrate Surface

Paper web

BoardComposites Extruded

celluloseBiopolymers

Injectionmolding

HybridCars

Construction

SmartPackaging;SensorsSecurity

Batteries

Fire resistance

Pest control

Toxicityreduction

Filters

Catalyst

Ceramics;Inorganic-organic

BREAKTHROUGH MANUFACTURING TECHNOLOGIES:Nano composites

POSITIVELY IMPACTING THE ENVIRONMENT

http://www.oilchief.com/logo/cellulose_nano.jpg

Nanofilter made with Nanocellulose

ZnO nanoparticles on a paper surface (thermolabile substrate) without the use of binders Ammonia and heat treatment of ZNO and cellulose followed by Ultrasound treatment enables coating ofZnO nanoparticles ZnO nanoparticles coated paperpossesses antibacterial activity against E. coli.

Anti-Toxin Coating

Preparation and characterization of ZnOnanoparticles coated paper and its antibacterial activity study;

Kalyani Ghule, Anil Vithal Ghule, Bo-Jung Chen and Yong-Chien LingGreen Chem., 2006, 8, 1034 - 1041, DOI:10.1039/b605623g

http://www.rsc.org/publishing/journals/GC/article.asp?doi=b605623g

http://www.rsc.org/publishing/journals/GC/article.asp?doi=b605623ghttp://www.rsc.org/publishing/journals/GC/article.asp?doi=b605623g

Modified

ModifiedModifiedSurfaceSurface

Printing

CoatingHydrophilic

Hydrophobic

Magnetic

Conductive InksMedical

O2 Scavenging

Biosensors

Powder

High Gloss

Ultra Matte

Iridescent

Printed Electrical Circuits

Printed Battery

Electric/BatteriesDisplays

Capacitors

Displays

OLED’sFuel cells

Security

Security

UV protection;preservation

Nanoclay

BREAKTHROUGH MANUFACTURINGTECHNOLOGIES :

POSITIVELY IMPACTING THE ENVIRONMENT

New Nano Silver Powder Enables Flexible Printed Circuits

http://www.nanoproducts.de/index.php?mp=products&file=info&language=eng&products_id=95

Silver kills odor-causing bacteria and neutralizes ammonia

Antimicrobial coated textiles for performance apparel, infection-resistant medical devices, and glazes for sanitary ware that permanently inhibit odors and stains without chemical cleaners.

http://www.nanoproducts.de/index.php?mp=products&file=info&language=eng&products_id=95http://www.nanoproducts.de/index.php?mp=products&file=info&language=eng&products_id=95http://www.nanoproducts.de/index.php?mp=products&file=info&language=eng&products_id=95

RFID antennae technology manufactured with Parelec’sParmod® conductive inks

http://www.parelec.com

Low-voltage inkjetted organic transistors for printed RFID and display applicationsSteven E. Molesa, Alejandro de la FuenteVornbrock, Paul C. Chang, and VivekSubramanian

Uses Hexanol ink jet solvent with cross linkable polyvinylpyrrolidone coating

http://organics.eecs.berkeley.edu/pdf/IEDM05.pdf

http://www.parelec.com/http://www.google.com/search?hl=en&sa=X&oi=spell&resnum=0&ct=result&cd=1&q=+PVP+polyvinylpyrrolidone&spell=1http://organics.eecs.berkeley.edu/pdf/IEDM05.pdfhttp://organics.eecs.berkeley.edu/pdf/IEDM05.pdf

http://www.cintelliq.com/docs/OSAD20070521_sample.htm

http://www.nanoident.com/technology/production-process-in-depth.html

http://www.nature.com/doifinder/10.1038/445342a

Paper printed with polymer channels

http://www.cintelliq.com/docs/OSAD20070521_sample.htmhttp://www.cintelliq.com/docs/OSAD20070521_sample.htmhttp://www.nanoident.com/technology/production-process-in-depth.htmlhttp://www.nanoident.com/technology/production-process-in-depth.htmlhttp://www.nature.com/doifinder/10.1038/445342ahttp://www.nature.com/doifinder/10.1038/445342a

Defense applications

• On site fuel production• Light weight body armor• Temporary shelter

– IR resistant shelter– Light weight shelter– Recyclable shelter

Nanotechnology value

http://www.nanomaterialscompany.com/images/Nanomaterials-growth-graph.gif

http://www.nanomaterialscompany.com/images/Nanomaterials-growth-graph.gifhttp://www.nanomaterialscompany.com/images/Nanomaterials-growth-graph.gif

Sappi: Nanotechnology and Sustainable Development

“Development which meets the needs of the present without compromising

the ability of future generations to meet their own needs.”

Brundtland Report, 1987, World Health Commission

Nanotechnology� and Forest products�Opportunity RoadmapGenetic Modification of treesCellulose NanowireNanofilter made with NanocelluloseAnti-Toxin CoatingDefense applicationsNanotechnology valueSappi: Nanotechnology and Sustainable Development