SAFETY DATA SHEET OSHA HCS (29 CFR 1910.1200) SAFETY … · OSHA/HCS status : This material is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

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1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

Trade Name : DAIKALUB 528D

Recommended Product Use : Lubricating

Restricted Uses : No limited use

Manufacturing Company or Supplier : Daishin Kako Company Ltd, 5F Makita Building, 2-5-8 Shiba Daimon, Minato-Ku, Tokyo 105-0012, JAPANTel: +81 3 34358561Fax : +81 3 34358564

Information in case of emergency : Tel: 1-949 407 7994 (USA)+81 3 34358561 (Japan)

2. HAZARDS IDENTIFICATION

OSHA/HCS status : This material is not considered hazardous by the 2012 OSHA HazardCommunication Standard (29 CFR 1910.1200)

OSHA/GHS signal word : None

OSHA/GHS pictograms : None

3. COMPOSITION/INFORMATION ON INGREDIENTS

Product description : This product is a mixture

Chemical Characterisation : Silicone Grease

Ingredients CAS Number % by weightGraphite 7782-42-5 10 - 30%

Dimethyl Polysiloxane 63148-62-9 60 - 80%Silicon dioxide 7631-86-9 < 5%

4. FIRST - AID MEASURES

General : None special

After inhalation : Remove the exposed person immediately and providefresh air. Get medical attention.

After skin contact : Promptly flush contaminated skin with soap or milddetergent and water. Contact physician if irritation continues

After eye contact : Promptly wash eyes with plenty of water while lifting theeye lids. Continue to rinse for at least 15 minutes and get medical attention.

After ingestion : Rinse mouth and throat with water. Get medical attentionimmediately.

The most important things of symptoms and effects on acute and delay :

Do not try to smell, if exposed smell lontermly, may get dizziness

Other Note to physicians : Treat symptomatically

SAFETY DATA SHEETOSHA HCS (29 CFR 1910.1200)

PBC Grease

SAFETY DATA SHEETOSHA HCS (29 CFR 1910.1200)

DAIKALUB 528D

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5. FIRE - FIGHTING MEASURES

Suitable extinguishing media : On large fires use dry chemicals, form. On small fires usecarbon dioxide (CO2), dry chemical.

Unsuitable extinguishing media : None known

Specific Hazards Arising from the Chemical : Occur irritate and poisonous gas when burningOccur explosion when heating but not easy to ignitionAs non-flammability materials, not burning but possible tooccur corrosive and toxicity fume.

Special equipment for fire-fighters : Self-contained breathing apparatus and protectiveclothing should be worn in fighting large fires involvingchemicals.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions and ProtectiveEquipment : See Section 8

Methods for Cleaning up : Observe all personal protective equipment recommendations described in this MSDSUsing absorptive tissue for chemical materials andfollowing related regulation.

7. HANDLING AND STORAGE

Handling Precautions : Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Workers must wear proper protective equipment andmust operate strictly according to relative rules.

Storage Conditions (including any� incompatibilities) :

Store in a dry frost-free area Store away from halogen, oxidizing material, alkalinematerial and Strong acids material.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ACGIH OSHAGraphite 7782-42-5 2 mg/m3 TWA 2 mg/m3 TWA

Dimethyl Polysiloxane 63148-62-9 N/A N/ASilicon dioxide 7631-86-9 N/A N/A

Engineering Controls : Recommended : Local ventilation of closed work room or total properventilation to prevent inhalation. Setting up safety shower and washing face facilities

Personal Protective Equipment

Respiratory Protection : Dust mask not required

Eye Protection : Goggles

Hand Protection : Gloves

Skin Protection : Long sleeved working clothing

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Grease

Color : Black

Odor : Slight odour

Odor threshold : No data available

pH : Not applicable

Melting point/freezing point : <-50 oC

Initial boiling point and boilingRange

: Not applicable

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Flash point : 200oC (Open cup) as base oil

Evaporation rate : <1 as base oil

Flammability (solid, gas) : Not classified as a flammability hazard

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapor pressure : Not applicable

Vapor density : 1 as base oil

Relative density : 1.19

Solubility(ies) in water : No data available

Partition coefficient n-octanol / water

: No data available

Auto-ignition temperature : >450 oC as base oil

Thermal decomposition : >200 oC as base oil

Viscosity : Not applicable

10. STABILITY AND REACTIVITY

Stability : Stable under ordinary temperature and normal pressure

Hazardous reactions : Halogen, oxidizing material, alkaline material, strongacids material, and flammable material.

Conditions to avoid : Heat, flame, spark and other source of ignition

Hazardous decomposition products : Carbon monoxide may occur by combustion.

Incompatible materials : Oxidizing agents

11. TOXICOLOGICAL INFORMATION

Product Toxicity Data : The toxicity data of this product has not been determined by testing or researchbecause of a mixture, but to our best knowledge. The toxicity data shown below is for basis oil for reference only. If a dangerous detrimental constituent exceeds a cut-off value to raw material, It indicates to the summary at thesection 2 (HAZARDS IDENTIFICATION)

Information on likely routes of exposure : Skin contact, Ingestion, Eye contact

Inhalation : Inhalation of vapours at elevated temperatures maycause respiratory irritation, coughing, sneezing, headache, and throat pain.

Ingestion : No significant health effects or gastrointestinal irritation isexpected.

Skin contact : No significant health effects or irritation is expected. Eye contact : Contact with eyes under normal product use is not

expected to cause irritation. Vapours from heated greasemay cause eye irritation, including redness, swelling, pain, and blurred vision.

Acute toxicity : Graphite LD50: >2000 mg/Kg � Oral Rat LC50: > 0.2 mg/L (4 hrs.) � Inhalation Rat

Dimethyl PolysiloxaneLD50: >5000 mg/Kg � Oral Rat LD50: >2000 mg/Kg � Dermal Rat

Silicon dioxideLD50: >3300 mg/Kg � Oral Rat LC50: > 0.139 mg/L (4 hrs.) � Inhalation Rat LD50: >5000 mg/Kg � Dermal Rabbit

Skin corrosion/Irritation : No significant irritation expected from a single short-termexposure.

Serious eye damage/eye irritation : Direct contact may cause temporary redness anddiscomfort.

Respiratory sensitization : Not classified based on available information.

Skin sensitization : Not classified based on available information.

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Germ cell mutagenicity : Not classified based on available information.

Reproductive toxicity : Not classified based on available information.

Specific target organ toxicitySingle exposure :

Graphite N/A

Dimethyl PolysiloxaneReported to be a fatal in high concentration of steamthrough animal testingMay occur to affect lung, liver, brain, kidney, spleen andpancreas

Silicon dioxideN/A

Specific target organ toxicityRepeated exposure :

Graphite When long term dust exposure, affect the lung likepneumoconiosis

Dimethyl PolysiloxaneN/A

Silicon dioxideN/A

Aspiration hazard : Not classified based on available information.

Other cautions : No data available

Carcinogenicity :NTP IARC ACGIH OSHA NIOSHN/A N/A N/A N/A N/A

12. ECOLOGICAL INFORMATION

Product Ecological Data : The ecological data of this product has not been determined by testing or researchbecause of a mixture, but to our best knowledge. The ecological data shown below is for basis oil for referenceonly. If a dangerous detrimental constituent exceeds a cut-off value to raw material, It indicates to the summary at thesection 2 (HAZARDS IDENTIFICATION)

Hazards to the aquatic environmentacute toxicity : Toxic to aquatic life. However, due to the physical form

and water-insolubility of the product the bioavailability isnegligible.

Hazards to the aquatic environmentchronic toxicity : No adverse effects on aquatic organisms are predicted

Fish toxicity : No data available

Degradability : No bioaccumulation potential.

Bioaccumulative potential : No bioaccumulation potential. This product is a solidwhich is not soluble in water and if ingested will not beabsorbed

Ozone layer : No Freon or Halon

13. DISPOSAL CONSIDERATIONS

Product : Dispose of in accordance with local regulations

Uncleansed packaging : Dispose of in accordance with local regulations

14. TRANSPORT INFORMATION

Air Transportation � IATA/ICAO :

Proper Shipping Name : Not subject to IATA codeHazard Class : Not subject to IATA code

UN Code : Not subject to IATA codePacking Group : Not subject to IATA code

Sea Transportation � IMO/IMDG :

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Proper Shipping Name : Not subject to IMDG codeHazard Class : Not subject to IMDG code

UN Code : Not subject to IMDG codePacking Group : Not subject to IMDG code

Precautions : Container should be transported in a secure position, in a well-ventilated.

15. REGULATORY INFORMATION

EPA TSCA Inventory : Graphite : Listed

Dimethl Polysiloxane : ListedSilicon dioxide : Listed

Dangerous Material Safety Control ActGraphite : N/A

Dimethl Polysiloxane : N/ASilicon dioxide : N/A

Wastes Management ActGraphite : Specified waste

Dimethl Polysiloxane : N/ASilicon dioxide : N/A

Other requirements in domestic and other countries

CERCLA regulationGraphite : Not Listed

Dimethl Polysiloxane : Not ListedSilicon dioxide : Not Listed

EPCRA 302 regulationGraphite : Not Listed

Dimethl Polysiloxane : Not ListedSilicon dioxide : Not Listed

EPCRA 304 regulationGraphite : Not Listed

Dimethl Polysiloxane : Not ListedSilicon dioxide : Not Listed

EPCRA 313 regulationGraphite : Not Listed

Dimethl Polysiloxane : Not Listed

Montreal Protocol on Substances that Deplete the Ozone LayerGraphite : N/A

Dimethl Polysiloxane : N/ASilicon dioxide : N/A

EU classification information(Fixed classification result)Graphite : N/A

Dimethl Polysiloxane : N/ASilicon dioxide : N/A

EU classification information(Hazard statement)Graphite : N/A

Dimethl Polysiloxane : N/ASilicon dioxide : N/A

US State RegulationsPennsylvania Right to Known

Graphite : 7782-42-5 10-30%Dimethl

Polysiloxane : 63148-62-9 60�80%

Silicon dioxide : 7631-86-9 < 5%

New Jersey Right to KnownGraphite : 7782-42-5 10-30%

Dimethl Polysiloxane : 63148-62-9 60�80%Silicon dioxide : 7631-86-9 < 5%

California Prop 65This product does not contain any chemicals known to State of California to cause cancer, birth defects, or anyother reproductive harm.

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The ingredients of this product are reported in the following inventoriesKECI All ingredients listed, exempt or notified. TSCA All chemical substances in this material are included on or exempted from listing on the

TSCA Inventory of Chemical Substances. AICS All ingredients listed or exempt. IECSC All ingredients listed or exempt. ENCS/ISHL All components are listed on ENCS/ISHL or exempted from inventory listing. PICCS All ingredients listed or exempt. DSL All chemical substances in this product comply with the CEPA 1999 and NSNR and are

on or exempt from listing on the Canadian Domestic Substances List (DSL).

16. OTHER INFORMATION

Date of first issue : 25 November 2014Revision Date : 31 August 2015Version : 4.0

DISCLAIMER: This data contained herein are furnished for information only and are believed to bereliable. However, Daishin Kako Company Limited. doesn�t assume responsibility for any resultsobtained by persons over whose methods are not controlled. It is the user�s responsibility to determinethe suitability of products or any production methods mentioned herein for a particular purpose, and toadopt such precautions as may be advisable for the protection of property and persons against anyhazards that may be involved in the handling and use of this product. Daishin Kako Company Limited.further disclaims any liability for consequential or incidental damages of any kind, including lost profits.

FIR No.: 196144