Applications of Fast Combustion Modes and Detonations in Industry ROCKET ENGINE WITH CONTINUOUSLY ROTATING LIQUID-FILM DETONATION S. M. Frolov 1,2,3 , I. O. Shamshin 1,2,3 , V. S. Aksenov 1,2 , I. A. Sadykov 1 , P. A. Gusev 1 , V. A. Zelenskii 4 , E. V. Evstratov 4 , and M. I. Alymov 5 1 Semenov Institute of Chemical Physics Russian Academy of Sciences Moscow, Russia e-mail: [email protected]2 National Research Nuclear University MEPhI Moscow, Russia 3 Scienti¦c Research Institute for System Analysis Russian Academy of Sciences Moscow, Russia 4 Institute of Metallurgy and Material Sciences Russian Academy of Sciences Moscow, Russia 5 Merzhanov Institute of Structural Macrokinetics and Materials Science Russian Academy of Sciences Moscow, Russia The possibility of organizing a continuous-detonation combustion of a liquid fuel ¦lm in an annular combustor of a Detonation Liquid- propellant Rocket Engine (DLRE) has been demonstrated. The near- limit mode of the longitudinally pulsating ¤¦lm¥ detonation (LPD) and the continuous spinning ¤¦lm¥ detonation (CSD) modes with one and two detonation waves circulating in the annular gap of the combustor are recorded in the ¦re tests. DOI: 10.30826/ICPCD201830 c The authors, published by TORUS PRESS S.M. Frolov et al. 397
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Applications of Fast Combustion Modes and Detonations in Industry
ROCKET ENGINE WITH CONTINUOUSLY
ROTATING LIQUID-FILM DETONATION
S.M. Frolov1,2,3, I. O. Shamshin1,2,3, V. S. Aksenov1,2,
I. A. Sadykov1, P. A. Gusev1, V.A. Zelenskii4,
E.V. Evstratov4, and M. I. Alymov5
1Semenov Institute of Chemical PhysicsRussian Academy of Sciences
Moscow, Russia3Scienti¦c Research Institute for System Analysis
Russian Academy of SciencesMoscow, Russia
4Institute of Metallurgy and Material SciencesRussian Academy of Sciences
Moscow, Russia5Merzhanov Institute of Structural Macrokinetics
and Materials ScienceRussian Academy of Sciences
Moscow, Russia
The possibility of organizing a continuous-detonation combustion ofa liquid fuel ¦lm in an annular combustor of a Detonation Liquid-propellant Rocket Engine (DLRE) has been demonstrated. The near-limit mode of the longitudinally pulsating ¤¦lm¥ detonation (LPD)and the continuous spinning ¤¦lm¥ detonation (CSD) modes withone and two detonation waves circulating in the annular gap of thecombustor are recorded in the ¦re tests.
ating on gaseous components (hydrogen [3�7], methane [5, 6, 8, 9],ethylene [10], etc.)∗. There are only a few publications on applyingliquid fuels in DLREs. The ¦rst experiments with continuous (rotat-ing) detonative combustion of a liquid fuel � gaseous oxygen mixturein an annular combustor were carried out by Bykovskii and Zhdan [6].They used kerosene, benzene, and acetone as liquid fuels and gaseousoxygen as oxidizer. Their annular combustors had the external di-ameter/length equal to 50/100, 100/100, and 280/60 mm and anannular gap of 10 mm in width. Liquid fuel was injected in the com-bustor through distributed triple-ori¦ce injectors with axial injectionof liquid fuel and two inclined impinging side jets of gaseous oxygen.The measured velocities of heterogeneous (spray) detonation rangedfrom 1750 to 2350 m/s depending on the fuel and the combustorused. The maximum de¦cit of the measured detonation velocity withrespect to the thermodynamic value calculated for the overall fuel-to-oxidizer equivalence ratio attained 30%.
∗Air-breathing rotating detonation engines and pulsed detonation rocket en-gines are beyond the scope of this article.
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At present, all prospective concepts of DLREs are based on thedistributed spraying of liquid fuel in the combustor like in conven-tional LREs. These concepts imply that the annular combustor ofthe DLRE is continuously ¦lled with two-phase gas�droplet reactivemixture and the latter is burned out in a single or several heteroge-neous (spray) detonation waves continuously rotating in the annulargap of the combustor. The shock waves leading the detonation in-duce very fast fragmentation of liquid sprays and droplets as well asfast liquid evaporation, turbulent and molecular mixing of fuel vaporwith oxygen, and spontaneous volumetric ignitions in the resultantmixture [11].In this paper, another concept of DLRE is considered. This con-
cept is based on the so-called ¤¦lm¥ detonation which was studiedextensively in the past century. Unlike spray detonation, ¦lm det-onation propagates in a strati¦ed two-phase medium consisting ofgaseous oxidizer and liquid fuel ¦lm deposited on bounding surfaces.The combustible fuel mixture in ¦lm detonation is formed because ofpartial prevaporization of the ¦lm ahead of the detonation front aswell as due to aerodynamic fragmentation of the ¦lm by the gas §owbehind the leading shock wave of the detonation front, evaporationof microdroplets entrained in the §ow, and turbulent and molecularmixing of fuel vapor with oxidizer. As in spray detonations, energyrelease in ¦lm detonation proceeds due to spontaneous volumetricignitions of the resultant mixture and subsequent fast afterburning.In 1952, Loison [12] observed detonation in such a system because
of transmitting gas detonation to an air-¦lled tube with a thin ¦lm ofa liquid fuel applied to the wall. In a large series of works by Troshinwith coworkers (see, e. g., [13�15]), ¦lm detonation was initiated byexploding lead azide charges, blasting caps, etc. in tubes 6 to 30 mm indiameter and 1.6 to 3.5 m in length. In these tubes, various liquid fuels(petroleum oils, viscous lubricants, and individual hydrocarbons) andcarbon in the form of carbon black were applied as ¦lms and layersof tens of micrometer to millimeter thickness onto the inner surfaceof the tubes, and various oxidizer gases (oxygen or oxygen-enrichedair) were used at an initial pressure of 1 to 40 atm. The measuredvelocities of ¦lm detonations ranged from 900 to 1900 m/s. The max-imum de¦cit of the measured detonation velocity with respect to thethermodynamic value calculated for the overall fuel-to-oxidizer equiv-
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alence ratio (within the detonability limits of premixed compositions)attained 60%; however, ¦lm detonations did not exhibit a fuel-richconcentration limit. Further studies were later performed by Nichollswith coworkers [16�18] and Gelfand with coworkers [19�21], and wererevisited recently by us [22, 23].
The heterogeneous gas�¦lm system has several important advan-tages for use in DLREs. Firstly, the gas�¦lm system can be addi-tionally used for active thermal protection of the walls of the DLREwhen the ¦lm is fed to the highly heated sections of the combus-tor. Secondly, in such a system, detonation can propagate virtuallyat any thickness of the liquid ¦lm (see, e. g., [14, 16]) which reducesthe requirements for the accuracy of dosing of fuel and increases thereliability of the operation process. Thirdly, in the strati¦ed gas�¦lmsystem, which is characterized by a relatively small area of the in-terface (in comparison with the gas�droplet system), the preliminaryevaporation of the liquid ahead of the propagating detonation waveis insigni¦cant, which prevents various disturbances in the operationprocess like §ame §ashback, etc.).
The objective of this work was to experimentally prove the possi-bility of organizing the continuous detonative combustion of a liquidfuel ¦lm in an annular combustor of a DLRE.
Experimental Installation and Test Procedure
Figure 1 shows a schematic of the DLRE demonstrator with a com-bustor in the form of an annular gap between the cylindrical centralbody and a coaxial outer cylindrical wall. This schematic is di¨erentfrom the DLRE schemes in which gaseous or liquid fuel is suppliedto the combustor via distributed fuel injectors in the form of gas jetsor liquid sprays. Here, the liquid fuel is supplied to the combustorthrough the outer surface of a porous ring insert of ¦nite length underthe pressure of a displacing gas (nitrogen) and forms a thin liquid ¦lmon the inner surface of the porous ring insert. The oxidizer (gaseousoxygen) is fed to the combustor through an annular gap in the axialdirection, thus promoting uniform spreading of the ¦lm along the in-ner surface of the porous insert. Film detonation is initiated with thehelp of an external initiator via transmitting the initiating shock wave
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Figure 1 Schematic of DLRE
into the annular combustor through the DLRE nozzle. The shockwave propagating above the liquid ¦lm ensures rapid mixture forma-tion and subsequent volumetric combustion of the resulting mixtureleading to the formation of a self-sustained detonation wave. The det-onation wave is capable of circulating in the annular combustor oncethe conditions necessary for its existence remain unchanged ahead ofthe wave front.The annular combustor of the DRE demonstrator (see Fig. 1) is
composed of 4 elements: a central body with a diameter of 90 mmand a length of a cylindrical section of 90 mm with a cone nozzle101 mm long made of copper; a porous ring insert with an internaldiameter of 98 mm, a length of 30 mm, and a thickness of 9 mm madeof a permeable material; clamping impermeable ring insert with aninner diameter of 98 mm, a length of 70 mm, and a thickness of 11 mmmade of copper; and the ¦ring head in the form of a knife ¡ a thincopper disk with a sharp edge blocking a part of the annular section atthe entrance to the combustor, leaving a gap of 1.2 mm. All elementsof the annular combustor are mounted in a cylindrical casing witha single end-§ange made of stainless steel. The casing contains holesfor the supply of liquid fuel (n-pentane) and the §ange contains theholes for the supply of gaseous oxidizer (oxygen). The fuel is chosen
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Figure 2 Detonation LRE withthe short nozzle attached
Figure 3 Porous ring insert
for reasons of high volatility of vapor (the boiling point of n-pentaneat atmospheric pressure is 36 ◦C). In subsequent studies, n-pentanewill be replaced by less volatile liquid fuels. In several tests, a taperingnozzle with a length of 34 mm and a cone angle of 35◦ was attachedto the open end of the combustor (Fig. 2).
Permeability of the porous ring insert was preliminarily measuredwith the help of special equipment, which made it possible to plot
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the calibration dependencies of the consumption of liquid fuel on thepressure of the displacement gas.The data acquisition system for the DLRE operation process
includes (see Fig. 1) two photosensors, low-frequency static pres-sure sensor, three high-frequency pressure sensors PT1, PT2, andPT3, and thermocouples. The photosensors with a bandwidth ofF−3dB > 2 MHz are based on the BPW34 photodiode and the AD8066operational ampli¦er. They are mounted in the end §ange in the mid-dle of the annular gap of the combustor. Low- and high-frequencypressure sensors are installed at the ends of the tubular waveguidesinserted into the central body and communicating with the annu-lar gap of the combustor. The low-frequency static pressure sensor(Courant-DA 2.5 MPa) measures the average static pressure in thecombustor at a distance of 15 mm downstream from the ¦ring head.Three high-frequency pressure sensors (Kistler 211B3) measure pres-sure pulsations at three points located at an angular distance of 120◦
from each other in one cross section of the combustor at a distanceof 30 mm downstream from the ¦ring head. Thermocouples (K type)measure the temperatures of the central body, porous ring insert, andclamping ring insert.The oxygen §ow rate is calculated based on the measured rate of
the pressure drop in the oxygen receiver. The consumption of liquidfuel is measured by a turbine §owmeter.Measurement errors: error in the frequency of the operation pro-
cess (using pressure pulsation sensors) does not exceed 3%; error inthe average static pressure in the combustor does not exceed 1%; er-ror in wall temperature does not exceed 10%; and errors in mass §owrates of fuel components are not more than 10%.
Figure 4 Photo of the DLRE exhaust plume in one of the ¦re tests
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A typical ¦re test of the DLRE demonstrator lasts 1 s. In additionto the operation process with combustion of the fuel mixture, this timeincludes the opening and closing time of the quick-acting fuel andoxidizer valves. All tests were carried out at an ambient temperatureof −3 · · ·+ 3 ◦C. Figure 4 shows a typical photograph of an exhaustplume of the DLRE demonstrator in a ¦re test.
Results and Discussion
The most important result of these experiments is the proof of the pos-sibility of organizing the continuous detonative combustion of a liquidfuel ¦lm in an annular combustor of the DLRE demonstrator. In the¦re tests, both a near-limit LPD and CSD modes with one and two¦lm detonation waves circulating in the annular gap of the combustorhave been registered.Figure 5 shows the primary recordings of two photosensors
(curves 1 and 2, right axis), the low-frequency static pressure sen-
Figure 5 Recordings of photosensors (1 and 2), static pressure sensorin the combustor (3), and high-frequency pressure sensors (4, 5, and 6) inone of the ¦re tests
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Applications of Fast Combustion Modes and Detonations in Industry
sor in the combustor (curve 3, left axis), and three high-frequencypressure sensors (curves 4, 5, and 6, left axis) in one of the ¦re tests(without an attached nozzle) with fuel component mass §ow ratesof 160 (oxygen) and 40 g/s (n-pentane) corresponding to a total fuel-to-oxidizer equivalence ratio of ∼ 0.9. In the time interval from 700to 1100 ms, an approximately constant luminescence intensity anda constant absolute mean static pressure in the combustor (0.22 MPa)are recorded. During the test, the temperature of the uncooled cen-tral body became much higher (about 100 ◦C) than the temperatureof the clamping ring insert (about 50 ◦C) despite the total mass of thecentral body and the conical nozzle (2.7 kg) was larger than the massof the clamping ring insert (2.1 kg). This e¨ect is presumably dueto cooling of the clamping-ring inner surface by the liquid ¦lm. Thetemperature of the porous ring insert cooled by displaced liquid fueldid not exceed 10 ◦C. Since this temperature is less than the boilingtemperature of n-pentane, one can assume that the fuel enters theannular gap of the combustor in the liquid state and forms a liquid¦lm on the inner surface of the porous ring insert.
Fourier analysis of the records of high-frequency pressure sensorsin the test relevant to Fig. 5 reveals a dominating frequency of theoperation process of 2.85 kHz (Fig. 6), i. e., the characteristic time ofthe quasi-stationary operation process in the combustor is ∼ 350 µs.Estimates show that during this time, the displacing system for sup-
Figure 6 Fourier transform of a fragment of records of three high-frequency pressure sensors
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Figure 7 A fragment of the records of high-frequency pressure sensors (a)and its ¤visualization¥ according to [27] (b) for the LPD mode
plying liquid fuel to the combustor provides the formation of a liquid¦lm of a thickness of about 5 µm on the inner surface of the porousring insert. An analysis of the phases of pressure pulsations showsthat in the ¦re test under consideration, a near-limit LPD mode isrealized, which is similar to the modes detected earlier in [24�26] whenoperating with gaseous components.
As a matter of fact, Fig. 7a shows a fragment of the records ofthree high-frequency pressure sensors of 2-millisecond duration at thevery beginning of the time interval 700�1100 ms. The records showregular pressure pulsations with steep fronts, and the phases of pres-sure pulsations on all three sensors are virtually (to within ∼ 100 µs)the same. This is clearly illustrated by the ¤visualization¥ of therecords of those pressure sensors shown in Fig. 7b. The records are¤visualized¥ according to the procedure described in [27]. Plottedalong the abscissa is the time (the same time interval as in Fig. 7a)
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Applications of Fast Combustion Modes and Detonations in Industry
and three pixels plotted along the ordinate correspond to pressuresensors PT1, PT2, and PT3. The white and black colors of the pixelsin Fig. 7b correspond to the maximum and minimum values of themeasured amplitude of the pressure pulsation (the pulsation ampli-tude is maximal at the detonation front and minimal in the cold gas).The pressure waves are seen to arrive to the positions of sensors PT1,PT2, and PT3 almost simultaneously but periodically, with a certaincycle. This situation is possible when a detonation wave periodically(at a frequency of ∼ 2.85 kHz) arises in the annular gap and prop-agates upstream with a large axial and relatively small tangentialvelocity components.An indirect con¦rmation of this implication can be found in the
results of measurements reported in [24�26], where the space�timewave dynamics of the onset, propagation, and attenuation of theLPD were studied, and pressure records similar to those shown inFig. 7 were obtained. Considering that the maximum rate of ¦ll-ing of the annular combustor with oxygen is approximately on theorder of the speed of sound (∼ 300 m/s), and the minimal (at thelimit of propagation) detonation velocity in the gas�¦lm system is∼ 1000 m/s [12, 14, 22, 23], the onset of LPD should occur at a dis-tance (1000− 300) · 0.00035 ≈ 0.25 m from the ¦ring head. It can bethus assumed that detonation periodically arises near the combustorexit as in experiments [24�26]: a detonation explosion occurs eitheras a result of local spontaneous ignition of a fresh fuel mixture onthe developed contact surface with the hot products of the previousdetonation wave or due to shock compression of a portion of a freshfuel mixture in the end-shock penetrating the combustor after theattenuation of the previous detonation wave. After local onset, thedetonation wave propagates upstream towards the ¦ring head, occu-pying the entire volume of the annular gap. In this case, the distancetraveled by the wave is comparable with the estimate obtained above.In addition to the near-limit LPD mode, in a number of ¦ring
tests, the CSD modes with one and two detonation waves circulatingin the annular gap of the combustor were detected. For example,Fig. 8a shows a fragment of the records of three high-frequency pres-sure sensors at the end of the operation process during the intervallasting 2 ms (in the time interval from 1490 to 1492 ms) in the same¦re test as shown in Fig. 5. The frequency of pressure pulsations
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Figure 8 A fragment of the records of high-frequency pressure sensors (a)and its visualization (b) for the CSD mode with a single rotating detonationwave
obtained with the help of Fourier transform is ∼ 2.9 kHz. As inFig. 7a, regular pulsations of pressure with steep fronts are seen onthe records; however, the pulsation phases are di¨erent. The ¤vi-sualization¥ of the records in Fig. 8b shows that a mode with onedetonation wave rotating at a tangential speed of about 900 m/s isrealized in the combustor during the time interval under considera-tion. The true normal velocity of the detonation wave is estimatedas ∼ 1000 m/s since the detonation front is inclined to the combus-tor axis due to the ¦nite ¦lling rate of the combustor by the freshmixture.
In one of the tests with an attached nozzle and with mass §owrates of fuel mixture components of 150 (oxygen) and 80 g/s(n-pentane), corresponding to a total fuel-to-oxidizer equivalence ra-tio of ∼ 2.0, the absolute mean static pressure in the combustor
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Applications of Fast Combustion Modes and Detonations in Industry
was 0.25 MPa, and the dominating frequency of the operation processturned out to be as high as ∼ 4.7 kHz. Analysis of phases of pres-sure pulsations showed that in this test, an operation process withtwo detonation waves continuously rotating in an annular gap witha tangential velocity of ∼ 730 m/s was recorded. If one takes intoaccount the ¦nite ¦lling rate of the combustor by the fresh mixture,then the true normal velocity of the detonation wave will be some-what higher (∼ 800 m/s). Such low propagation velocities of thedetonation front are possible only if the ignition of the mixture is notdetermined by the temperature behind the leading shock wave: it istoo low for fast spontaneous ignition of the fuel vapor. Following [26],under these conditions, the steady-state propagation of the detona-tion wave in the annular gap can be ensured only by ignition of thefuel mixture behind the shock wave re§ected from the compressiveexternal wall, followed by energy release in a turbulent §ame. It isworth emphasizing that the re§ection of the leading shock wave fromthe compressive external wall is the intrinsic feature of the continuousdetonation process in annular combustors [28,29]. As for turbulence,its intensity in the recirculation zone downstream from the ¦ring headis very high [28].
Concluding Remarks
Thus, the possibility of organizing the continuous detonative com-bustion of a liquid fuel ¦lm in an annular combustor of a DLRE hasbeen proved experimentally. In such a DLRE, the liquid fuel ¦lm isused both to provide a stable operation process and for active thermalprotection of the combustor walls.
Further work will be directed to a systematic study of the para-metric domains of existence of LPD and CSD modes for both liquidn-pentane and less volatile liquid hydrocarbons.
Acknowledgments
This work was ¦nancially supported by the subsidy allocated by theInstitute of Chemical Physics of the Russian Academy of Sciencesfor the execution of the State Task on the topic No. 0082-2016-0011
S.M. Frolov et al. 409
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¤Fundamental studies of the processes of transformation of energy-containing materials and the development of scienti¦c bases for con-trolling these processes¥ (State registration number No.AAAA-A17-117040610346-5).
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