SAMPLE ANALYSES - Superfund Records Collections Oxygen Demand Total Organic Carbon Total Suspended Solids PH Hach Water Analysis Handbook. 2nd Ed, 1992 Parameter Chemical Oxygen Demand

I N C H C A P E T E S T I N G S E R V I C E SWest-Paine Laboratories, Inc.7 9 7 9 G S R I A V C . • Baton Rouge, LA. 70820504-769-4900 Fax: 504-767-5717

144205

OO

S A M P L E A N A L Y S E S

f o r

** ] l i .I!-;i

L A . D E I ' T , O , "E N V I B O N i v l D i f A L . Q U A L I T Y! A S O ' i V l i J i O N

LA DEPT OF ENV QUALITY/I&AI N A C T I V E & ABANDONED S I T E S D I VPO BOX 82282BATON R O U G E , LA 708842282

A T T E N T I O N : M R HAROLD E T H R I D G E

May 6, 1993

hal 302245

I N C H C A P E T E S T I N G S E R V I C E SWcst-Painc Laboratories, Inc.7 9 7 9 G S R l A v e . • B»ton Rouge, LA 70820504-769-4900 Fax: 504-767-5717

LA DEPT OF ENV QUALITY/I&ABATON R O U G E , LA 708842282May 6, 1993

S a m p l e receipt at WEST-PAINE LABORATORIES INC i s documented for yourdes ignated s a m p l e ( s ) . Chain-o f- cu s t ody documentation, i f prov ided , i s includedin this report. S a m p l e analysis was in accordance with Environmental ProtectionAgency pro toco l .A. M e t h o d s for Chemical A n a l y s i s o f Water and W a s t e s . E P A - 6 0 0 / 4 - 7 9 - 0 2 0 , 1983

ParameterAntimonyArsenicBariumChromiumCyanideC o p p e r.Lead.MercuryZincOil & Grease

Method204.1206.2208.1218.1335.3220.1

-2-3-9-.-1245.1289.1413.2

B. Standard Method s for the Examination of Water and Wastewater . 17th Ed, 1989ParameterBiochemical Oxygen DemandT o t a l Organic CarbonT o t a l S u s p e n d e d S o l i d sPH

Hach Water A n a l y s i s Handbook. 2nd Ed, 1992ParameterChemical Oxygen Demand

Method5210-B5310 B2540 D4500-H+B

Method8000 & 8328

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BATON ROUGE, LA 708842282May 6, 1993

S a m p l e receipt a t WEST-PAINE LABORATORIES INC i s documented f or your de s ignateds a m p l e ( s ) . Chain of custody documentation, if provided, is included in this report. S a m p l eanalys i s was in accordance with Environmental Protec t ion Agency p r o t o c o l .

A. T e s t M e t h o d s f o r Eva lua t ing S o l i d W a s t e . S W - 8 4 6 3rd E d . , November 1986Parameter MethodA c i d ( P h e n o l ) F r a c t i o n 8270Base-Neutral Frac t i on 8270V o l a t i l e Organic Compounds 8240P C B ' s 8080

Documented results""are shown on the f o l l o w i n g page (s) .

W. R. PalmerC h i e f Operat ing O f f i c e r

302245

I N C H C A P E T E S T I N G S E R V I C E SWest-Painc Laboratories, Inc.7 9 7 9 G S R I A V C . • Baton Rouge, LA 70820504-769-4900 F«* 504-767-5717 LA DEPT OF ENV QUALITY/ I &A

BATON R O U G E , LA 708842282May 6, 1993S a m p l e Source: A 1 8 0 4 2 6 9 3 - 4 0Date C o l l e c t e d : 9 3 / 0 4 / 2 6 T i m eDate Received: 9 3 / 0 4 / 2 6 T i m e

Parameter( U n i t s ) Resul t sBiochemical Oxygen Demand( m g / L 0 2 ) 9 . 6Chemical Oxygen Demand( m g / L 0 2 ) 8 2T o t a l Organic Carbon"(mg7L C) 25T o t a l S u s p e n d e d S o l i d s( m g / L ) 15.2pH ( U n i t s ) 7 .8Oil & Grease( m g / L ) . < 2.0Cyanide( m g / L C N ) < 0.002Antimony( m g / L Sb) < 0 .1Arsenic( m g / L As) < 0.01

C o l l e c t e d :Received:Detect ionLimit

1.0

5.0

1.0

0.1

2.0

2.0

0.002

0.1

0.01

10:3012:39Qual i ty AssuranceActua 1 / Found

1 0 0 / 9 6

100/106

2 5 / 2 2

5 0 . 0 / 4 8 . 2

8 . 0 0 / 7 . 9 6

N / A

0 . 0 5 0 / 0 . 0 4 6

1 0 . 0 / 1 0 . 0

0 . 0 5 0 / 0 . 0 5 1

Date/ T i m eA n a l y s t

9 3 / 0 4 / 2 7 14:00 S N L

9 3 / 0 4 / 2 7 09:30 S N L

9 3 / 0 4 / 2 7 16:30 LML

9 3 / 0 4 / 2 7 2 2 : 2 5 J D T

9 3 / 0 4 / 2 6 15:45 S N L

9 3 / 0 4 / 2 9 00:00 T S B

9 3 / 0 4 / 2 8 18:39 H E R

9 3 / 0 4 / 2 8 10:00 DLG

9 3 / 0 5 / 0 3 13:00 DLG

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I N C H C A P E T E S T I N G S E R V I C E SWcst-Painc Laboratories, Inc.7 9 7 9 G S R I A V C . • Baton Rouge, LA 70820504,76?-4900 Fwc 504-767-5717

S a m p l e Source:Date C o l l e c t e d :Date Received:

LA DEPT OF ENV QUALITY/ISABATON R O U G E , LA 708842282May 6, 1993

A18042693-409 3 / 0 4 / 2 6 T i m e C o l l e c t e d : 10:309 3 / 0 4 / 2 6 T i m e Received: 12:39Parameter( u n i t s )Barium( m g / L B a )C o p p e r( m g / L C u )Chromium

Detect ion Q u a l i t y Assurance D a t e / T i m eResul t s Limit Actual / F o u n d A n a l y s t

0.23 0.1 1 0 . 0 / 9 . 9 9 3 / 0 4 / 2 8 10:00 DLG

< 0.02 0.02 1 0 . 0 / 9 . 9 9 3 / 0 4 / 2 8 10:00 DLG

< 0.05 0.05 1 0 . 0 / 9 . 9 9 3 / 0 4 / 2 8 10:00 DLGLead( m g / L P b )Mercury( m g / L H g )Z i n c( m g / L Z n )

< 0.1

< 0.0002

0.03

0.1

0.0002

0.01

1 0 . 0 / 1 0 . 0

0 . 0 0 5 / 0 . 0 0 5

10.0/10.1

9 3 / 0 4 / 2 8 10:00 DLG

9 3 / 0 4 / 2 9 09:00 RBM

9 3 / 0 4 / 2 8 10:00 DLG

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I N C H C A P E T E S T I N G S E R V I C E SWcst-Painc Laboratories, Inc.7 9 7 9 G S R I A v e . • Baton Rouge, LA 70820504-769-4900 Fax: 504-767-5717

P R I O R I T Y P O L L U T A N T SA c i d ( P h e n o l ) F r a c t i o n

LA DEJPT OF ENV QUALITY/ISABATON! R O U G E , LA 708842282S A M P L E #: 9304260058

All r e su l t s in micrograms per l i t e rS A M P L E SOURCE: A18042693-40S a m p l e Date: 9 3 / 0 4 / 2 6 S a m p l e T i m e : 10:30

Parameter2-chlorot>henol2 . 4-Dichlorophenol2 r 4-Dimethylpheno l4 . 6-Dinitro-o-Cresol2 , 4-Dinitroohenol2 - N i t r o p h e n o l4 - N i t r o p h e n o lp-Chloro-m-cresolP e n t a c h l o r o p h e n o lPhenol2 . 4 , 6 - T r i c h l o r o p h e n o l

Result< 10< 10< 10< 50< 50< 10< 50< 10< 50< 10< 10

Detec t ionLimit1010105050105010501010

Date o f A n a l y s i s : 9 3 / 0 5 / 0 3 A n a l y s t : J M K

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I N C H C A P E T E S T I N G S E R V I C E SWest-Paine Laboratories, Inc.7979 GSRI Ave. • Baton Rouge, LA 70820504-769-4900 FJOC 504-767-5717

LA D^PT OF ENV QUALITY/I&AB A T O l f R O U G E , LA 708842282S A M P L E #: 9304260058

Q U A L I T Y A S S U R A N C E / Q U A L I T Y C O N T R O LPERCENT RECOVERY

A c i d ( P h e n o l ) F r a c t i o n

Parameter_______________:_____________A18042693-40Phenol-d6 832 - F l u o r o p h e n o l 762 , 4 , 6 - T r i b r o m o p h e n o 1 85

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I N C H C A P E T E S T I N G S E R V I C E SWest-Paine Laboratories, Inc.7979 GSRI Ave. • Baton Rouge, LA 70820504-769-4900 Rue 504-767-5717

P R I O R I T Y P O L L U T A N T SBase-Neutral F r a c t i o n

LA DEPT OF ENV QUALITY/I&AB A T O l f ROUGE, LA 708842282S A M P L E #: 9304260058

;AH re su l t s in micrograms per l i t e rS A M P L E S O U R C E : A 1 8 0 4 2 6 9 3 - 4 0S a m p l e Date: 9 3 / 0 4 / 2 6 S a m p l e T i m e : 10:30

ParameterAcenaphtheneA c e n a p h t h y l e n e ;Anthracene iBenzid ineBenzo f a ) anthraceneBenzo ( a ) pyreneBenzo (b) f l u o r a n t h e n e :Benzo ( a h i ) p ery l eneBenzo ( k ) f l u o r a n t h e n ebis (2 -Chlo iro e thoxy) methanebis ( 2 - C h l o r o e t h y l ) etherbis C 2 - C h l o r o i s o p r o p v l ) etherbis ( 2 - E t h v l h e x y l ) p h t h a l a t e4-Bromophenyl phenyl etherButyl benzyl p h t h a l a t e2 - C h l o r o n a p h t h a l e n e4 - C h l o r o p h e n y l phenyl etherChryseneDibenzo( a, h) anthracene1 , 2-Dichlorobenzene1 f 3-Dichlorobenzene1 , 4-Dichlorobenzene3 . 3 ' - D i c h l o r o b e n z i d i n eDiethvl p h t h a l a t eDimethyl p h t h a l a t eDi-n-butyl p h t h a l a t e2 f 4-Dini tro to luene2 , 6-Dini tro to luene :

Di-n-octyl p h t h a l a t e1 ,2-Diphenylhydraz ine *F l u o r a n t h e n eF l u o r e n eHexach loroben z eneH e x a c h 1 or obut ad ieneH e x a c h l o r o c y c l o p e n t a d i e n e

Result< 10< 10< 10< 40< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 20< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10

DetectionLimit1010104010101010101010101010101010101010101020101010101010101010101010

* l r 2-Diphenylhydraz ine as Azqbenzene

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P R I O R I T Y P O L L U T A N T SBase-Neutral Frac t i on

LA DEtT OF ENV QUALITY/1 &ABATON ROUGE, LA 708842282S A M P L E #: 9304260058

All result s in micrograms per l i t erS A M P L E S O U R C E : A18042693-40S a m p l e Date: 9 3 / 0 4 / 2 6 S a m p l e T i m e : 10:30

1Parameter ( C o n t i n u e d )!

H e x a c h l o r o e t h a n eIndeno ( 1 . 2 , 3 -c , d) pyreneI s o p h o r o n eN a p h t h a l e n e iN i t r o b e n z e n eN - N i t r o s o d i m e t h v l a m i n eN - N i t r o s o d i - n - p r o p y l a m i n eN - N i t r o s o d i p h e n y l a r a i n e ** ;

PhenanthrenePyrene ••1 . 2 , 4-Trich lorob enzene

Result< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10

Detect ionLimit1010101010101010101010

Date o f A n a l y s i s : 9 3 / 0 5 / 0 3 ; A n a l y s t : J M K

**N-Nitro sod iphenylamine decomposes in the GC inlet and cannotbe separated from Diphenylainine.hal 302245

I N C H C A P E T E S T I N G S E R V I C E SWest-Painc Laboratories, Inc.7 9 7 9 G S R I A v e . • Baton Rouge, LA 70820504-769-4900 Fax: 504-767-5717

L A D E J P T O F E N V Q U A L I T Y / I & ABATON! ROUGE, LA 708842282SAMPLjE #: 9304260058

Q U A L I T Y A S S U R A N C E / Q U A L I T Y C O N T R O LP E R C E N T RECOVERY

Base-Neutral F r a c t i o n

Parameter A 1 8 0 4 2 6 9 3 - 4 0N i t r o b e n z e n e - d 52 - F l u o r o b i p h e n y lT e r p h e n y l - d l 4

809446

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I N C H C A P E T E S T I N G S E R V I C E SWest-Paine Laboratories, Inc.7 9 7 9 G S R I A v e . • Baton Rouge, LA 70820504-769-4900 F«c 504-767-5717

H A Z A R D O U S S U B S T A N C E L I S TV o l a t i l e Organic Compounds

LA DE$>T OF ENV QUALITY/1&ABATON|ROUGE, LA 708842282SAMPLE #: 9 3 0 4 2 6 0 0 5 8

All r e su l t s in micrograms per l i t e rS A M P L E S O U R C E : A18042693-40S a m p l e Date: 9 3 / 0 4 / 2 6 S a m p l e T i m e : 10:30

ParameterM e t h y l c h l o r i d eMethyl bromideVinyl chlorideChloroe thaneM e t h y l e n e ch l o r id eAcetoneCarbon d i s u l f i d e1 f 1-Dichloroethene1 , 1-Dichloroethanetrans-1 . 2-DichloroetheneC h l o r o f o r m1 , 2-Dichloroe thane ;Methyl ethyl ketone1,1, 1-Trich loroe thaneCarbon t e t r a c h l o r i d eVinyl A c e t a t eDichlorobromomethane1 „ 2 -Dich l oropropanecis-1 r 3 -Dich l oropropeneT r i c h l o r o e t h e n eCh lor od ibromome thane1 , 1 , 2 - T r i c h l o r o e t h a n eBenzene 'trans-1 , 3 -Dich l oropropene :Bromoform4-Methyl-2-pentanone2-HexanoneT e t r a c h l o r o e t h e n e ^1 , 1 , 2 , 2 - T e t r a c h l o r o e t h a n e ,T o l u e n eChlorobenzeneEthylbenzeneS t y r e n eT o t a l X y l e n e :

Result< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0

< 25.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0< 5.0

Detect ionLimi t5.05.05.05.05.05.05.05.05.05.05.05.0

25.05.05.05.05.05.05.05.05.05.05.05.05.05.05.05.05.05.05.05.05.05.0

Date o f A n a l y s i s : 9 3 / 0 5 / 0 3 A n a l y s t : H J P

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I N C H C A P E T E S T I N G S E R V I C E SWest-Paine Laboratories, Inc.7 9 7 9 G S R I A v e . • Baton Rouge, LA 70820504-769-4900 Fax: 504-767-5717

LA DEFT OF ENV QUALITY/I&ABATOfcf R O U G E , LA 708842282S A M P L E #: 9304260058

Q U A L I T Y A S S U R A N C E / Q U A L I T Y C O N T R O LP E R ' C E N T R E C O V E R YV o l a t i l e Organic Compounds

Parameter______________________________A18042693-40i

l , 2 - D i c h l o r o e t h a n e - d 4 ; 100T o l u e n e - d 8 884-Bromofluorobenzene 101

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I N C H C A P E T E S T I N G S E R V I C E SWest-Paine Laboratories, Inc.7979 GSRI Ave. • Batoa Rouge, L\ 70820504-769-4900 F*x: 504-767-5717

P R I O R I T Y P O L L U T A N T SP C B ' S

LA DEJPT OF ENV QUALITY/1&ABATON: ROUGE, LA 708842282SAMPLfe #: 9304260058

All result s in micrograms per l i t erS A M P L E S O U R C E : A 1 8 0 4 2 6 9 3 - 4 0S a m p l e Date: 9 3 / 0 4 / 2 6 S a m p l e T i m e : 10:30

ParameterAroclor-1242Aroc lor-1254Aroclor-1221Aroclor-1232Aroclor-1248Aroc lor-1260Aroclor-1016A r o c l o r - 1 2 6 2Aroc lor-1268

Result< l.O< 1.0< 2.0< 1.0< 1.0< 1.0< 1.0< 1.0< 1.0

Detec t ionLimit1.01.02.01.01.01.01.01.01.0

Date o f A n a l y s i s : 9 3 / 0 4 / 3 0 A n a l y s t : J E A

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W A T E R S E M I V O L A T I L E B L A N K S P I K E / B L A N K S P I K E D U P L I C A T E RECOVERY

S a m p l e N o : 042993MB L e v e l : ( l o w / m e d ) : L o w

C O M P O U N DPhenol2-chlorophenol1 , 4— DichlorobenzeneN - N i t r o s o - d i - n - p r o p .1 , 2 , 4-Tri ch l orob enz ene4 -Ch lor o- 3 -me thy Ipheno 1Acenaphthene4 - N i t r o p h e n o l2 , 4-DinitrotoluenePentach lor opheno 1Pyrene

COMPOUND

S P I K EADDED( u c r / L )

100.00100.00

50.0050.0050.00

100.0050.00

100.0050.00

100.0050.00

S P I K EADDEDf U Q / L )

S A M P L EC O N C E N T R A T I O N( u c r / L )0.00

! 0.000.000.000.000.000.000.000.000.000.00

M S DC O N C E N T R A T I O Nf w a / L )

MSC O N C E N T R A T I O N

( U C f / L )88.0093.0044.0044.0046.0082.0046.0099.0031.0090.0046.00

M S D% %REC# RPD#

MS%REC#

8792878891819198*629092

QCL I M I T S

R E C .12- 8927-12336- 9741-11639- 9823- 9746-11810- 8024- 969-103

26-127

Q C L I M I T SRPD REG

Phenol2-Chloropheno l1 , 4 -DichlorobenzeneN - N i t r o s o - d i - n - p r o p . ( 1)1 , 2 , 4-Trich lorobenzene4 , Chloro-3-methyloehnolAcenaphthene4 -N i t r opheno 12 , 4-Dini tro to luenePentachlorophenolPyrene

100.00100.00

50.0050.0050.00

100.0050.00

100.0050.00

100.0050.00

88.00;91.0045.0044.00

!44.00180.0045.0041.0028.0028.00

:45.00

8791898788808941562789

0121312

82*10

107*3

4240283828423150385031

12- 8927-12336- 9741-11639- 9823- 9746-118ID- 8024- 969-103

26-127; i ) N - N i t r o s o - d i - n - p r o p y l a m i n e# Column to be used to f l a g recovery and RPD values with an asterisk* V a l u e s out s ide of QC l i m i t s :

RPD: 2 out of 11 out s ide l i m i t sip ike Recovery; 1 out of 22 out s ide l i m i t sC O M M E N T S ; S V W L O - 3 6 2 05-03-93/JK_____________________________________

I N C H C A P E T E S T I N G S E R V I C E SWest-Paine Laboratories, Inc.7979 GSRI Ave. • Baton Rouge, LA 70820504-769-4900 Fax: 504-767-5717

N A R R A T I V Ei

( A N A L Y S I S )!

S p i k e A l l o c a t i o n : S V W L O - 3 6 2Date: 0 5 / 0 3 / 9 3

____The Blank S p i k e ( B S ) and Blank S p i k e D u p l i c a t e ( B S D ) were usedfor QC purpo s e s because there wias not s u f f i c i e n t s ampl e volume to

I

p e r f o r m sampl e matrix sp ike s . The recovery for 4 - N i t r o p h e n o l i ss l i g h t l y higher than QC l i m i t s in the BS; however, it is not outof a n a l y t i c a l bounds. The recoveries for 4 - N i t r o p h e n o l andiPentach loropheno l are lower in the B S D , r e s u l t i n g in a highiRelat ive Percent D i f f e r e n c e ( R P D ' ) . The sp ik e s were run twice on

I

d i f f e r e n t instruments with s imi lar re su l t s each time. T h e r e was nots u f f i c i e n t s a m p l e f o r re-extraction.________________________

S u p e r v i s o r D a r e

or LouisianaDepartment of Environmental Q u a l i t yI n a c t i v e and Abandoned S i t e s Divi s i onP.O. Box 44066, Baton Rouge, LA 70804(504) 342-8925

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