09081447 Certificate of Analysis Number: Spectra Energy Transmission, LLC HOUSTON LABORATORY 8880 INTERCHANGE DRIVE HOUSTON, TX 77054 (713) 660-0901 Spectra Energy Transmission, LLC 5400 Westheimer Court Houston TX 77056- Joe Bauer Date Reported: 8/31/2009 Project Name: Spectra Energy PO Number: Agreement No. ENV-0506 Site: Steckman Ridge State: Pennsylvania State Cert. No.: 68-03598 Report To: Site Address: (713) 627-5400 ph: fax: This Report Contains A Total Of 23 Pages Excluding This Page, Chain Of Custody Any Attachments And Date 9/1/2009 Test results meet all requirements of NELAC, unless specified in the narrative.
Test results m eet all requirem ents of N ELAC , unless specilied in the narrative.
HOUSTON LABORATORY
8880 INTERCHANGE DRIVE
HOUSTON, TX 77054
(713)660-0901
Case Narrative for: Spectra Energy Transmission, LLC
Certificate of Analysis Number: 09081447
Report To:
Project Name:
Spectra Energy
Spectra Energy Transmission, LLC
Site:
Steckman Ridge
Joe Bauer
Site Address:
5400 Westheimer Court
Houston
PO Number:
Agreement No. ENV-0506
TX
State:
Pennsylvania
77056-
State Cert. No.:
68-03598
ph: (713)627-5400 fax:
Date Reported:
8/31/2009
I. SAMPLE RECEIPT:
All samples were received intact. The internal ice chest temperatures were measured on receipt and are recorded on the attached Sample Receipt Checklist.
Samples for COC ARF 9834 were received at a temperature of 15.2 and 15.9 degrees Celsius.
Collection date and times were missing from the Chain of Custody; however, were noted on the sample containers.
Please note, containers received for COC ARF 9834 were labeled as "Kuhne-Well-082809". Per client request via e-mail on August 31 , 2009, samples were logged in as per sample IDs noted on the Chain of Custody "MISC Drinking Water - 2321 ".
Containers for the Metals analyses by Method E200.8 were received unpreserved and were preserved upon receipt with 3 milliliters of Nitric acid Lot # 072709-2EE.
Containers for the COD analyses by Method SM5220 C were received unpreserved and were preserved upon receipt with 2 milliliters of Sulfuric acid Lot #052509-2U.
Client was notified of the nonconformances mentioned above via Sample Receipt Confirmation e-mail on August 31 , 2009. Per client request via e- mail on August 31 , 2009 SPL, Inc. continued with analyses requested.
Please see attached sample receipt checklist for any further nonconformance issues.
II: ANALYSES AND EXCEPTIONS:
N-Hexane Extractable Material (1664A):
Due to limited sample volume a Matrix Spike Duplicate (MSD) was not extracted with Batch ID R282534. A Matrix Spike (MS) as well as a Laboratory Control Sample / Laboratory Control Sample Duplicate (LCS/LCSD) were extracted with the analytical batch and serve as the batch quality control (QC). Spike recoveries for the MS, LCS and LCSD were within QC limits.
PCB (E608):
Due to limited sample volume, a Matrix Spike (MS) or Matrix Spike Duplicate (MSD) was not extracted with Batch ID: (93407) for the PCBs analysis by EPA Method E608. A Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) were extracted with the analytical batch and serve as the batch quality control (QC). The LCS and LCSD recovered acceptably and precision criteria were met.
Volatile Organics (SW8260):
Client sample ID "MISC Drinking Water - 2321" (SPL ID: 09081447-01) was randomly selected for use in SPL's quality control program (Batch ID: R282519). The Matrix Spike and/or Matrix Spike Duplicate (MS/MSD) recoveries were outside of the advisory limits for the target analytes toluene, 1 ,2,3-trichlorobenzen
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09081447Certificate of Analysis Number:
Spectra Energy Transmission, LLC
HOUSTON LABORATORY8880 INTERCHANGE DRIVE
HOUSTON, TX 77054(713) 660-0901
Spectra Energy Transmission, LLC
5400 Westheimer Court
HoustonTX77056-
Joe Bauer
Date Reported: 8/31/2009
Project Name: Spectra Energy
PO Number: Agreement No. ENV-0506
Site: Steckman Ridge
State: Pennsylvania
State Cert. No.: 68-03598
Report To:
Site Address:
(713) 627-5400ph: fax:
This Report Contains A Total Of 23 Pages
Excluding This Page, Chain Of Custody
Any Attachments
And
Date
9/1/2009
Test results meet all requirements of NELAC, unless specified in the narrative.
Case Narrative for:
09081447Certificate of Analysis Number:
Spectra Energy Transmission, LLC
HOUSTON LABORATORY8880 INTERCHANGE DRIVE
HOUSTON, TX 77054(713) 660-0901
Spectra Energy Transmission, LLC
5400 Westheimer Court
HoustonTX77056-
Joe Bauer
Date Reported: 8/31/2009
Project Name: Spectra Energy
PO Number: Agreement No. ENV-0506
Site: Steckman Ridge
State: Pennsylvania
State Cert. No.: 68-03598
Report To:
Site Address:
(713) 627-5400ph: fax:
I. SAMPLE RECEIPT:
All samples were received intact. The internal ice chest temperatures were measured on receipt and are recorded on the attached Sample Receipt Checklist.
Samples for COC ARF 9834 were received at a temperature of 15.2 and 15.9 degrees Celsius.
Collection date and times were missing from the Chain of Custody; however, were noted on the sample containers.
Please note, containers received for COC ARF 9834 were labeled as "Kuhne-Well-082809". Per client request via e-mail on August 31, 2009, samples were logged in as per sample IDs noted on the Chain of Custody "MISC Drinking Water - 2321".
Containers for the Metals analyses by Method E200.8 were received unpreserved and were preserved upon receipt with 3 milliliters of Nitric acid Lot # 072709-2EE.
Containers for the COD analyses by Method SM5220 C were received unpreserved and were preserved upon receipt with 2 milliliters of Sulfuric acid Lot # 052509-2U.
Client was notified of the nonconformances mentioned above via Sample Receipt Confirmation e-mail on August 31, 2009. Per client request via e-mail on August 31, 2009 SPL, Inc. continued with analyses requested. Please see attached sample receipt checklist for any further nonconformance issues.
II: ANALYSES AND EXCEPTIONS:
N-Hexane Extractable Material (1664A):
Due to limited sample volume a Matrix Spike Duplicate (MSD) was not extracted with Batch ID R282534. A Matrix Spike (MS) as well as a Laboratory Control Sample / Laboratory Control Sample Duplicate (LCS/LCSD) were extracted with the analytical batch and serve as the batch quality control (QC). Spike recoveries for the MS, LCS and LCSD were within QC limits.
PCB (E608):
Due to limited sample volume, a Matrix Spike (MS) or Matrix Spike Duplicate (MSD) was not extracted with Batch ID: (93407) for the PCBs analysis by EPA Method E608. A Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) were extracted with the analytical batch and serve as the batch quality control (QC). The LCS and LCSD recovered acceptably and precision criteria were met.
Volatile Organics (SW8260):
Client sample ID "MISC Drinking Water - 2321" (SPL ID: 09081447-01) was randomly selected for use in SPL's quality control program (Batch ID: R282519). The Matrix Spike and/or Matrix Spike Duplicate (MS/MSD) recoveries were outside of the advisory limits for the target analytes toluene, 1,2,3-trichlorobenzene and o-xylene. A Laboratory Control Sample (LCS) was analyzed as a quality control check for the analytical batch and all recoveries were within acceptable limits.
DateSylvia Grice
9/1/2009
Senior Project Manager
09081447 Page 1
Test results meet all requirements of NELAC, unless specified in the narrative.
Case Narrative for:
09081447Certificate of Analysis Number:
Spectra Energy Transmission, LLC
HOUSTON LABORATORY8880 INTERCHANGE DRIVE
HOUSTON, TX 77054(713) 660-0901
SIM PAH (SW8270C):
Due to limited sample volume, a Matrix Spike (MS) or Matrix Spike Duplicate (MSD) was not extracted with Batch ID: 93398 for the Semivolatile Organics analysis by SW846 Method 8270C. A Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) were extracted with the analytical batch and serve as the batch quality control (QC). The LCS and LCSD recovered acceptably and precision criteria were met.
III. GENERAL REPORTING COMMENTS:
Results are reported on a wet weight basis unless dry-weight correction is denoted in the units field on the analytical report (" mg\kg-dry " or " ug\kg-dry " ).
Matrix spike (MS) and matrix spike duplicate (MSD) samples are chosen and tested at random from an analytical batch of "like" matrix to check for possible matrix effect. The MS and MSD will provide site specific matrix data only for those samples which are spiked by the laboratory. Since the MS and MSD are chosen at random from an analytical batch, the sample chosen for spike purposes may or may not have been a sample submitted in this sample delivery group. The validity of the analytical procedures for which data is reported in this analytical report is determined by the Laboratory Control Sample (LCS) and the Method Blank (MB). The Laboratory Control Sample (LCS) and the Method Blank (MB) are processed with the samples and the MS/MSD to ensure method criteria are achieved throughout the entire analytical process.
Some of the percent recoveries and RPD's on the QC report for the MS/MSD may be different than the calculated recoveries and RPD's using the sample result and the MS/MSD results that appear on the report because, the actual raw result is used to perform the calculations for percent recovery and RPD.
Any other exceptions associated with this report will be footnoted in the analytical result page(s) or the quality control summary page(s).
Please do not hesitate to contact us if you have any questions or comments pertaining to this data report. Please reference the above Certificate of Analysis Number.
This report shall not be reproduced except in full, without the written approval of the laboratory. The reported results are only representative of the samples submitted for testing.
SPL, Inc. is pleased to be of service to you. We anticipate working with you in fulfilling all your current and future analytical needs.
I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or by his designee, as verified by the following signature.
DateSylvia Grice
9/1/2009
Senior Project Manager
09081447 Page 2
Test results meet all requirements of NELAC, unless specified in the narrative.
09081447Certificate of Analysis Number:
Spectra Energy Transmission, LLC
HOUSTON LABORATORY8880 INTERCHANGE DRIVE
HOUSTON, TX 77054(713) 660-0901
Spectra Energy Transmission, LLC
5400 Westheimer Court
HoustonTX77056-
(713) 627-5400
Joe Bauer
Date Reported: 8/31/2009
Project Name: Spectra Energy
PO Number: Agreement No. ENV-0506
Site: Steckman Ridge
State: Pennsylvania
State Cert. No.: 68-03598
Report To:
Site Address:
(713) 989-8347ph: fax:
Fax To:
Client Sample ID Lab Sample ID Date Collected Date Received COC IDMatrix HOLD
Lab Sample ID Client Sample ID09081447-01F MISC Drinking Water - 2321
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:43 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 9N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
Spectra Energy Transmission, LLCSpectra Energy
Lab Batch ID: 93407WorkOrder: 09081447
Method: E608Analysis: Pesticide/PCBs
HOUSTON LABORATORY8880 INTERCHANGE DRIVE
HOUSTON, TX 77054(713) 660-0901
Analyte LCS Spike Added
LCS Result
LCS Percent Recovery
Lower Limit
Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
Lab Sample ID Client Sample ID09081447-01C MISC Drinking Water - 2321
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:43 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 10N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
Spectra Energy Transmission, LLCSpectra Energy
Lab Batch ID: 93430-IWorkOrder: 09081447
Method: E200.8Analysis: Total Metals by Method 200.8
Lab Sample ID Client Sample ID09081447-01B MISC Drinking Water - 2321
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:43 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 11N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
Spectra Energy Transmission, LLCSpectra Energy
Lab Batch ID: 93430-IWorkOrder: 09081447
Method: E200.8Analysis: Total Metals by Method 200.8
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:43 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 12N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
Spectra Energy Transmission, LLCSpectra Energy
Lab Batch ID: 93398WorkOrder: 09081447
Method: SW8270CAnalysis: SIM Semivolatiles Organics by Method 8270C
HOUSTON LABORATORY8880 INTERCHANGE DRIVE
HOUSTON, TX 77054(713) 660-0901
Analyte LCS Spike Added
LCS Result
LCS Percent Recovery
Lower Limit
Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
Lab Sample ID Client Sample ID09081447-01D MISC Drinking Water - 2321
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:43 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 13N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
Spectra Energy Transmission, LLCSpectra Energy
Lab Batch ID: 93398WorkOrder: 09081447
Method: SW8270CAnalysis: SIM Semivolatiles Organics by Method 8270C
HOUSTON LABORATORY8880 INTERCHANGE DRIVE
HOUSTON, TX 77054(713) 660-0901
Analyte LCS Spike Added
LCS Result
LCS Percent Recovery
Lower Limit
Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:43 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 14N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
Spectra Energy Transmission, LLCSpectra Energy
Lab Batch ID: R282519WorkOrder: 09081447
Method: SW8260BAnalysis: Volatile Organics by Method 8260B
Lab Sample ID Client Sample ID09081447-01A MISC Drinking Water - 2321
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:44 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 15N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
Spectra Energy Transmission, LLCSpectra Energy
Lab Batch ID: R282519WorkOrder: 09081447
Method: SW8260BAnalysis: Volatile Organics by Method 8260B
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:44 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 16N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
Spectra Energy Transmission, LLCSpectra Energy
Lab Batch ID: R282519WorkOrder: 09081447
Method: SW8260BAnalysis: Volatile Organics by Method 8260B
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:44 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 17N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
Spectra Energy Transmission, LLCSpectra Energy
Lab Batch ID: R282519WorkOrder: 09081447
Method: SW8260BAnalysis: Volatile Organics by Method 8260B
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:44 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 18N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
Spectra Energy Transmission, LLCSpectra Energy
Lab Batch ID: R282519WorkOrder: 09081447
Method: SW8260BAnalysis: Volatile Organics by Method 8260B
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:44 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 19N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
Spectra Energy Transmission, LLCSpectra Energy
Lab Batch ID: R282519WorkOrder: 09081447
Method: SW8260BAnalysis: Volatile Organics by Method 8260B
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:44 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 20N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
Lab Sample ID Client Sample ID09081447-01E MISC Drinking Water - 2321
Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
9/1/2009 9:28:45 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09081447 Page 21N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Chain of CustodyAnd
Sample Receipt Checklist
9/1/2009 9:28:45 AM
09081447 Page 22
Sample Receipt Checklist
HOUSTON LABORATORY8880 INTERCHANGE DRIVE
HOUSTON, TX 77054(713) 660-0901
Workorder: 09081447
Date and Time Received: 8/31/2009 9:00:00 AM Carrier name: Fedex-Priority
Shipping container/cooler in good condition? Yes No Not Present
Custody seals intact on shippping container/cooler? Yes No Not Present
Custody seals intact on sample bottles? Yes No Not Present
Chain of custody present? Yes No
Chain of custody signed when relinquished and received? Yes No
Chain of custody agrees with sample labels? Yes No
Samples in proper container/bottle? Yes No
Sample containers intact? Yes No
Sufficient sample volume for indicated test? Yes No
All samples received within holding time? Yes No
Container/Temp Blank temperature in compliance? Yes No
Water - VOA vials have zero headspace? Yes No VOA Vials Not Present
Temperature: 15.2, 15.9°C
Received By: CAW
2. Well sample for COD and metals was received unpreserved.
1. 795503878505-15.9C, 870101736740- 15.2C
SPL Representative:
Non Conformance Issues:
1. Proceed as per client. 2. Preserved COD with 2 mls Sulfuric Lot # 052509-2U. Preserved metals with 3 mls. Nitric Acid Lot#072709-2EE
Client Name Contacted:
Contact Date & Time:
Client Instructions:
Water IceChilled by:
Yes No Not ApplicableWater - Preservation checked upon receipt (except VOA*)?