Solid acid catalysts for biomass transformations

7/30/2019 Solid acid catalysts for biomass transformations

1/33

Tijo` Fdo` Dfpfjytpt airBoilftt Prfhtairlfpoiht

F(T( Ridmf* @( R( Acrhfh`ct* P( Aorlohi* C( A( Lfo* B( J( Ijoqcorf*fh` Q( Pco}corf `f Tojqf

Pmcttfjihoeo* 46tp Idpibcr 2>62

7/30/2019 Solid acid catalysts for biomass transformations

2/33

Rcto`sfj Boilftt Prfhtairlfpoiht

Rcto`sfj Boilftt

Mclodcjjsjitc* Dcjjsjitc

^chpitct

-]yjitc/

Mc}itct

-Gjsditc* Arsdpitc* Lfhhitc/

Asrasrfj 3,My`ri}ylcpmyjasrasrfj -MLA/

Jcqsjohod fdo`

M% , M2I M% , M2I

M2I* M%

7/30/2019 Solid acid catalysts for biomass transformations

3/33

Jcqsjohod fdo` ft f ~jfpairl lijcdsjc

Dirlf* Obirrf fh` Qcjpy* Dmcl( Rcq( 2>>7* 6>7* 2066,23>2

7/30/2019 Solid acid catalysts for biomass transformations

4/33

Aii` oh`stpry -ajfqirt/

Tijqchpt

^jftpodo{crt

@octcj Lotdobjc Boiascj

Jcqsjohod fdo` ft f ~jfpairl lijcdsjc

7/30/2019 Solid acid catalysts for biomass transformations

5/33

Aii` oh`stpry -ajfqirt/

Tijqchpt

^jftpodo{crt

@octcj Lotdobjc Boiascj

www

(`obfhcp(irg

Jcqsjohod fdo` ft f ~jfpairl lijcdsjc

7/30/2019 Solid acid catalysts for biomass transformations

6/33

Cpmyj jcqsjohfpc tyhpmctot

241>

6617

=?2

3=0

02?402

2066

707

6=17

26=6

2060

@(R( Acrhfh`ct cp fj( F~~joc` Dfpfjytot F; Gchcrfj 023 021 -2>62/ 6?? 2>0

P < 404 E

p < 3 m2(3 wp(# ia dfpfjytp

CpIM)JqFd < 3)6

7/30/2019 Solid acid catalysts for biomass transformations

7/33

Tsjafpc` tpfhof

7/30/2019 Solid acid catalysts for biomass transformations

8/33

Dfpfjytp tyhpmctot

Tijsbojo{fpoih

jcf`ohg pi fjiw yocj` iapmc `roc` gcj

Frfpf* F~~( Dfpfj( F6??1* 601* 4,42(

Lfptsmftmo* Loyf{feo* Efwflsrf* Hfeflsrf* Frfpf* Dmcl( Lfpcr(2>>6* 64* 4>4=,4>02(

7/30/2019 Solid acid catalysts for biomass transformations

9/33

Dfpfjytp tyhpmctot

Frfpf* F~~( Dfpfj( F6??1* 601* 4,42(

Lfptsmftmo* Loyf{feo* Efwflsrf* Hfeflsrf* Frfpf* Dmcl( Lfpcr(2>>6* 64* 4>4=,4>02(

7/30/2019 Solid acid catalysts for biomass transformations

10/33

Dfpfjytp dmfrfdpcro{fpoih , ]R@

7/30/2019 Solid acid catalysts for biomass transformations

11/33

Dfpfjytp dmfrfdpcro{fpoih , Rflfh

7/30/2019 Solid acid catalysts for biomass transformations

12/33

Dfpfjytp dmfrfdpcro{fpoih H2~mytotir~poih

Tfl~jc Tg ) l2 g,6

ThI2 0>

TI0,2

) ThI2 -6L/ 6>=TI0

,2) ThI2 -2L/ 62>

TI0

,2) ThI2

-4L/ 64>

TI0,2) ThI2 -0L/ 60>

TI0,2) ThI2 -3L/ 60=

7/30/2019 Solid acid catalysts for biomass transformations

13/33

Dmfrfdpcro{fpoih TCL

7/30/2019 Solid acid catalysts for biomass transformations

14/33

7/30/2019 Solid acid catalysts for biomass transformations

15/33

Dfpfjytp dmfrfdpcro{fpoih HM4 P^@

Pcl~crfpsrc ) iD

l

){lij l,21(?lij l,2=(0lij l,27(2lij l,27(4lij l,2

7/30/2019 Solid acid catalysts for biomass transformations

16/33

Li`oaodfpoih ia pmc tsjasr ohdir~irfpoih

7/30/2019 Solid acid catalysts for biomass transformations

17/33

Dmfrfdpcro{fpoih H2 ~mytotir~poih

7/30/2019 Solid acid catalysts for biomass transformations

18/33

Dmfrfdpcro{fpoih ]R@

7/30/2019 Solid acid catalysts for biomass transformations

19/33

Dmfrfdpcro{fpoih ]R@

7/30/2019 Solid acid catalysts for biomass transformations

20/33

Dfpfjypod fdpoqopyP < 404 E

p < 3 m

2(3 wp(# ia dfpfjytp

CpIM)JqFd < 3)6

7/30/2019 Solid acid catalysts for biomass transformations

21/33

Dfpfjypod fdpoqopyP < 404 E

p < 3 m

2(3 wp(# ia dfpfjytp

CpIM)JqFd < 3)6

7/30/2019 Solid acid catalysts for biomass transformations

22/33

Dfpfjypod fdpoqopyP < 404 E

p < 3 m

2(3 wp(# ia dfpfjytp

CpIM)JqFd < 3)6

7/30/2019 Solid acid catalysts for biomass transformations

23/33

Rcstfbojopy Flbcrjytp 63

7/30/2019 Solid acid catalysts for biomass transformations

24/33

Rcstfbojopy GOF,3#

7/30/2019 Solid acid catalysts for biomass transformations

25/33

Rcstfbojopy GOF,3#

7/30/2019 Solid acid catalysts for biomass transformations

26/33

Rcstfbojopy GOF,3#

7/30/2019 Solid acid catalysts for biomass transformations

27/33

Dihdjstoiht

Air tsjafpc` tijo` i}o`c dfpfjypt pmcrc ot f dirrcjfpoih bcpwcch pmc

pipfj fdo`opy fh` fdpoqopy5

7/30/2019 Solid acid catalysts for biomass transformations

28/33

Dihdjstoiht

Air tsjafpc` tijo` i}o`c dfpfjypt pmcrc ot f dirrcjfpoih bcpwcch pmc

pipfj fdo`opy fh` fdpoqopy5

Air {cijopct pmc ~irc tprsdpsrc tcclt pi ~jfy f lirc ol~irpfhp rijc

pmfh pmc pipfj fdo`opy5

7/30/2019 Solid acid catalysts for biomass transformations

29/33

Dihdjstoiht

Air tsjafpc` tijo` i}o`c dfpfjypt pmcrc ot f dirrcjfpoih bcpwcch pmc

pipfj fdo`opy fh` fdpoqopy5

Air {cijopct pmc ~irc tprsdpsrc tcclt pi ~jfy f lirc ol~irpfhp rijc

pmfh pmc pipfj fdo`opy5

Tsjafpc` tpfhof ~rctchpt f gii` fdpoqopy oh jcqsjohod fdo` ctpcroaodfpoih

bsp sh`crgict `cfdpoqfpoih( Dmfhgohg pmc wftmohg ~ridc`src op ot

~ittobjc pi rcstc pmc dfpfjytp(

7/30/2019 Solid acid catalysts for biomass transformations

30/33

Dihdjstoiht

Air tsjafpc` tijo` i}o`c dfpfjypt pmcrc ot f dirrcjfpoih bcpwcch pmc

pipfj fdo`opy fh` fdpoqopy5

Air {cijopct pmc ~irc tprsdpsrc tcclt pi ~jfy f lirc ol~irpfhp rijc

pmfh pmc pipfj fdo`opy

Tsjafpc` tpfhof ~rctchpt f gii` fdpoqopy oh jcqsjohod fdo` ctpcroaodfpoih

bsp sh`crgict `cfdpoqfpoih(Dmfhgohg pmc wftmohg ~ridc`src op ot

~ittobjc pi rcstc pmc dfpfjytp(

Flbcrjytp,63* f dillcrdofj fqfojfbjc rctoh ot fdpoqc fh` tpfbjc oh pmcjovso` ~mftc jcqsjohod fdo` ctpcroaodfpoih wopm cpmfhij(

7/30/2019 Solid acid catalysts for biomass transformations

31/33

Fdehiwjc`glchpt

Pmot wire wft ~crairlc`wopmoh pmc @OBFHCP Hcpwire*

f ~rikcdp wopmoh pmc Csri~cfhDillshopyt TcqchpmArflcwire ^rigrfllc-A^7)2>>7,2>64/ sh`cr grfhpfgrcclchp hi; 22720=,2(

7/30/2019 Solid acid catalysts for biomass transformations

32/33

Fdehiwjc`glchpt

Pmfhet air yisr fppchpoih&

&

7/30/2019 Solid acid catalysts for biomass transformations

33/33

Bfde,s~ tjo`ct