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Science Experiments Do NOT PRESUME that you are allowed to carry out any of these experiments. You must always seek permission of your head of department. If you are not confident, get someone else to demonstrate for your class, or show the video! A number of these experiments are extremely dangerous and should only be attempted by trained staff, use recommended quantities whilst taking appropriate precautions and under CLEAPPS, and any other local, guidance rules. DO NOT be tempted to ‘make it a little more exciting’ by increasing the recommended scale of a reaction. Your, and more importantly, your students safety must always be paramount. You could end your career very quickly by unprofessional conduct and God forbid you should do actual bodily harm. Use your laboratory technicians! These people are usually an excellent source of information, the likelihood is they have set up the demonstration, if not performed it before. You also need to ensure that what you’re about to demonstrate has not recently been banned. Always check with more experienced colleagues and you head of department. NEVER attempt any experiment in front of a class that you have not tried and tested before. Any added safety comments to be found in this document are over and above CLEAPPS or any local requirement. They are included as a result of experience and indicate what might else be considered or what may go wrong, even when the experiment is correctly performed. A number of these demonstrations may irritate a pre-existing lung condition (asthma etc) – be aware of this possibility. Remember – you need to develop a little showmanship - tell them it’s not dangerous then act a little nervous. Ask misleading questions to help them think ‘a balloon cannot possibly…’ For me the best demonstration is a little scary, but always controlled. Above all convey a love for science, it is infectious! [email protected]
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Page 1: Science Experiments

Science Experiments

Do NOT PRESUME that you are allowed to carry out any of these experiments You must always seek permission of your head of department If you are not confident get someone else to demonstrate for your class or show the video

A number of these experiments are extremely dangerous and should only be attempted by trained staff use recommended quantities whilst taking appropriate precautions and under CLEAPPS and any other local guidance rules DO NOT be tempted to lsquomake it a little more excitingrsquo by increasing the recommended scale of a reaction Your and more importantly your students safety must always be paramount You could end your career very quickly by unprofessional conduct and God forbid you should do actual bodily harm Use your laboratory technicians These people are usually an excellent source of information the likelihood is they have set up the demonstration if not performed it before You also need to ensure that what yoursquore about to demonstrate has not recently been banned Always check with more experienced colleagues and you head of department NEVER attempt any experiment in front of a class that you have not tried and tested before

Any added safety comments to be found in this document are over and above CLEAPPS or any local requirement They are included as a result of experience and indicate what might else be considered or what may go wrong even when the experiment is correctly performed

A number of these demonstrations may irritate a pre-existing lung condition (asthma etc) ndash be aware of this possibility

Remember ndash you need to develop a little showmanship - tell them itrsquos not dangerous then act a little nervous Ask misleading questions to help them think lsquoa balloon cannot possiblyhelliprsquo

For me the best demonstration is a little scary but always controlled

Above all convey a love for science it is infectious

alanglazetauntonsacuk

Balloons

Water balloon ndash partially fill balloon with water inflate and seal Hold a candle under the balloon taking care only to heat where the water is Soot will show you were not cheating but the balloon will not burst You can do a similar trick making a paper box and filling with water Heat over a roaring Bunsen and make tea The paper (provided it doesnrsquot leak) can be seen to be glowing orange underneath (actually the mesh holding it)

Blanket on the floor (to protect from grit) four balloons (quality not the very thin ones) MDF board on top (1x1 m doesnrsquot really matter) Get the first student to stand on top lsquoBig up the riskrsquo (at the same time taking care not to trap your fingers underneath the board Great fun to see how many you can balance on the board ndash probably safest to do with single sexhellip

Propulsion ndash tape a balloon to a straw and watch it zip along a line Lot of variations on this ndash toy carshellip

Match head

Straighten a paper clip and twist around a match close to the head Suspend on the mouth of a Bunsen and light the Bunsen The match should survive happily in the cold blue cone

Laser pens

ndash fantastic for lots of demos keep a careful track of them with students Ebay Green Laser Pointer amp Star Projector also simple pens 3 colours at the moment

Ice cube blocks

Two seemingly identical black blocks (in the range of 3cm high 10x5 wide) Do not let the student pick them up or the difference will be immediately apparent (density) One feels warm to the touch (made of wood) the other cold (metal) Put an ice cube on each and watch what happens (conductor vs non conductor but counter intuitive as one might expect the warm block to melt faster)

Xylene cyanolAn indicator you may have lurking in the preproom or scrounge from the local collegeuni Solution in 1M HCl in a volumetric flask port decanter or similar Green at the top red at the bottom (best lit from underneath using an OHP)Explanation ndash email me

Singing rods1m metal rod (aluminium is easiest) about 5mm diameter - BampQ

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Hold the rod firmly dead centre between thumb and first finger Apply a little violin rosin to you other thumb and finger and draw firmly down the rod You should hear it lsquosingrsquo (takes a little practice) Halve the distance between the thumbfinger and the rod and try again You should be able to get at least 3 notes

IR cameraIR webcam can se into the IR Use a clothbag to remove daylight and look at the security features of a banknote (the Queenrsquos head only present in pound5 note) Will also show-up veins (difference in temperature vs skin) Ebay search for Night Vision Web cam

Exploding waterU-tube containing 4M sulphuric acid fitted with two platinum electrodes Apply enough voltage (20+ typically) to split the water ndash bubbles at each electrodeUse polypropylene tubes (rubber perishes) to join the two ends of the tube via a t-piece and into a single tube which is under a bubble solution (soapglycerolwater ndash see internet) The bubbles catch hydrogen and oxygen in perfect harmony ready to be reunited with a (VERY) loud bang Protect your own ears as you will be closest ndash inverse square of the distance from the source (I use plugs or at least stick a finger in the closest ear)Caution ndash the sulphuric acid will get very hot This is great for discussion of the hydrogen economy

Dragons breathGas-canister blow torch from BampQ (always handy) Fill an empty spray bottle with methanol adding the salt of your choice (lithium chloride boric acid etc) spray across the blow torch flame creating Dragons Breath Best in a darkened room Do not set fire to the bottle in your hand This will quickly fill the room with smoke ndash do not over use You can create a lesser version using methanol in evaporating basins Again add the salt of your choice to produce beautiful colours

Copper coin

2p copper coin (or similar) is suspended from a glass rod using high temp wire - nicrome should do Holding the coin in tongs heat over a roaring Bunsen until red hot the carefully suspend (a slight angle works best) just above a small volume of propanone in a beakerconical flask) Works best in a darkened room The coin with continue to glow with lsquoclouds of orangersquo sweeping across the surface until all the propanone has evaporatedCaution the coin stay very hot ( 400degC) for a long time the beaker too becomes hot The vapours will cause headache (contains ethanol)

Exploding wax

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Wax from a candle kit or grated is place in a test tube (ca 3cm deep) and heated to a gentle boil over a roaring Bunsen The test tube is plunged into coldiced water to the height of the wax (no more or it kills the reaction) The cold water cracksshatters the tube and the column of steam carries the wax up into the air as it condenses as white clouds At about 05m the energy released as the wax goes from gas to solid causes spontaneous combustion and a resulting fire ball

Caution wear a glove (wax vapour is very hot) cover the desk use the same beaker as it is difficult to clean DO NOT BE TEMPTED TO SCALE UP NOT EVEN TO A BOILING TUBE

Silly putty

Syllabus Links Fun experiment ndash fits best with 21st C polymers ndash borax crosslinks the PVA polymer to change its physical properties depending on the degree of crosslinking the polymer goes from a viscous liquid to gel (silly putty) to a rubber

Method PVA water borax solution food dye 25 ml PVA adhesive 20ml water (you mar add a few drops of one or more food dyes for effect) 15ml borax solution (14 boraxwater) Add waterdye to PVA and stir Add borax solution and stir This should give lsquosilly puttyrsquo the reaction is relatively slow and the product will thicken with stirring or as it is played with Adding more borax solution will further crosslink the polymer turning it into a rubber The age and quality of the PVA and borax make quantities rather in exact A small trial should give the required amounts

Safety Silly putty may cause irritation if directly handled Insist that students wash thoroughly with soap and water after touching silly putty Students are not allowed to remove anything from the laboratory However they may be reluctant to part with a rubber ball they have made

Update ndash magnetic silly putty hellip add a spoon full of black iron oxideFe3O4 ndash the expensive black stuff not common red rust Fe203 This will create silly putty the will move with a super magenthellip

Possible source ebay Black iron oxide

See httpwwwyoutubecomwatchfeature=player_embeddedampv=UlCm9Pni6ME

Green fire

Syllabus Links Energetic reactions in KS3 chemistry displacement reactions AppliedAdditional science

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Method Ammonium nitrate (3g) salt (05g) ndash grind these together in a mortar and pestle Add zinc powder (7g) grind again Transfer to crucible add few drops water ndash stand clear

As soon as the zinc has been added take EXTREME care as the least drop of water will initiate this reaction

Safety lsquoDonrsquot try this at homersquo ammonium nitrate is readily available in most garden supply centres as it is a common fertiliser Hopefully students will not make this link This is an extremely vigorous reaction even a drop of sweat could initiate it

Nitrogen triiodide

1 The first step is to prepare the NI3 One method is to simply pour up to a gram of iodine crystals into a a small volume of concentrated aqueous ammonia allow the contents to sit for 5 minutes then pour the liquid over a filter paper to collect the NI3 which will be a dark brownblack solid However if you grind the pre-weighed iodine with a mortarpestle beforehand a larger surface area will be available for the iodine to react with the ammonia giving a significantly larger yield

2 The reaction for producing the nitrogen triiodide from iodine and ammonia is

3I2 + NH3 -gt NI3 + 3HI

3 You want to avoid handling the NI3 at all so my recommendation would be to set up the demonstration in advance of pouring off the ammonia Traditionally the demonstration uses a ring stand on which a wet filter paper with NI3 is placed with a second filter paper of damp NI3 sitting above the first The force of the decomposition reaction on one paper will cause decomposition to occur on the other paper as well

4 For optimal safety set up the ring stand with filter paper and pour the reacted solution over the paper where the demonstration is to occur A fume hood is the preferred location The demonstration location should be free of traffic and vibrations The decomposition is touch-sensitive and will be activated by the slightest vibration

5 To activate the decomposition tickle the dry NI3 solid with a feather attached to a long stick The decomposition occurs according to this reaction

2NI3 (s) --gt N2 (g) + 3I2 (g)

6 In its simplest form the demonstration is performed by pouring the damp solid onto a paper towel in a fume hood letting it dry and activating it with a meter stick

Tips

1 Caution This demonstration should only be performed by an instructor using proper safety precautions Wet NI3 is more stable than the dry compound but still should be handled with care Iodine will stain clothing and surfaces purple or orange The stain can be removed using a sodium thiosulfate solution Eye and ear protection are recommended Iodine is a respiratory and eye irritant the decomposition reaction is loud

2 NI3 in the ammonia is very stable and can be transported if the demonstration is to be performed at a remote location

3 How it works NI3 is highly unstable because of the size difference between the nitrogen and iodine atoms There is not enough room around the central nitrogen to keep the iodine atoms stable The bonds between the nuclei

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are under stress and therefore weakened The outside electrons of the iodine atoms are forced into close proximity which increases the instability of the molecule

4 The amount of energy released upon detonating NI3 exceeds that required to form the compound which is the definition of a high yield explosive

What You Need

up to 1 g iodine (do not use more) concentrated aqueous ammonia (0880 SG) filter paper or paper towel ring stand (optional) feather attached to a long stick

Pop Can Collapse

Syllabus Links Energy transfer pressure

Method -Put a little water in the can heat and invert into bowl of cold water ndash can collapses Physics ndash pressure the can becomes filled with hot water vapour inverted in the bowl the temperature drops

Safety Students can find it difficult to grip the can even more so to invert it into the bowl of cold water Inverting the can risks spraying boiling water

Empty soda cans tongs bowl of water Bunsen water

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Pocket Rockets

Syllabus Links acids and alkali pressure actionreaction

Method Citric acid sodium carbonate (23) grind as necessary Wrap carbcitric in tissue and put into the mouth of a old plastic 35mm film canister with water in the bottom Seal the lid firmly and invert - explodes as CO2 is releasedCitric can be replaced with lemonacetic (vinegar)

Safety Can be messy and surprisingly explosive ndash eyes

Thermit

Syllabus Links energetic reactions energy transfer

Method Thermit reactants (enough for TWO demonstrations)Iron (III) Oxide 374gAluminium powder 126 gMagnesium powder 3 spatulaBarium Oxide powder 3 spatulaMagnesium ribbonMix the iron and aluminium then cover with a mixture of the magnesium and barium oxide The Magnesium forms a wick to set off the reaction

Safety Thermit ndash messy and hot (molten iron 1500C +) Potentially this is one of the most dangerous of all the lsquoclassicrsquo reactions Can be unpredictable and explode from the pot

Methane Bubbles

Syllabus Links Energy transfer combustion

Method There are endless variations Methane long rubber hose The lsquobubblerrsquo is made from an inverted plastic soda bottle cut in half - discarding the base The cap of the soda bottle is replaced with a rubber bung through which has been inserted a glass tube The end of the tube has been bent over to form a hook which is below the level of the bubble mixture Methane is blown through the bubble mixture via a hose connected to the end of the tube

Bubble mixture many folk have their own secret recipe but generally 18 part dishwashing liquid 1 part water 2 tbs glycerine You may wish to lsquoSimpsonizersquo the experiment by adding blue food dye to the bubbles and a picture of Margersquos face to the bubble blower Ensure the students hands are we and no bubbles are under their hands Another variation is to lsquoshake offrsquo the bubbles and ignite in mid air

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Safety If you find yoursquove got a headache at the end of this you have insufficient ventilation Do not be tempted to over-do this one Do not forget to wet the students hands and have the hand stretched out fully and horizontal It is essential they wear goggles The flames tend to mushroom into the students face The experiment goes wrong when the students panic and drop their hands bringing the flames close to the face Have a sink of cold water near to hand the odd student will think they were burned

Gas explosion (various)

Syllabus Links Energy transfer combustion

Methane long rubber hose heat proof mats Pringles tube plastic soda bottle

Method See accompanying videos ndash much easier than explanation

Safety methaneair is relatively safe Should only be carried out in well ventilated laboratory

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Pringles lsquobombrsquo

Empty a tube of Pringles keeping the plastic lid Taking care not to otherwise damage the tube punchdrill a 10mm (or so) hole in the metal base In the side of the tube near the top drillpunch another hole 2-3mm in diameter (important) Put your finger over the large hole in the base and fill the tube with methane from a rubber hose Turn off the gas and push the tube onto the plastic cap which is now the base Remove your finger and light the gas forming a Pringles candle Discuss why the flame is yellow yadda yadda The students will forget about the tube as it apparently lsquogoes outrsquo Sometime later the gasair in the tube that has lsquogone outrsquo reaches an explosive limit and the can jumps up with a whoosh (safe to do on a desk in front of students They will ask to do it again Shake the can to replace the air inside and lsquoset it off againrsquo Waiting for it to pop is worse than the first time

Methane + oxygen

Syllabus Links energy transfer combustion rocket design

Method Using a PET soda bottle of MAXIMUM 500ml capacity fill with 23 oxygen to 13 methane This is best done by marking the bottle first then filling and inverting in water Measure the required gas volumes by displacement of water Close the bottle off using a balloon Support the bottle in a suitable holder and melt through the balloon with a gas lighter

Safety Only use carbonated drinks bottles as PVC bottle are significantly weakerThe explosion that will follow should propel the bottle 30 metres or more The explosion is EXTREMELY LOUD especially for the staff member melting through the balloon I have seen this done in a large lab but would recommend it only be done outside

Screaming Jelly babies

Syllabus Links energy transfer combustion rocket design

Method 5-10 g potassium chlorate in a boiling tube (will be destroyed) jelly babiesMelt the chlorate with a Bunsen then drop in the jelly baby

Safety It is suggested that this can be done in an open lab but I would never recommend this on the basis of the gassmoke produced if nothing else I only ever do this experiment in a fixed or portable fume hood Occasionally the Jelly baby fights back and refuses to slide down the tube You are now in the situation of a fire work that has not gone off If you try to poke the jelly baby down the tube you risk having your hand in the jet of the reaction It is safer to change the angle of the tube

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Balloon tricks

Syllabus Links Upthrust pressure 21st C materials and their properties Actionreaction

Method There are 101 balloon tricks Blow up a balloon and stick a pin in it It explodes Keep threatening to do thishelliphellipThe old trick is to put sellotape on the balloon and push a knitting needle through this The tape stops the tear in the rubber propagating At then end of the balloon there is a small lsquonipplersquo where the rubber is thicker ndash it is possible to push a sharp pinskewer through this without popping the balloon ndash Why

Try to push a balloon under waterhellip

Blow up a balloon and put it over a night-light candle The balloon bursts and the candle is snuffed out There is a lesson there alone ndash whyhellipPartially fill a balloon with water and then blow it up Hold the balloon over the candle ndash nothing happens why Show the soot on the base of the balloon ndash this is no trick A variation of this is to make a paper boat and fill with water Put this over a roaring Bunsen The paper will not burn whilst there is still water in the boat You may wish to add a tea bag for effect

Attach a balloon to a paper plane attached to a straw Pass a thread through the straw and use the balloon to project the plane along the thread across the class room Great fun

Inflate a balloon and statically charge it by rubbing or using a Van de GraffHold the balloon near a slowly running stream of water ndash why does the water bend How could you get the water to bend in the opposite directionBetter stillhellip Hold the charged balloon near a slowly pouring stream of golden syrup ndash with care you can get the syrup to bend horizontally

Water trickSyllabus Links lsquoFlogistan theoryrsquo pressure

Method Put a small amount of water coloured with food dye in a shallow plate Use a wedge of apple or orange to hold 4 matches Place the wedge with the matches in the water and light Quickly cover the matches with a glass ands press down firmly The water is sucked from the plate into the glass

Flaming money

Syllabus Links Combustion

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Method Soak paper money in a 50 solution of waterethanol The ethanol burns but the paper is protected by the water More spectacular (and riskyhellip) is to burn a scarf instead

Safety Do not ignite the beaker or anything else

Tea Bags

Syllabus Links Combustion

Method Unwrap the tea bag to give a hollow tube Put the tube on something valuable (pound5) and set fire to the top The panic comes when the flames approach the money buthellip

Safety Watch where the ignited bag goes

Rubens Tube

Syllabus Links Pressure sound

Method Signal generator Rubens Tube gas supply I have never seen a Rubens tube for sale but they are relatively easy to make (email for instructions) The Rubens tube is essentially a tube forming a gas grill One end for the tube is closed off with a plastic membrane which is vibrated by a speaker Us the signal generator to discuss the range of human youngold hearing

Safety The tube gets hot Residual gas in the tube can linger and smell

Magnetic Rail gun

Syllabus Links actionreaction magnetism

Method Easily constructed from electrical conduit cable ties and neodymium magnets The last ball leave the gun faster than the entering ball appearing to have gained energyhellip

Ferromagnetic Liquid Syllabus Links Magnetism

Method Ferrofluid can be bought from Ebay Cover with 50 IPAdeionised water in a glass jar

Safety Neodymium magnets can cause pinch injuries wipe data or smash the vessel the Ferrofluid is in

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Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

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Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

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This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

alanglazetauntonsacuk

Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

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5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

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diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

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pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
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  • Whats happening
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  • Whats happening
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  • Whatrsquos happening
  • What you need
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  • What you need
  • What to do
  • What you need
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  • Whats happening
  • What you need
  • What To Do
  • Whats happening
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  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 2: Science Experiments

Balloons

Water balloon ndash partially fill balloon with water inflate and seal Hold a candle under the balloon taking care only to heat where the water is Soot will show you were not cheating but the balloon will not burst You can do a similar trick making a paper box and filling with water Heat over a roaring Bunsen and make tea The paper (provided it doesnrsquot leak) can be seen to be glowing orange underneath (actually the mesh holding it)

Blanket on the floor (to protect from grit) four balloons (quality not the very thin ones) MDF board on top (1x1 m doesnrsquot really matter) Get the first student to stand on top lsquoBig up the riskrsquo (at the same time taking care not to trap your fingers underneath the board Great fun to see how many you can balance on the board ndash probably safest to do with single sexhellip

Propulsion ndash tape a balloon to a straw and watch it zip along a line Lot of variations on this ndash toy carshellip

Match head

Straighten a paper clip and twist around a match close to the head Suspend on the mouth of a Bunsen and light the Bunsen The match should survive happily in the cold blue cone

Laser pens

ndash fantastic for lots of demos keep a careful track of them with students Ebay Green Laser Pointer amp Star Projector also simple pens 3 colours at the moment

Ice cube blocks

Two seemingly identical black blocks (in the range of 3cm high 10x5 wide) Do not let the student pick them up or the difference will be immediately apparent (density) One feels warm to the touch (made of wood) the other cold (metal) Put an ice cube on each and watch what happens (conductor vs non conductor but counter intuitive as one might expect the warm block to melt faster)

Xylene cyanolAn indicator you may have lurking in the preproom or scrounge from the local collegeuni Solution in 1M HCl in a volumetric flask port decanter or similar Green at the top red at the bottom (best lit from underneath using an OHP)Explanation ndash email me

Singing rods1m metal rod (aluminium is easiest) about 5mm diameter - BampQ

alanglazetauntonsacuk

Hold the rod firmly dead centre between thumb and first finger Apply a little violin rosin to you other thumb and finger and draw firmly down the rod You should hear it lsquosingrsquo (takes a little practice) Halve the distance between the thumbfinger and the rod and try again You should be able to get at least 3 notes

IR cameraIR webcam can se into the IR Use a clothbag to remove daylight and look at the security features of a banknote (the Queenrsquos head only present in pound5 note) Will also show-up veins (difference in temperature vs skin) Ebay search for Night Vision Web cam

Exploding waterU-tube containing 4M sulphuric acid fitted with two platinum electrodes Apply enough voltage (20+ typically) to split the water ndash bubbles at each electrodeUse polypropylene tubes (rubber perishes) to join the two ends of the tube via a t-piece and into a single tube which is under a bubble solution (soapglycerolwater ndash see internet) The bubbles catch hydrogen and oxygen in perfect harmony ready to be reunited with a (VERY) loud bang Protect your own ears as you will be closest ndash inverse square of the distance from the source (I use plugs or at least stick a finger in the closest ear)Caution ndash the sulphuric acid will get very hot This is great for discussion of the hydrogen economy

Dragons breathGas-canister blow torch from BampQ (always handy) Fill an empty spray bottle with methanol adding the salt of your choice (lithium chloride boric acid etc) spray across the blow torch flame creating Dragons Breath Best in a darkened room Do not set fire to the bottle in your hand This will quickly fill the room with smoke ndash do not over use You can create a lesser version using methanol in evaporating basins Again add the salt of your choice to produce beautiful colours

Copper coin

2p copper coin (or similar) is suspended from a glass rod using high temp wire - nicrome should do Holding the coin in tongs heat over a roaring Bunsen until red hot the carefully suspend (a slight angle works best) just above a small volume of propanone in a beakerconical flask) Works best in a darkened room The coin with continue to glow with lsquoclouds of orangersquo sweeping across the surface until all the propanone has evaporatedCaution the coin stay very hot ( 400degC) for a long time the beaker too becomes hot The vapours will cause headache (contains ethanol)

Exploding wax

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Wax from a candle kit or grated is place in a test tube (ca 3cm deep) and heated to a gentle boil over a roaring Bunsen The test tube is plunged into coldiced water to the height of the wax (no more or it kills the reaction) The cold water cracksshatters the tube and the column of steam carries the wax up into the air as it condenses as white clouds At about 05m the energy released as the wax goes from gas to solid causes spontaneous combustion and a resulting fire ball

Caution wear a glove (wax vapour is very hot) cover the desk use the same beaker as it is difficult to clean DO NOT BE TEMPTED TO SCALE UP NOT EVEN TO A BOILING TUBE

Silly putty

Syllabus Links Fun experiment ndash fits best with 21st C polymers ndash borax crosslinks the PVA polymer to change its physical properties depending on the degree of crosslinking the polymer goes from a viscous liquid to gel (silly putty) to a rubber

Method PVA water borax solution food dye 25 ml PVA adhesive 20ml water (you mar add a few drops of one or more food dyes for effect) 15ml borax solution (14 boraxwater) Add waterdye to PVA and stir Add borax solution and stir This should give lsquosilly puttyrsquo the reaction is relatively slow and the product will thicken with stirring or as it is played with Adding more borax solution will further crosslink the polymer turning it into a rubber The age and quality of the PVA and borax make quantities rather in exact A small trial should give the required amounts

Safety Silly putty may cause irritation if directly handled Insist that students wash thoroughly with soap and water after touching silly putty Students are not allowed to remove anything from the laboratory However they may be reluctant to part with a rubber ball they have made

Update ndash magnetic silly putty hellip add a spoon full of black iron oxideFe3O4 ndash the expensive black stuff not common red rust Fe203 This will create silly putty the will move with a super magenthellip

Possible source ebay Black iron oxide

See httpwwwyoutubecomwatchfeature=player_embeddedampv=UlCm9Pni6ME

Green fire

Syllabus Links Energetic reactions in KS3 chemistry displacement reactions AppliedAdditional science

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Method Ammonium nitrate (3g) salt (05g) ndash grind these together in a mortar and pestle Add zinc powder (7g) grind again Transfer to crucible add few drops water ndash stand clear

As soon as the zinc has been added take EXTREME care as the least drop of water will initiate this reaction

Safety lsquoDonrsquot try this at homersquo ammonium nitrate is readily available in most garden supply centres as it is a common fertiliser Hopefully students will not make this link This is an extremely vigorous reaction even a drop of sweat could initiate it

Nitrogen triiodide

1 The first step is to prepare the NI3 One method is to simply pour up to a gram of iodine crystals into a a small volume of concentrated aqueous ammonia allow the contents to sit for 5 minutes then pour the liquid over a filter paper to collect the NI3 which will be a dark brownblack solid However if you grind the pre-weighed iodine with a mortarpestle beforehand a larger surface area will be available for the iodine to react with the ammonia giving a significantly larger yield

2 The reaction for producing the nitrogen triiodide from iodine and ammonia is

3I2 + NH3 -gt NI3 + 3HI

3 You want to avoid handling the NI3 at all so my recommendation would be to set up the demonstration in advance of pouring off the ammonia Traditionally the demonstration uses a ring stand on which a wet filter paper with NI3 is placed with a second filter paper of damp NI3 sitting above the first The force of the decomposition reaction on one paper will cause decomposition to occur on the other paper as well

4 For optimal safety set up the ring stand with filter paper and pour the reacted solution over the paper where the demonstration is to occur A fume hood is the preferred location The demonstration location should be free of traffic and vibrations The decomposition is touch-sensitive and will be activated by the slightest vibration

5 To activate the decomposition tickle the dry NI3 solid with a feather attached to a long stick The decomposition occurs according to this reaction

2NI3 (s) --gt N2 (g) + 3I2 (g)

6 In its simplest form the demonstration is performed by pouring the damp solid onto a paper towel in a fume hood letting it dry and activating it with a meter stick

Tips

1 Caution This demonstration should only be performed by an instructor using proper safety precautions Wet NI3 is more stable than the dry compound but still should be handled with care Iodine will stain clothing and surfaces purple or orange The stain can be removed using a sodium thiosulfate solution Eye and ear protection are recommended Iodine is a respiratory and eye irritant the decomposition reaction is loud

2 NI3 in the ammonia is very stable and can be transported if the demonstration is to be performed at a remote location

3 How it works NI3 is highly unstable because of the size difference between the nitrogen and iodine atoms There is not enough room around the central nitrogen to keep the iodine atoms stable The bonds between the nuclei

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are under stress and therefore weakened The outside electrons of the iodine atoms are forced into close proximity which increases the instability of the molecule

4 The amount of energy released upon detonating NI3 exceeds that required to form the compound which is the definition of a high yield explosive

What You Need

up to 1 g iodine (do not use more) concentrated aqueous ammonia (0880 SG) filter paper or paper towel ring stand (optional) feather attached to a long stick

Pop Can Collapse

Syllabus Links Energy transfer pressure

Method -Put a little water in the can heat and invert into bowl of cold water ndash can collapses Physics ndash pressure the can becomes filled with hot water vapour inverted in the bowl the temperature drops

Safety Students can find it difficult to grip the can even more so to invert it into the bowl of cold water Inverting the can risks spraying boiling water

Empty soda cans tongs bowl of water Bunsen water

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Pocket Rockets

Syllabus Links acids and alkali pressure actionreaction

Method Citric acid sodium carbonate (23) grind as necessary Wrap carbcitric in tissue and put into the mouth of a old plastic 35mm film canister with water in the bottom Seal the lid firmly and invert - explodes as CO2 is releasedCitric can be replaced with lemonacetic (vinegar)

Safety Can be messy and surprisingly explosive ndash eyes

Thermit

Syllabus Links energetic reactions energy transfer

Method Thermit reactants (enough for TWO demonstrations)Iron (III) Oxide 374gAluminium powder 126 gMagnesium powder 3 spatulaBarium Oxide powder 3 spatulaMagnesium ribbonMix the iron and aluminium then cover with a mixture of the magnesium and barium oxide The Magnesium forms a wick to set off the reaction

Safety Thermit ndash messy and hot (molten iron 1500C +) Potentially this is one of the most dangerous of all the lsquoclassicrsquo reactions Can be unpredictable and explode from the pot

Methane Bubbles

Syllabus Links Energy transfer combustion

Method There are endless variations Methane long rubber hose The lsquobubblerrsquo is made from an inverted plastic soda bottle cut in half - discarding the base The cap of the soda bottle is replaced with a rubber bung through which has been inserted a glass tube The end of the tube has been bent over to form a hook which is below the level of the bubble mixture Methane is blown through the bubble mixture via a hose connected to the end of the tube

Bubble mixture many folk have their own secret recipe but generally 18 part dishwashing liquid 1 part water 2 tbs glycerine You may wish to lsquoSimpsonizersquo the experiment by adding blue food dye to the bubbles and a picture of Margersquos face to the bubble blower Ensure the students hands are we and no bubbles are under their hands Another variation is to lsquoshake offrsquo the bubbles and ignite in mid air

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Safety If you find yoursquove got a headache at the end of this you have insufficient ventilation Do not be tempted to over-do this one Do not forget to wet the students hands and have the hand stretched out fully and horizontal It is essential they wear goggles The flames tend to mushroom into the students face The experiment goes wrong when the students panic and drop their hands bringing the flames close to the face Have a sink of cold water near to hand the odd student will think they were burned

Gas explosion (various)

Syllabus Links Energy transfer combustion

Methane long rubber hose heat proof mats Pringles tube plastic soda bottle

Method See accompanying videos ndash much easier than explanation

Safety methaneair is relatively safe Should only be carried out in well ventilated laboratory

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Pringles lsquobombrsquo

Empty a tube of Pringles keeping the plastic lid Taking care not to otherwise damage the tube punchdrill a 10mm (or so) hole in the metal base In the side of the tube near the top drillpunch another hole 2-3mm in diameter (important) Put your finger over the large hole in the base and fill the tube with methane from a rubber hose Turn off the gas and push the tube onto the plastic cap which is now the base Remove your finger and light the gas forming a Pringles candle Discuss why the flame is yellow yadda yadda The students will forget about the tube as it apparently lsquogoes outrsquo Sometime later the gasair in the tube that has lsquogone outrsquo reaches an explosive limit and the can jumps up with a whoosh (safe to do on a desk in front of students They will ask to do it again Shake the can to replace the air inside and lsquoset it off againrsquo Waiting for it to pop is worse than the first time

Methane + oxygen

Syllabus Links energy transfer combustion rocket design

Method Using a PET soda bottle of MAXIMUM 500ml capacity fill with 23 oxygen to 13 methane This is best done by marking the bottle first then filling and inverting in water Measure the required gas volumes by displacement of water Close the bottle off using a balloon Support the bottle in a suitable holder and melt through the balloon with a gas lighter

Safety Only use carbonated drinks bottles as PVC bottle are significantly weakerThe explosion that will follow should propel the bottle 30 metres or more The explosion is EXTREMELY LOUD especially for the staff member melting through the balloon I have seen this done in a large lab but would recommend it only be done outside

Screaming Jelly babies

Syllabus Links energy transfer combustion rocket design

Method 5-10 g potassium chlorate in a boiling tube (will be destroyed) jelly babiesMelt the chlorate with a Bunsen then drop in the jelly baby

Safety It is suggested that this can be done in an open lab but I would never recommend this on the basis of the gassmoke produced if nothing else I only ever do this experiment in a fixed or portable fume hood Occasionally the Jelly baby fights back and refuses to slide down the tube You are now in the situation of a fire work that has not gone off If you try to poke the jelly baby down the tube you risk having your hand in the jet of the reaction It is safer to change the angle of the tube

alanglazetauntonsacuk

Balloon tricks

Syllabus Links Upthrust pressure 21st C materials and their properties Actionreaction

Method There are 101 balloon tricks Blow up a balloon and stick a pin in it It explodes Keep threatening to do thishelliphellipThe old trick is to put sellotape on the balloon and push a knitting needle through this The tape stops the tear in the rubber propagating At then end of the balloon there is a small lsquonipplersquo where the rubber is thicker ndash it is possible to push a sharp pinskewer through this without popping the balloon ndash Why

Try to push a balloon under waterhellip

Blow up a balloon and put it over a night-light candle The balloon bursts and the candle is snuffed out There is a lesson there alone ndash whyhellipPartially fill a balloon with water and then blow it up Hold the balloon over the candle ndash nothing happens why Show the soot on the base of the balloon ndash this is no trick A variation of this is to make a paper boat and fill with water Put this over a roaring Bunsen The paper will not burn whilst there is still water in the boat You may wish to add a tea bag for effect

Attach a balloon to a paper plane attached to a straw Pass a thread through the straw and use the balloon to project the plane along the thread across the class room Great fun

Inflate a balloon and statically charge it by rubbing or using a Van de GraffHold the balloon near a slowly running stream of water ndash why does the water bend How could you get the water to bend in the opposite directionBetter stillhellip Hold the charged balloon near a slowly pouring stream of golden syrup ndash with care you can get the syrup to bend horizontally

Water trickSyllabus Links lsquoFlogistan theoryrsquo pressure

Method Put a small amount of water coloured with food dye in a shallow plate Use a wedge of apple or orange to hold 4 matches Place the wedge with the matches in the water and light Quickly cover the matches with a glass ands press down firmly The water is sucked from the plate into the glass

Flaming money

Syllabus Links Combustion

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Method Soak paper money in a 50 solution of waterethanol The ethanol burns but the paper is protected by the water More spectacular (and riskyhellip) is to burn a scarf instead

Safety Do not ignite the beaker or anything else

Tea Bags

Syllabus Links Combustion

Method Unwrap the tea bag to give a hollow tube Put the tube on something valuable (pound5) and set fire to the top The panic comes when the flames approach the money buthellip

Safety Watch where the ignited bag goes

Rubens Tube

Syllabus Links Pressure sound

Method Signal generator Rubens Tube gas supply I have never seen a Rubens tube for sale but they are relatively easy to make (email for instructions) The Rubens tube is essentially a tube forming a gas grill One end for the tube is closed off with a plastic membrane which is vibrated by a speaker Us the signal generator to discuss the range of human youngold hearing

Safety The tube gets hot Residual gas in the tube can linger and smell

Magnetic Rail gun

Syllabus Links actionreaction magnetism

Method Easily constructed from electrical conduit cable ties and neodymium magnets The last ball leave the gun faster than the entering ball appearing to have gained energyhellip

Ferromagnetic Liquid Syllabus Links Magnetism

Method Ferrofluid can be bought from Ebay Cover with 50 IPAdeionised water in a glass jar

Safety Neodymium magnets can cause pinch injuries wipe data or smash the vessel the Ferrofluid is in

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Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

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Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

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This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

alanglazetauntonsacuk

Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

alanglazetauntonsacuk

5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

alanglazetauntonsacuk

diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

alanglazetauntonsacuk

pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

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Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

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Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

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Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

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Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

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White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

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Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
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  • Whats happening
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  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
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  • Applications
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  • Experiment 2 Drop Cup
  • What you need
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  • Whats happening
  • Applications
  • What to do
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  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 3: Science Experiments

Hold the rod firmly dead centre between thumb and first finger Apply a little violin rosin to you other thumb and finger and draw firmly down the rod You should hear it lsquosingrsquo (takes a little practice) Halve the distance between the thumbfinger and the rod and try again You should be able to get at least 3 notes

IR cameraIR webcam can se into the IR Use a clothbag to remove daylight and look at the security features of a banknote (the Queenrsquos head only present in pound5 note) Will also show-up veins (difference in temperature vs skin) Ebay search for Night Vision Web cam

Exploding waterU-tube containing 4M sulphuric acid fitted with two platinum electrodes Apply enough voltage (20+ typically) to split the water ndash bubbles at each electrodeUse polypropylene tubes (rubber perishes) to join the two ends of the tube via a t-piece and into a single tube which is under a bubble solution (soapglycerolwater ndash see internet) The bubbles catch hydrogen and oxygen in perfect harmony ready to be reunited with a (VERY) loud bang Protect your own ears as you will be closest ndash inverse square of the distance from the source (I use plugs or at least stick a finger in the closest ear)Caution ndash the sulphuric acid will get very hot This is great for discussion of the hydrogen economy

Dragons breathGas-canister blow torch from BampQ (always handy) Fill an empty spray bottle with methanol adding the salt of your choice (lithium chloride boric acid etc) spray across the blow torch flame creating Dragons Breath Best in a darkened room Do not set fire to the bottle in your hand This will quickly fill the room with smoke ndash do not over use You can create a lesser version using methanol in evaporating basins Again add the salt of your choice to produce beautiful colours

Copper coin

2p copper coin (or similar) is suspended from a glass rod using high temp wire - nicrome should do Holding the coin in tongs heat over a roaring Bunsen until red hot the carefully suspend (a slight angle works best) just above a small volume of propanone in a beakerconical flask) Works best in a darkened room The coin with continue to glow with lsquoclouds of orangersquo sweeping across the surface until all the propanone has evaporatedCaution the coin stay very hot ( 400degC) for a long time the beaker too becomes hot The vapours will cause headache (contains ethanol)

Exploding wax

alanglazetauntonsacuk

Wax from a candle kit or grated is place in a test tube (ca 3cm deep) and heated to a gentle boil over a roaring Bunsen The test tube is plunged into coldiced water to the height of the wax (no more or it kills the reaction) The cold water cracksshatters the tube and the column of steam carries the wax up into the air as it condenses as white clouds At about 05m the energy released as the wax goes from gas to solid causes spontaneous combustion and a resulting fire ball

Caution wear a glove (wax vapour is very hot) cover the desk use the same beaker as it is difficult to clean DO NOT BE TEMPTED TO SCALE UP NOT EVEN TO A BOILING TUBE

Silly putty

Syllabus Links Fun experiment ndash fits best with 21st C polymers ndash borax crosslinks the PVA polymer to change its physical properties depending on the degree of crosslinking the polymer goes from a viscous liquid to gel (silly putty) to a rubber

Method PVA water borax solution food dye 25 ml PVA adhesive 20ml water (you mar add a few drops of one or more food dyes for effect) 15ml borax solution (14 boraxwater) Add waterdye to PVA and stir Add borax solution and stir This should give lsquosilly puttyrsquo the reaction is relatively slow and the product will thicken with stirring or as it is played with Adding more borax solution will further crosslink the polymer turning it into a rubber The age and quality of the PVA and borax make quantities rather in exact A small trial should give the required amounts

Safety Silly putty may cause irritation if directly handled Insist that students wash thoroughly with soap and water after touching silly putty Students are not allowed to remove anything from the laboratory However they may be reluctant to part with a rubber ball they have made

Update ndash magnetic silly putty hellip add a spoon full of black iron oxideFe3O4 ndash the expensive black stuff not common red rust Fe203 This will create silly putty the will move with a super magenthellip

Possible source ebay Black iron oxide

See httpwwwyoutubecomwatchfeature=player_embeddedampv=UlCm9Pni6ME

Green fire

Syllabus Links Energetic reactions in KS3 chemistry displacement reactions AppliedAdditional science

alanglazetauntonsacuk

Method Ammonium nitrate (3g) salt (05g) ndash grind these together in a mortar and pestle Add zinc powder (7g) grind again Transfer to crucible add few drops water ndash stand clear

As soon as the zinc has been added take EXTREME care as the least drop of water will initiate this reaction

Safety lsquoDonrsquot try this at homersquo ammonium nitrate is readily available in most garden supply centres as it is a common fertiliser Hopefully students will not make this link This is an extremely vigorous reaction even a drop of sweat could initiate it

Nitrogen triiodide

1 The first step is to prepare the NI3 One method is to simply pour up to a gram of iodine crystals into a a small volume of concentrated aqueous ammonia allow the contents to sit for 5 minutes then pour the liquid over a filter paper to collect the NI3 which will be a dark brownblack solid However if you grind the pre-weighed iodine with a mortarpestle beforehand a larger surface area will be available for the iodine to react with the ammonia giving a significantly larger yield

2 The reaction for producing the nitrogen triiodide from iodine and ammonia is

3I2 + NH3 -gt NI3 + 3HI

3 You want to avoid handling the NI3 at all so my recommendation would be to set up the demonstration in advance of pouring off the ammonia Traditionally the demonstration uses a ring stand on which a wet filter paper with NI3 is placed with a second filter paper of damp NI3 sitting above the first The force of the decomposition reaction on one paper will cause decomposition to occur on the other paper as well

4 For optimal safety set up the ring stand with filter paper and pour the reacted solution over the paper where the demonstration is to occur A fume hood is the preferred location The demonstration location should be free of traffic and vibrations The decomposition is touch-sensitive and will be activated by the slightest vibration

5 To activate the decomposition tickle the dry NI3 solid with a feather attached to a long stick The decomposition occurs according to this reaction

2NI3 (s) --gt N2 (g) + 3I2 (g)

6 In its simplest form the demonstration is performed by pouring the damp solid onto a paper towel in a fume hood letting it dry and activating it with a meter stick

Tips

1 Caution This demonstration should only be performed by an instructor using proper safety precautions Wet NI3 is more stable than the dry compound but still should be handled with care Iodine will stain clothing and surfaces purple or orange The stain can be removed using a sodium thiosulfate solution Eye and ear protection are recommended Iodine is a respiratory and eye irritant the decomposition reaction is loud

2 NI3 in the ammonia is very stable and can be transported if the demonstration is to be performed at a remote location

3 How it works NI3 is highly unstable because of the size difference between the nitrogen and iodine atoms There is not enough room around the central nitrogen to keep the iodine atoms stable The bonds between the nuclei

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are under stress and therefore weakened The outside electrons of the iodine atoms are forced into close proximity which increases the instability of the molecule

4 The amount of energy released upon detonating NI3 exceeds that required to form the compound which is the definition of a high yield explosive

What You Need

up to 1 g iodine (do not use more) concentrated aqueous ammonia (0880 SG) filter paper or paper towel ring stand (optional) feather attached to a long stick

Pop Can Collapse

Syllabus Links Energy transfer pressure

Method -Put a little water in the can heat and invert into bowl of cold water ndash can collapses Physics ndash pressure the can becomes filled with hot water vapour inverted in the bowl the temperature drops

Safety Students can find it difficult to grip the can even more so to invert it into the bowl of cold water Inverting the can risks spraying boiling water

Empty soda cans tongs bowl of water Bunsen water

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Pocket Rockets

Syllabus Links acids and alkali pressure actionreaction

Method Citric acid sodium carbonate (23) grind as necessary Wrap carbcitric in tissue and put into the mouth of a old plastic 35mm film canister with water in the bottom Seal the lid firmly and invert - explodes as CO2 is releasedCitric can be replaced with lemonacetic (vinegar)

Safety Can be messy and surprisingly explosive ndash eyes

Thermit

Syllabus Links energetic reactions energy transfer

Method Thermit reactants (enough for TWO demonstrations)Iron (III) Oxide 374gAluminium powder 126 gMagnesium powder 3 spatulaBarium Oxide powder 3 spatulaMagnesium ribbonMix the iron and aluminium then cover with a mixture of the magnesium and barium oxide The Magnesium forms a wick to set off the reaction

Safety Thermit ndash messy and hot (molten iron 1500C +) Potentially this is one of the most dangerous of all the lsquoclassicrsquo reactions Can be unpredictable and explode from the pot

Methane Bubbles

Syllabus Links Energy transfer combustion

Method There are endless variations Methane long rubber hose The lsquobubblerrsquo is made from an inverted plastic soda bottle cut in half - discarding the base The cap of the soda bottle is replaced with a rubber bung through which has been inserted a glass tube The end of the tube has been bent over to form a hook which is below the level of the bubble mixture Methane is blown through the bubble mixture via a hose connected to the end of the tube

Bubble mixture many folk have their own secret recipe but generally 18 part dishwashing liquid 1 part water 2 tbs glycerine You may wish to lsquoSimpsonizersquo the experiment by adding blue food dye to the bubbles and a picture of Margersquos face to the bubble blower Ensure the students hands are we and no bubbles are under their hands Another variation is to lsquoshake offrsquo the bubbles and ignite in mid air

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Safety If you find yoursquove got a headache at the end of this you have insufficient ventilation Do not be tempted to over-do this one Do not forget to wet the students hands and have the hand stretched out fully and horizontal It is essential they wear goggles The flames tend to mushroom into the students face The experiment goes wrong when the students panic and drop their hands bringing the flames close to the face Have a sink of cold water near to hand the odd student will think they were burned

Gas explosion (various)

Syllabus Links Energy transfer combustion

Methane long rubber hose heat proof mats Pringles tube plastic soda bottle

Method See accompanying videos ndash much easier than explanation

Safety methaneair is relatively safe Should only be carried out in well ventilated laboratory

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Pringles lsquobombrsquo

Empty a tube of Pringles keeping the plastic lid Taking care not to otherwise damage the tube punchdrill a 10mm (or so) hole in the metal base In the side of the tube near the top drillpunch another hole 2-3mm in diameter (important) Put your finger over the large hole in the base and fill the tube with methane from a rubber hose Turn off the gas and push the tube onto the plastic cap which is now the base Remove your finger and light the gas forming a Pringles candle Discuss why the flame is yellow yadda yadda The students will forget about the tube as it apparently lsquogoes outrsquo Sometime later the gasair in the tube that has lsquogone outrsquo reaches an explosive limit and the can jumps up with a whoosh (safe to do on a desk in front of students They will ask to do it again Shake the can to replace the air inside and lsquoset it off againrsquo Waiting for it to pop is worse than the first time

Methane + oxygen

Syllabus Links energy transfer combustion rocket design

Method Using a PET soda bottle of MAXIMUM 500ml capacity fill with 23 oxygen to 13 methane This is best done by marking the bottle first then filling and inverting in water Measure the required gas volumes by displacement of water Close the bottle off using a balloon Support the bottle in a suitable holder and melt through the balloon with a gas lighter

Safety Only use carbonated drinks bottles as PVC bottle are significantly weakerThe explosion that will follow should propel the bottle 30 metres or more The explosion is EXTREMELY LOUD especially for the staff member melting through the balloon I have seen this done in a large lab but would recommend it only be done outside

Screaming Jelly babies

Syllabus Links energy transfer combustion rocket design

Method 5-10 g potassium chlorate in a boiling tube (will be destroyed) jelly babiesMelt the chlorate with a Bunsen then drop in the jelly baby

Safety It is suggested that this can be done in an open lab but I would never recommend this on the basis of the gassmoke produced if nothing else I only ever do this experiment in a fixed or portable fume hood Occasionally the Jelly baby fights back and refuses to slide down the tube You are now in the situation of a fire work that has not gone off If you try to poke the jelly baby down the tube you risk having your hand in the jet of the reaction It is safer to change the angle of the tube

alanglazetauntonsacuk

Balloon tricks

Syllabus Links Upthrust pressure 21st C materials and their properties Actionreaction

Method There are 101 balloon tricks Blow up a balloon and stick a pin in it It explodes Keep threatening to do thishelliphellipThe old trick is to put sellotape on the balloon and push a knitting needle through this The tape stops the tear in the rubber propagating At then end of the balloon there is a small lsquonipplersquo where the rubber is thicker ndash it is possible to push a sharp pinskewer through this without popping the balloon ndash Why

Try to push a balloon under waterhellip

Blow up a balloon and put it over a night-light candle The balloon bursts and the candle is snuffed out There is a lesson there alone ndash whyhellipPartially fill a balloon with water and then blow it up Hold the balloon over the candle ndash nothing happens why Show the soot on the base of the balloon ndash this is no trick A variation of this is to make a paper boat and fill with water Put this over a roaring Bunsen The paper will not burn whilst there is still water in the boat You may wish to add a tea bag for effect

Attach a balloon to a paper plane attached to a straw Pass a thread through the straw and use the balloon to project the plane along the thread across the class room Great fun

Inflate a balloon and statically charge it by rubbing or using a Van de GraffHold the balloon near a slowly running stream of water ndash why does the water bend How could you get the water to bend in the opposite directionBetter stillhellip Hold the charged balloon near a slowly pouring stream of golden syrup ndash with care you can get the syrup to bend horizontally

Water trickSyllabus Links lsquoFlogistan theoryrsquo pressure

Method Put a small amount of water coloured with food dye in a shallow plate Use a wedge of apple or orange to hold 4 matches Place the wedge with the matches in the water and light Quickly cover the matches with a glass ands press down firmly The water is sucked from the plate into the glass

Flaming money

Syllabus Links Combustion

alanglazetauntonsacuk

Method Soak paper money in a 50 solution of waterethanol The ethanol burns but the paper is protected by the water More spectacular (and riskyhellip) is to burn a scarf instead

Safety Do not ignite the beaker or anything else

Tea Bags

Syllabus Links Combustion

Method Unwrap the tea bag to give a hollow tube Put the tube on something valuable (pound5) and set fire to the top The panic comes when the flames approach the money buthellip

Safety Watch where the ignited bag goes

Rubens Tube

Syllabus Links Pressure sound

Method Signal generator Rubens Tube gas supply I have never seen a Rubens tube for sale but they are relatively easy to make (email for instructions) The Rubens tube is essentially a tube forming a gas grill One end for the tube is closed off with a plastic membrane which is vibrated by a speaker Us the signal generator to discuss the range of human youngold hearing

Safety The tube gets hot Residual gas in the tube can linger and smell

Magnetic Rail gun

Syllabus Links actionreaction magnetism

Method Easily constructed from electrical conduit cable ties and neodymium magnets The last ball leave the gun faster than the entering ball appearing to have gained energyhellip

Ferromagnetic Liquid Syllabus Links Magnetism

Method Ferrofluid can be bought from Ebay Cover with 50 IPAdeionised water in a glass jar

Safety Neodymium magnets can cause pinch injuries wipe data or smash the vessel the Ferrofluid is in

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Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

alanglazetauntonsacuk

Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

alanglazetauntonsacuk

This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

alanglazetauntonsacuk

Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

alanglazetauntonsacuk

5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

alanglazetauntonsacuk

diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

alanglazetauntonsacuk

pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

alanglazetauntonsacuk

food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

alanglazetauntonsacuk

1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

alanglazetauntonsacuk

5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

alanglazetauntonsacuk

a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

alanglazetauntonsacuk

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 4: Science Experiments

Wax from a candle kit or grated is place in a test tube (ca 3cm deep) and heated to a gentle boil over a roaring Bunsen The test tube is plunged into coldiced water to the height of the wax (no more or it kills the reaction) The cold water cracksshatters the tube and the column of steam carries the wax up into the air as it condenses as white clouds At about 05m the energy released as the wax goes from gas to solid causes spontaneous combustion and a resulting fire ball

Caution wear a glove (wax vapour is very hot) cover the desk use the same beaker as it is difficult to clean DO NOT BE TEMPTED TO SCALE UP NOT EVEN TO A BOILING TUBE

Silly putty

Syllabus Links Fun experiment ndash fits best with 21st C polymers ndash borax crosslinks the PVA polymer to change its physical properties depending on the degree of crosslinking the polymer goes from a viscous liquid to gel (silly putty) to a rubber

Method PVA water borax solution food dye 25 ml PVA adhesive 20ml water (you mar add a few drops of one or more food dyes for effect) 15ml borax solution (14 boraxwater) Add waterdye to PVA and stir Add borax solution and stir This should give lsquosilly puttyrsquo the reaction is relatively slow and the product will thicken with stirring or as it is played with Adding more borax solution will further crosslink the polymer turning it into a rubber The age and quality of the PVA and borax make quantities rather in exact A small trial should give the required amounts

Safety Silly putty may cause irritation if directly handled Insist that students wash thoroughly with soap and water after touching silly putty Students are not allowed to remove anything from the laboratory However they may be reluctant to part with a rubber ball they have made

Update ndash magnetic silly putty hellip add a spoon full of black iron oxideFe3O4 ndash the expensive black stuff not common red rust Fe203 This will create silly putty the will move with a super magenthellip

Possible source ebay Black iron oxide

See httpwwwyoutubecomwatchfeature=player_embeddedampv=UlCm9Pni6ME

Green fire

Syllabus Links Energetic reactions in KS3 chemistry displacement reactions AppliedAdditional science

alanglazetauntonsacuk

Method Ammonium nitrate (3g) salt (05g) ndash grind these together in a mortar and pestle Add zinc powder (7g) grind again Transfer to crucible add few drops water ndash stand clear

As soon as the zinc has been added take EXTREME care as the least drop of water will initiate this reaction

Safety lsquoDonrsquot try this at homersquo ammonium nitrate is readily available in most garden supply centres as it is a common fertiliser Hopefully students will not make this link This is an extremely vigorous reaction even a drop of sweat could initiate it

Nitrogen triiodide

1 The first step is to prepare the NI3 One method is to simply pour up to a gram of iodine crystals into a a small volume of concentrated aqueous ammonia allow the contents to sit for 5 minutes then pour the liquid over a filter paper to collect the NI3 which will be a dark brownblack solid However if you grind the pre-weighed iodine with a mortarpestle beforehand a larger surface area will be available for the iodine to react with the ammonia giving a significantly larger yield

2 The reaction for producing the nitrogen triiodide from iodine and ammonia is

3I2 + NH3 -gt NI3 + 3HI

3 You want to avoid handling the NI3 at all so my recommendation would be to set up the demonstration in advance of pouring off the ammonia Traditionally the demonstration uses a ring stand on which a wet filter paper with NI3 is placed with a second filter paper of damp NI3 sitting above the first The force of the decomposition reaction on one paper will cause decomposition to occur on the other paper as well

4 For optimal safety set up the ring stand with filter paper and pour the reacted solution over the paper where the demonstration is to occur A fume hood is the preferred location The demonstration location should be free of traffic and vibrations The decomposition is touch-sensitive and will be activated by the slightest vibration

5 To activate the decomposition tickle the dry NI3 solid with a feather attached to a long stick The decomposition occurs according to this reaction

2NI3 (s) --gt N2 (g) + 3I2 (g)

6 In its simplest form the demonstration is performed by pouring the damp solid onto a paper towel in a fume hood letting it dry and activating it with a meter stick

Tips

1 Caution This demonstration should only be performed by an instructor using proper safety precautions Wet NI3 is more stable than the dry compound but still should be handled with care Iodine will stain clothing and surfaces purple or orange The stain can be removed using a sodium thiosulfate solution Eye and ear protection are recommended Iodine is a respiratory and eye irritant the decomposition reaction is loud

2 NI3 in the ammonia is very stable and can be transported if the demonstration is to be performed at a remote location

3 How it works NI3 is highly unstable because of the size difference between the nitrogen and iodine atoms There is not enough room around the central nitrogen to keep the iodine atoms stable The bonds between the nuclei

alanglazetauntonsacuk

are under stress and therefore weakened The outside electrons of the iodine atoms are forced into close proximity which increases the instability of the molecule

4 The amount of energy released upon detonating NI3 exceeds that required to form the compound which is the definition of a high yield explosive

What You Need

up to 1 g iodine (do not use more) concentrated aqueous ammonia (0880 SG) filter paper or paper towel ring stand (optional) feather attached to a long stick

Pop Can Collapse

Syllabus Links Energy transfer pressure

Method -Put a little water in the can heat and invert into bowl of cold water ndash can collapses Physics ndash pressure the can becomes filled with hot water vapour inverted in the bowl the temperature drops

Safety Students can find it difficult to grip the can even more so to invert it into the bowl of cold water Inverting the can risks spraying boiling water

Empty soda cans tongs bowl of water Bunsen water

alanglazetauntonsacuk

Pocket Rockets

Syllabus Links acids and alkali pressure actionreaction

Method Citric acid sodium carbonate (23) grind as necessary Wrap carbcitric in tissue and put into the mouth of a old plastic 35mm film canister with water in the bottom Seal the lid firmly and invert - explodes as CO2 is releasedCitric can be replaced with lemonacetic (vinegar)

Safety Can be messy and surprisingly explosive ndash eyes

Thermit

Syllabus Links energetic reactions energy transfer

Method Thermit reactants (enough for TWO demonstrations)Iron (III) Oxide 374gAluminium powder 126 gMagnesium powder 3 spatulaBarium Oxide powder 3 spatulaMagnesium ribbonMix the iron and aluminium then cover with a mixture of the magnesium and barium oxide The Magnesium forms a wick to set off the reaction

Safety Thermit ndash messy and hot (molten iron 1500C +) Potentially this is one of the most dangerous of all the lsquoclassicrsquo reactions Can be unpredictable and explode from the pot

Methane Bubbles

Syllabus Links Energy transfer combustion

Method There are endless variations Methane long rubber hose The lsquobubblerrsquo is made from an inverted plastic soda bottle cut in half - discarding the base The cap of the soda bottle is replaced with a rubber bung through which has been inserted a glass tube The end of the tube has been bent over to form a hook which is below the level of the bubble mixture Methane is blown through the bubble mixture via a hose connected to the end of the tube

Bubble mixture many folk have their own secret recipe but generally 18 part dishwashing liquid 1 part water 2 tbs glycerine You may wish to lsquoSimpsonizersquo the experiment by adding blue food dye to the bubbles and a picture of Margersquos face to the bubble blower Ensure the students hands are we and no bubbles are under their hands Another variation is to lsquoshake offrsquo the bubbles and ignite in mid air

alanglazetauntonsacuk

Safety If you find yoursquove got a headache at the end of this you have insufficient ventilation Do not be tempted to over-do this one Do not forget to wet the students hands and have the hand stretched out fully and horizontal It is essential they wear goggles The flames tend to mushroom into the students face The experiment goes wrong when the students panic and drop their hands bringing the flames close to the face Have a sink of cold water near to hand the odd student will think they were burned

Gas explosion (various)

Syllabus Links Energy transfer combustion

Methane long rubber hose heat proof mats Pringles tube plastic soda bottle

Method See accompanying videos ndash much easier than explanation

Safety methaneair is relatively safe Should only be carried out in well ventilated laboratory

alanglazetauntonsacuk

Pringles lsquobombrsquo

Empty a tube of Pringles keeping the plastic lid Taking care not to otherwise damage the tube punchdrill a 10mm (or so) hole in the metal base In the side of the tube near the top drillpunch another hole 2-3mm in diameter (important) Put your finger over the large hole in the base and fill the tube with methane from a rubber hose Turn off the gas and push the tube onto the plastic cap which is now the base Remove your finger and light the gas forming a Pringles candle Discuss why the flame is yellow yadda yadda The students will forget about the tube as it apparently lsquogoes outrsquo Sometime later the gasair in the tube that has lsquogone outrsquo reaches an explosive limit and the can jumps up with a whoosh (safe to do on a desk in front of students They will ask to do it again Shake the can to replace the air inside and lsquoset it off againrsquo Waiting for it to pop is worse than the first time

Methane + oxygen

Syllabus Links energy transfer combustion rocket design

Method Using a PET soda bottle of MAXIMUM 500ml capacity fill with 23 oxygen to 13 methane This is best done by marking the bottle first then filling and inverting in water Measure the required gas volumes by displacement of water Close the bottle off using a balloon Support the bottle in a suitable holder and melt through the balloon with a gas lighter

Safety Only use carbonated drinks bottles as PVC bottle are significantly weakerThe explosion that will follow should propel the bottle 30 metres or more The explosion is EXTREMELY LOUD especially for the staff member melting through the balloon I have seen this done in a large lab but would recommend it only be done outside

Screaming Jelly babies

Syllabus Links energy transfer combustion rocket design

Method 5-10 g potassium chlorate in a boiling tube (will be destroyed) jelly babiesMelt the chlorate with a Bunsen then drop in the jelly baby

Safety It is suggested that this can be done in an open lab but I would never recommend this on the basis of the gassmoke produced if nothing else I only ever do this experiment in a fixed or portable fume hood Occasionally the Jelly baby fights back and refuses to slide down the tube You are now in the situation of a fire work that has not gone off If you try to poke the jelly baby down the tube you risk having your hand in the jet of the reaction It is safer to change the angle of the tube

alanglazetauntonsacuk

Balloon tricks

Syllabus Links Upthrust pressure 21st C materials and their properties Actionreaction

Method There are 101 balloon tricks Blow up a balloon and stick a pin in it It explodes Keep threatening to do thishelliphellipThe old trick is to put sellotape on the balloon and push a knitting needle through this The tape stops the tear in the rubber propagating At then end of the balloon there is a small lsquonipplersquo where the rubber is thicker ndash it is possible to push a sharp pinskewer through this without popping the balloon ndash Why

Try to push a balloon under waterhellip

Blow up a balloon and put it over a night-light candle The balloon bursts and the candle is snuffed out There is a lesson there alone ndash whyhellipPartially fill a balloon with water and then blow it up Hold the balloon over the candle ndash nothing happens why Show the soot on the base of the balloon ndash this is no trick A variation of this is to make a paper boat and fill with water Put this over a roaring Bunsen The paper will not burn whilst there is still water in the boat You may wish to add a tea bag for effect

Attach a balloon to a paper plane attached to a straw Pass a thread through the straw and use the balloon to project the plane along the thread across the class room Great fun

Inflate a balloon and statically charge it by rubbing or using a Van de GraffHold the balloon near a slowly running stream of water ndash why does the water bend How could you get the water to bend in the opposite directionBetter stillhellip Hold the charged balloon near a slowly pouring stream of golden syrup ndash with care you can get the syrup to bend horizontally

Water trickSyllabus Links lsquoFlogistan theoryrsquo pressure

Method Put a small amount of water coloured with food dye in a shallow plate Use a wedge of apple or orange to hold 4 matches Place the wedge with the matches in the water and light Quickly cover the matches with a glass ands press down firmly The water is sucked from the plate into the glass

Flaming money

Syllabus Links Combustion

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Method Soak paper money in a 50 solution of waterethanol The ethanol burns but the paper is protected by the water More spectacular (and riskyhellip) is to burn a scarf instead

Safety Do not ignite the beaker or anything else

Tea Bags

Syllabus Links Combustion

Method Unwrap the tea bag to give a hollow tube Put the tube on something valuable (pound5) and set fire to the top The panic comes when the flames approach the money buthellip

Safety Watch where the ignited bag goes

Rubens Tube

Syllabus Links Pressure sound

Method Signal generator Rubens Tube gas supply I have never seen a Rubens tube for sale but they are relatively easy to make (email for instructions) The Rubens tube is essentially a tube forming a gas grill One end for the tube is closed off with a plastic membrane which is vibrated by a speaker Us the signal generator to discuss the range of human youngold hearing

Safety The tube gets hot Residual gas in the tube can linger and smell

Magnetic Rail gun

Syllabus Links actionreaction magnetism

Method Easily constructed from electrical conduit cable ties and neodymium magnets The last ball leave the gun faster than the entering ball appearing to have gained energyhellip

Ferromagnetic Liquid Syllabus Links Magnetism

Method Ferrofluid can be bought from Ebay Cover with 50 IPAdeionised water in a glass jar

Safety Neodymium magnets can cause pinch injuries wipe data or smash the vessel the Ferrofluid is in

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Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

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Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

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This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

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Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

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5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

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diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

alanglazetauntonsacuk

pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

alanglazetauntonsacuk

The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 5: Science Experiments

Method Ammonium nitrate (3g) salt (05g) ndash grind these together in a mortar and pestle Add zinc powder (7g) grind again Transfer to crucible add few drops water ndash stand clear

As soon as the zinc has been added take EXTREME care as the least drop of water will initiate this reaction

Safety lsquoDonrsquot try this at homersquo ammonium nitrate is readily available in most garden supply centres as it is a common fertiliser Hopefully students will not make this link This is an extremely vigorous reaction even a drop of sweat could initiate it

Nitrogen triiodide

1 The first step is to prepare the NI3 One method is to simply pour up to a gram of iodine crystals into a a small volume of concentrated aqueous ammonia allow the contents to sit for 5 minutes then pour the liquid over a filter paper to collect the NI3 which will be a dark brownblack solid However if you grind the pre-weighed iodine with a mortarpestle beforehand a larger surface area will be available for the iodine to react with the ammonia giving a significantly larger yield

2 The reaction for producing the nitrogen triiodide from iodine and ammonia is

3I2 + NH3 -gt NI3 + 3HI

3 You want to avoid handling the NI3 at all so my recommendation would be to set up the demonstration in advance of pouring off the ammonia Traditionally the demonstration uses a ring stand on which a wet filter paper with NI3 is placed with a second filter paper of damp NI3 sitting above the first The force of the decomposition reaction on one paper will cause decomposition to occur on the other paper as well

4 For optimal safety set up the ring stand with filter paper and pour the reacted solution over the paper where the demonstration is to occur A fume hood is the preferred location The demonstration location should be free of traffic and vibrations The decomposition is touch-sensitive and will be activated by the slightest vibration

5 To activate the decomposition tickle the dry NI3 solid with a feather attached to a long stick The decomposition occurs according to this reaction

2NI3 (s) --gt N2 (g) + 3I2 (g)

6 In its simplest form the demonstration is performed by pouring the damp solid onto a paper towel in a fume hood letting it dry and activating it with a meter stick

Tips

1 Caution This demonstration should only be performed by an instructor using proper safety precautions Wet NI3 is more stable than the dry compound but still should be handled with care Iodine will stain clothing and surfaces purple or orange The stain can be removed using a sodium thiosulfate solution Eye and ear protection are recommended Iodine is a respiratory and eye irritant the decomposition reaction is loud

2 NI3 in the ammonia is very stable and can be transported if the demonstration is to be performed at a remote location

3 How it works NI3 is highly unstable because of the size difference between the nitrogen and iodine atoms There is not enough room around the central nitrogen to keep the iodine atoms stable The bonds between the nuclei

alanglazetauntonsacuk

are under stress and therefore weakened The outside electrons of the iodine atoms are forced into close proximity which increases the instability of the molecule

4 The amount of energy released upon detonating NI3 exceeds that required to form the compound which is the definition of a high yield explosive

What You Need

up to 1 g iodine (do not use more) concentrated aqueous ammonia (0880 SG) filter paper or paper towel ring stand (optional) feather attached to a long stick

Pop Can Collapse

Syllabus Links Energy transfer pressure

Method -Put a little water in the can heat and invert into bowl of cold water ndash can collapses Physics ndash pressure the can becomes filled with hot water vapour inverted in the bowl the temperature drops

Safety Students can find it difficult to grip the can even more so to invert it into the bowl of cold water Inverting the can risks spraying boiling water

Empty soda cans tongs bowl of water Bunsen water

alanglazetauntonsacuk

Pocket Rockets

Syllabus Links acids and alkali pressure actionreaction

Method Citric acid sodium carbonate (23) grind as necessary Wrap carbcitric in tissue and put into the mouth of a old plastic 35mm film canister with water in the bottom Seal the lid firmly and invert - explodes as CO2 is releasedCitric can be replaced with lemonacetic (vinegar)

Safety Can be messy and surprisingly explosive ndash eyes

Thermit

Syllabus Links energetic reactions energy transfer

Method Thermit reactants (enough for TWO demonstrations)Iron (III) Oxide 374gAluminium powder 126 gMagnesium powder 3 spatulaBarium Oxide powder 3 spatulaMagnesium ribbonMix the iron and aluminium then cover with a mixture of the magnesium and barium oxide The Magnesium forms a wick to set off the reaction

Safety Thermit ndash messy and hot (molten iron 1500C +) Potentially this is one of the most dangerous of all the lsquoclassicrsquo reactions Can be unpredictable and explode from the pot

Methane Bubbles

Syllabus Links Energy transfer combustion

Method There are endless variations Methane long rubber hose The lsquobubblerrsquo is made from an inverted plastic soda bottle cut in half - discarding the base The cap of the soda bottle is replaced with a rubber bung through which has been inserted a glass tube The end of the tube has been bent over to form a hook which is below the level of the bubble mixture Methane is blown through the bubble mixture via a hose connected to the end of the tube

Bubble mixture many folk have their own secret recipe but generally 18 part dishwashing liquid 1 part water 2 tbs glycerine You may wish to lsquoSimpsonizersquo the experiment by adding blue food dye to the bubbles and a picture of Margersquos face to the bubble blower Ensure the students hands are we and no bubbles are under their hands Another variation is to lsquoshake offrsquo the bubbles and ignite in mid air

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Safety If you find yoursquove got a headache at the end of this you have insufficient ventilation Do not be tempted to over-do this one Do not forget to wet the students hands and have the hand stretched out fully and horizontal It is essential they wear goggles The flames tend to mushroom into the students face The experiment goes wrong when the students panic and drop their hands bringing the flames close to the face Have a sink of cold water near to hand the odd student will think they were burned

Gas explosion (various)

Syllabus Links Energy transfer combustion

Methane long rubber hose heat proof mats Pringles tube plastic soda bottle

Method See accompanying videos ndash much easier than explanation

Safety methaneair is relatively safe Should only be carried out in well ventilated laboratory

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Pringles lsquobombrsquo

Empty a tube of Pringles keeping the plastic lid Taking care not to otherwise damage the tube punchdrill a 10mm (or so) hole in the metal base In the side of the tube near the top drillpunch another hole 2-3mm in diameter (important) Put your finger over the large hole in the base and fill the tube with methane from a rubber hose Turn off the gas and push the tube onto the plastic cap which is now the base Remove your finger and light the gas forming a Pringles candle Discuss why the flame is yellow yadda yadda The students will forget about the tube as it apparently lsquogoes outrsquo Sometime later the gasair in the tube that has lsquogone outrsquo reaches an explosive limit and the can jumps up with a whoosh (safe to do on a desk in front of students They will ask to do it again Shake the can to replace the air inside and lsquoset it off againrsquo Waiting for it to pop is worse than the first time

Methane + oxygen

Syllabus Links energy transfer combustion rocket design

Method Using a PET soda bottle of MAXIMUM 500ml capacity fill with 23 oxygen to 13 methane This is best done by marking the bottle first then filling and inverting in water Measure the required gas volumes by displacement of water Close the bottle off using a balloon Support the bottle in a suitable holder and melt through the balloon with a gas lighter

Safety Only use carbonated drinks bottles as PVC bottle are significantly weakerThe explosion that will follow should propel the bottle 30 metres or more The explosion is EXTREMELY LOUD especially for the staff member melting through the balloon I have seen this done in a large lab but would recommend it only be done outside

Screaming Jelly babies

Syllabus Links energy transfer combustion rocket design

Method 5-10 g potassium chlorate in a boiling tube (will be destroyed) jelly babiesMelt the chlorate with a Bunsen then drop in the jelly baby

Safety It is suggested that this can be done in an open lab but I would never recommend this on the basis of the gassmoke produced if nothing else I only ever do this experiment in a fixed or portable fume hood Occasionally the Jelly baby fights back and refuses to slide down the tube You are now in the situation of a fire work that has not gone off If you try to poke the jelly baby down the tube you risk having your hand in the jet of the reaction It is safer to change the angle of the tube

alanglazetauntonsacuk

Balloon tricks

Syllabus Links Upthrust pressure 21st C materials and their properties Actionreaction

Method There are 101 balloon tricks Blow up a balloon and stick a pin in it It explodes Keep threatening to do thishelliphellipThe old trick is to put sellotape on the balloon and push a knitting needle through this The tape stops the tear in the rubber propagating At then end of the balloon there is a small lsquonipplersquo where the rubber is thicker ndash it is possible to push a sharp pinskewer through this without popping the balloon ndash Why

Try to push a balloon under waterhellip

Blow up a balloon and put it over a night-light candle The balloon bursts and the candle is snuffed out There is a lesson there alone ndash whyhellipPartially fill a balloon with water and then blow it up Hold the balloon over the candle ndash nothing happens why Show the soot on the base of the balloon ndash this is no trick A variation of this is to make a paper boat and fill with water Put this over a roaring Bunsen The paper will not burn whilst there is still water in the boat You may wish to add a tea bag for effect

Attach a balloon to a paper plane attached to a straw Pass a thread through the straw and use the balloon to project the plane along the thread across the class room Great fun

Inflate a balloon and statically charge it by rubbing or using a Van de GraffHold the balloon near a slowly running stream of water ndash why does the water bend How could you get the water to bend in the opposite directionBetter stillhellip Hold the charged balloon near a slowly pouring stream of golden syrup ndash with care you can get the syrup to bend horizontally

Water trickSyllabus Links lsquoFlogistan theoryrsquo pressure

Method Put a small amount of water coloured with food dye in a shallow plate Use a wedge of apple or orange to hold 4 matches Place the wedge with the matches in the water and light Quickly cover the matches with a glass ands press down firmly The water is sucked from the plate into the glass

Flaming money

Syllabus Links Combustion

alanglazetauntonsacuk

Method Soak paper money in a 50 solution of waterethanol The ethanol burns but the paper is protected by the water More spectacular (and riskyhellip) is to burn a scarf instead

Safety Do not ignite the beaker or anything else

Tea Bags

Syllabus Links Combustion

Method Unwrap the tea bag to give a hollow tube Put the tube on something valuable (pound5) and set fire to the top The panic comes when the flames approach the money buthellip

Safety Watch where the ignited bag goes

Rubens Tube

Syllabus Links Pressure sound

Method Signal generator Rubens Tube gas supply I have never seen a Rubens tube for sale but they are relatively easy to make (email for instructions) The Rubens tube is essentially a tube forming a gas grill One end for the tube is closed off with a plastic membrane which is vibrated by a speaker Us the signal generator to discuss the range of human youngold hearing

Safety The tube gets hot Residual gas in the tube can linger and smell

Magnetic Rail gun

Syllabus Links actionreaction magnetism

Method Easily constructed from electrical conduit cable ties and neodymium magnets The last ball leave the gun faster than the entering ball appearing to have gained energyhellip

Ferromagnetic Liquid Syllabus Links Magnetism

Method Ferrofluid can be bought from Ebay Cover with 50 IPAdeionised water in a glass jar

Safety Neodymium magnets can cause pinch injuries wipe data or smash the vessel the Ferrofluid is in

alanglazetauntonsacuk

Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

alanglazetauntonsacuk

4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

alanglazetauntonsacuk

Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

alanglazetauntonsacuk

This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

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Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

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5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

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diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

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pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

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  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 6: Science Experiments

are under stress and therefore weakened The outside electrons of the iodine atoms are forced into close proximity which increases the instability of the molecule

4 The amount of energy released upon detonating NI3 exceeds that required to form the compound which is the definition of a high yield explosive

What You Need

up to 1 g iodine (do not use more) concentrated aqueous ammonia (0880 SG) filter paper or paper towel ring stand (optional) feather attached to a long stick

Pop Can Collapse

Syllabus Links Energy transfer pressure

Method -Put a little water in the can heat and invert into bowl of cold water ndash can collapses Physics ndash pressure the can becomes filled with hot water vapour inverted in the bowl the temperature drops

Safety Students can find it difficult to grip the can even more so to invert it into the bowl of cold water Inverting the can risks spraying boiling water

Empty soda cans tongs bowl of water Bunsen water

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Pocket Rockets

Syllabus Links acids and alkali pressure actionreaction

Method Citric acid sodium carbonate (23) grind as necessary Wrap carbcitric in tissue and put into the mouth of a old plastic 35mm film canister with water in the bottom Seal the lid firmly and invert - explodes as CO2 is releasedCitric can be replaced with lemonacetic (vinegar)

Safety Can be messy and surprisingly explosive ndash eyes

Thermit

Syllabus Links energetic reactions energy transfer

Method Thermit reactants (enough for TWO demonstrations)Iron (III) Oxide 374gAluminium powder 126 gMagnesium powder 3 spatulaBarium Oxide powder 3 spatulaMagnesium ribbonMix the iron and aluminium then cover with a mixture of the magnesium and barium oxide The Magnesium forms a wick to set off the reaction

Safety Thermit ndash messy and hot (molten iron 1500C +) Potentially this is one of the most dangerous of all the lsquoclassicrsquo reactions Can be unpredictable and explode from the pot

Methane Bubbles

Syllabus Links Energy transfer combustion

Method There are endless variations Methane long rubber hose The lsquobubblerrsquo is made from an inverted plastic soda bottle cut in half - discarding the base The cap of the soda bottle is replaced with a rubber bung through which has been inserted a glass tube The end of the tube has been bent over to form a hook which is below the level of the bubble mixture Methane is blown through the bubble mixture via a hose connected to the end of the tube

Bubble mixture many folk have their own secret recipe but generally 18 part dishwashing liquid 1 part water 2 tbs glycerine You may wish to lsquoSimpsonizersquo the experiment by adding blue food dye to the bubbles and a picture of Margersquos face to the bubble blower Ensure the students hands are we and no bubbles are under their hands Another variation is to lsquoshake offrsquo the bubbles and ignite in mid air

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Safety If you find yoursquove got a headache at the end of this you have insufficient ventilation Do not be tempted to over-do this one Do not forget to wet the students hands and have the hand stretched out fully and horizontal It is essential they wear goggles The flames tend to mushroom into the students face The experiment goes wrong when the students panic and drop their hands bringing the flames close to the face Have a sink of cold water near to hand the odd student will think they were burned

Gas explosion (various)

Syllabus Links Energy transfer combustion

Methane long rubber hose heat proof mats Pringles tube plastic soda bottle

Method See accompanying videos ndash much easier than explanation

Safety methaneair is relatively safe Should only be carried out in well ventilated laboratory

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Pringles lsquobombrsquo

Empty a tube of Pringles keeping the plastic lid Taking care not to otherwise damage the tube punchdrill a 10mm (or so) hole in the metal base In the side of the tube near the top drillpunch another hole 2-3mm in diameter (important) Put your finger over the large hole in the base and fill the tube with methane from a rubber hose Turn off the gas and push the tube onto the plastic cap which is now the base Remove your finger and light the gas forming a Pringles candle Discuss why the flame is yellow yadda yadda The students will forget about the tube as it apparently lsquogoes outrsquo Sometime later the gasair in the tube that has lsquogone outrsquo reaches an explosive limit and the can jumps up with a whoosh (safe to do on a desk in front of students They will ask to do it again Shake the can to replace the air inside and lsquoset it off againrsquo Waiting for it to pop is worse than the first time

Methane + oxygen

Syllabus Links energy transfer combustion rocket design

Method Using a PET soda bottle of MAXIMUM 500ml capacity fill with 23 oxygen to 13 methane This is best done by marking the bottle first then filling and inverting in water Measure the required gas volumes by displacement of water Close the bottle off using a balloon Support the bottle in a suitable holder and melt through the balloon with a gas lighter

Safety Only use carbonated drinks bottles as PVC bottle are significantly weakerThe explosion that will follow should propel the bottle 30 metres or more The explosion is EXTREMELY LOUD especially for the staff member melting through the balloon I have seen this done in a large lab but would recommend it only be done outside

Screaming Jelly babies

Syllabus Links energy transfer combustion rocket design

Method 5-10 g potassium chlorate in a boiling tube (will be destroyed) jelly babiesMelt the chlorate with a Bunsen then drop in the jelly baby

Safety It is suggested that this can be done in an open lab but I would never recommend this on the basis of the gassmoke produced if nothing else I only ever do this experiment in a fixed or portable fume hood Occasionally the Jelly baby fights back and refuses to slide down the tube You are now in the situation of a fire work that has not gone off If you try to poke the jelly baby down the tube you risk having your hand in the jet of the reaction It is safer to change the angle of the tube

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Balloon tricks

Syllabus Links Upthrust pressure 21st C materials and their properties Actionreaction

Method There are 101 balloon tricks Blow up a balloon and stick a pin in it It explodes Keep threatening to do thishelliphellipThe old trick is to put sellotape on the balloon and push a knitting needle through this The tape stops the tear in the rubber propagating At then end of the balloon there is a small lsquonipplersquo where the rubber is thicker ndash it is possible to push a sharp pinskewer through this without popping the balloon ndash Why

Try to push a balloon under waterhellip

Blow up a balloon and put it over a night-light candle The balloon bursts and the candle is snuffed out There is a lesson there alone ndash whyhellipPartially fill a balloon with water and then blow it up Hold the balloon over the candle ndash nothing happens why Show the soot on the base of the balloon ndash this is no trick A variation of this is to make a paper boat and fill with water Put this over a roaring Bunsen The paper will not burn whilst there is still water in the boat You may wish to add a tea bag for effect

Attach a balloon to a paper plane attached to a straw Pass a thread through the straw and use the balloon to project the plane along the thread across the class room Great fun

Inflate a balloon and statically charge it by rubbing or using a Van de GraffHold the balloon near a slowly running stream of water ndash why does the water bend How could you get the water to bend in the opposite directionBetter stillhellip Hold the charged balloon near a slowly pouring stream of golden syrup ndash with care you can get the syrup to bend horizontally

Water trickSyllabus Links lsquoFlogistan theoryrsquo pressure

Method Put a small amount of water coloured with food dye in a shallow plate Use a wedge of apple or orange to hold 4 matches Place the wedge with the matches in the water and light Quickly cover the matches with a glass ands press down firmly The water is sucked from the plate into the glass

Flaming money

Syllabus Links Combustion

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Method Soak paper money in a 50 solution of waterethanol The ethanol burns but the paper is protected by the water More spectacular (and riskyhellip) is to burn a scarf instead

Safety Do not ignite the beaker or anything else

Tea Bags

Syllabus Links Combustion

Method Unwrap the tea bag to give a hollow tube Put the tube on something valuable (pound5) and set fire to the top The panic comes when the flames approach the money buthellip

Safety Watch where the ignited bag goes

Rubens Tube

Syllabus Links Pressure sound

Method Signal generator Rubens Tube gas supply I have never seen a Rubens tube for sale but they are relatively easy to make (email for instructions) The Rubens tube is essentially a tube forming a gas grill One end for the tube is closed off with a plastic membrane which is vibrated by a speaker Us the signal generator to discuss the range of human youngold hearing

Safety The tube gets hot Residual gas in the tube can linger and smell

Magnetic Rail gun

Syllabus Links actionreaction magnetism

Method Easily constructed from electrical conduit cable ties and neodymium magnets The last ball leave the gun faster than the entering ball appearing to have gained energyhellip

Ferromagnetic Liquid Syllabus Links Magnetism

Method Ferrofluid can be bought from Ebay Cover with 50 IPAdeionised water in a glass jar

Safety Neodymium magnets can cause pinch injuries wipe data or smash the vessel the Ferrofluid is in

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Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

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Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

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This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

alanglazetauntonsacuk

Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

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5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

alanglazetauntonsacuk

diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

alanglazetauntonsacuk

pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

alanglazetauntonsacuk

food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

alanglazetauntonsacuk

1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

alanglazetauntonsacuk

5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

alanglazetauntonsacuk

a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

alanglazetauntonsacuk

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
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  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
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  • Whatrsquos happening
  • What you need
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  • What you need
  • What to do
  • What you need
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  • Whats happening
  • What you need
  • What To Do
  • Whats happening
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  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 7: Science Experiments

Pocket Rockets

Syllabus Links acids and alkali pressure actionreaction

Method Citric acid sodium carbonate (23) grind as necessary Wrap carbcitric in tissue and put into the mouth of a old plastic 35mm film canister with water in the bottom Seal the lid firmly and invert - explodes as CO2 is releasedCitric can be replaced with lemonacetic (vinegar)

Safety Can be messy and surprisingly explosive ndash eyes

Thermit

Syllabus Links energetic reactions energy transfer

Method Thermit reactants (enough for TWO demonstrations)Iron (III) Oxide 374gAluminium powder 126 gMagnesium powder 3 spatulaBarium Oxide powder 3 spatulaMagnesium ribbonMix the iron and aluminium then cover with a mixture of the magnesium and barium oxide The Magnesium forms a wick to set off the reaction

Safety Thermit ndash messy and hot (molten iron 1500C +) Potentially this is one of the most dangerous of all the lsquoclassicrsquo reactions Can be unpredictable and explode from the pot

Methane Bubbles

Syllabus Links Energy transfer combustion

Method There are endless variations Methane long rubber hose The lsquobubblerrsquo is made from an inverted plastic soda bottle cut in half - discarding the base The cap of the soda bottle is replaced with a rubber bung through which has been inserted a glass tube The end of the tube has been bent over to form a hook which is below the level of the bubble mixture Methane is blown through the bubble mixture via a hose connected to the end of the tube

Bubble mixture many folk have their own secret recipe but generally 18 part dishwashing liquid 1 part water 2 tbs glycerine You may wish to lsquoSimpsonizersquo the experiment by adding blue food dye to the bubbles and a picture of Margersquos face to the bubble blower Ensure the students hands are we and no bubbles are under their hands Another variation is to lsquoshake offrsquo the bubbles and ignite in mid air

alanglazetauntonsacuk

Safety If you find yoursquove got a headache at the end of this you have insufficient ventilation Do not be tempted to over-do this one Do not forget to wet the students hands and have the hand stretched out fully and horizontal It is essential they wear goggles The flames tend to mushroom into the students face The experiment goes wrong when the students panic and drop their hands bringing the flames close to the face Have a sink of cold water near to hand the odd student will think they were burned

Gas explosion (various)

Syllabus Links Energy transfer combustion

Methane long rubber hose heat proof mats Pringles tube plastic soda bottle

Method See accompanying videos ndash much easier than explanation

Safety methaneair is relatively safe Should only be carried out in well ventilated laboratory

alanglazetauntonsacuk

Pringles lsquobombrsquo

Empty a tube of Pringles keeping the plastic lid Taking care not to otherwise damage the tube punchdrill a 10mm (or so) hole in the metal base In the side of the tube near the top drillpunch another hole 2-3mm in diameter (important) Put your finger over the large hole in the base and fill the tube with methane from a rubber hose Turn off the gas and push the tube onto the plastic cap which is now the base Remove your finger and light the gas forming a Pringles candle Discuss why the flame is yellow yadda yadda The students will forget about the tube as it apparently lsquogoes outrsquo Sometime later the gasair in the tube that has lsquogone outrsquo reaches an explosive limit and the can jumps up with a whoosh (safe to do on a desk in front of students They will ask to do it again Shake the can to replace the air inside and lsquoset it off againrsquo Waiting for it to pop is worse than the first time

Methane + oxygen

Syllabus Links energy transfer combustion rocket design

Method Using a PET soda bottle of MAXIMUM 500ml capacity fill with 23 oxygen to 13 methane This is best done by marking the bottle first then filling and inverting in water Measure the required gas volumes by displacement of water Close the bottle off using a balloon Support the bottle in a suitable holder and melt through the balloon with a gas lighter

Safety Only use carbonated drinks bottles as PVC bottle are significantly weakerThe explosion that will follow should propel the bottle 30 metres or more The explosion is EXTREMELY LOUD especially for the staff member melting through the balloon I have seen this done in a large lab but would recommend it only be done outside

Screaming Jelly babies

Syllabus Links energy transfer combustion rocket design

Method 5-10 g potassium chlorate in a boiling tube (will be destroyed) jelly babiesMelt the chlorate with a Bunsen then drop in the jelly baby

Safety It is suggested that this can be done in an open lab but I would never recommend this on the basis of the gassmoke produced if nothing else I only ever do this experiment in a fixed or portable fume hood Occasionally the Jelly baby fights back and refuses to slide down the tube You are now in the situation of a fire work that has not gone off If you try to poke the jelly baby down the tube you risk having your hand in the jet of the reaction It is safer to change the angle of the tube

alanglazetauntonsacuk

Balloon tricks

Syllabus Links Upthrust pressure 21st C materials and their properties Actionreaction

Method There are 101 balloon tricks Blow up a balloon and stick a pin in it It explodes Keep threatening to do thishelliphellipThe old trick is to put sellotape on the balloon and push a knitting needle through this The tape stops the tear in the rubber propagating At then end of the balloon there is a small lsquonipplersquo where the rubber is thicker ndash it is possible to push a sharp pinskewer through this without popping the balloon ndash Why

Try to push a balloon under waterhellip

Blow up a balloon and put it over a night-light candle The balloon bursts and the candle is snuffed out There is a lesson there alone ndash whyhellipPartially fill a balloon with water and then blow it up Hold the balloon over the candle ndash nothing happens why Show the soot on the base of the balloon ndash this is no trick A variation of this is to make a paper boat and fill with water Put this over a roaring Bunsen The paper will not burn whilst there is still water in the boat You may wish to add a tea bag for effect

Attach a balloon to a paper plane attached to a straw Pass a thread through the straw and use the balloon to project the plane along the thread across the class room Great fun

Inflate a balloon and statically charge it by rubbing or using a Van de GraffHold the balloon near a slowly running stream of water ndash why does the water bend How could you get the water to bend in the opposite directionBetter stillhellip Hold the charged balloon near a slowly pouring stream of golden syrup ndash with care you can get the syrup to bend horizontally

Water trickSyllabus Links lsquoFlogistan theoryrsquo pressure

Method Put a small amount of water coloured with food dye in a shallow plate Use a wedge of apple or orange to hold 4 matches Place the wedge with the matches in the water and light Quickly cover the matches with a glass ands press down firmly The water is sucked from the plate into the glass

Flaming money

Syllabus Links Combustion

alanglazetauntonsacuk

Method Soak paper money in a 50 solution of waterethanol The ethanol burns but the paper is protected by the water More spectacular (and riskyhellip) is to burn a scarf instead

Safety Do not ignite the beaker or anything else

Tea Bags

Syllabus Links Combustion

Method Unwrap the tea bag to give a hollow tube Put the tube on something valuable (pound5) and set fire to the top The panic comes when the flames approach the money buthellip

Safety Watch where the ignited bag goes

Rubens Tube

Syllabus Links Pressure sound

Method Signal generator Rubens Tube gas supply I have never seen a Rubens tube for sale but they are relatively easy to make (email for instructions) The Rubens tube is essentially a tube forming a gas grill One end for the tube is closed off with a plastic membrane which is vibrated by a speaker Us the signal generator to discuss the range of human youngold hearing

Safety The tube gets hot Residual gas in the tube can linger and smell

Magnetic Rail gun

Syllabus Links actionreaction magnetism

Method Easily constructed from electrical conduit cable ties and neodymium magnets The last ball leave the gun faster than the entering ball appearing to have gained energyhellip

Ferromagnetic Liquid Syllabus Links Magnetism

Method Ferrofluid can be bought from Ebay Cover with 50 IPAdeionised water in a glass jar

Safety Neodymium magnets can cause pinch injuries wipe data or smash the vessel the Ferrofluid is in

alanglazetauntonsacuk

Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

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Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

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This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

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Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

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5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

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diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

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pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

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Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

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A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
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  • What to do
  • Whatrsquos happening
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  • What you need
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  • What you need
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  • Whats happening
  • What you need
  • What To Do
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  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
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  • What to do
  • Whats happening
  • What to do
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  • What you need
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  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
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  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 8: Science Experiments

Safety If you find yoursquove got a headache at the end of this you have insufficient ventilation Do not be tempted to over-do this one Do not forget to wet the students hands and have the hand stretched out fully and horizontal It is essential they wear goggles The flames tend to mushroom into the students face The experiment goes wrong when the students panic and drop their hands bringing the flames close to the face Have a sink of cold water near to hand the odd student will think they were burned

Gas explosion (various)

Syllabus Links Energy transfer combustion

Methane long rubber hose heat proof mats Pringles tube plastic soda bottle

Method See accompanying videos ndash much easier than explanation

Safety methaneair is relatively safe Should only be carried out in well ventilated laboratory

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Pringles lsquobombrsquo

Empty a tube of Pringles keeping the plastic lid Taking care not to otherwise damage the tube punchdrill a 10mm (or so) hole in the metal base In the side of the tube near the top drillpunch another hole 2-3mm in diameter (important) Put your finger over the large hole in the base and fill the tube with methane from a rubber hose Turn off the gas and push the tube onto the plastic cap which is now the base Remove your finger and light the gas forming a Pringles candle Discuss why the flame is yellow yadda yadda The students will forget about the tube as it apparently lsquogoes outrsquo Sometime later the gasair in the tube that has lsquogone outrsquo reaches an explosive limit and the can jumps up with a whoosh (safe to do on a desk in front of students They will ask to do it again Shake the can to replace the air inside and lsquoset it off againrsquo Waiting for it to pop is worse than the first time

Methane + oxygen

Syllabus Links energy transfer combustion rocket design

Method Using a PET soda bottle of MAXIMUM 500ml capacity fill with 23 oxygen to 13 methane This is best done by marking the bottle first then filling and inverting in water Measure the required gas volumes by displacement of water Close the bottle off using a balloon Support the bottle in a suitable holder and melt through the balloon with a gas lighter

Safety Only use carbonated drinks bottles as PVC bottle are significantly weakerThe explosion that will follow should propel the bottle 30 metres or more The explosion is EXTREMELY LOUD especially for the staff member melting through the balloon I have seen this done in a large lab but would recommend it only be done outside

Screaming Jelly babies

Syllabus Links energy transfer combustion rocket design

Method 5-10 g potassium chlorate in a boiling tube (will be destroyed) jelly babiesMelt the chlorate with a Bunsen then drop in the jelly baby

Safety It is suggested that this can be done in an open lab but I would never recommend this on the basis of the gassmoke produced if nothing else I only ever do this experiment in a fixed or portable fume hood Occasionally the Jelly baby fights back and refuses to slide down the tube You are now in the situation of a fire work that has not gone off If you try to poke the jelly baby down the tube you risk having your hand in the jet of the reaction It is safer to change the angle of the tube

alanglazetauntonsacuk

Balloon tricks

Syllabus Links Upthrust pressure 21st C materials and their properties Actionreaction

Method There are 101 balloon tricks Blow up a balloon and stick a pin in it It explodes Keep threatening to do thishelliphellipThe old trick is to put sellotape on the balloon and push a knitting needle through this The tape stops the tear in the rubber propagating At then end of the balloon there is a small lsquonipplersquo where the rubber is thicker ndash it is possible to push a sharp pinskewer through this without popping the balloon ndash Why

Try to push a balloon under waterhellip

Blow up a balloon and put it over a night-light candle The balloon bursts and the candle is snuffed out There is a lesson there alone ndash whyhellipPartially fill a balloon with water and then blow it up Hold the balloon over the candle ndash nothing happens why Show the soot on the base of the balloon ndash this is no trick A variation of this is to make a paper boat and fill with water Put this over a roaring Bunsen The paper will not burn whilst there is still water in the boat You may wish to add a tea bag for effect

Attach a balloon to a paper plane attached to a straw Pass a thread through the straw and use the balloon to project the plane along the thread across the class room Great fun

Inflate a balloon and statically charge it by rubbing or using a Van de GraffHold the balloon near a slowly running stream of water ndash why does the water bend How could you get the water to bend in the opposite directionBetter stillhellip Hold the charged balloon near a slowly pouring stream of golden syrup ndash with care you can get the syrup to bend horizontally

Water trickSyllabus Links lsquoFlogistan theoryrsquo pressure

Method Put a small amount of water coloured with food dye in a shallow plate Use a wedge of apple or orange to hold 4 matches Place the wedge with the matches in the water and light Quickly cover the matches with a glass ands press down firmly The water is sucked from the plate into the glass

Flaming money

Syllabus Links Combustion

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Method Soak paper money in a 50 solution of waterethanol The ethanol burns but the paper is protected by the water More spectacular (and riskyhellip) is to burn a scarf instead

Safety Do not ignite the beaker or anything else

Tea Bags

Syllabus Links Combustion

Method Unwrap the tea bag to give a hollow tube Put the tube on something valuable (pound5) and set fire to the top The panic comes when the flames approach the money buthellip

Safety Watch where the ignited bag goes

Rubens Tube

Syllabus Links Pressure sound

Method Signal generator Rubens Tube gas supply I have never seen a Rubens tube for sale but they are relatively easy to make (email for instructions) The Rubens tube is essentially a tube forming a gas grill One end for the tube is closed off with a plastic membrane which is vibrated by a speaker Us the signal generator to discuss the range of human youngold hearing

Safety The tube gets hot Residual gas in the tube can linger and smell

Magnetic Rail gun

Syllabus Links actionreaction magnetism

Method Easily constructed from electrical conduit cable ties and neodymium magnets The last ball leave the gun faster than the entering ball appearing to have gained energyhellip

Ferromagnetic Liquid Syllabus Links Magnetism

Method Ferrofluid can be bought from Ebay Cover with 50 IPAdeionised water in a glass jar

Safety Neodymium magnets can cause pinch injuries wipe data or smash the vessel the Ferrofluid is in

alanglazetauntonsacuk

Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

alanglazetauntonsacuk

Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

alanglazetauntonsacuk

This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

alanglazetauntonsacuk

Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

alanglazetauntonsacuk

5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

alanglazetauntonsacuk

diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

alanglazetauntonsacuk

pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

alanglazetauntonsacuk

1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

alanglazetauntonsacuk

4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

alanglazetauntonsacuk

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

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Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 9: Science Experiments

Pringles lsquobombrsquo

Empty a tube of Pringles keeping the plastic lid Taking care not to otherwise damage the tube punchdrill a 10mm (or so) hole in the metal base In the side of the tube near the top drillpunch another hole 2-3mm in diameter (important) Put your finger over the large hole in the base and fill the tube with methane from a rubber hose Turn off the gas and push the tube onto the plastic cap which is now the base Remove your finger and light the gas forming a Pringles candle Discuss why the flame is yellow yadda yadda The students will forget about the tube as it apparently lsquogoes outrsquo Sometime later the gasair in the tube that has lsquogone outrsquo reaches an explosive limit and the can jumps up with a whoosh (safe to do on a desk in front of students They will ask to do it again Shake the can to replace the air inside and lsquoset it off againrsquo Waiting for it to pop is worse than the first time

Methane + oxygen

Syllabus Links energy transfer combustion rocket design

Method Using a PET soda bottle of MAXIMUM 500ml capacity fill with 23 oxygen to 13 methane This is best done by marking the bottle first then filling and inverting in water Measure the required gas volumes by displacement of water Close the bottle off using a balloon Support the bottle in a suitable holder and melt through the balloon with a gas lighter

Safety Only use carbonated drinks bottles as PVC bottle are significantly weakerThe explosion that will follow should propel the bottle 30 metres or more The explosion is EXTREMELY LOUD especially for the staff member melting through the balloon I have seen this done in a large lab but would recommend it only be done outside

Screaming Jelly babies

Syllabus Links energy transfer combustion rocket design

Method 5-10 g potassium chlorate in a boiling tube (will be destroyed) jelly babiesMelt the chlorate with a Bunsen then drop in the jelly baby

Safety It is suggested that this can be done in an open lab but I would never recommend this on the basis of the gassmoke produced if nothing else I only ever do this experiment in a fixed or portable fume hood Occasionally the Jelly baby fights back and refuses to slide down the tube You are now in the situation of a fire work that has not gone off If you try to poke the jelly baby down the tube you risk having your hand in the jet of the reaction It is safer to change the angle of the tube

alanglazetauntonsacuk

Balloon tricks

Syllabus Links Upthrust pressure 21st C materials and their properties Actionreaction

Method There are 101 balloon tricks Blow up a balloon and stick a pin in it It explodes Keep threatening to do thishelliphellipThe old trick is to put sellotape on the balloon and push a knitting needle through this The tape stops the tear in the rubber propagating At then end of the balloon there is a small lsquonipplersquo where the rubber is thicker ndash it is possible to push a sharp pinskewer through this without popping the balloon ndash Why

Try to push a balloon under waterhellip

Blow up a balloon and put it over a night-light candle The balloon bursts and the candle is snuffed out There is a lesson there alone ndash whyhellipPartially fill a balloon with water and then blow it up Hold the balloon over the candle ndash nothing happens why Show the soot on the base of the balloon ndash this is no trick A variation of this is to make a paper boat and fill with water Put this over a roaring Bunsen The paper will not burn whilst there is still water in the boat You may wish to add a tea bag for effect

Attach a balloon to a paper plane attached to a straw Pass a thread through the straw and use the balloon to project the plane along the thread across the class room Great fun

Inflate a balloon and statically charge it by rubbing or using a Van de GraffHold the balloon near a slowly running stream of water ndash why does the water bend How could you get the water to bend in the opposite directionBetter stillhellip Hold the charged balloon near a slowly pouring stream of golden syrup ndash with care you can get the syrup to bend horizontally

Water trickSyllabus Links lsquoFlogistan theoryrsquo pressure

Method Put a small amount of water coloured with food dye in a shallow plate Use a wedge of apple or orange to hold 4 matches Place the wedge with the matches in the water and light Quickly cover the matches with a glass ands press down firmly The water is sucked from the plate into the glass

Flaming money

Syllabus Links Combustion

alanglazetauntonsacuk

Method Soak paper money in a 50 solution of waterethanol The ethanol burns but the paper is protected by the water More spectacular (and riskyhellip) is to burn a scarf instead

Safety Do not ignite the beaker or anything else

Tea Bags

Syllabus Links Combustion

Method Unwrap the tea bag to give a hollow tube Put the tube on something valuable (pound5) and set fire to the top The panic comes when the flames approach the money buthellip

Safety Watch where the ignited bag goes

Rubens Tube

Syllabus Links Pressure sound

Method Signal generator Rubens Tube gas supply I have never seen a Rubens tube for sale but they are relatively easy to make (email for instructions) The Rubens tube is essentially a tube forming a gas grill One end for the tube is closed off with a plastic membrane which is vibrated by a speaker Us the signal generator to discuss the range of human youngold hearing

Safety The tube gets hot Residual gas in the tube can linger and smell

Magnetic Rail gun

Syllabus Links actionreaction magnetism

Method Easily constructed from electrical conduit cable ties and neodymium magnets The last ball leave the gun faster than the entering ball appearing to have gained energyhellip

Ferromagnetic Liquid Syllabus Links Magnetism

Method Ferrofluid can be bought from Ebay Cover with 50 IPAdeionised water in a glass jar

Safety Neodymium magnets can cause pinch injuries wipe data or smash the vessel the Ferrofluid is in

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Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

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Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

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This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

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Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

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5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

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diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

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pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

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Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
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  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 10: Science Experiments

Balloon tricks

Syllabus Links Upthrust pressure 21st C materials and their properties Actionreaction

Method There are 101 balloon tricks Blow up a balloon and stick a pin in it It explodes Keep threatening to do thishelliphellipThe old trick is to put sellotape on the balloon and push a knitting needle through this The tape stops the tear in the rubber propagating At then end of the balloon there is a small lsquonipplersquo where the rubber is thicker ndash it is possible to push a sharp pinskewer through this without popping the balloon ndash Why

Try to push a balloon under waterhellip

Blow up a balloon and put it over a night-light candle The balloon bursts and the candle is snuffed out There is a lesson there alone ndash whyhellipPartially fill a balloon with water and then blow it up Hold the balloon over the candle ndash nothing happens why Show the soot on the base of the balloon ndash this is no trick A variation of this is to make a paper boat and fill with water Put this over a roaring Bunsen The paper will not burn whilst there is still water in the boat You may wish to add a tea bag for effect

Attach a balloon to a paper plane attached to a straw Pass a thread through the straw and use the balloon to project the plane along the thread across the class room Great fun

Inflate a balloon and statically charge it by rubbing or using a Van de GraffHold the balloon near a slowly running stream of water ndash why does the water bend How could you get the water to bend in the opposite directionBetter stillhellip Hold the charged balloon near a slowly pouring stream of golden syrup ndash with care you can get the syrup to bend horizontally

Water trickSyllabus Links lsquoFlogistan theoryrsquo pressure

Method Put a small amount of water coloured with food dye in a shallow plate Use a wedge of apple or orange to hold 4 matches Place the wedge with the matches in the water and light Quickly cover the matches with a glass ands press down firmly The water is sucked from the plate into the glass

Flaming money

Syllabus Links Combustion

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Method Soak paper money in a 50 solution of waterethanol The ethanol burns but the paper is protected by the water More spectacular (and riskyhellip) is to burn a scarf instead

Safety Do not ignite the beaker or anything else

Tea Bags

Syllabus Links Combustion

Method Unwrap the tea bag to give a hollow tube Put the tube on something valuable (pound5) and set fire to the top The panic comes when the flames approach the money buthellip

Safety Watch where the ignited bag goes

Rubens Tube

Syllabus Links Pressure sound

Method Signal generator Rubens Tube gas supply I have never seen a Rubens tube for sale but they are relatively easy to make (email for instructions) The Rubens tube is essentially a tube forming a gas grill One end for the tube is closed off with a plastic membrane which is vibrated by a speaker Us the signal generator to discuss the range of human youngold hearing

Safety The tube gets hot Residual gas in the tube can linger and smell

Magnetic Rail gun

Syllabus Links actionreaction magnetism

Method Easily constructed from electrical conduit cable ties and neodymium magnets The last ball leave the gun faster than the entering ball appearing to have gained energyhellip

Ferromagnetic Liquid Syllabus Links Magnetism

Method Ferrofluid can be bought from Ebay Cover with 50 IPAdeionised water in a glass jar

Safety Neodymium magnets can cause pinch injuries wipe data or smash the vessel the Ferrofluid is in

alanglazetauntonsacuk

Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

alanglazetauntonsacuk

Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

alanglazetauntonsacuk

This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

alanglazetauntonsacuk

Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

alanglazetauntonsacuk

5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

alanglazetauntonsacuk

diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

alanglazetauntonsacuk

pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

alanglazetauntonsacuk

food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

alanglazetauntonsacuk

1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

alanglazetauntonsacuk

5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

alanglazetauntonsacuk

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

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Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
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  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 11: Science Experiments

Method Soak paper money in a 50 solution of waterethanol The ethanol burns but the paper is protected by the water More spectacular (and riskyhellip) is to burn a scarf instead

Safety Do not ignite the beaker or anything else

Tea Bags

Syllabus Links Combustion

Method Unwrap the tea bag to give a hollow tube Put the tube on something valuable (pound5) and set fire to the top The panic comes when the flames approach the money buthellip

Safety Watch where the ignited bag goes

Rubens Tube

Syllabus Links Pressure sound

Method Signal generator Rubens Tube gas supply I have never seen a Rubens tube for sale but they are relatively easy to make (email for instructions) The Rubens tube is essentially a tube forming a gas grill One end for the tube is closed off with a plastic membrane which is vibrated by a speaker Us the signal generator to discuss the range of human youngold hearing

Safety The tube gets hot Residual gas in the tube can linger and smell

Magnetic Rail gun

Syllabus Links actionreaction magnetism

Method Easily constructed from electrical conduit cable ties and neodymium magnets The last ball leave the gun faster than the entering ball appearing to have gained energyhellip

Ferromagnetic Liquid Syllabus Links Magnetism

Method Ferrofluid can be bought from Ebay Cover with 50 IPAdeionised water in a glass jar

Safety Neodymium magnets can cause pinch injuries wipe data or smash the vessel the Ferrofluid is in

alanglazetauntonsacuk

Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

alanglazetauntonsacuk

Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

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This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

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Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

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5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

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diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

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pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

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  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
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  • Whats happening
  • What you need
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  • Whatrsquos happening
  • Applications
  • What you need
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  • What to do
  • Whatrsquos happening
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  • What To Do
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  • Experiment 2 Drop Cup
  • What you need
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  • Whats happening
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  • Applications
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  • What you need
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  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 12: Science Experiments

Cannon Fire

1 Measure 20 ml ethanol 20 cm3 hydrogen peroxide solution into a crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into the crystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish5 Wash everything up (solution can go down the sink)

You will have to experiment with the quantity of peroxide as the concentration is rarely what is lsquosays on the canrsquo having sat in the fridge for the last year

Potassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOH

These pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

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Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

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This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

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Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

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5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

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diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

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pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

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Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

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White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

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Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

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A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

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  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
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  • Whatrsquos happening
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  • What you need
  • What To Do
  • Whats happening
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  • What you need
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  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
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  • Whats happening
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  • What to do
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  • What you need
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  • Whats happening
  • Applications
  • What to do
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  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 13: Science Experiments

Other (incomplete)

WHAT YOU NEEDTo do this experiment you will need

a saucer milk food colouring (four different colours) detergent

WHAT TO DO1 Fill the saucer with milk2 Add one drop of each food colour to the milk around the edge of the saucer3 Add one drop of detergent into the centre of the saucer

WHATS HAPPENINGThe colours swirl and zoom around the saucerMilk stays together as one liquid because of surface tension This acts like a skin and keeps the milk in a puddle When you add the detergent it breaks the surface tension of the milk in one spotThe pull of the surface tension from the milk at the edge of the saucer causes the milk in the centre to move to the outside taking the colours along with itThe colours keep moving until the detergent stops affecting the milk

WHAT YOU NEEDTo do this experiment you will need

four clear glasses each half full of water cooking oil food colouring ndash red or blue show up best liquid detergent

WHAT TO DO1 Add a few drops of food colour to the first glass and stir Notice how well the colour mixes with the

water2 Pour some cooking oil into the second glass Does it mix in like the food colour did Try stirring the oil

and observe what happens The oil will eventually rise to form a layer on top of the water3 Pour enough cooking oil into the third glass to form a layer on top of the water approximately five

centimetres thick When the oil layer has settled add a few drops of food colour Donrsquot stir Watch how each drop behaves as it hits the oil layer

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4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

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Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

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This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

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Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

alanglazetauntonsacuk

5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

alanglazetauntonsacuk

diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

alanglazetauntonsacuk

pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

alanglazetauntonsacuk

food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

alanglazetauntonsacuk

1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

alanglazetauntonsacuk

5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

alanglazetauntonsacuk

a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

alanglazetauntonsacuk

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

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Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

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Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

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Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
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  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 14: Science Experiments

4 Now mix everything in together What happens to the drops of colour Some tiny drops of colour will

probably stay in the oil layer Watch what happens to them after a while5 Create the same oil and water mixture in the fourth glass with several drops of food colour Add a

teaspoon of dishwashing detergent and stir vigorously What is different this time Notice the colour of the oil layer Is it the same as the water layer

WHATS HAPPENINGOil and water donrsquot mix Even when you stir them together they will soon separate The oil which is lighter (or less dense) rises to the top Food colouring is water-based so it mixes easily with water but canrsquot mix with the oil Did you notice how the drops of food colour behaved when they travelled through the oil Sometimes the food colour forms perfect little beads which slowly drop through the oil layerMIX IT UPYou can make oil and water mix by breaking them down into tiny drops that wonrsquot re-form The homogenised milk that we buy from the shop is made this way Milk from the cow naturally separates into cream (oil based) on top and skim milk (water based) on the bottom Before milk is bottled it is squirted through a sieve at high speed This breaks down the two liquids into tiny drops that wonrsquot separateAny mix of two liquids similar to this is called an emulsion An emulsion consists of millions of tiny droplets of one liquid suspended inside another liquidOil based paint is an emulsion Many medicines and cosmetics are as well They are mixtures of oils and water-based substances held together by an emulsifierEgg yolk is a natural emulsifier Artists use it in tempera paint to hold the various ingredients together It is also used in making mayonnaiseNow for that recipeSALAD DRESSINGTo make your own salad dressing you will need to gather the following items

14 cup fresh lemon juice 13 cup olive oil salt and pepper to taste 1 teaspoon seeded mustard

Place all ingredients in a screw top jar and shake until well mixedTaste itTry adding other flavourings such as chopped chives or garlic if you like You can also use vinegar instead of lemon juice Do what all good scientists and chefs do ndash experimentPour over salad vegetables and tossMAYONNAISEMayonnaise is a bit trickier It uses an egg yolk to emulsify vinegar or lemon juice with olive oilYou will need to gather these items to make it

1 cup of light olive oil 1 egg 1 lemon a pinch of salt and pepper water

Open the egg and separate the yolk from the white (only the egg yolk is used in this recipe) The egg yolk contains an emulsifier called lecithin which helps form the mayonnaise emulsionMix the juice of one lemon the egg yolk salt and pepper with a whisk Continue to whisk the mixture and slowly add the olive oil Do not add the oil too quickly or the mixture will not form an emulsionIf the emulsion is too thick you can add a small amount of water to thin it If the emulsion doesnrsquot begin to thicken after adding a quarter of the oil you will need to start again

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Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

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This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

alanglazetauntonsacuk

Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

alanglazetauntonsacuk

5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

alanglazetauntonsacuk

diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

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pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

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Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 15: Science Experiments

Once you have finished adding the oil you can adjust its taste with extra lemon salt pepper or even mustard

WHAT YOU NEEDTo do this experiment you will need

fresh red cabbage a sharp knife a cutting board hot tap water seven clear plastic disposable cups seven plastic spoons a large plastic bottle a range of the household substances which may includeo strongly acidic For example powdered toilet cleanero acidic For example vinegar lemon juice white wine lemonade or citric acido weakly acidic For example cream of tartaro neutral For example pure water shampoo or baby shampooo slightly basic For example bicarbonate of sodao basic For example milk of magnesia washing soda or floor cleanero strongly basic For example dishwasher liquid or powder

WHAT TO DO1 Using a sharp knife and cutting board finely slice three or four red cabbage leaves2 Place the cabbage leaves in the plastic bottle half fill the bottle with hot water and screw the lid on

tightly3 Shake the bottle for a few minutes until the water becomes a deep purple colour Leave the solution to

cool4 Strain the solution and add sufficient water to the solution to make about one litre5 In each of the cups place a small amount of one of the above household substances in the following

order strongly acidic acidic slightly acidic neutral slightly basic basic and strongly basic6 Now half fill each cup with the red cabbage water and stir the solution If arranged in order the jars

should display a spectrum of colours from cherry red (strongly acidic) pink-red (acidic) lilac (slightly acidic) purple (neutral) blue (slightly basic) green (basic) and yellow (strongly basic)

WHATS HAPPENINGThe things we eat and drink are all acidic and the things we use for cleaning are basic This is because basic substances taste unpleasant but a cleaning agent usually needs to be basic to remove dirt and greaseSubstances that are acidic or basic make the eyes sting so baby shampoo is made neutral

WHAT YOU NEEDTo do this experiment you will need the following items

paper towel scissors a jar felt-tipped pens and markers two paper clips water

WHAT TO DO

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This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

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Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

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5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

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diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

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pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

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  • Tips
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  • Mix it up
  • Salad dressing
  • Mayonnaise
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  • Applications
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  • Experiment 2 Drop Cup
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  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 16: Science Experiments

This is what your experiment should look like1 Cut some absorbent paper (such as paper towel) into strips about 2 cm wide The length isnt really

important and will depend on the size of the jar you hang them in2 Draw a small circle 1 cm from the bottom of the paper with different black markers or felt-tipped pens3 Fill a clean jar with about 1 cm of water and carefully place the paper into the jar making sure that the

bottom of the paper is in the water The circle must be ABOVE the water level Use paper clips to hold the paper upright in the jar Watch the water rise up the paper

4 After a few minutes remove the paper from the jar Notice how different colours in the ink travel up the paper at different speeds

5 Now try some different colour pens and markers Can you see any differences6 Did you have any pens for which the ink did not separate If so repeat the experiment using methylated

spirits instead of water in the jar Try out a variety of pens Can you see any differences The method used to compare inks is called chromatography It involves separating the ink in each of the pens As the solvent (water) rises up the paper the different colours of the ink separateAsk your family to play your suspects Have them use specific pens for the job and see if you can figure out which ink comes from which pen and nab your suspect

WHAT YOU NEEDTo do this experiment you will need

cornflour food colouring a small mixing bowl water

WHAT TO DO1 Pour some cornflour into a mixing bowl2 Stir in small amounts of water until the cornflour has become a very thick paste3 To make the slime the colour of your choice thoroughly stir about five drops of food colouring into the

mixture4 Stir your slime REALLY slowly This shouldnt be hard to do5 Stir your slime REALLY fast This should be almost impossible6 Now punch your slime REALLY hard and fast It should feel like youre punching a solid

You can keep your cornflour and water mixture covered in a fridge for several days If the cornflour settles you need to stir it to make it work well againWHATS HAPPENINGAnything that flows is called a fluid This means that both gases and liquids are fluids

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Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

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5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

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diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

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pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

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Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
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  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
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  • Whats happening
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  • What to do
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  • Whatrsquos happening
  • Applications
  • What you need
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  • Whatrsquos happening
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  • What you need
  • What To Do
  • Whats happening
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  • What you need
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  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
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  • What to do
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  • What you need
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  • Applications
  • What to do
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  • What you need
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  • Whats happening
  • What you need
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  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 17: Science Experiments

Fluids like water which flow easily are said to have low viscosity whereas fluids like cold honey which do not flow so easily are said to have a high viscosityCornflour slime is a special type of fluid that doesnt follow the usual rules of fluid behaviour When a pressure is applied to slime its viscosity increases and the cornflour slime becomes thickerAt a certain point slime actually seems to lose its flow and behave like a solid Cornflour slime is an example of a sheer-thickening fluidThe opposite happens in sheer-thinning fluids they get runnier when you stir them or shake

them up For example when toothpaste is sitting on a toothbrush it is pretty thick so you can turn the toothbrush upside down and the toothpaste doesnt fall offBut if it was that thick when you tried to squeeze it out of the tube there is no way you could manage it Fortunately toothpaste gets runnier when you are squeezing it out of the tube Other sheer-thinning fluids include

blood paint ballpoint pen ink nail polish

Although there are lots of sheer-thinning and sheer-thickening fluids nobody has a really good idea why they behave the way they doThe interactions between atoms in the fluids are so complicated that even the worlds most powerful supercomputers can not model what is happening This can be a real problem for people who design machinery that involves sheer-thinning fluids because it makes it hard to be sure if they will work

WHAT YOU NEEDTo do this experiment you will need the following

a helper a tin container with a tin lid such as a coffee tin four long pencils a metal bottle cap (a soft drink bottle cap is less effective) strong sticky tape adhesive putty (Blu-Tack or similar)

WHAT TO DO

diagram of the Cracking Fun experiment1 Fill the container with water until it is overflowing and press the lid on2 Place the metal bottle cap on the centre of the lid and secure it with a small piece of adhesive putty3 Place three of the pencils next to each other on the table and tape them together to make a flat platform4 Rest the container on the pencil platform so that the pencils poke out on both sides

alanglazetauntonsacuk

5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

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diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

alanglazetauntonsacuk

pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

alanglazetauntonsacuk

1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

alanglazetauntonsacuk

5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

alanglazetauntonsacuk

a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

alanglazetauntonsacuk

4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

alanglazetauntonsacuk

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

alanglazetauntonsacuk

The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

alanglazetauntonsacuk

As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

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A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
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  • What to do
  • Whats happening
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  • Mix it up
  • Salad dressing
  • Mayonnaise
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  • Whatrsquos happening
  • Applications
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  • Whatrsquos happening
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  • What To Do
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  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
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  • Applications
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  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 18: Science Experiments

5 Place the fourth pencil on top of the bottle cap and fasten it with a bit of adhesive putty6 As one person holds all the pieces together use strong tape to strap the top pencil tightly to the pencil

platform on either side of the tin and then place in the freezerHave a look after 24 hours (if you have used a large container it may take 48 hours) Marvel at the power of iceWHATrsquoS HAPPENINGWater is one of a few chemicals that expands when it changes from liquid to solid As water cools it contracts like any other substance ndash the molecules slow down they have less energy and get closer togetherBut as its temperature drops below four degrees Celsius water begins to expand The molecules begin forming stiff bonds with their neighbouring molecules which push them outwards to form a hollow structure or crystal lattice which can float in liquid waterAs water freezes and expands it can exert incredible pressure For example it has enough energy to burst open the walls of plant and animal cells crack rocks burst water pipes and crack your pencilPlant and animal cells contain water As this water turns to ice the cells expand causing them to burst In mountain and polar explorers such burst cells can cause frostbite which is an irreversible condition Also severe damage to fruit and vegetable crops can occur when sudden cold snaps cause plant cells to burstAPPLICATIONSPeople in cold climates need to add anti-freeze to the coolant in their motor vehicles The anti-freeze lowers the freezing point of the coolant beyond the coldest temperature that the vehicle will be exposed to This means that the coolant does not freeze solid and cause damage to the engineSome people believe that they can lsquocheat deathrsquo by having themselves cryogenically frozen The idea is that if you die from an incurable disease such as cancer and have yourself frozen you can be re-animated in the future once people discover a curePeople who are cryogenically frozen are kept at temperatures well below -196deg Celsius using liquid nitrogen If they were to be placed straight into liquid nitrogen all the cells in their body would freeze and burst To prevent damage to the cells all the water in the body is removed and replaced with a glycerol-based mixture called cryoprotectant which is similar to antifreezeSo far dozens of people have been cryogenically frozen but no one has been reanimated ndash the technology to do so is yet to be discovered

WHAT YOU NEEDTo do this experiment you will need the following items

a large glass jar with a lid a thin piece of string Blu-Tack (or similar) a sugar crystal 1 - 2 kg of sugar food colouring (optional) a saucepan

WHAT TO DO

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diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

alanglazetauntonsacuk

pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

alanglazetauntonsacuk

1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

alanglazetauntonsacuk

5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

alanglazetauntonsacuk

a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

alanglazetauntonsacuk

4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

alanglazetauntonsacuk

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

alanglazetauntonsacuk

The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

alanglazetauntonsacuk

As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

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Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
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  • Mix it up
  • Salad dressing
  • Mayonnaise
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  • Applications
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  • What To Do
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  • Experiment 2 Drop Cup
  • What you need
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  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 19: Science Experiments

diagram of the Crystal Grower experiment1 Drill or punch a small hole through the lid of the jar (you may need an adult to help you) Thread the

string through the hole Secure the strand with a small ball of Blu-tack covering the top of the hole or alternatively tie a knot above the hole Tie a good-sized sugar crystal (seed crystal) to the other end of the string

2 Place frac34 cup of water in the saucepan bring it to the boil then reduce to a simmer Pour sugar into the hot water until no more sugar will dissolve If you do not add enough sugar the solution will not become super-saturated Turn off the heat and allow the sugar solution to cool Dont touch or move the saucepan as the sugar solution will be extremely hot

3 Once the solution is cold pour it into the jar until it is approximately frac34 filled Poor the remaining solution into a spare container for later Secure the lid ensuring that the strand and sugar crystal are in the solution

4 Place the jar in a cool location such as a cupboard Check the crystal each day If the crystal hasnt grown for a day or two replace the solution with remaining sugar solution or make some more in a saucepan The crystal needs to sit in a super-saturated solution to continue growing Time and patience are required because crystals are slow growing The crystals in the photo at the top of this page were growing for about a month You may want to leave yours to grow for more than a month The crystals will eventually reach a point where they will stop growing

Once your crystal has become large enough you can remove it from the stringFor added flair add food colouring to the water to create colourful crystals (A small drop of the colouring is sufficient)WHATS HAPPENINGA solution is a mixture of a solute and a solvent In this example the solute is sugar and the solvent is water If you add a small amount of solute to the solvent typically the solution is under-saturated Adding more solute will cause the concentration of the solution to increase until you cannot dissolve anymore solute The solution is now called saturatedBy heating the solution it is possible to dissolve more solute making the solution super-saturated This is an unstable state for the solution and as soon as conditions change (for example the temperature lowers) some of the solute will reappear in solid form - precipitationTo precipitate the dissolved solute looks for a seed to build upon In the case of our experiment it uses the sugar crystal Over time more of the solute precipitates on the outside of the seed layer upon layer forming a larger crystal Once the solution returns to a saturated state the crystal stops growingCreating a seed crystalIf you need a seed crystal large enough to tie on the end of your string heres an idea Half fill a jar with water from the tap and stir in a few tablespoonfuls of sugar until the solution is saturated Tie a piece of string to a

alanglazetauntonsacuk

pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

alanglazetauntonsacuk

1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

alanglazetauntonsacuk

a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

alanglazetauntonsacuk

4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

alanglazetauntonsacuk

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

alanglazetauntonsacuk

The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

alanglazetauntonsacuk

As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

alanglazetauntonsacuk

When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
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  • Whats happening
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  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
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  • Whatrsquos happening
  • Applications
  • What you need
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  • Whats happening
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  • Whatrsquos happening
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  • What To Do
  • Whats happening
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  • Experiment 2 Drop Cup
  • What you need
  • What to do
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  • What you need
  • What to do
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  • What you need
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  • Applications
  • What to do
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  • What you need
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  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 20: Science Experiments

pencil and balance it over the top of an open glass jar with the string hanging in the sugar solution Place the jar in a sunny position and within a few days you should have a number of good-sized seed crystals

WHAT YOU NEEDTo do this experiment you will need the following

a tall glass or plastic container some vegetable oil ice (try adding some food colouring to make it easier to see)

WHAT TO DO1 Fill the glass with oil2 Drop a block of ice into the glass The ice should float in the middle of the oil3 Watch the ice as it melts

You will find drops form on the ice then drop off to fall slowly through the oil As the drops form and fall the ice will rock from side to side and move up and downWHATS HAPPENINGThis activity is all about density The density of a material is how much a given volume of that material weighs For example one cubic metre of liquid water weighs 1000 kg so it has a density of 1000 kgmsup3When you drop an object into a liquid it feels the forces of

gravity which pulls it down buoyancy which pushes it up

When you drop something into a liquid it displaces some of the liquid (pushes it out of the way) An object placed in a liquid feels an upward force equal to the weight of the liquid it is displacing This force is called buoyancyIf the weight of the object is less than the weight of the liquid it is displacing it will float If it is greater it will sink Another way to say this is that if the object is less dense than the liquid it will float but if it is denser it will sink This is even true for liquids Liquid water is denser than oil so the oil floats on the waterWater is weird stuff We dont normally notice it because water is so common but water does some things that almost no other chemical will do One of the ways water is strange is that it is less dense as a solid than as a liquidIce and vegetable oil have almost the same density around 920 kgmsup3 so a block of ice dropped into oil will barely move As the water melts it turns into denser liquid water The water tends to stick to the ice for a while before it drops off If there is enough liquid water on the ice then the density of the ice and water together is greater than the oil so they will sink Once the drop of water falls off the ice the ice floats up againIts a good thing that ice floats on water In winter some rivers and lakes freeze on the surface If ice was denser than water then the rivers and lakes would freeze from the bottom up which would kill plants growing in them and starve most of the fish and other marine life

WHAT YOU NEEDTo do this experiment you will need the following items

a tall clear jar or PET bottle golden syrup or honey water oil screws paperclips and any other small objects ice cubes

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food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

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1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

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5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

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Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 21: Science Experiments

food colouring detergent

WHAT TO DO1 Carefully pour some golden syrup water and oil into the container in that order You might want to add

food colouring to the different layers to be able to see them better What do you see2 Drop in the small objects Do they reach the bottom Try dropping in the ice-cubes3 Add a drop of detergent What happens

WHATrsquoS HAPPENING

Diagram of the Density Column experimentGolden syrup water and oil have different densities so they donrsquot mix Instead they form three different layers The denser fluids sink to the bottom while less dense fluids rise to the top Where other objects sit in the density column depends on how dense the objects areTemperature can affect the density of fluids and solids The strange thing about ice is that it is less dense than water so it floats in the oil level However cold water is denser than warm water Try adding a few droplets of colouring to half a cup of very hot water (ask an adult to help you) and add it to your density column Does the colouring mix with all the water or does the hot coloured water form another layerEver wondered why you need detergent for washing up your dishes Normally oil and water donrsquot mix together When you add soap or detergent it reduces the surface tension of water allowing it to dissolve the oil Adding a few drops of detergent wonrsquot be enough to dissolve all the oil in your density column However you should be able to see lsquobreaksrsquo in the layers where some of the oil dissolved in the water

Turn a margarine container into a balloon-powered jet boat Its easyWHAT YOU NEEDTo do this experiment you will need to gather

a margarine container a balloon a straw a rubber band plasticine scissors something that will pierce the margarine container to make a hole big enough to fit a straw through

WHAT TO DO

alanglazetauntonsacuk

1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

alanglazetauntonsacuk

5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

alanglazetauntonsacuk

a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

alanglazetauntonsacuk

4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

alanglazetauntonsacuk

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

alanglazetauntonsacuk

The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

alanglazetauntonsacuk

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
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  • Mix it up
  • Salad dressing
  • Mayonnaise
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  • Experiment 2 Drop Cup
  • What you need
  • What to do
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  • Applications
  • What to do
  • Whats happening
  • What you need
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  • Whats happening
  • What you need
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  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 22: Science Experiments

1 Find a clean rectangular margarine container and carefully make a hole in the centre of one of the

shorter sides about 1 cm from the bottom2 Cut a straw in half and insert one end into the neck of a balloon Fix the balloon firmly to the straw with a

rubber band3 Push the straw through the hole in the marg container and seal it in place with plasticine Weigh the back

of the marg container with more plasticine in the centre Blow the balloon up through the straw and pinch the end to keep the air inside

4 Put the boat in the water let go - and away she goesThis is an example of Newtons third law of motion - every action has an opposite and equal reaction The air rushing out of the straw is the action and the equal reaction is the push against the boat in the opposite directionCan you improve the design of your boat

Who needs a beach when you can surf on balloons Try this activity at home or at school WHAT YOU NEEDTo do this experiment you will need to gather

an adult assistant balloons an upside-down desk or some other flat-bottomed object that can survive you standing on it a carpeted floor a table pole or wall you can use to help yourself balance

WHAT TO DO1 Check that there is nothing sharp on the desk or floor that could damage a balloon2 Half-inflate four balloons and tie them off3 Place the balloons under the corners of the desk4 Have your assistant hold the desk still They shouldnt try to take the weight just help keep it balanced

Make sure they do not put any of their fingers under the desk - they might get squashed5 Carefully step up onto the desk You can use another table or a pole to help you balance as you climb up

Unless something sharp bursts them the balloons should be able to support your weightIf there are other people around you could try testing to see how many people the balloons can support

WHAT YOU NEEDTo do this experiment you will need to gather

two balloons two plastic PET bottles (125 L softdrink bottles work well) a metal skewer large darning needle or a knife

WHAT TO DO1 Ask an adult to make a small hole (less than one centimetre across) in the bottom of one of the bottles Be

very careful when you do this because PET plastic is extremely strong 2 Stretch the neck of a balloon across the opening of each of the bottles Gently push the balloons so they

sit inside the bottles3 Try and blow the balloons up in the bottles Which one is the easiest to blow up4 Take the PET bottle with the hole in it and place your finger tightly over the hole What happens when

you try and blow it up now

alanglazetauntonsacuk

5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

alanglazetauntonsacuk

a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

alanglazetauntonsacuk

4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

alanglazetauntonsacuk

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

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Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

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White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

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Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

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A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

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  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
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  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
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  • What to do
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  • What to do
  • Whatrsquos happening
  • Applications
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  • Whatrsquos happening
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  • What you need
  • What To Do
  • Whats happening
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  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
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  • Applications
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  • What you need
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  • Whats happening
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  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 23: Science Experiments

5 Take the PET bottle with the hole in it and blow the balloon up inside it At the end

of your last breath place your finger over the hole and take your lips off the bottle What happens to the balloon

6 Gradually release the pressure of your finger What happens to the balloon nowWHATS HAPPENINGYou probably found that you could blow up the balloon in the bottle with the hole in it You wouldnt have had much luck with the other one though Dont worry There is nothing wrong with your lungs Its got to do with spaceAir takes up space just like anything else When you blew up the balloons in the bottles you were trying to push air into a limited space There wasnt enough room for the air in the sealed bottle as well as the extra air you were trying to blow into the balloon And your lungs certainly dont have the power of an air compressor so you cant blow much extra air into the balloon in the hole-less bottleYou could blow up the balloon when the hole was uncovered because air escaped from the hole and made room for all the extra air you blew into it So you were blowing some air in the top but some was also escaping through the hole You saw the reverse happening when you blew up the balloon in the bottle with the hole and then put your finger over the hole As you released the pressure of your finger the elastic sides of the balloon forced the air out of the balloon returning it to its original size So air was forced out the top but was replaced by air entering back through the hole at the bottom

WHAT YOU NEEDTo do this experiment you will need

a balloon 25 cm of cotton thread a tap

WHAT TO DO1 Blow up the balloon and tie the end2 Tie the piece of thread to the end of the balloon3 Hang the balloon a few centimetres away from a stream of cold water rushing from a tap

WHATS HAPPENINGYou should see the balloon move towards the stream of water If you hold the balloon with your fingers instead of by the thread you may be able to make the stream of water move towards the balloon (as in the photo above)When you turned on the tap the rushing stream of water started moving the air around it Due to the fact that this air was moving it had a lower pressure than the surrounding still air Holding the balloon near the stream of water meant it had low pressure air on one side (the side near the water) and higher pressure air on the other side High pressure air always pushes towards low pressure air The higher pressure air on the other side of the balloon pushed the balloon towards the stream of water This is called the Bernoulli Principle

WHAT YOU NEEDTo do this experiment you will need to gather

a hard boiled egg (boiled for 15-20 minutes) that has been allowed to cool a glass bottle or jar with an opening at the top a couple of millimetres smaller than the egg some newspaper matches or a lighter

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a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

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4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

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As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

alanglazetauntonsacuk

When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 24: Science Experiments

a sink to do the activity on an adult helper

WHAT TO DO1 Peel the shell off the hard boiled egg2 Place the pointy end of the egg in the neck of the glass bottle or jar3 Scrunch up a piece of paper and light it then lift the egg up and carefully (but quickly) put the burning

paper into the bottle and replace the eggWHATS HAPPENINGThwump - the egg gets sucked into the bottleThe burning paper causes the air inside the bottle to expand pushing some of it out of the bottle When the paper goes out the air cools and contracts The air pressure outside the bottle is greater and the egg is pushed into the bottleTo get the egg back out of the bottle wash the ashes out of the bottle Turn it upside down and position the egg with the pointy end back in the opening Take a deep breath and blow in Continue to hold the bottle upside down wait and watch

WHAT YOU NEED

What will happen when you drop itTo do this experiment you will need

four pieces of plywood a balloon a lead sinker a needle rubber bands tape nails a hammer

WHAT TO DO1 Put together a rectangular wooden frame2 Using elastic bands suspend a lead sinker from the top of the inside of the frame so that the rubber bands

are stretched Attach an upward facing needle to the sinker3 Inflate a balloon and stick it to the top of the frame so the needle is suspended below the balloon

alanglazetauntonsacuk

4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

alanglazetauntonsacuk

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

alanglazetauntonsacuk

The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

alanglazetauntonsacuk

As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

alanglazetauntonsacuk

When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

alanglazetauntonsacuk

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

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Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

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Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

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White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

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Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
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  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
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  • Whatrsquos happening
  • Applications
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  • Whatrsquos happening
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  • What you need
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  • What To Do
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  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
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  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 25: Science Experiments

4 Try dropping the frame from a couple of metres high with someone there to catch it so your construction

isnt damaged when it hits the ground What happens to the balloonWHATS HAPPENINGWhen an object falls the effects of gravity are cancelled out and an object experiences weightlessness In this case the frame and the objects inside become weightless However if the lead sinker becomes weightless the elastic bands which are stretched will now pull the sinker up causing the needle to puncture the balloon

EXPERIMENT 2 DROP CUPMany strange things happen with falling objects due to the effects of gravity being cancelled out Whats not happening in this experiment that you would expect to happen under normal circumstancesIts best to do this experiment outside as it will make a messWHAT YOU NEEDTo do this experiment you will need

a styrofoam cup a pen or pencil water

WHAT TO DO

What a difference a drop makes1 Fill a styrofoam cup with water and put a hole in the bottom side of the cup with a pencil As

youd expect water pours out (as in the cup on the left in the image)2 Now drop the cup full of water Its a good idea to have a bucket under the falling cup to prevent a mess

when it hits the groundWHATS HAPPENINGThe water becomes weightless while the cup is falling and for the duration of the fall it no longer pours out of the holeSee if you can come up with your own falling demonstrations that might produce other interesting effects

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WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

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Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

alanglazetauntonsacuk

The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

alanglazetauntonsacuk

As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 26: Science Experiments

WHAT YOU NEEDTo do this experiment you will need

a film canister baking soda (sodium bicarbonate) vinegar (any kind will work but white vinegar is easiest to clean up) an ice cream stick or teaspoon a plate saucer tray or similar eye protection (glasses sun glasses or safety goggles) an adult

WHAT TO DO1 Take the lid off the film canister Before adding the ingredients practise putting on the lid and placing it

upside down as described in step 52 Put on your eye protection3 Pour a small amount of vinegar about 5 millimetres deep into the body of the canister4 Using the teaspoon or icecream stick place enough baking soda to fill the recess in the lid5 Hold the body of the canister in one hand and the lid in the other Quickly and firmly press the lid

completely on place the canister lid down on the plate and stand back Make sure your plate is on a level surface Your canister rocket will blast off seconds later The exact timing will depend on the canister temperature amount of ingredients and how tightly you packed the baking soda in

6 Have a close look at the lid and bubbling ingredients left on the plateWHATS HAPPENINGWhen vinegar and baking soda mix together there is a fast chemical reaction There are several products of the reaction although it is the carbon dioxide gas (C02) that pops the lid offAs more and more carbon dioxide is produced the bits of carbon dioxide (called molecules) are squashed together and begin to push or apply a force on all the inside surfaces of the canister including the lidPressure is defined as a force over an area In this case its the force of the carbon dioxide pushing over the inside area of the canister As the carbon dioxide builds up so does the pressure inside the canister The pressure quickly pops the lid offA good way to understand what is happening is to take a deep breath in seal your lips and slowly breathe back out into your mouth Eventually your mouth cannot hold the pressure and your lips will unseal letting some air out Caution dont overdo this as you can hurt your eardrumsThe carbon dioxide gas pushes down on the lid although as it is sitting on the plate it cant go anywhere when it pops The carbon dioxide is also pushing on the inside base of the canister (the top of your rocket) and this pushes it into the air

To do this experiment you will need a balloon (not blown up) a short piece of drinking straw a long piece of string sticky tape two friends

WHAT TO DO1 Blow up the balloon and hold the neck to stop the air escaping

alanglazetauntonsacuk

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

alanglazetauntonsacuk

The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

alanglazetauntonsacuk

As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

alanglazetauntonsacuk

When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

alanglazetauntonsacuk

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

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Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 27: Science Experiments

Cartoon of the jet balloon experiment2 Ask your friends to hold either end of your string so the string is taut3 Thread the straw onto the string and tape it to the balloon so that one end of the straw points to the neck

of the balloon4 Hold the balloon at one end of the string and let go of it

WHATS HAPPENINGThe balloon should fly to the other end of the string as it deflatesMany years ago a scientist named Isaac Newton realised that when an object applies a force onto another object the other object pushes back with an equal force in the opposite directionWhen you let go of the balloon the air is pushed out of the neck of the balloon As it does the air pushes on the balloon with equal force in the opposite direction so the balloon is pushed along the string The air comes out of the balloon faster than the balloon is pushed along because the air is much lighter than the balloonAll rockets work by using the same principle In a rocket fuel is burned in a combustion chamber which is open at one end As the fuel burns it produces hot gases which rush out the open end of the chamber Since the gases are being pushed in one direction by the rocket the rocket is pushed in the opposite direction with equal force

WHAT YOU NEEDFor this experiment you will need

a small soft-drink bottle with its label removed (one with straight sides works best) a torch milk correction fluid (such as liquid paper) or paint a very dark room (try to do the experiment when it is dark outside) sink bucket or jar a thumbtack or safety pin sticky tape scissors paper

For this activity we will need to make a thin straight beam of light Most torches produce a fairly wide beam so you may need to use the paper to cover most of the end so only a thin beam of light comes out Try for a beam with a width of one centimetre or lessWHAT TO DOThere are two parts to this activity The first part shows how light bounces underwater

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The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

alanglazetauntonsacuk

As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

alanglazetauntonsacuk

When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

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  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 28: Science Experiments

The light beam is reflected back into the water1 Fill your bottle partway with water2 Add a drop of milk to make it easier to see the path of the light through the water3 Place the bottle near the edge of a table in your dark room4 Hold the torch down fairly low and shine it up through the side of the bottle onto the bottom of the

waters surface You should find the light travels up through the water through the surface and into the air

5 Keep the beam of light aimed at the same point on the surface but slowly lift the torch up so the angle between the light and the water becomes smaller and smaller

6 When the angle between the water and the beam of light becomes small enough the light will not go through the surface any more but will bounce off it like it was a mirror

The next part shows how to trap light in a stream of water1 With the thumbtack make a small hole in the bottle a couple of centimetres from the bottom You might

find this easier if the bottle is filled with water so the sides dont bend when you push on them2 Empty the bottle dry off the outside and paint around the hole with correction fluid or paint Paint at

least one centimetre in each direction and a couple of centimetres downwards This ensures that the beam of light only travels down the stream of water

3 Fill the bottle with water until the water squirts out the hole in a steady stream Make sure you have a sink or bucket set up to catch the water

4 Shine your torch at the hole from the other side of the bottle5 As the water comes out of the bottle it will look clear until it starts to break up into drops At that point

you may see some light glittering on the drops Hold your finger in the water stream above the point where it breaks up You should see a spot of light on your finger

6 If you look closely you should find that the point of light is actually below the level of the hole The light has stayed inside the stream of water as it bent down

WHATS HAPPENINGBoth of these activities rely on an effect called total internal reflection

The beam of light stays inside the stream of waterWhen light hits a boundary between two substances like the surface of water it often bends This is called refraction In the case of water and air light bends towards the surface of the water when it goes from water into air

alanglazetauntonsacuk

As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

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a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

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probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 29: Science Experiments

As the angle on the water side becomes smaller the angle on the air side gets smaller even faster When the angle on the water side is just right the angle on the air side would have to be zero so the light would be trying to go along the surfaceIf the angle on the water side is any smaller then instead of going through into the air the light bounces off the surface of the water This is called total internal reflection For the surface between water and air the critical angle is 415 degreesIn this activity the light stayed inside the stream of water because of total internal reflection To start with the light and the water both come out of the hole horizontally As the water

curves down the light eventually hits the surface Since the angle between the surface and the light is very slight the light bounces offAs the water keeps bending the light inside it keeps bouncing off the surface until the water starts to break upThe same effect happens inside other clear materials such as long thin strands of glass or plastic even if the strand curves or goes around in circles This is called an optic fibreAPPLICATIONSDoctors can look inside a persons body using a bundle of optic fibres connected to a television camera outside the body This has lead to keyhole surgery where doctors carry out complicated operations through small holes in the skin instead of having to make large incisionsOptic fibres are also used to carry information like telephone calls By sending the information as carefully controlled pulses of different coloured light it is possible for a single fibre less than a millimetre wide to carry thousands of phone callsOptic fibres are becoming more important as scientists and engineers are developing technology called photonics which is the study of ways to generate and harness light and other forms of radiant energy

WHAT TO DO1 Cut a circle from a piece of cardboard2 On one side draw a head with an apple on it3 On the other side of the cardboard draw an arrow (or pick two other related pictures like a fish and a

fishbowl)4 Use sticky tape to attach the circle onto a straw5 Roll the straw back and forth between the palms of your hands while you look at the cardboard What do

you seeWHATS HAPPENINGModern movies use technology to produce an optical illusion and fool our brainsWhen you look at a picture your eye and brain retain the image for a fraction of a second after it has gone This is called persistence of visionIf you are shown more than ten pictures a second your brain will merge the separate images into a series of moving imagesMotion pictures show 24 still frames per second that give the illusion of smooth motion The brightness of an image also affects the length of time the image will remain in your brain

WHAT YOU NEEDTo do this activity you will need

sunlight a piece of card with a one millimetre wide slit cut into the middle a straight-sided glass filled with water

alanglazetauntonsacuk

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

alanglazetauntonsacuk

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

alanglazetauntonsacuk

When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

alanglazetauntonsacuk

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

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Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

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Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

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White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

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Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

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A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
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  • What you need
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  • Whatrsquos happening
  • Applications
  • What you need
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  • Whats happening
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  • Whatrsquos happening
  • What you need
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  • What you need
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  • What you need
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  • Whats happening
  • What you need
  • What To Do
  • Whats happening
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  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 30: Science Experiments

a sheet of white A4 paper

WHAT TO DO1 Fill a straight-sided glass with water and tape the card onto the side of the glass2 Place the white sheet of paper close to a window where sunlight is entering3 Stand the glass on the paper with the slit facing towards the Sun4 The sunlight should pass through the slit and split into its colour components as it enters the glass The

colours should appear on the paperWHATS HAPPENINGWhite light is a mixture of many different colours Sir Isaac Newton proved this more than 300 years ago when he directed a beam of sunlight through a slit and prism in a darkened room in 1666The prism bent or refracted the white light so that it fanned out into a rainbow (spectrum) of coloursSplitting light using prisms is known as spectroscopy Each chemical element has a unique signature when its light is split upAstronomers use spectroscopy to determine what planets and stars are made of by examining their light

WHAT YOU NEEDTo do this experiment you will need

a balloon a hair dryer

WHAT TO DO1 Blow up the balloon and tie it off2 Turn on the hair dryer and point it so the stream of air is blowing towards the ceiling3 Hold the balloon in the stream of air and then let go

If youve never done this experiment before youd probably expect the balloon to float up and then fall to one side What actually happens is that the balloon hangs in the middle of the air stream

Diagram of the staying up there experimentWHATS HAPPENINGThe balloon hangs in the stream through a balance of forces The downward pull of gravity is balanced by the upward push of the air flowThe balloon stays in the centre of the air stream because the fast moving air has a lower pressure than the surrounding still air If the balloon starts to move out of the air stream the higher pressure of the surrounding air pushes it back

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Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

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When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

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Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

alanglazetauntonsacuk

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

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Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

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The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

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Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

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3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

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Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

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White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

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Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

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Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
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  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
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  • Experiment 2 Drop Cup
  • What you need
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  • Applications
  • What to do
  • Whats happening
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  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 31: Science Experiments

Try tilting the hair dryer a bit What happens now

WHAT YOU NEEDTo do this experiment you will need to gather

an egg (uncooked) sugar hot water two containers such as glass jars

WHAT TO DOPour about seven centimetres of water into each jar Add a tablespoon of sugar to the water in one jar then stir until it has dissolved Repeat this until no more sugar will dissolve into the water This is called a saturated solutionCarefully lower the egg into each jar Does it float or sinkWHATS HAPPENINGBy adding sugar to water you increase the density of the water Very sugary water is denser than an egg while fresh water is less dense than an egg This means that the egg will float in the sugary water and sink in the fresh waterTry it yourself with a range of sugary solutions Can you figure out a way of creating a solution which is sugary at the bottom and fresh at the top The egg would then float midway

WHAT YOU NEEDTo do this experiment you will need the following items

a glass bowl a small glass baby oil a glass eye-dropper

WHAT TO DO1

Place the small glass inside the glass bowl Pour baby oil into the bowl until the oil covers the glass The refractive index of baby oil is very close to that of glass The small glass should therefore appear practically invisible

2 Gently place the glass eyedropper into the small glass It should appear visible because the eye-dropper contains air - the refractive indices of air and glass are different

3 Retrieve the eye-dropper fill it with baby oil and place it back inside the glass The eye-dropper should become almost invisible because the air has been removed When light passes from the oil into the glass (and visa versa) it is only slightly bent

Note If you dont want to waste the baby oil use the glass to pour it back into the bottle Make sure you do this over the bowl so it doesnt get everywhereWHATS HAPPENINGCould Harry Potters invisibility cloak really exist Well science can begin to explain how Harrys cloak could actually be invisible to the human eyeFor Harrys cloak to be invisible it needs to change the way light interacts with it An object is only visible if it reflects or bends (refracts) light that lands on its surface If an object doesnt reflect or bend light it becomes invisible

alanglazetauntonsacuk

When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

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f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

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Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

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  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 32: Science Experiments

When light travels from one material to another it usually changes speed This change in speed causes the light to bend and our eyes can detect the difference For example when light moves from the air into a raindrop and back out again the light changes its speed in the raindrop and bends When a straw is placed in a glass of water it may look broken because the light reflecting off the straw in the water is refractedEach transparent material bends light by a particular amount depending on the material the light is travelling from We call the amount of bent light the refractive index For example if the refractive index of water were the same as air light would not bend as it passes through If light didnt bend as it passed through water we wouldnt see raindrops falling They would be invisibleTherefore the refractive index of Harrys cloak would have to be the same as air to make it appear invisible But even if Harrys cloak were invisible would Harry appear invisible tooHarrys body would have a different refractive index compared to the air and his cloak He would therefore appear visible the same way that you are visible behind a glass window For the cloak to make Harry invisible Harrys body would also need to have the same refractive index as the airInterestingly Harrys cloak would not be invisible if he wore it underwater The refractive index of water is different to air and therefore different to Harrys cloak - making it visible

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clamp

alanglazetauntonsacuk

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

alanglazetauntonsacuk

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 33: Science Experiments

Distilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically againf Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

alanglazetauntonsacuk

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

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ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

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Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

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i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

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5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
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  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 34: Science Experiments

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requiresBeaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

alanglazetauntonsacuk

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
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  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
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  • Experiment 2 Drop Cup
  • What you need
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  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 35: Science Experiments

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscousi Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have

alanglazetauntonsacuk

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

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Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 36: Science Experiments

probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

Ammonium dichromate volcano Ammonium dichromate () alcohol soaked wooden splint

Indicator RainbowLong glass tube stoppered at both ends stand and clamp droppers Universal indicator solution 05-1M acid and base (HClNaOH) Similar ndash u-tube with salt solution universal indicator copper electrodes power supply

Waxsand volcanoBeaker wax sand water

Syllabus Links

Method

Safety

alanglazetauntonsacuk

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 37: Science Experiments

Universal Indicator lsquoRainbowrsquoIntroductionA long glass tube is filled with a neutral solution of Universal indicator Hydrochloric acid is added to one end and sodium hydroxide solution to the other The tube is inverted a few times to mix the solutions and the lsquorainbowrsquo of Universal indicator colours appearsRead our standard health amp safety guidance Lesson organisationThe demonstration itself takes only a few minutes It provides a good attention-grabbing lesson starter or lesson endpointApparatus and chemicalsEye protectionFor one demonstration the teacher will needGlass tube See note 1Bungs (rubber) 2 to fit the glass tubeBeaker (100 cm3)Dropper pipettes 3Clamp stand boss and clampDistilled or deionised waterHydrochloric acid 01 mol dm-3 (Low hazard at this concentration)Sodium hydroxide solution 01 mol-3 (Irritant)Universal indicator solution (Highly flammable) See note 2Technical notesHydrochloric acid (Low hazard) Refer to CLEAPSS Hazcard 47ASodium hydroxide (Irritant) Refer to CLEAPSS Hazcard 91Universal indicator solution (Highly flammable) Refer to CLEAPSS Hazcard 32 and 40A and CLEAPSS Recipe Card 361 The glass tube needs to be about 60 cm long with an internal diameter of around 1 cm2 The concentrations of the solutions are not criticalProcedureSAFETY wear eye protection throughouta Add sufficient Universal indicator to about 60 cm3 of distilled or deionised water in a beaker to give a solution with a visible green colourb Ensure that one end of the glass tube is firmly stoppered with a rubber bungc Fill the tube to about 2 cm from the top with the Universal indicator solution Then clamp the tube vertically It is important to leave a space above the liquid in the tube so that there is an air bubble ndash this helps the mixing in step hd Add 3-4 drops of the hydrochloric acid solution The top few centimetres of the liquid should turn rede Stopper the upper end of the tube remove it from the clamp carefully invert it and then clamp it vertically again

alanglazetauntonsacuk

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
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  • Whats happening
  • What you need
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  • What you need
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  • What you need
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  • Whats happening
  • What you need
  • What To Do
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  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
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  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 38: Science Experiments

f Remove what is now the top stopper Add 3-4 drops of the sodium hydroxide solution The top few centimetres of the liquid should turn purpleg Stopper the tube Both ends of the tube should now be firmly stopperedh Remove the tube from the clamp and carefully invert it 2 or 3 times The movement of the air bubble will mix the contents and produce a lsquorainbowrsquo in the tube showing all the colours of Universal indicator from red through orange yellow green blue and purpleBurning moneyFireproof papera Put 2-3 g of potassium manganate(VII) in a small pile on the tin lid standing on the heatproof mat Make a small hollow in the centre of the pileb Pour about 1 cm3 of glycerol into the hollow in the pile of potassium manganate(VII) It is sometimes better if the glycerol is warmed just before use After about 20 seconds (but beware ndash it can be much longer) the mixture starts to give off steam The glycerol in the mixture then ignites burning with a bright pinkish (lilac) flame for a few seconds more leaving a dark brown or black residue

Making glue from milkA form of glue can be made from the protein casein in milk The casein is separated from milk by coagulation and precipitationRead our standard health amp safety guidance Lesson organisationThis experiment should take no more than about 30 minutes It can be done by students in groups of two or threeApparatus and chemicalsEye protectionEach group requires

alanglazetauntonsacuk

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 39: Science Experiments

Beaker (250 cm3)Glass stirring rodFilter funnel and filter paperPaper towelTeaspoonConical flask (250 cm3)Bunsen burner tripod and gauzeSkimmed milk 125 cm3

Distilled vinegar 25 cm3 See note 1Sodium hydrogencarbonate about a teaspoonfulTechnical notes1 Distilled vinegar is best because it is colourless Other forms of vinegar can be used A dilute solution of ethanoic acid could also be used

ProcedureSAFETY Wear eye protectiona Place about 125 cm3 of skimmed milk into the 250 cm3 beaker and add about 25 cm3 of vinegarb Heat the beaker gently with constant stirring until small lumps begin to formc Remove the beaker from the heat and continue to stir until no more lumps formd Allow the curds to settle Decant off some of the liquid (known as whey) Filter off the remainder into the conical flask using the funnel and filter papere Use the paper towel to remove excess liquid from the curds in the filter paperf Transfer the curds to the empty beaker add about 15 cm3 of water and stirg Add about half a teaspoonful of sodium hydrogen carbonate Watch for bubbles of gas Then add a little more sodium hydrogen carbonate until no more bubbles appearh Stir the solid You will find that it now has the consistency of glue and is very viscous

alanglazetauntonsacuk

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 40: Science Experiments

i Students could devise a way to test their glue The teacher must check students plans before they start testing Teaching notesCasein is the predominant protein found in fresh milk and cheese In milk it exists in the form of a soluble calcium saltIn its acidic form casein is precipitated by acids such as ethanoic acid (the predominant acid in vinegar) In this experiment calcium ethanoate is a by-product of the initial souring process and it is one of the components of the whey solution The insoluble casein which forms the curds has relatively little secondary or tertiary structure This means it cannot denature (change structure) It is relatively hydrophobic and this is why it is fairly insoluble in waterIf appropriate students may like to be reminded of Little Miss Muffet lsquowho sat on a tuffet eating her curds and whey rsquo Students should realise that they have probably eaten curds and whey because these are the lumps and the liquid in cottage cheese However in cheese manufacture vinegar isnrsquot the agent used to precipitate out the casein the enzyme lsquorenninrsquo is used insteadIn addition to being consumed in milk casein is used to manufacture adhesives binders protective coatings plastics (such as for knife handles and knitting needles) fabrics food additives and many other products It is commonly used by bodybuilders as a slow-digesting source of amino acidsStudent questionsHere are some possible questions for students (Answers in brackets)1 What do you think is the purpose of the vinegar in this experiment (To convert the casein into an insoluble form - the curds)2 Why is sodium hydrogen carbonate added (To remove any excess acid)3 What is the gas given off when the sodium hydrogen carbonate is being added (Carbon dioxide - acids react with carbonates to form this gas)4 Use a search engine to find information about casein which is present in milk What type of substance is casein (Casein is a protein or more precisely a phosphoprotein)Health and Safety checked September 2007Web linksThis gives general information on casein in milkwwwfoodsciuoguelphcadairyeduchemhtml

alanglazetauntonsacuk

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 41: Science Experiments

Flame colours ndash a demonstrationThis demonstration experiment can be used to show the flame colours given by alkali metal alkaline earth metal and other metal salts This is a spectacular version of the lsquoflame testsrsquo experiment that can be used with chemists and non-chemists alike

It can be extended as an introduction to atomic spectra for post-16 students

Read our standard health amp safety guidance

Lesson organisation

This experiment must be done as a demonstration It takes about ten minutes if all is prepared in advance

Preparation includes making up the spray bottles and conducting a risk assessment

Your employers risk assessment must be customised by determining where to spray the flame to guarantee the audiencersquos safety Use a fume cupboard unless you are sure of an alternative space

Apparatus and chemicals

Eye protection

Access to fume cupboard (unless a safe alternative space is available)

Trigger pump operated spray bottles (see note 1) Bunsen burner Heat resistant mat(s)Hand-held spectroscopes or diffraction gratings (optional)

Samples of the following metal salts (no more than 1 g of each) (see note 2)

Sodium chloride (Low hazard)Potassium chloride (Low hazard) (see note 3)Lithium chloride (Harmful) (see note 3)Copper sulfate (Harmful Danger to the environment) Ethanol (Highly flammable) approx 10 cm3 for each metal salt or IDA (industrial denatured alcohol) (Highly flammable Harmful)

Technical notes

Sodium chloride is Low hazard Refer to CLEAPSS Hazcard 47BPotassium chloride is Low hazard Refer to CLEAPSS Hazcard 47BLithium chloride is Harmful Refer to CLEAPSS Hazcard 47BCopper sulfate is Harmful Danger to the environment Refer to CLEAPSS Hazcard 27C

alanglazetauntonsacuk

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 42: Science Experiments

Ethanol is Highly flammable IDA (industrial denatured alcohol) is Highly flammable Harmful Refer to CLEAPSS Hazcard 40A

1 Spray bottles of the type used for products such as window cleaner should be used These piston-operated spray bottles should be emptied cleaned thoroughly and finally rinsed with distilled water Ideally one bottle is needed for each metal salt Never use spray bottles with a rubber bulb - the flame may flash back into the container

2 The chlorides of metals are the best but other salts also work Make a saturated solution of each salt in about 10 cm3 ethanol To do this add the salt to the ethanol in small quantities with stirring until no more will dissolve ndash often only a few mg of salt will be needed Place each solution in a spray bottle and label the bottle The solutions can be retained for future use They can be stored in the plastic bottles for several weeks at least without apparent deterioration of the bottles

3 Potassium iodide and lithium iodide can be used instead As a general rule chlorides are usually suggested as they tend to be more volatile and more readily available These two are in fact a little more volatile than the chloride and potassion iodide is certainly likely to be available (refer to CLEAPSS Hazcard 47B) Other metal salts (eg those of calcium and barium) can also be used provided an appropriate risk assessment is carried out Barium chloride is toxic but gives a different colour (refer to CLEAPSS Hazcard 10A) while calcium chloride (Irritant) and strontium chloride (Irritant) are different again (refer to CLEAPSS Hazcard 19A)

Procedure

HEALTH amp SAFETY Carry out the whole experiment in a fume cupboard or an area you have previously shown to be safe Wear eye protection Ensure that the spray can be safely directed away from yourself and the audience

a Darken the room if possible

b Light the Bunsen and adjust it to give a non-luminous roaring flame (air hole open)

c Conduct a preliminary spray in a safe direction away from the Bunsen flameAdjust the nozzles of the spray bottles to give a fine mist

d Choose one spray bottle Spray the solution into the flame in the direction you have rehearsed Repeat with the other bottles

e A spectacular coloured flame or jet should be seen in each case The colour of the flame depends on the metal in the salt used

f As an extension students can view the flames through hand-held spectroscopes or diffraction gratings in order to see the line spectrum of the element (Diffraction gratings work better A better way to produce a steady source of light is to use discharge tubes from the Physics Department ndash with a suitable risk assessment)

Teaching notes

alanglazetauntonsacuk

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 43: Science Experiments

The colours that should be seen are

sodium ndash yellow-orange (typical lsquostreet lamprsquo yellow)potassium ndash purple-pink traditionally referred to as lsquolilacrsquo (often contaminated with small amounts of sodium)lithium ndash crimson redcopper ndash greenbluecalcium ndash orange-red (probably the least spectacular)barium ndash apple greenstrontium ndash crimson

The electrons in the metal ions are excited to higher energy levels by the heat When the electrons fall back to lower energy levels they emit light of various specific wavelengths (the atomic emission spectrum) Certain bright lines in these spectra cause the characteristic flame colour

The colour can be used to identify the metal or its compounds (eg sodium vapour in a street lamp) The colours of fireworks are of course due to the presence of particular metal salts

Health amp Safety checked June 2007

Teacherrsquos Instructions ndash Cannon FireFor Demonstration OnlyMake sure you havehellipCrystallising dishHydrogen peroxide (H2O2 100 Volume)Potassium permanganate (Manganate (VII) KMnO4)EthanolSpatulaMatchesTaper2 x heatproof matsMeasuring cylinderWhat to dohellip1 Measure 20 ml ethanol 5 cm3 hydrogen peroxide and 20 ml water into the crystallising dish on a heatproof mat Place a second heatproof mat to one side2 Light the solution with a taper3 Scoop the end (tiny amount) of a spatula of potassium permanganate and tip it into thecrystallising dish You should see an increase in the size of the flame and hear a popping sound4 Extinguish the flame by placing the second heatproof mat on top of the crystallising dish

alanglazetauntonsacuk

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 44: Science Experiments

5 Wash everything up (solution can go down the sink)

Whatrsquos HappeningPotassium permanganate oxidises hydrogen peroxide to produce oxygen (NB Contrary to popular belief the potassium permanganate is NOT a catalyst) Ethanol burns to give a transparent blue flame When you add the potassium permanganate it reacts with the hydrogen peroxide to produce oxygen in small ldquopocketsrdquo

2KMnO4 + 3H2O2 1048576 1048576 2MnO2 + 2H2O + 3O2 + 2KOHThese pockets of oxygen increase the intensity of the reaction and you get the cannon fire noise as the pockets of oxygen hit the flameIf you look carefully when the flame erupts you can sometimes see a violet colour This is because there is a metal in a flame ndash potassium Potassium gives a violet flame colour

alanglazetauntonsacuk

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 45: Science Experiments

Supersaturated sodium ethanoate crystallisation To prepare solution add 160g of sodium ethanoate to 30ml distilled water in a clean dry 250ml conical flask Use distilled water to wash any loose crystals from side of flask into solution Place flask on hotplate heat until all crystals dissolved Remove from heat and cover with parafilm or equivalent Allow to cool to room temperature (may take hours)

alanglazetauntonsacuk

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 46: Science Experiments

Smoke Bombs

potassium nitrate sugar (sucrose) water fuse paper or plastic cups plastic spoon waxed paper

Construct the Smoke Bombs 1 In a paper or plastic cup mix 3 parts potassium nitrate with 2 parts sugar (eg 3 tablespoons

potassium nitrate and 2 tablespoons sugar)2 Using your plastic spoon stir in just enough water to make a thick paste Continue stirring until the

ingredients are evenly mixed3 Set lumps of the mixture (~1 tablespoon each or a little less) onto the waxed paper Insert a fuse

into each lump4 Allow the smoke bombs to set up for 1-2 days The drying time will depend on temperature and

humidity Warmer and drier is faster cooler and damper will take longer Keep the smoke bombs away from excessive heat or flame The smoke bombs will be like clay when they are ready not hard and solid

5 Set a completed smoke bomb outdoors on a fireproof surface and light it

Coloured Smoke Bomb Materials

60 g (3 tablespoons) potassium nitrate (sold as saltpeter in garden supply shops) 40 g (2 tablespoons) sugar 1 teaspoon baking soda 60 g (3 tablespoons) powdered organic dye (found in laundry sections of the store as well as craft

amp hobby shops) cardboard tube (best is an iced push-pop tube (eat the treat first) or you could use a toilet paper

roll or section of paper towel tube or even a rolledtaped paper tube) duct tape pen or pencil firework fuse (hardware rocketry construction or hobby shops or scavenge it from a firework) cotton balls saucepan

Make the Coloured Smoke Bomb Mixture 1 Mix 60 g potassium nitrate with 40 g sugar in a saucepan over low heat Its a 32 ratio so if you

dont have grams use three large spoonfuls of potassium nitrate and two large spoonfuls of sugar (3 tablespoons and 2 tablespoons if you feel the need to be precise)

2 The sugar will caramelise and brown Stir the mixture continuously until it resembles smooth peanut butter

alanglazetauntonsacuk

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 47: Science Experiments

3 Remove the mixture from heat 4 Stir in a spoonful of baking soda (rounded teaspoon is fine) The baking soda is added to slow

down the combustion when the smoke bomb is ignited 5 Add three large spoonfuls (3 tablespoons) of powdered organic dye Blue dye and orange dye are

said to produce better results than the other colors Stir to mix well 6 Construct the smoke bomb while the mixture is still hot and pliable

Assemble the Smoke Bomb 1 Fill a cardboard tube with the warm smoke bomb mixture 2 Push a pen or pencil down into the centre of the mix (doesnt have to be all the way to the bottom

but should be enough that the pen stands in the mixture) You could use a different shape but the cylinder works really well

3 Let the mixture harden (about an hour) 4 Remove the pen 5 Insert a firework fuse Push pieces of cotton balls into the hole to tamp the fuse securely inside the

smoke bomb Be sure there is fuse left outside of the tube so that you will be able to light your smoke bomb

6 Wrap the smoke bomb with duct tape Cover the top and bottom of the tube too but leave the hole area with the cotton and fuse uncovered

7 Go outside and light your smoke bomb

Many commercial smoke machines use fog juice that consists of glycols glycerine andor mineral oil with varying amounts of distilled water The glycols are heated and forced into the atmosphere under pressure to create a fog or haze There are a variety of mixtures that may be used See the reference bar to the right of this article for Material Safety Data Sheets on some example types Some homemade recipes for fog juice are

1 15-35 food grade glycerine to 1 quart distilled water2 125 ml glycerine to 1 liter distilled water

(glycerine creates a haze at concentrations of 15 or less and more of a fog or smoke at concentrations higher than 15)

3 Unscented mineral oil (baby oil) with or without water(I cant vouch for the safety of using mineral oil for fog juice)

4 10 distilled water 90 propylene glycol (dense fog) 40 distilled water 60 propylene glycol (quick dissipating) 60 water 40 propylene glycol (very quick dissipation)

5 30 distilled water 35 dipropylene glycol 35 triethylene glycol (long-lasting fog) 6 30 distilled water 70 dipropylene glycol (dense fog)

The resulting smoke should not smell burnt If it does likely causes are too high of an operating temperature or too much glycerineglycolmineral oil in the mixture The lower the percentage of organic the less expensive the fog juice but the fog will be lighter and will not last as long Distilled water is only necessary if a heat exchanger or other tubing is used in the system Using a homemade fog mixture in a commercial machine will almost certainly void the warranty possibly damage the machine and possibly pose a fire andor health hazard

alanglazetauntonsacuk

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 48: Science Experiments

Important Points

This type of fog is heated and will rise or disperse at a higher level than dry ice or liquid nitrogen fog Coolers can be used if low-lying fog is desired

Changing the mixture or conditions of dispersion of atomized glycols can result in many special effects that are difficult to achieve with other simulated smokes

Glycols can undergo heat denaturation into highly toxic substances such as formaldehyde This is one of the major problems with homemade smoke machines - they may operate at a temperature that is incompatible with the substances being used Also this is a danger with homemade fog juice used in commercial machines

Glycols glycerine and mineral oil can all leave an oily residue resulting in slick or sometimes slightly sticky surfaces Be aware of the potential safety hazards especially since the smoke may limit visibility Also some people may experience skin irritation from exposure to glycol fog

Some glycols are toxic and should not be used to create smoke Ethylene glycol is poisonous Some glycols are sold as mixtures Medical or pharmaceutical grade non-toxic glycols only should be used in smoke machines Do not use antifreeze to make a fog mixture The ethylene glycol types are poisonous and the propylene glycol types always contain undesirable impurities

If water is used it needs to be distilled water since hard water deposits can damage the atomizer apparatus

Some of the chemicals that can be used for this type of smoke are flammable

How to light a smoke bomb

The solid smoke bomb material is flammable and can be lit directly You can light your smoke bomb using a lighter preferably one of the long-handled types used for barbeque grills Only light your smoke bomb in a well-ventilated area on a surface that wont catch fire The smoke bomb will burn vigorously (more slowly with a higher percentage of sugar) with a purple flame

Alternatively you could place a short length of wick into the smoke bomb when you pour it and then light the wick

alanglazetauntonsacuk

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
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  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
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  • Whats happening
  • What you need
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  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 49: Science Experiments

White Smoke Recipe

Potassium nitrate - 4 parts Charcoal - 5 parts Sulfur - 10 parts Wood dust - 3 parts

Red Smoke Recipe

Potassium chlorate - 15 para-nitroaniline red - 65 Lactose - 20

Green Smoke Recipe

Synthetic indigo - 26 Auramine (yellow) - 15 Potassium chlorate - 35 Lactose - 26

Elephant Toothpaste Materials

50-100 ml of 30 hydrogen peroxide (H2O2) solution saturated potassium iodide (KI) solution liquid dishwashing detergent food coloring 500 mL graduated cylinder splint (optional)

Safety

Wear disposable gloves and safety glasses Oxygen is evolved in this reaction so do not perform this demonstration near an open flame Also the reaction is exothermic producing a fair amount of heat so do not lean over the graduated cylinder when the solutions are mixed Leave your gloves on following the demonstration to aid with cleanup The solution and foam may be rinsed down the drain with water

Procedure

1 Put on gloves and safety glasses The iodine from the reaction may stain surfaces so you might want to cover your workspace with an open garbage bag or a layer of paper towels

2 Pour ~50 mL of 30 hydrogen peroxide solution into the graduated cylinder3 Squirt in a little dishwashing detergent and swirl it around4 You can place 5-10 drops of food coloring along the wall of the cylinder to make the foam

resemble striped toothpaste5 Add ~10 mL of potassium iodide solution Do not lean over the cylinder when you do this as the

reaction is very vigorous and you may get splashed or possibly burned by steam6 You may touch a glowing splint to the foam to to relight it indicating the presence of oxygen

alanglazetauntonsacuk

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
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  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 50: Science Experiments

Elephant Toothpaste Chemistry

The overall equation for this reaction is

2 H2O2(aq) --gt 2 H2O(l) + O2(g)

However the decomposition of the hydrogen peroxide into water and oxygen is catalzyed by the iodide ion

H2O2(aq) + I-(aq) --gt OI-(aq) + H2O(l)

H2O2(aq) + OI-(aq) --gt I-(aq) + H2O(l) + O2(g)

The dishwashing detergent captures the oxygen as bubbles Food coloring can color the foam The heat from this exothermic reaction is such that the foam may steam If the demonstration is performed using a plastic bottle you can expect slight distortion of the bottle from the heat

One of the most spectacular chemistry demonstrations is also one of the simplest Its the dehydration of sugar (sucrose) with sulfuric acid Basically all you do to perform this demonstration is put ordinary table sugar in a glass beaker and stir in some concentrated sulfuric acid (you can dampen the sugar with a small volume of water before adding the sulfuric acid) The sulfuric acid removes water from the sugar in a highly exothermic reaction releasing heat steam and sulfur oxide fumes Aside from the sulfurous odor the reaction smells a lot like caramel The white sugar turns into a black carbonized tube that pushes itself out of the beaker Heres a nice youtube video for you if youd like to see what to expect

What HappensSugar is a carbohydrate so when you remove the water from the molecule youre basically left with elemental carbon The dehydration reaction is a type of elimination reaction

C12H22O11 (sugar) + H2SO4 (sulfuric acid) rarr 12 C (carbon) + 11 H2O (water) + mixture water and acid

Although the sugar is dehydrated the water isnt lost in the reaction Some of it remains as a liquid in the acid Since the reaction is exothermic much of the water is boiled off as steam

Safety Precautions If you do this demonstration use proper safety precautions Whenever you deal with concentrated sulfuric acid you should wear gloves eye protection and a lab coat Consider the beaker a loss since scraping burnt sugar and carbon off of it isnt an easy task Its preferable to perform the demonstration inside of a fume hood

alanglazetauntonsacuk

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 51: Science Experiments

Look at the websites of the chemistry department at your local or nearest University ndash most do have a link

to school activities but if not do have a look at the widening participation (WP)of that University

A good summary of different enrichment activities for in or outside the classroom can be found in the STEMNET directory ndash hopefully this will be updated for the next academic yearhttpwwwstemdirectoriesorgukteachers_amp_lecturersstem_directories_print_copiescfm

Some useful websitesSpectroscopy ndash tutorials videos etc for NMR IR and MS

httpwwwchemuclacukschoolsindexhtml

httpwwwleacukspectraschool

httpwwwrscorgeducationteacherslearnnetspectraindexhtm

httpwwwchemualbertaca~iipspectrotutorialTblofConthtml

Interactive lab-primer (excellent resource developed by last yearrsquos RSC Teacher Fellows on lab

techniques (videos and animations) - httpwwwrsc-teacher-fellowsnetindexhtm

Theory and revision

httpwwwchemguidecouk

httpwwwknockhardyorgukscihtm

httpchemincontexteppgcomchapter1indexhtml

httpwwwwwnortoncomcollegechemistrygilberthomehtm

httpwwwdocbrowninfoindexhtm

httpwwwbestchoicenetnz

httpwwwchemcollectiveorg httpwwwsucceedingwithsciencecomlabmouseindexphp (AQA specification)httpscienceuweacuklsorgchem (resource on organic chemistry)

Useful site summarising the RSC publications and resources for teachers

httpwwwrscorgimagesPubCatalogue_tcm18-128260pdf

Link that contains a list of useful resources with websites

httpwwwrscorgeducationteacherslearnnetcflearnnetresource_detscfmsubj=t

Chemistry resources KS3 AS and A2 ndash (AQA specification) httpchemsheetscouk

alanglazetauntonsacuk

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes
Page 52: Science Experiments

A good resource for Chemistry Biology and Maths but not free (look at the 30 day trial)

httpwwwyteachcouk

Some interesting articles and podcasts httpwwwthenakedscientistscomHTMLarticleschemistry

Chemistry diagrams httpwwwbtinternetcom~chemistrydiagramsindexhtm

PowerPoint presentations developed by teachers httpwwwworldofteachingcomchemistrypowerpointshtml

A teacher resource exchange for a range of subjects ndash a keyword search will take you to the chemistry resources httpwwwtrengflgovukserverphprequest=cmVzb3VyY2UuZnVsbhZpZXc

Careers in Sciencehttpwwwnoisemakersorgukindexcfm httpwwwicouldorgukIndexaspxhttpwwwfuturemorphorg httpwwwplanet-sciencecomnextstepsstarthtml

Publication ndash Science Enhancement Programme (SEP) httpwwwseporguk

videoshttpwwwsciencetvhttpwwwperiodicvideoscomabouthtm (videos on elements of the periodic table Nottingham University)

workresearch experience and work based learning Nuffield Science Bursaries and Engineering Development trusthttpwwwetrustorgukhttpwwwnuffieldfoundationorggograntsnsbpage_390html

Chemistry podcasts on articles from Chemistry World and the elements (RSC) httpwwwrscorgchemistryworldpodcastindexasp

alanglazetauntonsacuk

  • Tips
  • What You Need
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Mix it up
  • Salad dressing
  • Mayonnaise
  • What you need
  • What to do
  • Whats happening
  • What you need
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  • What you need
  • What to do
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  • What you need
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  • Whatrsquos happening
  • Applications
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whatrsquos happening
  • What you need
  • What to do
  • What you need
  • What to do
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What To Do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Experiment 2 Drop Cup
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Applications
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • What you need
  • What to do
  • Whats happening
  • Flame colours ndash a demonstration
    • Lesson organisation
    • Apparatus and chemicals
    • Technical notes
    • Procedure
    • Teaching notes