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Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A. Bland, P.E. Burns & McDonnell Senior Environmental Engineer
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Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Apr 12, 2018

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Page 1: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Selenium Reduction in Constructed Wetland Treatment

Systems: Naturally Attenuating Problematic

Pollutants

Katie A. Bland, P.E. Burns & McDonnell

Senior Environmental Engineer

Page 2: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Overview

• What are Constructed Wetlands? • Why the Power Industry? • Westar Energy Pilot Project • Pilot Project Results • Full Scale Design/Construction • Path Forward

Page 3: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

• Constructed Wetland Treatment System – “An artificial wetland created or restored…..for

anthropogenic discharge such as wastewater, stormwater runoff, or sewage treatment. Natural wetlands act as a biofilter, removing sediments and pollutants such as heavy metals from the water, and constructed wetlands can be designed to emulate these features.”

Constructed Wetland Treatment System

Page 4: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

• Three General Systems – Free Water Cell – Vertical Flow Wetland – Vegetated Submerged Bed Wetland

Constructed Wetland Treatment System

Page 5: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

• Free Water Surface Wetland

Constructed Wetland Treatment System

Page 6: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

• Vertical Flow Bed Wetland

Constructed Wetland Treatment System

Page 7: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

• Vegetated Submerged Bed Wetland

Constructed Wetland Treatment System

Page 8: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

• Stormwater • Mine drainage • Domestic sewage • Landfill leachate • Fairly new to the power industry

CWTS in the Power Industry

Page 9: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

A promising technology…

CWTS in the Power Industry

• Polishing FGD Wastewater

• Landfill leachate/CCR Contact Water

• Polishing Biological • Coal Pile Runoff • Stormwater

Page 10: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Westar Jeffrey Energy Center

Page 11: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Westar Jeffrey Energy Center

• Polishing FGD Wastewater – FGD Scrubber upgrade complete in 2008 – Low chlorides – Dewatering/solids removal already in place – Land available – Multiple options considered

Page 12: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

• Multiple options considered, with some being complex mechanical systems with high capital costs

• Wide range in cost between CWTS and ZLD

Westar Jeffrey Energy Center

Page 13: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Constructed Wetland Project Jeffrey Energy Center

Plant Reuse

Makeup Lake

Pilot Wetland

Water / Material Balance

Page 14: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Constructed Wetland Project Jeffrey Energy Center

Page 15: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Pilot Wetland Construction Complete

Page 16: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Free Water Surface Cell

Page 17: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Vegetated Submerged Bed

Page 18: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Vertical Flow Bed Wetland Cell

Page 19: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Ecological Risks

Selenium and Mercury Ecological Exposure

Page 20: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Laboratory Column Studies

Page 21: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Pilot Constructed Wetland Results

CONSTITUENT MASS LOAD REDUCTION

AVERAGE INFLUENT

(ug/L)

AVERAGE EFFLUENT

(ug/L)

Mercury 83% 1.2 <0.2

Selenium 92% 114 12*

Boron 42% 3,459 2,120

Fluoride 93% 11,209 1,551

*Selenium: 31% non-detect ( < 5 ug/L )

Page 22: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Some Lessons Learned…

• Topsoil – Selenium • Economically viable • It works!

Page 23: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Full Scale Design/Construction

• Considerations for the full scale design – Further mitigate ecological risk – Flexibility of operation – Extensive Modeling

• Plant Water Balance • CORMIX

– Beneficial Reuse • Cooling tower feed

– Test Pad

Page 24: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Full Scale Design/Construction

• Design Incorporated Ecological Risk Assessment

• Very Long HRT in CWTS - 30+ Days • Synthetics & Upflow • Constructability Challenges

Page 25: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Isolate Mercury and

Selenium

Full Scale Design/Construction

Page 26: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Treatment Soil

Single Sided Geocomposite and Gravel Drains

Compacted Clay Liner (1x10-7 cm/sec)

Tier 1 Soil

Gravel/Sand Drainage Layer

Geotextile

60 MIL HDPE

Full Scale Design/Construction

Page 27: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Full Scale Design/Construction

Page 28: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Full Scale Design/Construction

• Earthwork completed in December of 2013 • Mechanical installation complete in May

2014 • Startup of system is ongoing

Page 29: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Full Scale Design/Construction

Page 30: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Full Scale Design/Construction

Page 31: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Wetlands = Opportunity

• CWTS effectively treats metals including Selenium and other constituents…

Potassium (K)

Aluminum (Al)

Fluoride (F)

Nitrogen (N)

Barium (Ba)

Boron (B)

Chromium (Cr)

Iron (Fe)

Molybdenum (Mo)

Selenium (Se)

Mercury (Hg)

Page 32: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Wetlands = Opportunity

• CWTS provide a green treatment solution that is appealing to the public and local stakeholders

• Edison Electric Award Winner 2014 • Economically appealing • Effective for metals reduction

Page 33: Selenium Reduction in Constructed Wetland … Presentations/July...Selenium Reduction in Constructed Wetland Treatment Systems: Naturally Attenuating Problematic Pollutants Katie A.

Questions?

Katie A. Bland, P.E. [email protected]

(816) 823-7042