Report No: Meeting Date: Alameda-Contra Costa Transit District STAFF REPORT TO: Operations Committee AC Transit Board of Directors FROM: David J. Armijo, General Manager SUBJECT: lithium Battery Usage and Safety BRIEFING ITEM RECOMMENDED ACTION(S): Consider receiving a report on the use and safety of lithium batteries. EXECUTIVE SUMMARY: 13-086 AprillO, 2013 On January 7, a lithium battery overheated and started a fire in an empty Boeing 787 at Boston's Logan International Airport. On January 9, United Airlines reported a wiring problem in the same area as the Boeing 787 battery fire. Subsequently, the U.S . National Transportation Safety Board {NTSB) began a safety investigation, and on January 16 the FAA grounded all 787 planes. While NTSB has not issued an official public report, preliminary findings indicate that the lithium-ion batteries in the first incident likely short-circuited resulting in a "thermal runaway" and fire which completely destroyed the battery. It is estimated, however, that more than one million lithium batteries are now used in the automotive sector, and forecasts for lithium batteries in light-duty transportation show growth from $1.6 billion in 2012 to nearly $22 billion in 2020. AC Transit's fuel cell bus fleet utilizes lithium-ion batteries designed and manufactured by EnerDel Inc., a U. S. battery manufacturer, which has more than 1,500 lithium batteries installed in vehicles worldwide with more than five million miles of service. EnerDel's batteries on AC Transit's fleet have more than 300,000 miles of service since September 2010. In July 2011, a connecting cable on one battery overheated causing heat damage, but not a fire, in two of the seven modules that make up the battery pack. The EnerDel battery management system worked as designed to minimize thermal damage. BUDGETARY/FISCAL IMPACT: There is no budgetary impact associated with this report. BACKGROUND/RATIONALE: Lithium batteries are used in a variety of applications including consumer electronics and transportation, where they are primarily used for energy storage on hybrid, plug-in hybrid, and battery-electric vehicles. Two Boeing 787's had reported lithium battery incidents in January 2013 and an AC Transit fuel cell bus experienced an incident in July 2011.
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STAFF REPORT - AC Transit · and battery-electrics use lithium batteries, including the Toyota Prius, Chevy Volt, Nissan Leaf, and Tesla. Pike Research's paper on lithium technology
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T~NS/T Report No:
Meeting Date:
Alameda-Contra Costa Transit District
STAFF REPORT TO: Operations Committee
AC Transit Board of Directors
FROM: David J. Armijo, General Manager
SUBJECT: lithium Battery Usage and Safety
BRIEFING ITEM
RECOMMENDED ACTION(S):
Consider receiving a report on the use and safety of lithium batteries.
EXECUTIVE SUMMARY:
13-086 AprillO, 2013
On January 7, a lithium battery overheated and started a fire in an empty Boeing 787 at Boston's Logan International Airport. On January 9, United Airlines reported a wiring problem in the same area as the Boeing 787 battery fire. Subsequently, the U.S. National Transportation Safety Board {NTSB) began a safety investigation, and on January 16 the FAA grounded all 787 planes. While NTSB has not issued an official public report, preliminary findings indicate that the lithium-ion batteries in the first incident likely short-circuited resulting in a "thermal runaway" and fire which completely destroyed the battery. It is estimated, however, that more than one million lithium batteries are now used in the automotive sector, and forecasts for lithium batteries in light-duty transportation show growth from $1.6 billion in 2012 to nearly $22 billion in 2020.
AC Transit's fuel cell bus fleet utilizes lithium-ion batteries designed and manufactured by EnerDel Inc., a U.S. battery manufacturer, which has more than 1,500 lithium batteries installed in vehicles worldwide with more than five million miles of service. EnerDel's batteries on AC Transit's fleet have more than 300,000 miles of service since September 2010. In July 2011, a connecting cable on one battery overheated causing heat damage, but not a fire, in two of the seven modules that make up the battery pack. The EnerDel battery management system worked as designed to minimize thermal damage.
BUDGETARY/FISCAL IMPACT:
There is no budgetary impact associated with this report.
BACKGROUND/RATIONALE:
Lithium batteries are used in a variety of applications including consumer electronics and transportation, where they are primarily used for energy storage on hybrid, plug-in hybrid, and battery-electric vehicles. Two Boeing 787' s had reported lithium battery incidents in January 2013 and an AC Transit fuel cell bus experienced an incident in July 2011.
Report No. 13-086 Page 2 of 3
AC Transit Batterv Incident: AC Transit's fuel cell bus number 6 experienced an overheated battery in July 2011 while in passenger service near the Oakland Airport. The problem stemmed from a cable connection between two of the seven modules that make up a single battery pack. The driver was alerted to the problem by the visual and audible alarms. The battery went into a shut-down mode requiring the driver to pull to the side of the road. The safety mechanisms controlled by the battery management system operated properly and safely vented heated gases and activated the battery's fire-suppression system; as a result, limiting thermal damage.
EnerDel conducted a root cause investigation and found a component failure in the seating of an electrical cable connection, which caused high electrical resistance in that connection point, producing high voltage across the battery cells and resulting in abnormally high battery pack temperatures. The individual lithium-ion batteries did not fail or perform abnormally.
To address this problem, EnerDel immediately inspected, cleaned, and aligned all high voltage connections and changed the software operating parameters to limit the state of charge of the battery packs to reduce the likelihood of future over-voltage events. EnerDel has since redesigned the high voltage electrical connection circuit in the battery pack assembly, utilizing a more robust terminal connection, and retrofitted all of the District's batteries in 2012.
Boeing Comparison: The AC Transit battery incident was unlike the battery on the Boeing plane, where a fire erupted and the entire battery was destroyed threatening the integrity of the plane. The AC Transit battery safely limited the damage due to battery design, cell packaging, and the battery management system. There was no damage to the bus, and the battery was restored and returned to service.
• Chemistry: The battery chemistry used in the Boeing plane and many small consumer electronics is composed of a lithium cobalt oxide cathode material and graphite anode. The EnerDel battery used on AC Transit buses features a mixed-oxide cathode, which has a higher temperature threshold of more than 50 degrees Celcius, along with a hard carbon anode that is less susceptible to short circuits.
• Battery Management System: The EnerDel battery management system takes into account both the temperature and state of charge (SOC) of the battery to effectively regulate charge and discharge rates to reduce the chance of short circuits and overheating.
• Architecture: The EnerDel battery cells are prismatic and packaged in a soft laminate pouch to effectively "breathe" to minimize particulate debris and temperature increases, compared to the cylindrical and hard metal-cased packaging used by the Boeing battery manufacturer that has a greater likelihood of generating debris. Prismatic architecture provides for improved packaging that requires less highly flammable electrolytes used in all lithium batteries and has more cells with lower capacity and more compartmentalization of the cells within a battery pack. These features distribute the available energy and reduce the chance of propagating temperature increases and thermal runaways.
Automotive and Heavy-Dutv Applications: Nearly all new automotive hybrids, plug-in hybrids, and battery-electrics use lithium batteries, including the Toyota Prius, Chevy Volt, Nissan Leaf, and Tesla. Pike Research's paper on lithium technology growth in the automotive sector reported that "in 2012, Toyota introduced the fifth-generation Prius, powered for the first time with lithium ion (Li-ion) batteries. The shift from nickel-metal hydride (NiMH) batteries to Li-ion
Report No. 13-086 Page 3 of 3
represents a major endorsement of this chemistry as well as its ability to perform consistently in an automotive environment."
ADVANTAGES/DISADVANTAGES:
While lithium batteries are subject to "thermal runaways," improvements in chemistry, architecture and design, manufacturing, and battery management minimize the threat of damage or fires. The benefits of using lithium batteries in comparison with other storage technologies, such as nickel metal hydride or lead acid, are significant reductions in weight and size, without compromising power and energy density. lithium batteries are lighter, smaller, more powerful, and capable of storing more energy to enable sustained power output.
ALTERNATIVES ANALYSIS:
Nearly all of the automotive sector, including heavy-duty buses and trucks, are gravitating to lithium battery storage options due to their enhanced performance characteristics, and because improvements in the design, manufacturing, and software management systems are able to ensure safe and reliable operation.
PRIOR RELEVANT BOARD ACTIONS/POLICIES:
There are no prior relevant Board actions or policies associated with this report.
ATTACHMENTS:
1. EnerDel White Paper on lithium-ion Energy Storage Safety
2. AC Transit EnerDel Battery Safety Features
Department Head Approval: James Pachan, Director of Environmental Technology
Reviewed by: Ken Scheidig, Interim General Counsel
Prepared by: Jaimie Levin, Director of Environmental Technology
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tric, th y all carry some challenges in the and contain energy. But, the risks involved age are not unique to electricity. Since the
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Care. Monitor. Manage. EnerDel's Holistice Approach to Lithium-Jon Energy Storage Safety. Pagel
phases are managed in a controlled manner to ensure
the system performs reliably and safely.
Nearly everyone is familiar with Aristotle's saying, "The whole is more than the sum of its parts," and nowhere
is this more true than in the design of an energy storage
system. The saying also underpins EnerDel's safety philosophy, which in one word, can be stated as "holistic." With any energy storage system, safety must begin at
the lowest component level, but must also include every
subsequent building block that goes into producing the entire system. Each and every level of assembly adds to the amount of stored energy, but it also adds complexity,
which must be managed properly to ensure safety.
Cell chemistry selection - EnerDel's cathode material is
a mixed oxide, namely lithium nickel manganese cobalt (NMC) oxide. The earliest available cathode material for
lithium-ion cells was lithium cobalt oxide (LCO), which is still used in batteries for small consumer products, such
as mobile phones and laptops. EnerDel's NMC cathode
material is inherently safer than LCO; it has a thermal runaway onset temperature that is 50 degrees Celsius higher than that of LCO. When discussing lithium-ion
batteries, thermal runaway refers to a situation where
the cell temperature reaches a threshold that causes an uncontrollable rapid release of energy and corresponding temperature rise resulting in a thermal event, such as a
fire.
EnerDel's anode material is hard carbon. Most comSafety Begins at the Cell Level While cell chemistry, packag
ing, design, and manufactur-
ing are each important build-
+--C-ha_r&_e_ e Discharge
mercially available lithium-ion
cells utilize graphite, which has many positive attributes. However, hard carbon ex
ceeds graphite in providing
higher power density and smaller volume changes when charged and discharged, which encourages longer mechanical stability and life
expectancy. Hard carbon is
also more resistant to degradation reactions, such as dendrite formation, and offers
more chemical stability.
ing blocks in EnerDel's holistic
approach to lithium-ion battery
safety, cell chemistry is a critical starting point.
Current Collector
Current Collector
ll+
The essential parts of a
lithium-ion battery cell are the cathode, anode, separator,
electrolyte, packaging, and tabs. The cathode is a material that contains lithium ions
within its crystal structure.
The anode accepts the lithium ions from the cathode dur- Carbon
Anode Separator layered Insertion
Cathode The electrolyte in commercial
ly available lithium-ion cells, such as EnerDel's Moxie+
Prismatic Cells, contains
ing charge and then releases
them during discharge. The separator, which electrically
Figure 1: Diagram of a discharging lithium-ion cell
isolates the cathode from the anode to prevent internal short circuits, contains small pores that allow the lithium
ions in the electrolyte to travel between the cathode and anode during charge and discharge (see Figure 1). The cell package contains the cathode, anode, separator, and
electrolyte, while tabs allow electrical connections to be made. Careful selection of these components and cell design improve the safety, life expectancy and perfor
mance of a lithium-ion cell.
organic solvents and a salt. Familiar battery technolo
gies such as lead-acid, alkaline, nickel cadmium, and
nickel metal hydride use a water-based electrolyte, which is compatible to their voltage range of about 1.2V to 2.1V. The higher voltage lithium-ion cell requires use of
organic, solvent-based electrolyte because water would be decomposed if used. The organic solvents used in lithium-ion cell electrolyte are flammable, so it is critically
important that they are properly sealed and contained
Care. Monitor. Manage. EnerDe/'s Holistice Approach to Lithium-/on Energy Storage Safety. Page3
within the packaging. EnerDel cells use just enough electrolyte to fill the pores of the electrodes and separa
tor. This minimizes the chance of electrolyte leaking from
the packaging should a breach occur.
The EnerDel separator is a polymer that encases the cathode and anode electrodes using Z-fold winding, which immobilizes the electrodes so their alignment is
maintained though the life of the cell. The separator helps shut down the cell by melting and thus closing its
pores if high temperatures are experienced.
EnerDel's cells are packaged in laminate, which allows for efficient packing. Appropriately-sized tabs are eas-
ily sealed into laminate packaging with high mechani-cal strength. Since the multi-layer laminate consists of
aluminum foil sandwiched between layers of electricallyinsulating polymers, the risk of shorting to the metal case is eliminated. In contrast, cylindrical cells require the use
of many more parts, which can increase the risk of manufacturing flaws and short-circuits.
There are two tabs per lithium-ion cell, one for the cath
ode and one for the anode. Connections to the external load are made using these tabs. Many lithium-ion cells
have top tabs that are extremely close to each other. En
erDel's cells feature wide-plated tabs situated at opposite sides of the prismatic cell. This side tab configuration
offers several advantages:
Minimizing the chance of inadvertent shorting Wide, opposite tabs support a larger current density
with less temperature rise Wide tabs have a thinner cross section providing bet
ter sealing characteristics Plated tabs are less prone to corrosion, which maintain low contact resistance and result in less heat and
longer life expectancy thereby enhancing safety
Cell design - Some lithium-ion cells have a cylindrical configuration with long sheet of electrodes and separators wound-up inside. EnerDel's cells are configured in
a flat stack of electrodes, which results in better uniformity of their electrical, mechanical, and thermal proper
ties. The flat stack also provides a more uniform current density enabling prismatic cells to support higher currents
Figure 2: Infrared image of a 4 Ah cylindrical cell with 100 A continuous current
Figure 3: Infrared image of a 4 Ah capacity prismatic cell with 1 OOA continuous current
60,.0 57 54 51 48 45 42 39 36 33 30 27
23.0 ·c
60.0 57 54 51 48 45 42 39 36 33 30 27 24 22.0 ·c
with lower temperature rise than cylindrical cells. This
is particularly important in large format cells with high
Care. Monitor. Manage. EnerDel's Ho/istice Approach to Lithium-/on Energy Storage Safety. Page4
to occupy. We monitor cell health through voltage and temperature measurements, and we manage the cell
environment by giving it a method to better manage heat
dissipation.
Stacked prismatic cells offer benefits in packaging ef
ficiency and heat removal. However, they present a set
EnerDel designs products with safety as the paramount consideration stemming from its deep
knowledge of lithium-ion cell behavior.
of unique needs that must be addressed to successfully package them into a module. The first requirement is
that the cell stack, or the layers of anodes and cathodes
that are interleaved in the prismatic cell, must be stabilized within the module. Whether the module is used for a mobile or
stationary application, mechanical
retention of the anode and cathode layers is critical. The second requirement is that the cell must be
allowed to 'breathe.' This breathing function is the natural expansion and contraction of the cell as it undergoes charge and discharge
cycles. This is caused by the transport of lithium-ions within the
cell that results in a natural volume change or "breathing" of each electrode.
EnerDel addresses stabilization
and volume change needs through the use of a foam sheet that is
paired with each cell of our mod
ule design (see Figure 4). The foam sheet, in conjunction with the module end-plates and cell ele-
could cause internal shorts. The foam also allows the
cell to breathe by providing a compliant layer between a
cell and its adjacent neighboring cell. In conjunction with
the foam, the module assembly is designed to compress the cells. This force promotes ionic conductivity and results in low internal cell resistance and heat generation.
The mechanical pieces that form the module are made
from an electrically-insulating material, which is selfextinguishing per UL 94. The material is also chemicallyresistant. In addition to providing the backbone for the
compressed cells, the mechanical module also protects the prismatic cells from mechanical intrusion.
At every electrical connection level, special attention
must be given to connection points. This starts from the
moment the two cell tabs are joined and continues to the
Cell Elements
Cells per Element
Side Tabs
ments, stabilizes the cell stack by applying a uniform pressure across
Figure 4: Expanded view of EnerDel module construction
the entire surface area of the cell face. The foam hangs
over the active area of the cell creating a 'picture frame' around the periphery of the cell stack. In effect, the cell stack is restrained from any physical movement which
point where two high voltage power busses are brought
together. Loose connections can be the cause of potential system failures by creating high electrical resistance which generates heat. Consequently, this is why EnerDel
AC Transit Lithium-lon Battery Pack Safety Features
EnerDel has a strong focus on safety that touches every aspect of our business and is reflected in the products we develop and manufacture for our customers. We value our relationship with AC Transit and have outlined the various safety features represented in our cells, packs and battery management systems to demonstrate the features and approach given to safety in the packs installed on AC Transit's clean energy buses.
Quality System Automotive-grade quality system based on Automotive Industry Action Group (AIAG) product and manufacturing development and qualification processes
Cells Cells are manufactured using strictly controlled processes and material standards to promote consistently high quality and uniformity
• Cell chemistry is temperature tolerant and therefore harder to induce thermal runaway Hard Carbon helps inhibit dendrite growth and promotes higher C-rates resulting in improved reliability Cells utilize a Z-fold process for separator installation stabilizing the cell stack reducing chances of internal shorts Prismatic cells have thin cell cross sections and large surface areas to promote heat removal
• Prismatic cells have fewer components compared to cylindrical cells
• Laminate packaging is electrically case neutral by design • Side terminals promote uniform current density and thermal
profile resulting in higher currents with less heat compared to cylindrical cells Wide terminals on opposite sides of the cell promote safety due to increased creepage and clearance distances. Wide terminals result in a thinner cross section which improves cell sealing
• Side terminals reduce risk of terminal-to-terminal shorts (direct shorts or salt bridging) Terminals are nickel-plated to reduce long-term electrical resistance
Battery Management System • High speed CAN bus vehicle interface
Low-voltage to high-voltage isolation Synchronized pack voltage and pack current measurements
• Cell voltage monitoring and balancing Module temperature sensing Contactor, fuse, and service disconnect status detection Isolation fault detection Contactor control/ high voltage interlock
• Pack pre-charge control • Power PC processor for high processing capability
On-board diagnostics and self·test capability improve safety Integrated precision measurements promote safer control of the battery Redundant voltage measurements Multiple zone temperature measurements on both modules and BMS circuit boards
• Contactor control of high voltage interlock Isolation fault detection High voltage isolation fully compatible with EN 60950 standards All high voltage nodes require a minimum of two levels of fault tolerance - not just failsafe. Improved protection against over charge, over discharge
• Continuous cell balancing in all modes of operation
Packaging Cells are packaged in an electrically insulating frame that also inhibits mechanical intrusion
• Cell frames and endplates in conjunction with the elemental foam keep the cells in compression to promote ionic conductivity which promotes low internal cell resistance and heat generation Elemental foam "picture frames" the electrode stack within the laminate packaging to prevent physical movement and the possibility of internal electrical shorts Elemental foam provides a non-rigid uniform force load distribution on the surface of the cell while allowing the cell to expand and contract under charge/discharge cycling Battery module max voltage is less than 50V for safe assembly, handling, storage and service
• All module components are electrolyte/chemical resistant and have a minimum fire rating of UL94 HB
• All power buss connections utilizing mechanical fasteners are applied using dynamic/close loop torque control with thread-locker to ensure joint integrity for the life of the product All power bussing mechanical fastener hardware is plated to promote low electrical resistance and long term mechanical integrity Sub pack cover provides insulated mounting surfaces for RLEC's and mounting snap features to the case for ease of service (no loose hardware that could cause electrical shorts) Sub pack enclosure provides compliance to EN 60950 standards Sub pack serves as the lowest level field serviceable unit in battery system Sub pack is ergonomically friendly with integrated lift assist features
• All major system components down to the discrete cell level are serialized for traceability Pack enclosures and connectors are IP67 rated
• Module and pack enclosures are steel with protective coatings to protect battery from harsh environmental elements System architecture is broken up in to discrete cells of the appropriate capacity which in turn minimizes impact of thermal runaway and magnitude of event
Thermal Event Countermeasures (Non-BMS dependent)
Integrated module frame out-gassing ventilation ports All battery module components compliant to UL94 HB (minimum requirement) Modules and entire battery packaged in to a steel case to prevent thermal event propagation
• Independent fire suppression system activated by high heat (autonomous from BMS system) Directionally controlled rupture disks for high pressure outgassing