Quick-FDS [16105-64582-24827-015648] - 2012-02-03 - 17:56:22 Print Close 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Commercial Name: SILICA MIX Cu Definition: Unshaped refractory material Usage: Usages according to the ECHA (European CHemical Agency) - Guidance R.12 Use descriptor system - draft version 2.0 SU10; 13 + NACE C23.2 + PC 10 + PROC 1; 2; 3; 4; 5; 8a; 9; 13; 14; 19; 21; 22; 23; 24; 26 + ERC 2; 3; 5 + AC 12-1; 12-2 Restricted to industrial or professional users for application as safety or wear linings and maintenance of both in all industrial devices Installation Method Ramming Vibrating Creation date: Date : 08/02/2007 ( DD / MM / YY ) SDS status: Revision Manufacturer: Produced by CALDERYS within the EU Contact manufacturing: Dr. Dirk HOLLAND +49 (0)1 607 070 307 - CALDERYS Deutschland GmbH _ Co OHG - Research Centre - In der Sohl 122 - D-56564 Neuwied -- CALDERYS France - Research Centre - 4 allee de Lausanne - F-38070 Saint-Quentin Fallavier Supplier: CALDERYS Person to contact: J-P.Targe - Tel +33 (0)4.74.99.99.40 - Fax 33 (0)4.74.99.99.66 : CALDERYS France - Research Centre - 4 allee de Lausanne - F-38070 Saint Quentin Fallavier jean-[email protected]Emergency telephone: UK: Medical Toxicology Unit - Avonley Road - Cse14 ER London - Phone: 44 441 716 359 191 - Fax: 44 4 417 177 153 109 See enclosed annex for other Emergency telephone 2. HAZARDS IDENTIFICATION Miscellaneous (REACH - GHS/CLP): The product named above contains a notable proportion of particules which can be suspended in the workshop air by the processes used for installation and also can become respirable dust having an effect on health. The product should be installed in a ventilated area. To avoid risks to human health and the environment, comply with the instructions for use. Hazard linked to route of exposure: Eyes (REACH): Dust can cause eye irritation. Eyes (GHS/CLP): Dust can cause eye irritation. Skin (REACH): Possible temporary irritation. Skin (GHS/CLP): Possible temporary irritation. Inhalation (REACH): Prolonged inhalation of dust less than 12 µm may effect the lungs. Prolonged and/or massive inhalation of respirable crystalline silica dust (RCS) may cause lung SAFETY DATA SHEET SILICA MIX Cu Version : 10 MQD90029 Page 1 sur 17
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Restricted to industrial or professional users for application as safety or wear linings and maintenance of both in all industrial devices
Installation MethodRamming
VibratingCreation date:
Date : 08/02/2007 ( DD / MM / YY )
SDS status:
RevisionManufacturer:
Produced by CALDERYS within the EUContact manufacturing:
Dr. Dirk HOLLAND +49 (0)1 607 070 307 - CALDERYS Deutschland GmbH _ Co OHG - Research Centre - In der Sohl 122 - D-56564 Neuwied -- CALDERYS France - Research Centre - 4 allee de
J-P.Targe - Tel +33 (0)4.74.99.99.40 - Fax 33 (0)4.74.99.99.66 : CALDERYS France - Research Centre - 4 allee de Lausanne - F-38070 Saint Quentin Fallavier
UK: Medical Toxicology Unit - Avonley Road - Cse14 ER London - Phone: 44 441 716 359 191 -Fax: 44 4 417 177 153 109
See enclosed annex for other Emergency telephone
2. HAZARDS IDENTIFICATION
Miscellaneous (REACH - GHS/CLP):
The product named above contains a notable proportion of particules which can be suspended in the workshop air by the processes used for installation and also can become respirable dust
having an effect on health.The product should be installed in a ventilated area.
To avoid risks to human health and the environment, comply with the instructions for use.Hazard linked to route of exposure:
Eyes (REACH):Dust can cause eye irritation.
Eyes (GHS/CLP):Dust can cause eye irritation.
Skin (REACH):Possible temporary irritation.
Skin (GHS/CLP):Possible temporary irritation.
Inhalation (REACH):Prolonged inhalation of dust less than 12 µm may effect the lungs.
Prolonged and/or massive inhalation of respirable crystalline silica dust (RCS) may cause lung
fibrosis, commonly referred to as silicosis. Principal symptoms of silicosis are cough and
breathlessness.May cause damage to lungs through prolonged or repeated exposure if inhaled.
See Section 16. OTHER INFORMATION. Additionnal safety information.Inhalation (GHS/CLP):
May cause respiratory irritation.Prolonged inhalation of dust less than 12 µm may effect the lungs.
Prolonged and/or massive inhalation of respirable crystalline silica dust (RCS) may cause lung fibrosis, commonly referred to as silicosis. Principal symptoms of silicosis are cough and
breathlessness.May cause damage to lungs through prolonged or repeated exposure if inhaled.See Section 16. OTHER INFORMATION. Additionnal safety information.
Ingestion (REACH):Non relevant
Ingestion (GHS/CLP):Non relevant
Environnemental hazards :EU/REACH classification:
This preparation requires the danger label :Miscellaneous :
Owing to the potential for generation of airborne respirable crystalline silica dust (> 1% ; < 2,5 %), the product has been classified and labelled as follows:
EU/REACH classification:Xn : Harmful
EU/REACH Risk phrasesR48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation.
EU/REACH Safety phrasesS22: Do not breathe dust.
S38: In case of insufficient ventilation, wear suitable respiratory equipment.GHS/CLP classification
STOT RE2, H373GHS/CLP phrases (H - EUH)
H373: May cause damage to lung through prolonged or repeated exposure by inhalation.GHS/CLP phrases (P)
P260: Do not breathe dust.P285: In case of inadequate ventilation wear respiratory protection.
P501: Dispose of contents/containers in accordance with local regulation.REACH Pictograms
Classification GHS/CLP :This preparation does not require a hazard warning label in European Union
3. COMPOSITION / INFORMATION ON INGREDIENT
Data linked to the pure substance or its reglementary concentration
REACH: T ; Repr.Cat.2, R60-R61 --- CLP: Repr.1B; H360FD - R 60-R 61
CAS : 10043-35-3
Einecs : 233-139-2>=1 <2.5
Occupational illness
Commission Recommendation of 19 September 2003 concerning the European schedule of occupational diseases (Text with EEA relevance) (notified under document number C(2003) 3297)
301 Diseases of the respiratory system and cancers301.11 Silicosis
301.12 Silicosis combined with pulmonary tuberculosis301.31 Pneumoconioses caused by dusts of silicates
2.1 Diseases caused by the following agents:2.160 Silicium oxide
Other informations :Data linked to the pure substance or its reglementary concentration
Informations on substances - under EU/REACH :Alpha-quartz: CAS Nr.14808-60-7 - Einecs Nr.238-878-4 - R48/20 - Label: Xn; R48/20 if C = 10%
Personal precautions : see Section 8.Hazardous decomposition substances or volatiles
None
6. ACCIDENTAL RELEASE MEASURES
Miscellaneous :
Personal precautions : see section 8.Neutralising reagents:
Non relevantEnvironment:
Non relevantMiscellaneous :
Avoid dust formation.Avoid dry sweeping and use water spraying or ventilated vacuum cleaning system to prevent dust
formation.
7. HANDLING AND STORAGE
Miscellaneous :
Engineering measures,such as local dust extraction, to ensure compliance with Occupational Exposure Limits.
Avoid dust formation.In case of insufficient ventilation, wear suitable respiratory equipment. Your supplier can advise
you on safe handling, please contact him.Handling:
Avoid bulk handling susceptible to create dust.Storage:
Store in dry conditionsStore the bagged products in a way preventing accidental bursting.
Recommended packing:Multi-ply paper sacks or big-bags.
Wooden pallet with shrink film.Always keep the main pallet label.
Unsuitable packaging.Non relevant
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Exposure Controls:Approved Occupational Exposure values for total inhalable dust.
Customers are advised to check National legislation for limit values and period of referenceThe chart below mentionnes the maximal exposure limit values known in the EU for each
substance.Technical measure:
Provide appropriate exhaust ventilation and filtering at the places where dust can be generated.Provide appropriate exhaust ventilation.
For details about the following HS personal devices, please see the annex dedicated to. (Section .17)
Eyes:Wear safety glasses with lateral protection
Skin :Standard industrial clothing is suitable for installations at ambient temperatures
Do not shake the working clothes. Do not remove dust with compressed air.
Hands:Wear leather security gloves
Respiratory protection for standard installation at ambiant temperature:
Maintain adequate ventilation whenever dust is present.Consult the local reglementation.
Wear appropriete anti-dust mask (EN149:2001 FFP3)Use a filtering respiratory device, in case of airbone concentrations are expected to exceed
exposure limits.
Respiratory protection for installation on hot lining, over 100°C:Wear appropriete anti-dust mask (EN149:2001 FFP3)
Exposure scenario :
Read carefully the relevant Installation Guideline that is indicated in the Technical Data Sheet.Read carefully the relevant Exposure Scenario for borates placed as annex of the §17
Prolonged and/or massive inhalation of respirable crystalline silica dust may cause lung fibrosis, commonly referred to as silicosis. Principal symptoms of silicosis are cough and breathlessness.
Ingestion:Non relevant
Miscellaneous :Symptoms of lungoedema mostly reveal after a few hours, intensified by physical effort.
12. ECOLOGICAL INFORMATION
Comportement écologiqueAir :
Non relevantWater:
Non relevantSoil :
Non relevantEcotoxicity:
The unused product is not considered dangerous for the environmentMobility :
Non relevantDurability and biodegradablity :
Non relevantPotentially bioaccumulative :
Non relevantPBT Evaluation :
No
Persistent Organic Pollutants (POP):No
Other nocive effects :Non relevant
13. DISPOSAL CONSIDERATIONS
Potential danger from the waste:
The unused product is not considered dangerous for the environmentPlease consult local regulations and statuary European Union provisions
European waste catalogue16 03 03: inorganic wastes containing dangerous substances
Dumping measures :Used packaging should be treated in the same way as the received product
Unused material can be disposed according to local regulations and statuary EU provisionsPlease consult local regulations and statuary European Union provisions
Recycling and disposal of packaging has to be organised in cooperation with a suitable waste disposal company. The re-use of packaging is not recommended.
Waste treatment:
Please consult local regulations and statuary European Union provisionsPackaging : In all cases dust formation from residues in the packaging should be avoided and
suitable worker protection be assured.Packagings that cannot be cleaned are to be disposed of in the same manner as the product.
Miscellaneous :Before destruction and disposal of the refractory lining, customers are adviced to evaluate any
changes to the product that may be induced by the introduction of substances, or operating conditions outside the control of the Vendor
WgK: German Water hazard class (from the Administrative Regulation on substances hazardous to water -assessment):
The product, (according to German regulation) is classified as (in the sense of 17.05.1999):WGK 1: slightly hazardous to water
16. OTHER INFORMATION
Additionnal safety information:The following substances are present in the product, as announced in the §.3.Therefore, because their maximum amount are lower than those indicated in these UE directives, the product does
not need any specific label nor risk or safety sentences linked to these substances that are reminded only because of our voluntary health and safety policy.
R60: May impair fertility.R61: May cause harm to the unborn child.
Training:Workers must be informed of the presence of crystalline silica and trained in the proper use and
handling of this product as required under applicable regulations.Other informations :
This safety data sheet (SDS) has been compiled according to Directive 1999-45-CE
This safety data sheet (SDS) has been compiled according to annexe II of the CE 1907/2007 (18 december 2006) regulations concerning the adoption of REACH
The limits shown are from annex I of the European Directive 67/548 EEC modified 17th March 2007.
The limits shown are from annex VI of the GHS as of 27th June 2007.SDS status :
Modifier JP Targe Modification Date :
Modification:Modified section : 1
Modified section : 2Modified section : 3
Modified section : 4Modified section : 5
Modified section : 6Modified section : 7
Modified section : 8Modified section : 9
Modified section : 10Modified section : 11
Modified section : 12Modified section : 13
Modified section : 14Modified section : 15
Modified section : 16Acronyms and abbreviations used:
ADR: European regulation on transport of dangerous goods by road.CAS: Chemical Abstracts Service
CLP : Classification, Labelling and Packaging of chemicalsCMR : Carcinogenic, Mutagenic or Toxic for ReproductionCSA : Chemical Safety Assessment
CSR : Chemical Safety ReportDNEL : Derived No-Effect Level
DU : Downstream UsersECHA : European CHemical Agency
EINECS: European Inventory of Existing Commercial Chemical Substance.ES : Exposure Scenario
eSDS : extended Safety Data SheetGefStoffV: German regulation on hazardous substances.
GHS : Global Harmonized System of classification and labelling of chemicalsGHS/CLP: Gobally Harmonized System of Classification, Labelling and Packaging of chemicals
GLP : Good Laboratory PracticeHPV : High Production Volume chemicals
IATA: International Air Transport Association.IATA-DGR: Dangerous Goods Regulation by the International Air Transport Association
ICAO: International Civil Aviation Organization.ICAO-TI: Technical Instruction by the International Air Transport Association
IMDG: International Maritime code for Dangerous Goods.LC50: Lethal Contration, 50%.
LD50: Lethal Dose, 50%.M / I : Manufacturer / Importer
NLP : No-Longer PolymersOSOR : One Substance, One Registration
General Hospital, Wachringer courroie 18-20, 1090 Wien -Tel: +43 (1) 404 00 22 22 / +43 (1) 406 43 43
Australia:
1- South Australian Poisons Information Centre Women's and Children's Hospital, 72 King William Road North Adelaide SA 5006 - Tel: +61 82 04 72 22 - Fax: +61 82 04 60 49
Poison Information Centre National Institute of Occupational Health Meghani Nagar, Ahmedabad -India 320016 - Tel: +91-272-867351 - Fax: +91-272-866630
RSA :
Poison Information Centre, University of Cape Town, Department of Paediatrics and Child Health, Red Cross War Memorial Children's Hospital, Klipfontein Road, Rondesbosch, Cape 7700, South Africa -Tel: +27 21 658 5308 - Fax: +27 21 689 1287
Brazil:
Centro de Informacao Toxicologica, Rua Domingos Cresencio, 132/8 andar CEP 90650-090 Porto Alegre-RS - Tel: +55 51-223-6110 - Fax: +55 51 2299067